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WO1993003617A1 - Composition insecticide - Google Patents

Composition insecticide Download PDF

Info

Publication number
WO1993003617A1
WO1993003617A1 PCT/JP1992/001070 JP9201070W WO9303617A1 WO 1993003617 A1 WO1993003617 A1 WO 1993003617A1 JP 9201070 W JP9201070 W JP 9201070W WO 9303617 A1 WO9303617 A1 WO 9303617A1
Authority
WO
WIPO (PCT)
Prior art keywords
group
optionally substituted
parts
insecticidal
insecticidal composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP1992/001070
Other languages
English (en)
Japanese (ja)
Inventor
Michihiko Matsuda
Nobuo Takakusa
Jun Mitsui
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Soda Co Ltd
Original Assignee
Nippon Soda Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Soda Co Ltd filed Critical Nippon Soda Co Ltd
Publication of WO1993003617A1 publication Critical patent/WO1993003617A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring

Definitions

  • the present invention relates to a novel insecticidal composition having an excellent insecticidal effect, comprising a combination of an amide derivative of the following formula [I] and a synergist having a methylenedioxyphenyl group.
  • the present inventor studied a more effective use of the amine derivative represented by the following formula [I] and studied a combination with a synergist having a methylenedioxyphenyl group. It has been found that a powerful insecticidal effect can be obtained.
  • the present invention has the general formula (I)
  • R is an optionally substituted pyridyl group, virazyl group, or thiazolyl group, excluding an unsubstituted 2-pyridyl group
  • R 2 is a hydrogen atom
  • an optionally substituted R 3 represents a hydrogen atom, a substituted or unsubstituted alkyl group, and represents a cyano group or a nitro group.
  • a salt thereof and a synergist having a methylenedioxyphenyl group It has been found that a novel active substance combination exhibits an excellent insecticidal effect.
  • Amin derivatives alone are used to control the insects such as aphid, leafhopper, rice weevil, brown beetle, fruit tree, vegetables, etc. It is more effective than usual and shows a synergistic insecticidal effect.
  • Preferred amide derivatives of the general formula [I] used in the insecticidal composition according to the present invention are defined as follows. .
  • R is a pyridyl group, a virazinyl group or a thiazolyl group which may be substituted with a halogen atom such as a chloro atom, excluding an unsubstituted 2-pyridyl group;
  • R 2 is a hydrogen atom;
  • R 3 represents a hydrogen atom, an alkyl group, and represents a Shimano group or a nitro group.
  • Examples of the amide derivative of the general formula [I] used in the insecticidal composition according to the present invention include the compounds shown in Table 1 below. Method for producing the amine derivative or salt thereof The methods and their use as insecticides are described in WO 91/04965 in the P Table 1
  • synergists having a methylenedioxyphenyl group used in the present invention include the compounds shown in Table 2. Common name structure
  • the weight ratio of the active substance in each group in the active substance is generally the same as that of the active substance in the active substance group of the amide derivative of the general formula [I] or a salt thereof.
  • 1 to 20 parts by weight of the agent can be used.
  • the insecticidal composition according to the present invention exhibits an excellent insecticidal effect, and is applied by spraying, top dressing, underwater application, water surface application, soil surface application, soil mixing treatment, planting hole treatment, seedling immersion, seed disinfection, seedling raising box It can be used for application, smoking, fumigation, application, bait etc.
  • the insecticidal composition according to the present invention exhibits a stronger insecticidal effect than when each active compound is applied alone, so that it has no phytotoxicity to crops, has low toxicity to mixed-breed animals, and can be used safely.
  • the insecticidal composition of the present invention comprises a compound represented by the general formula [I] and methylenedioxy. It contains a synergist having a fluorine group as an active ingredient, and can be used as it is as a pure product of the active ingredient compound. Water solvent, powder, emulsion, oil, granule, flowable, fumigation, fumigant, aerosol, liniment, bait, etc. Those prepared separately may be used as a mixture. Additives and carriers include solid powders, such as soy flour and flour, vegetable powders, diatomaceous earth, apatite, gypsum, talc, bentonite, clay, and other mineral powders, sodium benzoate, urea, and the like. Organic and inorganic compounds such as sodium sulfate are used.
  • liquid dosage form uses vegetable oil, mineral oil, petroleum fractions such as kerosene, xylene and sorbent naphtha, cyclohexane, cyclohexanone, dimethylformamide, dimethylsulfoxide, trichloroethylene, methylisobutyl Use ketone and water as solvents.
  • a surfactant can be added if necessary to obtain a uniform and stable form.
  • the wettable powder, emulsion, aqueous solvent, flowable, etc. thus obtained is diluted with water to a predetermined concentration to form a suspension or emulsion, and the oils, powders, and granules are sprayed as they are. Used in.
  • Example 2 wettable powder 10 parts of the active compound of the formula (I)
  • Test Example 1 Test on housefly Absorbent cotton was placed in a small petri dish having a diameter of 3 cm, and an aqueous solution of sugar having a predetermined concentration of a wettable powder according to the example was dropped, and used as poison bait. This petri dish was placed in a high petri dish and inoculated with 10 housefly adults. They were covered with a wire mesh and placed in a thermostatic chamber at a temperature of 25 ° C and a humidity of 65%, and the insecticidal rate was examined two days later. Table 3 shows the results.
  • a cabbage leaf piece was added to an aqueous solution of a drug diluted to a predetermined concentration of a wettable powder according to Example 2. 170

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

L'invention se rapporte à une composition insecticide qui contient comme ingrédients actifs un composé représenté par la formule générale (I) ou un sel de ce composé, ainsi qu'un agent augmentant la synergie comportant un groupe méthylène-dioxyphényle. Dans la formule (I), R1 représente pyridyle éventuellement subtitué, pyrazyle ou thiazolyle, à l'exception de 2-pyridyle non substitué; R2 représente hydrogène, alkyle éventuellement substitué, cycloalkyle ou alcoxy; R3 représente hydrogène ou alkyle éventuellement substitué; et R4 représente cyano ou nitro. Cette composition a un effet insecticide plus grand que celui de l'ingrédient utilisé seul, de sorte que la synergie de la composition est excellente.
PCT/JP1992/001070 1991-08-27 1992-08-25 Composition insecticide Ceased WO1993003617A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP3/238925 1991-08-27
JP3238925A JPH0558811A (ja) 1991-08-27 1991-08-27 殺虫組成物

Publications (1)

Publication Number Publication Date
WO1993003617A1 true WO1993003617A1 (fr) 1993-03-04

Family

ID=17037319

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP1992/001070 Ceased WO1993003617A1 (fr) 1991-08-27 1992-08-25 Composition insecticide

Country Status (2)

Country Link
JP (1) JPH0558811A (fr)
WO (1) WO1993003617A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996003879A1 (fr) * 1994-07-29 1996-02-15 Bayer Aktiengesellschaft Insecticides
EP0617890B1 (fr) * 1993-03-18 1998-11-18 Nihon Bayer Agrochem K.K. Compositions insecticides synergiques

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006298767A (ja) * 2005-04-15 2006-11-02 Sumitomo Chemical Co Ltd ハエ亜目害虫防除剤
ITMI20050729A1 (it) * 2005-04-22 2006-10-23 Endura Spa Nuova formulazione biologicamente attiva

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1991004965A1 (fr) * 1989-10-06 1991-04-18 Nippon Soda Co., Ltd. Derives d'amine

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1991004965A1 (fr) * 1989-10-06 1991-04-18 Nippon Soda Co., Ltd. Derives d'amine

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0617890B1 (fr) * 1993-03-18 1998-11-18 Nihon Bayer Agrochem K.K. Compositions insecticides synergiques
WO1996003879A1 (fr) * 1994-07-29 1996-02-15 Bayer Aktiengesellschaft Insecticides

Also Published As

Publication number Publication date
JPH0558811A (ja) 1993-03-09

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