WO1985004069A1 - Heat treatment with an autoregulating heater - Google Patents
Heat treatment with an autoregulating heater Download PDFInfo
- Publication number
- WO1985004069A1 WO1985004069A1 PCT/US1985/000368 US8500368W WO8504069A1 WO 1985004069 A1 WO1985004069 A1 WO 1985004069A1 US 8500368 W US8500368 W US 8500368W WO 8504069 A1 WO8504069 A1 WO 8504069A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- article
- temperature
- layer
- magnetic material
- heat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D11/00—Process control or regulation for heat treatments
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/34—Methods of heating
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/08—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for tubular bodies or pipes
Definitions
- heat treatment In the field of metallurgy, heat treatment is employed to achieve numerous results. In a broad sense heat treatment includes any thermal treatment intended to control properties. With respect to metal alloys, such as steel, tempering and annealing are particularly well known methods of heat treatment.
- Heat treating to achieve a desired alteration of properties is often times a process that is performed optimally at a specific temperature.
- temperature chambers and complex heater/thermostat arrangements are generally employed.
- heat treating is performed " before an article is sent to the field—the properties of the arti ⁇ cle being defined at the mill, factory, or other producing facility.
- it may be deemed desirable to effectuate changes in the metallurgical properties of the article in the field, or in situ, without the need for a temperature chamber, oven or heater-thermostat arrangement.
- an article of metal can be heat treated to effectuate property changes therein in the field by an autoregulating heater.
- the autoregulating heater is disposed along the portions of the article to be heat treated, thereby achieving the object of local heat treating.
- the autoregulating heater includes at least a first magnetic material which changes sharply in skin depth between temperatures below and above an auto- . regulating temperature (AR).
- AR auto- . regulating temperature
- the AR temperature is closely related to and determined by the Curie tempera ⁇ ture.
- the changing skin depth results in corresponding variations in the level of heat produced in response to an a.c. current being applied to the first magnetic material.
- the heat generated is inversely related to the temperature of the heater.
- the inverse relationship between the temperature of the heater and the heat generated thereby renders the heater autoregulating or self-regulating.
- an object of the invention to generate autoregulating heat in at least one magnetic layer of an autoregulating heater, wherein the magnetic layer has an AR temperature substantially corresponding to the temperature at which heat treatment—such as tempering or annealing—is to be conducted. It is yet another object to provide an auto ⁇ regulating heater along an article to be heat treated, wherein the heater has at least two thermally conductive layers—one comprising a magnetic layer and another cora- prising a low resistance nonmagnetic layer—wherein the magnetic layer has an AR temperature which substantially corresponds to the desired temperature for heat treatment of the article. According to this embodiment, a.c.
- a plurality of mag ⁇ netic layers are provided in an autoregulating heater that is disposed along and transfers heat to an article in the field that is to be heat treated.
- a.c. current can be selectively applied to the magnetic layers so that regulation at different AR temperatures—corresponding to the different magnetic layers—can be achieved.
- an article may be heat treated at any of the several temperatures.
- heat treating such as tempering
- Interposing a low resistance non-magnetic layer between and in contact with two magnetic layers may also be employed in the auto ⁇ regulating heater to enable selectable temperature regula ⁇ tion in heat treating an article in the field.
- the article-heater may be installed and, as required, the heater may be actuated by connecting a.c. current thereto to effectuate heat treatment in the field.
- the heater may be fixedly imbedded in the article or may, alternatively, be integrally formed along the article.
- the pipe itself may comprise a magnetic layer of the auto ⁇ regulating heater.
- the invention contemplates relieving stress in articles or portions thereof which have been over-hardened in the field or which have been rendered brittle due to exposure to radiation or which have been heavily work hardened due to machining or which have undergone fatigue cycling while in the field which might lead to fracture or failure.
- the invention contemplates heat treating tooled steel in the field and surface treating an article by nitriding or carborizing at a proper heat treating temperature.
- Figure I is an illustration of pipe being heat treated in situ by an autoregulating heater in accordance with the invention.
- Figures II and III are cross-section views of two alternative types of autoregulating heaters.
- Figure IV is a front perspective view of an embodiment of the invention that is illustrated in Figure III.
- Figure V is a view illustrating an embodiment of the invention wherein a spring is heat treated to optimize its end-use properties.
- Figure VI is an illustration of an autoregu ⁇ lating heater and article to be heat treated integrally incorporated into a single crimp element.
- Figure VII is a front perspective view of a three-layer pipe which is both the article to be heat treated and an autoregulating heater, which selectively controls the temperature of heat treatment.
- a metal pipe section 100 is shown coupled between two other pipe sections 102 and 104.
- the pipe section 100 is located along a pipeline 106 which, preferably, carries a fluid—such as oil or gas.
- a fluid such as oil or gas.
- the pipe section 100 is often times exposed to numerous conditions that may adversely affect the structure and properties thereof. For example, thermal changes may result in stressing the pipe section 100.
- welds along the pipe section 100 may require stress relief after field welding.
- an autoregulating heater 110 for heat treating the pipe section 100 in the field (in situ) is provided.
- the autoregulating heater 110 may be of various forms—in each case the autoregulating heater 110 (a) being disposed along the pipe section 100 (or other workpiece) in the field along a length that is to be heat treated and (b) regulating at a temperature appropriate to heat treat the section 100 in the field.
- the autoregulating heater 100 is of a nature which permits the maintaining of a uniform temperature locally along the length L of the pipe section 100 to be heat treated.
- an a.c. current source 112 is shown.
- the source 112 provides a "constant" current which, preferably, is at a selected fixed frequency.
- the current is applied to enable the current to flow through a heating structure 114.
- heating structure 114 Several embodiments of heating structure 114 are illustrated in Figures II and III.
- the pipe section 200 is shown emcompassed by a single magnetic layex 202.
- the magnetic layer 202 has a clamp member 204 which enables the magnetic layer 202 to be wrapped and held around the pipe section , 200 in the field.
- the mag ⁇ netic layer 202 has a prescribed resistivity (p) and a permeability ( ) which varies sharply—at points above and below an autoregulation (AR) temperature.
- the AR tempera ⁇ ture is typically a few degrees lower than the conven ⁇ tionally defined—Curie temperature of the magnetic layer 200.
- a sample table of magnetic materials is set forth below.
- the permeability ( ) of the magnetic layer 202 corresponds substantially to the effective permeability well below the AR temperature and approxi ⁇ mately one above the AR temperature.
- This variation in permeability with temperature results in a corresponding change in skin depth, where skin depth is proportional to !/ u f ⁇ * ⁇ ⁇ at is- s temperature increases to above the AR temperature, the permeability falls to one from, for example, 400 which results in the skin depth increasing by a factor of 20.
- the increase in skin depth results in an increase in the cross-section through which a.c. current is primarily confined. In this regard, it is noted that a.c.
- a.c. current is applied to the magnetic layer 202 the current is confined to a shallow depth about the outer periphery thereof when the temperature of the magnetic layer 202 is below the AR temperature thereof. As the temperature increases and exceeds the AR tempera ⁇ ture, the skin depth spreads to deeper thicknesses and current thereby flows through a larger cross-section. The heat generated is thereby reduced.
- the magnetic layer 202 is thermally conductive, the heat generated thereby when the skin depth is shallow is transferred to the pipe section 200.
- each portion of the magnetic layer 202 since each portion of the magnetic layer 202 generates heat in response to its temperature, the heat is distributed so that greater heat is supplied to colder areas and less heat is supplied to warmer areas. Thus, heat from the magnetic layer 202 serves to raise the temperature of the length L (see Figure I) to a uniform level.
- the uniform level substantially corresponds to the AR temperature of the magnetic layer 202 and the temperature at which the desired heat treatment ' of the length L is effectuated.
- the AR temperature of the first magnetic layer 202 is selectable to correspond to the tempering temperature or the annealing temperature of- the pipe section 100.
- auto- regulation'temperatures—near the Curie points—as high as 1120°C (the Curie temperature of Cobalt) are readily achievable by proper selection of magnetic alloy for the magnetic layer 202.
- the heat treatment of steel and other metals are readily achievable by proper selection of magnetic alloy for the magnetic layer 202.
- the source 112 may be selectively switched on and off to provide the desired heat treatment period.
- the heater or heater/article may have plug or contact elements to which the source 112 can be selectively connected or disconnected as desired.
- the source 112 is connected to the pipe section 100 and the magnetic layer 110.
- the pipe section 100 may be a low resistance non-magnetic material.
- the resistance R thereby drops sharply and little I R heat is produced. If needed, a circuit (not shown) may be provided to protect the source 112.
- the magnetic layer may be provided to protect the source 112.
- the magnetic layer 110 has a thickness defined to enable current to spread into pipe section 100 when temperatures rise above the Curie temperature.
- the magnetic layer is 1.0 to 1.8 skin depths (at the effective permeability) in thickness although other thicknesses may be employed.
- the source li2 would be connected directly across the magnetic layer 110 which, as desired, may include coupling elements (not shown) for receiving leads from the source 112.
- pipe section 300 is encircled by a heater 301 that includes a low resistance layer 302 (e.g. copper) which is encircled by magnetic layer 304.
- the layers 302 and 304 are in contact with each other and are each thermally conductive.
- An a.c. current is applied to the heater 301, the current being primarily confined to a shallow depth below the AR temperature and the current spreading to flow along the low resistance path above the AR temperature.
- the pipe section 300 has heat supplied thereto by the autoregu- . lating heater 301 to portions of the pipe section 300 in contact therewith.
- Figure IV shows the connection of substantially constant a.c. current to an autoregulating heater 400 which is similar to heater 301.
- a source 402 supplies a.c.
- the inner layer 406 comprises a low resistance, non-magnetic layer 406 which encompasses a solid article 408—such as a pipe, strut, girder, or the like.
- a solid article 408 such as a pipe, strut, girder, or the like.
- the a.c. current spreads through the layer 404, which preferably has a thickness of several skin depths when the layer 406 is at its effective permeability, and into the layer 406 resulting in. less I 2R heat.
- a connection of a.c. to the embodiment of Figure II may be made in a manner similar to that shown in Figure IV.
- the heater of Figure II may also encircle a solid article—rather than the hollow article shown therein—to achieve the heat treatment thereof.
- Such heat treatment includes tempering, annealing, strengthening, increasing ductility, relieving stress, or otherwise affecting the metallurgical properties of a metal member.
- the heat treatment may be effected during. assembly, repair, or servicing of the metal member to obtain, retain, or regain desired properties.
- a spring 500 comprises a Beryllium-copper layer 502 and a magnetic alloy layer 504.
- the Beryllium-copper layer 502 in a soft and ductile condition may be formed and fit to be placed in a desired location.
- the magnetic alloy layer 504 has a.c. current supplied thereto by a source 506—which results in the heater 500 initially increasing in temperature.
- the temperature is regulated at the Curie temperature of the layer 504.
- the regulated temperature substantially corresponds to the temperature at which the Beryllium-copper layer 502 hardens to a strong, spring-temper condition. This heat treating is preferably conducted for several minutes at about 400 ⁇ C.
- a power cable 600 is terminated at a terminal bus 602 by a clamp ring 604.
- the ring 604 is initially soft, to crimp and conform well to form the termination.
- the ring 604 comprises a magnetic alloy (see table above) which has an a.c. current applied thereto.
- the ring 604 autoregulates at the AR temperature thereof and hardens to achieve the desired end-use functionality.
- the crimp 604 represents both the article to be heat treated and the heater.
- the invention described therein is not limited to embodiments in which a heater is wrapped around an article in the field.
- the invention also extends to embodiments wherein the heater and article are incorpo ⁇ rated as a single structure. That is, the article to be heated may itself comprise a magnetic material which auto- regulates its own temperature.
- the article may include plural layer embodiments where, for example, a pipe as in Figure I, may include a magnetic layer and a non-magnetic layer concentric and disposed against the magnetic layer. Such an embodiment operates like the layers 302 and 304 of Figure III.
- the pipe may comprise two magnetic layers with a non-magnetic layer interposed therebetween.
- FIG. VII shows a three layer pipe 700 including two concentric magnetic layers 702, 704 with a non-magnetic layer 706 therebetween.
- a "constant" a.c. source 708 is switchably connectable so that current flows along either the outer surface or inner surface of the pipe 700 when below the AR temperature of layer 702 or of layer 704 respectively.
- the pipe 700 comprises both the article to be heat treated and the heater disposed therealong.
- heat treatment may be performed repeatedly as required by simply connecting the a.c. source and applying current to the heater.
- the invention contemplates heating a metal by any of the various mechanisms discussed above and flushing the heated metal in the field with a gas to effectuate nitriding or carborizing.
- Carborizing and nitriding are known forms of surface-treating which, in accordance with the invention, are performed in the field, when the article is at the autoregulated temperature.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Physics & Mathematics (AREA)
- Heat Treatment Of Articles (AREA)
- General Induction Heating (AREA)
- Control Of Resistance Heating (AREA)
- Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)
- Soft Magnetic Materials (AREA)
- Control Of Heat Treatment Processes (AREA)
- Processing Of Meat And Fish (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Abstract
Apparatus and process for selectively heat treating at least a portion of an article in the field with autoregulated heating. The autoregulated heating is provided by heater (110) including at least a first magnetic material (202) disposed along the portion of the article (100) to be head treated. The first magnetic material (202) has a magnetic permeability which sharply changes at temperatures at or near the autoregulating (AR) temperature thereof. The changes in permeability result in corresponding changes in the skin depth of the first magnetic material (202) and, hence, the heating produced therein responsive to a.c. current passing therethrough. By maintaining the a.c. current constant in amplitude and frequency, the first magnetic material (202) and the portion of the article (100) are regulated at substantially the AR temperature of the first magnetic material. By selecting the first magnetic material (202) to have AR temperature substantially corresponding to the temperature at which metal anneals, tempers, hardens, softens stress relieves or the like, heat treating at an autoregulated temperature is achieved. The autoregulated heater can be incorporated into the article or can be applied to the article (100) thereafter, in each case permitting in field heat treating. Autoregulated heating can also be achieved by any of various multilayer structures to provide desired autoregulation effects.
Description
HEAT TREATMENT WITH AN AUTOREGULATING HEATER
BACKGROUND OF THE INVENTION
In the field of metallurgy, heat treatment is employed to achieve numerous results. In a broad sense heat treatment includes any thermal treatment intended to control properties. With respect to metal alloys, such as steel, tempering and annealing are particularly well known methods of heat treatment.
Heat treating to achieve a desired alteration of properties is often times a process that is performed optimally at a specific temperature. In order to maintain control over temperature during such heat treatment, temperature chambers and complex heater/thermostat arrangements are generally employed. Typically, heat treating is performed "before an article is sent to the field—the properties of the arti¬ cle being defined at the mill, factory, or other producing facility. However, at the time of installation of the article or after the article has been in use for a period of time, it may be deemed desirable to effectuate changes in the metallurgical properties of the article in the field, or in situ, without the need for a temperature chamber, oven or heater-thermostat arrangement. For example, where a pipe section along a pipline is subject to cold temperatures and attendant degradation of proper¬ ties, it is often desirable to service the pipe section by heat treatment in the field without the need for removing the section. Similarly, when stress, fatigue, or tempera¬ ture adversely affect a section of pipe along a pipeline or a strut along a bridge or the like, heat treatment in the field is often desirable. In addition, steels exposed to heavy neutron irradiation are generally embrittled. Stress relief in situ is again often of great value. In these and other situations, it is often found that only portions of an article require heat treat¬ ment and that, in fact, the heat treatment should be confined to only those portions and that those portions be
heated to a uniform temperature. That is, it may be that only part of an article is to be hardened, softened, strengthened, stress-relieved, tempered,. annealed, or otherwise treated—in which case it is desired that heat treating be localized.
SUMMARY OF THE INVENTION
In accordance with the invention, apparatus and process are provided wherein an article of metal can be heat treated to effectuate property changes therein in the field by an autoregulating heater. The autoregulating heater is disposed along the portions of the article to be heat treated, thereby achieving the object of local heat treating.
Moreover, the autoregulating heater includes at least a first magnetic material which changes sharply in skin depth between temperatures below and above an auto-. regulating temperature (AR). The AR temperature is closely related to and determined by the Curie tempera¬ ture. The changing skin depth results in corresponding variations in the level of heat produced in response to an a.c. current being applied to the first magnetic material. Accordingly, as discussed in U.S. Patent 4,256,945 to Carter and Krumme, and entitled "AUTOREGULATING HEATER" which is incorporated herein by reference, the heat generated is inversely related to the temperature of the heater. The inverse relationship between the temperature of the heater and the heat generated thereby renders the heater autoregulating or self-regulating. Hence, it is an object of the invention to heat treat a metal article in the field to a temperature determined by an autoregulating heater.
Furthermore, it -is an object of the invention to generate autoregulating heat in at least one magnetic layer of an autoregulating heater, wherein the magnetic layer has an AR temperature substantially corresponding to the temperature at which heat treatment—such as tempering or annealing—is to be conducted.
It is yet another object to provide an auto¬ regulating heater along an article to be heat treated, wherein the heater has at least two thermally conductive layers—one comprising a magnetic layer and another cora- prising a low resistance nonmagnetic layer—wherein the magnetic layer has an AR temperature which substantially corresponds to the desired temperature for heat treatment of the article. According to this embodiment, a.c. current flows primarily through a shallow depth of the magnetic layer below the AR temperature and into the low resistance non-magnetic layer above the AR temperature, thereby greatly reducing heat generation at temperatures above the AR temperature. Autoregulation at a temperature substantially corresponding to the desired heat treatment temperature is achieved at generally several degrees less than the Curie point of the magnetic layer. Moreover, by properly defining the thickness of the low resistance non¬ magnetic layer a shielding effect is achieved for applica¬ tions in which the generation of signals outside the heater is not desired.
In a further embodiment, a plurality of mag¬ netic layers are provided in an autoregulating heater that is disposed along and transfers heat to an article in the field that is to be heat treated. In accordance with this embodiment, a.c. current can be selectively applied to the magnetic layers so that regulation at different AR temperatures—corresponding to the different magnetic layers—can be achieved. In this way, an article may be heat treated at any of the several temperatures. Where heat treating, such as tempering, may include a plurality of stages—each characterized by given temperature and time specifications—this embodiment enables selected regulation at selectable temperatures. Interposing a low resistance non-magnetic layer between and in contact with two magnetic layers may also be employed in the auto¬ regulating heater to enable selectable temperature regula¬ tion in heat treating an article in the field.
It is yet another object of the invention to incorporate any one of the autoregulating heaters set forth above into the article or portion thereof that is to
be heat treated. The article-heater may be installed and, as required, the heater may be actuated by connecting a.c. current thereto to effectuate heat treatment in the field. In this regard, the heater may be fixedly imbedded in the article or may, alternatively, be integrally formed along the article. In the case of a steel pipe for example, the pipe itself may comprise a magnetic layer of the auto¬ regulating heater.
It is still yet another object of the invention to provide a process whereby an autoregulating heater may be wrapped about a selected portion of a metal article in the field and the heater autoregulates at a corresponding AR temperature of a magnetic layer thereof—the magnetic layer being selected to have an AR temperature sub- stantially corresponding to the desired heat treating temperature.
It is thus a major object of the invention to provide efficient, practical heat treatment without requiring an oven, furnace, or complex heater/thermostat in a controlled atmosphere and heat treatment that is conveniently performed in the field.
Finally, it is an object of the invention to provide autoregulated heating of an article to obtain, retain, and/or regain desired metallurgical properties therein by heat treating to harden, soften, relieve stress, temper, anneal, strengthen, or otherwise render the metallurgical properties of the article more appropriate for its function or end use. For example, the invention contemplates relieving stress in articles or portions thereof which have been over-hardened in the field or which have been rendered brittle due to exposure to radiation or which have been heavily work hardened due to machining or which have undergone fatigue cycling while in the field which might lead to fracture or failure. And, the invention contemplates heat treating tooled steel in the field and surface treating an article by nitriding or carborizing at a proper heat treating temperature.
BRIEF DESCRIPTION OF THE DRAWINGS
Figure I is an illustration of pipe being heat treated in situ by an autoregulating heater in accordance with the invention. Figures II and III are cross-section views of two alternative types of autoregulating heaters.
Figure IV is a front perspective view of an embodiment of the invention that is illustrated in Figure III. Figure V is a view illustrating an embodiment of the invention wherein a spring is heat treated to optimize its end-use properties.
Figure VI is an illustration of an autoregu¬ lating heater and article to be heat treated integrally incorporated into a single crimp element.
Figure VII is a front perspective view of a three-layer pipe which is both the article to be heat treated and an autoregulating heater, which selectively controls the temperature of heat treatment.
DESCRIPTION OF THE INVENTION
Referring to Figure I, a metal pipe section 100 is shown coupled between two other pipe sections 102 and 104. The pipe section 100 is located along a pipeline 106 which, preferably, carries a fluid—such as oil or gas. When so employed, the pipe section 100 is often times exposed to numerous conditions that may adversely affect the structure and properties thereof. For example, thermal changes may result in stressing the pipe section 100. In addition, welds along the pipe section 100 may require stress relief after field welding. ' To relieve such stess or otherwise enhance the metallurgical properties of the pipe section 100, an autoregulating heater 110 for heat treating the pipe section 100 in the field (in situ) is provided. In this regard, it must be realized that accurate heat treating control is important to avoid overheating or underheating which seriously
detracts from the heat treatment. As discussed below, the autoregulating heater 110 may be of various forms—in each case the autoregulating heater 110 (a) being disposed along the pipe section 100 (or other workpiece) in the field along a length that is to be heat treated and (b) regulating at a temperature appropriate to heat treat the section 100 in the field. Moreover, the autoregulating heater 100 is of a nature which permits the maintaining of a uniform temperature locally along the length L of the pipe section 100 to be heat treated.
Referring still to Figure I, an a.c. current source 112 is shown. The source 112 provides a "constant" current which, preferably, is at a selected fixed frequency. The current is applied to enable the current to flow through a heating structure 114.
Several embodiments of heating structure 114 are illustrated in Figures II and III. In Figure II, the pipe section 200 is shown emcompassed by a single magnetic layex 202. The magnetic layer 202 has a clamp member 204 which enables the magnetic layer 202 to be wrapped and held around the pipe section, 200 in the field. The mag¬ netic layer 202 has a prescribed resistivity (p) and a permeability ( ) which varies sharply—at points above and below an autoregulation (AR) temperature. The AR tempera¬ ture is typically a few degrees lower than the conven¬ tionally defined—Curie temperature of the magnetic layer 200. A sample table of magnetic materials is set forth below.
TABLE
EFFECTIVE
MATERIAL . CURIE POINT P (Ω-cm) PERMEABILITY
30% Ni Bal Fe 100βC """""" 80 X 10 -6 100-300
36% Ni Bal Fe 279βC 82 X 10-6 -
42% Ni Bal Fe 325°C 71 X 10-6 200-600
46% Ni Bal Fe • 460°C 46 X 10-6 4-
52% Ni Bal Fe 565°C 43 X 10-6 +
80% Ni Bal Fe 460βC 58 X 10-6 400-1000
Kovar 435βC * 49 X 10 ,'-6
As is well known, the permeability ( ) of the magnetic layer 202 corresponds substantially to the effective permeability well below the AR temperature and approxi¬ mately one above the AR temperature. This variation in permeability with temperature results in a corresponding change in skin depth, where skin depth is proportional to!/ uf~ * τ^at is- s temperature increases to above the AR temperature, the permeability falls to one from, for example, 400 which results in the skin depth increasing by a factor of 20. The increase in skin depth, in turn, results in an increase in the cross-section through which a.c. current is primarily confined. In this regard, it is noted that a.c. current distribution relative to depth in a magnetic material is an exponential function, namely current falls off at the rate of l-ett/S.D. where t is thickness and S.D. is skin depth. Accordingly, 63.2% of the current is confined to one skin depth. That is, where I*-R is the heat generated and where I is considered relatively "constant", changes in R primarily determine changes in heat generation. Hence, as the temperature of the magnetic layer 202 increases above the AR temperature, the I heat generated drops. Conversely, as the tempera- ture drops below the AR temperature, the IΛR heat increases in accordance with skin depth changes. This effect is what characterizes a heater as autoregulating or self-regulating.
It should be noted that according to the invention a current is considered "constant" if the change in current (ΔI) and change in resistance (ΔR) follow the relationship:
Still referring to Figure II, it is noted then that as "constant" a.c. current is applied to the magnetic layer 202 the current is confined to a shallow depth about the outer periphery thereof when the temperature of the magnetic layer 202 is below the AR temperature thereof. As the temperature increases and exceeds the AR tempera¬ ture, the skin depth spreads to deeper thicknesses and
current thereby flows through a larger cross-section. The heat generated is thereby reduced.
In that the magnetic layer 202 is thermally conductive, the heat generated thereby when the skin depth is shallow is transferred to the pipe section 200.
Moreover, since each portion of the magnetic layer 202 generates heat in response to its temperature, the heat is distributed so that greater heat is supplied to colder areas and less heat is supplied to warmer areas. Thus, heat from the magnetic layer 202 serves to raise the temperature of the length L (see Figure I) to a uniform level. In accordance with the invention as embodied in Figure II, the uniform level substantially corresponds to the AR temperature of the magnetic layer 202 and the temperature at which the desired heat treatment 'of the length L is effectuated.
Specifically, the AR temperature of the first magnetic layer 202 is selectable to correspond to the tempering temperature or the annealing temperature of- the pipe section 100. In this regard it is noted that auto- regulation'temperatures—near the Curie points—as high as 1120°C (the Curie temperature of Cobalt) are readily achievable by proper selection of magnetic alloy for the magnetic layer 202. The heat treatment of steel and other metals
(e.g. alloys) from which the pipe section 100 can be made is typically performed at temperatures below the autoregulation upper limits. Accordingly, the proper selection of an alloy wherein AR temperature- substantially corresponds to the desired heat treatment temperature can be made.
Where heat treating is normally conducted for a given period of time, it is further noted that the source 112 may be selectively switched on and off to provide the desired heat treatment period. Alternatively, the heater (or heater/article) may have plug or contact elements to which the source 112 can be selectively connected or disconnected as desired.
Referring again to Figure I, it is observed that the source 112 is connected to the pipe section 100
and the magnetic layer 110. In this embodiment the pipe section 100 may be a low resistance non-magnetic material.
As the skin depth of the magnetic layer 110 increases, current will eventually spread to the pipe section 100.
_ The resistance R thereby drops sharply and little I R heat is produced. If needed, a circuit (not shown) may be provided to protect the source 112. The magnetic layer
110, it is noted, has a thickness defined to enable current to spread into pipe section 100 when temperatures rise above the Curie temperature. Preferably the magnetic layer is 1.0 to 1.8 skin depths (at the effective permeability) in thickness although other thicknesses may be employed.
Still referring to Figure I, if the pipe. section 100 is not of a low resistance material, the source li2 would be connected directly across the magnetic layer 110 which, as desired, may include coupling elements (not shown) for receiving leads from the source 112.
Turning now to Figure III, pipe section 300 is encircled by a heater 301 that includes a low resistance layer 302 (e.g. copper) which is encircled by magnetic layer 304. The layers 302 and 304 are in contact with each other and are each thermally conductive. An a.c. current is applied to the heater 301, the current being primarily confined to a shallow depth below the AR temperature and the current spreading to flow along the low resistance path above the AR temperature. The pipe section 300 has heat supplied thereto by the autoregu- . lating heater 301 to portions of the pipe section 300 in contact therewith. Figure IV shows the connection of substantially constant a.c. current to an autoregulating heater 400 which is similar to heater 301. A source 402 supplies a.c. current which is initially confined to the outer skin of an outer magnetic layer 404. The inner layer 406 comprises a low resistance, non-magnetic layer 406 which encompasses a solid article 408—such as a pipe, strut, girder, or the like. When the magnetic layer 404 is below its AR temperature— hich is typically several degrees below the Curie point—considerable heat is generated
therein. As the temperature climbs to the AR temperature, a.c. current penetrates into the low resistance layer 406 resulting in a decrease in generated heat. That is, as is known in the art, the a.c. current flows mainly along the outer surface of layer 404—the surface adjacent the cir¬ cuit loo —when the temperature is below the AR tempera¬ ture. When the temperature reaches the AR temperature, the a.c. current spreads through the layer 404, which preferably has a thickness of several skin depths when the layer 406 is at its effective permeability, and into the layer 406 resulting in. less I 2R heat.
A connection of a.c. to the embodiment of Figure II may be made in a manner similar to that shown in Figure IV. Moreover, the heater of Figure II may also encircle a solid article—rather than the hollow article shown therein—to achieve the heat treatment thereof. Such heat treatment includes tempering, annealing, strengthening, increasing ductility, relieving stress, or otherwise affecting the metallurgical properties of a metal member. The heat treatment may be effected during. assembly, repair, or servicing of the metal member to obtain, retain, or regain desired properties.
Referring now to Figure V, a spring 500 comprises a Beryllium-copper layer 502 and a magnetic alloy layer 504. The Beryllium-copper layer 502 in a soft and ductile condition may be formed and fit to be placed in a desired location. After placement, the magnetic alloy layer 504 has a.c. current supplied thereto by a source 506—which results in the heater 500 initially increasing in temperature. The temperature is regulated at the Curie temperature of the layer 504. The regulated temperature substantially corresponds to the temperature at which the Beryllium-copper layer 502 hardens to a strong, spring-temper condition. This heat treating is preferably conducted for several minutes at about 400βC. Other alloys, such as aluminum and magnesium alloys may also be hardened by such short, low temperature treating. Due to their high inherent conductivity, fabricating such alloys into the heater is contemplated by the invention.
In addition to the hardening, it is noted that alloys may soften if heated too hot or too long. Accordingly, the invention contemplates softening as well in situ. Referring next to Figure VI, a power cable 600 is terminated at a terminal bus 602 by a clamp ring 604. The ring 604 is initially soft, to crimp and conform well to form the termination. The ring 604 comprises a magnetic alloy (see table above) which has an a.c. current applied thereto. The ring 604 autoregulates at the AR temperature thereof and hardens to achieve the desired end-use functionality. The crimp 604 represents both the article to be heat treated and the heater.
In reviewing Figures I through IV, it should be noted that the invention described therein is not limited to embodiments in which a heater is wrapped around an article in the field. The invention also extends to embodiments wherein the heater and article are incorpo¬ rated as a single structure. That is, the article to be heated may itself comprise a magnetic material which auto- regulates its own temperature. Moreover, the article may include plural layer embodiments where, for example, a pipe as in Figure I, may include a magnetic layer and a non-magnetic layer concentric and disposed against the magnetic layer. Such an embodiment operates like the layers 302 and 304 of Figure III. Similarly, the pipe may comprise two magnetic layers with a non-magnetic layer interposed therebetween. This embodiment operates like the three layers 404 through 408 of Figure IV, except that the heater 402 is not only disposed along but is also at least part of the article being heat treated. Figure VII shows a three layer pipe 700 including two concentric magnetic layers 702, 704 with a non-magnetic layer 706 therebetween. A "constant" a.c. source 708 is switchably connectable so that current flows along either the outer surface or inner surface of the pipe 700 when below the AR temperature of layer 702 or of layer 704 respectively. The pipe 700 comprises both the article to be heat treated and the heater disposed therealong.
In any of the embodiments, it is further noted, heat treatment may be performed repeatedly as required by simply connecting the a.c. source and applying current to the heater. Moreover, in yet another embodiment of heat treating in the field, the invention contemplates heating a metal by any of the various mechanisms discussed above and flushing the heated metal in the field with a gas to effectuate nitriding or carborizing. Carborizing and nitriding are known forms of surface-treating which, in accordance with the invention, are performed in the field, when the article is at the autoregulated temperature.
Given the above teachings, it is noted that the insulation and circuit protection may be included in the various embodiments by one of skill in the art. Other improvements, modifications and embodiments will become apparent to one of ordinary skill in the art upon review of this disclosure. Such improvements, modifications and embodiments are considered to be within the scope of this invention as defined by the following claims.
Claims
1. A process for altering the metallurgical properties of an article, the process comprising the steps of: generating autoregulated heat by at. least a first magnetic material having an autoregulating (AR) temperature and a magnetic permeability which sharply varies as the temperature of the first magenetic material varies above and below the AR temperature thereof, the heat generating step including the step of: applying an a.c. current of at least substantially constant amplitude and frequency to the first magnetic material; and heat treating a portion of the article in situ substantially at the AR temperature of the first magnetic material with the generated autoregulated heat.
2. A process as in claim 1, comprising the further step of: forming the first magnetic material integrally with the portion of the article to be heat treated.
3. A process as in claim 2, wherein said heat treating includes the step of annealing at least a portion of the article.
4. A process as in claim 2 wherein said heat treating includes the step of tempering at least a portion of the article.
5. A process as in claim 1, wherein said heat treating includes the step of annealing at least a portion of the article.
6. A process as in claim 1, wherein said heat treating includes the step of tempering at least a portion of the article.
7. A process as in claim 1 comprising the further step of: forming the first magnetic material as an element separate from the article; and positioning the first magnetic material in heat transfer relationship with the portion of the article to be heated.
8. A process as in claim 7, wherein said heat treating includes the step of annealing at least a portion of the article.
9. A process as in claim 7 comprising the further step of dimensioning the first magnetic material to correspond with the portion of the article to be heat treated.
10. A process for altering the metallurgical properties of a metal article, the process comprising the steps of: uniting the article with an autoregulating heater which is operable in the field to provide autoregulated heat to at least a portion of the article; forming the autoregulating heater to include a first magnetic material having an autoregulating (AR) temperature substantially corresponding to at least a heat treating temperature of the article; and driving the temperature of the heater and the article united therewith to at least approximately the Curie temperature of the first magnetic material, which includes the step of: applying an a.c. current of substantially constant amplitude and frequency to the first magnetic material.
11. A process as in claim 10 wherein the forming step includes the step of selecting a first magnetic material having an effective magnetic permeability which is at least 100 at temperatures below the AR temperaure.
12. A process as in claim 10, wherein the forming step includes the steps of: defining the first magnetic material as a first layer; defining a second layer of material which differs from the first magnetic material; and positioning the first layer and the second layer against each other in electrical contact; wherein current flows mainly through a shallow depth of the first layer when the magnetic permeability thereof greatly exceeds one; and wherein substantial current flows in the second layer when the magnetic permeability of the first layer is substantially one.
13. A process as in claim 11, wherein the forming step further includes the step of: defining the first magnetic material as a first layer; defning a second layer of material which differs from the first magnetic material; and positioning the first layer and the second layer against each other in electrical contact; wherein current flows mainly through a shallow depth of the first layer when the magnetic permeability thereof greatly exceeds one; and wherein substantial current flows in the second layer when the magnetic permeability of the first layer is substantially one.
14. A process as in claim 13, wherein the defining of the second layer includes the step of selecting the second layer to be of low electrical resistance.
15. A process as in claim 13, wherein the defining of the second layer includes the step of selecting the second layer to be a second magnetic material having an AR temperature higher than the AR temperature of the first layer.
16. A process as in claim 10, wherein the driving step is performed in the field.
17. A process as in claim 16, wherein the article and the heater are separate elements; and wherein the uniting step is performed in the field and includes the step of positioning the heater in heat transfer relationship with the portion of the article to be heated.
18. A process as in claim 17, wherein the driving step includes the step of maintaining the temperature of the article to achieve annealing.
19. A process as in claim 17, wherein the driving step includes the step of maintaining the temperature of the article to achieve tempering.
20. A process as in claim 15, comprising the further step of selectively regulating the temperature of the heater and the article to the AR temperature of the first magnetic material or the AR temperature of the second magnetic material.
21. A process as in claim 10, wherein the article is initially in a ductile state; and wherein the process includes the further step of: shaping the metal to a desired configuration prior to said temperature driving step, said temperature driving step serving to strengthen the article.
22. " A process as in claim 10 comprising the further ste .of: surface treating the article in situ after the temperature driving step.
23. A process as in claim 22 wherein the surface treating step comprises the step of: nitriding the article surface.
24. A process as in claim 22 wherein the surface treating step comprises the step of: carborizing the article surface.
25. Apparatus for heat treating in the field at least a portion of a metal article, .the apparatus comprising: an autoregulating heater comprising:
(a) a first layer of a magnetic material having a magnetic permeability which greatly exceeds one when below a first autoregulating (AR) temperature and at least approximates when above the first AR temperature, the first AR temperature substantially corresponding to the temperature at which the portion of the article is heat treated; and
(b) means for passing a.c. current through said first layer; said autoregulating heater being disposed along the portion of the article which is to be heat treated.
26. Apparatus as in claim 25 further comprising: a source of current having a constant amplitude and a constant frequency connected across the points on said first layer.
27. Apparatus as in claim 26, wherein the article is of annealable metal; and wherein the AR temperature of said first layer substantially corresponds to the annealing temperature of the portion of the article that is to be heat treated.
28. Apparatus as in claim 26, wherein the article is of temperable metal; and wherein the AR temperature of said first layer substantially corresponds to the heat tempering tempera¬ ture of the portion of the article that is to be heat treated.
29. Apparatus as in claim 25, wherein said autoregulating heater is integrally incorporated into and along the portion of the article to be heat treated.
30. Apparatus as in claim 25, wherein the article is cylindrical in shape; and wherein said autoregulating heater comprises a strap, which wraps around an annular band of the article and directs heat treating heat thereto.
31. Apparatus as in claim 25, wherein the article is a BertyIlium-copper alloy spring; and
- wherein the AR temperature of said first layer substantially corresponds to a temperature at which the spring achieves enhanced strength properties.
32. Apparatus as in claim 25, wherein the article is a metallic alloy; and wherein the AR temperature of said first layer substantially corresponds to a temperature whereat brittleness of the alloy along the portion of the article to be heat treated is reduced and stress relief therein achieved.
33. Apparatus as in claim 25, wherein the article is a metallic alloy; and wherein the AR temperature of said first layer substantially corresponds to a temperature whereat the alloy softens to enhance the ductility of the alloy along the portion of the article to be heat treated.
34. Apparatus as in claim 26, wherein the autoregulating heater further includes: a second layer laying against said"first layer, said second layer having resistivity and magnetic permeability characteristics which differ from said first layer; said two points on said first layer and said second layer being respectively positioned so that current from said source is confined mainly to a shallow depth of said first layer at temperatures below the AR temperature thereof and so that the skin depth of said first layer exceeds the thickness thereof at temperatures above the AR temperature of said first layer to enable substantial current to flow through said second layer.
35. An article capable of heating itself in the field to a heat treating temperature, the article comprising: an autoregulating heater including: (a) a first layer of a magnetic material having a magnetic permeability which greatly exceeds one when below a first autoregulating (AR) temperature and at least approximates one "when above the first AR temperature, the first AR temperature substantially corresponding to the temperature at which the portion of the article is heat treated; and
(b) means for coupling a source of a.c. current to provide a.c. current flow through said first layer, said coupling means enabling the source to be coupled to said first layer in the field; said autoregulating heater being fixedly incorporated within the .article along the portion thereof which is to be heat treated in the field.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60501327A JPH0656793B2 (en) | 1984-03-06 | 1985-03-06 | Heat treatment device with automatic temperature control heater |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US58671984A | 1984-03-06 | 1984-03-06 | |
| US586,719 | 1984-03-06 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1985004069A1 true WO1985004069A1 (en) | 1985-09-12 |
Family
ID=24346880
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US1985/000368 Ceased WO1985004069A1 (en) | 1984-03-06 | 1985-03-06 | Heat treatment with an autoregulating heater |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0156545B1 (en) |
| JP (1) | JPH0656793B2 (en) |
| AT (1) | ATE56476T1 (en) |
| CA (1) | CA1265419A (en) |
| DE (1) | DE3579605D1 (en) |
| WO (1) | WO1985004069A1 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4814587A (en) * | 1986-06-10 | 1989-03-21 | Metcal, Inc. | High power self-regulating heater |
| JPH0760017B2 (en) * | 1986-07-07 | 1995-06-28 | チッソエンジニアリング株式会社 | Electric fluid heater |
| DE102011009947A1 (en) * | 2011-02-01 | 2012-08-02 | Rwe Technology Gmbh | Process for the heat treatment of welds on power plant components |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2785263A (en) * | 1952-03-28 | 1957-03-12 | Philips Corp | Method for the local heating of metallic work-pieces by inductive hf-heating and hf-inductor |
| US4001054A (en) * | 1974-04-10 | 1977-01-04 | Makepeace Charles E | Process for making metal pipe |
| US4229235A (en) * | 1977-10-25 | 1980-10-21 | Hitachi, Ltd. | Heat-treating method for pipes |
| US4256945A (en) * | 1979-08-31 | 1981-03-17 | Iris Associates | Alternating current electrically resistive heating element having intrinsic temperature control |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4091813A (en) * | 1975-03-14 | 1978-05-30 | Robert F. Shaw | Surgical instrument having self-regulated electrical proximity heating of its cutting edge and method of using the same |
| US4701587A (en) * | 1979-08-31 | 1987-10-20 | Metcal, Inc. | Shielded heating element having intrinsic temperature control |
| EP0073190B1 (en) * | 1981-03-02 | 1990-06-13 | Metcal Inc. | Electrically resistive heating element having temperature control |
-
1985
- 1985-03-05 CA CA000475792A patent/CA1265419A/en not_active Expired - Fee Related
- 1985-03-05 AT AT85301501T patent/ATE56476T1/en not_active IP Right Cessation
- 1985-03-05 DE DE8585301501T patent/DE3579605D1/en not_active Expired - Fee Related
- 1985-03-05 EP EP85301501A patent/EP0156545B1/en not_active Expired - Lifetime
- 1985-03-06 WO PCT/US1985/000368 patent/WO1985004069A1/en not_active Ceased
- 1985-03-06 JP JP60501327A patent/JPH0656793B2/en not_active Expired - Lifetime
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2785263A (en) * | 1952-03-28 | 1957-03-12 | Philips Corp | Method for the local heating of metallic work-pieces by inductive hf-heating and hf-inductor |
| US4001054A (en) * | 1974-04-10 | 1977-01-04 | Makepeace Charles E | Process for making metal pipe |
| US4229235A (en) * | 1977-10-25 | 1980-10-21 | Hitachi, Ltd. | Heat-treating method for pipes |
| US4256945A (en) * | 1979-08-31 | 1981-03-17 | Iris Associates | Alternating current electrically resistive heating element having intrinsic temperature control |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0156545B1 (en) | 1990-09-12 |
| JPS61501355A (en) | 1986-07-03 |
| ATE56476T1 (en) | 1990-09-15 |
| EP0156545A2 (en) | 1985-10-02 |
| EP0156545A3 (en) | 1987-05-13 |
| DE3579605D1 (en) | 1990-10-18 |
| CA1265419A (en) | 1990-02-06 |
| JPH0656793B2 (en) | 1994-07-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4623401A (en) | Heat treatment with an autoregulating heater | |
| US4447690A (en) | Inductive preheating of upset tubing | |
| US20090166353A1 (en) | Controlled Electric Induction Heating of an Electrically Conductive Workpiece in a Solenoidal Coil with Flux Compensators | |
| EP0075010A1 (en) | SHIELDED HEATING ELEMENT WITH INTERNAL TEMPERATURE CONTROL. | |
| EP0258827A1 (en) | A method for connecting a plastic pipe end to a plastic welding sleeve | |
| US5993915A (en) | Fusing thermal spray coating and heat treating base material using infrared heating | |
| US2556243A (en) | Means and method of simultaneous hardening of opposite surfaces of thin metallic members | |
| US4215259A (en) | Surface hardening of metals using electric currents | |
| JP3490342B2 (en) | Clad material for induction heating and method for producing the same | |
| US7256374B2 (en) | Induction heating apparatus for controlling the welding parameter of temperature for heat treating a section of piping | |
| US5428208A (en) | Method of induction case hardening a rack bar | |
| WO1985004069A1 (en) | Heat treatment with an autoregulating heater | |
| US6166360A (en) | Heat treating of metallurgic article with varying aspect ratios | |
| US2364623A (en) | Heat-treating gears and the like | |
| US4948435A (en) | Method for inhibiting stress corrosion cracking | |
| GB2077560A (en) | Hotplate | |
| US5881635A (en) | Enamelled cookware and method of manufacturing it | |
| US4588869A (en) | Method for relieving residual stresses by controlling weld heat input | |
| KR102357035B1 (en) | Method for preheating and heating thick steel for ship using induction heating | |
| US2308995A (en) | Method of electrically heating metallic strip | |
| JP2827089B2 (en) | High frequency heating coil | |
| CA1138535A (en) | Bolt heater | |
| JP3439024B2 (en) | Residual stress reduction method | |
| US5018706A (en) | Apparatus for inhibiting stress corrosion cracking | |
| JPS5852428A (en) | Heat treatment for improving stress of shaft |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| AK | Designated states |
Designated state(s): JP |