WO1993005366A2 - Mass flow meter - Google Patents
Mass flow meter Download PDFInfo
- Publication number
- WO1993005366A2 WO1993005366A2 PCT/CA1992/000364 CA9200364W WO9305366A2 WO 1993005366 A2 WO1993005366 A2 WO 1993005366A2 CA 9200364 W CA9200364 W CA 9200364W WO 9305366 A2 WO9305366 A2 WO 9305366A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- detritus
- weight
- variation
- drilling fluid
- receiving position
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01G—WEIGHING
- G01G11/00—Apparatus for weighing a continuous stream of material during flow; Conveyor belt weighers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D33/00—Filters with filtering elements which move during the filtering operation
- B01D33/01—Filters with filtering elements which move during the filtering operation with translationally moving filtering elements, e.g. pistons
- B01D33/03—Filters with filtering elements which move during the filtering operation with translationally moving filtering elements, e.g. pistons with vibrating filter elements
- B01D33/0346—Filters with filtering elements which move during the filtering operation with translationally moving filtering elements, e.g. pistons with vibrating filter elements with flat filtering elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D33/00—Filters with filtering elements which move during the filtering operation
- B01D33/80—Accessories
- B01D33/804—Accessories integrally combined with devices for controlling the filtration
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B21/00—Methods or apparatus for flushing boreholes, e.g. by use of exhaust air from motor
- E21B21/06—Arrangements for treating drilling fluids outside the borehole
- E21B21/063—Arrangements for treating drilling fluids outside the borehole by separating components
- E21B21/065—Separating solids from drilling fluids
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B49/00—Testing the nature of borehole walls; Formation testing; Methods or apparatus for obtaining samples of soil or well fluids, specially adapted to earth drilling or wells
- E21B49/005—Testing the nature of borehole walls or the formation by using drilling mud or cutting data
Definitions
- This invention relates to a method and system for continuously monitoring the variations in weight of fluent bulk material and particularly where the material is the amount of detritus, including cuttings sloughings or cavings, and other material, including contaminated drilling fluid and lost circulation material picked up by, or entrained in, a water or oil based drilling fluid being circulated in a subterranean well or excavation (Wellbore) during the drilling process into subterranean formations, circulated to the surface, and separated from the drilling fluid by a vibrating screening device ("shale shaker" is the generic term for a line of devices serving this purpose) and subsequently discharged from the fluid circulating system.
- a vibrating screening device (“shale shaker" is the generic term for a line of devices serving this purpose) and subsequently discharged from the fluid circulating system.
- drilling fluids are employed when drilling holes into subterranean formations.
- the drilling fluid usually referred to as drilling mud, consists of a mixture of fluids such as water, air hydrocarbons, vegetable oils and other organic and inorganic materials. These materials may be used individually or in admixture and optimized for special properties to better perform some or all of the following functions; though not limited to same:
- the drilling fluid is circulated into the wellbore by pumping the fluid down the hollow rods or drill pipes which are lowered into the well during the drilling process.
- the drill pipes are connected to a drilling "bit" through which the drilling fluid exits.
- the fluid subsequently returns to the surface through an annular space surrounding the drillpipes and the inner surface of the excavated wellbore (borehole wall).
- drilling circulation the drilling fluid is pumped down the annulus and returns up the drillpipes; this is known as reverse circulation.
- detritus including cuttings, sloughings or cavings and other material
- circulating contaminated drilling fluid and lost circulation material is "picked up" by the circulating fluid; either at the face of the drill bit or further up the wellbore; and returned to the surface for separation from the drilling mud and subsequent disposal.
- the effective removal of such detritus or cuttings, cavings, sloughings and millings from the drilling fluid contributes to the maintenance of the condition of the drilling fluid.
- the ability of the drilling fluid to effectively transport the detritus generated by the excavation process is fundamentally critical to the successful completion of a drilling project. Ineffective transport results in, or contributes to, drill pipes becoming stuck in the borehole, increased torque in rotary drilling operations with subsequent "twist off (breakage of a drillpipe) and damage to potential producing reservoirs. As a result an exceptional amount of time and effort has been invested in the study of "Hole Cleaning" and related topics. For instance the rheology of drilling fluids, by the energy exploration industry. This topic is especially important since the advent of the use of horizontal drilling techniques which suffer from severe problems directly associated with the difficulty in effectively removing detritus from the wellbore.
- Theological parameters, variations in circulating rate, variations in fluid density, effects of controlled or uncontrolled deviation, or as a result of sloughing or caving, will allow for real time optimization of drilling, or drilling fluid engineering.
- the ability to monitor the aforementioned variances further enhances the effort to improve the drilling art and to prevent catastrophic failure of a drilling project.
- the present invention provides a continuous, qualitative method of determining not only the hole cleaning potential of the drilling fluid, but the effectiveness or result of variations in all parameters involved in cuttings transport; ie. circulating rate or fluid velocity, fluid density, rheology, annular space, deviation, rate of deviation, etc.
- circulating rate or fluid velocity, fluid density, rheology, annular space, deviation, rate of deviation, etc By using real time monitoring of the effects of these parameters significant steps may be taken towards optimizing these parameters for both vertical and highly deviated excavations.
- Patent No. 4,413,511 of John K. Godbey which is assigned to Mobil Oil Corporation, that Patent being entitled "System for Measuring Cuttings and Mud Carryover During the Drilling of a Subterranean Well".
- Godbey discloses a method and system for continuously measuring the amount of solid cuttings picked up by a drilling mud being circulated in a well being drilled into a subterranean formation and the amount of drilling mud carried over with the cuttings when the cuttings are separated from the drilling mud by a shale shaker.
- Godbey, by his method and system as described in U.S. Patent No. 4,413,511 seeks to accurately quantify the exact amount of detritus being delivered to the surface during the drilling operation.
- the system described by Godbey is quite complex and costly to operate; and because of this, its application to drilling operations is very limited. As a result, systems for the continuous monitoring of the delivery of cuttings and other detritus to the surface during drilling operations do not appear to be currrently in use.
- the present invention in contrast to that described by Godbey, only monitors trends in delivery of detritus in drilling fluid to the surface i.e. whether the delivery is steady or whether it is increasing or decreasing.
- This invention seeks to provide a method and apparatus for continuously monitoring the volume of fluent bulk material being discharged from an industrial process and more particularly detritus being discharged from a well during an excavation or a subterranean well drilling process.
- an apparatus for continuously determining the variation in weight of fluent bulk material discharged during an industrial operation comprising: means for collecting said bulk material; measuring means operatively connected to measure the weight of bulk material collected by said means for collecting and for producing an electrical output in response to the weight measured; means for selectively discharging said material from said collecting means; and means for monitoring the variation in electrical output from said measuring means, said output being indicative of the variation of material collected.
- a further embodiment of the invention provides for a method for continuously dete ⁇ nining the variation in weight of fluent bulk material discharged during an industrial operation, the apparatus comprising:
- an apparatus for continuously determining the variation in weight of fluent bulk material discharged during an industrial operation comprising: a plurality of receptacles; means supporting the receptacles for sequential movement to and through a bulk material receiving position; measuring means operatively connected to measure the weight of bulk material collected in a selected receptacle and for producing an output in response to the weight measured; and lock means operatively associated with the supporting means for maintaining a selected receptacle in the receiving position for receipt of bulk material, the lock means being releasable when the weight in the selected receptacle reaches a predetermined weight to allow the support means to move under the weight of bulk material in the receptacle away from the receiving position while at the same time a subsequent receptacle moves into the receiving position.
- a still further embodiment of the invention provides for a method for continuously determining the variation in weight of fluent bulk material discharged during an industrial operation, the method comprising the steps of: (a) moving a support means which supports a plurality of receptacles for sequential movement of the receptacles to and through a bulk material receiving position;
- Another embodiment of the invention provides a method for continuously dete ⁇ nining the variation in detritus in a drilling fluid discharged during a well drilling operation; comprising the steps of: (a) passing the drilling fluid discharged from the borehole through a shale shaker to remove the detritus;
- a further embodiment of the invention provides for a method for continuously determining the variation in detritus in a drilling fluid discharged during the drilling operation; comprising the steps of:
- the shale shaker including a spring mounted vibrating screen, at least one load cell being located beneath, and connected to a spring or springs on which the screen is mounted whereby variations in weight of the detritus passed over the screen cause a variation in stress on the load cell(s);
- a still further embodiment of the invention provides for a method for continuously determining the variation in detritus in a drilling fluid discharged during a well drilling operation; comprising the steps of: (a) passing the drilling fluid discharged from the borehole through a shale shaker to remove the detritus; the shale shaker including a spring mounted vibrating screen beneath which are positioned a plurality of means for measuring change in rate of velocity and the means for measuring being operatively connected to the vibrating screen;
- a still further embodiment of the invention provides for a method for continuously determining the variation in detritus in a drilling fluid discharged during a well drilling operation; comprising the steps of:
- a still further embodiment of the invention provides for an apparatus for continuously determining the variation in detritus in a drilling fluid discharged during a well drilling operation where drilling fluid discharged from the borehole is passed through a shale shaker to remove the detritus, the apparatus comprising: a trough means for receiving the detritus from the shaker; a load measuring means operatively connected to the trough means for producing an output indicative of the weight of detritus collected in the trough means; and release means operatively connected to the trough for discharging the detritus from the trough upon the weight of the detritus reaching a predetermined limit.
- Figure 1 is a diagrammatic vertical cross-section of a drilling rig and excavation or borehole, showing the drilling fluid circulating paths;
- Figure 2(a) is a top view of a shale shaker;
- Figure 2(b) is a side view of the shale shaker in Figure 2(a);
- Figure 2(c) is a side view of a conveyor for use with the shale shaker of figure 2;
- Figure 3(a) is a side view of one embodiment of a drilling fluid processing unit according to the present invention.
- Figure 3(b) is a top view of the embodiment illustrated in Figure 3(a);
- Figure 3(c) is a side view of a receptacle according to the present invention;
- Figure 4(a) is a top view of a further embodiment of the invention
- Figure 4(b) is a side view of a conveyor of Figure 4(a)
- Figure 5(a) is a top view of a further embodiment of the present invention
- Figure 5(b) is a side view of the embodiment illustrated in Figure 5(a).
- the invention relates to methods for monitoring the qualitative variations in the delivery of detritus; from an excavation or wellbore produced during the drilling process, after or during its separation by a shale shaker.
- a subsequent monitoring of the factors controlling detritus delivery will be achieved, namely; the effects of; Rheology, Fluid Density, Fluid circulating rate, variations in well bore diameter, variations in both hole inclination, rate of change of hole inclination, etc.
- a vertical cross-section of a drilling rig and excavation or borehole, along with the drilling fluid circulating paths is indicated generally by numeral 1.
- a well is drilled or excavated into a subterranean formation 12.
- Drilling fluid 11 is circulated down the drill pipes or drill string 14.
- the drilling fluid 11 is then passed through openings or jets in a drill bit or hammer 15 and is returned to the surface through an annular space 16 between the well wall 10 and the drill string 14.
- the drilling fluid 11 picks up detritus produced by the drill bit 15, along with detritus, cavings, sloughings, and such like from the borehole wall and transports this detritus from the well 10 via a pipeline 18 to a shale shaker 3 shown in Figure 2(a).
- the shale shaker 3 has an adjustable deck angle and is capable of a lateral shaking motion.
- the drilling fluid 11 and detritus received from line 18 is discharged into the shaker and evenly distributed through channels 4 onto a vibrating screen 5.
- the drilling fluid 11 passes through the screens 5 immediately.
- a small amount of the fluid is however retained on the detritus.
- a significant proportion of the drilling fluid is removed from the detritus and passes through the vibrating screens 5 and into a receiving tank or pit (not shown) that may be located under the shale shaker 3.
- the drilling fluid is then subsequently processed and then recirculated down the well bore via the drillstring 14, or immediately recirculated depending on the complexity of the drill string in use.
- the detritus is discharged onto a low friction surface, sloping ramp 8 and then subsequently slides off to be collected by a suitable receptacle.
- An embodiment of the present invention is shown in figure 2(c), in which the detritus from the sloping ramp 8 slides onto a conveyor belt 9 which is rotated at a constant or variable velocity X by a belt driver 10.
- the conveyor belt 9 then transports the detritus down its length at this constant or variable speed to a point directly above an idler pulley 12 as more clearly indicated in Figure 2(c).
- This pulley is termed a weighing idler.
- the weighing idler 12 is connected to a load cell 11. Variations in the weight of the detritus as a result of variations in volume of detritus will then be monitored as a result of variations in Stress on the load cell 11 in response to the movement of the weighing idler 12.
- the variations in loading on the load cells 11 may be output directly through a conditioning amplifier to a Chart Recorder, (not shown) personal Computer, or voltmeter or any other device designed to translate the variations in electrical output ⁇ v produced by the load cell 11 to a weight reading.
- X Velocity of the conveyor belt at any time (t n ) when a ⁇ v is measured at points 11 on the conveyor 9.
- an apparatus for continuously monitoring the variation in detritus from a well drilling operation is shown generally by numeral 80.
- the sloping ramp 8 of the shale shaker is shown positioned over a receptacle or tray 82.
- a pair of spaced apart supports 84 each have a pivot point 86 for pivotally supporting a beam
- Support arms 88 are attached to the beam 96 and extend radially each at approximately 90° to each other.
- the support arms are arranged in groups of four and with each group spaced on the beam in a plane perpendicular to the length axis of the beam 96.
- the receptacle or tray 82 is mounted on one side of each of the four arms 88. It can been seen from Figure 3(a) that as the support arms 88 are rotated with respect to the supports 84, each of the trays 82 are sequentially positioned below the outlet of the sloping ramp 8.
- a control box 90 housing a latching device 92 and a load measure device is also attached between the supports 84, but on a side opposite to that of the shale shaker.
- the latching device 90 comprises a locking pin activated by a solenoid.
- the locking pin 92 in an extended position, is positioned over a support box 88.
- the receptacle or tray indicated by numeral 94 receives the detritus from the shale shaker, the weight of the detritus in the tray 94 translates to an upward force on the locking pin 92 with the pin extended and the trays 88 are prevented from rotating.
- By retracting the pin 92 the trays are allowed to rotate and thus tray 94 discharges its contents.
- These trays may be made of narrow gauge aluminum sheet or any other suitable material, such as plastics, and are concavely curved to receive the detritus.
- the brackets 88 are mounted on a rectangular cross-section beam 96.
- each of the brackets 88 are attached to the beam 96 to radiate from each of the vertices of the beam 96.
- the beam 96 is pivotally mounted on the support 94 by means of a cylindrical steel axle 98 which inserts into an axle slot 100 in the beam 96.
- the other end of the axle 98 is fitted into the pivot 86 of the support 84.
- the support arms 88 are attached to the beam 96 by an L-shaped bracket having holes drilled therethrough. Allan screws may be inserted through these holes to secure the brackets 88 to the beam 96.
- the support 84 is positioned so that a tray 82 is positioned to receive detritus from the ramp 8 of the shaker.
- a load cell in the control box 90 measures the torque produced on the beam 88 which supports the tray 94.
- This force exerted on the load cell produces a current variation at the load cell output which may be amplified by an amplifier 106 and subsequently passed to a plotter, a chart recorder, Voltmeter or computer (now shown).
- a comparator circuit 110 is connected to a seize signal from the amplifier 106. The output of the comparator 110 produces an output signal when the signal at its input reaches a preset value X.
- This output signal may be used to trigger the solenoid housed in the control box 90 and which maintains one of the trays in the selected position.
- the solenoid arm 92 as clearly indicated in Figure 3(b), may be retracted to allow the axle carrying the trays to rotate under the weight of the detritus in the tray 82 whereby the detritus in the tray is discharged as it rotates through 90°. It may be seen that in this time the solenoid is released to lock the arm as it rotates through 90° to bring the next empty tray in position to receive detritus from the shaker.
- the shale shaker 3 is indicated as in Figure 2.
- the drilling fluid and detritus received from the line 18 is discharged into the shaker and evenly distributed through channels 4 onto the vibrating screen 5. In the majority of cases virtually all the drilling fluid passes through the screens immediately with a small amount retained on the detritus.
- load cells 6 are located at the screen damper supports.
- the loading on the shaker screens may be detected with these load cells 6, a significant proportion of the drilling fluid is removed from the detritus and passes through the vibrating screens 5 and into a receiving tank or pit (not shown) that may be located under the shale shaker 3.
- the drilling fluid is subsequently processed and then recirculate down the well bore via the drills tring 14, or immediately recirculated depending on the complexity of the drilling rig in use.
- the loading on the shaker screens is detected by accelerometers 7.
- the accelerometers are located either at all spring damper locations around the shaker box that holds the shaker screens 5, or at the two locations furthest from the channel region 4 where the drilling fluid is distributed onto the shaker screens.
- the electrical output variations produced by the accelerometers 7 will be passed through a conditioning amplifier and may then be output through a chart recorder, volt meter, personal computer or other such device capable of monitoring variations in electrical output.
- a receiving trough 50 is positioned at the outlet of the vibrating screen 5.
- the trough is mounted at the end of one of the arms of a series of parallel L-shaped bars 50'.
- a box or support is shown by numeral 65 having a shaft 51 at an upper end thereof The bars 50' are pivotally mounted, at the knee of the L, on the shaft 51, allowing the trough to swing between a receiving and a discharge position.
- a load cell 53 is attached to the box 65 at a position in proximity to the free arm of the bars 50' and in a region indicated by numeral 55.
- An electromagnet 52 is rigidly attached to the load cell 53 so as to exert a magnetic force on the bar 50' at the region 55. This force holds the trough in its receiving position.
- Detritus discharged into the trough exerts a downward force and an upward force on the bar at point 55.
- the upward force at 55 initiated by detritus loading at 50 causes an excitation in the load cell 53 this excitation is related as a small current variation which is amplified by an amplifier 56 and plotted or monitored by a chart recorder, voltage meter, or computer 61.
- An enhancement of the device includes a comparator 58 circuit which eliminates the manual release of detritus from 50.
- a signal is received from the amplifier 56 and passed through a conditioning filter 57 and on to the comparator 58 which monitors the received voltage for a reference value stored/set in 59.
- the electromagnet actuator 60 disconnects current to the electromagnet 52, allowing the detritus to be discharged from 50 by permitting the downward movement of the trough 50 to a point where gravity will allow the detritus to discharge itself.
- This downward movement of the trough 50 allows the pivoting bar 51 to move its opposite end 55 up to a point in contact with an electromagnet 54 where it may be temporarily held for a preset time, to allow the cuttings to completely discharge from the trough 50.
- the data collected by these methods can be used not only to provide continuous, qualitative method of determining not only the hole cleaning potential of the drilling fluid, but the effectiveness or result of variations in all parameters involved in cuttings transport; ie. circulating rate or fluid velocity, fluid density, rheology, annular space, deviation, rate of deviation, etc.
- circulating rate or fluid velocity, fluid density, rheology, annular space, deviation, rate of deviation, etc By using real time monitoring of the effects of these parameters significant steps may be taken towards optimizing these parameters for both vertical and highly deviated excavations.
- a graph (not shown) of volume of cuttings vs depth may be plotted which may be used to identify areas of the borehole which may be "washed out" (a condition where the diameter of the actual bore hole is substantially larger than the diameter of the excavating drill bit). By identifying such locations in the well during the drilling process, remedial steps may be taken to deal with these troublesome hole sections.
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- Engineering & Computer Science (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Mining & Mineral Resources (AREA)
- Physics & Mathematics (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Fluid Mechanics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Mechanical Engineering (AREA)
- General Physics & Mathematics (AREA)
- Measuring Volume Flow (AREA)
- Earth Drilling (AREA)
Abstract
Description
Claims
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA 2050388 CA2050388A1 (en) | 1991-08-30 | 1991-08-30 | System(s) for monitoring the qualitative variation in drilled cutting delivery to the surface during the drilling of a subterranean well |
| CA2,050,388 | 1991-08-30 | ||
| CA2,052,565 | 1991-10-03 | ||
| CA 2052565 CA2052565A1 (en) | 1991-10-03 | 1991-10-03 | Mass flow meter |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| WO1993005366A2 true WO1993005366A2 (en) | 1993-03-18 |
| WO1993005366A3 WO1993005366A3 (en) | 1993-08-05 |
Family
ID=25674771
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/CA1992/000364 Ceased WO1993005366A2 (en) | 1991-08-30 | 1992-08-28 | Mass flow meter |
Country Status (2)
| Country | Link |
|---|---|
| AU (1) | AU2472992A (en) |
| WO (1) | WO1993005366A2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999057415A1 (en) * | 1998-05-07 | 1999-11-11 | Geoservices S.A. | Device and method for measuring the flow rate of drill cuttings |
| EP2959093A4 (en) * | 2013-02-22 | 2016-09-14 | Baker Hughes Inc | APPARATUS AND METHOD FOR SEPARATING AND WEIGHING DRILLING DRAWINGS RECEIVED FROM A DRILLING HOLE DURING DRILLING |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3074654A (en) * | 1958-10-10 | 1963-01-22 | Ralph B Guggemos | Control system for loading and weighing assembly |
| US2993625A (en) * | 1960-02-11 | 1961-07-25 | Sperry Rand Corp | Continuous integrator weighing apparatus |
| GB958266A (en) * | 1961-09-21 | 1964-05-21 | Polymart Ltd | Article collecting and despatch device |
-
1992
- 1992-08-28 WO PCT/CA1992/000364 patent/WO1993005366A2/en not_active Ceased
- 1992-08-28 AU AU24729/92A patent/AU2472992A/en not_active Abandoned
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999057415A1 (en) * | 1998-05-07 | 1999-11-11 | Geoservices S.A. | Device and method for measuring the flow rate of drill cuttings |
| FR2778428A1 (en) * | 1998-05-07 | 1999-11-12 | Geoservices | DEVICE AND METHOD FOR MEASURING THE FLOW OF DRILL CUTTINGS |
| GB2342673A (en) * | 1998-05-07 | 2000-04-19 | Geoservices | Device and method for measuring the flow rate of drill cuttings |
| GB2342673B (en) * | 1998-05-07 | 2002-11-20 | Geoservices | Device and method for measuring the flow rate of spoil from drilling |
| EP2959093A4 (en) * | 2013-02-22 | 2016-09-14 | Baker Hughes Inc | APPARATUS AND METHOD FOR SEPARATING AND WEIGHING DRILLING DRAWINGS RECEIVED FROM A DRILLING HOLE DURING DRILLING |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2472992A (en) | 1993-04-05 |
| WO1993005366A3 (en) | 1993-08-05 |
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