WO1994004963A1 - Element, device and associated method for capturing a latent radiographic image - Google Patents
Element, device and associated method for capturing a latent radiographic image Download PDFInfo
- Publication number
- WO1994004963A1 WO1994004963A1 PCT/US1992/006891 US9206891W WO9404963A1 WO 1994004963 A1 WO1994004963 A1 WO 1994004963A1 US 9206891 W US9206891 W US 9206891W WO 9404963 A1 WO9404963 A1 WO 9404963A1
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- WIPO (PCT)
- Prior art keywords
- layer
- conductive
- microplates
- photoconductive
- actinic
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G15/00—Apparatus for electrographic processes using a charge pattern
- G03G15/054—Apparatus for electrographic processes using a charge pattern using X-rays, e.g. electroradiography
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01T—MEASUREMENT OF NUCLEAR OR X-RADIATION
- G01T1/00—Measuring X-radiation, gamma radiation, corpuscular radiation, or cosmic radiation
- G01T1/16—Measuring radiation intensity
- G01T1/24—Measuring radiation intensity with semiconductor detectors
- G01T1/246—Measuring radiation intensity with semiconductor detectors utilizing latent read-out, e.g. charge stored and read-out later
Definitions
- the present invention relates to an element, a device and an associated method for capturing radiographic images. More particularly, the present invention uses a unique microcapacitor matrix structure to hold varying electrical charges representing a latent radiographic image.
- SUBSTITUTE SHEET is thus greatly enhanced.
- X-ray films are often coated on both sides with photosensitive emulsion and two screens are used to expose the film from both sides, further increasing the efficiency of the system and reducing the exposure time required to obtain a radiogram.
- Radiograms have also been produced by capturing a latent radiographic image using a photoconductive plate in a xeroradiographic process.
- a photoconductive plate sensitive to X-ray radiation comprising at least a photoconductive layer coated over a conductive backing layer is first charged by passing under a charging station typically comprising a corona wire. Positive or negative charge is uniformly deposited over the plate surface. The plate is next exposed to X-ray radiation. Depending on the intensity of the incident radiation, electron hole pairs generated by the X-ray radiation are separated by a field incident to the charge laid over the surface and as a result move along the field to recombine with the surface charge.
- a latent image in the form of electrical charges of varying magnitude remain on the plate surface, representing a latent electrostatic radiogram.
- This latent image may then be rendered visible by toning and preferably transferring onto a receiving surface for better viewing.
- Xeroradiography a specific application of electroradiography offers high resolution and, because the photoconductive layer may be made fairly thick comparative to the the phosphor screens, results in good X-ray conversion efficiency. It is, however, limited by the same limitations found in xerography in general, i.e., dynamic range and the complexity of processing equipment. Furthermore, the image is not in a format that can readily provide a digital output.
- SUBSTITUTE SHEET More recent developments include the use of an electrostatic image capture element to capture a latent X-ray image, the element comprising a photoconductive layer over an insulating layer on a conductive support, the photoconductive layer also covered by a dielectric layer, and the dielectric layer overcoated with a transparent electrode.
- a biasing voltage is applied between the transparent electrode and the conductive support to charge the element which is a large parallel plate capacitor. While the bias voltage is applied, the element is exposed to image wise modulated X-ray radiation. Following exposure, the bias is removed and a latent image is preserved as a charge distribution trapped in the dielectric layer.
- the latent image represented by local charge variations is a very small signal charge that must be extracted in the presence of random noise in the total capacitive charge in the full plate.
- Signal to noise ratio is typically poor.
- the transparent electrode is laid over the dielectric layer as a plurality of parallel narrow strips . In this manner the overall plate capacity is reduced and the signal extracted per picture element has a better signal to noise ratio.
- Methods to readout the latent image include inter alia, scanning the length of the strip electrode with a laser beam while reading the charge flow across the electrode and the conductive plate.
- an X-ray image capture element comprising a microcapacitor matrix structure that effectively retains charge while limiting the effects of dark current leakage during reading of the image.
- an X-ray image capture element comprising: a first, electrically conductive, backing layer; a second, photoconductive layer responsive to both actinic and X-ray radiation extending substantially over said backing layer; a third, dielectric layer substantially transparent to both actinic and X-ray radiation, the dielectric layer having a front surface and a back surface extending substantially over and in contact with said photoconductive layer; and a plurality of discrete conductive microplates substantially transparent to both actinic and X-ray radiation, said microplates on said front surface, each of said microplates having dimensions coextensive with a minimum resolvable picture element .
- the barrier layer may behave as a blocking diode blocking the flow of charges in one direction.
- an X-ray image capture device comprising: (a) an element having: a first, electrically conductive, backing layer; a second, photoconductive layer responsive to both actinic and X-ray radiation extending substantially over said backing layer;
- SUBSTITUTE SHEET a third, dielectric layer substantially transparent to both actinic and X-ray radiation, the dielectric layer having a front surface and a back surface extending substantially over and in contact with said photoconductive layer; and a plurality of discrete conductive microplates substantially transparent to both actinic and X-ray radiation, said microplates on said front surface, each of said microplates having dimensions coextensive with a minimum resolvable picture element;
- conductive contacting means preferably resilient, for simultaneously contacting said plurality of microplates movable between a first position in contact with said microplates to a second position away from contact with said microplates;
- Still another object of the present invention is to provide a method for capturing a radiogram on an X-ray image capture element comprising: a first, electrically conductive, backing layer; a second, photoconductive layer responsive to both actinic and X-ray radiation extending substantially over said backing layer; a third, dielectric layer substantially transparent to both actinic and X-ray radiation, the dielectric layer having a front surface and a back surface extending substantially over and in contact with said photoconductive layer; and
- SUBSTITUTE SHEET a plurality of discrete conductive microplates substantially transparent to both actinic and X-ray radiation, said microplates on said front surface, each of said microplates having dimensions coextensive with a minimum resolvable picture element; the method comprising:
- the method further comprises an additional step (e) after step (d) , the step (e) comprising exposing the element to uniform actinic radiation for a second time period.
- Figure 1 shows a schematic cross sectional view of an X-ray capture element in accordance with the present invention.
- Figure 2 shows a schematic cross sectional view of an alternate embodiment of an X-ray capture element in accordance with the present invention incorporating a charge barrier layer.
- Figure 2a is a top view of the embodiment of the X- ray capture element shown in Figure 2.
- Figure 3 shows a schematic cross sectional view of a device for capturing a latent X-ray image in accordance with the present invention.
- SUBSTITUTE SHEET Figure 4 depicts a schematic representation of the device of Figure 3 in an enclosure to protect the device from exposure to actinic radiation.
- Figure 5 shows in schematic representation an arrangement using the enclosure of Figure 4 for capturing a latent X-ray image.
- Figure 6 represents an electrical equivalent of the element prior to exposure to x-ray radiation.
- Figure 7 represents an electrical equivalent of the element just after exposure to x-ray radiation.
- Figure 8 represents an electrical equivalent of the element just after exposure to x-ray radiation and removal of the conductive, resilient contacting layer.
- Figure 9 represents an electrical equivalent of the element just after a uniform actinic exposure following exposure to x-ray radiation and removal of the bias source and of the conductive, resilient contacting layer.
- Figure 10 is a schematic representation of a preferred arrangement of a resilient conductive contacting layer with pneumatic backing.
- an X- ray image capture element 16 has a first conductive backing layer 12.
- This conductive backing layer 12 is made of conductive material, and may be rigid or flexible, transparent or non transparent. Preferably it is a continuous layer made of a sufficiently thick and rigid conductive material to serve as support for the other layers that comprise the image capture element 16.
- the photoconductive layer 8 preferably exhibits very high dark resistivity.
- the photoconductive layer 8 may comprise amorphous selenium, lead oxide, cadmium sulfide, mercuric iodide or any other such material, including organic materials such as photoconductive polymers preferably loaded with X-ray absorbing compounds, which exhibit photoconductivity.
- exhibiting photoconductivity means that upon exposure to actinic or X-ray radiation, the material exhibits reduced resistivity than in the absence of such exposure.
- the reduced resistivity is in reality the effect of electron hole pairs generated in the material by the incident radiation.
- the change in apparent resistivity is proportional to the intensity of the incident radiation.
- actinic radiation again for purposes of describing the present invention, is meant ultraviolet (U.V.), infrared (I.R.) or visible but excludes X-ray and gamma radiation.
- the photoconductive layer 8 should be chosen of sufficient thickness to absorb the incident X-ray radiation, or a substantial portion thereof, to provide high efficiency in radiation detection.
- the specific type of material selected will further depend upon the desired charge retention time, and the desired simplicity of manufacture. Selenium is one preferred such material.
- dielectric layer 6 Over the front surface of photoconductive layer 8 there is applied a dielectric layer 6.
- the dielectric layer 6 must be transparent to both X-ray and actinic radiation and have sufficient thickness to prevent charge leakage. In the preferred embodiment of the present invention, the dielectric layer 6 should have a thickness greater than 100 Angstroms. Mylar® with a
- SUBSTITUTE SHEET thickness of 50 ⁇ m may be used for layer 6, although thinner layers are suitable.
- microplates As shown in Figures 1, 2 and 2a, over the dielectric layer 6 there is created a plurality of discrete minute conductive electrodes, 4a, 4b, 4c, etc., referred to herein as microplates .
- the dimensions of the microplates define a smallest picture element (PIXEL) resolvable by this element 16.
- PIXEL picture element
- the electrodes 4a, 4b, 4c, etc. are substantially transparent to both actinic and X-ray radiation. They are deposited on the dielectric layer 6, typically, though not necessarily, using vapor or chemical deposition techniques, and can be made of a very thin film of metal such as gold, silver, aluminum, copper, chromium, titanium, platinum and the like.
- the microplates 4a, 4b, 4c, etc. are made of transparent indium-tin oxide.
- the microplates 4a, 4b, 4c, etc. are normally deposited as a continuous layer which is then etched to produce a plurality of individual discrete microplates having dimensions coextensive with the smallest resolvable picture element.
- the microplates 4a, 4b, 4c, etc. may also be produced using laser ablation or photoetching.
- the technology to produce such microplates is well known in the art and is not further discussed herein. A good description of photomicrofabrication techniques is given in imaging Processing _&. Material, chapter 18, entitled “Imaging for Microfabrication", P. 567 by J. M. Shaw of IBM Watson Research Center.
- each one of the microplates 4a, 4b, 4c, etc., with the dielectric layer 6, the photoconductive layer 8, and the backing conductive layer 12 form two microcapacitors in series, a first microcapacitor being created between the microplate and the front surface of the photoconductive layer 8 and a
- a charge barrier layer 10 is added on top of the conductive layer 12.
- the base plate or layer 12 is made of an oxide forming metal such as aluminum, and the charge barrier layer 10 is provided by an aluminum oxide layer formed on the surface of the base plate or layer 12.
- the subsequent coating thereon of a selenium photoconductive layer 8 produces a barrier layer 10 behaving as a blocking diode, inhibiting charge flow in one direction.
- the charge barrier layer 10 may also be a simple insulating layer such as Polyethylene Terephthalate (Mylar®) , of dimensions comparable to the dielectric layer 6.
- Mylar® Polyethylene Terephthalate
- Dielectric layer 6 substantially transparent to both X-ray and actinic radiation and having sufficient thickness to prevent charge leakage, is placed over the front surface of photoconductive medium layer 8.
- Transparent, discrete, microplates or electrodes 4a, 4b, 4c, etc., are formed over the dielectric layer 6 as before.
- the entire element 16 can be made by depositing successive layers of conductor, insulator, photoconductor, insulator, and conductor upon a substrate. Assembly may be accomplished by vapor deposition, vacuum deposition, lamination, sputtering or any other known technique useful to deposit even thickness films.
- the conductive backing layer 12, the charge barrier layer 10, the photoconductive layer 8 and the dielectric layer 6, are all continuous layers. However, it is still within the contemplation of the present invention to manufacture an
- SUBSTITUTE SHEET element for X-ray capture as herein above structured, in which not only the transparent electrode layer has been etched to produce a plurality of microplates 4a, 4b, 4c, etc., but one or more of the underlying layers 6, 8, 10 and 12 may also be etched with substantially the same pattern as the electrode layer, to form a plurality of discrete dielectric portions, photoconductive portions, barrier layer portions or even conductive portions lying below the microplates 4a, 4b, 4c, etc., in registration therewith.
- microplates 4a, 4b, 4c, etc. rather than etching a continuous layer to generate the microplates 4a, 4b, 4c, etc., direct deposition of the microplates 4a, 4b, 4c, etc., using masking techniques may be used, the method of manufacturing being one of choice depending on available resources and cost considerations, rather than an essential element or step of the present invention.
- the element 16 of Figure 1 or 2 is preferably used in a device of the type shown in Figure 3 to capture a latent X-ray image in a manner somewhat similar to the use of traditional silver halide film in a screen containing cassette.
- a device comprises in addition to an element for x-ray capture as described above, additional layers 2 and 20.
- Layer 2 is a conductive contacting layer which, in order to assure good electrical contact is preferably a resilient conductive layer, such as conductive foam, conductive velvet or conductive rubber.
- the use of the term resilient herein includes flexible layers.
- Layer 2 is movable between two positions, a first position in contact with the microplates 4a, 4b, 4c, etc., and a second position, not shown in the Figures, away from the microplates 4a, 4b, 4c, etc.
- This resilient layer 2 is preferably affixed onto a rigid supporting layer 20.
- Layers 20 and 2 are substantially transparent to X-ray radiation.
- An electrical bias source 30 is connected to the backing electrode 12 and the conductive resilient layer 2 to apply a DC bias voltage across the element 16.
- the conductive layer 2 comprises a conductive membrane 62 mounted on a framework which allows the application of pressure from a back side of the membrane 62 by injection of a fluid medium, such as air.
- Figure 10 shows such a possible structure which may be incorporated as an integral part of a cassette 22 shown in Figure 4 and discussed in detail below.
- the structure comprises a supporting enclosure 60 which is preferably airtight, and which supports on its lower end the flexible conductive membrane 62.
- the membrane 62 may be conductive rubber.
- Contact means 72 are available to provide a path for connecting an external electrical bias source, i.e., source 30 which is not shown in Figure 10, to the membrane 62.
- An orifice means 66 through a valve 68 allows one to supply the fluid medium to chamber 64 formed by the airtight enclosure 60 and the flexible membrane 62.
- This structure results in a support for the membrane 62 that exhibits good and uniform flexibility and resiliency, assuring that each and everyone of the microplates 4a, 4b, 4c, etc., is contacted by the conductive layer 62.
- the contacting layer 2 may comprise a layer of ionized gas contained in an enclosure covering the top surface of the element 16 to provide electrical contact between the microplates 4a, 4b, 4c, etc., and the bias source 30.
- the ionization of the gas may be achieved using a two dimensional corona device which may be built within an enclosure which may also be built as an integral part of cassette 22.
- the device described may include a cassette enclosure to shield the element 16 from exposure to
- FIG. 4 shows such an arrangement in which a cassette-like enclosure 22 is used.
- the cassette enclosure 22 is made of material which is opaque to ambient actinic radiation but transparent to X-rays. Since the ambient levels of gamma radiation are not usually high enough to present any exposure problems, it is not necessary that the material be opaque to gamma radiation. Similarly, in the absence of ambient IR radiation the enclosure need not be opaque thereto.
- the enclosure 22 may include a hinge 24 hingedly connecting a top section 25 and a bottom section 27, allowing the cassette 22 to open and close at will.
- a hinge 24 hingedly connecting a top section 25 and a bottom section 27, allowing the cassette 22 to open and close at will.
- the cassette 22 further includes electrical connecting means 34 which permits one to connect power source 30 via wiring 26 and 28 to the conductive layer 2 and the conductive backing 12. Supporting layer 20 may also be conductive to facilitate the connection arrangement.
- a switch 32 is optionally provided to permit applying and stopping the applying of a bias voltage to the cassette 22.
- the element 16 is placed in the cassette 22 as shown in Figure 4, and the cassette 22 is placed in the path of information modulated X-ray radiation in a manner similar to the way a traditional cassette-photosensitive film combination is positioned.
- This arrangement is schematically depicted in Figure 5 which shows a source of X-ray radiation 35, emitting a beam 36 of X-rays.
- a target 38 i.e., a patient in the case of medical diagnostic imaging, is placed in the X-ray beam path. The emerging radiation through the patient is intensity modulated
- SUBSTITUTE SHEET because of the different degree of X-ray absorption in the target 38.
- the modulated X-ray radiation beam 36 is then intercepted by the cassette 22 containing element 16.
- X-rays penetrate the enclosure 22 and are eventually absorbed by the photoconductive layer 8 altering its apparent resistivity in proportion to the radiation intensity along the X-ray paths therethrough. Viewed in a different way, the X-rays generate a flow of electron hole pairs, of which the electrons are accumulated in the interface between the photoconductive layer 8 and the dielectric layer 6.
- Switch 32 is closed during the exposure step in synchronization therewith or prior thereto, applying a bias D.C. voltage to the element.
- the X-ray flux is interrupted and X-rays no longer impinge on the element 16.
- the application of the bias voltage is then, either simultaneously or soon thereafter removed from the element 16, such as, by opening the switch 32.
- the layer 2 is moved away from contact with element 16 and the cassette 22 may then be opened.
- the cassette 22 may be so arranged that moving layer 2 away from contact with element 16 results in the removal of the bias voltage in a manner similar to that obtained through the action of switch 32.
- the element 16 can now be handled in the presence of actinic radiation without loss of the stored image information contained in it as a charge distribution in the microcapacitors in the dielectric layer 6.
- the element 16 is intentionally exposed to a large dose of actinic radiation, as by a flash exposure, to eliminate the charges stored in the photoconductive layer 8, by momentarily rendering such photoconductive layer 8
- SUBSTITUTE SHEET substantially conductive.
- the layer 8 behaves as substantially conductive, because the abundant illumination produces an ample supply of electron hole pairs, in effect neutralizing any charges stored in the photoconductive layer 8.
- Figure 6 which represents an equivalent electric circuit of the combination of the transparent electrode, the dielectric, the photoconductive and the backing conductive layers 4, 6, 8 and 10.
- a variable resistance in dotted lines representing the effect of the electron hole pair generation in the photoconductive layer 8.
- the microcapacitors When voltage supply 30 is connected across the element 16 as shown in Figure 6, in the absence of actinic or X-ray radiation, the microcapacitors are all charged uniformly, the charge being a function of the capacitance of each capacitor. In the present case where all capacitors have the same area plates, the capacitance will depend on the plate separation and dielectric constant of the material between the plates . In the described structure this will result in two different voltages appearing across the capacitors, one in the capacitors representing the photoconductor layer 8, the other in the dielectric layer 6. If, for instance, the applied voltage difference from the bias source 30 is 2000 volts, it could be distributed across the two capacitors as 1200 volts across the dielectric layer 6 and 800 volts across the photoconductor layer 8.
- the optional charge barrier layer 10 acts to assure that there is no charge leakage to equalize the charges over long periods of time.
- the conductive contacting resilient layer 2 After termination of the X-ray exposure, the conductive contacting resilient layer 2 is moved to a position away from the microplates 4a, 4b, etc., breaking contact therewith and removing the source 30 from the element 16.
- Figure 8 shows the voltage distribution at this point . The charges having nowhere to go and remain fixed as they were at the end of the X- ray exposure time period. At this time the voltage source 30 may be completely removed from contact with the element 16 or the cassette 22.
- each capacitor pair is still 2000 volts.
- the charges in the dielectric portion of each capacitor are no longer uniform across the full surface of element 16, but vary, representing a latent radiographic image.
- the flash exposure while preferably done using actinic radiation, can also be performed using additional, unmodulated X- ray radiation.
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Abstract
An element, a device and an associated method for capturing radiographic images. More particularly, the present invention uses a unique microcapacitor matrix structure to hold varying electrical charges representing a latent radiographic image.
Description
TITLE OF THE INVENTION
ELEMENT, DEVICE AND ASSOCIATED METHOD FOR CAPTURING A LATENT RADIOGRAPHIC IMAGE
BACKGROUND OF THE INVENTION 1. FIELD OF THE INVENTION.
The present invention relates to an element, a device and an associated method for capturing radiographic images. More particularly, the present invention uses a unique microcapacitor matrix structure to hold varying electrical charges representing a latent radiographic image.
2. DESCRIPTION OF RELATED ART.
Traditional radiography employs a silver halide photosensitive film in a light tight cassette enclosure to capture a latent radiographic image which is subsequently rendered visible following chemical development and fixing. Because silver halide film is not very sensitive to X-ray radiation, and large exposures are required to obtain an image, most applications use a combination of an intensifying screen incorporated in the cassette with the silver halide film to achieve lower exposures. Intensifying screens typically comprise a phosphor layer coated over a supporting substrate. As a result of the impingement of X-ray radiation, the phosphor layers emit photons. The emitted photons, i.e., the light intensity output, are proportional to the X-ray energy level absorbed by the phosphor particles in the screen. The film sensitivity is adjusted to match the color output of the phosphor. The phosphor layer has a greater thickness than typical film emulsion and increased X-ray stopping efficiency. The overall response of the combined film screen system
- 1 -
SUBSTITUTE SHEET
is thus greatly enhanced. In practice. X-ray films are often coated on both sides with photosensitive emulsion and two screens are used to expose the film from both sides, further increasing the efficiency of the system and reducing the exposure time required to obtain a radiogram.
Radiograms have also been produced by capturing a latent radiographic image using a photoconductive plate in a xeroradiographic process. In this instance, a photoconductive plate sensitive to X-ray radiation comprising at least a photoconductive layer coated over a conductive backing layer is first charged by passing under a charging station typically comprising a corona wire. Positive or negative charge is uniformly deposited over the plate surface. The plate is next exposed to X-ray radiation. Depending on the intensity of the incident radiation, electron hole pairs generated by the X-ray radiation are separated by a field incident to the charge laid over the surface and as a result move along the field to recombine with the surface charge. After X-ray exposure, a latent image in the form of electrical charges of varying magnitude remain on the plate surface, representing a latent electrostatic radiogram. This latent image may then be rendered visible by toning and preferably transferring onto a receiving surface for better viewing.
Xeroradiography, a specific application of electroradiography offers high resolution and, because the photoconductive layer may be made fairly thick comparative to the the phosphor screens, results in good X-ray conversion efficiency. It is, however, limited by the same limitations found in xerography in general, i.e., dynamic range and the complexity of processing equipment. Furthermore, the image is not in a format that can readily provide a digital output.
- 2 -
SUBSTITUTE SHEET
More recent developments include the use of an electrostatic image capture element to capture a latent X-ray image, the element comprising a photoconductive layer over an insulating layer on a conductive support, the photoconductive layer also covered by a dielectric layer, and the dielectric layer overcoated with a transparent electrode. A biasing voltage is applied between the transparent electrode and the conductive support to charge the element which is a large parallel plate capacitor. While the bias voltage is applied, the element is exposed to image wise modulated X-ray radiation. Following exposure, the bias is removed and a latent image is preserved as a charge distribution trapped in the dielectric layer. The problem with this element structure is that the latent image represented by local charge variations is a very small signal charge that must be extracted in the presence of random noise in the total capacitive charge in the full plate. Signal to noise ratio is typically poor. In an effort to improve the signal to noise ratio, the transparent electrode is laid over the dielectric layer as a plurality of parallel narrow strips . In this manner the overall plate capacity is reduced and the signal extracted per picture element has a better signal to noise ratio. Methods to readout the latent image include inter alia, scanning the length of the strip electrode with a laser beam while reading the charge flow across the electrode and the conductive plate. While this element is a vast improvement over the continuous electrode structure covering the full plate, the signal to noise ratio is still a problem because of the relatively high dark current leakage under the electrode strip. Thus, an X-ray capture system based on this element structure still suffers in image quality.
- 3 -
SUBSTITUTE SHEET
SUMMARY OF THE INVENTION
It is an object of the present invention to provide an X-ray image capture element comprising a microcapacitor matrix structure that effectively retains charge while limiting the effects of dark current leakage during reading of the image. Thus, in accordance with the present invention, there is provided an X-ray image capture element, comprising: a first, electrically conductive, backing layer; a second, photoconductive layer responsive to both actinic and X-ray radiation extending substantially over said backing layer; a third, dielectric layer substantially transparent to both actinic and X-ray radiation, the dielectric layer having a front surface and a back surface extending substantially over and in contact with said photoconductive layer; and a plurality of discrete conductive microplates substantially transparent to both actinic and X-ray radiation, said microplates on said front surface, each of said microplates having dimensions coextensive with a minimum resolvable picture element .
It is also an object of this invention to provide an element which further comprises a charge barrier layer extending between the photoconductive layer and the backing layer. The barrier layer may behave as a blocking diode blocking the flow of charges in one direction.
It is a further object of this invention to provide an X-ray image capture device, comprising: (a) an element having: a first, electrically conductive, backing layer; a second, photoconductive layer responsive to both actinic and X-ray radiation extending substantially over said backing layer;
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SUBSTITUTE SHEET
a third, dielectric layer substantially transparent to both actinic and X-ray radiation, the dielectric layer having a front surface and a back surface extending substantially over and in contact with said photoconductive layer; and a plurality of discrete conductive microplates substantially transparent to both actinic and X-ray radiation, said microplates on said front surface, each of said microplates having dimensions coextensive with a minimum resolvable picture element;
(b) conductive contacting means, preferably resilient, for simultaneously contacting said plurality of microplates movable between a first position in contact with said microplates to a second position away from contact with said microplates; and
(c) electric power source means for applying an electric potential difference between said conductive contacting means and said backing layer.
Also within the objects of the present invention are means associated with the above described device for preventing actinic radiation from impinging on said element .
Still another object of the present invention is to provide a method for capturing a radiogram on an X-ray image capture element comprising: a first, electrically conductive, backing layer; a second, photoconductive layer responsive to both actinic and X-ray radiation extending substantially over said backing layer; a third, dielectric layer substantially transparent to both actinic and X-ray radiation, the dielectric layer having a front surface and a back surface extending substantially over and in contact with said photoconductive layer; and
- 5 -
SUBSTITUTE SHEET
a plurality of discrete conductive microplates substantially transparent to both actinic and X-ray radiation, said microplates on said front surface, each of said microplates having dimensions coextensive with a minimum resolvable picture element; the method comprising:
(a) preventing actinic radiation from impinging on said element;
(b) applying an electric potential difference between said plurality of discrete conductive microplates and said backing layer;
(c) impinging imagewise modulated X-ray radiation for a first time period onto the element; and
(d) after the first time period, stopping the applying step.
Optionally, the method further comprises an additional step (e) after step (d) , the step (e) comprising exposing the element to uniform actinic radiation for a second time period.
BRIEF DESCRIPTION OF THE DRAWINGS
Figure 1 shows a schematic cross sectional view of an X-ray capture element in accordance with the present invention. Figure 2 shows a schematic cross sectional view of an alternate embodiment of an X-ray capture element in accordance with the present invention incorporating a charge barrier layer.
Figure 2a is a top view of the embodiment of the X- ray capture element shown in Figure 2.
Figure 3 shows a schematic cross sectional view of a device for capturing a latent X-ray image in accordance with the present invention.
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SUBSTITUTE SHEET
Figure 4 depicts a schematic representation of the device of Figure 3 in an enclosure to protect the device from exposure to actinic radiation.
Figure 5 shows in schematic representation an arrangement using the enclosure of Figure 4 for capturing a latent X-ray image.
Figure 6 represents an electrical equivalent of the element prior to exposure to x-ray radiation.
Figure 7 represents an electrical equivalent of the element just after exposure to x-ray radiation.
Figure 8 represents an electrical equivalent of the element just after exposure to x-ray radiation and removal of the conductive, resilient contacting layer.
Figure 9 represents an electrical equivalent of the element just after a uniform actinic exposure following exposure to x-ray radiation and removal of the bias source and of the conductive, resilient contacting layer.
Figure 10 is a schematic representation of a preferred arrangement of a resilient conductive contacting layer with pneumatic backing.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
Referring now to the drawings, in Figure 1, an X- ray image capture element 16 has a first conductive backing layer 12. This conductive backing layer 12 is made of conductive material, and may be rigid or flexible, transparent or non transparent. Preferably it is a continuous layer made of a sufficiently thick and rigid conductive material to serve as support for the other layers that comprise the image capture element 16. In its simpler structure, there is coated over the conductive backing layer 12 a photoconductive layer 8 having a back surface in contact with the conductive
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SUBSTITUTE SHEET
backing layer, and a front surface. The photoconductive layer 8 preferably exhibits very high dark resistivity. The photoconductive layer 8 may comprise amorphous selenium, lead oxide, cadmium sulfide, mercuric iodide or any other such material, including organic materials such as photoconductive polymers preferably loaded with X-ray absorbing compounds, which exhibit photoconductivity.
In the context of the present invention, exhibiting photoconductivity means that upon exposure to actinic or X-ray radiation, the material exhibits reduced resistivity than in the absence of such exposure. The reduced resistivity is in reality the effect of electron hole pairs generated in the material by the incident radiation. Preferably, the change in apparent resistivity is proportional to the intensity of the incident radiation. By actinic radiation, again for purposes of describing the present invention, is meant ultraviolet (U.V.), infrared (I.R.) or visible but excludes X-ray and gamma radiation.
The photoconductive layer 8 should be chosen of sufficient thickness to absorb the incident X-ray radiation, or a substantial portion thereof, to provide high efficiency in radiation detection. The specific type of material selected will further depend upon the desired charge retention time, and the desired simplicity of manufacture. Selenium is one preferred such material.
Over the front surface of photoconductive layer 8 there is applied a dielectric layer 6. The dielectric layer 6 must be transparent to both X-ray and actinic radiation and have sufficient thickness to prevent charge leakage. In the preferred embodiment of the present invention, the dielectric layer 6 should have a thickness greater than 100 Angstroms. Mylar® with a
- 8 -
SUBSTITUTE SHEET
thickness of 50 μm may be used for layer 6, although thinner layers are suitable.
As shown in Figures 1, 2 and 2a, over the dielectric layer 6 there is created a plurality of discrete minute conductive electrodes, 4a, 4b, 4c, etc., referred to herein as microplates . The dimensions of the microplates define a smallest picture element (PIXEL) resolvable by this element 16. The electrodes 4a, 4b, 4c, etc., are substantially transparent to both actinic and X-ray radiation. They are deposited on the dielectric layer 6, typically, though not necessarily, using vapor or chemical deposition techniques, and can be made of a very thin film of metal such as gold, silver, aluminum, copper, chromium, titanium, platinum and the like. Preferably the microplates 4a, 4b, 4c, etc., are made of transparent indium-tin oxide. The microplates 4a, 4b, 4c, etc., are normally deposited as a continuous layer which is then etched to produce a plurality of individual discrete microplates having dimensions coextensive with the smallest resolvable picture element. The microplates 4a, 4b, 4c, etc., may also be produced using laser ablation or photoetching. The technology to produce such microplates is well known in the art and is not further discussed herein. A good description of photomicrofabrication techniques is given in imaging Processing _&. Material, chapter 18, entitled "Imaging for Microfabrication", P. 567 by J. M. Shaw of IBM Watson Research Center.
The combination of each one of the microplates 4a, 4b, 4c, etc., with the dielectric layer 6, the photoconductive layer 8, and the backing conductive layer 12 form two microcapacitors in series, a first microcapacitor being created between the microplate and the front surface of the photoconductive layer 8 and a
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SUBSTITUTE SHEET
second microcapacitor between that same surface and the conductive backing layer 12.
In an alternate and preferred structure, shown in Figure 2, a charge barrier layer 10, is added on top of the conductive layer 12. Preferably, the base plate or layer 12 is made of an oxide forming metal such as aluminum, and the charge barrier layer 10 is provided by an aluminum oxide layer formed on the surface of the base plate or layer 12. In this case, the subsequent coating thereon of a selenium photoconductive layer 8 produces a barrier layer 10 behaving as a blocking diode, inhibiting charge flow in one direction.
The charge barrier layer 10 may also be a simple insulating layer such as Polyethylene Terephthalate (Mylar®) , of dimensions comparable to the dielectric layer 6.
Dielectric layer 6, substantially transparent to both X-ray and actinic radiation and having sufficient thickness to prevent charge leakage, is placed over the front surface of photoconductive medium layer 8.
Transparent, discrete, microplates or electrodes 4a, 4b, 4c, etc., are formed over the dielectric layer 6 as before.
The entire element 16 can be made by depositing successive layers of conductor, insulator, photoconductor, insulator, and conductor upon a substrate. Assembly may be accomplished by vapor deposition, vacuum deposition, lamination, sputtering or any other known technique useful to deposit even thickness films.
In the preferred embodiment, the conductive backing layer 12, the charge barrier layer 10, the photoconductive layer 8 and the dielectric layer 6, are all continuous layers. However, it is still within the contemplation of the present invention to manufacture an
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SUBSTITUTE SHEET
element for X-ray capture as herein above structured, in which not only the transparent electrode layer has been etched to produce a plurality of microplates 4a, 4b, 4c, etc., but one or more of the underlying layers 6, 8, 10 and 12 may also be etched with substantially the same pattern as the electrode layer, to form a plurality of discrete dielectric portions, photoconductive portions, barrier layer portions or even conductive portions lying below the microplates 4a, 4b, 4c, etc., in registration therewith. Furthermore, rather than etching a continuous layer to generate the microplates 4a, 4b, 4c, etc., direct deposition of the microplates 4a, 4b, 4c, etc., using masking techniques may be used, the method of manufacturing being one of choice depending on available resources and cost considerations, rather than an essential element or step of the present invention.
The element 16 of Figure 1 or 2 is preferably used in a device of the type shown in Figure 3 to capture a latent X-ray image in a manner somewhat similar to the use of traditional silver halide film in a screen containing cassette. Such a device comprises in addition to an element for x-ray capture as described above, additional layers 2 and 20. Layer 2 is a conductive contacting layer which, in order to assure good electrical contact is preferably a resilient conductive layer, such as conductive foam, conductive velvet or conductive rubber. The use of the term resilient herein includes flexible layers. Layer 2 is movable between two positions, a first position in contact with the microplates 4a, 4b, 4c, etc., and a second position, not shown in the Figures, away from the microplates 4a, 4b, 4c, etc. This resilient layer 2 is preferably affixed onto a rigid supporting layer 20. Layers 20 and 2 are substantially transparent to X-ray radiation.
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SUBSTITUTE SHEET
An electrical bias source 30 is connected to the backing electrode 12 and the conductive resilient layer 2 to apply a DC bias voltage across the element 16.
In a preferred embodiment, the conductive layer 2 comprises a conductive membrane 62 mounted on a framework which allows the application of pressure from a back side of the membrane 62 by injection of a fluid medium, such as air. Figure 10 shows such a possible structure which may be incorporated as an integral part of a cassette 22 shown in Figure 4 and discussed in detail below. The structure comprises a supporting enclosure 60 which is preferably airtight, and which supports on its lower end the flexible conductive membrane 62. The membrane 62 may be conductive rubber. Contact means 72 are available to provide a path for connecting an external electrical bias source, i.e., source 30 which is not shown in Figure 10, to the membrane 62. An orifice means 66 through a valve 68 allows one to supply the fluid medium to chamber 64 formed by the airtight enclosure 60 and the flexible membrane 62. This structure results in a support for the membrane 62 that exhibits good and uniform flexibility and resiliency, assuring that each and everyone of the microplates 4a, 4b, 4c, etc., is contacted by the conductive layer 62.
In an alternate embodiment, the contacting layer 2 may comprise a layer of ionized gas contained in an enclosure covering the top surface of the element 16 to provide electrical contact between the microplates 4a, 4b, 4c, etc., and the bias source 30. The ionization of the gas may be achieved using a two dimensional corona device which may be built within an enclosure which may also be built as an integral part of cassette 22.
In use, the device described may include a cassette enclosure to shield the element 16 from exposure to
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SUBSTITUTE SHEET
actinic radiation, much in the manner a cassette shields an X-ray film. Figure 4 shows such an arrangement in which a cassette-like enclosure 22 is used. The cassette enclosure 22 is made of material which is opaque to ambient actinic radiation but transparent to X-rays. Since the ambient levels of gamma radiation are not usually high enough to present any exposure problems, it is not necessary that the material be opaque to gamma radiation. Similarly, in the absence of ambient IR radiation the enclosure need not be opaque thereto.
The enclosure 22 may include a hinge 24 hingedly connecting a top section 25 and a bottom section 27, allowing the cassette 22 to open and close at will. Within the top section 25, there is affixed supporting layer 20 and conductive contacting layer 2.
The cassette 22 further includes electrical connecting means 34 which permits one to connect power source 30 via wiring 26 and 28 to the conductive layer 2 and the conductive backing 12. Supporting layer 20 may also be conductive to facilitate the connection arrangement. A switch 32 is optionally provided to permit applying and stopping the applying of a bias voltage to the cassette 22. To obtain a latent radiographic image, the element 16 is placed in the cassette 22 as shown in Figure 4, and the cassette 22 is placed in the path of information modulated X-ray radiation in a manner similar to the way a traditional cassette-photosensitive film combination is positioned. This arrangement is schematically depicted in Figure 5 which shows a source of X-ray radiation 35, emitting a beam 36 of X-rays. A target 38, i.e., a patient in the case of medical diagnostic imaging, is placed in the X-ray beam path. The emerging radiation through the patient is intensity modulated
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SUBSTITUTE SHEET
because of the different degree of X-ray absorption in the target 38. The modulated X-ray radiation beam 36 is then intercepted by the cassette 22 containing element 16. X-rays penetrate the enclosure 22 and are eventually absorbed by the photoconductive layer 8 altering its apparent resistivity in proportion to the radiation intensity along the X-ray paths therethrough. Viewed in a different way, the X-rays generate a flow of electron hole pairs, of which the electrons are accumulated in the interface between the photoconductive layer 8 and the dielectric layer 6. Switch 32 is closed during the exposure step in synchronization therewith or prior thereto, applying a bias D.C. voltage to the element. After a predetermined first time period the X-ray flux is interrupted and X-rays no longer impinge on the element 16. The application of the bias voltage is then, either simultaneously or soon thereafter removed from the element 16, such as, by opening the switch 32. Following removal of the bias voltage from the element 16, the layer 2 is moved away from contact with element 16 and the cassette 22 may then be opened. In the alternative, the cassette 22 may be so arranged that moving layer 2 away from contact with element 16 results in the removal of the bias voltage in a manner similar to that obtained through the action of switch 32.
The element 16 can now be handled in the presence of actinic radiation without loss of the stored image information contained in it as a charge distribution in the microcapacitors in the dielectric layer 6. Preferably at this point, the element 16 is intentionally exposed to a large dose of actinic radiation, as by a flash exposure, to eliminate the charges stored in the photoconductive layer 8, by momentarily rendering such photoconductive layer 8
- 14 -
SUBSTITUTE SHEET
substantially conductive. The layer 8 behaves as substantially conductive, because the abundant illumination produces an ample supply of electron hole pairs, in effect neutralizing any charges stored in the photoconductive layer 8.
The combination of the dielectric and photoconductive layers 6 and 8 between the conductive microplates 4a, 4b, 4c, etc., and the backing layer 12, behave as two capacitors in series, one representing the dielectric, the other representing the photoconductor as shown in Figure 6 which represents an equivalent electric circuit of the combination of the transparent electrode, the dielectric, the photoconductive and the backing conductive layers 4, 6, 8 and 10. In parallel with the photoconductive layer 8, there is shown a variable resistance in dotted lines representing the effect of the electron hole pair generation in the photoconductive layer 8.
When voltage supply 30 is connected across the element 16 as shown in Figure 6, in the absence of actinic or X-ray radiation, the microcapacitors are all charged uniformly, the charge being a function of the capacitance of each capacitor. In the present case where all capacitors have the same area plates, the capacitance will depend on the plate separation and dielectric constant of the material between the plates . In the described structure this will result in two different voltages appearing across the capacitors, one in the capacitors representing the photoconductor layer 8, the other in the dielectric layer 6. If, for instance, the applied voltage difference from the bias source 30 is 2000 volts, it could be distributed across the two capacitors as 1200 volts across the dielectric layer 6 and 800 volts across the photoconductor layer 8.
- 15 -
SUBSTITUTE SHEET
When the element 16 is exposed to X-ray radiation, the overall voltage does not change, but because of the generation and movement of electron hole pairs, there is a new charge distribution in each of the microcapacitors, dependent on the radiation intensity incident on each of the microcapacitors, which produces a new voltage distribution between the two series connected microcapacitors. Figure 7 shows schematically such a hypothetical consequential voltage redistribution.
When the X-ray exposure is terminated, the charges remain trapped in the microcapacitors. The optional charge barrier layer 10 in this case acts to assure that there is no charge leakage to equalize the charges over long periods of time.
After termination of the X-ray exposure, the conductive contacting resilient layer 2 is moved to a position away from the microplates 4a, 4b, etc., breaking contact therewith and removing the source 30 from the element 16. Figure 8 shows the voltage distribution at this point . The charges having nowhere to go and remain fixed as they were at the end of the X- ray exposure time period. At this time the voltage source 30 may be completely removed from contact with the element 16 or the cassette 22.
The total voltage appearing across each capacitor pair is still 2000 volts. However, the charges in the dielectric portion of each capacitor are no longer uniform across the full surface of element 16, but vary, representing a latent radiographic image. In order to reduce the overall voltage, it is preferred at this stage to flash expose the element 16 with actinic radiation, as shown in Figure 9. The result of such flash exposure, which is done in the absence of a bias voltage and with resilient conductive layer 2 moved away
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SUBSTITUTE SHE!
from contact with the microplates 4a, 4b, etc., is to discharge each of the microcapacitors representing the photoconductive layer 8 in essence bringing one end of each of the dielectric microcapacitors to essentially ground potential. This has the advantage that on readout of the image, which in certain modes entails discharging sequentially each microcapacitor, the potential difference between a fully discharged microcapacitor and an adjacent undischarged as yet microcapacitor is less than it would be if the flash exposure had not occurred. This in turn results in a lesser chance of undesirable arcing between microcapacitors .
It is readily realized of course that the flash exposure, while preferably done using actinic radiation, can also be performed using additional, unmodulated X- ray radiation.
The above description of the manner in which a radiogram is captured by the element 16 and device in terms of a simple electrical equivalent is an oversimplification, given as an aid in understanding why such an element may capture an image in the form of trapped charges in a plurality of microcapacitors. A more accurate description would be one which takes into account the presence of the charge barrier layer 10 and the parasitic capacitances present therein, in addition to the layers discussed herein above. A physicist may also prefer to explain the image capture in terms of charge flow and entrapment, however, the general description of the operation of the element 16 in capturing a latent radiogram as herein above set forth describes the present invention sufficiently to enable an understanding of the underlying principles .
The example and suggested systems illustrated and discussed in this specification are intended to teach
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SUBSTITUTE SHEET
those skilled in the art the best ways known to the inventors to make and use their invention. Thus, the specific embodiments of this specification should be considered as illustrative rather than limiting the scope of the present invention. Many changes could be made by those skilled in the art to produce equivalent systems without departing from this invention.
- 18 -
SUBSTITUTE SHEET
Claims
1. An X-ray image capture element, comprising: a first, electrically conductive, backing layer; a second, photoconductive layer responsive to both actinic and X-ray radiation extending substantially over said backing layer; a third, dielectric layer substantially transparent to both actinic and X-ray radiation, the dielectric layer having a back surface extending substantially over and in contact with said photoconductive layer and a front surface; and a plurality of discrete conductive microplates substantially transparent to both actinic and X-ray radiation, said microplates on said front surface, each of said microplates having dimensions coextensive with a minimum resolvable picture element .
2. The element of claim 1, further comprising a charge barrier layer extending between the photoconductive layer and the backing layer.
3. The element of claim 1, wherein the photoconductive layer comprises selenium.
4. The element of claim 1, wherein the conductive layer comprises aluminum and the photoconductive layer is coated over a surface of the conductive layer after an aluminum oxide layer has developed over substantially all of the surface of the conductive layer.
- 19 -
SUBSTITUTE SHEET
5. The element of claim 1, wherein the conductive, photoconductive, and dielectric layers are continuous layers.
6. The element of claim 2, wherein the conductive, photoconductive, dielectric, and barrier layers are continuous layers.
7. The element of claim 2, wherein the barrier layer is a blocking diode layer allowing charges to flow in one direction only.
8. An X-ray image capture device, comprising: (a) an element having: a first, electrically conductive, backing layer; a second, photoconductive layer responsive to both actinic and X-ray radiation extending substantially over said backing layer; a third, dielectric layer substantially transparent to both actinic and X-ray radiation, the dielectric layer having a back surface extending substantially over and in contact with said photoconductive layer and a front surface; and a plurality of discrete conductive microplates substantially transparent to both actinic and X-ray radiation, said microplates on said front surface, each of said microplates having dimensions coextensive with a minimum resolvable picture element; (b) conductive contacting means for simultaneously contacting said plurality of microplates movable between a first position in contact with said microplates to a second position away from contact with said microplates; and
- 20 -
SUBSTITUTE SHI (c) electric power source means for applying an electric potential difference between said conductive contacting means and said backing layer.
9. The device of claim 8, wherein the conductive contacting means is a resilient conductive layer.
10. The device of claim 8 or 9, further comprising a charge barrier layer extending between the photoconductive layer and the backing layer in the element .
11. The device of claim 8 or 9, wherein the photoconductive layer comprises selenium.
12. The device of claim 8 or 9, wherein the photoconductive layer comprises selenium, the conductive backing layer comprises aluminum, and wherein the photoconductive layer is coated over a surface of the conductive layer after an aluminum oxide layer has developed over substantially all of the surface of the conductive layer.
13. The device of claim 8 or 9, further comprising means for preventing actinic radiation from impinging on said element.
14. The device of claim 8 or 9, further comprising means for switchably applying said potential difference between said conductive contacting means and said backing layer when said contacting means contacts said microplates in said first position.
15. The device of claim 8 or 9, further comprising means for switchably applying said potential difference
- 21 -
SUBSTITUTE SHEET between said conductive contacting means and said backing layer when said contacting means contacts said microplates in said first position, and wherein the photoconductive layer comprises selenium.
16. The device of claim 8 or 9, further comprising means for preventing actinic radiation from impinging on said element, means for switchably applying said potential difference between said conductive contacting means and said backing layer when said contacting means contacts said microplates in said first position, and wherein the photoconductive layer comprises selenium.
17. The device of claim 8 or 9, further comprising a charge barrier layer extending between the photoconductive layer and the backing layer in the element wherein the barrier layer is a blocking diode layer allowing charges to flow in one direction only.
18. The device of claim 8 or 9, wherein the conductive, photoconductive, and dielectric layers are continuous layers.
19. The device of claim 8 or 9, further comprising a charge barrier layer extending between the photoconductive layer and the backing layer in the element wherein the conductive, photoconductive, dielectric, and barrier layers are continuous layers and the photoconductive layer is selenium.
20. A method for capturing a radiogram on an X-ray image capture element comprising: a first, electrically conductive, backing layer;
- 22 -
SUBSTITUTE SHEET a second, photoconductive layer responsive to both actinic and X-ray radiation extending substantially over said backing layer; a third, dielectric layer substantially transparent to both actinic and X-ray radiation, the dielectric layer having a back surface extending substantially over and in contact with said photoconductive layer and a front surface; and a plurality of discrete conductive microplates substantially transparent to both actinic and X-ray radiation, said microplates on said front surface, each of said microplates having dimensions coextensive with a minimum resolvable picture element; the method comprising: (a) preventing actinic radiation from impinging on said element;
(b) applying an electric potential difference between said plurality of discrete conductive microplates and said backing layer; (c) impinging imagewise modulated X-ray radiation for a first time period onto the element; and
(d) after the first time period, stopping the applying step.
21. The method of Claim 20, further comprising:
(e) after step (d) , exposing the element to uniform radiation for a second time period.
22. The method of Claim 20, further comprising': (e) after step (d) , exposing the element to uniform actinic radiation for a second time period.
- 23 -
SUBSTITUTE SHEET
23. The method of claim 20, wherein step (b) further comprises:
(1) contacting said plurality of discrete conductive microplates with a resilient electrically conductive means; and
(2) applying an electric potential difference between said resilient electrical conductive means and said backing layer.
24. The method of claim 23, further comprising:
(e) after step (d) , moving the resilient electrical conductive means away from contacting said plurality of discrete microplates and exposing the element to radiation for a second time period.
25. The method of claim 24, wherein the radiation is uniform actinic radiation.
- 24 -
SUBSTITUTE SHEET
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US1992/006891 WO1994004963A1 (en) | 1992-08-14 | 1992-08-14 | Element, device and associated method for capturing a latent radiographic image |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US1992/006891 WO1994004963A1 (en) | 1992-08-14 | 1992-08-14 | Element, device and associated method for capturing a latent radiographic image |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1994004963A1 true WO1994004963A1 (en) | 1994-03-03 |
Family
ID=22231311
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US1992/006891 Ceased WO1994004963A1 (en) | 1992-08-14 | 1992-08-14 | Element, device and associated method for capturing a latent radiographic image |
Country Status (1)
| Country | Link |
|---|---|
| WO (1) | WO1994004963A1 (en) |
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| US4268750A (en) * | 1979-03-22 | 1981-05-19 | The University Of Texas System | Realtime radiation exposure monitor and control apparatus |
| DE3236137A1 (en) * | 1982-09-29 | 1984-03-29 | Siemens AG, 1000 Berlin und 8000 München | IMAGE RECORDING DEVICE |
| EP0200300A1 (en) * | 1985-04-03 | 1986-11-05 | Emil Kamienicki | Nondestructive readout of a latent electrostatic image formed on an insulating material |
| EP0252820A1 (en) * | 1986-07-08 | 1988-01-13 | Thomson-Csf | Photoconductor image detector with a memory |
| US4778985A (en) * | 1987-09-14 | 1988-10-18 | Texas Medical Instruments, Inc. | Imaging plate structure |
| EP0318807A1 (en) * | 1987-12-01 | 1989-06-07 | Noranda Inc. | Systeme for measuring the charge distribution on a photoreceptor surface |
| DE3910462A1 (en) * | 1988-04-01 | 1989-10-19 | Hitachi Ltd | RADIOGRAPHIC IMAGING DEVICE |
| US5127038A (en) * | 1991-06-28 | 1992-06-30 | E. I. Du Pont De Nemours And Company | Method for capturing and displaying a latent radiographic image |
| US5166524A (en) * | 1991-06-28 | 1992-11-24 | E. I. Du Pont De Nemours & Company | Element, device and associated method for capturing a latent radiographic image |
| US5168160A (en) * | 1991-06-28 | 1992-12-01 | E. I. Du Pont De Nemours And Company | Method and apparatus for acquiring an electrical signal representing a radiographic image |
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1992
- 1992-08-14 WO PCT/US1992/006891 patent/WO1994004963A1/en not_active Ceased
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4268750A (en) * | 1979-03-22 | 1981-05-19 | The University Of Texas System | Realtime radiation exposure monitor and control apparatus |
| DE3236137A1 (en) * | 1982-09-29 | 1984-03-29 | Siemens AG, 1000 Berlin und 8000 München | IMAGE RECORDING DEVICE |
| EP0200300A1 (en) * | 1985-04-03 | 1986-11-05 | Emil Kamienicki | Nondestructive readout of a latent electrostatic image formed on an insulating material |
| EP0252820A1 (en) * | 1986-07-08 | 1988-01-13 | Thomson-Csf | Photoconductor image detector with a memory |
| US4778985A (en) * | 1987-09-14 | 1988-10-18 | Texas Medical Instruments, Inc. | Imaging plate structure |
| EP0318807A1 (en) * | 1987-12-01 | 1989-06-07 | Noranda Inc. | Systeme for measuring the charge distribution on a photoreceptor surface |
| DE3910462A1 (en) * | 1988-04-01 | 1989-10-19 | Hitachi Ltd | RADIOGRAPHIC IMAGING DEVICE |
| US5127038A (en) * | 1991-06-28 | 1992-06-30 | E. I. Du Pont De Nemours And Company | Method for capturing and displaying a latent radiographic image |
| US5166524A (en) * | 1991-06-28 | 1992-11-24 | E. I. Du Pont De Nemours & Company | Element, device and associated method for capturing a latent radiographic image |
| US5168160A (en) * | 1991-06-28 | 1992-12-01 | E. I. Du Pont De Nemours And Company | Method and apparatus for acquiring an electrical signal representing a radiographic image |
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