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WO1993015836A1 - Catalyseurs de cobalt contenant du praseodyme, destines au procede fischer-tropsch - Google Patents

Catalyseurs de cobalt contenant du praseodyme, destines au procede fischer-tropsch Download PDF

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Publication number
WO1993015836A1
WO1993015836A1 PCT/AU1993/000067 AU9300067W WO9315836A1 WO 1993015836 A1 WO1993015836 A1 WO 1993015836A1 AU 9300067 W AU9300067 W AU 9300067W WO 9315836 A1 WO9315836 A1 WO 9315836A1
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WO
WIPO (PCT)
Prior art keywords
catalyst
fischer tropsch
zsm
zeolite
cobalt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/AU1993/000067
Other languages
English (en)
Inventor
Sandra Bessell
Alan Loyd Chaffee
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Broken Hill Proprietary Company Pty Ltd
Original Assignee
Broken Hill Proprietary Company Pty Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Broken Hill Proprietary Company Pty Ltd filed Critical Broken Hill Proprietary Company Pty Ltd
Publication of WO1993015836A1 publication Critical patent/WO1993015836A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/0445—Preparation; Activation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/46—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/086—Decomposition of an organometallic compound, a metal complex or a metal salt of a carboxylic acid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/10—Magnesium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/12—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of actinides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/26—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32—Manganese, technetium or rhenium
    • C07C2523/34—Manganese
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65

Definitions

  • Fischer-Tropsch process for hydrocarbon production is ell known and described in various texts such as "The Fischer-Tropsch and Related Synthesis" by H.H. Storch, N. Golumbic and R.B. Anderson (John Wiley and Sons,
  • Nickel although one of the most active metals for carbon monoxide hydrogenation, is not preferred for hydrocarbon production because of its high methane (rather than higher hydrocarbon) selectivity.
  • Example 1 Preparation of ZSM-5 Zeolite (Code MA21) A solution of 16.74 of Ludox R HS40 (40% silica) in 6 1 of water was stirred while adding a solution of 1000 g tetrapropylammonium bromide (Fluka) in 3 1 water.
  • the ZSM-5 zeolite MA21 was impregnated with appropriate amounts of cobalt carbonyl and chromium, scandium or thorium nitrates (where appropriate) dissolved in dimethyl ether, so as to make the desired catalyst formulations.
  • An aqueous praseodymium nitrate solution (3.9% Pr) was used as the praseodymium source.
  • the solvent was evaporated from the catalyst in a rotary evaporator, and the catalyst calcined at 500°C for approximately four hours.
  • the resulting catalysts, identified by their "FT" code names and their desired compositions in parts by weight were as follows:

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

L'invention concerne un catalyseur Fischer-Tropsch, un procédé pour fabriquer un tel catalyseur et un procédé pour fabriquer des hydrocarbures liquides utilisant ce catalyseur. Ce catalyseur comprend du cobalt et du praséodyme sur un support de zéolite de la famille ZSM-5. Un procédé pour fabriquer le catalyseur consiste à imprégner la zéolite avec un sel de praséodyme et une solution de cobalt tétracarbonyle dans un solvant organique, à évaporer le solvant organique, à évaporer le solvant organique et à calciner le catalyseur. L'éther diméthylique constitue un solvant organique approprié. Le procédé pour fabriquer des hydrocarbures liquides consiste à faire passer un gaz de synthèse sur le catalyseur à une température dans la gamme allant de 200 °C à 300 °.
PCT/AU1993/000067 1992-02-18 1993-02-18 Catalyseurs de cobalt contenant du praseodyme, destines au procede fischer-tropsch Ceased WO1993015836A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
AUPL094192 1992-02-18
AUPL0941 1992-02-18

Publications (1)

Publication Number Publication Date
WO1993015836A1 true WO1993015836A1 (fr) 1993-08-19

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/AU1993/000067 Ceased WO1993015836A1 (fr) 1992-02-18 1993-02-18 Catalyseurs de cobalt contenant du praseodyme, destines au procede fischer-tropsch

Country Status (1)

Country Link
WO (1) WO1993015836A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998057743A3 (fr) * 1997-06-18 1999-05-27 Exxon Chemical Patents Inc Conversion d'un gaz de synthese en olefines de faible poids moleculaire a l'aide de tamis moleculaires modifies
EP1153660A3 (fr) * 1997-06-18 2002-01-09 ExxonMobil Chemical Patents Inc. Procédé de conversion du gaz de synthèse en oléfines légères en utilisant des tamis moléculaires modifiés
EP2990103A4 (fr) * 2013-04-25 2017-01-25 Wuhan Kaidi Engineering Technology Research Institute Co., Ltd. Catalyseur de synthèse de fischer-tropsch pour transformer du gaz de synthèse en oléfines à faible teneur en carbone, support de tamis moléculaire modifié et procédé de préparation correspondant
EP3643404A1 (fr) * 2018-10-25 2020-04-29 IFP Energies nouvelles Catalyseur de cobalt a base d'un support comprenant une phase d'oxyde mixte contenant du cobalt et/ou du nickel prepare a partir d'un compose ether et procédé de fischer-tropsch utilisant celui-ci

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU3637784A (en) * 1983-12-07 1986-06-12 Compagnie Francaise De Raffinage Catalyst of iron or cobalt with zeolite
US4605680A (en) * 1981-10-13 1986-08-12 Chevron Research Company Conversion of synthesis gas to diesel fuel and gasoline
US4842720A (en) * 1981-12-30 1989-06-27 Union Oil Company Of California Fischer-Tropsch synthesis process utilizing a catalyst containing a siliceous metal-containing crystalline composition
AU4474789A (en) * 1988-11-22 1990-05-31 Broken Hill Proprietary Company Limited, The Conversion of synthesis gas into hydrocarbons
EP0434063A1 (fr) * 1989-12-21 1991-06-26 Toyota Jidosha Kabushiki Kaisha Procédé pour purifier des gaz d'échappement contenant un excès d'oxygène
DE4219690A1 (de) * 1991-06-19 1992-12-24 Inst Francais Du Petrole Verfahren zur synthese von kohlenwasserstoffen aus synthesegas in gegenwart eines katalysators auf basis von kobalt

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4605680A (en) * 1981-10-13 1986-08-12 Chevron Research Company Conversion of synthesis gas to diesel fuel and gasoline
US4842720A (en) * 1981-12-30 1989-06-27 Union Oil Company Of California Fischer-Tropsch synthesis process utilizing a catalyst containing a siliceous metal-containing crystalline composition
AU3637784A (en) * 1983-12-07 1986-06-12 Compagnie Francaise De Raffinage Catalyst of iron or cobalt with zeolite
AU4474789A (en) * 1988-11-22 1990-05-31 Broken Hill Proprietary Company Limited, The Conversion of synthesis gas into hydrocarbons
EP0434063A1 (fr) * 1989-12-21 1991-06-26 Toyota Jidosha Kabushiki Kaisha Procédé pour purifier des gaz d'échappement contenant un excès d'oxygène
DE4219690A1 (de) * 1991-06-19 1992-12-24 Inst Francais Du Petrole Verfahren zur synthese von kohlenwasserstoffen aus synthesegas in gegenwart eines katalysators auf basis von kobalt

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998057743A3 (fr) * 1997-06-18 1999-05-27 Exxon Chemical Patents Inc Conversion d'un gaz de synthese en olefines de faible poids moleculaire a l'aide de tamis moleculaires modifies
EP1153660A3 (fr) * 1997-06-18 2002-01-09 ExxonMobil Chemical Patents Inc. Procédé de conversion du gaz de synthèse en oléfines légères en utilisant des tamis moléculaires modifiés
EP2990103A4 (fr) * 2013-04-25 2017-01-25 Wuhan Kaidi Engineering Technology Research Institute Co., Ltd. Catalyseur de synthèse de fischer-tropsch pour transformer du gaz de synthèse en oléfines à faible teneur en carbone, support de tamis moléculaire modifié et procédé de préparation correspondant
EP3643404A1 (fr) * 2018-10-25 2020-04-29 IFP Energies nouvelles Catalyseur de cobalt a base d'un support comprenant une phase d'oxyde mixte contenant du cobalt et/ou du nickel prepare a partir d'un compose ether et procédé de fischer-tropsch utilisant celui-ci
FR3087671A1 (fr) * 2018-10-25 2020-05-01 IFP Energies Nouvelles Catalyseur de cobalt a base d’un support comprenant une phase d’oxyde mixte contenant du cobalt et/ou du nickel prepare a partir d’un compose ether
US11071972B2 (en) 2018-10-25 2021-07-27 IFP Energies Nouvelles Cobalt catalyst comprising a support comprising a mixed oxide phase including cobalt and/or nickel produced from an ether compound

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