WO1996032554A1 - Reusable concrete form panel sheeting - Google Patents
Reusable concrete form panel sheeting Download PDFInfo
- Publication number
- WO1996032554A1 WO1996032554A1 PCT/US1996/005118 US9605118W WO9632554A1 WO 1996032554 A1 WO1996032554 A1 WO 1996032554A1 US 9605118 W US9605118 W US 9605118W WO 9632554 A1 WO9632554 A1 WO 9632554A1
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- WO
- WIPO (PCT)
- Prior art keywords
- concrete
- concrete form
- form panel
- panel sheeting
- resins
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
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Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04G—SCAFFOLDING; FORMS; SHUTTERING; BUILDING IMPLEMENTS OR AIDS, OR THEIR USE; HANDLING BUILDING MATERIALS ON THE SITE; REPAIRING, BREAKING-UP OR OTHER WORK ON EXISTING BUILDINGS
- E04G9/00—Forming or shuttering elements for general use
- E04G9/02—Forming boards or similar elements
- E04G9/05—Forming boards or similar elements the form surface being of plastics
Definitions
- This invention relates to a new structural member that is a useful substitute for plywood and other structural materials, e.g., for general construction purposes.
- the new structural member has particular utility as a component in concrete forms that are erected for pouring a concrete member, such as a wall, floor, ceiling, deck, or the like, which forms are subsequently removed from the concrete member after the concrete has cured.
- Removable, modular concrete forms typically comprise a rectangular plywood panel sheet, e.g., high-density overlay (HDO) Douglas Fir plywood, supported by, e.g., a steel or wooden frame on the backside face and, in some embodiments, on the circumference of the panel sheet.
- HDO high-density overlay
- the concrete forms are temporarily assembled in a spaced, parallel relationship with inwardly-facing panel sheets, and fresh (liquid) concrete is poured in the cavity or hollow defined by the forms.
- the thickness of the concrete wall is established by the spacing between panel sheets, which spacing typically is maintained by wall ties.
- the height and length of the concrete wall is adjusted by adjacently interconnecting a plurality of forms to vary the height or length of the hollow.
- job-built concrete form networks and frameworks are used in the industry to construct concrete members, e.g., concrete bridges and dams.
- concrete members e.g., concrete bridges and dams.
- plywood panel sheeting typically having no prefabricated frame, is interconnected and supported with, e.g., a lumber frame that is custom-built on-sight, to meet the particular engineering specifications of the job.
- Plywood possesses a useful combination of physical properties (e.g., strength, durability, flexibility, nail retention) that make it an industry standard for use as concrete form panel sheeting. Nonetheless, plywood concrete form panel sheeting has many undesirable features and disadvantages.
- plywood is an increasingly expensive construction material made from trees, which constitute a natural resource of increasing scarcity that has been the subject of increased environmental protection in recent years.
- Standard building foundation concrete forms may be 2 feet x 8 feet (2' x 8') in size and have plywood panel sheeting that is 1/2 to 1 1/2 inches (1/2" - 1 1/2") thick.
- the weight of such forms makes the forms awkward and difficult for construction workers to maneuver and increases the cost of shipping such forms to and from a construction site. Therefore, a need exists for lighter concrete form panel sheeting, to use in construction of lighter concrete forms.
- concrete forms typically are roughly treated (e.g., during assembly for pouring a concrete structure; stripping and disassembly; and stacking for storage and transportation) .
- Conventional plywood concrete form panel sheeting requires the use of an external form release agent (e.g., form oil) which results in a further set of problems and disadvantages. More particularly, prior to pouring a concrete wall or other member, the concrete-form face (i.e., the concrete-facing face) of the plywood panel sheeting of a concrete form is oiled to prevent the plywood from adhering strongly to the concrete. Failure to oil the plywood forms results in splintering of the plywood when it is pulled from the concrete, drastically shortening the life of the concrete form. The oiling step consumes time and form oil. Thus, economic reasons create a need for oil-free concrete forms.
- an external form release agent e.g., form oil
- the oiling of concrete forms has undesirable environmental impacts, too.
- a certain amount of the form oil that is used e.g., when pouring a concrete building foundation, inevitably ends up on the ground.
- the plywood in a concrete form panel absorbs oil during each use; a conventional 2 ' x 8' panel can be expected to absorb about three pounds of oil during its useful life of 5-200 concrete pours.
- the absorbed oil softens the panel sheeting, which leads to unacceptable flexing and cracking.
- the oil-soaked plywood is worthless; safe disposal of this waste material is an environmental and economic concern of significant proportion, when one considers that at least about 500 million square feet of plywood concrete forms are produced annually.
- Plastic-coated plywood has been used successfully as concrete form panel sheeting, and some such materials will release more easily from cured concrete than HDO plywood.
- these materials typically are heavier than HDO plywood panel sheeting, and their useful life is limited due to the inability to create a durable bond between the plastic and plywood laminates. Concrete lime destroys this bond and results in delamination, particularly at nail holes and impact holes in a panel.
- the present invention is directed to a structural member that is a useful substitute for plywood and other structural materials wherever such materials are employed, e.g., for constructing walls, floors, roofs, ceilings, and the like.
- the structural member is recyclable without time-consuming and expensive separation of incompatible materials.
- the invention is directed to concrete form panel sheeting formed from a polymer resin.
- the invention is directed to a concrete form panel sheeting comprising a resinous polymer core defining a concrete-form face and an opposite (backside) face, and a concrete-facing surface layer (or "face sheet") attached to the concrete-form face of the core.
- the concrete-facing surface layer is adapted to be contacted by fresh concrete and to release from the concrete after curing thereof, to facilitate reuse of the concrete form panel sheeting.
- the invention is directed to a concrete form panel sheeting comprising a resinous polymer foam core defining a concrete-form face and an opposite face, and a concrete-facing surface layer attached to the concrete-form face of the core, the concrete-facing surface layer comprising a thermoplastic resin.
- the concrete form panel sheeting further comprises a backside surface layer attached to the opposite face of the core, the backside surface layer imparting resistance to deflection to the concrete form panel sheeting.
- the concrete form panel sheeting further comprises a stiffening means for imparting resistance to deflection to the concrete form panel sheeting, the stiffening means being integral with the resinous polymer core.
- the concrete form panel sheeting includes both a stiffening means and a backside surface layer.
- the concrete form panel sheeting of the present invention preferably answers one or more of the art-recognized needs discussed above.
- the panel sheeting is less expensive to construct and/or less expensive over the useable life of the sheeting; is lighter; is more durable; is releasable from concrete with limited application or without application of an external form release agent; is longer-lasting; and/or is recyclable.
- the invention is directed to a removable concrete form comprising (1) a concrete form panel sheeting of the present invention, and (2) a concrete form frame attached to the concrete form panel sheeting.
- Such concrete forms preferably answer one or more of the art- recognized needs discussed above.
- the invention in another aspect, relates to a concrete form network comprising a plurality of connected concrete form panel sheetings, wherein at least one of said concrete form panel sheetings is a concrete form panel sheeting of the present invention; and further comprising a support structure for maintaining the panel sheetings in a substantially fixed position when said panel sheetings are contacted by fresh concrete.
- the invention is directed to methods for creating a concrete member.
- the invention includes a method of creating a concrete member comprising the steps of: (a) defining a cavity for pouring fresh concrete, the cavity defined by at least one concrete form panel sheeting of the invention, the concrete form panel sheeting comprising, e.g., a resinous polymer core defining a concrete-form face and an opposite face, and a concrete-facing surface layer attached to the concrete-form face of the core, the concrete- facing surface layer being adapted to be contacted by fresh concrete and to release from the concrete after curing thereof, to facilitate reuse of the concrete form panel sheeting; (b) pouring concrete into the cavity; (c) curing the concrete to form a concrete member; and (d) separating the concrete member and the concrete form panel sheeting.
- the invention includes a method for creating a concrete member comprising: (a) interconnecting a plurality of concrete form panel sheetings to define a hollow, wherein at least one of the concrete form panel sheetings comprises a resinous polymer core defining a concrete-form face and an opposite face, and a concrete-facing surface layer attached to the concrete-form face of the core, the concrete-facing surface layer comprising a thermoplastic resin; (b) pouring concrete into the hollow; (c) curing the concrete to form a concrete member; and (d) separating the concrete member and the concrete form panel sheetings.
- a related aspect of the invention is a method of creating a concrete member (e.g., a wall. a deck, or other structure) using the removable concrete forms of the present invention. More particularly, the invention is directed to a method of creating a concrete member using the novel removable concrete forms described herein, comprising the steps of: (a) interconnecting a plurality of the concrete forms, the concrete-facing surface layers of the concrete forms defining a cavity; (b) pouring concrete into the cavity; (c) curing the concrete to form a concrete member; and (d) removing the concrete forms from the concrete member.
- the invention is directed to a method of creating a horizontally disposed concrete member using the novel concrete form panel sheeting described herein, comprising the steps of: (a) interconnecting a plurality of the concrete form panel sheetings, the concrete-facing surface layers thereof defining a shoring surface; (b) pouring concrete onto the shoring surface; (c) curing the concrete to form a horizontally disposed concrete member; and (d) removing the concrete forms from the concrete member.
- Fig. 1 is a perspective, partially elevated, partially cut away view of concrete form panel sheeting having a core and a concrete-facing surface layer adhered to the core with an adhesive.
- Fig. 2A is a partially-elevated perspective view, partially cut away, of concrete form panel sheeting having a core, a concrete-facing surface layer, and a backside surface layer.
- Figs. 2B and 2C are partially-elevated perspective views, partially cut away, of two embodiments of concrete form panel sheeting having a core, a stiffener integral with the core, a concrete-facing surface layer, and a backside surface layer.
- Figs. 2D-2G are partially-elevated perspective views of corrugated stiffener members having wavy, rectangular, triangular, and trapezoidal cross-sectional geometries, respectively.
- Fig. 3 is a partially-elevated, partially cut away perspective view of a rectangular concrete form having concrete form panel sheeting and a frame.
- Fig. 4 is a cross-sectional view of a portion of a concrete form, depicting the attachment of a frame to concrete form panel sheeting.
- Fig. 5 is a view of a the corner of a concrete form.
- Fig. 6 is a cross-sectional view of a portion of a concrete form, depicting an alternative attachment of a frame to concrete form panel sheeting.
- Fig. 7 is a partially-elevated perspective view, partially cut away, of a concrete form network.
- Fig. 8 is a perspective view of a portion of a concrete form network, depicting the connection of two adjacent concrete forms and a spacer.
- Figs. 9 and 10 are partially-elevated perspective views of rectangular concrete forms each having concrete form panel sheeting and a frame.
- Fig. 11 is a perspective view of a portion of a concrete form network, partially cut away, depicting the connection of two adjacent concrete forms and a spacer.
- Figs. 12 and 13 are partially-elevated perspective views, partially cut away, of concrete form networks.
- Fig. 14 is a perspective view, partially cut away, of a shoring concrete form network.
- Fig. 15A depicts tensile strength (ASTM-1)
- Fig. 15B depicts flexural strength (ASTM- C203) for varying densities of GECET* FlOO resins.
- Fig. 15C depicts flexural modulus for varying densities of GECET* FlOO resins.
- Fig. 1SD depicts co pressive strength (ASTM-D1621) for varying densities of GECET* FlOO resins at varying strains.
- Fig. 15E depicts energy impact (in foot ⁇ pounds) at room temperature using 0.375 inch samples made from GECET* FlOO resins of varying densities.
- Fig. 15F depicts energy impact (in foot- pounds) after 96 hours at 248F using 0.375 inch samples made from GECET* FlOO resins of varying densities.
- Figs. 15G - 151 depict the fastener retention properties of GECET* FlOO resins. Force (in pounds) required to remove dry wall screws (Fig 15G) , finishing nails (Fig. 15H) , and galvanized roof nails (151) from GECET* FlOO resin at different densities is depicted.
- Fig. 16A depicts tensile strength (ASTM- D1623) for varying densities of GECET* F200 resins.
- Fig. 16B depicts flexural strength (ASTM- C203) for varying densities of GECET* F200 resins.
- Fig. 16C depicts flexural modulus for varying densities of GECET* F200 resins.
- Fig. 16D depicts compressive strength (ASTM-D1621) for varying densities of GECET* F200 resins at varying strains.
- Fig. 16E depicts energy impact (in foot ⁇ pounds) at room temperature using 0.375 inch samples made from GECET* F200 resins of varying densities.
- Fig. 16F depicts energy impact (in foot ⁇ pounds) after 96 hours at 248 F using 0.375 inch samples made from GECET* F200 resins of varying densities.
- Figs. 166 - 161 depict the fastener retention properties of GECET* F200 resins. Force (in pounds) required to remove dry wall screws (Fig 16G) , finishing nails (Fig. 16H) , and galvanized roof nails (161) from GECET* F200 resin at different densities is depicted.
- Fig. 17A depicts tensile strength (ASTM- D1623) for varying densities of GECET* F300 resins.
- Fig. 17B depicts tensile strength at break in psi for varying densities of GECET* F300 resins.
- Fig. 17C depicts flexural strength (ASTM- C203) for varying densities of GECET* F300 resins.
- Fig. 17D depicts flexural modulus for varying densities of GECET* F300 resins.
- Fig. 17E depicts compressive strength (ASTM-D1621) for varying densities of GECET* F300 resins at varying strains.
- Fig. 17F depicts energy impact (in foot ⁇ pounds) at room temperature using 0.375 inch samples made from GECET* F300 resins of varying densities.
- Fig. 17G depicts energy impact (in foot- pounds) after 96 hours at 248F using 0.375 inch samples made from GECET* F300 resins of varying densities.
- Figs. 17H - 17J depict the fastener retention properties of GECET* F300 resins. Force (in pounds) required to remove dry wall screws (Fig 17H) , finishing nails (Fig. 171) , and galvanized roof nails (17J) from GECET* F300 resin at different densities is depicted.
- the concrete form panel sheeting of the present invention comprises (A) a resinous polymer core 2 defining a concrete-form face 4 and an opposite face 6, the core member being attached to (B) a concrete- facing surface layer (or "face sheet") 8 adapted to be contacted by uncured concrete and to release from the concrete after curing thereof.
- the core member may be attached to the concrete-facing surface layer by means of an adhesive layer 10, or by other suitable connection means.
- the core member itself may be constructed from multiple, attached layers of material.
- a backside surface layer (or "back sheet") 12, which may be of the same or different material as the concrete-facing surface layer 8, and
- ISA/EP - 11 - which also is attached to the core by an adhesive or other attachment means.
- the concrete form panel sheeting has a resinous polymer core 2 attached to a concrete-facing surface layer 8 and a backside surface layer 12, which may be of the same or different material as the concrete-facing surface layer 8.
- the (A) core further comprises an integral stiffener 14, the stiffener imparting resistance to deflection to the concrete form panel sheeting.
- the stiffener has substantially identical length and width dimensions as the core, the concrete-facing surface layer, and the backside surface layer. As depicted in Figs.
- the stiffener preferably has a cross-sectional geometry that extends from the concrete-form face to the opposite face of the core, i.e., extends substantially entirely through the core.
- Exemplary wavy, rectangular, triangular, and trapezoidal stiffener geometries are depicted in Figs. 2D, 2E, 2F, and 2G, respectively.
- Stiffeners having corrugated geometries, such as those depicted in Figs. 2D-2G provide increased resistance to deflection compared to a substantially planar stiffener. Corrugations in multiple directions (e.g., a waffle-shaped geometry) also are contemplated for stiffener members.
- the stiffener is manufactured having holes 16 as depicted in Fig. 2F.
- injected polymer is capable of passing through the holes to allow for the formation of a core member having an integral stiffener.
- the panel sheeting of the present invention is a useful substitute for plywood and other structural materials wherever such materials are employed, e.g., for wall, floors, roofs, ceilings, and the like.
- the concrete form panel sheeting of the present invention is useful for constructing prefabricated, modular concrete forms; for constructing custom "job-built” concrete form networks and frameworks; for shoring applications; and for other concrete forming applications in which reusable concrete form panel sheeting may be employed.
- a number of exemplary embodiments for employing the inventive panel sheeting are depicted in Figs. 3-14, as described below.
- the invention is also embodied in a removable concrete form comprising (D) a concrete form support frame structure attached to the basic embodiment [(A) + (B) ] and/or the embodiment [ (A) + (B) + (C) ] of the novel concrete form panel sheeting.
- the support frame imparts rigidity to the panel sheeting, protects edges and corners of the panel sheeting from damage, provides support and strength to the panel sheeting such that it can withstand increased pressure from fresh (liquid) concrete, and/or provides attachment structure for interconnecting the concrete form to additional concrete forms.
- the concrete form frame includes edge members 32, 34, 36, and 38 that surround the circumference of the panel sheeting 40 to protect the edges and corners of the panel sheeting from damage and to provide structure for attachment to additional concrete forms.
- edge - 13 - members are attached to the panel sheeting 40 by means of a screw 42, rivet 44, nail 46, or like member.
- the rivet 44 extends through the concrete-facing surface layer 8, the core 2, the backside surface layer 12, and through an attachment flange 48 that is attached to or integral with the frame edge member 38 and that is adjacent to the backside of the panel sheeting 40.
- Adjacent edge members themselves are attached to or integral with each other, e.g., by screws, solder, or weld.
- adjacent edge members may be joined by corner supports 50, and opposite edge members may be joined by one or more cross-supports 52.
- Such frames may be provided with one or more handles 54.
- Such a frame may be manufactured from a metal such as steel or aluminum; alternative materials will be apparent to those in the art.
- a concrete form network for pouring a wall or other concrete member of a desired height and width is constructed by interconnecting a plurality of concrete forms, end to end.
- edge members 32, 34, 36, and 38 are formed having one or more apertures 80.
- Connecting hardware 82 permits construction workers to quickly join adjacent forms for pouring concrete, and subsequently disassemble such forms quickly after the concrete has cured.
- the thickness of a concrete member is determined by the distance between the oppositely- - 14 - oriented concrete-facing surfaces 8A and 8B of concrete form networks 100A and 100B that have been assembled as described above. This distance is maintained, and the oppositely-oriented form networks are attached, using spacers (or "ties") 110 oriented perpendicular to the panel sheetings of the networks and attached to the edge members 32, 34, 36, and/or 38 of forms that comprise each network. More particularly, the edge members have one or more recesses 112, and the recesses of the abutting edge members of two adjacent concrete forms in a network define a channel through which a spacer 110 is placed. To secure a spacer to a form network (Fig.
- connecting hardware 82 is passed first through an aperture in the recessed portion 112C of the edge member 36C of a first concrete form in the network, then through an aperture in the spacer 110, then through an aperture in the recessed portion 112D of the edge member 32D of an abutting concrete form in the network.
- the connecting hardware is in turn secured with additional connecting hardware 82A.
- FIG. 3 Numerous variations of the modular concrete form depicted in Fig. 3 are known in the art, and can be fitted with concrete form panel sheeting of the present invention.
- frame edge members 32, 34, 36, and 38 are attached to the backside face 6 (or the backside surface layer, if employed) of the panel sheeting 40, and the edges 132 of the panel sheeting are exposed.
- the panel sheeting edges 132 of adjacent forms fit flush against each other, with no interruption by frame edge members.
- the concrete form depicted in Fig. 9 has, in addition to cross-supports 52, perpendicular cross-supports 152.
- FIG. 10 depicts a concrete form having a frame with no edge members.
- Cross-supports 52 are attached to the backside of the panel sheeting 40 by means of rivets 44.
- the construction of a concrete form network with a plurality of the forms is facilitated by recesses 180 in the concrete form panel sheeting, corresponding recesses 112 in the cross-support frame members, pivoting attachment hardware 182, and flanges 184. As depicted in Figs.
- FIG. 12 depicts a concrete form framework, comprising two concrete form networks, erected atop a cement footing 196. - 16 -
- Adjacent concrete form panel sheets 40A, 4OB, and 40C are interconnected with rods 204 and further secured with waler beams 208 constructed of, e.g., aluminum or lumber.
- Spacers 210 pass through apertures 212 in the panel sheeting.
- the rods 204 pass through apertures defined by the spacers.
- the rods and spacers cooperate to prevent opposite form networks 200A and 200B from separating when liquid concrete is poured into the hollow defined by the concrete form framework, but the rods themselves are not physically attached to the panel sheeting with, e.g., a nail, screw, rivet, or the like.
- Additional top spacers 216 cooperate with the rods, walers, and spacers 210 to maintain the fixed positions of the opposite form networks that comprise the concrete form framework.
- the concrete form panel sheeting of the present invention has excellent utility as a plywood substitute in the construction of custom "job-built” concrete form networks and frameworks.
- the panel sheeting 40A and 40B in job-built networks and frameworks is interconnected using metal bars (e.g., steel or aluminum bars) , wooden beam supports, or the like.
- the supports 250 are attached to the panel sheeting to maintain the sheeting in a fixed position and to provide load-bearing support, and connected to each other with additional supports 252 to erect concrete. form networks and frameworks of any desired size or shape.
- Job-built concrete form networks and frameworks are well-known in the art, e.g., for the construction of bridges and dams, and may be connected to prefabricated concrete forms if desired.
- the lighter concrete form panel sheeting preferred for the present invention is particularly - 17 - advantageous, compared to plywood, in many job-built applications because relatively thick (e.g., 1.125 inches or more) sheeting is often employed in such applications, and because such panel sheeting is manipulated without attached frame structures during assembly and disassembly of the concrete form networks and frameworks.
- plywood concrete form panel sheeting is planar and rectangular in shape, e.g., 2' x 8' in dimension.
- This size and shape has proven useful for pouring, e.g., concrete walls having essentially planar surfaces, and this is a preferred shape and dimension for the concrete form panel sheeting and concrete forms of the present invention.
- the concrete form panel sheeting of the present invention can be made to have essentially any desired shape and dimension, and a steel or other frame can readily be constructed to match any shape of panel sheeting that is constructed.
- Frame adapters can be constructed to attach adjacent frames at preselected angles.
- Shoring concrete form networks for pouring horizontal concrete members constitute another significant application for the concrete form panel sheeting of the present invention.
- a typical shoring structure includes a tower comprising two support frameworks 300A and
- the core (A) of the panel sheeting comprises a resinous polymer.
- resinous polymer is meant any suitable polymer resin.
- Preferred resinous polymers are thermoplastic resins.
- thermoplastic resin is intended to include any suitable thermoplastic resin, particularly engineering thermoplastic resins possessing superior mechanical properties.
- suitable thermoplastic resins include, but are not limited to, homopolymers or copolymers of polyphenylene ethers, aromatic polycarbonates, polyesters, polyamides, polyarylates, polyetherimides, polysulfones, polyolefins, combinations of more than one of the foregoing, and combinations of one or more of the foregoing with an alkenyl aromatic polymer.
- the polyphenylene ether (PPE) (commonly referred to as polyphenylene oxide) resin is normally a homopolymer or copolymer having units of the formula - 19 -
- Q", and Q" ' are independently selected from the group consisting of hydrogen, halogens, hydrocarbons, halohydrocarbons, hydrocarbonoxys, and halohydrocarbonoxys; and n represents the total number of monomer units and is an integer of at least about 20, and more usually at least 50.
- the polyphenylene ether resin can be prepared in accordance with known procedures, such as those described in U.S. Pat. Nos. 3,306,874 and 3,306,875, from the reaction of phenols, including but not limited to: 2,6-dimethyIphenol; 2,6- diethyIphenol; 2,6-dibutyIphenol; 2,6- dilauryIphenol; 2,6-dipropyIphenol; 2,6- diphenyIphenol; 2-methyl-6-tolyIphenol; 2- methoxyphenol; 2,3,6-trimethylphenol; 2,3,5,6- tetramethyIphenol, 2,3,5,6-tetraethylphenol and 2,6- diethoxyphenol.
- phenols including but not limited to: 2,6-dimethyIphenol; 2,6- diethyIphenol; 2,6-dibutyIphenol; 2,6- dilauryIphenol; 2,6-dipropyIphenol; 2,6- diphenyIphenol; 2-methyl-6-tolyIphenol
- homopolymers examples include: poly(2,6-dimethyl-l,4-phenylene ether) , poly(2,6-diethyl-l,4-phenylene ether), poly(2,6-dibutyl-l,4-phenylene ether) , poly(2,6-dilauryl-l,4-phenylene ether) , poly(2,6-dipropy1-1,4-phenylene ether) , poly(2,6-diphenyl-l,4-phenylene ether) , - 20 - poly(2-methyl-6-tolyl-l,4-phenylene ether) poly(2-methyl-6-methoxy-l,4-phenylene ether) poly(2-methy1-6-buty1-1,4-phenylene ether) poly(2,6-dimethoxy-l,4-phenylene ether) , poly(2,3,6-trimethyl-l,4-phenylene ether) , poly(2,3,5,6-
- copolymers examples include especially those of 2,6-dimethyIphenol with other phenols, such as poly(2,6-dimethyl-co-2,3,6- trimethyl-1,4-phenylene ether) and poly(2,6- dimethyl-co-2-methyl-6-butyl-l,4-phenylene ether) .
- an especially preferred family of polyphenylene ethers includes those having alkyl substitution in the two positions ortho to the oxygen ether atom, i.e., those of the above formula where Q and Q' are alkyl, most preferably having from 1 to 4 carbon atoms.
- Illustrative members of this class are: poly(2,6-dimethy1-1,4-phenylene)ether; poly(2,6-diethyl-l,4-phenylene)ether; poly(2-methy1-6-ethyl,1, -phenylene)ether; poly(2-methyl-6-propyl-l,4- phenylene)ether; poly(2,6-dipropy1-1,4-phenylene)ether; poly(2-ethyl-6-propyl-l,4-phenylene)ether; and the like.
- poly(2,6-dimethy1-1,4-phenylene)ether poly(2,6-diethyl-l,4-phenylene)ether
- poly(2-methy1-6-ethyl,1, -phenylene)ether poly(2-methyl-6-propyl-l,4- phenylene)ether
- poly(2,6-dipropy1-1,4-phenylene)ether poly(2-ethyl-6-prop
- a highly preferred polyphenylene ether resin for purposes of the present invention is poly(2,6-dimethy1-1,4-phenylene)ether.
- Low density foams comprising polyphenylene ether or its copolymers as the primary high polymer component blended with low molecular weight additives, such as triaryl phosphates, fatty amides, plasticizers, brominated BPA derivatives, brominated diphenyl ethers, oligomeric styrenics and hydrogenated derivatives thereof, or esters are also included within the scope of polymers for constructing the core of the invention.
- low molecular weight additives such as triaryl phosphates, fatty amides, plasticizers, brominated BPA derivatives, brominated diphenyl ethers, oligomeric styrenics and hydrogenated derivatives thereof, or esters are also included within the scope of polymers for constructing the core of the invention.
- thermoplastic polyphenylene ether resin can be used alone or modified (e.g., in combination with) at least one other substance, preferably with a polymer, more preferably with an alkenyl aromatic polymer.
- alkenyl aromatic polymer is intended to encompass homopolymers as well as copolymers and terpolymers of alkenyl aromatic compounds with one or more other materials.
- the alkenyl aromatic polymer is based at least in part on units of the formula
- R 1 and R 2 are selected from the group consisting of lower alkyl or alkenyl groups of from 1 to 6 carbon atoms and hydrogen;
- R 3 and R 4 are selected from the group consisting of chloro, bromo, hydrogen, and lower alkyl of from 1 to 6 carbon atoms;
- R 5 and R 6 are selected from the group - 22 - consisting of hydrogen and lower alkyl and alkenyl aromatic groups of from 1 to 6 carbon atoms; or R 5 and R 6 may be concatenated together with hydrocarbyl groups to form a naphthyl group.
- the above will encompass styrene, as well as homologs and analogs of styrene.
- styrene examples include, in addition to styrene, chlorostyrene, bromostyrene, alpha-methyl styrene, para-methyl styrene, vinyl styrene, divinyl-benzene and vinyl naphthalene.
- Substantially atactic styrene is especially preferred.
- alkenyl aromatic is intended to include modified alkenyl aromatic compounds, such as rubber modified, high impact alkenyl aromatic resins known in the art.
- Suitable rubber modifiers which can be in admixture or interpolymerized with the alkenyl aromatic resin, include natural rubber, as well as synthetic rubbers, such as polyisoprene, polybutadiene, polychloroprene, ethylene-propylene- diene terpolymers (EPDM rubber) , styrene-butadiene copolymers (SBR rubber) , styrene-acrylonitrile copolymers (SAN) , ethylene-propylene copolymers (EPR rubber) , acrylonitrile rubbers, polyurethane rubbers and polyorganosiloxane (silicone) rubbers.
- EPDM rubber ethylene-propylene- diene terpolymers
- SBR rubber styrene-butadiene copolymers
- Polyphenylene ether (PPE) resins and polystyrene (PS) resins are combinable in wide proportions, e.g., from about 1 to 99 to about 99 to about 1 parts by weight. It is contemplated, however, that low density compositions of the present invention comprise at least two weight percent PPE (based upon the weight of PPE and PS taken together) . Compositions containing less than two weight percent PPE are considered to be primarily polystyrene compositions and do not generally exhibit the preferred property - 23 - improvements associated with PPE/PS blends.
- PPE/PS blends useful in the practice of the present invention comprise between 10 to 90 percent, and preferably 15 to 80 percent by weight PPE and 90 to 10 percent, preferably 80 to 15 percent by weight PS based upon the weight of the two resins taken together. More preferably, blends of 15 to 50 percent PPE and 85 to 50 percent PS are employed.
- PPE/PS blends are well described in the literature, including U.S. Patent No.
- the polyphenylene ether resin may further comprise a flame retarding agent.
- a flame retarding agent e.g., chlorine-and/or bromine-containing
- phosphorous- containing compounds e.g., organophosphate compounds
- nitrogen-containing compounds e.g., me1amine
- fluoropolymers e.g., PTFE
- the flame retardant agent may be used alone or in combination with a flame retardant synergist such as an antimony compound (e.g., antimony trioxide) , a molybdenum compound, hydrated alumina, and the like.
- a flame retardant synergist such as an antimony compound (e.g., antimony trioxide) , a molybdenum compound, hydrated alumina, and the like.
- thermoplastic resin includes aromatic polycarbonates.
- the aromatic polycarbonates can be polymers of dihydric phenols and carbonate precursors.
- the dihydric phenols that can be employed are bisphenols such as bis(4-hydroxyphenol) methane, 2,2-bis(4- hydroxyphenyl) propane (hereinafter referred to as bisphenol-A) , 2,2-bis(4-hydroxy-3-methylphenyl) propane, 4,4-bis(4-hydroxyphenyl) heptane, 2,2- bis(4-hydroxy-3,5-dichlorophenyl) propane and 2,2- bis(4-hydroxy-3,5-dibromophenyl) propane; dihydric phenol ethers such as bis(4-hydroxyphenyl) ether, bis(3,5-dichloro-4-hydroxypheny1) ether, etc.
- dihydroxydiphenols such as p,p'-dihydroxydiphenyl, 3,3'-dichloro-4,4'-dihydroxydiphenyl
- dihydroxyaryl sulfones such as bis(4-hydroxypheny1) sulfone, bis(3,5-dimethy1-4-hydroxypheny1) sulfone
- dihydroxy benzenes such as resorcinol and hydroquinone
- halo- and alkyl-substituted dihydroxy benzenes such as l,4-dihydroxy-2,5-dichlorobenzene, l,4-dihydroxy-3- methylbenzene, etc.
- dihydroxy diphenyl sulfoxides such as bis(4-hydroxypheny1) sulfoxide and bis(4-hydroxyphenol) sulfoxide and bis(3,5- dibromo-4-hydroxyphenol) sulfoxide.
- a variety of additional dihydric phenols are also available to provide
- aromatic carbonate polymers are copolymers prepared from any of the above which have been copolymerized with halogen-containing dihydric phenols such as 2,2- bis(3,5-dichloro-4-hydroxyphenyl) propane, 2,2- bis(3,5-dibromo-4-hydroxyphenol) propane. Also employed in the practice of the invention may be - 25 - blends of any of the above materials to provide the aromatic carbonate polymer.
- the carbonate precursor may be either a carbonyl halide, a carbonate ester, or a haloformate.
- the carbonyl halides which can be employed herein are carbonyl bromide, carbonyl chloride, and mixtures thereof.
- Typical of the carbonate esters which may be employed herein are diphenyl carbonate; di-(halophenyl) carbonates such as di-(chlorophenyl) carbonate, di-(bro ophenyl) carbonate, di-(trichlorophenyl) carbonate, di- * (chloronaphthyl) carbonate, and di-(tribromophenyl) carbonate; di-(alkylphenyl) carbonates such as di- (tolyl) carbonate, di-(naphthyl) carbonate, phenyl tolyl carbonate and chlorophenylchloronaphthyl carbonate, or mixtures thereof.
- diphenyl carbonate di-(halophenyl) carbonates such as di-(chlorophenyl) carbonate, di-(bro ophenyl) carbonate, di-(trichlorophenyl) carbonate, di- * (chloronaphthyl) carbonate
- haloformates suitable for use herein include bis-haloformates of dihydric phenols (bischloroformates of hydroquinone) or glycols (bis-haloformates of ethylene glycol, neopentyl glycol, or polyethylene glycol). While other carbonate precursors will occur to those skilled in the art, carbonyl chloride, also known as phosgene, is preferred.
- the polycarbonates are prepared by methods well-known to those skilled in the art.
- the polyesters include linear saturated condensation products of diols and dicarboxylic acids, or reactive derivatives thereof. Preferably they will comprise condensation products of aromatic dicarboxylic acids or esters and aliphatic diols. It is also possible to use polyesters such as poly(l,4-dimethylolcyclohexane dicarboxylates, e.g., terephthalates) . In addition to phthalates, small amounts, e.g., from 0.5 to 15% by weight, of other aromatic dicarboxylic acids, such as naphthalene - 26 - dicarboxylic acid, or aliphatic dicarboxylic acids, such as adipic acid, can also be present in the compositions.
- polyesters such as poly(l,4-dimethylolcyclohexane dicarboxylates, e.g., terephthalates) .
- small amounts e.g., from 0.5 to 15% by weight, of other aromatic dicar
- poly(butylene terephthalate) copolyester resins are also included.
- aliphatic dicarboxylic acids e.g., of up to 50 carbon atoms, including cycloaliphatic, straight and branched chain, acids, such as adipic acid, cyclohexanediacetic acid, dimerized C 16 -C 18 unsaturated acids (which have 32 to 36 carbon atoms) , trimerized such acids, and the like.
- the units in the copolyesters can also be minor amounts derived from aromatic dicarboxylic acids, e.g.
- polyamide resins useful in the practice of the present invention are a generic family of resins known as nylons, characterized by the presence of an amide group (-CONH-) Nylon-6 and nylon-6,6 are the generally preferred polyamides and are available from a variety of commercial sources.
- Other polyamides, however, such as nylon-4, nylon- 12, nylon-6,10, nylon-6,9, or others such as the amorphous nylons may be useful for particular applications.
- the polyolefin resin useful in the practice of the present invention includes polyethylenes, polypropylenes, polyisobutylenes, copolymers of olefins, such as of ethylene and propylene, as well as copolymers of olefins (e.g., ethylene) and organic esters such as ethylene vinyl acetate, ethylene ethyl acetate, ethylene methylacrylate, and the like. These are commercially available or are otherwise prepared from known teachings.
- a useful resinous polymeric material for formation of the concrete form panel sheeting core is selected by consideration of a material's - 28 - physical properties, which can be measured with standard mechanical tests and compared, for reference, against the physical properties of conventional HDO plywood concrete form panel sheeting.
- concrete form panel sheeting desirably is relatively rigid, so as to withstand the lateral force exerted on a concrete form by fresh (liquid) concrete.
- ACI American Concrete Institute
- a concrete form (comprising concrete form panel sheeting) cannot flex more than 1/16 of an inch or more than 1/360 the length of the form's longest dimension.
- a typical 2' x 8' x 1/2" concrete form desirably is capable of withstanding, e.g., 1000 lbs./ft 2 pressure, and greater strength is desirable because it permits the concrete to be poured more quickly. While an integral stiffener and one or more surface layers of the panel sheeting of the invention contribute(s) significantly to the strength of the panel sheeting, a core material should be selected that contributes to this property of the panel sheeting. At the same time, selection of a material that is less dense (and hence lighter in weight) than HDO plywood is highly preferred. Concrete form panel sheeting preferably is attached to a concrete form frame or support structure by means of screws, nails, rivets, or the like.
- preferred core materials are sufficiently ductile such that a nail hole can be drilled, or preferably formed by hammering a nail, into the core without cracking the core.
- the core should possess good nail/screw retention characteristics.
- the core also must withstand the physical abuse likely to be encountered in the field, particularly in an embodiment wherein the - 29 - panel sheeting consists of a core and a concrete- facing surface layer, but no backside surface layer.
- the core material also should be resistant to the environment encountered when pouring concrete. Thus, the material should be capable of withstanding temperatures of, e.g., 20°F to 180°F without cracking, warping, appreciable shrinkage, or appreciable expansion.
- the core material also is capable of withstanding temperatures below -20°F, to permit year-round outdoor storage of the panel sheeting and concrete forms made therefrom.
- the behavior of the core material at different temperatures should be compatible with the behavior of the other materials with which the core cooperates during a pour, such as the concrete- facing surface layer, a backside surface layer, an integral stiffener, and/or a wooden or metal frame.
- the core material preferably is selected to be compatible with the material selected to form a concrete-facing surface layer (B) ; the material selected to form an optional backside surface layer (C) ; and the material selected to form an optional integral stiffener.
- the core and concrete-facing surface layer most preferably are formed from materials that will form a strong, chemically-resistant bond. Also, the materials are selected to have similar coefficients of thermal expansion and contraction. Because a highly preferred aspect of the inventive panel sheeting is that it possess reduced weight, relative to conventional HDO plywood panel sheeting, a highly preferred resinous polymer core is a foam (e.g., closed or open cell) polymer core. A closed cell polymer is preferred.
- foaming (expanding) resinous polymers are well-known in the art and described in the literature.
- methods are known for imbibing polymer resin beads with a blowing agent, which beads may be expanded (e.g., in a heating operation) at a later time for formation into a foamed article.
- the foam core itself may be formed from the expandable or expanded resinous polymers by well- known means, e.g. , by extrusion (see, e.g. , Allen et al., U.S. Patent No. 4,857,390, incorporated herein by reference) or as a molded article (e.g., by expandable bead molding or steam chest molding) .
- thermoplastic polymer core of the inventive structural member comprise - 31 - foamed or foamable modified polyphenylene ether resins, expanded or expandable polyolefins, (e.g., expanded polypropylene, expanded polyethylene) , expanded or expandable polyolefin copolymers or blends (e.g. polystyrene/polyethylene blends such as ARCELTM) , or foamed or foamable polyurethanes.
- Preferred compositions for forming the thermoplastic polymer core of the inventive structural member comprise foamed or foamable modified polyphenylene ether resins having compositions described above. More preferably, the core is formed from PPE/PS blends.
- the core is formed from high performance expandable PS/PPE particles, developed by General Electric Company (GE) and Huntsman Corporation (HC) and commercially available from HC (Peru, Illinois) as GECET* expandable engineering resins.
- GE Plastics produces a base resin, to which HC imbibes a blowing agent and various additives to produce a class of resin beads having the following general composition: poly(phenylene oxide) (PPO* resin) , 1-99 wt.%; polystyrene (PS), 1-99 wt.%; pentanes, 6.5 wt.% max.; - 32 - halogenated organic flame retardants, 0.9 wt.% max. ; plasticizers, 0.4 wt.% max.; external and internal lubricants, 0.3 wt.% max. ; and
- GECET* resin beads of 0.01 - 0.1 inches in diameter, having a specific gravity of 1.14-1.18 and a softening point of 215 - 250°F, are commercially available in three grades: GECET* FlOO RESINS, GECET ⁇ F200 RESINS, and GECET* F300 RESINS. Typical properties of these three materials, as provided by the manufacturer, are shown in Figs. 15A-15I, Figs. 16A-16I, and Figs. 17A-17J, respectively.
- All three GECET* grades possess excellent resistance to acids (e.g., concentrated HC1, concentrated H 2 S0 4 , acetic acid, and oleic acid), bases (e.g., 30% KOH) , petroleum products (e.g., diesel fuel, kerosene, motor oil, and Murphy's Oil Soap), and lubricating oils (e.g., mineral oil and, cotton seed oil).
- acids e.g., concentrated HC1, concentrated H 2 S0 4 , acetic acid, and oleic acid
- bases e.g., 30% KOH
- petroleum products e.g., diesel fuel, kerosene, motor oil, and Murphy's Oil Soap
- lubricating oils e.g., mineral oil and, cotton seed oil.
- Grade FlOO resin having a density range of 2.5-40 lbs./ft 3 , offers the widest range of mechanical properties and moderate heat resistance.
- Grade F200 having a density range of 3.5-40 lbs./ft 3 , offers medium heat resistance (usable with temperatures up to 230°F) .
- Grade F300 has a density range of 4.5-40 lbs/ft 3 and is usable at temperatures up to 250°F.
- GECET* FlOO and GECET* F200 resins are preferred for the present invention.
- GECET* F300 is preferred.
- impregnated GECET* resin beads at a bulk density of about 40 lbs./ft 3 are heated with steam or hot air in a steam-jacketed pre-expander or similar apparatus to expand the beads to a desired density.
- Final densities of 2-30 lbs/ft 3 , preferably 5-15 lbs./ft 3 , and more preferably 6 - 10 lbs./ft. 3 are preferred, because cores of lower densities may exhibit nail retention problems, and cores of greater densities are undesirably heavy and more expensive to process into finished panel sheeting.
- Exemplary processing conditions using a high temperature steam jacketed expander are provided in Table I:
- the expanded GECET resin beads are injected into a steam chest mold (which may be coated with Teflon* resins or the like to facilitate removal of molded articles) via vacuum transfer and fused under pressure to form a core of - 34 - desired density.
- a steam chest mold which may be coated with Teflon* resins or the like to facilitate removal of molded articles
- Exemplary molding conditions are provided in Table II:
- the expanded GECET* resin beads are formed into a core by extruding the beads with an extruder to form a sheet of desired thickness (e.g., 0.25" to 1.5"), and cutting the sheet into core members of desired dimensions.
- extrusion may be a preferred method for reasons of cost.
- Other methods for constructing a GECET core, including pultrusion methods, will be apparent to those in the art.
- a preferred supplier of a GECET foam core suitable for the present invention is - 35 -
- CARILTM expandable engineering beads manufactured and sold by Shell Nederland Che ie B.V. (The Netherlands) and marketed by GE Plastics Europe (The Netherlands) , comprise an alternative polystyrene/polyphenylene ether material suitable for forming the core of the concrete form panel sheeting.
- Such beads supplied in multiple grades (e.g., CARILTM EX402, CARILTM EX403, CARILTM EX404) , provide heat resistance up to about 120°C (glass transition temperature of 110 - 130°C for the aforementioned grades) .
- the raw spherical beads (which contain about 6% of pentane expansion agent) are pre-expanded with steam, dried, and molded
- Structural members formed from such materials may absorb undesirably large volumes of water and may change shape in response to changes in water content.
- the core (A) of the concrete form panel sheeting includes an integral stiffener, which stiffener imparts resistance to deflection to the panel sheeting.
- Such stiffeners may be composed of, e.g., commercially-available sheet metal (aluminum or - 36 - steel, for example) or polymer resin materials (including fiber-reinforced polymer materials) such as the polymer materials described herein for face sheets and back sheets.
- a stiffener member having (i) a length and width corresponding to the length and width dimensions of the concrete form panel sheeting (e.g., 2' x 8'); (ii) a desired corrugation geometry (e.g., trapezoidal); (iii) a corrugation depth less than or equal to the thickness of the core member of the concrete form panel sheeting; and (iv) holes to facilitate manufacture of the core via injection molding procedures.
- a desired corrugation geometry e.g., trapezoidal
- a corrugation depth less than or equal to the thickness of the core member of the concrete form panel sheeting
- holes to facilitate manufacture of the core via injection molding procedures.
- a concrete form panel sheeting having the dimensions of 2' x 8' x 1/2" may be constructed having a face sheet of 2' x 8' x 1/16", a back sheet of 2' x 8' x 1/16", a core of 2' x 8' x 3/8", and a 2' x 8' stiffener integral with the core and having corrugation to provide the stiffener with 3/8" depth.
- An exemplary aluminum stiffener for a 2' x 8' x 1/2" panel is stamped from 14 gauge aluminum and has a trapezoidal corrugation geometry that repeats about every 2 - 3 inches. To manufacture a core member having an integral stiffener, the stamped stiffener member is placed into a steam chest mold.
- Expanded GECET* resin beads are injected into the steam chest mold as described above, the filling of the mold being facilitated by the perforations (e.g., 0.25 - 2 inches in diameter) in the stiffener.
- the stiffener has one to five large holes 18 (e.g., 20 - 40 mm in diameter) , spaced to correspond with the location of one to five polymer bead injectors of - 37 - the steam chest mold, and a plurality of smaller holes 16 (e.g., 10 - 20 mm in diameter) to facilitate flow-through during the molding process (to form an integral core structure) while maintaining the strength of the stiffener. Fusion of the beads under pressure forms a core having an integral stiffener.
- the concrete form panel sheeting of the present invention is intended to be reusable, and consequently an essential property of the concrete-facing surface layer is that the layer be adapted to be contacted by fresh (liquid) concrete and to release from the concrete after the concrete has cured.
- concrete is meant those concretes used in the construction industry, which typically contain hydraulic cements (e.g., Portland cement) having some or all of the following common constituents, which chemically react during the curing process of the concrete: calcium oxide (CaO) ; silicon dioxide (Si0 2 ) ; aluminum oxide - 38 -
- the panel sheeting of the invention may be employed in conjunction with masonry cements, oil well cements, refractory cements, and other specialty cements known in the art, without departing from the teachings herein.
- the surface layer must, at a minimum, be resistant to chemical or thermal degradation by the concrete, before and during curing thereof.
- the concrete-facing surface layer should neither react with nor absorb water, fresh concrete, or components thereof.
- a surface layer is "adapted to release from concrete after the concrete has cured" if concrete form panel sheeting comprising the surface layer can be separated from the cured concrete (l) without damaging the concrete member, while (2) maintaining the integrity of the panel sheeting, such that the panel sheeting subsequently can be reused. More preferred embodiments of panel sheeting comprise a surface layer requiring less force to release from cured concrete. Preferably, the surface layer is adapted to release from cured concrete with minimal application of an external form release agent or without application of an external form release agent.
- the concrete facing surface layer must also be capable of withstanding other conditions encountered by concrete forms in the field.
- the concrete-facing surface layer desirably is impact resistant, scratch resistant, and - 39 - sufficiently ductile such that it can be neatly penetrated with a drill or nail, all over the broad temperature ranges likely to be encountered at a job site.
- the core and concrete-facing surface layers should be made from compatible materials to ensure that a strong, chemically resistant bond may be formed therebetween. Lighter concrete-facing surface layers are preferred, though this feature is more important for the core, which generally occupies the major volume of the panel sheeting.
- the tests used to arrive at preferred materials of the invention included a concrete adhesion test to measure the ease with which a material releases from cured concrete; a penetration test to measure the ease with which a nail may be driven through and removed from a material and the cleanness of penetration; scratch-resistance tests; impact resistance tests; and cleanup tests to measure the ease with which a material can be cleaned for reuse in a subsequent concrete pour.
- a concrete form framework was assembled using industry-standard, steel-framed and plywood-faced concrete forms, resting on a - 40 - plywood base.
- a 1/8 to 3/4 inch thick test sheet of a candidate surface material (5.25 to 9.75" long x 7 to 11.75" inches high) was labelled and attached to the concrete-form face of one of the concrete forms, using double-sided tape.
- Similar adhesion tests were performed with 1/2" thick samples of high density overlay Douglas Fir plywood, cut to the same dimensions and treated with Symons® Magic Kote® form oil. Concrete (5 bag #57 AE 3000PSI mix) was shoveled into the hollow defined by the concrete forms to cover all but the top 1/2 inch of the test sheet samples.
- test samples adhered to the concrete after the concrete form framework was disassembled.
- a clip was attached to the center of the top edge of the sample and also connected to a 50 pound capacity hanging straight scale, calibrated in 8 ounce increments. Force was applied to the scale assembly, in a direction perpendicular to the plane of the test sample until the sample sheet released from the concrete. A separate observer recorded the maximum force applied before release.
- This adhesion test was repeated as - 41 - many as 29 times for a given sample, and was performed on samples that had been test scratched as described below and samples that had been frozen to 30°F to simulate varying environmental conditions that are encountered in the field.
- samples were given a rating of "1" if a heavy concrete build-up was observed following the adhesion test, and a rating of "10” if the samples were relatively clean, with little build-up (or a rating between 1 and 10) .
- Samples were given a relative clean-up rating inversely proportional to the force needed to clean the sample. Samples that were difficult to clean or very scratched were rated "1"; samples that were easily cleaned with few visible scratches were rated “10.”
- Penetration tests were conducted at 30°F and 70°F by placing test samples of the dimensions described above against a wood backing and driving a 16-penny steel nail through the sample using a standard carpenter's hammer. The nail was then removed by hand. The test samples were examined for undesirable fracturing, and were subjectively evaluated for ease of nail-removal. The cleanliness of nail penetration also was evaluated. A sample was given a penetration rating of "1" if penetration was rough and multiple fractures were observed. A rating of "10" was given to samples that were penetrated smoothly with no observable fractures.
- Such tested materials included polyethylenes (PE) , polypropylenes (PP) , glass- reinforced polypropylenes (e.g. , AZDEL* materials (Azdel Inc., Shelby, N.C., U.S.A.)), polyvinyl chloride (PVC) , polyamides, polytetrafluoro- ethylenes (PTFE) , acrylonitrile-butadiene-styrene (ABS) polymers, high impact polystyrenes (HIPS) , modified polyphenylene ethers (including Noryl* resins from General Electric Co.
- PE polyethylenes
- PP polypropylenes
- PP glass- reinforced polypropylenes
- PVC polyvinyl chloride
- PTFE polytetrafluoro- ethylenes
- ABS acrylonitrile-butadiene-styrene
- HIPS high impact polystyrenes
- modified polyphenylene ethers including Noryl*
- Polypropylene materials released well from concrete and were easy to clean, but demonstrated a tendency to shatter at low temperatures in impact tests. Such materials also may undergo undesirable post-crystallization and warp in the sunlight or when exposed to excessive heat.
- Polyethylene materials provided acceptable results in the above- battery of tests, but performed poorly on release from concrete after several pours.
- Polyolefin surface materials in general e.g., PE and PP materials
- the Azdel* materials bonded GECET* resin cores more favorably, but also shattered at low temperatures.
- Azdel* thermoplastic composite materials are preferred face sheet materials by virtue of their superior strength properties.
- Azdel* thermoplastic composites comprise 80 - 20% polypropylene, 20 - 80% fibrous glass (consisting principally of oxides of silicon, aluminum, calcium, boron, and magnesium fused in an amorphous vitreous state) , and 0 - 5 % antioxidants, pigments, and processing aids; have a melting point of 327°F; and a specific gravity of 1.08-1.30.
- Typical physical properties of exemplary, commercially-available Azdel* products are depicted in Tables IIA - IIC:
- PROPERTY (Measured TYPICAL UNIT METHOD in longitudial DATA direction)
- HDT heat deflection temperature - 48 -
- PROPERTY (Measured TYPICAL UNIT METHOD in transverse DATA direction)
- HDT heat deflection temperature - 49 -
- ABS materials performed well in concrete adhesion tests, but are less preferred for reasons of cost and because of sub-optimal performance in the durability tests. Also, ABS materials have an undesirable tendency to become embrittled from UV radiation exposure. DE RIN* acetal resins released well from concrete in concrete adhesion tests, but performed below average in the battery of durability tests.
- Polystyrene materials performed suboptimally in durability tests and were difficult to clean, and hence, are less preferred.
- HIPS materials are less preferred due to their softness. These materials performed average or below average in impact-resistance tests and scratch-resistance tests, and large holes and a minor fracture were formed in the penetration test. Most importantly, HIPS materials performed poorly relative to preferred materials in concrete adhesion tests, particularly after 6 or more pours against a sample, and also became more difficult to clean. Urethane coatings in general (sprayed and painted onto GECET*, and urethane-coated aluminum) bonded strongly to concrete in the adhesion test, and therefore are less preferred.
- Polyamide materials performed above average in some durability tests and in concrete adhesion tests, but scratched easily and display a tendency to absorb water, making such materials less preferred.
- Noryl* PX1718 resins commercially available from GE Plastics, comprise PPE/HIPS blends to which triarylphosphate ester flame retardants have been added. The manufacturer reports that these resins typically possesses the properties depicted in Table IV A:
- Noryl MX5314 resins commercially available from GE Plastics, are flame-retardant PPE/HIPS blends fire retarded with triarylphosphate esters and having a composition and properties similar to PX1718 resins, except that MX5314 resins contain post-consumer recycled materials.
- Table V A contains typical properties reported by the manufacturer for MX5314 resins: - 56 -
- Noryl PX4685 resins commercially available from GE Plastics, also comprise PPE/HIPS blends. This low-cost product is made with scrap materials and will contain variable levels of flame retardants.
- Table VI A contains typical properties reported by the manufacturer for PX4685 resins:
- Noryl* HS1000X resins commercially available from GE Plastics, are flame-retardant, mineral-filled PPE resins, and typically possess properties as reported in Table VII A, according to the manufacturer:
- Noryl* GTX* 909 resins commercially available from GE Plastics, are PPE/nylon-6,6 blends that, according to the manufacturer, typically possess the properties depicted in Table VIII A:
- Overdrying can cause loss of physical properties and/or create appearance defects. Do not exceed recommended basic drying time and temperature above or: - 6-12 hrs at 175°F, 16 hrs. max. 8-16 hrs at 150°F, 24 hrs. max.
- AVOID air circulating tray ovens Moisture levels in heated ambient air can exceed moisture level in the resin itself, causing moisture ABSORPTION not drying.
- Nozzle temperature controls assist in elimination of drool and premature freeze-off.
- internal release agents may be added to resins to improve the ease with which a surface layer comprising the resin will release from cured concrete.
- a concrete-facing surface layer is formed from any of the foregoing materials using techniques known in the art. Such techniques include various molding techniques, such as compression molding and injection molding, and more preferably extrusion techniques.
- a preferred concrete-facing surface layer (face sheet) is constructed from a modified PPE resin and has a thickness up to about 1/4 inch, and preferably a thickness of about 1/16 inch.
- a - 69 - preferred supplier of Noryl* face sheet materials of the present invention is General Electric Plastics.
- the core and concrete- facing surface layers are attached together using any procedure known in the art, including adhesives, solvent bonding techniques, ultrasonic welding, radio frequency welding, and the like. Less preferred methods include staples, fasteners, and the like. Where attachment is by means of an adhesive, the composition of the core and surface layers will dictate appropriate adhesives such as rubber-based or polystyrene- based adhesives. Similar considerations apply with respect to appropriate solvents for solvent bonding techniques.
- Azdel* or other glass fiber-reinforced thermoplastic face sheets
- are employed and are attached to the core by means of an adhesive lofting of the Azdel* face sheet (heating of one side to allow the glass fibers to raise) according to the manufacturer's instructions may improve adhesion between the Azdel* and the adhesive.
- both the core and concrete-facing surface layer are composed of modified PPE resins
- techniques which form a unified, integral structure from the laminates are preferred.
- Such techniques include, for example, solvent bonding techniques and ultrasonic welding.
- solvent bonding of such resins a manufacturer's recommended solvent combination is 1:1 TCE (trichloroethylene, 1:1:2 trichloroethylene) :MCB (monochlorobenzene, chlorobenzene) .
- An alternative - 70 - recommendation is 4:1 TCE:MBE mixed with 5-25% weight/vol. of NORYL* resin.
- an adhesive is applied to the core and/or the concrete-facing surface layer, which are then stacked upon each other.
- the stacked substrates are fed through rollers under high pressure, or pressed in a press, to create an integral unit from the parts.
- the adhesive is a rubber-based adhesive (e.g., H.B. Fuller Product No. H.L. 2081) or a polystyrene-based or polystyrene-compatible hot melt adhesive which is sprayed upon the core and/or concrete facing surface layer with automatic spraying equipment. Pressure of 25,000 - 30,000 lbs./ft 2 is applied using rollers or a hydraulic press to create a mechanical and chemical bond.
- the bonded product is cured one to two hours at about 125°F, while maintaining a relative humidity at or below 50%.
- a preferred finisher for adhering a GECET* foam core to a face sheet is Diversified Plastics Corporation (Nixa MO) . It will be appreciated that, in an embodiment wherein the core and concrete-facing surface layer each comprise a polyphenylene ether/polystyrene blended resin, the use of a polystyrene-based adhesive results in an integral panel sheeting product that will not delaminate from exposure to water, form oil, concrete lime, and the like.
- Adhesives generally recommended by GE Plastics for Noryl* resins include methyl - 71 - cyanoacrylate and ethyl cyanoacrylate adhesives (Permabond Intl. Co., Loctite Corp.); epoxy adhesives (Bacon Industries, 3M) ; silicone adhesives (GE) ; and acrylic adhesives (Lord Corp.; Loctite).
- a backside surface layer (C) optionally may be attached to the inventive concrete form panel sheeting, primarily for the purpose of imparting lateral strength to the panel sheeting to withstand the lateral force exerted on a concrete form by fresh (liquid) concrete (i.e., to impart increased resistance to deflection to the concrete form panel sheeting) .
- Other means for imparting increased lateral strength to panel sheeting e.g., increasing the thickness or density of the core; increasing the thickness of the concrete-facing surface layer
- attaching a backside surface layer (backing sheet) is a preferred method for increasing the flexural strength of the panel sheeting, while minimizing the increase in mass of the sheeting.
- the optional backside surface layer contacts wet concrete only incidentally (i.e., from splashing) , and consequently releasability from cured concrete is of less importance for the backside surface layer than for the concrete-facing surface layer (B) .
- the backside surface layer preferably possesses the other desirable physical properties of the concrete-facing surface layer, including ease of penetration, scratch-resistance, impact resistance, chemical resistance, and ease of cleaning.
- the backside surface layer comprises a material that is selected to maximize these properties while - 72 - minimizing the weight and cost of the backside surface layer.
- the backside surface layer may comprise a resinous polymer, particularly a thermoplastic resin as defined previously for the core (A) and concrete-facing surface layer (B) .
- the backside surface layer also may comprise many additional strength-imparting materials known to those of ordinary skill, including a thin sheet of aluminum or other metal, or a fiber-reinforced resinous material.
- Preferred backside surface layers comprise a layer of material identical to the material used to form the concrete-facing surface layer, up to about V thick, and a sheet of aluminum up to about 1/16" thick.
- the backside surface layer may be attached to the core by any known means, including means described above for attachment of the concrete-facing surface layer to the core.
- An aluminum backside surface layer preferably is attached to the core with an adhesive.
- the potential recyclability of the concrete form panel sheeting of the present invention is an advantage over plywood panel sheeting of the prior art.
- the polymeric panel sheeting of the invention will absorb little or no external form release agent (e.g. , form oil) , if such release agents are used at all.
- form release agent e.g. , form oil
- a batch of "spent" concrete forms comprising (A) a GECET* core and (B) + (C) one or more surface layers of a Noryl* that is a
- PPE/polystyrene blend adhered to the core by means of a polystyrene adhesive, are cleaned of extraneous concrete and metal fasteners.
- the "spent" panel sheeting comprises essentially PPE, polystyrene, and minor additives, and may be recycled without separation of components.
- the cleaned panel sheeting is densified by means well known in the art (i.e., in a heating step).
- the densified material is ground up in a grinder and homogenized by passing it through an extruder.
- the extruded material is cut or ground into pellets and reformed into useful articles.
- the "spent" concrete form panel sheeting comprises at least two materials that are chemically incompatible and cannot be recycled together.
- the adhesive used to attach a GECET* core to a Noryl* surface layer comprises a chemical that cannot be recycled with modified PPE resins, or the backside surface layer comprises an aluminum sheeting that cannot be recycled with a thermoplastic core.
- the incompatible adhesive, metal, or other material is removed by means known in the art (e.g., with mechanical means, heat. - 74 - solvents, floatation devices or the like) . Recycling then proceeds as in the previous example.
- Concrete form panel sheeting manufactured according to the teachings herein (e.g., a 2' x 8' x 1/2" panel) is inserted into a standard concrete form frame, such as a frame depicted in Fig. 3 or Fig. 9.
- the frame of the form is then securely locked down (immobilized) .
- An inflatable air bag having a surface 2' x 8' in dimension is placed in contact with the concrete-facing surface of the concrete form.
- the air bag is inflated to impart a controlled pressure (e.g., 1.5 - 10.5 pounds per square inch or more) to the concrete facing surface, simulating the pressure of liquid concrete (10.5 PSI corresponds to about 1500 pounds/ft 2 of pressure) .
- a controlled pressure e.g. 1.5 - 10.5 pounds per square inch or more
- Gauges attached to the back of the concrete form at selected locations are used to measure deflection of the concrete form in response to the pressure.
- the air pressure is then released and the gauges are read to determine whether the - 75 - deflection of the panel is permanent, or whether the panel regains its original shape.
- deflection measurements taken along the concrete form frame may be subtracted from measurements taken at the center of the panel.
- measurements are taken under identical conditions using an identical concrete form wherein HDO plywood is substituted for concrete form panel sheeting of the invention.
Landscapes
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Mechanical Engineering (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Forms Removed On Construction Sites Or Auxiliary Members Thereof (AREA)
Abstract
Description
Claims
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP96912735A EP0892878A1 (en) | 1995-04-12 | 1996-04-12 | Reusable concrete form panel sheeting |
| CA002254984A CA2254984C (en) | 1996-04-12 | 1996-04-12 | Reusable concrete form panel sheeting |
| AU55439/96A AU720937B2 (en) | 1996-04-12 | 1996-04-12 | Reusable concrete form panel sheeting |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US42069595A | 1995-04-12 | 1995-04-12 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1996032554A1 true WO1996032554A1 (en) | 1996-10-17 |
Family
ID=23667492
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US1996/005118 Ceased WO1996032554A1 (en) | 1995-04-12 | 1996-04-12 | Reusable concrete form panel sheeting |
Country Status (2)
| Country | Link |
|---|---|
| EP (1) | EP0892878A1 (en) |
| WO (1) | WO1996032554A1 (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997045611A1 (en) * | 1996-05-24 | 1997-12-04 | Antonius Gerardus De Hart | A shuttering element for repeated use |
| ES2154509A1 (en) * | 1996-06-04 | 2001-04-01 | Gavilan Crisanto Palacios | Board or panel for forming plank linings has sandwich construction with two end caps of laminas of polyester-glass fiber, superficially polished and enclosing multiplicity of high density polyurethane rectangular prisms |
| FR2844538A1 (en) * | 2003-02-14 | 2004-03-19 | Saint Gobain Vetrotex | Shuttering panel for use in construction has thermoplastic core and composition covering with reinforcement on at least one surface |
| NL1020062C2 (en) * | 2002-02-26 | 2004-04-06 | Rombouts Kunststof Techniek B | Bonding articles to fibre reinforced amorphous plastic bodies, e.g. for making shuttering sections, by heating surface of body prior to applying adhesive |
| RU2507355C1 (en) * | 2012-08-01 | 2014-02-20 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования Поволжский государственный технологический университет | Thermosetting casing with automatic software control of process of thermal treatment of concrete |
| WO2014075131A1 (en) * | 2012-11-13 | 2014-05-22 | Consystex Pty Ltd | A formwork or construction element and a new material |
| ES2738915A1 (en) * | 2018-07-27 | 2020-01-27 | Salinas Jose Manuel Valero | COVERING FOR FORMWORK PANELS AND PROCEDURE FOR OBTAINING SUCH COATING (Machine-translation by Google Translate, not legally binding) |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2041892A1 (en) * | 1969-09-03 | 1971-03-18 | Geisert Hans Werner | Shuttering element |
| US3592435A (en) * | 1968-09-09 | 1971-07-13 | Mattingly Inc | Form structure |
| FR2398151A1 (en) * | 1977-07-22 | 1979-02-16 | Devars Naudo Entreprises | Sandwich construction load-bearing panel for e.g. building - has solid core of e.g. phenolic foam or expanded polystyrene, between plane compression layer and convex tension layer |
| EP0077579A1 (en) * | 1981-10-19 | 1983-04-27 | GIBA AG Gesellschaft für Industrialisierung im Bauwesen | Shuttering of assembled elements for pouring concrete |
| EP0353637A1 (en) * | 1988-07-29 | 1990-02-07 | Peri Gmbh | Forming element with a plastic forming board and process for producing it |
| US5098059A (en) * | 1990-04-11 | 1992-03-24 | Sawyer Robert D | Concrete forming member for use in concrete casting |
| EP0487952A1 (en) * | 1990-11-14 | 1992-06-03 | Gerhard Dingler | Building element |
| FR2683574A1 (en) * | 1991-11-07 | 1993-05-14 | Soframat | Shuttering panel made of a laminated material |
| DE9415570U1 (en) * | 1994-09-14 | 1995-01-26 | Starke, Lothar, Dr., 06128 Halle | Formwork panel made of plastic |
-
1996
- 1996-04-12 EP EP96912735A patent/EP0892878A1/en not_active Withdrawn
- 1996-04-12 WO PCT/US1996/005118 patent/WO1996032554A1/en not_active Ceased
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3592435A (en) * | 1968-09-09 | 1971-07-13 | Mattingly Inc | Form structure |
| DE2041892A1 (en) * | 1969-09-03 | 1971-03-18 | Geisert Hans Werner | Shuttering element |
| FR2398151A1 (en) * | 1977-07-22 | 1979-02-16 | Devars Naudo Entreprises | Sandwich construction load-bearing panel for e.g. building - has solid core of e.g. phenolic foam or expanded polystyrene, between plane compression layer and convex tension layer |
| EP0077579A1 (en) * | 1981-10-19 | 1983-04-27 | GIBA AG Gesellschaft für Industrialisierung im Bauwesen | Shuttering of assembled elements for pouring concrete |
| EP0353637A1 (en) * | 1988-07-29 | 1990-02-07 | Peri Gmbh | Forming element with a plastic forming board and process for producing it |
| US5098059A (en) * | 1990-04-11 | 1992-03-24 | Sawyer Robert D | Concrete forming member for use in concrete casting |
| EP0487952A1 (en) * | 1990-11-14 | 1992-06-03 | Gerhard Dingler | Building element |
| FR2683574A1 (en) * | 1991-11-07 | 1993-05-14 | Soframat | Shuttering panel made of a laminated material |
| DE9415570U1 (en) * | 1994-09-14 | 1995-01-26 | Starke, Lothar, Dr., 06128 Halle | Formwork panel made of plastic |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997045611A1 (en) * | 1996-05-24 | 1997-12-04 | Antonius Gerardus De Hart | A shuttering element for repeated use |
| ES2154509A1 (en) * | 1996-06-04 | 2001-04-01 | Gavilan Crisanto Palacios | Board or panel for forming plank linings has sandwich construction with two end caps of laminas of polyester-glass fiber, superficially polished and enclosing multiplicity of high density polyurethane rectangular prisms |
| NL1020062C2 (en) * | 2002-02-26 | 2004-04-06 | Rombouts Kunststof Techniek B | Bonding articles to fibre reinforced amorphous plastic bodies, e.g. for making shuttering sections, by heating surface of body prior to applying adhesive |
| FR2844538A1 (en) * | 2003-02-14 | 2004-03-19 | Saint Gobain Vetrotex | Shuttering panel for use in construction has thermoplastic core and composition covering with reinforcement on at least one surface |
| RU2507355C1 (en) * | 2012-08-01 | 2014-02-20 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования Поволжский государственный технологический университет | Thermosetting casing with automatic software control of process of thermal treatment of concrete |
| WO2014075131A1 (en) * | 2012-11-13 | 2014-05-22 | Consystex Pty Ltd | A formwork or construction element and a new material |
| ES2738915A1 (en) * | 2018-07-27 | 2020-01-27 | Salinas Jose Manuel Valero | COVERING FOR FORMWORK PANELS AND PROCEDURE FOR OBTAINING SUCH COATING (Machine-translation by Google Translate, not legally binding) |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0892878A1 (en) | 1999-01-27 |
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