WO1996015305A1

WO1996015305A1 - Alkyl polyglycosides in textile scour/bleach processing

Info

Publication number: WO1996015305A1
Application number: PCT/US1995/013998
Authority: WO
Inventors: Howard Cole; Kristina Erler; Kenneth L. Smith; Brian C. Francois; William Noble; Stephen F. Gross
Original assignee: Henkel Corp
Current assignee: Henkel Corp
Priority date: 1994-11-10
Filing date: 1995-11-08
Publication date: 1996-05-23
Anticipated expiration: 1997-05-10
Also published as: TR199501405A2

Abstract

The present invention provides a process for scouring and bleaching textile materials comprising adding to an aqueous peroxide bleaching bath a surfactant composition comprising: (a) from about 94.0 to about 6.0 % by weight of an alkyl polyglycoside; (b) from about 6.0 to about 94.0 % by weight of a synthetic alkoxylated C11-C15 linear alcohol, and (c) the remainder water, and then contacting the textile materials with the bath. The foaming properties of the alkyl polyglycoside composition may be reduced by adding thereto an effective amount of an ethylene oxide-propylene oxide copolymer or a chlorine-capped ethoxylated isodecyl alcohol.

Description

ALKYL POLYGLYCOSIDES IN TEXTILE SCOUR/BLEACH PROCESSING

FIELD OF THE INVENTION

The present invention generally relates to a process for scouring and bleaching textile materials. More particularly, by combining an alkyl polyglycoside with an alkoxylated primary linear alcohol, a synergistic scouring and bleaching effect is realized. The invention also relates to a process for

reducing foam in an aqueous alkyl polyglycoside system.

Background of the Invention Textile materials are among the most ubiquitous in society. They provide shelter and protection from the environment in the form of apparel, and comfort and decoration in the form of household textiles, such as sheets, upholstery, carpeting, drapery and wall covering, and they have a variety of industrial functions, such as tire reinforcement, tenting, filter media, conveyor belts, insulation, etc. O 96/15305 PCIYUS95/13998

3 preparation for the application of other finishing processes as well as the removal of any residual impurities left over from the scouring process.

Both the scouring and bleaching processes are performed under

extremely alkaline conditions using high concentrations of peroxide and/or caustic soda, and at high temperatures. Due to the extremely hot and alkaline

environment, there is a need for a textile scouring and bleaching composition which is stable under these circumstances, while at the same time having low levels of foam formation under high agitation. Moreover, as a result of the current degree of enhanced consciousness with respect to the protection of our environment, the composition employed should be highly biodegradable as well. Thus, it is primary object of this invention to provide a more effective means of scouring and bleaching textile fibers in an environmentally safe manner.

Another aspect of the present invention is reduction in the foam associated with the use of alkyl polyglycoside surfactants. It is known that alkyl polyglycosides exhibit significantly higher foaming profiles than other nonionic surfactants such as alcohol ethoxylates. In fact, it can be said that the foaming tendencies of alkyl polylgycosides more closely resemble those of anionic surfactants such as alcohol sulfates than the foaming tendencies of other nonionic surfactants. The higher foaming tendency of alkyl polyglycosides makes their use in certain types of applications disadvantageous. For example, public transportation vehicles are normally cleaned by spray washing with aqueous cleaning compositions applied from high pressure nozzles. Since such high pressure applications can produce significant amounts of foam, the 2

Textile materials are produced from fibers (finite lengths) and filaments (continuous lengths) by a variety of processes to form woven, knitted and

nonwoven (felt-like) fabrics. In the case of woven and knitted fabrics, the fibers and filaments are formed into intermediate continuous-length structures known as yams, which are interlaced by weaving or interlooped by knitting into planar- flexible sheetlike structures known as fabrics. Nonwoven fabrics are formed directly from fibers and filaments by chemically or physically bonding or interlocking fibers that have been arranged in a planar configuration.

Textile fibers are classified into two main categories, man-made and natural. Man-made fibers are formed by extrusion processes known as melt- dry, or wet spinning. The spinning or extrusion of filaments is normally followed by an operation known as drawing. In this step, the newly formed filaments are irreversibly extended and stabilized by setting or crystallization processes.

With the exception of silk, naturally occurring fibers have finite lengths and generally require several cleaning and purification steps prior to processing into yarns and fabrics.

There are a number of finishing processes that textile fibers are subjected to after their formation. The two with which the present invention is mostly concerned are scouring and bleaching. Scouring refers to the removal of sizing materials, lubricants and other impurities which are contained in and/or

adhere to the fibers during their formation. These various impurities must be removed so that the textile fibers may be further processed. Another finishing

process is bleaching whereby a white color is imparted to the fabric. This bleaching step also enhances the absorbency of the fiber materials in surfactant used in these cleaning operations must have a minimum foaming tendency. Foaming problems can also arise when high foaming surfactants are used with floor cleaning machines. Consequently, users of alkyl polyglycosides are always looking for methods of decreasing the foaming tendency of aqueous alkyl polyglycoside compositions without simultaneously affecting the beneficial properties of the alkyl polyglycosides such as cleaning ability. It is, therefore, another object of the present invention to reduce the foaming tendency of aqueous alkyl polyglycoside compositions.

SUMMARY OF THE INVENTION Other than in the operating examples, or where otherwise indicated, all numbers expressing quantities of ingredients or reaction conditions used herein are to be understood as modified in all instances by the term "about".

One aspect of the present invention is directed to a process for scouring and bleaching textile materials comprising adding to an aqueous peroxide bleaching bath an effective amount of a scouring and bleaching surfactant composition comprising:

(a) from about 6.0 to about 94.0% by weight of an alkyl polyglycoside having the general formula I

O(Z)_β (I) wherein R is a monovalent organic radical having from about 8 to about 16 carbon atoms; Z is a saccharide residue having 5 or 6 carbon atoms; and a is a number having a value from about 1 to about 6,

(b) from about 94.0 to about 6.0% by weight of a synthetic alkoxylated C₈- C_1S linear alcohol, and

(c) the remainder water, all weights being based on the weight of the composition, and then contacting said textile materials with said bath.

Another aspect of the present invention is directed to a process for reducing foam in an aqueous alkyl polyglycoside composition which comprises adding to the composition an effective amount of an ethylene oxide-propylene oxide copolymer of the formula II

R¹[(EO)_b(PO)_c(EO)_d(PO)_f]_pH (II) or formula III R²(EO)_b(PO)_c(EO)_d(PO)_f H (III) or a combination thereof, wherein R¹ is an ethylenepolyamino group of the formula -NH-(CH₂ CH₂-N-)_k-CH₂ CH₂-NH- and

I R² is a C₈-C₁₅ alkyl group and wherein each of b,c,d, and f is 0 or a number having a value of at least 1 with the proviso that when f is 0, each of b,c, and d is at least 1 and when b is 0, each of c, d, and f is at least 1 ; p is an integer from 2 to 5; k is an integer from 0 to 3; and EO is -CH₂ CH₂-0- and PO is -CH₂ CH( CH₃)-O-.

A further aspect of the present invention is directed to a process for reducing foam in an aqueous alkyl polyglycoside composition which comprises adding to the composition a foam-reducing effective amount of a chlorine- capped ethoxylated isodecyl alcohol. The chlorine-capped ethoxylated isodecyl alcohol preferably contains from about 6.0 to about 10.0 moles of ethylene

oxide such as commercially available from Henkel Corporation, Textiles Division, Charlotte, NC under the tradename Syntergent^® CSW. BRIEF DESCRIPTION OF THE DRAWINGS

Fig. 1 is a bar graph illustrating the degree of foam generated by various blends of APG® 600 AND TRYLON® 6735, by measuring the height of foam formed after 2 minutes, at a temperature of about 120°F. Fig. 2 is a bar graph illustrating the effects of various blends of APG® 600

AND TRYLON® 6735 on caustic stability, represented by sodium hydroxide content, at a temperature of about 160°F.

Fig. 3 is a bar graph illustrating the effects of various blends of APG® 600 AND TRYLON® 6735 on Draves wetting speed using a cotton substrate. Fig. 4 is a bar graph illustrating the effects of various blends of APG® 600

AND TRYLON® 6735 on bleached whiteness using the Gardner Whiteness test.

Fig. 5 is a graph of foam height versus time for various weight ratios of APG® 425 surfactant and TETRONIC® 1501R surfactant.

Fig. 6 is a bar graph of foam heights for various weight ratios of APG® 425 surfactant and TETRONIC® 1501R surfactant for foams generated in a Waring Blender at 25 °C for 1 and 5 minutes.

Fig. 7 is a bar graph of foam volume for various weight ratios of APG® 425 surfactant and TETRONIC® 1501R surfactant in a Modified Inverted Cylinder Test at 25°C. Fig. 8 is a graph of Ross-Miles foam height and % soil removal versus time for various weight ratios of APG® 425 surfactant and TETRONIC® 1501R surfactant.

Fig. 9 is a graph of Ross-Miles foam height and % soil removal versus time for various weight ratios of APG® 225 surfactant and TETRONIC® 1501R surfactant.

Fig. 10 is a bar graph of foam height versus time for various weight ratios of Glucopon^®600 CS AND SYNTERGENT^® CSW (chlorine-capped ethoxylated isodecyl alcohol) by measuring foam height after 2 minutes at a temperature of about 120°F.

Fig. 11 is a bar graph illustrating the effects of various blends of Glucopon^®600 CS AND SYNTERGENT^®CSW on caustic stability, represented

by sodium hydroxide content, at a temperature of about 160°F.

Fig. 12 is a bar graph illustrating the effects of various blends of Glucopon^®600 CS and SYNTERGENT^®CSW on Draves wetting speed using a cotton substrate.

Fig. 13 is a bar graph illustrating the effects of various blends of Glucopon^® 600 CS and SYNTERGENT^®CSW on bleached whiteness using the Gardner Whiteness test.

DESCRIPTION OF THE INVENTION

It has surprisingly been found that an exceedingly synergistic scouring and bleaching effect can be obtained for a wide variety of textile materials when combining the alkyl polyglycoside surfactant of this invention with a synthetic primary linear C₈-C₁₅ alcohol that has been alkoxylated. The aqueous peroxide bleaching bath typically contains finishing components present in an amount of from about 5.0 to about 20.0% by weight, based on weight of the bath. These finishing components include an alkali material, caustic soda, chelating agents and a surface-active material such as a surfactant. It is preferred that the composition be phosphate-free and contain no phenols.

The alkyl polyglycosides which can be used in the compositions and processes according to the invention have the formula I

R₁0(R₂0)_b(Z)₈ I wherein R, is a monovalent organic radical having from about 6 to about 30 carbon atoms; R₂ is divalent alkylene radical having from 2 to 4 carbon atoms; Z is a saccharide residue having 5 or 6 carbon atoms; b is a number having a value from 0 to about 12; a is a number having a value from 1 to about 6. Preferred alkyl polyglycosides which can be used in the compositions according to the invention have the formula I wherein Z is a glucose residue and b is zero. Such alkyl polyglycosides are commercially available, for example, as APG®, GLUCOPON®, or PLANTAREN® surfactants from Henkel Corporation, Ambler, PA., 19002. Examples of such surfactants include but are not limited to:

1. APG® 225 Surfactant - an alkyl polyglycoside in which the alkyl group contains 8 to 10 carbon atoms and having an average degree of polymerization of 1.7.

2. APG® 425 Surfactant - an alkyl polyglycoside in which the alkyl group contains 8 to 16 carbon atoms and having an average degree of polymerization of 1.6.

3. APG® 625 Surfactant - an alkyl polyglycoside in which the alkyl groups contains 12 to 16 carbon atoms and having an average degree of polymerization of 1.6.

4. APG® 325 Surfactant - an alkyl polyglycoside in which the alkyl groups contains 9 to 11 carbon atoms and having an average degree of polymerization of 1.6.

5. GLUCOPON® 600 Surfactant - an alkyl polyglycoside in which the alkyl 9 groups contains 12 to 16 carbon atoms and having an average degree of polymerization of 1.4.

6. PLANTAREN® 2000 Surfactant - a C^₆ alkyl polyglycoside in which the alkyl group contains 8 to 16 carbon atoms and having an average degree of polymerization of 1.4.

7. PLANTAREN® 1300 Surfactant - a C₁₂-_1β alkyl polyglycoside in which the alkyl groups contains 12 to 16 carbon atoms and having an average degree of polymerization of 1.6.

Other examples include alkyl polyglycoside surfactant compositions which are comprised of mixtures of compounds of formula I wherein Z represents a moiety derived from a reducing saccharide containing 5 or 6 carbon atoms; a is a number having a value from 1 to about 6; b is zero; and R., is an alkyl radical having from 8 to 20 carbon atoms. The compositions are characterized in that they have increased surfactant properties and an HLB in the range of about 10 to about 16 and a non-Flory distribution of glycosides, which is comprised of a mixture of an alkyl monoglycoside and a mixture of alkyl polyglycosides having varying degrees of polymerization of 2 and higher in progressively decreasing amounts, in which the amount by weight of polyglycoside having a degree of polymerization of 2, or mixtures thereof with the polyglycoside having a degree of polymerization of 3, predominate in relation to the amount of monoglycoside, said composition having an average degree of polymerization of about 1.8 to about 3. Such compositions, also known as peaked alkyl polyglycosides, can be prepared by separation of the monoglycoside from the original reaction mixture of alkyl monoglycoside and alkyl polyglycosides after removal of the alcohol. This separation may be earned out by molecular distillation and normally results in the removal of about 70-95% by weight of the alkyl monoglycosides. After removal of the alkyl monoglycosides, the relative distribution of the various components, mono- and poly-glycosides, in the resulting product changes and the concentration in the product of the polyglycosides relative to the monoglycoside increases as well as the concentration of individual polyglycosides to the total, i.e. DP2 and DP3 fractions in relation to the sum of all DP fractions. Such compositions are disclosed in U.S. patent 5,266,690, the entire contents of which are incorporated herein by reference. The alkoxylated primary linear alcohols of the present invention are the condensation products of organic C₈-C₁₅ alcohols with from about 6 to about 7 moles of ethylene oxide and from about 3 to about 6 moles of propylene oxide, per mole of alcohol. These alkoxylated alcohols preferably have an HLB value of from about 7.0 to about 8.5. An example of a commercially available alkoxylated alcohol of this type is TRYLON® 6735, marketed by Henkel Corporation, Textiles Division, Charlotte, NC.

The amount of alkyl polyglycoside and alkoxylated synthetic alcohol to be used should be sufficient to effectively wet, i.e., impregnate and bleach the textile substrate and thus scour the substrate and improve the bleaching properties of the bath. The types of substrates which will be treated with the bleaching composition will vary, but will include articles of apparel made of cotton and polyester/cotton woven and knit goods.

In a particularly preferred embodiment of the present invention, the composition to be added to the aqueous peroxide bleaching bath contains from about 20 to 60% by weight of the alkyl polyglycoside and from about 80 to 40% by weight of the synthetic alkoxylated linear alcohol. Also, the amount of the scouring and bleaching surfactant composition to be added to the bath is typically in the range from 0.1 to 1.0% by weight, based on the weight of the bath, and preferably from about 0.1 to about 0.2% by weight.

Generally, the continuous scouring and bleaching process for cotton and polyester/cotton woven goods is carried out in two separate steps, and in either rope or open-width form using an exhaust bath..

In the scouring step, the pH of the alkaline aqueous impregnation (exhaust) bath is most preferably between about 11 and 12.0 and the temperature of the bath is preferably between about 120 and 200°F, and most preferably about 160°F. The desized fabric is immersed in the alkaline scour bath and squeezed, by pad rolls, to a wet pickup of from about 90 to 110% owg (i.e. on the weight of the goods). The treated fabric is then placed in a steam chamber for about 15 minutes (to simulate the open-width process) or about 60 minutes (to simulate the rope process). The steamed fabric is then washed in water at a temperature from about 180 to 200°F, for about 60 to 90 seconds.

In the bleaching step, the pH of the alkaline aqueous bleaching exhaust bath is preferably between about 10.8 and about 11.2, and most preferably about 11.0. The temperature of the aqueous bath is preferably between about 75 to about 120°F , and most preferably about 100°F. The scoured fabric is then impregnated with the aqueous alkaline bleaching bath in the same manner as in the scouring process above. The treated fabric is then steamed in the same manner as disclosed above for the scouring process. The steamed fabric is then washed in water at a temperature of about 180 to 200°F, for approximately 60 to 90 seconds, followed by a cold rinse in water containing acetic acid to neutralize any residual alkali that may be present. The washed fabric is then dried at about 250 °F. The continuous scouring and bleaching process for cotton and polyester/cotton knit goods may also be performed per the one-bath under liquor method. The pH of the bath is preferably between about 10.8 and 11.2 , and most preferably about 11.0. The temperature of the aqueous bath is preferably between about 180 and about 200 °F, and most preferably about 185°F with the dwell time being about 30 to 45 minutes. This step is followed by washing at about 160 to 185°F for approximately 15 to 20 minutes. It should be noted, however, that the pH and temperature ranges are dependent on a number of variables including the type of substrate being treated.

Another method of applying the aqueous bath is known as a padding operation, i.e., using a padding bath, whereby the bath is padded or blotted onto the substrate. This operation is very similar to that of the continuous dyeing operation since the substrate is mechanically carried into and out of the padding apparatus. When employing the padding bath, the aqueous scouring and/or bleaching bath will have a pH in the range of about 11.0 to 12.0, and preferably in the range of about 10.8 to 11.2. It should be noted, however, that either the exhaust bath or padding bath may be employed to scour and/or bleach the fabric when using the scouring and bleaching surfactant composition in the present invention.

It has also been surprisingly discovered that the foaming tendency of an aqueous alkyl polyglycoside formulation can be significantly reduced by incorporating an effective amount of an ethylene oxide-propylene oxide copolymer of the formula II and/or III as described above into the formulation. Compounds of the formula II are alkoxylated fatty alcohols of the ethylene oxide-propylene oxide block copolymer type. Such compounds are commercially available from, for example, Henkel Corporation, Textiles Division, Charlotte, NC as TRYLON® 6735 surfactant. Compounds of the formula III are alkoxylated alkylenepolyamines of the ethylene oxide-propylene oxide block copolymer type. Such compounds are commercially available from, for example, BASF Corp., Performance Chemicals, Parsippany, NJ 07054, as TETRONIC® 1501 R surfactant and TETRONIC® 901 R surfactant. The effective amount of an ethylene oxide-propylene oxide copolymer of the formula II and/or III as described above required to reduce the foam in an aqueous alkyl polyglycoside composition will depend upon the end use of the composition. Typically, the effective amount will be any amount necessary to reduce the foam an aqueous alkyl polyglycoside composition to a desired level and will be readily determinable by the person of ordinary skill in the art. The ethylene oxide- propylene oxide copolymer of the formula II and/or III can be incorporated into an aqueous alkyl polyglycoside composition by any means known to those skilled in the art.

The addition of an ethylene oxide-p< -.ylene oxide copolymer of the formula II wherein R¹ is -HN-CH₂CH₂-NH- and each of k and f is 0; p is 2 and each of b,c, and d is at least 1 into an aqueous alkyl polyglycoside composition reduces the foam without a concomitant reduction in the cleaning ability of the composition. Very effective foam reduction in an aqueous composition comprised of an alkyl polyglycoside in which the alkyl group contains 8 to 10 carbon atoms and having an average degree of polymerization of 1.7 is achieved without a concomitant reduction in the cleaning ability of the composition by adding an equal amount by weight of ethylene diamine alkoxylated with two EO-PO-EO block copolymers which has the formula

HO_d(EO)_c(PO)_b(EO)-NH-CH₂-CH₂-NH-(EO)_b(PO)_c(EO)_dOH and a molecular weight of about 4,700 Daltons. This compound corresponds to a compound of the formula II wherein R¹ is -HN-CH₂CH₂-NH- and each of k and f is 0; p is 2 and each of b,c, and d is at least 1 and is commercially available as, for example, TETRONIC® 901 R surfactant. Very effective foam reduction in an aqueous composition comprised of an alkyl polyglycoside in which the alkyl group contains 8 to 16 carbon atoms and having an average degree of polymerization of 1.6 is achieved with some concomitant reduction in the cleaning ability of the composition by adding ethylene diamine alkoxylated with two PO-EO-PO block copolymers which has the formula

HO,(PO)_d(EO)_c(PO)-NH-CH₂-CH₂-NH-(PO)_c(EO)_d(PO)_fOH and a molecular weight of about 8,000 Daltons to the alkyl polyglycoside in a block copolymer/alkyl polyglycoside weight ratio of 4/1. This compound corresponds to a compound of the formula II wherein R¹ is -HN-CH₂CH₂-NH- and each of k and b is 0; p is 2 and each of c, d and f is at least 1 and is commercially available as, for example, TETRONIC® 150 R1 surfactant.

It has also been surprisingly discovered that the foaming tendency of an aqueous alkyl polyglycoside formulation can be significantly reduced by 15 incorporating an effective amount of a chlorine-capped ethoxylated isodecyl alcohol into the formulation. The chlorine capped ethoxylated isodecyl alcohol may contain from about 6 moles to about 10 moles of ethylene oxide per mole of alcohol, but preferably contains from about 9 moles to about 10 moles of ethylene oxide per mole of alcohol. Such compounds are commercially available from, for example, Henkel Corporation under the tradename

Syntergent^® CSW. The effective amount of a chlorine-capped ethoxylated

isodecyl alcohol required to reduce the foam in an aqueous alkyl polyglycoside solution will depend upon the end use of the composition. Typically, the effective amount will be any amount necessary to reduce the foam in an aqueous alkyl polyglycoside solution to a desired level and will be readily determinable by the person of ordinary skill in the art. The chlorine-capped ethoxylated isodecyl alcohol can be incorporated into an aqueous alkyl polyglycoside composition by any means known to those skilled in the art. The addition of a chlorine-capped ethoxylated isodecyl alcohol into an

aqueous alkyl polyglycoside composition reduces the foam without a concomitant reduction in the cleaning ability of the composition. Very effective foam reduction in an aqueous composition comprised of an alkyl polyglycoside in which the alkyl group contains 8 to 10 carbon atoms and having an average degree of polymerization of 1.7 is achieved without a concomitant reduction in the cleaning ability of the composition by adding thereto a chlorine-capped

ethoxylated isodecyl alcohol.

The present invention will be better understood when read in light of the following examples. In the following examples, parts and percentages are by weight and the temperatures are in degrees Celsius.

In the examples, the following five test methods were used to evaluate the effectiveness of the scouring and bleaching composition:

1. Whiteness Measurement: Procedure

(1) Desized, scoured cotton or polyester/cotton woven goods were immersed in the aqueous bleaching and scouring composition and squeezed, by pad rolls, to a wet pickup of 90-110% owg (on the weight of the goods).

(2) The treated fabric was then placed in a steamer for about 15 minutes (to simulate open-width bleach) or 60 minutes (to simulate rope bleach).

(3) The steamed fabric was then washed in water at about 180 to 200 °F for approximately 60 seconds. This washing process was then repeated and followed by a cold rinse in water containing acetic acid to neutralize any residual alkalinity. (4) The washed fabric was then dried at about 250 °F.

Evaluation Method For Whiteness

The bleached and scoured fabric was then evaluated using a Gardner Reflectometer to measure whiteness.

2. Foam Measurement: Bleach baths (see Comparative Examples) were tested for foam propensity using either a scour bath formulation or bleach bath formulation. The test apparatus was a recirculating foam tester that sprays the bath onto the surface of the bath held in the reservoir. For this particular test, the foam 17 measurement was performed using a recirculation pump foam tester at 70 volts,

at 120° F for 60 seconds.

3.Wettinα Property Measurement:

Draves Test: Performed using AATCC-17-1989.

4. Cleanliness (%Extractibles.:

Performed using: (1) Enzyme and water, and (2) perchloroethylene (AATCC-97-

1989).

5. Caustic Stability:

Performed using 10g/l test sample in 50% caustic soda solution, at 160°F. EXAMPLE I

A scouring and bleaching surfactant composition was prepared having the following components:

COMPONENT %/wt. (a) TRYLON® 6735 1.25

(b) GLUCOPON® 600 cs 37.50

(c) water 61.25

100.00

(a) TRYLON® 6735, commercially available from Henkel Corporation, Textiles Division, Charlotte, NC is a 12-15 carbon chain length synthetic linear alcohol sold under the trade name NEODOL® 25, available from Shell Oil Co., which is reacted with 5 moles of propylene oxide and 7 moles of ethylene oxide.

(b) GLUCOPON® 600 cs, commercially available from Henkel Coφoration, Ambler, PA, is an alkyl polyglycoside composition having 12 to 16 carbons and an average degree of polymerization of 1.4.

The components listed above and in the following examples were mixed together in a vat at a temperature of about 50°C under agitation.

EXAMPLE 2

COMPONENT %/wt.

(a) TRYLON® 6735 10.0 b) GLUCOPON® 600 cs 20.0

(c) water 70.0

100.0

EXAMPLE 3

COMPONENT %/wt.

(a) TRYLON® 6735 16.0

(b) GLUCOPON® 600 cs 8.0

(c) water 76.0

100.0

EXAMPLE 4

A scouring and bleaching surfactant composition was prepared having the following components: COMPONENT %/wt.

(a) TRYLON® 6735 36.0

(b) GLUCOPON® 325 cs 15.0

(c) water 49.0 100.0

(b) GLUCOPON® 325 cs, commercially available from Henkel Coφoration, APG Division, is an alkyl polyglycoside composition having 9 to 11 carbon atoms and an average degree of polymerization of 1.6.

EXAMPLE 5 A scouring and bleaching surfactant composition was prepared having the

following components:

COMPONENT % wt.

(a) TRYLON® 6735 20.0

(b) water 80.0

100.0

EXAMPLE 6

A scouring and bleaching surfactant composition was prepared having the

following components:

COMPONENT %/wt. (a) GLUCOPON® 600 40.0

(b) water 60.0

100.0

COMPARATIVE EXAMPLE 1

A scouring and bleaching composition was prepared having the following tnents: COMPONENT %/wt.

(a) SYNTERGENT® WOR 0.10

(b) hydrogen peroxide (50%) 3.00

(c) sodium hydroxide (50%) 0.35

(d) STANDAPOL® 617 0.20

(e) water 96.35

100.00

^*STANDAPOL® 617 is an organic peroxide stabilizer. 'SYNTERGENT® WOR is a blend of 2-ethyl-hexyl ether phosphate, potassium salt, and TRYLON® 6735.

EXAMPLES 1-6 AND COMPARATIVE EXAMPLE C1 Examples 1-6 and Comparative Example C1 were used to scour and bleach cotton substrates by impregnation with an aqueous peroxide bleaching bath having a pH of about 11.0, followed by steaming at a temperature of about 98 °C for a period of about 60 minutes.

Each sample was evaluated per the above stated testing methods for whiteness, foam formation, alkali stability, wetting properties and cleanliness, i.e., % Extractives, the results being set forth in Table I. TABLE I

EXAMPLE FOAM WHITENESS DRAVES (%) CAUSTIC PRODUCED RATING TEST EXTRAC- STABILITY (sec.) TIBLES (% of 50% NaOH)

1 very 75.9 10.0 0.06 99.0% high

2 high 76.3 5.3 0.03 70.0%

3 very low 77.9 6.0 0.07 50.0%

4 low 78.1 3.4 0.11 10.0%

5 very low 76.8 6.7 0.04 2.0%

6 very high 77.4 6.1 0.10 99.0%

C1 very low 77.0 2.4 0.15 4.0%

From the foregoing evaluation results, it can be seen that the bleaching and scouring process of this invention synergistically provides excellent whiteness to fabric materials, low residual impurities, is stable in high concentrations of strongly alkaline materials at high temperatures, is very low- foaming under high agitation conditions, and is biodegradable, thus avoiding pollution concerns.

EXAMPLE 7 The soil removing efficiency of compositions containing alkyl polyglycosides and ethylene oxide-propylene oxide block copolymers of the formula II according to ASTM D-4485-85 using soil A3 and the foam height measured according to ASTM D 1173-53 at 25°C. are shown in Table II. The percent soil removal (%SR), is calculated according to the following equation wherein Y_s is the reflectance value for tiles treated with the indicated treatment solution, YH₂O is the reflectance value for tiles treated with water, and Y₀ is the reflectance value for untreated tiles.

DEHYPON® LT104 Surfactant, a trademark product of Henkel Corporation, is a C_12.18 fatty alcohol ethoxylated with about 10 moles of EO and capped with an n-butyl group. POLYTERGENT® SLF 18, a trademark product of the Olin Corporation, is a low molecular weight alcohol alkoxylated with an EO-PO block copolymer.

TABLE II

Treatment Solution" Reflectance %SR Foam Height"

—

Water 59.83 —

1 77.67 52.75 135

2 77.36 51.83 110

3 77.38 51.89 20

4 82.83 66.53 20

5 75.14 45.23 10

6 74.19 42.47 20

Unsoiled 93.65 — —

1- 0.6% GLUCOPON® 225 Surfactant in water

2- 0.6% GLUCOPON® 600 Surfactant in water

3- 0.3% GLUCOPON® 225 Surfactant + 0.3% DEHYPON® LT104 Surfactant in water.

4- 0.3% GLUCOPON® 225 Surfactant + 0.3% TETRONIC® 901 in water

5- 0.3% GLUCOPON® 225 Surfactant + 0.3% POLYTERGENT® SLF 18 in water

6- 0.32% GLUCOPON® 600 Surfactant + 0.16% GLUCOPON® 225 Surfactant + 0.12% TETRONIC® 150R1 in water, b. Foam Height in mm according to ASTM D 1173-53 at 25°C.

EXAMPLE 8 A surfactant composition for use in a scouring and bleaching bath was

prepared having the following components:

COMPONENT %/wt.

(a) SYNTERGENT^®CSW 16.0

(b) Glucopon^®600 CS 8.0

(c) water 76.0 100.0

SYNTERGENT^® CSW, commercially available from Henkel Coφoration, Textile Division, Charlotte, NC, is a 10 carbon atom chain length isomeric alcohol which is reacted with about 6 to about 10 moles of ethylene oxide and

capped with thionyl chloride.

EXAMPLE 9

A surfactant composition for use in a scouring and bleaching bath was

prepared having the following components:

COMPONENT %/wt.

(a) SYNTERGENT^®CSW 12.0

(b) Glucopon^®600 CS 16.0

(c) water 7Z0

100.0 COMPARATIVE EXAMPLE 2

A scouring and bleaching composition was prepared having the following components:

COMPONENT %/wt.

(a) SYNTERGENT^® WOR 0.10

(b) hydrogen peroxide (50%) 3.00

(c) sodium hydroxide (50%) 0.35

(d) STANDAPOL^® 617 0.20

(e) water 96.35 100.00

'STANDAPOL^® 617 is an organic peroxide stabilizer. ^•SYNTERGENT^® WOR is a (15%/36%/wt) blend of 2-ethyl-hexyl ether

phosphate, potassium salt, and TRYLON^® 6735.

EXAMPLES 1-6. 8 and 9 AND COMPARATIVE EXAMPLE C2

Examples 1-6, 8 and 9 and Comparative Example C2 were used to scour and bleach cotton substrates by impregnation with an aqueous peroxide bleaching bath having a pH of about 11.0, followed by steaming at a temperature of about 98°C for a period of about 60 minutes.

Each sample was evaluated per the above stated testing methods for whiteness, foam formation, alkali stability, wetting properties and cleanliness, i.e., % Extractibles, the results being set forth in Table I. TABLE

EXAMPLE FOAM WHITENES DRAVE (%) CAUSTIC

PRODUCE S S EXTRA STABILITY

D RATING TEST C- (% OF 50% (sec.) TIBLES NaOH)

1 very 75.9 10.0 0.06 99.0%

high

2 high 76.3 5.3 0.03 70.0%

3 very low 77.9 6.0 0.07 50.0%

4 low 78.1 3.4 0.11 10.0%

5 very low 76.8 6.7 0.04 2.0%

6 very 77.4 6.1 0.10 99.0% high

8 low 76.8 2.4 0.06 60.0%

9 high 75.5 3.1 0.05 70.0%

C2 very low 77.0 2.4 0.15 4.0%

From the foregoing evaluation results and the bar graphs of Fig. 1-4 and 10-13, it can be seen that the bleaching and scouring process of this invention synergistically provides excellent whiteness to fabric materials, low residual

impurities, is stable in high temperatures, is very low-foaming under high

agitation conditions, and is biodegradable, thus avoiding pollution concerns.

Claims

What is claimed is:

1. A process for bleaching and scouring textile materials comprising adding

to an aqueous peroxide bleaching bath having a pH of at least about 10.8 an effective amount of a surfactant composition comprising: (a) from about 94.0 to about 6.0% by weight of an alkyl polyglycoside having the general formula I

RO(Z)_a (I) wherein R is a monovalent organic radical having from about 8 to about 16 carbon atoms; Z is a saccharide residue having 5 or 6 carbon atoms; and a is a number having a value from about 1 to about 6,

(b) from about 6.0 to about 94.0% by weight of a synthetic alkoxylated C₈-C₁₅ linear alcohol, and

2. The process of claim 1 wherein said alkyl polyglycoside has from about 12 to about 16 carbon atoms.

3. The process of claim 1 wherein said alkyl polyglycoside has a percent

actives of about 50%.

4. The process of claim 1 wherein said alkoxylated alcohol contains from about 6.0 to about 7.0 moles of ethylene oxide and from about 3.0 to about 6.0 moles of propylene oxide per mole of said alcohol.

5. The process of claim 4 wherein said alkoxylated alcohol has an HLB value of from about 7.0 to about 8.5.

6. The process of claim 1 wherein said textile materials comprise cotton or a blend of polyester and cotton.

7. The process of claim 1 wherein from about 0.1 to about 1.0% by weight of said surfactant composition is added to said aqueous bleaching bath, based on the weight of said bath.

8. The process of claim 7 wherein from about 0.1 to about 0.2% by weight of said surfactant composition is added to said aqueous bleaching bath, based on the weight of said bath.

9. The process of claim 1 wherein said surfactant composition contains from about 20 to about 60% by weight of said component (a) and from about

80 to about 40% by weight of said component (b).

10. The process of claim 1 wherein said bleaching bath further contains from

about 5.0 to about 20.0% by weight of additional finishing components, based on the weight of said aqueous bleaching bath.

11. The process of claim 10 wherein said finishing components are selected from the group consisting of sodium hydroxide, sodium silicate, and mixtures thereof.

12. The process of claim 1 wherein said bleaching bath is an exhaust bath.

13. The process of claim 1 wherein said bleaching bath is a scouring exhaust bath.

14. The process of claim 1 wherein said bleaching bath is both a scouring and bleaching exhaust bath.

15. The process of claim 1 wherein said bleaching bath is a bleaching padding bath.

16. The process of claim 1 wherein said bleaching bath is a scouring padding bath.

17. The process of claim 1 wherein said bleaching bath is both a scouring and bleaching padding bath.

18. The process of claim 14 wherein said scouring and bleaching exhaust bath has a pH in t e range of about 10.8 to 11.2.

19. The process of claim 14 wherein said scouring and bleaching exhaust bath is at a temperature in the range of about 180°F to 190°F.

20. The process of claim 17 wherein said scouring and bleaching padding bath has a pH in the range from about 11.0 to 12.0.

21. A process for reducing foam in an aqueous alkyl polyglycoside composition which comprises adding to said composition an effective amount of an ethylene oxide-propylene oxide copolymer of the formula II

R¹[(EO)_b(PO)_c(EO)_d(PO)_f]_p (II) or formula III

R²(EO)_b(PO)_c(EO)_d(PO)_f (III) or a combination thereof, wherein R¹ is an ethylenepolyamino group of the formula -NH-(CH₂ CH₂-N-)_k-CH₂ CH₂-NH- and

I R² is a C_β-C₁₅ alkyl group and wherein each of b,c,d, and f is 0 or a number having a value of at least 1 with the proviso that when f is 0, each of b,c, and d is at least 1 and when b is 0, each of c, d, and f is at least 1 ; p is an integer from 2 to 5; and k is an integer from 0 to 3 and EO is -CH₂ CH₂-0- and PO is -CH₂ CH( CH₃)-0-.

22. The process of claim 21 wherein in said ethylene oxide-propylene oxide

copolymer is a compound of the formula II, R¹ is -NH-CH₂ CH₂-NH-; f is 0; each of b,c, and d is at least 1 ; and p is 2.

23. The process of claim 21 wherein in said ethylene oxide-propylene oxide copolymer is a compound of formula II, R¹ is -NH-CH₂ CH₂-NH-; b is 0; each of c, d, and f is at least 1 ; and p is 2.

24. The process of claim 21 wherein in said ethylene oxide-propylene oxide copolymer is a compound of formula III wherein R² is a C₁₂-C_1S alkyl group; f is 0; each of b and d is about 7 and c is about 5.

25. A surfactant composition for use in bleaching and scouring textile

materials comprising:

(a) from about 94.0% to about 6.0% by weight of an alkyl polyglycoside having the general formula I

O (Z)_a (I) wherein R is a monovalent organic radical having from about 8 to about 16 carbon atoms; Z is a saccharide residue having 5 or 6 carbon atoms; and a is

a number having a value from 1 to about 6, (b) from about 6.0% to about 94.0% by weight of a synthetic alkoxylated

C₈-C₁₅ linear alcohol, or

(c) from about 6.0% to about 94.0% by weight of a chlorine-capped

ethoxylated isodecyl alcohol, and (d) the remainder water, all weights being based on the weight of the composition.

26. A composition as in claim 25 wherein said alkoxylated alcohol contains from about 6.0 to about 7.0 moles of ethylene oxide and from about 3.0 to about 6.0 moles of propylene oxide per mole of said alcohol.

27. A composition as in claim 25 wherein said chlorine-capped isodecyl

alcohol contains from about 6 to about 10 moles of ethylene oxide.

28. A process for scouring and bleaching textile materials while controlling foam generation comprising adding to an aqueous textile scouring and bleaching bath from about 0.1 to about 1.0% by weight of a surfactant composition comprising:

(a) from about 6% to about 94% by weight of an alkyl polyglycoside having the general formula I

RO (Z)_a (I) wherein R is a monovalent organic radical having from about 8 to about 16

carbon atoms; Z is a saccharide residue having 5 or 6 carbon atoms; and a is a number having a value from about 1 to about 6,

(b) from about 94% to about 6% by weight of a chlorine-capped ethoxylated isodecyl alcohol, and (c) the remainder, water, all weights being based on the weight of the composition, and then contacting said textile materials with said bath.

29. The process of claim 28 wherein said chlorine-capped ethoxylated isodecyl alcohol contains from about 6 to about 10 moles of ethylene oxide.

30. The process of claim 28 wherein said surfactant composition contains from about 20% to about 60% by weight of said component (a) and from about 80% to about 40% by weight of said component (b).