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WO1989008694A1 - Produit enzymatique detergent granulaire, son procede de production, son utilisation et detergent le contenant - Google Patents

Produit enzymatique detergent granulaire, son procede de production, son utilisation et detergent le contenant Download PDF

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Publication number
WO1989008694A1
WO1989008694A1 PCT/DK1989/000055 DK8900055W WO8908694A1 WO 1989008694 A1 WO1989008694 A1 WO 1989008694A1 DK 8900055 W DK8900055 W DK 8900055W WO 8908694 A1 WO8908694 A1 WO 8908694A1
Authority
WO
WIPO (PCT)
Prior art keywords
detergent
coating
product according
enzyme
product
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/DK1989/000055
Other languages
English (en)
Inventor
Erik Kjaer Markussen
Per Falholt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novo Nordisk AS
Original Assignee
Novo Nordisk AS
Novo Industri AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DK137788A external-priority patent/DK137788D0/da
Priority claimed from DK137888A external-priority patent/DK137888D0/da
Application filed by Novo Nordisk AS, Novo Industri AS filed Critical Novo Nordisk AS
Publication of WO1989008694A1 publication Critical patent/WO1989008694A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0084—Antioxidants; Free-radical scavengers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38672—Granulated or coated enzymes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3937—Stabilising agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C11D3/42—Brightening agents ; Blueing agents

Definitions

  • the technical field to which this invention pertains comprises a granulate detergent enzyme product comprising a core of a microbial enzyme containing material and a coating, a method for production of such product, a use of such product, and a detergent or a detergent component containing such product.
  • the commonest enzymatic detergent additive is a proteolytic additive, but also amylolytic, cellulolytic, and lipolytic detergent additives are described, e.g. in GB patent No. 1 554 482, BE patent No. 888 632, and US patent No. 4,011,169, column 4, line 65 to column 5, line 68.
  • the above list of enzymes is not exhaustive, but represents the commonest enzymatic additives used in detergents.
  • Enzymatic detergent additives for use in powder detergents are usually prepared in the form of dust-free granulates. These granulates can be produced in several different ways. Reference can be made to GB patent No. 1 362 365 which describes the production of enzyme containing granulates used as detergent additives by means of an apparatus comprising an extruder and a spheronizer (sold as MARUMERIZER ® ) , and to US patent No. 4 106 991, which describes the production of enzyme containing granulates used as detergent additives by means of a drum granulator. Reference is also made to European patent publication EP-A-0170360 which describes enzyme granulates containing certain salts to improve the storage stability.
  • enzyme granulates prepared according to known methods are entirely satisfactory for use in many commercial powder detergents, we have recognized that enzyme stability of these granulates is reduced in certain detergent formulations and at certain storage conditions. These include particularly detergents with high water content and/or high pH and/or high content of bleaching agents and particularly storage at high humidity and temperature.
  • the granulate detergent enzyme product according to the invention comprises a core of a microbial enzyme-containing material and a coating thereon, wherein the coating comprises a coating agent, which is a mono- and/or diglyceride of a fatty acid.
  • the coating agent comprising a mono- and/or diglyceride of a fatty acid should be solid at any normal use temperature of the product according to the invention.
  • the coating agent may be a single mono- and/or diester of a fatty acid or a mixture of such esters.
  • the detergent concept is to be understood in a broad sense.
  • the term granulate detergent enzyme product is intended to include any granulate enzyme product which is a part of or is intended later to be a part of any cleaning or cleansing composition, e.g. a heavy duty detergent, a dish washing agent, a bleaching agent, a softener, a color clarification agent or a pure surfactant.
  • the detergent according to the invention comprises any cleaning or cleansing composition containing the product according to the invention, and the detergent component according to the invention comprises for instance a bleaching agent, a softener, a color clarification agent or a pure surfactant containing the product according to the invention.
  • the invention is mainly concerned with microbially produced enzymes, as other enzymes usually are not suited as enzymatic detergent additives, ⁇ mainly due to cost and stability considerations.
  • the product according to the invention possesses the above indicated coating on a core.
  • the product according to the invention may also comprise a precoating of another coating agent on the core and/or a subsequently applied coating with another coating agent on the coating of the invention.
  • Such other coating agents may for instance be the coating agents described in DK patent application no. 121/88.
  • the coating agent does not generate any disturbing influence during the washing process, as it will emulsify in the washing liquid, whereafter the enzyme can exert its wanted activity on the laundry. Also, especially in a damp atmosphere and at relatively high temperatures it has been found that the enzymatic stability is satisfactory during storage of the product according to the invention in the presence of powerful bleaching agents .
  • the coating agent used according to the invention is produced and used as an emulsifier and stabilizer in the food industry.
  • the use of these glycerides as coating agents in order to stabilize enzyme activity in an aggressive environment generated by other detergent components is not described in these publications or made obvious on the basis thereof.
  • the melting point of the coating agent is above 35°C, preferably above 50°C. In this manner ordinarily no melting problems will occur, even in tropical regions.
  • more than 90% of the enzyme granulate cores exhibit particle sized between 2 and 3000 ⁇ m. This particle size interval covers practically all commercially used detergents.
  • more than 90% of the enzyme granulate cores exhibit particle sizes between 100 and 400 ⁇ m. This so-called microgranulate corresponds to a commercially available detergent.
  • more than 90% of the enzyme granulate cores exhibit particle sizes between 250 and 1200 ⁇ m.
  • This so-called standard granulate corresponds to usual commercially available detergents.
  • the weight of the coating is between 0.1 and 100% by weight of the core. If the weight of the coating is less then 0.1%, no satisfactory effect will be obtained, and if the weight of the coating is above 100%, the product will be too expensive, and also, no further stabilizing effect will be obtained. In a preferred embodiment of the product according to the invention the weight of the coating is between 1 and 30% by weight of the core, preferably between 2 and 20% by weight of the core. These intervals represent advantageous compromises between economy and satisfactory performance.
  • the main fatty acid(s) of the coating agent is/are palmitic and/or stearic acid.
  • These glycerol esters are available on the market and exhibit an excellent stabilizing effect.
  • the coating contains between 10 and 100% of the coating agent (on a dry substance basis). If the coating contains less than 10% of the coating agent, the impermeability of the coating is usually not satisfactory.
  • the part of the coating which is not the glyceride coating agent is a filler, which can be any salt, preferably CaCO,r talc, silica and/or TiO_ .
  • the filler may be added for economic and/or cosmetic purposes.
  • the coating can consist of coating agent entirely, and also, other additives than fillers may be present in the coating.
  • the enzyme is one or more of a protease, an amylase, a lipase, a cellulase, and an oxidase. These are the most commonly used detergent enzymes. Practice of the invention applies to any detergent enzyme.
  • the particles of enzyme containing material are commercially available granulates. These granulates may already be coated, but their coating does not generate a satisfactory enzyme stability in the presence of powerful bleaching agents. Such particles are easily available and are well suited for the invention.
  • the antioxidant in the undercoat will react with the bleaching agent and thus improve the enzyme stability.
  • the antioxidant may be a thiosulphate, preferably ammonium or sodium thiosulphate, a sulfite, a bisulfite, an ascorbic acid or a salt of ascorbic acid.
  • the invention comprises a method for production of the product according to the invention, wherein the cores are introduced into a rotating mixer and heated to a temperature above 35°C, whereafter melted coating agent is added, and the product is removed from the rotating mixer when equilibrium is obtained.
  • This method is cheap, dependable and well suited for large scale production.
  • the invention comprises a method for production of the product according to the invention, wherein the cores are suspended in melted coating agent and the thus formed mixture is introduced on the surface of a fast spinning, horizontal wheel, whereafter the product is collected downstream the spinning wheel.
  • a very homogenous product is obtained.
  • the general principle of this method is described in the International patent application no. PCT/US85/00827.
  • the invention comprises a method for production of the product according to the invention, wherein the cores are suspended in a solution of the coating agent in an organic solvent, whereafter the suspension is introduced into a fluid bed dryer and the product is collected.
  • This method is especially well suited for laboratory experiments and pilot plant runs.
  • the invention comprises a use of the granulate detergent enzyme product according to the invention as a constituent of a detergent or of a detergent component.
  • the detergent or the detergent component appear as a slurry. In this manner a physically stable mixture can easily be obtained by addition of sedimentation inhibition agents.
  • the detergent or the detergent component appear as a particulate material. In this manner it is possible to obtain a mixture, the homogeneity of which does not change with time.
  • the detergent component is a bleaching agent. It has been found that the stability of the product is satisfactory even in the presence of powerful bleaching agents.
  • the invention comprises a detergent or a detergent component, containing as a constituent the product according to the invention.
  • the detergent component appear as a slurry. In this manner a physically stable mixture can easily be obtained by addition of sedimentation inhibition agents.
  • the detergent or the detergent component appear as a particulate material. In this manner it is possible to obtain a mixture, the homogeneity of which does not change with time.
  • the detergent component appear as a particulate material, and the detergent component contains a bleaching agent. It has 5 been found that the stability of the product is satisfactory even in the presence of powerful bleaching agents.
  • the detergent 10 component appear as a particulate material
  • the detergent component contains a bleaching agent
  • the bleaching agent is coated with a sustained release coating agent, preferably a sustained release coating agent containing montmorillonite, as described in patent application DK 15 1378/88, filed on the same date as this application. It has been found that the stability of the product is excellent even in the presence of powerful bleaching agents.
  • proteolytic enzymes containing granulates are produced according to example 1 in US patent No. 4,106,991, except that a sulphate based formulation is used instead of a chloride • 25 based formulation.
  • This example describes a method for production of the granulate detergent enzyme product according to the invention.
  • Grindtek MSP 90 is a mixture of around 90% of monoglyceride of palmitic acid and stearic acid and around 10% of diglyceride of palmitic acid and stearic acid.
  • a powder mixture of titanium dioxide and magnesium silicate (700 g) is added as a colouring agent.
  • Preparations A, B, C, and E 7 kg of ALCALASE granulate (2.8 Anson Units/g) is coated as described in example 1 with Grindtek MSP40 (A), Grindtek MSP90 (B), Grindtek MSP90/bisulfite (C, titanium dioxide/Mg-silicate is mixed with finely ground Na-bisulfite corresponding to 4%, calculation based on uncoated granulate).
  • Sample E is coated with PEG4000 corresponding to prior art.
  • Preparation D This preparation is prepared with an extraordinary thick coating with MSP90, as follows: 7 kg of ALCALASE granulate (2.8 Anson units/g) is alternately sprayed with MSP90 and powdered with pure kaolin (type Speswhite/EEC) in such manner that there was never any significant excess of either MSP90 or kaolin. Totally 1.3 kg of MSP90 (18.6%) and 5.0 kg of kaolin (71.4%) is applied calculated on uncoated granulate.
  • Preparation A 7.0 kg of SAVINASE granulate is coated on a fluid-bed, Glatt WSG 5, whereby a layer consisting of 350 g of ammonium thiosulphate and 350 g of bentonite (type ASB 350 ECC) is applied with simultaneous drying. The thiosulphate/bentonite is sprayed from a solution/suspension of the indicated components in 1 kg of water. Process parameters: Temperature in/out: 50/35°C. After the coating a subsequent drying is performed.
  • Preparation B Preparation A coated with
  • Preparation C The prior art reference is coated with PEG4000 and colouring agent as preparation B; otherwise according to example 1.
  • Storage condi tions Powder detergent with 25% perborate , 37 °C , 70% relative humidity , open glasses .
  • Preparation B Corresponds to preparation A, but in coating with ammonium thiosulphate a bentonite of type ASB 350S, EEC is used.
  • Preparation C Corresponds to preparation A, but the bentonite in the thiosulphate coating is substituted by kaolin (Speswhite, ECC).
  • Preparation D Coating with Grindtek MSP90 and with colouring agent titanium dioxide: aolin; otherwise according to example 1.
  • Preparation E The prior art reference of coating is performed with PEG4000 and the colouring agent titanium dioxide:kaolin; otherwise according to example 1.
  • Storage conditions Powder detergent with 25% perborate, 37°C, 70% relative humidity, open glasses.
  • Preparation B ALCALASE granulate as preparation A coated with 7% PEG4000 and colouring agent as preparation A (prior art).
  • Preparation A Corresponds to preparation B, example 3.
  • Preparation B Corresponds to preparation C, example 3.
  • Preparation C ALCALASE granulate of 2.8 Anson Units/g coated with 7% PEG4000 and 12.5% colouring agent 4:1 titanium dioxide:Mg-silicate, whereby the colouring agent is mixed with 4% Na-bisulfite (antioxidant), calculation based on uncoated granulate. Finally, an enteric overcoating with 5% Eudragit L30D is performed according to EP-A-0 270 608 (prior art).
  • Preparation D Corresponds to preparation E, example 3 (prior art).
  • Residual activity is measured by dividing the contents of the cardboard box by means of a sample divider. 4 of the divided samples have been analyzed.
  • the contents of the cardboard box is divided by means of a sample divider. 4 samples have been analyzed.
  • Preparation A-D As example 7.
  • Preparation E Preparation as preparation B, example 7, whereby 4% Na-bisulfite is substituted by 2% Na-ascorbate.
  • the granulate was dried in a fluid-bed to a water content below 1% and sifted between 300 ⁇ m and 900 ⁇ m.
  • the dry sifted granulate with an activity of 66 KNU/g was coated to generate the preparations A, B and C.
  • Preparation A Fluid-bed coating with 5% Na- thiosulphate and 1.5% kaolin as described in example 4, preparation A, followed by a coating with 5.5% Grindtek MSP90 and 12.5% kaolin as described in example 1.
  • Preparation B Coating with 10.5% Grindtek MSP90 and 25% kaolin as described in example 1.
  • Preparation C Coating with 5.5% PEG4000 and 12.5% kaolin as described in example 1. This preparation is an example of prior art.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Biochemistry (AREA)
  • Detergent Compositions (AREA)
  • Enzymes And Modification Thereof (AREA)

Abstract

Le produit enzymatique détergent granulaire comprend un noyau d'une matière contenant une enzyme avec une couche de revêtement contenant un mono- et/ou diglycéride d'un acide gras, avec une teneur de monoglycéride par rapport à la quantité totale de mono- et diglycéride d'au moins 30 % en poids et de préférence avec un point de fusion supérieur à 35°C. Grâce à la couche de revêtement la stabilité enzymatique est augmentée en présence d'autres constituants détergents, notamment des agents de blanchiment puissants. On procéde habituellement au revêtement dans un mélangeur rotatif. De plus les couches de revêtement comportant des antioxydants augmentent la stabilité enzymatique.
PCT/DK1989/000055 1988-03-14 1989-03-13 Produit enzymatique detergent granulaire, son procede de production, son utilisation et detergent le contenant Ceased WO1989008694A1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DK1377/88 1988-03-14
DK1378/88 1988-03-14
DK137788A DK137788D0 (da) 1988-03-14 1988-03-14 Som granulat foreliggende dertergentenzymprodukt, fremgangsmaade til fremstilling deraf, anvendelse deraf og detergent indeholdende et saadant produkt
DK137888A DK137888D0 (da) 1988-03-14 1988-03-14 Stabiliseret partikelformet komposition

Publications (1)

Publication Number Publication Date
WO1989008694A1 true WO1989008694A1 (fr) 1989-09-21

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Family Applications (2)

Application Number Title Priority Date Filing Date
PCT/DK1989/000056 Ceased WO1989008695A1 (fr) 1988-03-14 1989-03-13 Composition particulaire stabilisee
PCT/DK1989/000055 Ceased WO1989008694A1 (fr) 1988-03-14 1989-03-13 Produit enzymatique detergent granulaire, son procede de production, son utilisation et detergent le contenant

Family Applications Before (1)

Application Number Title Priority Date Filing Date
PCT/DK1989/000056 Ceased WO1989008695A1 (fr) 1988-03-14 1989-03-13 Composition particulaire stabilisee

Country Status (3)

Country Link
EP (1) EP0404806B1 (fr)
JP (1) JP2624860B2 (fr)
WO (2) WO1989008695A1 (fr)

Cited By (145)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1990009440A1 (fr) * 1989-02-20 1990-08-23 Novo Nordisk A/S Granule contenant des enzymes et procede de production d'un tel granule
WO1992012645A1 (fr) * 1991-01-25 1992-08-06 Novo Nordisk A/S Utilisation d'un materiau granulaire contenant une enzyme et procede de production d'un fourrage en granules
US5376288A (en) * 1989-06-21 1994-12-27 Noro Nordisk A/S Detergent additive granulate and detergent
WO1996016151A1 (fr) * 1994-11-18 1996-05-30 Genencor International, Inc. Granules d'enzymes enrobes
WO1997042282A1 (fr) 1996-05-03 1997-11-13 The Procter & Gamble Company Compositions detergentes a base de polymeres de type polyamine a dispersion amelioree des salissures
US5733763A (en) * 1988-08-19 1998-03-31 Novo Nordisk A/S Enzyme granulate formed of an enzyme-containing core and an enzyme-containing shell
EP0755434A4 (fr) * 1994-04-13 1998-07-29 Procter & Gamble Detergents contenant un adjuvant de lavage et une enzyme liberee avec un retard
WO2001029170A1 (fr) * 1999-10-15 2001-04-26 Genencor International, Inc. Granule contenant des proteines et formulations de granules
US6268329B1 (en) 1998-06-30 2001-07-31 Nouozymes A/S Enzyme containing granule
WO2002061427A1 (fr) 2001-01-31 2002-08-08 Novozymes A/S Procede d'analyse d'une composition granulaire par fluorimetrie
WO2003080827A2 (fr) 2002-03-27 2003-10-02 Novozymes A/S Granules a enrobages filamenteux
WO2004033083A2 (fr) 2002-10-09 2004-04-22 Novozymes A/S Procede destine a ameliorer des compositions particulaires
WO2004067739A2 (fr) 2003-01-27 2004-08-12 Novozymes A/S Stabilisation de granules
WO2004082564A2 (fr) 2003-03-18 2004-09-30 Novozymes A/S Granules enzymatiques revetus
EP0780466B2 (fr) † 1995-12-22 2005-01-19 Kao Corporation Produit granulé contenant une enzyme, méthodes pour sa préparation et compositions contenant le granulat
US6866860B2 (en) 2002-12-19 2005-03-15 Ethicon, Inc. Cationic alkyd polyesters for medical applications
EP1586241A1 (fr) * 2004-04-16 2005-10-19 Paramelt B.V. Revêtement amélioré pour la stabilisation de principes actifs
US6967234B2 (en) 2002-12-18 2005-11-22 Ethicon, Inc. Alkyd-lactone copolymers for medical applications
US7005136B2 (en) 2002-03-29 2006-02-28 Ethicon, Inc. Bone replacement materials utilizing bioabsorbable liquid polymers
US7026374B2 (en) 2002-06-25 2006-04-11 Aruna Nathan Injectable microdispersions for medical applications
US7030127B2 (en) 2001-06-29 2006-04-18 Ethicon, Inc. Composition and medical devices utilizing bioabsorbable polymeric waxes
US7034037B2 (en) 2001-06-29 2006-04-25 Ethicon, Inc. Compositions and medical devices utilizing bioabsorbable polymeric waxes and rapamycin
US7101566B2 (en) 2002-06-28 2006-09-05 Ethicon, Inc. Polymer coated microparticles for sustained release
EP1700904A1 (fr) 2005-03-11 2006-09-13 Unilever N.V. Composition detergente liquide
US7153820B2 (en) 2001-08-13 2006-12-26 Ecolab Inc. Solid detergent composition and method for solidifying a detergent composition
WO2007098756A1 (fr) 2006-03-02 2007-09-07 Novozymes A/S Procédé d'encapsulation haute capacité
US7326426B2 (en) 2002-03-29 2008-02-05 Ethicon, Inc. Compositions and medical devices utilizing bioabsorbable liquid polymers
WO2008017661A1 (fr) 2006-08-07 2008-02-14 Novozymes A/S Granules d'enzyme pour alimentation animale
US7368125B2 (en) 2002-06-05 2008-05-06 Ethicon, Inc. Amphiphilic polymers for medical applications
WO2009118329A1 (fr) 2008-03-28 2009-10-01 Novozymes A/S Système à libération déclenchée
EP2143339A1 (fr) 2004-09-27 2010-01-13 Novozymes A/S Granules d'enzyme
WO2011000924A1 (fr) 2009-07-03 2011-01-06 Abbott Products Gmbh Amylase séchée par pulvérisation, préparations pharmaceutiques la comprenant et son utilisation
WO2011088089A1 (fr) 2010-01-12 2011-07-21 The Procter & Gamble Company Intermédiaires et tensioactifs utiles dans des compositions de nettoyage ménager et d'hygiène personnelle, et leurs procédés de fabrication
WO2012003316A1 (fr) 2010-07-02 2012-01-05 The Procter & Gamble Company Procédé de fabrication de films à partir de bandes non tissées
WO2012003360A2 (fr) 2010-07-02 2012-01-05 The Procter & Gamble Company Produit détergent et son procédé de fabrication
WO2012003319A2 (fr) 2010-07-02 2012-01-05 The Procter & Gamble Company Filaments comprenant des bandes non tissées avec agent actif et procédés de fabrication associés
WO2012003300A2 (fr) 2010-07-02 2012-01-05 The Procter & Gamble Company Filaments comprenant un agent actif sans parfum, voiles non tissés, et procédés de fabrication de ces filaments
WO2012003367A2 (fr) 2010-07-02 2012-01-05 The Procter & Gamble Company Procédé de diffusion d'un agent actif
WO2012009660A2 (fr) 2010-07-15 2012-01-19 The Procter & Gamble Company Compositions détergentes contenant des alcools gras et des dérivés de ceux-ci produits par voie microbienne
WO2012009525A2 (fr) 2010-07-15 2012-01-19 The Procter & Gamble Company Compositions comprenant un composé à ramification proche de l'extrémité et procédés pour les préparer
CN102533708A (zh) * 2011-12-29 2012-07-04 青岛蔚蓝生物集团有限公司 一种包被碱性蛋白酶的酶颗粒及其制备方法
WO2012112828A1 (fr) 2011-02-17 2012-08-23 The Procter & Gamble Company Sulfonates d'alkylphényle linéaires d'origine biologique
WO2012138423A1 (fr) 2011-02-17 2012-10-11 The Procter & Gamble Company Compositions comprenant des mélanges de sulfonates d'alkylphényle c10-c13
WO2012160498A2 (fr) 2011-05-20 2012-11-29 Ecolab Usa Inc. Formulations acides destinées à être utilisées dans un système de nettoyage d'articles manufacturés
EP2537918A1 (fr) 2011-06-20 2012-12-26 The Procter & Gamble Company Produits de consommation avec particules enrobées comprenant une lipase
WO2013002786A1 (fr) 2011-06-29 2013-01-03 Solae Compositions alimentaires destinées à être cuites au four et contenant des protéines de lait de soja isolées à partir de flux de traitement
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WO2013043805A1 (fr) 2011-09-20 2013-03-28 The Procter & Gamble Company Compositions détergentes contenant des systèmes de tensioactifs primaires comprenant des tensioactifs très ramifiés, notamment des tensioactifs à base d'isoprénoïdes
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WO2013043857A1 (fr) 2011-09-20 2013-03-28 The Procter & Gamble Company Compositions détergentes comprenant des systèmes de tensioactifs durables comprenant des tensioactifs dérivés d'isoprénoïdes
WO2013043852A2 (fr) 2011-09-20 2013-03-28 The Procter & Gamble Company Compositions détergentes faciles à rincer comprenant des agents tensio-actifs à base d'isoprénoïde
WO2013070559A1 (fr) 2011-11-11 2013-05-16 The Procter & Gamble Company Compositions de traitement de surface comprenant des sels protecteurs
FR2985273A1 (fr) 2012-01-04 2013-07-05 Procter & Gamble Structures fibreuses contenant des actifs et ayant des regions multiples
EP2617804A1 (fr) 2007-02-15 2013-07-24 Ecolab Inc. Détergent solide se dissolvant rapidement
EP2677023A2 (fr) 2007-10-18 2013-12-25 Ecolab Inc. Compositions nettoyantes solides, cireuses et comprimées, et leurs procédés de fabrication
WO2014018309A1 (fr) 2012-07-26 2014-01-30 The Procter & Gamble Company Compositions de nettoyage liquides à faible ph et à enzymes
US8802087B2 (en) 2004-03-22 2014-08-12 Abbott Products Gmbh Pharmaceutical compositions of lipase-containing products, in particular of pancreation
EP2792737A1 (fr) 2011-05-20 2014-10-22 Ecolab USA Inc. Détergents sans phosphates et sans acides phosphoriques dans un système alternatif basique/acide pour le lavage de la vaisselle
FR3014456A1 (fr) 2013-12-09 2015-06-12 Procter & Gamble
WO2015112671A1 (fr) 2014-01-24 2015-07-30 The Procter & Gamble Company Compositions de produits consommateurs
US9198871B2 (en) 2005-08-15 2015-12-01 Abbott Products Gmbh Delayed release pancreatin compositions
WO2016032995A1 (fr) 2014-08-27 2016-03-03 The Procter & Gamble Company Procédé de traitement d'un tissu
WO2016032991A1 (fr) 2014-08-27 2016-03-03 The Procter & Gamble Company Composition détergente comprenant un polymère cationique
WO2016032993A1 (fr) 2014-08-27 2016-03-03 The Procter & Gamble Company Composition détergente comprenant un polymère cationique
WO2016032992A1 (fr) 2014-08-27 2016-03-03 The Procter & Gamble Company Composition de détergent comprenant un polymère cationique
WO2016049388A1 (fr) 2014-09-25 2016-03-31 The Procter & Gamble Company Compositions d'entretien de tissus contenant une polyétheramine
CN105705622A (zh) * 2013-10-15 2016-06-22 丹尼斯科美国公司 粘土粒料
EP3072399A1 (fr) 2006-08-07 2016-09-28 Novozymes A/S Granules d'enzyme pour alimentation animale
EP3282004A1 (fr) 2011-12-13 2018-02-14 Ecolab USA Inc. Procédé pour le lavage mécanique de vaisselle
US9895427B2 (en) 2009-01-06 2018-02-20 Galenagen, Llc Compositions and methods for the treatment or the prevention of E. coli infections and for the eradication or reduction of E. coli surfaces
US9925250B2 (en) 2008-03-13 2018-03-27 Curemark, Llc Method of treating proteinuria in pregnancy
US9931302B2 (en) 2009-04-13 2018-04-03 Curemark , LLC Enzyme delivery systems and methods of preparation and use
WO2018085394A1 (fr) 2016-11-01 2018-05-11 Milliken & Company Composés leuco réactifs et compositions comprenant ceux-ci
WO2018085389A1 (fr) 2016-11-01 2018-05-11 Milliken & Company Leuco-polymères à titre d'agents d'azurage dans des compositions d'entretien du linge
WO2018085312A1 (fr) 2016-11-01 2018-05-11 The Procter & Gamble Company Leuco-colorants utilisés en tant que produits d'azurage dans des compositions de soin du linge
WO2018085302A1 (fr) 2016-11-01 2018-05-11 The Procter & Gamble Company Leuco polymères comme agents d'azurage dans des compositions d'entretien du linge
WO2018085388A1 (fr) 2016-11-01 2018-05-11 Milliken & Company Leuco-polymères à titre d'agents d'azurage dans des compositions d'entretien du linge
WO2018085380A1 (fr) 2016-11-01 2018-05-11 Milliken & Company Leuco-polymères utilisés en tant qu'agents d'azurage dans des compositions d'entretien du linge
WO2018085306A1 (fr) 2016-11-01 2018-05-11 The Procter & Gamble Company Leuco-colorants utilisés en tant qu'agents d'azurage dans des compositions de soin du linge
WO2018085300A1 (fr) 2016-11-01 2018-05-11 The Procter & Gamble Company Procédés d'utilisation de leuco-colorants en tant qu'agents d'azurage dans des compositions d'entretien du linge
WO2018085311A1 (fr) 2016-11-01 2018-05-11 The Procter & Gamble Company Leuco-polymères en tant qu'agents d'azurage dans des compositions pour l'entretien du linge
WO2018085303A1 (fr) 2016-11-01 2018-05-11 The Procter & Gamble Company Leuco polymères comme agents d'azurage dans des compositions de soin du linge
WO2018085372A1 (fr) 2016-11-01 2018-05-11 Milliken & Company Polymères leuco en tant qu'agents d'azurage dans des compositions de soin du linge
WO2018085308A1 (fr) 2016-11-01 2018-05-11 The Procter & Gamble Company Leuco-polymères utilisés en tant qu'agents d'azurage dans des compositions d'entretien du linge
WO2018085382A1 (fr) 2016-11-01 2018-05-11 Milliken & Company Polymères leuco à titre d'agents azurants dans des compositions d'entretien du linge
WO2018085378A1 (fr) 2016-11-01 2018-05-11 Milliken & Company Polymères leuco à titre d'agents azurants dans des compositions d'entretien du linge
WO2018085313A1 (fr) 2016-11-01 2018-05-11 The Procter & Gamble Company Procédés d'utilisation de leuco colorants comme agents d'azurage dans des compositions de soin du linge
WO2018085386A1 (fr) 2016-11-01 2018-05-11 Milliken & Company Leuco polymères destinés à des agents d'azurage dans des compositions de soin du linge
WO2018085305A1 (fr) 2016-11-01 2018-05-11 The Procter & Gamble Company Leuco-polymères en tant qu'agents d'azurage dans des compositions d'entretien du linge
WO2018085314A1 (fr) 2016-11-01 2018-05-11 The Procter & Gamble Company Composés leuco réactifs et compositions comprenant ceux-ci
WO2018085301A1 (fr) 2016-11-01 2018-05-11 The Procter & Gamble Company Leuco-colorants à base triphénylméthane en tant qu'agents d'azurage dans des compositions de soin du linge
WO2018085304A1 (fr) 2016-11-01 2018-05-11 The Procter & Gamble Company Leuco-polymères utilisés en tant qu'agents d'azurage dans des compositions d'entretien du linge
WO2018085309A1 (fr) 2016-11-01 2018-05-11 The Procter & Gamble Company Polymères leuco en tant qu'agents d'azurage dans des compositions de soin du linge
WO2018085391A1 (fr) 2016-11-01 2018-05-11 Milliken & Company Leuco-polymères en tant qu'agents d'azurage dans des compositions d'entretien du linge
WO2018140472A1 (fr) 2017-01-27 2018-08-02 The Procter & Gamble Company Articles contenant des agents actifs présentant des propriétés d'utilisation d'articles acceptables pour le consommateur
WO2018140432A1 (fr) 2017-01-27 2018-08-02 The Procter & Gamble Company Articles contenant des agents actifs présentant des propriétés d'utilisation acceptables pour le consommateur
WO2018140431A1 (fr) 2017-01-27 2018-08-02 The Procter & Gamble Company Articles contenant des agents actifs présentant des propriétés d'utilisation acceptables pour le consommateur
WO2018140454A1 (fr) 2017-01-27 2018-08-02 The Procter & Gamble Company Articles contenant un agent actif et ensembles de transport de produits destinés à les contenir
EP3369845A1 (fr) 2012-01-04 2018-09-05 The Procter & Gamble Company Structures fibreuses contenant des principes actifs et présentant de multiples zones ayant des densités différentes
US10072256B2 (en) 2006-05-22 2018-09-11 Abbott Products Gmbh Process for separating and determining the viral load in a pancreatin sample
US10209253B2 (en) 2000-11-16 2019-02-19 Curemark, Llc Methods for diagnosing pervasive development disorders, dysautonomia and other neurological conditions
EP3470516A1 (fr) 2012-09-10 2019-04-17 Ecolab USA Inc. Compositions pour laver la vaisselle à la main liquides et stables contenant des enzymes
WO2019075143A1 (fr) 2017-10-12 2019-04-18 The Procter & Gamble Company Leuco-colorants en tant qu'agents d'azurage dans des compositions d'entretien du linge
WO2019075230A1 (fr) 2017-10-12 2019-04-18 Milliken & Company Composés leuco et compositions les comprenant
WO2019075139A1 (fr) 2017-10-12 2019-04-18 The Procter & Gamble Company Compositions de soin du linge et procédés permettant de déterminer leur âge
WO2019075232A1 (fr) 2017-10-12 2019-04-18 Milliken & Company Composés leuco de triarylméthane et compositions les contenant
WO2019075142A1 (fr) 2017-10-12 2019-04-18 The Procter & Gamble Company Procédés d'utilisation de leuco colorants comme produits d'azurage dans des compositions d'entretien du linge
WO2019075145A1 (fr) 2017-10-12 2019-04-18 The Procter & Gamble Company Leuco-colorants à conjugaison étendue à titre d'agents d'azurage dans des formulations d'entretien du linge
WO2019075149A1 (fr) 2017-10-12 2019-04-18 The Procter & Gamble Company Compositions de soin du linge comprenant des composés leuco
WO2019075141A1 (fr) 2017-10-12 2019-04-18 The Procter & Gamble Company Procédés d'utilisation de leuco colorants comme agents d'azurage dans des compositions de soin du linge
WO2019075225A1 (fr) 2017-10-12 2019-04-18 Milliken & Company Leuco-colorants à conjugaison étendue
WO2019075223A1 (fr) 2017-10-12 2019-04-18 Milliken & Company Composés leuco
WO2019075150A1 (fr) 2017-10-12 2019-04-18 The Procter & Gamble Company Leuco-colorants en tant qu'agents d'azurage dans des compositions d'entretien du linge
WO2019075147A1 (fr) 2017-10-12 2019-04-18 The Procter & Gamble Company Procédés d'utilisation de leuco-colorants comme agents d'azurage dans des compositions d'entretien du linge
US10272141B2 (en) 2008-04-18 2019-04-30 Curemark, Llc Pharmaceutical preparation for the treatment of the symptoms of addiction and method of diagnosing same
US10279016B2 (en) 2011-04-21 2019-05-07 Curemark, Llc Method of treatment of schizophreniform disorder
US10350229B2 (en) 2005-08-30 2019-07-16 Curemark, Llc Use of lactulose in the treatment of autism
US10350278B2 (en) 2012-05-30 2019-07-16 Curemark, Llc Methods of treating Celiac disease
US10413601B2 (en) 2008-10-03 2019-09-17 Curemark, Llc Methods and compositions for the treatment of symptoms of prion diseases
WO2020023812A1 (fr) 2018-07-27 2020-01-30 The Procter & Gamble Company Colorants leuco utilisés comme agents d'azurage dans des compositions d'entretien du linge
WO2020023883A1 (fr) 2018-07-27 2020-01-30 Milliken & Company Antioxydants phénoliques polymères
WO2020023897A1 (fr) 2018-07-27 2020-01-30 Milliken & Company Compositions stabilisées comprenant des composés leuco
WO2020023892A1 (fr) 2018-07-27 2020-01-30 Milliken & Company Antioxydants aminé polymères
US10588948B2 (en) 2008-06-26 2020-03-17 Curemark, Llc Methods and compositions for the treatment of symptoms of Williams Syndrome
WO2020053238A1 (fr) 2018-09-11 2020-03-19 Novozymes A/S Granulés stables pour compositions d'alimentation
WO2020123888A1 (fr) 2018-12-14 2020-06-18 The Procter & Gamble Company Article produisant de la mousse, se désintégrant dans l'eau
WO2020123889A1 (fr) 2018-12-14 2020-06-18 The Procter & Gamble Company Structures fibreuses moussantes comprenant des particules et leurs procédés de production
US10704037B2 (en) 2005-07-29 2020-07-07 Abbott Products Gmbh Processes for the manufacture and use of pancreatin
US10716835B2 (en) 2009-10-21 2020-07-21 Curemark, Llc Methods and compositions for the prevention and treatment of influenza
US10736946B2 (en) 2009-01-06 2020-08-11 Galenagen, Llc Compositions and methods for treatment or prevention of Staphylococcus aureus infections and for the eradication or reduction of Staphylococcus aureus on surfaces
US10776453B2 (en) 2008-08-04 2020-09-15 Galenagen, Llc Systems and methods employing remote data gathering and monitoring for diagnosing, staging, and treatment of Parkinsons disease, movement and neurological disorders, and chronic pain
EP3719192A1 (fr) 2012-01-04 2020-10-07 The Procter & Gamble Company Structures fibreuses comprenant des particules et leurs procédés de fabrication
WO2021022045A1 (fr) 2019-07-31 2021-02-04 Ecolab Usa Inc. Compositions de détartrage sans équipement de protection individuelle
WO2021026556A1 (fr) 2019-08-02 2021-02-11 The Procter & Gamble Company Compositions moussantes pour la production d'une mousse stable et leurs procédés de fabrication
WO2021097004A1 (fr) 2019-11-15 2021-05-20 The Procter & Gamble Company Articles solubles contenant des éléments graphiques et leurs procédés de fabrication
US11016104B2 (en) 2008-07-01 2021-05-25 Curemark, Llc Methods and compositions for the treatment of symptoms of neurological and mental health disorders
US11266607B2 (en) 2005-08-15 2022-03-08 AbbVie Pharmaceuticals GmbH Process for the manufacture and use of pancreatin micropellet cores
WO2022076535A1 (fr) 2020-10-06 2022-04-14 Danisco Us Inc. Granules bio-actifs pouvant être facilement dispersés et stables au stockage
WO2022074166A1 (fr) 2020-10-07 2022-04-14 Novozymes A/S Nouveaux granulés pour l'alimentation d'animaux
WO2022251838A1 (fr) 2021-05-28 2022-12-01 The Procter & Gamble Company Éléments fibreux à base de polymère naturel comprenant un tensioactif et leurs procédés de fabrication
US11541009B2 (en) 2020-09-10 2023-01-03 Curemark, Llc Methods of prophylaxis of coronavirus infection and treatment of coronaviruses
WO2024107400A1 (fr) 2022-11-15 2024-05-23 Milliken & Company Composition d'azurant optique et composition pour le soin du linge la comprenant
US12157869B2 (en) 2019-07-10 2024-12-03 Jeffrey Dean Lindsay Methods and compositions for reducing persistent odor in clothing and mitigating biofilms on various materials
US12226464B2 (en) 2017-04-10 2025-02-18 Curemark, Llc Compositions for treating addiction
US12350365B2 (en) 2009-12-23 2025-07-08 Lume Deodorant, Llc Products and methods for reducing malodor from the pudendum

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5443750A (en) * 1991-01-16 1995-08-22 The Procter & Gamble Company Detergent compositions with high activity cellulase and softening clays
SG52693A1 (en) * 1991-01-16 1998-09-28 Procter & Gamble Detergent compositions with high activity cellulase and softening clays
AU4877296A (en) * 1995-02-18 1996-09-11 Albright & Wilson Uk Limited Enzyme detergents
DK0773984T3 (da) * 1995-05-29 2000-04-10 Kao Corp Enzymholdig granuleret substans og fremgangsmåde til fremstilling heraf
EP0753567A1 (fr) * 1995-07-14 1997-01-15 The Procter & Gamble Company Compositions adoucissantes pour le lavage simultané
NZ321041A (en) 1995-10-06 1999-11-29 Genencor Int Microgranule for food/feed applications
DE19538028A1 (de) * 1995-10-12 1997-04-17 Sued Chemie Ag Waschmittelzusatz
DE19538029A1 (de) * 1995-10-12 1997-04-17 Sued Chemie Ag Waschmittelzusatz
DE19606343A1 (de) * 1996-02-21 1997-08-28 Hoechst Ag Bleichmittel
SK912003A3 (en) 2000-07-28 2003-07-01 Henkel Kgaa Novel amylolytic enzyme extracted from bacillus sp. A 7-7 (DSM 12368) and washing and cleaning agents containing this novel amylolytic enzyme
EP2216393B1 (fr) * 2009-02-09 2024-04-24 The Procter & Gamble Company Composition de détergent
CN102250871A (zh) * 2011-07-04 2011-11-23 绍兴文理学院 一种膨润土固定化脂肪酶的制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK130127A (fr) * 1967-10-06
EP0193829A2 (fr) * 1985-03-05 1986-09-10 SOLVAY ENZYMES, INC. (a Delaware corporation) Formulation d'enzyme particulaire et non poussiéreuse
EP0206417A2 (fr) * 1985-06-28 1986-12-30 The Procter & Gamble Company Composition sèche contenant une enzyme stable à l'égard d'agents de blanchiment

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3953292A (en) * 1974-02-01 1976-04-27 Engelhard Minerals & Chemicals Corporation Enzymes bound to heat-activated attapulgite clay
IE51848B1 (en) * 1980-11-06 1987-04-15 Procter & Gamble Bleach activator compositions,preparation thereof and use in granular detergent compositions
GB8424812D0 (en) * 1984-10-02 1984-11-07 Unilever Plc Enzymatic detergent composition

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK130127A (fr) * 1967-10-06
EP0193829A2 (fr) * 1985-03-05 1986-09-10 SOLVAY ENZYMES, INC. (a Delaware corporation) Formulation d'enzyme particulaire et non poussiéreuse
EP0206417A2 (fr) * 1985-06-28 1986-12-30 The Procter & Gamble Company Composition sèche contenant une enzyme stable à l'égard d'agents de blanchiment

Cited By (194)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5733763A (en) * 1988-08-19 1998-03-31 Novo Nordisk A/S Enzyme granulate formed of an enzyme-containing core and an enzyme-containing shell
WO1990009440A1 (fr) * 1989-02-20 1990-08-23 Novo Nordisk A/S Granule contenant des enzymes et procede de production d'un tel granule
US5376288A (en) * 1989-06-21 1994-12-27 Noro Nordisk A/S Detergent additive granulate and detergent
WO1992012645A1 (fr) * 1991-01-25 1992-08-06 Novo Nordisk A/S Utilisation d'un materiau granulaire contenant une enzyme et procede de production d'un fourrage en granules
US5391371A (en) * 1991-01-25 1995-02-21 Novo Nordisk A/S Use of an enzyme containing granulate in a method for production of a pelletized fodder
EP0755434A4 (fr) * 1994-04-13 1998-07-29 Procter & Gamble Detergents contenant un adjuvant de lavage et une enzyme liberee avec un retard
WO1996016151A1 (fr) * 1994-11-18 1996-05-30 Genencor International, Inc. Granules d'enzymes enrobes
EP0780466B2 (fr) † 1995-12-22 2005-01-19 Kao Corporation Produit granulé contenant une enzyme, méthodes pour sa préparation et compositions contenant le granulat
WO1997042282A1 (fr) 1996-05-03 1997-11-13 The Procter & Gamble Company Compositions detergentes a base de polymeres de type polyamine a dispersion amelioree des salissures
US6348442B2 (en) 1998-06-30 2002-02-19 Novozymes A/S Enzyme containing granule
US6268329B1 (en) 1998-06-30 2001-07-31 Nouozymes A/S Enzyme containing granule
WO2001029170A1 (fr) * 1999-10-15 2001-04-26 Genencor International, Inc. Granule contenant des proteines et formulations de granules
US10209253B2 (en) 2000-11-16 2019-02-19 Curemark, Llc Methods for diagnosing pervasive development disorders, dysautonomia and other neurological conditions
WO2002061427A1 (fr) 2001-01-31 2002-08-08 Novozymes A/S Procede d'analyse d'une composition granulaire par fluorimetrie
US7030127B2 (en) 2001-06-29 2006-04-18 Ethicon, Inc. Composition and medical devices utilizing bioabsorbable polymeric waxes
US7034037B2 (en) 2001-06-29 2006-04-25 Ethicon, Inc. Compositions and medical devices utilizing bioabsorbable polymeric waxes and rapamycin
US7153820B2 (en) 2001-08-13 2006-12-26 Ecolab Inc. Solid detergent composition and method for solidifying a detergent composition
WO2003080827A2 (fr) 2002-03-27 2003-10-02 Novozymes A/S Granules a enrobages filamenteux
US7326426B2 (en) 2002-03-29 2008-02-05 Ethicon, Inc. Compositions and medical devices utilizing bioabsorbable liquid polymers
US8623413B2 (en) 2002-03-29 2014-01-07 Ethicon, Inc. Compositions and medical devices utilizing bioabsorbable liquid polymers
US7005136B2 (en) 2002-03-29 2006-02-28 Ethicon, Inc. Bone replacement materials utilizing bioabsorbable liquid polymers
US7368125B2 (en) 2002-06-05 2008-05-06 Ethicon, Inc. Amphiphilic polymers for medical applications
US7026374B2 (en) 2002-06-25 2006-04-11 Aruna Nathan Injectable microdispersions for medical applications
US7101566B2 (en) 2002-06-28 2006-09-05 Ethicon, Inc. Polymer coated microparticles for sustained release
WO2004033083A2 (fr) 2002-10-09 2004-04-22 Novozymes A/S Procede destine a ameliorer des compositions particulaires
US6967234B2 (en) 2002-12-18 2005-11-22 Ethicon, Inc. Alkyd-lactone copolymers for medical applications
US6866860B2 (en) 2002-12-19 2005-03-15 Ethicon, Inc. Cationic alkyd polyesters for medical applications
WO2004067739A2 (fr) 2003-01-27 2004-08-12 Novozymes A/S Stabilisation de granules
WO2004082564A2 (fr) 2003-03-18 2004-09-30 Novozymes A/S Granules enzymatiques revetus
US8802087B2 (en) 2004-03-22 2014-08-12 Abbott Products Gmbh Pharmaceutical compositions of lipase-containing products, in particular of pancreation
EP1586241A1 (fr) * 2004-04-16 2005-10-19 Paramelt B.V. Revêtement amélioré pour la stabilisation de principes actifs
EP2143338A1 (fr) 2004-09-27 2010-01-13 Novozymes A/S Granules d'enzyme
EP2143339A1 (fr) 2004-09-27 2010-01-13 Novozymes A/S Granules d'enzyme
EP2160950A1 (fr) 2004-09-27 2010-03-10 Novozymes A/S Granules d'enzyme
DE202005021811U1 (de) 2004-09-27 2010-04-15 Novozymes A/S Körnchen mit einem Kern und einer Beschichtung
DE202005021810U1 (de) 2004-09-27 2010-04-22 Novozymes A/S Körnchen mit einem Kern und einer Beschichtung
EP2258209A1 (fr) 2004-09-27 2010-12-08 Novozymes A/S Granules d'enzyme
EP1700904A1 (fr) 2005-03-11 2006-09-13 Unilever N.V. Composition detergente liquide
US10704037B2 (en) 2005-07-29 2020-07-07 Abbott Products Gmbh Processes for the manufacture and use of pancreatin
US11266607B2 (en) 2005-08-15 2022-03-08 AbbVie Pharmaceuticals GmbH Process for the manufacture and use of pancreatin micropellet cores
US9198871B2 (en) 2005-08-15 2015-12-01 Abbott Products Gmbh Delayed release pancreatin compositions
US10350229B2 (en) 2005-08-30 2019-07-16 Curemark, Llc Use of lactulose in the treatment of autism
US11033563B2 (en) 2005-08-30 2021-06-15 Curemark, Llc Use of lactulose in the treatment of autism
WO2007098756A1 (fr) 2006-03-02 2007-09-07 Novozymes A/S Procédé d'encapsulation haute capacité
US10072256B2 (en) 2006-05-22 2018-09-11 Abbott Products Gmbh Process for separating and determining the viral load in a pancreatin sample
WO2008017661A1 (fr) 2006-08-07 2008-02-14 Novozymes A/S Granules d'enzyme pour alimentation animale
EP3072399A1 (fr) 2006-08-07 2016-09-28 Novozymes A/S Granules d'enzyme pour alimentation animale
US10577565B2 (en) 2007-02-15 2020-03-03 Ecolab Usa Inc. Fast dissolving solid detergent
US10005986B2 (en) 2007-02-15 2018-06-26 Ecolab Usa Inc. Fast dissolving solid detergent
EP3339412A1 (fr) 2007-02-15 2018-06-27 Ecolab Usa Inc. Détergent solide à dissolution rapide
US9267097B2 (en) 2007-02-15 2016-02-23 Ecolab Usa Inc. Fast dissolving solid detergent
EP2617804A1 (fr) 2007-02-15 2013-07-24 Ecolab Inc. Détergent solide se dissolvant rapidement
US11261406B2 (en) 2007-02-15 2022-03-01 Ecolab Usa Inc. Fast dissolving solid detergent
EP3438235A1 (fr) 2007-10-18 2019-02-06 Ecolab USA Inc. Compositions de nettoyage à presse, cire et solide et leurs procédés de fabrication
EP2677023A2 (fr) 2007-10-18 2013-12-25 Ecolab Inc. Compositions nettoyantes solides, cireuses et comprimées, et leurs procédés de fabrication
US11045527B2 (en) 2008-03-13 2021-06-29 Curemark, Llc Method of diagnosing preeclampsia or pregnancy-induced hypertension
US9925250B2 (en) 2008-03-13 2018-03-27 Curemark, Llc Method of treating proteinuria in pregnancy
WO2009118329A1 (fr) 2008-03-28 2009-10-01 Novozymes A/S Système à libération déclenchée
US11235038B2 (en) 2008-04-18 2022-02-01 Curemark, Llc Pharmaceutical preparation for the treatment of the symptoms of addiction and method of diagnosing same
US10272141B2 (en) 2008-04-18 2019-04-30 Curemark, Llc Pharmaceutical preparation for the treatment of the symptoms of addiction and method of diagnosing same
US10588948B2 (en) 2008-06-26 2020-03-17 Curemark, Llc Methods and compositions for the treatment of symptoms of Williams Syndrome
US11016104B2 (en) 2008-07-01 2021-05-25 Curemark, Llc Methods and compositions for the treatment of symptoms of neurological and mental health disorders
US10776453B2 (en) 2008-08-04 2020-09-15 Galenagen, Llc Systems and methods employing remote data gathering and monitoring for diagnosing, staging, and treatment of Parkinsons disease, movement and neurological disorders, and chronic pain
US10413601B2 (en) 2008-10-03 2019-09-17 Curemark, Llc Methods and compositions for the treatment of symptoms of prion diseases
US9895427B2 (en) 2009-01-06 2018-02-20 Galenagen, Llc Compositions and methods for the treatment or the prevention of E. coli infections and for the eradication or reduction of E. coli surfaces
US11357835B2 (en) 2009-01-06 2022-06-14 Galenagen, Llc Compositions and methods for the treatment or the prevention of E. coli infections and for the eradication or reduction of E. coli surfaces
US10736946B2 (en) 2009-01-06 2020-08-11 Galenagen, Llc Compositions and methods for treatment or prevention of Staphylococcus aureus infections and for the eradication or reduction of Staphylococcus aureus on surfaces
US11419821B2 (en) 2009-04-13 2022-08-23 Curemark, Llc Enzyme delivery systems and methods of preparation and use
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US10098844B2 (en) 2009-04-13 2018-10-16 Curemark, Llc Enzyme delivery systems and methods of preparation and use
WO2011000924A1 (fr) 2009-07-03 2011-01-06 Abbott Products Gmbh Amylase séchée par pulvérisation, préparations pharmaceutiques la comprenant et son utilisation
US10716835B2 (en) 2009-10-21 2020-07-21 Curemark, Llc Methods and compositions for the prevention and treatment of influenza
US12350365B2 (en) 2009-12-23 2025-07-08 Lume Deodorant, Llc Products and methods for reducing malodor from the pudendum
WO2011088089A1 (fr) 2010-01-12 2011-07-21 The Procter & Gamble Company Intermédiaires et tensioactifs utiles dans des compositions de nettoyage ménager et d'hygiène personnelle, et leurs procédés de fabrication
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US9193937B2 (en) 2011-02-17 2015-11-24 The Procter & Gamble Company Mixtures of C10-C13 alkylphenyl sulfonates
WO2012112828A1 (fr) 2011-02-17 2012-08-23 The Procter & Gamble Company Sulfonates d'alkylphényle linéaires d'origine biologique
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US10279016B2 (en) 2011-04-21 2019-05-07 Curemark, Llc Method of treatment of schizophreniform disorder
US10940187B2 (en) 2011-04-21 2021-03-09 Curemark, Llc Method of treatment of schizophreniform disorder
EP2792737A1 (fr) 2011-05-20 2014-10-22 Ecolab USA Inc. Détergents sans phosphates et sans acides phosphoriques dans un système alternatif basique/acide pour le lavage de la vaisselle
EP2902471A1 (fr) 2011-05-20 2015-08-05 Ecolab USA Inc. Détergents sans phosphates et acides non phosphoriques dans un système alternatif alcalin/acide pour le lavage de la vaisselle
WO2012160498A2 (fr) 2011-05-20 2012-11-29 Ecolab Usa Inc. Formulations acides destinées à être utilisées dans un système de nettoyage d'articles manufacturés
WO2013003025A1 (fr) 2011-06-20 2013-01-03 The Procter & Gamble Company Produits de consommation à base de lipase comprenant des particules enrobées
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WO2013002786A1 (fr) 2011-06-29 2013-01-03 Solae Compositions alimentaires destinées à être cuites au four et contenant des protéines de lait de soja isolées à partir de flux de traitement
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WO2013043857A1 (fr) 2011-09-20 2013-03-28 The Procter & Gamble Company Compositions détergentes comprenant des systèmes de tensioactifs durables comprenant des tensioactifs dérivés d'isoprénoïdes
WO2013043805A1 (fr) 2011-09-20 2013-03-28 The Procter & Gamble Company Compositions détergentes contenant des systèmes de tensioactifs primaires comprenant des tensioactifs très ramifiés, notamment des tensioactifs à base d'isoprénoïdes
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EP3282004A1 (fr) 2011-12-13 2018-02-14 Ecolab USA Inc. Procédé pour le lavage mécanique de vaisselle
CN102533708A (zh) * 2011-12-29 2012-07-04 青岛蔚蓝生物集团有限公司 一种包被碱性蛋白酶的酶颗粒及其制备方法
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EP3470516A1 (fr) 2012-09-10 2019-04-17 Ecolab USA Inc. Compositions pour laver la vaisselle à la main liquides et stables contenant des enzymes
CN105705622A (zh) * 2013-10-15 2016-06-22 丹尼斯科美国公司 粘土粒料
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WO2020053238A1 (fr) 2018-09-11 2020-03-19 Novozymes A/S Granulés stables pour compositions d'alimentation
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US12157869B2 (en) 2019-07-10 2024-12-03 Jeffrey Dean Lindsay Methods and compositions for reducing persistent odor in clothing and mitigating biofilms on various materials
WO2021022045A1 (fr) 2019-07-31 2021-02-04 Ecolab Usa Inc. Compositions de détartrage sans équipement de protection individuelle
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US12485094B2 (en) 2020-09-10 2025-12-02 Curemark, Llc Methods of prophylaxis of coronavirus infection and treatment of coronaviruses
WO2022076535A1 (fr) 2020-10-06 2022-04-14 Danisco Us Inc. Granules bio-actifs pouvant être facilement dispersés et stables au stockage
WO2022074166A1 (fr) 2020-10-07 2022-04-14 Novozymes A/S Nouveaux granulés pour l'alimentation d'animaux
WO2022251838A1 (fr) 2021-05-28 2022-12-01 The Procter & Gamble Company Éléments fibreux à base de polymère naturel comprenant un tensioactif et leurs procédés de fabrication
WO2024107400A1 (fr) 2022-11-15 2024-05-23 Milliken & Company Composition d'azurant optique et composition pour le soin du linge la comprenant

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EP0404806B1 (fr) 1992-03-11
WO1989008695A1 (fr) 1989-09-21
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EP0404806A1 (fr) 1991-01-02
JP2624860B2 (ja) 1997-06-25

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