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WO1996014376A1 - Gels a base de glycolipide/mpg - Google Patents

Gels a base de glycolipide/mpg Download PDF

Info

Publication number
WO1996014376A1
WO1996014376A1 PCT/DK1995/000432 DK9500432W WO9614376A1 WO 1996014376 A1 WO1996014376 A1 WO 1996014376A1 DK 9500432 W DK9500432 W DK 9500432W WO 9614376 A1 WO9614376 A1 WO 9614376A1
Authority
WO
WIPO (PCT)
Prior art keywords
gel
fatty acid
glycolipid
detergent composition
liquid detergent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/DK1995/000432
Other languages
English (en)
Inventor
Tine Olesen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novo Nordisk AS
Original Assignee
Novo Nordisk AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Novo Nordisk AS filed Critical Novo Nordisk AS
Priority to AU38018/95A priority Critical patent/AU687269B2/en
Priority to EP95935867A priority patent/EP0789743A1/fr
Priority to NZ294826A priority patent/NZ294826A/en
Priority to JP8514959A priority patent/JPH10508337A/ja
Publication of WO1996014376A1 publication Critical patent/WO1996014376A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/667—Neutral esters, e.g. sorbitan esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2041—Dihydric alcohols
    • C11D3/2044—Dihydric alcohols linear
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2065—Polyhydric alcohols

Definitions

  • This invention relates to an environmental friendly detergent composition useful in a gel for cleaning hard surfaces.
  • high pressure foam cleaning In industry hard surface cleaning has traditionally been carried out by high pressure foam cleaning. There are some severe safety and environmental problems by using high pressure foam cleaning such as high pH, aggressive cleaning agents, high water consumption, aerosol formation and mechanical noise.
  • the gel cleaners have the advantages of giving no or insignificant aerosol formation, they have a low water consumption, and they are easy to apply: Prior to dilution the gel compositions are readily mobile liquids which are convenient for transport etc., but when diluted to working concentrations they start to thicken to a gel-like consistency, which mean that they will remain in contact with the surface or object to be cleaned for sufficient time to enable the cleansing to occur (for reference see EP 0 314 232) , so if the detergents of the gel composition are environmental friendly, the gel application method is a very safe and gentle way of cleaning hard surfaces.
  • a gel can be made of very environmental friendly chemicals, namely glycolipid, polyalcohols and water. Accordingly, the present invention relates to a liquid detergent composition which undergoes a viscosity increase upon aqueous dilution, comprising a) one or more glycolipids b) one or more polyalcohols c) water.
  • a gel cleaning composition can be made of glycolipid(s) , poly- alcohol(s) and water.
  • the glycolipid may be a sugar or sugar alcohol fatty acid ester (as described in JP 63- 112,993) or a derivative thereof or a fatty acid monoester or a mixture of fatty acid monoesters of alkylglycoside (as described in US 5,191,071 and in US 5,200,328) or a derivative thereof.
  • the glycolipid is a fatty acid monoester of ethylglycoside, the fatty acid containing 8-22 carbon atoms, e.g. ethyl 6-O-dodecanoyl glucoside.
  • any polyalcohol which has two or more hydroxyl groups may be used in making the gel.
  • Useful examples are 1,2-ethanediol, 1,2-propandiol, 1,3- propandiol, 1,2,3-propantriol, butanediols, butanetriols, pentanediols, and sugar alcohols.
  • 1,2-propandiol is preferred.
  • the gel composition may optionally also contain other detergent ingredients such as solvents and sequestrants.
  • the gel composition may also contain an electrolyte (e.g. sodium chloride) . It has been found that sodium chloride should be added in more than 8 % w/w in order to maintain the gel formation when the gel components are ethyl 6-0-dodecanoyl glucoside, 1,2-propandiol and water (in lower concentrations the gel formation decreases, for reference see Example 1).
  • an electrolyte e.g. sodium chloride
  • the gel composition may also contain one or more enzymes.
  • the enzymes are in particular proteases (for instance Savinase* 16.0 L, Alcalase* 2.5 L, Esperase* 8.0 L or DurazymTM 16.0 L, all available from Novo Nordisk A/S) , amylases (for instance Termamyl* 300 L available from Novo Nordisk A/S) , lipases (for instance Lipolase* 100 L available from Novo Nordisk A/S) or cellulases (for instance Celluzyme 11 ' 1.0 L available from Novo Nordisk A/S) .
  • the amount of enzyme may be dosed so that the percentage of enzyme in the finished gel will be of 0.001-10%, preferably 0.01-1%, in particular about 0.01- 0.5%.
  • the gel is made in situ.
  • the detergent composition comprising the glycolipid(s) and the polyalcohol(s) are diluted with water and applied to the soiled surfaces by using some kind of application system (e.g. diluted through a venturi and applied via a special lance) .
  • the detergent composition is best applied using gel generation equipment which automatically draws in the required percentage.
  • the required percentage of a given glycolipid and a given polyalcohol may be found as described in Example 1.
  • Application equipment is available from for instance Scanio A/S, Blytaekkervej 4-6, DK-9000 Aalborg, Denmark.
  • the gel is applied to the soiled surfaces as described above.
  • the gel will set on the surfaces within a few seconds.
  • the gel will remain in its form even on complicated shaped equipment, vertical surfaces and ceilings and will therefore give very long contact times. Dwell times are difficult to estimate beforehand and should be determined by trial. A dwell time of 5-30 minutes may often be required.
  • the gel composition is rinsed off using a washing system.
  • a washing system In some cases it may be necessary to use a pressure washing system to rinse off the gel composition, but often removal by gentle flushing with water is easy and all that is needed.
  • the cleaning gel detergent described in this inven ⁇ tion may be used in all kinds of industries: in dairies, in slaughterhouses, in breweries, in sea food production units etc. It may also be used in the transport sector, for instance as a cleaning agent in car washing and for general vessel wash. Especially, the cleaning gel may be useful in removing oils (vegetable, animal and mineral) . It may also work as a general purpose cleaner in households, e.g., for cleaning windows, bathrooms and kitchens, in particular it may be useful as an efficient oven cleaner. It may also be useful for janitorial purposes such as computer cabinet cleaning etc.
  • the cleaning gel of the present invention may also be very useful for personal care purposes, in skin, hair and dental applications, such as cleaning dentures.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Molecular Biology (AREA)
  • Dispersion Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Colloid Chemistry (AREA)
  • Saccharide Compounds (AREA)

Abstract

L'invention concerne une composition de détergent non nuisible à l'environement, utile en un gel de nettoyage de surfaces dures comprenant un glycolipide et un polyalcool.
PCT/DK1995/000432 1994-11-04 1995-11-01 Gels a base de glycolipide/mpg Ceased WO1996014376A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
AU38018/95A AU687269B2 (en) 1994-11-04 1995-11-01 Glycolipid/MPG gels
EP95935867A EP0789743A1 (fr) 1994-11-04 1995-11-01 Gels a base de glycolipide/mpg
NZ294826A NZ294826A (en) 1994-11-04 1995-11-01 Use of a composition containing glycolipid and polyalcohol in making detergent gels
JP8514959A JPH10508337A (ja) 1994-11-04 1995-11-01 糖脂質／ｍｐｇゲル

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DK1279/94 1994-11-04
DK127994 1994-11-04

Publications (1)

Publication Number Publication Date
WO1996014376A1 true WO1996014376A1 (fr) 1996-05-17

Family

ID=8103061

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/DK1995/000432 Ceased WO1996014376A1 (fr) 1994-11-04 1995-11-01 Gels a base de glycolipide/mpg

Country Status (6)

Country Link
EP (1) EP0789743A1 (fr)
JP (1) JPH10508337A (fr)
AU (1) AU687269B2 (fr)
CA (1) CA2204258A1 (fr)
NZ (1) NZ294826A (fr)
WO (1) WO1996014376A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5922664A (en) * 1995-01-30 1999-07-13 Colgate-Palmolive Co. Pourable detergent concentrates which maintain or increase in viscosity after dilution with water
WO2001085897A1 (fr) * 2000-05-12 2001-11-15 Henkel Kommanditgesellschaft Auf Aktien Concentre a base de tensioactifs
WO2011051161A1 (fr) * 2009-10-29 2011-05-05 Henkel Ag & Co. Kgaa Produit de nettoyage laissant peu de résidus pour surfaces dures
WO2025125268A1 (fr) * 2023-12-14 2025-06-19 Norfalk Aps Utilisation de glycolipides mono-esters dans des compositions de produits de nettoyage de surfaces dures

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050058673A1 (en) 2003-09-09 2005-03-17 3M Innovative Properties Company Antimicrobial compositions and methods
CN101175474B (zh) 2005-03-10 2011-09-07 3M创新有限公司 降低微生物污染的方法
JP2008537732A (ja) 2005-03-10 2008-09-25 スリーエム イノベイティブ プロパティズ カンパニー ヒドロキシカルボン酸のエステルを含む抗菌組成物

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0491532A1 (fr) * 1990-12-18 1992-06-24 Unilever Plc Compositions détergentes
WO1992013055A1 (fr) * 1991-01-29 1992-08-06 Henkel Kommanditgesellschaft Auf Aktien Produits liquides de lavage
EP0499434A1 (fr) * 1991-02-12 1992-08-19 Unilever Plc Compositions détergentes

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0491532A1 (fr) * 1990-12-18 1992-06-24 Unilever Plc Compositions détergentes
WO1992013055A1 (fr) * 1991-01-29 1992-08-06 Henkel Kommanditgesellschaft Auf Aktien Produits liquides de lavage
EP0499434A1 (fr) * 1991-02-12 1992-08-19 Unilever Plc Compositions détergentes

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5922664A (en) * 1995-01-30 1999-07-13 Colgate-Palmolive Co. Pourable detergent concentrates which maintain or increase in viscosity after dilution with water
WO2001085897A1 (fr) * 2000-05-12 2001-11-15 Henkel Kommanditgesellschaft Auf Aktien Concentre a base de tensioactifs
WO2011051161A1 (fr) * 2009-10-29 2011-05-05 Henkel Ag & Co. Kgaa Produit de nettoyage laissant peu de résidus pour surfaces dures
WO2025125268A1 (fr) * 2023-12-14 2025-06-19 Norfalk Aps Utilisation de glycolipides mono-esters dans des compositions de produits de nettoyage de surfaces dures

Also Published As

Publication number Publication date
NZ294826A (en) 1998-05-27
AU3801895A (en) 1996-05-31
CA2204258A1 (fr) 1996-05-17
AU687269B2 (en) 1998-02-19
EP0789743A1 (fr) 1997-08-20
JPH10508337A (ja) 1998-08-18

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