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WO1995026991A1 - Procede d'oligomerisation d'olefines c4 en meme temps que d'olefines a longue chaine - Google Patents

Procede d'oligomerisation d'olefines c4 en meme temps que d'olefines a longue chaine Download PDF

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Publication number
WO1995026991A1
WO1995026991A1 PCT/FI1995/000176 FI9500176W WO9526991A1 WO 1995026991 A1 WO1995026991 A1 WO 1995026991A1 FI 9500176 W FI9500176 W FI 9500176W WO 9526991 A1 WO9526991 A1 WO 9526991A1
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WO
WIPO (PCT)
Prior art keywords
olefins
sep
process according
butene
butenes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/FI1995/000176
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English (en)
Inventor
Frantis^¿ek MIKES^¿
Vlastimil HALAS^¿KA
Jan Pecka
Miroslav Marek
Erkki Halme
Salme Koskimies
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Neste Oyj
Original Assignee
Neste Oyj
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Neste Oyj filed Critical Neste Oyj
Priority to AU21395/95A priority Critical patent/AU2139595A/en
Publication of WO1995026991A1 publication Critical patent/WO1995026991A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/30—Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/14—Catalytic processes with inorganic acids; with salts or anhydrides of acids
    • C07C2/20—Acids of halogen; Salts thereof ; Complexes thereof with organic compounds
    • C07C2/22—Metal halides; Complexes thereof with organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
    • C10G50/02—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation of hydrocarbon oils for lubricating purposes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/08—Halides
    • C07C2527/10—Chlorides
    • C07C2527/11—Hydrogen chloride
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/125—Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium
    • C07C2527/126—Aluminium chloride
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14—Monomers containing five or more carbon atoms

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

L'invention concerne un procédé de production d'huiles synthétiques et d'un produit à base de polymère oléfinique utile en tant qu'huile synthétique ou en tant que partie de celle-ci. Selon ce procédé, des hydrocarbures oléfiniques sont polymérisés de manière à former une huile possédant un index élevé de viscosité ainsi qu'un bas point d'écoulement. Selon l'invention, les hydrocarbures oléfiniques utilisés comprennent des oléfines C8-24 possédant une liaison interne double, lesquelles sont soumises à une réaction de polymérisation avec des oléfines inférieures, en particulier des 1- et 2-butènes. On effectue cette réaction en présence d'un initiateur de réaction contenant un composé de la formule générale (I) R2AlCl dans laquelle R représente halogène ou un groupe alcoyle contenant 1 à 6 atomes de carbone, de manière à obtenir un produit de polymérisation, puis on sépare le produit de polymérisation du mélange de réaction de manière à former une huile synthétique.
PCT/FI1995/000176 1994-03-31 1995-03-31 Procede d'oligomerisation d'olefines c4 en meme temps que d'olefines a longue chaine Ceased WO1995026991A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU21395/95A AU2139595A (en) 1994-03-31 1995-03-31 A method to oligomerize c4 olefins together with long chain olefins

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI941529 1994-03-31
FI941529A FI941529A7 (fi) 1994-03-31 1994-03-31 Menetelmä C4-öljyjen oligomeroimiseksi pitkäketjuisten olefiinien kanssa

Publications (1)

Publication Number Publication Date
WO1995026991A1 true WO1995026991A1 (fr) 1995-10-12

Family

ID=8540435

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FI1995/000176 Ceased WO1995026991A1 (fr) 1994-03-31 1995-03-31 Procede d'oligomerisation d'olefines c4 en meme temps que d'olefines a longue chaine

Country Status (3)

Country Link
AU (1) AU2139595A (fr)
FI (1) FI941529A7 (fr)
WO (1) WO1995026991A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101735366B (zh) * 2009-12-17 2011-09-14 中国石油化工股份有限公司 一种用于减阻剂聚合用的复合给电子体
CN103289731A (zh) * 2012-02-28 2013-09-11 赵阳 一种内烯烃制备含芳烃合成烃的方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3330883A (en) * 1964-04-06 1967-07-11 Gulf Research Development Co Copolymerization of low carbon number and high carbon number olefin fractions
US4311864A (en) * 1980-07-14 1982-01-19 Gulf Research & Development Company Method for preparing synthetic hydrocarbon fluids
US4434308A (en) * 1982-04-28 1984-02-28 Texaco Inc. Manufacture of synthetic lubricant additives from internal olefins using boron trifluoride catalysis
EP0337737A2 (fr) * 1988-04-15 1989-10-18 Neste Oy Procédé de préparation d'huiles de poly-N-butène d'une fraction-C4 résiduelle
EP0449453A2 (fr) * 1990-03-28 1991-10-02 Texaco Chemical Company Procédé pour l'oligomérisation d'oléfines pour préparer un matériau de base pour des lubrifiants synthétiques
WO1994015894A1 (fr) * 1992-12-30 1994-07-21 Neste Oy Procede d'oligomerisation d'olefines c4 avec des alpha-olefines lineaires

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3330883A (en) * 1964-04-06 1967-07-11 Gulf Research Development Co Copolymerization of low carbon number and high carbon number olefin fractions
US4311864A (en) * 1980-07-14 1982-01-19 Gulf Research & Development Company Method for preparing synthetic hydrocarbon fluids
US4434308A (en) * 1982-04-28 1984-02-28 Texaco Inc. Manufacture of synthetic lubricant additives from internal olefins using boron trifluoride catalysis
EP0337737A2 (fr) * 1988-04-15 1989-10-18 Neste Oy Procédé de préparation d'huiles de poly-N-butène d'une fraction-C4 résiduelle
EP0449453A2 (fr) * 1990-03-28 1991-10-02 Texaco Chemical Company Procédé pour l'oligomérisation d'oléfines pour préparer un matériau de base pour des lubrifiants synthétiques
WO1994015894A1 (fr) * 1992-12-30 1994-07-21 Neste Oy Procede d'oligomerisation d'olefines c4 avec des alpha-olefines lineaires

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101735366B (zh) * 2009-12-17 2011-09-14 中国石油化工股份有限公司 一种用于减阻剂聚合用的复合给电子体
CN103289731A (zh) * 2012-02-28 2013-09-11 赵阳 一种内烯烃制备含芳烃合成烃的方法

Also Published As

Publication number Publication date
FI941529A7 (fi) 1995-10-01
AU2139595A (en) 1995-10-23
FI941529A0 (fi) 1994-03-31

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