WO1981002562A1 - Double walled storage tank provided with an internal shell of plastic material - Google Patents
Double walled storage tank provided with an internal shell of plastic material Download PDFInfo
- Publication number
- WO1981002562A1 WO1981002562A1 PCT/CH1980/000035 CH8000035W WO8102562A1 WO 1981002562 A1 WO1981002562 A1 WO 1981002562A1 CH 8000035 W CH8000035 W CH 8000035W WO 8102562 A1 WO8102562 A1 WO 8102562A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- layer
- internal shell
- polyester
- plastic
- storage tank
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D90/00—Component parts, details or accessories for large containers
- B65D90/48—Arrangements of indicating or measuring devices
- B65D90/50—Arrangements of indicating or measuring devices of leakage-indicating devices
- B65D90/513—Arrangements of indicating or measuring devices of leakage-indicating devices comprising electrically conductive layers in walls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D90/00—Component parts, details or accessories for large containers
- B65D90/02—Wall construction
- B65D90/028—Wall construction hollow-walled, e.g. double-walled with spacers
Definitions
- the inner jacket is made of glass fiber reinforced polyester.
- polyester is not chemically resistant.
- certain amounts of alcohol or methanol have been added to gasoline for several years. Such a mixture can soften and destroy the inner jacket made of polyester.
- the breakdown voltage may increase so much that the test voltage is no longer sufficient to cause an electrical breakdown at the location of a leak.
- a metal container wall is therefore not suitable as a counterelectrode if the plastic jacket is arranged at a distance from the metal container wall in order to achieve a cavity for the above-mentioned purpose. The same problem arises when testing a plastic covering applied to an electrically non-conductive plastic base using the method mentioned.
- the invention now relates to a double-walled storage tank with an inner jacket made of plastic, in which the difficulties mentioned are eliminated in that
- the inner jacket is provided at least on the inside with a cover layer made of a material which is chemically resistant to the action of the stored goods and is not electrically conductive, and that the surface of the inner jacket adjacent to the cover layer is electrically conductive.
- FIG. 1 to 4 of the drawing each show a partial cross section of the wall of a double-walled storage tank, which has an outer jacket 1 made of steel, an inner jacket -2 made of plastic, with spacer cams 3, and one on the inside of the inner jacket 2 Cover layer 4 made of a chemically resistant to the action of the stored goods, electrically non-conductive material.
- the surface of the inner jacket 2 adjoining the corner layer 4 is electrically conductive, so that the top layer 4 can be checked in a known manner for freedom from pores and layer thickness using electrical high voltage and suitable measuring instruments.
- the electrical conductivity on the inner surface on the back of the storage-resistant cover layer 4 can be achieved in various ways.
- the inner jacket 2 which essentially consists, for example, of fiberglass-reinforced polyester, has an electrically conductive plastic layer 5 on the inside, which can be sprayed on or rolled on, for example. Electrically conductive plastic in the form suitable for the processing mentioned is known per se. Then the cover layer 4, which is resistant to stored goods, is applied to the electrically conductive plastic layer 5 with a layer thickness of, for example, 0.5 to 0.7 mm. Suitable epoxy resins are available for a top layer that is resistant to petrol with the addition of alcohol or methanol. The coating of the inner jacket 2 can be carried out both before and after it is installed in the outer tank 1 of the storage tank.
- an electrically conductive plastic is itself used for the inner jacket 2, so that the additional application of a layer (5 in FIG. 1) made of conductive plastic can be omitted.
- layer-by-layer conductive plastic or electrically conductive particles e.g. Incorporate graphite or metal powder or semolina into the non-conductive material of the inner shell 2 on its inner surface.
- the top layer 4, which is stable in storage, is again located above this.
- FIG. 4 A further embodiment for particularly stringent requirements is shown in FIG. 4.
- the inner shell 2 consists of glass-fiber reinforced plastic in the supporting part, e.g. Polyester, and has a storage-resistant cover layer 4 and 7 both on the inside and on the outside. This measure has the advantage that the inner casing 2 cannot be chemically destroyed from the outside by the stored goods in the event of any leaks.
- the surfaces of the inner casing 2 adjoining the cover layers 4 and 7 can be made electrically conductive in one or other of the described ways.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Laminated Bodies (AREA)
Abstract
Description
Doppelwandiger Lagertank mit einem Innenmantel aus Kunststoff Double-walled storage tank with an inner jacket made of plastic
Es ist bekannt, Lagertanks für wassergefährdende Flüs- sigkeit.en, wie Heizöl und Benzin, doppelwandig auszufüh¬ ren, wobei der Aussenmantel z.B. aus Beton oder Metall und der oft erst nachträglich angebrachte Innenmantel z.B. aus glasfaserverstärkte 'Kunststoff besteht. In dem in sich geschlossenen Hohlraum zwischen den beiden Be- hälterwänden befindet sich in der Regel ein der Leckwar¬ nung dienendes Testmedium, z.B. eine Flüssigkeit oder ein unter Ueber- oder Unterdruck gehaltenes Gas.It is known sigkeit.en storage tanks for water polluting liquid-, such as heating oil and gasoline, reindeer double auszufüh¬, wherein the outer jacket, for example made of concrete or metal and often only later attached to inner shell for example from glass fiber-reinforced 'plastic. In the self-contained cavity between the two container walls there is usually a test medium serving for leak warning, for example a liquid or a gas kept under positive or negative pressure.
In der gebräuchlichsten Ausführungsform besteht der In- nenmantel aus glasfaserverstärktem Polyester. Es gibt jedoch Lager lüssigkeiten, gegen deren Einwirkung Polyes¬ ter chemisch nicht beständig ist. Beispielsweise werden seit einigen Jahren dem Benzin bestimmte Mengen Alkohol bzw. Methanol beigemischt. Ein solches Gemisch kann den aus Polyester bestehenden Innenmantel erweichen und zer¬ stören.In the most common embodiment, the inner jacket is made of glass fiber reinforced polyester. However, there are storage liquids against which polyester is not chemically resistant. For example, certain amounts of alcohol or methanol have been added to gasoline for several years. Such a mixture can soften and destroy the inner jacket made of polyester.
Um diesen Nachteil zu beheben, liegt es auf der Hand, für den Innenmantel anstelle von Polyester ein lagergutbe- ständiges Material zu verwenden, im Falle von Benzin mit Zusatz als Lagergut beispielsweise ein Epoxydharz. Da Epoxydharz erheblich teurer ist als Polyester, wird man jedoch besonders bei einem selbsttragenden daher verhält- nismässig dickwandigen Innenmantel eine Lösung anstreben, bei der nur die lagergutseitige Oberfläche des Innen¬ mantels lagergutbeständig ist. Im genannten Beispiel könnte also ein zur Hauptsache aus Polyester bestehender Innenmantel mit einem Belag aus Epoxydharz ausgekleidet sein. Diese Massnahme allein ist jedoch ungenügend. Der Belag aus lagergutbeständigem Material muss eine minimale Schichtdicke aufweisen und frei von Poren sein, und es muss möglich sein, diese Eigenschaften des Belages am fertigen Lagertank auf einfache und zuverlässige Weise zu prüfen. Es ist bekannt, Behälterwände aus Kunststoff zu diesem Zweck einer elektrischen Durchschlagprüfung zu unterziehen. Mit diesem Verfahren gelingt es, auch kleinste Lecks aufzuspüren. Die elektrische Durchschlag- prüfung wird so gehandhabt, dass der zu prüfende Kunst- stoffmantel mit einer unter Hochspannung stehenden Elek¬ trode (z.B. Metallbesen) abgetastet wird. Dazu wird je¬ doch eine Gegenelektrode auf der Rückseite des Kunst¬ stoffmantels benötigt, und da die Höhe der PrüfSpannung auf die normale Dicke des Kunststoffmantels abgestimmt wird, damit bei einer undichten oder abnormal, dünnen Stelle des Kunststoffmantels und nur dann ein Durchschlag erfolgt, muss diese Gegenelektrode ohne Zwischenraum an der Rückseite des Kunststoffmantels anliegen. Beim Vor- handensein eines solchen unerwünschten Zwischenraums er¬ höht sich die Durchschlagspannung unter Umständen so stark, dass die PrüfSpannung nicht mehr ausreicht, um an der Stelle eines Lecks einen elektrischen Durchschlag herbeizuführen. Eine metallene Behälterwand ist also dann nicht als Gegenelektrode geeignet, wenn der Kunst¬ stoffmantel zur Erzielung eines Hohlraumes für den ein¬ gangs genannten Zweck mit Abstand von der metallenen Be¬ hälterwand angeordnet ist. Das gleiche Problem ergibt sich bei der Prüfung eines auf einer elektrisch nicht leitenden Kunststoff-Grundlage aufgebrachten Kunststoff¬ belages nach der genannten Methode.In order to remedy this disadvantage, it is obvious to use a material that is resistant to storage for the inner jacket instead of polyester, in the case of petrol with an additive as storage, for example, an epoxy resin. Since epoxy resin is considerably more expensive than polyester, however, a solution will be sought, particularly in the case of a self-supporting, therefore relatively thick-walled inner jacket, in which only the surface of the inner jacket on the stored product side is resistant to stored goods. In the example mentioned, an inner jacket consisting mainly of polyester could be lined with an epoxy resin covering. However, this measure alone is insufficient. The covering made of material resistant to stored goods must have a minimum layer thickness and be free of pores, and it must be possible to test these properties of the covering on the finished storage tank in a simple and reliable manner. It is known to subject container walls made of plastic to an electrical breakdown test for this purpose. With this procedure, even the smallest leaks can be found. The electrical breakdown test is handled in such a way that the plastic sheath to be tested is scanned with an electrode which is under high voltage (for example a metal broom). For this purpose, however, a counterelectrode is required on the back of the plastic jacket, and since the level of the test voltage is matched to the normal thickness of the plastic jacket, so that there is a breakdown in the event of a leaky or abnormal, thin area of the plastic jacket this counter electrode should lie on the back of the plastic jacket without any space. If such an undesirable intermediate space is present, the breakdown voltage may increase so much that the test voltage is no longer sufficient to cause an electrical breakdown at the location of a leak. A metal container wall is therefore not suitable as a counterelectrode if the plastic jacket is arranged at a distance from the metal container wall in order to achieve a cavity for the above-mentioned purpose. The same problem arises when testing a plastic covering applied to an electrically non-conductive plastic base using the method mentioned.
Die Erfindung betrifft nun einen doppelwandigen Lager¬ tank mit einem Innenmantel aus Kunststoff, bei dem die erwähnten Schwierigkeiten dadurch beseitigt sind, dass erfindungsgemäss der Innenmantel wenigstens innenseitig mit einer Deckschicht aus einem gegen die Einwirkung des Lagergutes chemisch beständigen, elektrisch nicht lei¬ tenden Material versehen ist und dass die an die Deck- schicht angrenzende Oberfläche des Innenmantels elek¬ trisch leitend ist.The invention now relates to a double-walled storage tank with an inner jacket made of plastic, in which the difficulties mentioned are eliminated in that According to the invention, the inner jacket is provided at least on the inside with a cover layer made of a material which is chemically resistant to the action of the stored goods and is not electrically conductive, and that the surface of the inner jacket adjacent to the cover layer is electrically conductive.
Einige Ausführungsbeispiele der Erfindung werden nach¬ stehend anhand der Zeichnung näher erläutert. Die Fig. 1 bis 4 der Zeichnung zeigen je einen Teilquerschnitt der Wandung eines doppelwandigen Lagertanks, der einen Aus- senmantel 1 aus Stahl, einen Innenmantel -2 aus Kunst¬ stoff, mit Distanznocken 3, und an der Innenseite des In¬ nenmantels 2 eine Deckschicht 4 aus einem gegen die Ein- Wirkung des Lagergutes chemisch beständigen, elektrisch nicht leitenden Material aufweist. Öie an die* eck¬ schicht 4. angrenzende Oberfläche des Innenmantels 2 ist elektrisch leitend, so dass die Deckschicht 4 mit elek¬ trischer Hochspannung und geeigneten Messinstrumenten in bekannter Weise auf Porenfreiheit und Schichtdicke ge¬ prüft werden kann.Some exemplary embodiments of the invention are explained in more detail below with reference to the drawing. 1 to 4 of the drawing each show a partial cross section of the wall of a double-walled storage tank, which has an outer jacket 1 made of steel, an inner jacket -2 made of plastic, with spacer cams 3, and one on the inside of the inner jacket 2 Cover layer 4 made of a chemically resistant to the action of the stored goods, electrically non-conductive material. The surface of the inner jacket 2 adjoining the corner layer 4 is electrically conductive, so that the top layer 4 can be checked in a known manner for freedom from pores and layer thickness using electrical high voltage and suitable measuring instruments.
Die elektrische Leitfähigkeit an der Innenmantelfläche auf der Rückseite der lagergutbeständigen Deckschicht 4 lässt sich auf verschiedene Weise erzielen.The electrical conductivity on the inner surface on the back of the storage-resistant cover layer 4 can be achieved in various ways.
Gemäss Fig. 1 weist der Innenmantel 2, der im wesentli¬ chen z.B. aus glasfaserverstärktem Polyester besteht, an der Innenseite eine elektrisch leitende Kunststoffschicht 5 auf, die z.B. aufgespritzt oder aufgerollt sein kann. Elektrisch leitender Kunststoff in der für die genannte Verarbeitung geeigneten Form ist an sich bekannt. Auf die elektrisch leitende Kunststoffschicht 5 wird an- schliessend die lagergutbeständige Deckschicht 4 mit einer Schichtdicke von z.B. 0,5 bis 0,7 mm aufgebracht. Für eine gegen Benzin mit Alkohol- bzw. Methanolzusatz beständige Deckschicht gibt es geeignete Epoxydharze» Die Beschichtung des Innenmantels 2 kann sowohl vor als auch nach dessen Einbau in den Aussen antel 1 des Lager- tanks vorgenommen werden.1, the inner jacket 2, which essentially consists, for example, of fiberglass-reinforced polyester, has an electrically conductive plastic layer 5 on the inside, which can be sprayed on or rolled on, for example. Electrically conductive plastic in the form suitable for the processing mentioned is known per se. Then the cover layer 4, which is resistant to stored goods, is applied to the electrically conductive plastic layer 5 with a layer thickness of, for example, 0.5 to 0.7 mm. Suitable epoxy resins are available for a top layer that is resistant to petrol with the addition of alcohol or methanol. The coating of the inner jacket 2 can be carried out both before and after it is installed in the outer tank 1 of the storage tank.
Bei der Aus ührungsform nach Fig..2 wird für den Innen¬ mantel 2 selbst ein elektrisch leitender Kunststoff ver¬ wendet, so dass das zusätzliche Aufbringen einer Schicht (5 in Fig. 1) aus leitendem Kunststoff entfallen kann.In the embodiment according to FIG. 2, an electrically conductive plastic is itself used for the inner jacket 2, so that the additional application of a layer (5 in FIG. 1) made of conductive plastic can be omitted.
Es besteht ferner gemäss Fig. 3 die Möglichkeit, den In¬ nenmantel 2 bei seiner Herstellung, d.h. im noch nassen oder klebrigen Zustand, an seiner lagergutseitigen Ober- fläche mit einer elektrisch leitenden Schicht 6 zu ver-According to FIG. 3, there is also the possibility of producing the inner shell 2 during its manufacture, i.e. in the wet or sticky state, to be coated with an electrically conductive layer 6 on its surface on the side of the goods to be stored
'sehen, also nur schichtweise leitenden Kunststoff zu ver¬ wenden bzw. elektrisch leitende Partikel, z.B. Graphit oder Metallpulver oder -griess in das an sich nicht lei¬ tende Material des Innenmantels 2 an dessen Innenfläche einzuarbeiten. Darüber befindet sich wiederum die lager¬ gutbeständige Deckschicht 4.'see, i.e. only use layer-by-layer conductive plastic or electrically conductive particles, e.g. Incorporate graphite or metal powder or semolina into the non-conductive material of the inner shell 2 on its inner surface. The top layer 4, which is stable in storage, is again located above this.
Eine weitere Ausführungsform für besonders strenge Anfor¬ derungen ist in Fig. 4 dargestellt. Der Innenmantel 2 be- steht im tragenden Teil aus glasfaserverstärktem Kunst¬ stoff, z.B. Polyester, und weist sowohl auf der Innen¬ ais auch auf der Aussenseite eine lagergutbeständige Deck schicht 4 bzw. 7 auf. Diese Massnahme hat den Vorteil, dass der Innenmantel 2 bei allfälligen Undichtheiten auch von aussen vom Lagergut nicht chemisch zerstört werden kann. Die an die Deckschichten 4 und 7 angrenzenden Ober¬ flächen des Innenmantels 2 können auf die eine oder an¬ dere der beschriebenen "Arten elektrisch leitend gemacht sein.A further embodiment for particularly stringent requirements is shown in FIG. 4. The inner shell 2 consists of glass-fiber reinforced plastic in the supporting part, e.g. Polyester, and has a storage-resistant cover layer 4 and 7 both on the inside and on the outside. This measure has the advantage that the inner casing 2 cannot be chemically destroyed from the outside by the stored goods in the event of any leaks. The surfaces of the inner casing 2 adjoining the cover layers 4 and 7 can be made electrically conductive in one or other of the described ways.
O O
Claims
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP80900399A EP0047235A1 (en) | 1980-03-07 | 1980-03-07 | Double walled storage tankprovided with an internal shell of plastic material |
| PCT/CH1980/000035 WO1981002562A1 (en) | 1980-03-07 | 1980-03-07 | Double walled storage tank provided with an internal shell of plastic material |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| WOCH80/00035 | 1980-03-07 | ||
| PCT/CH1980/000035 WO1981002562A1 (en) | 1980-03-07 | 1980-03-07 | Double walled storage tank provided with an internal shell of plastic material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1981002562A1 true WO1981002562A1 (en) | 1981-09-17 |
Family
ID=4537571
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/CH1980/000035 Ceased WO1981002562A1 (en) | 1980-03-07 | 1980-03-07 | Double walled storage tank provided with an internal shell of plastic material |
Country Status (2)
| Country | Link |
|---|---|
| EP (1) | EP0047235A1 (en) |
| WO (1) | WO1981002562A1 (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0069303A1 (en) * | 1981-07-02 | 1983-01-12 | Neo Vac Aktiengesellschaft | Double-walled tank and a method of making the same |
| EP0710610A1 (en) | 1994-11-02 | 1996-05-08 | Bayer Ag | Tank with multilayered wall construction and its manufacturing process |
| FR2735755A1 (en) * | 1995-06-20 | 1996-12-27 | Laguens Y Perez Sa Lapesa | Fluid storage tank |
| EP2014580A1 (en) * | 2007-07-10 | 2009-01-14 | Gewässerschutz-Systeme Europa Werner Bachmann | Leakage protection cladding and double walled tank with the same |
| EA016651B1 (en) * | 2009-04-28 | 2012-06-29 | Оно Уотерпротекшн Гмбх | Leakage protection cladding and double walled tank with the same |
| FR3088079A1 (en) * | 2018-11-07 | 2020-05-08 | Max Perles Et Cie | WALL COMPRISING A POROUS SUPPORT COVERED WITH A SEALING SYSTEM COMPRISING AT LEAST ONE ELECTRICALLY CONDUCTIVE PRIMER LAYER |
| CN121247266A (en) * | 2025-12-05 | 2026-01-02 | 冀州中意复合材料股份有限公司 | Glass fiber reinforced plastic tank with conductive structure and manufacturing method thereof |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2402283B1 (en) * | 2011-09-28 | 2014-03-04 | Construcciones Biovivenda, S.L. | METHOD FOR REMOVING Pores IN WALLS OF DEPOSITS FOR HYDROCARBONS. |
| CN107472734A (en) * | 2016-06-08 | 2017-12-15 | 沃尔夫坦克-阿迪萨控股股份公司 | Case tank and be the lined method of case tank |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH499710A (en) * | 1970-03-05 | 1970-11-30 | Ironflex Ag | Oil storage tank liner |
| CH521268A (en) * | 1970-03-20 | 1972-04-15 | Huber+Suhner Ag | Metal containers, in particular of steel, for insulating liquids |
| FR2319535A1 (en) * | 1975-07-26 | 1977-02-25 | Clouth Gummiwerke Ag | CONTAINER WITH A COATING |
-
1980
- 1980-03-07 WO PCT/CH1980/000035 patent/WO1981002562A1/en not_active Ceased
- 1980-03-07 EP EP80900399A patent/EP0047235A1/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH499710A (en) * | 1970-03-05 | 1970-11-30 | Ironflex Ag | Oil storage tank liner |
| CH521268A (en) * | 1970-03-20 | 1972-04-15 | Huber+Suhner Ag | Metal containers, in particular of steel, for insulating liquids |
| FR2319535A1 (en) * | 1975-07-26 | 1977-02-25 | Clouth Gummiwerke Ag | CONTAINER WITH A COATING |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0069303A1 (en) * | 1981-07-02 | 1983-01-12 | Neo Vac Aktiengesellschaft | Double-walled tank and a method of making the same |
| EP0710610A1 (en) | 1994-11-02 | 1996-05-08 | Bayer Ag | Tank with multilayered wall construction and its manufacturing process |
| FR2735755A1 (en) * | 1995-06-20 | 1996-12-27 | Laguens Y Perez Sa Lapesa | Fluid storage tank |
| EP2014580A1 (en) * | 2007-07-10 | 2009-01-14 | Gewässerschutz-Systeme Europa Werner Bachmann | Leakage protection cladding and double walled tank with the same |
| EA016651B1 (en) * | 2009-04-28 | 2012-06-29 | Оно Уотерпротекшн Гмбх | Leakage protection cladding and double walled tank with the same |
| FR3088079A1 (en) * | 2018-11-07 | 2020-05-08 | Max Perles Et Cie | WALL COMPRISING A POROUS SUPPORT COVERED WITH A SEALING SYSTEM COMPRISING AT LEAST ONE ELECTRICALLY CONDUCTIVE PRIMER LAYER |
| EP3650618A1 (en) | 2018-11-07 | 2020-05-13 | Max Perles et Cie | Wall comprising a porous medium likely to crack, in particular concrete, covered with a sealing system which comprises at least one electrically conductive primary layer, associated storage system |
| CN121247266A (en) * | 2025-12-05 | 2026-01-02 | 冀州中意复合材料股份有限公司 | Glass fiber reinforced plastic tank with conductive structure and manufacturing method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0047235A1 (en) | 1982-03-17 |
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