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WO1988007069A1 - Composition de revetement et procede servant a former un film auto-protecteur anti-corrosion - Google Patents

Composition de revetement et procede servant a former un film auto-protecteur anti-corrosion Download PDF

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Publication number
WO1988007069A1
WO1988007069A1 PCT/US1987/000619 US8700619W WO8807069A1 WO 1988007069 A1 WO1988007069 A1 WO 1988007069A1 US 8700619 W US8700619 W US 8700619W WO 8807069 A1 WO8807069 A1 WO 8807069A1
Authority
WO
WIPO (PCT)
Prior art keywords
oil
coating
composition
water
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US1987/000619
Other languages
English (en)
Inventor
Perry E. Landers
George F. Felton
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ashland LLC
Original Assignee
Ashland Oil Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to EP86117532A priority Critical patent/EP0229349A3/fr
Application filed by Ashland Oil Inc filed Critical Ashland Oil Inc
Priority to PCT/US1987/000619 priority patent/WO1988007069A1/fr
Priority to JP62502277A priority patent/JPH02501832A/ja
Priority to BR8707977A priority patent/BR8707977A/pt
Priority to AU72336/87A priority patent/AU616378B2/en
Publication of WO1988007069A1 publication Critical patent/WO1988007069A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints

Definitions

  • the present invention pertains to coatings and metal surface treatments preparatory to applying such coatings .
  • U. S. 3 ,457, 173 to Pater lubricates metal surfaces by applying siloxane-polyoxyalkylene block co-polymers .
  • the present invention by using emulsions produced from oil-based concentrates comprising petroleum oils , siloxanes , and organic salts produced by reacting polyfunctional long chain organic compounds, e. g. polyamines or polyhydroxides or mixed polyamine/polyhydroxides with an organic acid provides when measured dramatically improved salt spray performance, particularly after car wash or contact with other detergent solutions .
  • polyfunctional long chain organic compounds e. g. polyamines or polyhydroxides or mixed polyamine/polyhydroxides
  • an organic acid e. g. polyamines or polyhydroxides or mixed polyamine/polyhydroxides
  • the compositions of the invention provide essentially self-healing polymer coatings , particularly suited for use in motor vehicles , military equipment, and all sorts of machinery.
  • the invention is applicable to virtually any phosphated or nitrided work piece requiring substantial corrosion protection and can provide some protection for even nonferrous workpieces.
  • the invention is useful for protecting metals , particularly ferrous work pieces and especially those which have been previously phosphated or nitrided. While not wishing to be held to any theory of the invention, it appears that the nitriding or phosphating increase the roughness of the metal surface , providing irregularities which more firmly grip and bond the coating layer to the metal work piece.
  • Figure 1 is a graph of salt-spray resistance (hours) for several inventive and conventional formulations .
  • Figure 2 is a schematic diagram of a manufacture according to the invention.
  • Figure 3 is a schematic diagram of a process of the present invention showing the phosphatizing followed by the dip coating into the emulsion compositions of the invention.
  • oils useful in the present invention are petroleum-derived, with naphthenic oils being less preferred and paraffinic being more preferred. More preferable paraffinic oils include those having an SSU viscosity in the range of about 50 SSU to about 700, more preferably 100 to 400 and most preferably 250 to 370 seconds at 38°C (100°F) . Particularly preferred are oils having a viscosity index of above 90 , more preferably above 95.
  • the oil will preferably comprise from about 20 to 95 , more preferably 30 to 80 and most preferably 45 to 85 wt % of the total formulation of the invention concentrate .
  • the invention comprises glycols , glycol ethers and derivatives thereof.
  • alkyl carbitols especially Butyl carbitol or most preferably, butyl cellosolve manufactured by Eastman Kodak, Rochester.
  • the glycols , etc . will preferably comprise from about 0.1 to 15 , more preferably 1 to 10 wt. % of the total formulation.
  • Emulsifying Agent :
  • the invention comprises emulsifying agents such as oxygenated hydrocarbons partially neutralized with alkaline earth metal (e. g. barium) then blended with alkali metal (e. g. sodium) sulfonates such as ALOX575 available from ALOX Corp . of Niagara Falls or IDASOL D274 from Ideas , Inc. Woodale, IL, or similar products from N . L. Kimes , Inc. , Allison Park, PA.
  • alkaline earth metal e. g. barium
  • alkali metal e. g. sodium
  • the emulsifying agent will preferably comprise about 5 to 50, more preferably 8 to 35 , and most preferably 20 to 30 wt. % of the total formulation.
  • Siloxanes useful in the present invention are substituted with one or more alkyl groups , each alkyl group comprising preferably 1 to stet, more preferably 1 to 6, and most preferably 1 to 5 carbon atoms .
  • Preferred alkyl-substituted polysiloxanes are amino-functional silicones, such as those described in U. S . patents 3 , 836 ,371, 3 , 508,933, 3,890, 271 and 3 ,960 ,575.
  • the polysiloxanes will generally comprise from about 0.5 to 10 wt. %, more preferably from 0.5 to 5 wt. % and most preferably from 1 to 4 wt. % of the concentrates of the present invention.
  • concentrate formations may contain 0.01 to 40 wt. % or more of water (preferably demineralized) , 0.05 to 10 wt. % water is preferred and 0.1 to 5 wt. % is most preferred.
  • Emulsions will generally contain about 50 to 95 wt. % water , or more , with 70 to 90% being more preferred.
  • the polyoxyethylene derivative or fatty acid partial esters of sorbitol anhydrides of the present invention are preferably sorbitan derivatives and, without detracting from the generality, will be so referred to throughout this application. Without being bound by any theory, it appears that these molecules, having a hydrophlic end which seeks water and a hydrophobic end which seeks oil , tend to balance and couple the formulation into particularly stable emulsions . It is particularly surprising that, in addition, these sorbintan derivatives provide increased corrosion protective performance.
  • Preferred are the long chain polyfunctional organic compounds e .g. sorbitan monooleate , sorbitan trioleate, myristates with hydroxoy or amine polyfunctionality.
  • organic acids which are a preferred but optional ingredient to the inventions of the present invention are preferably 12 to 54 carbon atoms , more preferably 14 to 20 and most preferably 18 (stearic) or isostearic and derivatives thereof .
  • isostearic acid which is liquid at room temperature.
  • the organic acid may possibly somehow react with the amino functional polysiloxane ingredient of the compositions , but the function of the organic acid is not entirely clear. It is known that the addition of organic acid will, in most cases , substantially increase the stability of the concentrate and the performance of the resulting coatings .
  • a preferred feature of the present invention is the inclusion in the formulations of organic sulfonates .
  • the preferred organic sulfonates are overbased (i.e. , made with an excess of calcium, barium or other metal carbonate) .
  • the preferred sulfonates are overbased with barium, calcium, potassium or sodium, and have sufficient equivalent weight to provide extended rust protection against corrosive environments .
  • the preferable equivalent weights of these sulfonates which are derived from alkyl benzene, are as follows when overbased with the following metal sulfonates : sodium sulfonate or a equivalent weight preferably 370 to 750 , more preferably 400 to 650 and most preferably 450 to 600; barium sulfonate of a equivalent weight preferably 400 to 1400, more preferably 700 to 1300 , most preferably 800 to 1200 ; and calcium sulfonate of a equivalent weight preferably 370 to 850 , more preferably 400 to 800 , most preferably 500 to 750.
  • a preferred commercial alkali metal sulfonate is Lubrizol 5530 manufactured by Lubrizol Corp . , Cleveland.
  • organic sulfonates of the present invention will generally be employed in quantities of from about 1 to 60%, more preferably from about 5 to about 40% and most preferably from about 5 to about 30% based on the total weight of the formulation .
  • the preferred chain length is from about 10 to 30 , more preferably 12 to 24 and most preferably 16 to 20 carbon atoms .
  • Molecular weights are preferably 10 to 50 , more preferably 15 to 40 and most preferably 20 to 30.
  • the most preferred sorbitan derivative is sorbitan monooleate (molecular weight equals 465) , which is readily available under a number of brand names e. g. "Tweens” 20 through 85 , “Spans” 20 through 85 , “Sorbax” (by Chemax of Greenville , SC) , etc. from various suppliers , Atlas Chemical Division of ICI , Wilmington , DE , e .g. those described in McCutcheon "Emulsifiers and Detergents” , MC Pub . Co . , Glen Rock, NJ .
  • the sorbitan derivatives will generally be used in the formulations of the invention at levels of about 0.1 to 20 wt. %, more preferably 0.5 to 15 and most preferably 1 to 10 weight percent.
  • alkanol amine preferably triethanol amine
  • Optional conventional ingredients might also be added, e . g. pigments , dyes , etc.
  • Surface treatment processes can be conventional such as chromate, and particularly preferred nitriding or phosphating .
  • Phosphating can be accomplished by the conventional techniques such as those set forth in "Practical Phosphate Coatings" , Mangill Company, and U. S . patents 3 ,967,948 , 2,465,247, 3,686,031 , 4,419, 199, 4,539,051 and 4,540,637 and references thereto.
  • preferred phosphating is to a thickness of at least 2000-3000 mg zinc phosphate/square foot of workpiece.
  • Nitriding can be either salt bath or fluidized bed nitriding , such as the commercial processes “Tuff Tride” , “Meionite” , “QPQ” (Quench-Polish-Quench, in which salt bath nitriding is followed b y quench in an oxidizing salt bath, followed by mechanical polishing, and a second quench) , or fluidized bed nitriding as described in "Fluidized Bed Furnace Heat Treating Applications for the Dye Casting Industry” , JAPKA , May- June , 1983 , Dye Casting Engineer .
  • Miscellaneous surface treatment processes which may be employed with the invention include Procedyne's "Dyna-Case Surface Hardening Treatment” , deep case carburization in a fluidized furnace by adding methanol which is vaporized and mixed with nitrogen and a small amount of natural gas to form a synthetic endothermic atmosphere within the treating furnace at about 899-1010°C (1650-1850°F) for 1-8 hours , carbonitriding at 815-871°C (1500-1600°F) for 10 minutes-1 hour, followed by quenching; nitriding by adding nitrogen from raw ammonia onto the surface of the material at 510-593oC (950-1100oF) to provide a case of 0.001-0.015 inches deep ; nitrocarburizing providing a case o f 0.0005-0.0020 inches deep by contacting mixtures of natural gas and raw ammonia in a fluid bed furnace at 566-621°C (1050-1150°F) for 0.5-2 hours ; steam bluing in a fluid
  • the apparatus for the present invention will be that conventionally utilized in the preparation of coatings compositions , e. g. kettles and mixing tanks having flow metering or measuring devices and agitation means , e. g. pumps mounted on side-arms connecting with the main vessel , internal stirrers , contra-rotating shearing devices and any of the other available devices which are well known to the art.
  • Temperature The temperature during mixing may be different during different stages in the formulation. These temperatures are not narrowly critical and will vary to provide faster mixing or better compatability of ingredients according to observation of those skilled in the art.
  • pressure vessels may be utilized for the purpose of lowering ingredient melting and boiling points , where useful, in order to provide better dispersion of difficult-to-mix ingredients .
  • the finished formulation prior to packaging, will generally be checked for viscosity, freeze-thaw stability, corrosion-protection under accelerated conditions and other tests utilizing techniques well known to the coatings industry.
  • the formulations of the present invention may be applied to substrates to be protected by conventional application techniques , such as spraying, brushing, dipping, flow-coating, dipspinning, "Filwhirl” , or airless spraying.
  • Coating thickness can be varied by changing the formulation, the number of coats , or the amount applied per coat but in general will be in the range from about 2 to about 5 mils after drying.
  • Emulsion Preparation The concentrate (e . g . prepared according to Example 1 ) is diluted with 1 to 20 , or more preferably 2 to 15 , and most preferably 3 to 8 parts by weight of water to form the emulsion which is applied to the workpieces . Dilution is preferably about 38°C (100°F) , more preferably above 52°C (125°F) , and most preferably at 52-71°C (125-160°F) .
  • a conventional steam jacketed mixing kettle equipped with rotary stirrer are added 66 parts by weight of naphthanic oil having a viscosity of 100 SSU at 38°C (100°F) and purchased as McMillan and 100 VR which is heated to 54°C (130°F) .
  • To the oil is added 20 parts by weight of emulsifying agent, ALOX 575 purchased from ALOX Corp . , Niagara Falls, 5 parts by weight in the form of butyl cellosolve from Eastman Kodak Company, Rochester, NY, 2 parts by weight sorbitan derivative as sorbitan monooleate purchased from Chemax Corp .
  • the contents of the mixing vessel are then sampled, quality control tests for viscosity , stability and appearance are run and the formulation is draw off into 55 gallon drums. (Water is not added separately because the individual ingredients contain about .5 parts by weight based on the weight of the total formulation of water. )
  • the resulting formulation is tested for corrosion protection by applying it to a ferrous work piece which has been previously phosphated by conventional techniques , by dipping the work piece into an emulsion formed by adding one part by volume of the above formulation with 4 parts by volume of demineralized water. After drying for 24 hours , the test work piece is subjected to a 5% neutral pH salt (NaCl) spray at a temperature of 35°C (95°F) according to ASTB-117. The test panel resists failure (corrosion) for 39 days (936 hours) .
  • NaCl neutral pH salt
  • a sample of emulsion shows no significant separation (i . e. , less than 2% "cream” ) upon standing at room temperature for 24 hours .
  • a work piece as previously described is dipped into the above formulation (diluted) and allowed to dry at room temperature at approximately 50% relative humidity, the coating is cured and cured in 24 hours . But remains self-healing i. e . , scratch made with a scribe heals to protect the metal for about 24 hours .
  • Example 2 When a formulation is prepared according to the techniques of Example 1 and using the same parts by weight except that the sorbitan monooleate stabilizer is omitted, the work piece treated with the diluted formulation in accordance with the techniques of Example 1 survives 38 days (816 hours) in the salt spray before failure, a substantial improvement over the comparative formulation of Example 2, but slightly less than the preferred formulation of Example 1. However, the formulation exhibits substantial separation during a 24 hour room temperature test on the undiluted concentrate.
  • Example 1 When the techniques and tests of Example 1 are repeated but substituting a paraffinic oil for the naphthanic oil employed in Example 1, the resulting formulation survives 44 days (1056 hours) of salt spray test and the formulation is stable in both concentrated and emulsion form. This preferred formulation shows the superiority of the results obtained when paraffinic oil is substituted for naphthanic oil.
  • Example VI When Example VI is repeated, substituting a nitrided workpiece for the phosphated workpiece, 42 days excellent protection is obtained, but the test is terminated before failure.
  • compositions , methods , or embodiments discussed are intended to be only illustrative of the invention disclosed by this Specification. Variation on these compositions , methods , or embodiments are readily apparent to a person of skill in the art based upon the teachings of this specification and are therefore intended to be included as part of the inventions disclosed herein.
  • the formulation may contain biocides, antifoamers , dyes , pigments , etc.

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Laminated Bodies (AREA)

Abstract

On obtient des couches de revêtement auto-protecteur en soumettant les parties ferreuses d'abord à une opération de phosphatation ou de nitruration, puis en les enduisant d'une émulsion constituée par exemple par du polysiloxane, une huile minérale, un dérivé de sorbitane, du sulfonate de sodium, du ''cellosolve'' de butyle et un acide oléique. L'opération de phosphatation préférée s'effectue jusqu'à une épaisseur de 2.000 à 3.000 mg de phosphate de Zn par pied carré. Cette couche de revêtement peut être soumise pendant plus de 240 heures à une vaporisation de sel à 5 % (selon ASTM B-117) et résiste au lavage avec du savon utilisé pour le lavage des voitures.
PCT/US1987/000619 1986-01-13 1987-03-19 Composition de revetement et procede servant a former un film auto-protecteur anti-corrosion Ceased WO1988007069A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP86117532A EP0229349A3 (fr) 1986-01-13 1986-12-17 Composition de revêtement et procédé pour obtenir un film anticorrosion autocicatrisant
PCT/US1987/000619 WO1988007069A1 (fr) 1987-03-19 1987-03-19 Composition de revetement et procede servant a former un film auto-protecteur anti-corrosion
JP62502277A JPH02501832A (ja) 1987-03-19 1987-03-19 被覆組成物及び自己修復性防食フィルムの形成法
BR8707977A BR8707977A (pt) 1987-03-19 1987-03-19 Composicao a base de oleo,emulsao de oleo em agua,processo para fabricacao de composicao,processo para propiciar superficie anti-corrosiva,composicao de revestimento e processo para revestir pecas de metal a trabalhar
AU72336/87A AU616378B2 (en) 1987-03-19 1987-03-19 Coating composition and method for forming a self-healing corrosion preventative film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US1987/000619 WO1988007069A1 (fr) 1987-03-19 1987-03-19 Composition de revetement et procede servant a former un film auto-protecteur anti-corrosion

Publications (1)

Publication Number Publication Date
WO1988007069A1 true WO1988007069A1 (fr) 1988-09-22

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1987/000619 Ceased WO1988007069A1 (fr) 1986-01-13 1987-03-19 Composition de revetement et procede servant a former un film auto-protecteur anti-corrosion

Country Status (4)

Country Link
JP (1) JPH02501832A (fr)
AU (1) AU616378B2 (fr)
BR (1) BR8707977A (fr)
WO (1) WO1988007069A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110240847A (zh) * 2019-05-20 2019-09-17 北京科技大学 一种热响应高分子自修复涂层及其制备方法
WO2020035113A1 (fr) * 2018-08-17 2020-02-20 Saarstahl Ag Procédé de fabrication d'un fil phosphaté recouvert d'un moyen de protection contre la corrosion, en particulier d'un fil d'acier
US10995236B2 (en) 2015-10-28 2021-05-04 Swimc Llc Polyurethane coating composition

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2023147923A (ja) * 2022-03-30 2023-10-13 古河電気工業株式会社 端子付き絶縁電線および金属表面コーティング用組成物
JP2023147924A (ja) * 2022-03-30 2023-10-13 古河電気工業株式会社 端子付き絶縁電線および金属表面コーティング用組成物

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0093388A2 (fr) * 1982-05-03 1983-11-09 Ashland Oil, Inc. Compositions aqueuses pour revêtement doux et procédé pour les préparer
US4440582A (en) * 1982-04-15 1984-04-03 Saran Protective Coating Company Protective coating composition and method of use therefor
EP0200916A2 (fr) * 1985-04-02 1986-11-12 Dow Corning Corporation Procédé d'émulsification et émulsions ainsi obtenues

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4440582A (en) * 1982-04-15 1984-04-03 Saran Protective Coating Company Protective coating composition and method of use therefor
EP0093388A2 (fr) * 1982-05-03 1983-11-09 Ashland Oil, Inc. Compositions aqueuses pour revêtement doux et procédé pour les préparer
EP0200916A2 (fr) * 1985-04-02 1986-11-12 Dow Corning Corporation Procédé d'émulsification et émulsions ainsi obtenues

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10995236B2 (en) 2015-10-28 2021-05-04 Swimc Llc Polyurethane coating composition
WO2020035113A1 (fr) * 2018-08-17 2020-02-20 Saarstahl Ag Procédé de fabrication d'un fil phosphaté recouvert d'un moyen de protection contre la corrosion, en particulier d'un fil d'acier
DE102018120137A1 (de) * 2018-08-17 2020-02-20 Saarstahl Ag Verfahren zur Herstellung eines phosphatierten, mit einem Korrosionsschutzmittel belegten metallischen Körpers, insbesondere eines Drahts
CN110240847A (zh) * 2019-05-20 2019-09-17 北京科技大学 一种热响应高分子自修复涂层及其制备方法
CN110240847B (zh) * 2019-05-20 2020-06-26 北京科技大学 一种热响应高分子自修复涂层及其制备方法

Also Published As

Publication number Publication date
AU7233687A (en) 1988-10-10
BR8707977A (pt) 1990-03-20
JPH02501832A (ja) 1990-06-21
AU616378B2 (en) 1991-10-31

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