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WO1996007212B1 - Solid electrolyte high-temperature fuel cell and fuel cell arrangement - Google Patents

Solid electrolyte high-temperature fuel cell and fuel cell arrangement

Info

Publication number
WO1996007212B1
WO1996007212B1 PCT/DE1995/001169 DE9501169W WO9607212B1 WO 1996007212 B1 WO1996007212 B1 WO 1996007212B1 DE 9501169 W DE9501169 W DE 9501169W WO 9607212 B1 WO9607212 B1 WO 9607212B1
Authority
WO
WIPO (PCT)
Prior art keywords
fuel cell
solid electrolyte
gas
hollow body
anode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/DE1995/001169
Other languages
German (de)
French (fr)
Other versions
WO1996007212A1 (en
Filing date
Publication date
Priority claimed from DE4430958A external-priority patent/DE4430958C1/en
Application filed filed Critical
Publication of WO1996007212A1 publication Critical patent/WO1996007212A1/en
Publication of WO1996007212B1 publication Critical patent/WO1996007212B1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Abstract

The invention relates to a solid electrolyte high-temperature fuel cell. Gas is taken past the anode from a gas supply via a gas channel. A corresponding airsupply takes air over the cathode. There is also a discharge pipe for the exhaust gas. According to the invention, the solid electrolyte element consists of a vertical open-topped, closed-bottomed hollow body (2) of ceramic electrolyte material. The anode (3) is fitted on the inner surface of the hollow body and the cathode (8) on its outer surface. Through the hollow body passes the gas channel which is also the anode chamber (4). It is supplied from a gas inlet (1a) opening in or on the bottom of the hollow body. On the cathode side the hollow body is surrounded by and spaced from a further closed element (5) of highly heat-resistant material from beneath as far as the air inlet aperture. The space thus created forms the air channel (7) and the cathode chamber at the same time. The gas-air mixture leaving the gas and air channel is taken upwards from the component to the exhaust gas line in this arrangement.

Claims

GEÄNDERTE ANSPRÜCHE[beim Internationalen Büro am 12. März 1996 (12.03.96) eingegangen; ursprüngliche Ansprüche 1-12 durch geänderte Ansprüche 1-11 ersetzt (4 Seiten)] AMENDED CLAIMS [received at the International Bureau on 12 March 1996 (12.03.96); original claims 1-12 replaced by amended claims 1-11 (4 pages)] 1. Festelektrolyt-Hochtemperatur-Brennstoffzelle mit Anode und Kathode aufweisendem Festelektrolyt- element, bei der eine Gaszuführung mit über die Anode führendem Gaskanal und eine Luftzuführung mit über die Kathode führendem Luftkanal sowie eine Ableitung für das Abgas vorgesehen sind, d a d u r c h g e k e n n z e i c h n e t , daß das Festelektrolytelement aus einem senkrecht anzuordnenden, oben offenen, unten geschlossenen Hohlkörper (2) aus keramischem Elektrolytmaterial besteht, auf dessen innerer Oberfläche die Anode (3) und auf dessen äußerer Oberfläche die Kathode (8) aufgetragen sind und in welchem der Gaskanal, der zugleich Anodenraum (4) ist, verläuft, der von der im oder am Boden des Hohl¬ körpers mündenden Gaszuführung (la, lb) gespeist wird, und daß der das Festelektrolytelement bil¬ dende Hohlkörper (2) kathodenseitig mit Abstand von einem weiteren, unten bis auf die Mündung der LuftZuführung (11) geschlossenen Element (5) aus hochwarmfestem Material umhüllt ist, dabei der zwischen dem Hohlkörper (2) und dem diesen umhül¬ lenden Element (5) befindliche Raum den Katho¬ denraum und zugleich den Luftkanal (7) bildet und das den Gas- und Luftkanal (7) verlassende Gas-1. solid electrolyte high-temperature fuel cell with anode and cathode having Festelektrolyt- element in which a gas supply with over the anode leading gas channel and an air supply with over the cathode leading air duct and a discharge for the exhaust gas are provided, characterized in that the solid electrolyte element a hollow body (2) made of ceramic electrolyte material which is open at the top and is closed at the bottom, on the inner surface of which the anode (3) and on the outer surface of which the cathode (8) is applied and in which the gas channel, the anode space (4 ), which is fed by the gas inlet (1a, 1b) opening in or at the bottom of the hollow body, and in that the hollow body (2) forming the solid electrolyte element is at the cathode side at a distance from another, down to the mouth the air supply (11) closed element (5) made of heat-resistant Mate In this case, the space located between the hollow body (2) and the element (5) enclosing it forms the cathode space and at the same time the air channel (7) and the gas leaving the gas and air duct (7). Luft-Gemisch oben aus dem Element zur Abgaslei- tung (13) geführt ist und daß ein in den Hohlkörper (2) ragendes, unten offenes Tauchrohr (12) vorgesehen ist, das oben an die Gasleitung (16) angeschlossen ist. Air mixture at the top of the element to the exhaust pipe (13) is guided and that in the hollow body (2) projecting, downwardly open dip tube (12) is provided, which is connected to the top of the gas line (16). 2. Festelektrolyt-Hochtemperatur-Brennstoffzelle nach Anspruch 1, d a d u r c h g e k e n n z e i c h n e t , daß die beiden einander gegenüberliegenden Anodenflächen innerhalb des Hohlkörpers (2) elek¬ trisch leitend miteinander verbunden sind.2. A solid electrolyte high-temperature fuel cell according to claim 1, characterized in that the two opposing anode surfaces within the hollow body (2) are connected to one another in an electrically conductive manner. 3. Festelektrolyt-Hochtemperatur-Brennstoffzelle nach Anspruch 2 , d a d u r c h g e k e n n z e i c h n e t , daß zur elektrischen Verbindung der beiden Anodenflächen ein Drahtgeflecht vorgesehen ist.3. A solid electrolyte high-temperature fuel cell according to claim 2, wherein a wire mesh is provided for the electrical connection of the two anode surfaces. 4. Festelektrolyt-Hochtemperatur-Brennstoffzelle nach Anspruch 2, d a d u r c h g e k e n n z e i c h n e t , daß zur elektrischen Verbindung der beiden Anodenflächen Stege aus Anodenmaterial vorgesehen sind.4. High-temperature solid electrolyte fuel cell according to claim 2, characterized in that there are provided webs of anode material for the electrical connection of the two anode surfaces. 5. Festelektrolyt-Hochtemperatur-Brennstoffzelle ge¬ mäß einem der Ansprüche 1 bis 4, d a d u r c h g e k e n n z e i c h n e t , daß das den Hohlkörper (2) umhüllende Element (5) den Hohlkörper überragt und der oberhalb des5. Solid electrolyte high-temperature fuel cell ge according to one of claims 1 to 4, d a d u r c h e c e n e c e s in that the hollow body (2) enveloping element (5) projects beyond the hollow body and above the Hohlkörpers befindliche Raum im Element eine Nachbrennkammer (9) für das den Gas- und den Luftkanal (7) verlassende Gas-Luft-Gemisch bildet. Hollow body space in the element forms a Nachbrennkammer (9) for the gas and the air duct (7) leaving the gas-air mixture. 6. Festelektrolyt-Hochtemperatur-Brennstoffzellen- Anordnung, bestehend aus mehreren, in Serie ge¬ schalteten, unmittelbar benachbarten Brennstoff¬ zellen nach einem der Ansprüche 1 bis 5.6. solid electrolyte high-temperature fuel cell arrangement, consisting of several, in series ge switched, immediately adjacent Brennstoff¬ cells according to one of claims 1 to 5. 7. Festelektrolyt-Hochtemperatur-Brennstoffzellen- Anordnung, bestehend aus mehreren, in Serie ge¬ schalteten, unmittelbar benachbarten Brennstoff¬ zellen nach Anspruch 6, d a d u r c h g e k e n n z e i c h n e t , daß zwischen zwei benachbarten Brennstoffzellen je ein gemeinsamer Luftzufuhrkanal (10) vorgese¬ hen ist, der unten in den Luftkanal (7) mündet und oben an die Luftzuleitung angeschlossen ist.7. solid electrolyte high-temperature fuel cell assembly, consisting of several, in series ge switched, immediately adjacent Brennstoff¬ cells according to claim 6, characterized in that between two adjacent fuel cells depending on a common air supply channel (10) is vorgese¬ hen, the bottom in the air channel (7) opens and is connected to the top of the air supply line. 8. Festelektrolyt-Hochtemperatur-Brennstoffzelle nach Anspruch 7, d a d u r c h g e k e n n z e i c h n e t , daß die Luftzufuhrkanäle sich über die Außenflä- ehe des den Hohlkörper umhüllenden Elementes er¬ strecken.8. A high-temperature solid electrolyte fuel cell according to claim 7, wherein: the air supply ducts extend over the outer surface of the element surrounding the hollow body. 9. Festelektrolyt-Hochtemperatur-Brennstoffzellen- Anordnung gemäß einem der Ansprüche 7 oder 8, d a d u r c h g e k e n n z e i c h n e t , daß stirnseitig an den Brennstoffzellen eine Luftvorwärmkammer (14) vorgesehen ist, die von unten durch die Luftzuleitung gespeist wird und oben an die Luftzufuhrkanäle (10) angeschlossen ist.9. solid electrolyte high-temperature fuel cell assembly according to one of claims 7 or 8, characterized in that the end face of the fuel cell Luftvorwärmkammer (14) is provided, which is fed from below through the air supply line and the top of the air supply channels (10) is connected , 10. Festelektrolyt-Hochtemperatur-Brennstoffzellen- Anordnung gemäß einem der Ansprüche 6 bis 9 , d a d u r c h g e k e n n z e i c h n e t , daß die die Hohlkörper umhüllenden Elemente oben von einer gemeinsamen Kopfplatte (17) abgeschlos¬ sen sind und der Boden des Brennstoffzellenofens, auf dem die Elemente (15) ohne feste Verbindung stehen, den unteren Abschluß der Elemente bildet. 10 . Solid electrolyte high-temperature fuel cell arrangement according to one of Claims 6 to 9, characterized in that the elements enclosing the hollow bodies are closed off at the top by a common head plate (17) and the bottom of the fuel cell oven, on which the elements (15) have no firm connection, forms the lower end of the elements. 11. Festelektrolyt-Hochtemperatur-Brennstoffzellen- Anordnung gemäß einem der Ansprüche 6 bis 9, d a d u r c h g e k e n n z e i c h n e t , daß die die Hohlkörper (2) umhüllenden Ele¬ mente (15) von einer gemeinsamen Kopfplatte (17) getragen werden und unten durch eine gemeinsame Bodenplatte abgeschlossen sind. 11. Solid electrolyte high-temperature fuel cell arrangement according to one of claims 6 to 9, characterized in that the hollow body (2) enveloping elements (15) are supported by a common head plate (17) and are closed at the bottom by a common bottom plate ,
PCT/DE1995/001169 1994-08-31 1995-08-29 Solid electrolyte high-temperature fuel cell and fuel cell arrangement Ceased WO1996007212A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4430958A DE4430958C1 (en) 1994-08-31 1994-08-31 Solid electrolyte high temperature fuel cell and fuel cell assembly
DEP4430958.9 1994-08-31

Publications (2)

Publication Number Publication Date
WO1996007212A1 WO1996007212A1 (en) 1996-03-07
WO1996007212B1 true WO1996007212B1 (en) 1996-05-02

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/DE1995/001169 Ceased WO1996007212A1 (en) 1994-08-31 1995-08-29 Solid electrolyte high-temperature fuel cell and fuel cell arrangement

Country Status (2)

Country Link
DE (1) DE4430958C1 (en)
WO (1) WO1996007212A1 (en)

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DE19935719C2 (en) * 1999-07-29 2003-01-30 Forschungszentrum Juelich Gmbh Cooling system for fuel cells
DE10000465C2 (en) * 2000-01-07 2003-06-18 Forschungszentrum Juelich Gmbh Fuel cells connected mechanically to one another and methods for their production
DE10033898B4 (en) * 2000-07-12 2009-06-18 Forschungszentrum Jülich GmbH High temperature fuel cell and fuel cell stack
DE10040499C2 (en) * 2000-08-18 2002-06-27 Forschungszentrum Juelich Gmbh Contact layer and a fuel cell comprising such a contact layer
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