WO1994002376A1 - Threaded plug - Google Patents
Threaded plug Download PDFInfo
- Publication number
- WO1994002376A1 WO1994002376A1 PCT/EP1993/001679 EP9301679W WO9402376A1 WO 1994002376 A1 WO1994002376 A1 WO 1994002376A1 EP 9301679 W EP9301679 W EP 9301679W WO 9402376 A1 WO9402376 A1 WO 9402376A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- screw cap
- degassing device
- degassing
- plug
- bung
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D90/00—Component parts, details or accessories for large containers
- B65D90/22—Safety features
- B65D90/32—Arrangements for preventing, or minimising the effect of, excessive or insufficient pressure
- B65D90/34—Venting means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D39/00—Closures arranged within necks or pouring openings or in discharge apertures, e.g. stoppers
- B65D39/08—Threaded or like closure members secured by rotation; Bushes therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D43/00—Lids or covers for rigid or semi-rigid containers
- B65D43/02—Removable lids or covers
- B65D43/0202—Removable lids or covers without integral tamper element
- B65D43/0225—Removable lids or covers without integral tamper element secured by rotation
- B65D43/0231—Removable lids or covers without integral tamper element secured by rotation only on the outside, or a part turned to the outside, of the mouth of the container
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D51/00—Closures not otherwise provided for
- B65D51/16—Closures not otherwise provided for with means for venting air or gas
- B65D51/1605—Closures not otherwise provided for with means for venting air or gas whereby the interior of the container is maintained in permanent gaseous communication with the exterior
- B65D51/1616—Closures not otherwise provided for with means for venting air or gas whereby the interior of the container is maintained in permanent gaseous communication with the exterior by means of a filter
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D2251/00—Details relating to container closures
- B65D2251/02—Grip means
- B65D2251/023—Ribs or recesses
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D2543/00—Lids or covers essentially for box-like containers
- B65D2543/00009—Details of lids or covers for rigid or semi-rigid containers
- B65D2543/00018—Overall construction of the lid
- B65D2543/00064—Shape of the outer periphery
- B65D2543/00074—Shape of the outer periphery curved
- B65D2543/00092—Shape of the outer periphery curved circular
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D2543/00—Lids or covers essentially for box-like containers
- B65D2543/00009—Details of lids or covers for rigid or semi-rigid containers
- B65D2543/00018—Overall construction of the lid
- B65D2543/00259—Materials used
- B65D2543/00296—Plastic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D2543/00—Lids or covers essentially for box-like containers
- B65D2543/00009—Details of lids or covers for rigid or semi-rigid containers
- B65D2543/00342—Central part of the lid
- B65D2543/00398—Reinforcing ribs in the central part of the closure
- B65D2543/00407—Reinforcing ribs in the central part of the closure radial
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D2543/00—Lids or covers essentially for box-like containers
- B65D2543/00009—Details of lids or covers for rigid or semi-rigid containers
- B65D2543/00342—Central part of the lid
- B65D2543/00398—Reinforcing ribs in the central part of the closure
- B65D2543/00416—Reinforcing ribs in the central part of the closure circular
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D2543/00—Lids or covers essentially for box-like containers
- B65D2543/00009—Details of lids or covers for rigid or semi-rigid containers
- B65D2543/00444—Contact between the container and the lid
- B65D2543/00481—Contact between the container and the lid on the inside or the outside of the container
- B65D2543/0049—Contact between the container and the lid on the inside or the outside of the container on the inside, or a part turned to the inside of the mouth of the container
- B65D2543/00518—Skirt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D2543/00—Lids or covers essentially for box-like containers
- B65D2543/00009—Details of lids or covers for rigid or semi-rigid containers
- B65D2543/00444—Contact between the container and the lid
- B65D2543/00481—Contact between the container and the lid on the inside or the outside of the container
- B65D2543/00537—Contact between the container and the lid on the inside or the outside of the container on the outside, or a part turned to the outside of the mouth of the container
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D2543/00—Lids or covers essentially for box-like containers
- B65D2543/00009—Details of lids or covers for rigid or semi-rigid containers
- B65D2543/00444—Contact between the container and the lid
- B65D2543/00481—Contact between the container and the lid on the inside or the outside of the container
- B65D2543/00555—Contact between the container and the lid on the inside or the outside of the container on both the inside and the outside
Definitions
- the invention relates to a screw cap with a disk-shaped upper part and a flange edge which adjoins its outer circumference and extends at right angles thereto and has an internal thread as a closure cap for a large-volume container, which is intended in particular for the storage and transport of gassing or degassing filling goods.
- Such screw caps are e.g. for large-volume pallet containers with a filling volume of e.g. 600 1, 800 1, 1000 1 or more as well as for industrial screw-top L-ring drums with a filling volume of e.g. 60 1 to 220 1 used.
- the degassing device is designed such that no vapor pressure higher than 0.3 bar can build up in the gas phase or in the free space above the liquid content.
- an opening or a bung hole with thread is provided centrally in the disk-shaped upper part of the screw cap for inserting a further screw cap or bung plug with a correspondingly smaller diameter (for example 2 "), the additional bung plug having the degassing device
- Degassing device can be designed as a one-way degassing device for internal overpressure degassing from the inside out. This prevents the build-up of an internal overpressure that could lead to permanent deformation or bulging of the container.
- Such an internal overpressure degassing device can be designed, for example, in the form of a rubber mushroom nipple (venting plug made of silicone rubber) pressed into a hole in the bung plug.
- the degassing device is designed as a two-way degassing device for internal positive pressure degassing and for preventing vacuum formation within the container.
- the screw cap with two-way degassing device device is useful, for example, for containers that are filled with hot contents and in which a vacuum could form by cooling the contents without venting the container.
- an air outlet (ventilation) via the two-way degassing device in the screw cap of the filler opening ensures a uniform outlet without annoying gurgling and without creating a vacuum inside the container.
- the degassing device itself is also designed as a threaded screw plug of smaller diameter and is arranged in the center of the bung plug.
- the screw cap be designed for a bung opening of 220 mm of the large container, then the bung plug is a 2 "bung plug and the degassing device, for example a permeable degassing foil, a porous sintered metal or plastic fiber plug, is in a 3/4" thread by means of a holding cup -Screw plug attached.
- the bung plug can again have the same size or a size of 1 1/2 "and the threaded screw plug 1/2".
- Figure 1 shows a screw cap according to the invention with unscrewed bung plug in a side view with partial section
- Figure 2 is a plan view of the screw cap acc.
- FIG. 1 and 3 show an enlarged illustration of the screw cover according to FIG. 1 with the bung plug screwed out in its individual parts.
- the reference number 10 in FIG. 1 denotes a screw cap for a large container according to the invention.
- the screw cap 10 is initially characterized by its size, which is 100 mm or more, but is smaller than 400 mm. This screw cap has nothing to do with even larger known screw caps for cover drums such as mash drums, the diameter of which can still be over 400 mm.
- the screw cap 10 essentially consists of a flat, disc-shaped upper part 12 and an adjoining flange 14 with an internal thread which extends essentially at right angles thereto.
- the internal thread has at least three circumferential load-bearing threads.
- a corresponding inner flange 32 of almost the same length as the outer flange is formed on the inside parallel to the thread-carrying outer flange 14.
- a smaller screw cap according to the invention is e.g. manufactured in a size of approx. 190 mm outside diameter (for a 150 mm bung hole), another somewhat larger screw cap has an outside diameter of approx. 260 mm (for a 220 mm bung hole).
- a bung hole 16 (diameter approx. 56 mm) with a bung hole connector 18 and an internal thread formed therein is formed centrally in the disk-shaped upper part 12 of the screw cap 10.
- a bung plug 20 is inserted in the bung hole 16 or in the internal thread of the bung hole connector 18, with the appropriate diameter and sealed gas and liquid-tight by means of a seal.
- the bung 18 is preferably countersunk in a bung housing 22 such that the one used
- the plug 20 is essentially flush with the disc-shaped upper part 12 of the screw cap 10.
- the plug 20 has a degassing device 24 in the center.
- the degassing device 24 can either be designed as a one-way degassing device for internal positive pressure degassing from the inside out or as a two-way degassing device.
- the two-way degassing device also prevents possible vacuum formation within the container.
- a sealing cap 26 is also pressed onto the bung 20 or the bung 18, which can only be removed from the bung by destruction or tearing.
- the degassing device is shown in its screwed apart form (exploded view) with its individual parts.
- the bung plug 20 is provided with a sealing ring 34 and screwed into the bung hole 18.
- a bore 36 with an internal thread is made centrally in the bung plug 20, into which the actual degassing plug 40 (small threaded screw plug) provided with a sealing ring 38 is screwed.
- the degassing plug 40 in turn has a bore 42 into which a pereable degassing film 44 is inserted and fixed by means of a pressed-in holding body 46 or holding ring.
- a pereable degassing film 44 is inserted and fixed by means of a pressed-in holding body 46 or holding ring.
- a correspondingly gas-permeable but liquid-retaining porous body for example made of sintered metal, sintered ceramic, fabric structure, parallel plastic Fibers or the like are used. If necessary, only the small degassing plug 40 needs to be replaced; it could also be replaced by a corresponding gastight blind plug.
- this embodiment of the screw cap according to the invention offers great variation possibilities.
- pallet containers or large-volume barrels for liquid fillers must be able to release a sufficient amount of steam to prevent the packaging container from bursting under the influence of fire.
- the bung plug 20 has a small central bore (without thread) of approximately 6.5 mm in diameter with an inwardly projecting latching lug.
- a stiff mushroom-like insert made of plastic e.g. polyethylene or polypropylene
- O-ring made of rubber on the underside of the mushroom head and seals against the surface of the plug.
- the mushroom-like insert engages behind the locking lug in the bore and seals the bore against an internal overpressure (only one-way degassing from the inside to the outside).
- the mushroom-like use as a pressure relief device is designed so that it only or at the earliest at an internal pressure of 0.25 kPA (0.25 bar), but at the latest at an pressure of 0.65 kPa ( 0.65 bar) opens and the steam pressure is released.
- the preferred opening range is between 0.35 to 0.5 kPa.
- the degassing device should, for certain reasons, only be designed as a one-way degassing device. e.g. after a possible vacuum in the container - is expediently made at least a small bore 30 of approximately 2 to 5 mm on the outer edge of the screw cap 10 approximately in the transition region from the outer flange edge 14 to the disk-shaped upper part 12 but below the screw cap seal 28, through which If necessary, air can be sucked in instead of rainwater.
- the bore 30 could of course also be designed as a slot in the flange edge 14.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Closures For Containers (AREA)
- Pallets (AREA)
- Dowels (AREA)
- Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Pressure Vessels And Lids Thereof (AREA)
Abstract
Description
SCHRAUBDECKEL SCREW CAP
Die Erfindung bezieht sich auf einen Schraubdeckel mit einem scheibenförmigen Oberteil und einem an dessen Außenumfang sich anschließenden rechtwinklig dazu erstreckenden Flanschrand mit Innengewinde als Verschlußkappe für einen großvolumigen Behälter, der ins¬ besondere zur Lagerung und zum Transport von gasenden bzw. entgasenden Füllgütern vorgesehen ist.The invention relates to a screw cap with a disk-shaped upper part and a flange edge which adjoins its outer circumference and extends at right angles thereto and has an internal thread as a closure cap for a large-volume container, which is intended in particular for the storage and transport of gassing or degassing filling goods.
Derartige Schraubdeckel werden z.B. für großvolumige Palettencontainer mit einem Füllvolumen von z.B. 600 1, 800 1, 1000 1 oder mehr sowie auch für industrielle Schraubdeckel-L-Ring-Fässer mit einem Füllvolumen von z.B. 60 1 bis 220 1 verwendet.Such screw caps are e.g. for large-volume pallet containers with a filling volume of e.g. 600 1, 800 1, 1000 1 or more as well as for industrial screw-top L-ring drums with a filling volume of e.g. 60 1 to 220 1 used.
Bei einem Einsatz von bestimmten Füllgütern, die beim Transport durch Rüttelbewegungen oder bei einer Lagerung im Freien (z.B. Sonneneinstrahlung und Temperaturschwan¬ kungen) besonderen Belastungen ausgesetzt sind oder/und grundsätzlich zur Entgasung neigen, kann sich ein nachteiliger Innendruck (Überdruck oder Unterdr ck) im Behälter aufbauen. Daher ist es wünschenswert, einen derartigen Innendruckaufbau zu vermeiden.When using certain filling materials which are exposed to special loads during transport due to vibrating movements or when stored outdoors (e.g. sunshine and temperature fluctuations) and / or generally tend to degassing, a disadvantageous internal pressure (overpressure or underpressure) can occur Build up the container. It is therefore desirable to avoid such an internal pressure build-up.
Es ist Aufgabe der vorliegenden Erfindung, einen Schraub¬ deckel - insbesondere für Großbehälter - mit geeigneten Mitteln anzugeben, der einen solchen Druckaufbau verhindert.It is an object of the present invention to provide a screw cap - in particular for large containers - with suitable means which prevents such pressure build-up.
Diese Aufgabe wird dadurch gelöst, daß bei einem Schraubdeckel mit einem Außendurchmesser von 100 mm oder mehr zentralmittig in dem scheibenförmigen Oberteil des Schraubdeckels eine Öffnung vorgesehen ist, in welche eine Entgasungseinrichtung eingesetzt ist. Mittels der in den Schraubdeckel eingesetzten Entgasungseinrichtung wird ein Druckaufbau oder eine Vakuumbildung im Inneren des Behälters mit Sicherheit vermieden. Die Entgasungsein¬ richtung ist erfindungsgemäß so ausgelegt, daß sich kein höherer Dampfdruck als 0,3 bar in der Gasphase bzw. in dem Freiraum über dem Flüssigkeitsinhalt aufbauen kann.This object is achieved in that, in the case of a screw cap with an outer diameter of 100 mm or more, an opening is provided centrally in the disk-shaped upper part of the screw cap, into which an degassing device is inserted. By means of the a pressure build-up or a vacuum formation inside the container is definitely avoided. According to the invention, the degassing device is designed such that no vapor pressure higher than 0.3 bar can build up in the gas phase or in the free space above the liquid content.
In bevorzugter Ausführungsform ist zentralmittig in dem scheibenförmigen Oberteil des Schraubdeckels eine Öffnung bzw. ein Spundloch mit Gewinde zum Einsetzen eines weiteren Schraubdeckels bzw. Spundstopfens mit entsprechend kleinerem Durchmesser (z.B. 2") vorgesehen ist, wobei der zusätzliche Spundstopfen die Entgasungseinrichtung aufweist. Dabei kann die Entgasungseinrichtung als Ein-Wege-Entgasungseinrichtung zur Innenüberdruck-Entgasung von innen nach außen ausgebildet sein. Hierdurch wird der Aufbau eines inneren Überdruckes verhindert, der zu einer bleibenden Deformation bzw. Ausbauchung des Behälters führen könnte. Andererseits kann aber auch kein möglicherweise im Spundgehäuse angesammeltes Regenwasser nach innen in den Behälter gelangen. Eine derartige Innenüberdruck- Entgasungseinrichtung kann z.B. in Form eines in eine Bohrung im Spundstopfen eingedrückten Gummi-Pilznippels (Entlüftungsstopfen aus Silikon-Kautschuk) ausgeführt sein.In a preferred embodiment, an opening or a bung hole with thread is provided centrally in the disk-shaped upper part of the screw cap for inserting a further screw cap or bung plug with a correspondingly smaller diameter (for example 2 "), the additional bung plug having the degassing device Degassing device can be designed as a one-way degassing device for internal overpressure degassing from the inside out. This prevents the build-up of an internal overpressure that could lead to permanent deformation or bulging of the container. On the other hand, rainwater that may have accumulated in the bung housing cannot Such an internal overpressure degassing device can be designed, for example, in the form of a rubber mushroom nipple (venting plug made of silicone rubber) pressed into a hole in the bung plug.
In anderer Ausgestaltung der Erfindung ist vorgesehen, daß die Entgasungseinrichtung als Zwei-Wege-Entgasungs¬ einrichtung zur Innenüberdruck-Entgasung und zur Verhin¬ derung von Vakuumbildung innerhalb des Behälters ausge¬ bildet ist. Bei dieser Ausbildung der Entgasungseinrich¬ tung wird zusätzlich vermieden, daß ein eventueller Un¬ terdruck im Behälter zu nachteiligen Einbuchtungen der Behälterwandung bzw. Einsenkungen des Oberbodens führen kann. Der Schraubdeckel mit Zwei-Wege-Entgasungseinrich- tung ist z.B. für Behälter zweckmäßig, die mit heißem Füllgut befüllt werden und bei denen sich ohne Belüftung des Behälters durch Abkühlung des Füllgutes ein Vakuum bilden könnte. Auch bei einer Füllgutentnähme aus dem Bodenventil wird durch einen Luftzutritt (Belüftung) über die Zwei-Wege-Entgasungseinrichtung im Schraubdeckel der Einfüllöffnung ein gleichmäßiger Auslauf ohne störendes Gluckern und ohne Vakuumbildung im Behälterinneren bewirkt.In another embodiment of the invention it is provided that the degassing device is designed as a two-way degassing device for internal positive pressure degassing and for preventing vacuum formation within the container. With this design of the degassing device, it is additionally avoided that a possible negative pressure in the container can lead to disadvantageous indentations of the container wall or depressions of the upper floor. The screw cap with two-way degassing device device is useful, for example, for containers that are filled with hot contents and in which a vacuum could form by cooling the contents without venting the container. Even when the product is removed from the bottom valve, an air outlet (ventilation) via the two-way degassing device in the screw cap of the filler opening ensures a uniform outlet without annoying gurgling and without creating a vacuum inside the container.
In weiterer Ausgestaltung der Erfindung ist vorgesehen, daß die Entgasungseinrichtung selbst ebenfalls als Gewinde-Schraubstopfen kleineren Durchmessers ausgebildet und zentralmittig in dem Spundstopfen angeordnet ist. So kann der Schraubdeckel z.B. für eine Spundstutzenöffnung von 220 mm des Großbehälters ausgelegt sein, dann ist der Spundstopfen ein 2"-Spundstopfen und die Entgasungsein¬ richtung z.B. eine permeable Entgasungsfolie, ein poröses Sintermetall oder Kunststoff-Faserstopfen, ist mittels eines Haltenapfes in einem 3/4"-Gewinde-Schraubstopfen befestigt. Bei einem Schraubdeckel für eine 150 mm- Spundstutzenöffnung kann der Spundstopfen wiederum die gleiche Größe oder eine Größe von 1 1/2" und der Gewinde- Schraubstopfen 1/2" aufweisen.In a further embodiment of the invention it is provided that the degassing device itself is also designed as a threaded screw plug of smaller diameter and is arranged in the center of the bung plug. For example, the screw cap be designed for a bung opening of 220 mm of the large container, then the bung plug is a 2 "bung plug and the degassing device, for example a permeable degassing foil, a porous sintered metal or plastic fiber plug, is in a 3/4" thread by means of a holding cup -Screw plug attached. In the case of a screw cap for a 150 mm bung opening, the bung plug can again have the same size or a size of 1 1/2 "and the threaded screw plug 1/2".
Bei Bedarf ist es so möglich, lediglich den kleinen Gewinde-Schraubstopfen mit der Entgasungseinrichtung auszutauschen. Bei Verwendung des Schraubdeckels für nicht gasende Füllstoffe bzw. wenn ein gasdichter Verschluß gewünscht ist, braucht lediglich der kleine Gewinde-Schraubstopfen herausgedreht und durch einen Blindstopfen ersetzt zu werden.If necessary, it is possible to replace only the small threaded screw plug with the degassing device. If the screw cap is used for non-gassing fillers or if a gas-tight seal is required, all that is required is to unscrew the small threaded screw plug and replace it with a blind plug.
Damit die Entgasungseinrichtung in dem inneren Spund- stopfen selbst einerseits gegen Regenwasser geschützt ist und andererseits gegen eine unberechtigte Manipulation oder Verschmutzung gesichert ist, ist weiterhin vorgesehen, daß der zusätzliche Spundstopfen vollständig mit einer Siegelkappe abgedeckt ist.So that the degassing device in the inner bung plug itself is protected against rainwater on the one hand and is secured against unauthorized manipulation or contamination on the other hand provided that the additional bung plug is completely covered with a sealing cap.
Da der große Schraubdeckel selbst auf einen in ein Spund¬ gehäuse eingesenkten Spundstutzen des Großbehälters (z.B. bei einem Spundfaß) aufgeschraubt ist, besteht hier gegebenenfalls die Gefahr, daß sich Regenwasser im Spundgehäuse ansammelt und dieses z.B. bei Unterdruck im Behälter nach innen in den Behälter eingezogen wird. Dieser nachteilige Effekt wird auf einfache und vorteilhafte Weise dadurch beseitigt, daß an dem Außenrand des Schraubdeckels etwa im Übergangsbereich vom Flanschrand zum scheibenförmigen Oberteil, aber unterhalb der Schraubdeckeldichtung und im wesentlichen oberhalb des Gewindes eine oder mehrere kleine Bohrungen bzw. Durchbrechungen in den Flanschrand eingebracht sind. Hierdurch kann dann ggf. Luft, aber kein Regenwasser in den Behälter eingezogen werden. Diese Maßnahme gewinnt insbesondere dann an Bedeutung, wenn die Entgasungseinrichtung für eine Ein-Wege-Entgasung (Innenüberdruck) ausgelegt ist oder vollständig herausgeschraubt und z.B. durch einen Blindstopfen ersetzt ist.Since the large screw cap itself is screwed onto a bung neck of the large container (e.g. in a bung), there is a risk of rainwater collecting in the bung housing and this e.g. if there is negative pressure in the container, it is drawn into the container. This disadvantageous effect is eliminated in a simple and advantageous manner in that one or more small bores or openings are made in the flange edge on the outer edge of the screw cover, for example in the transition region from the flange edge to the disk-shaped upper part, but below the screw cover seal and essentially above the thread . As a result, air, but no rainwater, may then be drawn into the container. This measure becomes particularly important if the degassing device is designed for one-way degassing (internal pressure) or is completely unscrewed and e.g. is replaced by a blind plug.
Die Erfindung wird nachfolgend anhand eines in den Zeich¬ nungen dargestellten Ausführungsbeispieles näher erläu¬ tert und beschrieben. Es zeigen:The invention is explained and described in more detail below with reference to an embodiment shown in the drawings. Show it:
Figur 1 einen erfindungsgemäßen Schraubdeckel mit herausgeschraubtem Spundstopfen in Seitenansicht mit Teilschnitt, Figur 2 eine Draufsicht auf den Schraubdeckel gem.Figure 1 shows a screw cap according to the invention with unscrewed bung plug in a side view with partial section, Figure 2 is a plan view of the screw cap acc.
Fig. 1 und Figur 3 eine vergrößerte Darstellung des Schraub¬ deckels gemäß Fig. 1 mit herausge¬ schraubtem Spundstopfen in dessen Einzel¬ teilen. Mit der Bezugsziffer 10 ist in Figur 1 ein erfindungsge¬ mäßer Schraubdeckel für einen Großbehälter bezeichnet. Der Schraubdeckel 10 zeichnet sich zunächst einmal durch seine Größe aus, die 100 mm oder mehr beträgt, aber klei¬ ner als 400 mm ist. Dieser Schraubdeckel hat also nichts mit noch größeren bekannten Schraubdeckeln für Deckel¬ fässer wie z.B. Maische-Fässer zu tun, deren Durchmesser noch über 400 mm liegen kann.1 and 3 show an enlarged illustration of the screw cover according to FIG. 1 with the bung plug screwed out in its individual parts. The reference number 10 in FIG. 1 denotes a screw cap for a large container according to the invention. The screw cap 10 is initially characterized by its size, which is 100 mm or more, but is smaller than 400 mm. This screw cap has nothing to do with even larger known screw caps for cover drums such as mash drums, the diameter of which can still be over 400 mm.
Wie auch Figur 2 zeigt, besteht der Schraubdeckel 10 im wesentlichen aus einem flachen, scheibenförmigen Oberteil 12 und einem sich daran anschließenden, im wesentlichen rechtwinkelig dazu erstreckenden Flanschrand 14 mit Innengewinde. Das Innengewinde hat mindestens drei umlaufende tragende Gewindegänge. Zur Versteifung und zum besseren Sitz des Schraubdeckels ist innen parallel zu dem gewindetragenden Außenflansch 14 ein entsprechender Innenflansch 32 von nahezu gleicher Länge wie der Außenflansch ausgebildet.As also shown in FIG. 2, the screw cap 10 essentially consists of a flat, disc-shaped upper part 12 and an adjoining flange 14 with an internal thread which extends essentially at right angles thereto. The internal thread has at least three circumferential load-bearing threads. For stiffening and for a better fit of the screw cap, a corresponding inner flange 32 of almost the same length as the outer flange is formed on the inside parallel to the thread-carrying outer flange 14.
Ein kleinerer erfindungsgemäßer Schraubdeckel wird z.B. in einer Größe von ca. 190 mm Außendurchmesser (für ein 150 mm Spundloch) gefertigt, ein anderer etwas größerer Schraubdeckel hat einen Außendurchmesser von ca. 260 mm (für ein 220 mm Spundloch).A smaller screw cap according to the invention is e.g. manufactured in a size of approx. 190 mm outside diameter (for a 150 mm bung hole), another somewhat larger screw cap has an outside diameter of approx. 260 mm (for a 220 mm bung hole).
Wie in Figur 3 deutlicher erkennbar ist, ist zentral- mittig in dem scheibenförmigen Oberteil 12 des Schraubdeckels 10 ein Spundloch 16 (Durchmesser ca. 56 mm) mit Spundlochstutzen 18 und darin eingeformtem Innengewinde ausgebildet. In das Spundloch 16 bzw. in das Innengewinde des Spundlochstutzens 18 ist ein Spundstopfen 20 mit entsprechendem Durchmesser eingesetzt und mittels einer Dichtung gas- und flüssigkeitsdicht abgedichtet.As can be seen more clearly in FIG. 3, a bung hole 16 (diameter approx. 56 mm) with a bung hole connector 18 and an internal thread formed therein is formed centrally in the disk-shaped upper part 12 of the screw cap 10. In the bung hole 16 or in the internal thread of the bung hole connector 18, a bung plug 20 is inserted with the appropriate diameter and sealed gas and liquid-tight by means of a seal.
Vorzugsweise ist der Spundstutzen 18 in einem Spundgehäuse 22 derart versenkt, daß der eingesetzte Spundstopfen 20 im wesentlichen oben bündig mit dem scheibenförmigen Oberteil 12 des Schraubdeckels 10 abschließt.The bung 18 is preferably countersunk in a bung housing 22 such that the one used The plug 20 is essentially flush with the disc-shaped upper part 12 of the screw cap 10.
Der Spundstopfen 20 weist zentralmittig eine Entgasungs¬ einrichtung 24 auf. Die Entgasungseinrichtung 24 kann entweder als Ein-Wege-Entgasungseinrichtung zur Innenüberdruck-Entgasung von innen nach außen oder als Zwei-Wege-Entgasungseinrichtung ausgebildet sein. Die Zwei-Wege-Entgasungseinrichtung verhindert zusätzlich eine mögliche Vakuumbildung innerhalb des Behälters. Um den Spundstopfen 20 gegen unberechtigtes Öffnen oder das Eindringen von z.B. Regenwasser in die Entgasungs¬ einrichtung zu schützen, ist weiterhin eine Siegelkappe 26 auf den Spundstopfen 20 bzw. auf den Spundlochstutzen 18 aufgedrückt, die nur durch Zerstörung bzw. Aufreißen von dem Spundstopfen entfernt werden kann.The plug 20 has a degassing device 24 in the center. The degassing device 24 can either be designed as a one-way degassing device for internal positive pressure degassing from the inside out or as a two-way degassing device. The two-way degassing device also prevents possible vacuum formation within the container. Around the plug 20 against unauthorized opening or the penetration of e.g. To protect rainwater in the degassing device, a sealing cap 26 is also pressed onto the bung 20 or the bung 18, which can only be removed from the bung by destruction or tearing.
In Fig. 3 ist die Entgasungseinrichtung in auseinander¬ geschraubter Form (Explosionsdarstellung) mit ihren Einzelteilen dargestellt. Der Spundstopfen 20 wird mit einem Dichtungsring 34 versehen in den Spundlochstutzen 18 eingeschraubt. Zentralmittig in dem Spundstopfen 20 ist eine Bohrung 36 mit Innengewinde eingebracht, in welche der eigentliche mit einem Dichtungsring 38 versehene Entgasungs-Stopfen 40 (kleiner Gewinde- Schraubstopfen) eingeschraubt wird.In Fig. 3, the degassing device is shown in its screwed apart form (exploded view) with its individual parts. The bung plug 20 is provided with a sealing ring 34 and screwed into the bung hole 18. A bore 36 with an internal thread is made centrally in the bung plug 20, into which the actual degassing plug 40 (small threaded screw plug) provided with a sealing ring 38 is screwed.
Der Entgasungs-Stopfen 40 hat wiederum eine Bohrung 42, in welche eine per eable Entgasungsfolie 44 eingesetzt und mittels eines eingepreßten Haltekörpers 46 bzw. Halteringes fixiert wird. Anstelle der Entgasungsfolie kann - wie gesagt - in Abhängigkeit von dem Entgasungs- verhalten der jeweils eingefüllten Flüssigkeit ein entsprechend gasdurchlässiger aber flüssigkeitszurück¬ haltender poröser Körper z.B. aus Sintermetall, Sinterkeramik, Gewebestruktur, parallelen Kunststoff- Fasern o.a. eingesetzt werden. Im Bedarfsfalle braucht also nur der kleine Entgasungs-Stopfen 40 ausgetauscht zu werden; er könnte auch durch einen entsprechenden gas¬ dichten Blindstopfen ersetzt werden. Für den Anwender bietet diese Ausführung der erfindungsgemäßen Schraub¬ kappe große Variationsmöglichkeiten.The degassing plug 40 in turn has a bore 42 into which a pereable degassing film 44 is inserted and fixed by means of a pressed-in holding body 46 or holding ring. Instead of the degassing film, as mentioned, depending on the degassing behavior of the liquid filled in, a correspondingly gas-permeable but liquid-retaining porous body, for example made of sintered metal, sintered ceramic, fabric structure, parallel plastic Fibers or the like are used. If necessary, only the small degassing plug 40 needs to be replaced; it could also be replaced by a corresponding gastight blind plug. For the user, this embodiment of the screw cap according to the invention offers great variation possibilities.
Für einen besonderen Fall, z.B. bei Überhitzung müssen Palettencontainer oder großvolumige Fässer für flüssige Füllstoffe eine ausreichende Menge Dampf abgeben können, um zu vermeiden, daß es unter Feuereinwirkung zum Bersten des Verpackungsbehälters kommt.For a special case, e.g. in the event of overheating, pallet containers or large-volume barrels for liquid fillers must be able to release a sufficient amount of steam to prevent the packaging container from bursting under the influence of fire.
Dazu ist vorgesehen, daß der Spundstopfen 20 zentral¬ mittig eine kleine Bohrung (ohne Gewinde) von ca. 6,5 mm Durchmesser mit einer nach innen vorstehenden Rastnase aufweist. In die Bohrung ist von oben (von außen) ein steifer pilzartiger Einsatz aus Kunststoff (z.B. Polyethylen oder Polypropylen) eingesetzt, der auf der Unterseite des Pilzkopfes mit einem O-Ring aus Gummi versehen ist und gegen die Oberfläche des Spundstopfens abdichtet.For this purpose, it is provided that the bung plug 20 has a small central bore (without thread) of approximately 6.5 mm in diameter with an inwardly projecting latching lug. A stiff mushroom-like insert made of plastic (e.g. polyethylene or polypropylene) is inserted into the hole from above (from the outside), which is provided with an O-ring made of rubber on the underside of the mushroom head and seals against the surface of the plug.
Der pilzartige Einsatz rastet hinter der Rastnase in der Bohrung ein und dichtet die Bohrung über den O-Ring gegen einen inneren Überdruck ab (nur Einwege-Entgasung von innen nach außen) . Nach einem besonderen Merkmal der Erfindung ist der pilzartige Einsatz als Überdruck¬ sicherung so ausgelegt, daß er erst bzw. frühestens bei einem inneren Überdruck von 0,25 kPA (0,25 bar), spätestens aber bei einem Überdruck von 0,65 kPa (0,65 bar) öffnet und Dampfdruck abläßt. Der bevorzugte Öffnungsbereich liegt zwischen 0,35 bis 0,5 kPa.The mushroom-like insert engages behind the locking lug in the bore and seals the bore against an internal overpressure (only one-way degassing from the inside to the outside). According to a special feature of the invention, the mushroom-like use as a pressure relief device is designed so that it only or at the earliest at an internal pressure of 0.25 kPA (0.25 bar), but at the latest at an pressure of 0.65 kPa ( 0.65 bar) opens and the steam pressure is released. The preferred opening range is between 0.35 to 0.5 kPa.
Zur Verhinderung eines Ansaugens von Regenwasser aus der Spundgehäusemulde des Großbehälters - für den Fall, daß die Entgasungseinrichtung aus bestimmten Gründen nur als Ein-Wege-Entgasungseinrichtung ausgebildet sein soll. z.B. nach einer eventuellen Unterdruckbildung im Behälter - ist zweckmäßigerweise am Außenrand des Schraubdeckels 10 etwa im Übergangsbereich von äußerem Flanschrand 14 zum scheibenförmigen Oberteil 12 aber unterhalb der Schraubdeckel-Dichtung 28 wenigstens eine kleine Bohrung 30 von ca. 2 bis 5 mm eingebracht, durch welche im Bedarfsfall Luft anstatt Regenwasser angesaugt werden kann. Die Bohrung 30 könnte prinzipiell natürlich auch als Schlitz im Flanschrand 14 ausgebildet sein. To prevent rainwater from being sucked in from the bunghole recess of the large container - in the event that the degassing device should, for certain reasons, only be designed as a one-way degassing device. e.g. after a possible vacuum in the container - is expediently made at least a small bore 30 of approximately 2 to 5 mm on the outer edge of the screw cap 10 approximately in the transition region from the outer flange edge 14 to the disk-shaped upper part 12 but below the screw cap seal 28, through which If necessary, air can be sucked in instead of rainwater. In principle, the bore 30 could of course also be designed as a slot in the flange edge 14.
Claims
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP93915746A EP0650446B1 (en) | 1992-07-20 | 1993-06-30 | Threaded plug |
| DE59304140T DE59304140D1 (en) | 1992-07-20 | 1993-06-30 | SCREW CAP |
| AU45618/93A AU4561893A (en) | 1992-07-20 | 1993-06-30 | Threaded plug |
| JP6504103A JPH07508957A (en) | 1992-07-20 | 1993-06-30 | screw-on lid |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE9209650 | 1992-07-20 | ||
| DEG9209650.6U | 1992-07-20 | ||
| DEG9217291.1U | 1992-12-17 | ||
| DE9217291U DE9217291U1 (en) | 1992-07-20 | 1992-12-17 | Screw cap |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1994002376A1 true WO1994002376A1 (en) | 1994-02-03 |
Family
ID=25959718
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP1993/001679 Ceased WO1994002376A1 (en) | 1992-07-20 | 1993-06-30 | Threaded plug |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0650446B1 (en) |
| JP (1) | JPH07508957A (en) |
| AT (1) | ATE143891T1 (en) |
| AU (1) | AU4561893A (en) |
| DE (2) | DE9217291U1 (en) |
| DK (1) | DK0650446T3 (en) |
| ES (1) | ES2093973T3 (en) |
| WO (1) | WO1994002376A1 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004050679A1 (en) * | 2004-10-13 | 2006-04-20 | Ing. Erich Pfeiffer Gmbh | metering |
| FR2880004A1 (en) * | 2004-12-23 | 2006-06-30 | Polyvalents Chateauneuf Sa Ate | Container for e.g. transport container in e.g. building, has tapping and threading with respective helicoidal screw gears whose sections have edges inclined inwards of tank, when cover is screwed on tank |
| EP1911685A1 (en) * | 2006-10-14 | 2008-04-16 | Schütz GmbH & Co. KGaA | Threaded cover |
| CN101323383B (en) * | 2007-06-15 | 2011-06-01 | 毕舒 | Container for packing dry powder mortar |
| US12202647B2 (en) * | 2020-11-30 | 2025-01-21 | Protechna S.A. | Bung plug seal |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE9403990U1 (en) * | 1994-03-10 | 1994-06-09 | Mauser-Werke GmbH, 50321 Brühl | Overpressure protection |
| GB9514870D0 (en) * | 1995-07-20 | 1995-09-20 | Wtb Company The Ltd | Wide-mouthed pressurisable beverage container |
| JP4530692B2 (en) * | 2004-03-18 | 2010-08-25 | 花王株式会社 | Container with cap |
| DE102008031736B3 (en) | 2008-07-04 | 2009-07-23 | Protechna S.A. | screw |
| DE102018103137B3 (en) * | 2018-02-13 | 2018-11-08 | Schütz GmbH & Co. KGaA | Bung plug closure for bung container |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT90120B (en) * | 1919-03-31 | 1922-11-25 | Heinrich Geering | Closure for canning jars. |
| DE1142785B (en) * | 1958-03-05 | 1963-01-24 | Jerome S Heisler | Container lock |
| EP0079025A1 (en) * | 1981-11-10 | 1983-05-18 | Henkel Kommanditgesellschaft auf Aktien | Venting device |
| EP0111119A1 (en) * | 1982-12-06 | 1984-06-20 | Allied Corporation | Bulk container closure and system for high purity liquids |
| DE3905017A1 (en) * | 1989-02-18 | 1990-08-23 | Wilhelm Goetz | Closure for bottles and similar containers |
| EP0490129A1 (en) * | 1990-12-14 | 1992-06-17 | B L A U GmbH | Closure cap for the opening in a container, in particular a car radiator |
-
1992
- 1992-12-17 DE DE9217291U patent/DE9217291U1/en not_active Expired - Lifetime
-
1993
- 1993-06-30 EP EP93915746A patent/EP0650446B1/en not_active Revoked
- 1993-06-30 DE DE59304140T patent/DE59304140D1/en not_active Revoked
- 1993-06-30 AT AT93915746T patent/ATE143891T1/en active
- 1993-06-30 JP JP6504103A patent/JPH07508957A/en active Pending
- 1993-06-30 AU AU45618/93A patent/AU4561893A/en not_active Abandoned
- 1993-06-30 ES ES93915746T patent/ES2093973T3/en not_active Expired - Lifetime
- 1993-06-30 WO PCT/EP1993/001679 patent/WO1994002376A1/en not_active Ceased
- 1993-06-30 DK DK93915746.7T patent/DK0650446T3/da active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT90120B (en) * | 1919-03-31 | 1922-11-25 | Heinrich Geering | Closure for canning jars. |
| DE1142785B (en) * | 1958-03-05 | 1963-01-24 | Jerome S Heisler | Container lock |
| EP0079025A1 (en) * | 1981-11-10 | 1983-05-18 | Henkel Kommanditgesellschaft auf Aktien | Venting device |
| EP0111119A1 (en) * | 1982-12-06 | 1984-06-20 | Allied Corporation | Bulk container closure and system for high purity liquids |
| DE3905017A1 (en) * | 1989-02-18 | 1990-08-23 | Wilhelm Goetz | Closure for bottles and similar containers |
| EP0490129A1 (en) * | 1990-12-14 | 1992-06-17 | B L A U GmbH | Closure cap for the opening in a container, in particular a car radiator |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004050679A1 (en) * | 2004-10-13 | 2006-04-20 | Ing. Erich Pfeiffer Gmbh | metering |
| FR2880004A1 (en) * | 2004-12-23 | 2006-06-30 | Polyvalents Chateauneuf Sa Ate | Container for e.g. transport container in e.g. building, has tapping and threading with respective helicoidal screw gears whose sections have edges inclined inwards of tank, when cover is screwed on tank |
| EP1911685A1 (en) * | 2006-10-14 | 2008-04-16 | Schütz GmbH & Co. KGaA | Threaded cover |
| AU2007200193B2 (en) * | 2006-10-14 | 2010-01-28 | Schutz Gmbh & Co. Kgaa | Screw cap |
| AU2007200193B9 (en) * | 2006-10-14 | 2010-03-04 | Schutz Gmbh & Co. Kgaa | Screw cap |
| CN101323383B (en) * | 2007-06-15 | 2011-06-01 | 毕舒 | Container for packing dry powder mortar |
| US12202647B2 (en) * | 2020-11-30 | 2025-01-21 | Protechna S.A. | Bung plug seal |
Also Published As
| Publication number | Publication date |
|---|---|
| DE59304140D1 (en) | 1996-11-14 |
| ES2093973T3 (en) | 1997-01-01 |
| ATE143891T1 (en) | 1996-10-15 |
| AU4561893A (en) | 1994-02-14 |
| JPH07508957A (en) | 1995-10-05 |
| DE9217291U1 (en) | 1993-02-18 |
| EP0650446B1 (en) | 1996-10-09 |
| DK0650446T3 (en) | 1997-03-24 |
| EP0650446A1 (en) | 1995-05-03 |
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