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UY23707A1 - PROCEDURE FOR THE PREPARATION OF NONATETRAENOIC ACID DERIVATIVES - Google Patents

PROCEDURE FOR THE PREPARATION OF NONATETRAENOIC ACID DERIVATIVES

Info

Publication number
UY23707A1
UY23707A1 UY23707A UY23707A UY23707A1 UY 23707 A1 UY23707 A1 UY 23707A1 UY 23707 A UY23707 A UY 23707A UY 23707 A UY23707 A UY 23707A UY 23707 A1 UY23707 A1 UY 23707A1
Authority
UY
Uruguay
Prior art keywords
formula
compound
preparation
represented
dimethyl
Prior art date
Application number
UY23707A
Other languages
Spanish (es)
Inventor
Thomas Doran
Michael Rosenberger
Michael Shapiro
Stanley Seymour
Original Assignee
Hoffmann La Roche
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoffmann La Roche filed Critical Hoffmann La Roche
Publication of UY23707A1 publication Critical patent/UY23707A1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/66Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
    • C07C69/73Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of unsaturated acids
    • C07C69/734Ethers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00Medicinal preparations containing organic active ingredients
    • A61K31/185Acids; Anhydrides, halides or salts thereof, e.g. sulfur acids, imidic, hydrazonic or hydroximic acids
    • A61K31/19Carboxylic acids, e.g. valproic acid
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P17/00Drugs for dermatological disorders
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00Ethers; Compounds having groups, groups or groups
    • C07C43/02Ethers
    • C07C43/20Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring
    • C07C43/225Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring containing halogen
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C59/00Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C59/40Unsaturated compounds
    • C07C59/58Unsaturated compounds containing ether groups, groups, groups, or groups
    • C07C59/64Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Veterinary Medicine (AREA)
  • General Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Animal Behavior & Ethology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Epidemiology (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dermatology (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Cosmetics (AREA)
  • Processing Of Meat And Fish (AREA)
  • Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)
  • Optical Communication System (AREA)
  • Compounds Of Unknown Constitution (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Medicinal Preparation (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

Procedimiento para la preparación del compuesto ácido (all-E)-3,7-dimetil-9-[3,5-dimetil-2-(noniloxi)-fenil]-2,4,6,8-nonatetranoico con fórmula (I) representada en la figura 1, y sus sales farmacéuticamente aceptables y ésteres hidrolizables farmacéuticamente aceptables, que comprende hacer reaccionar un compuesto de fórmula (II) representada en la figura 2, donde Ph es fenilo y X- es un anión, bajo las condiciones de una reacción Witting con un compuesto de fórmula (III) representada en la figura 3; y si se desea, hidrolizar el grupo éster alquílico para obtener el ácido carboxílico de fórmula (I). Se incluye también un procedimiento conforme a lo descrito para la preparación de una composición farmacéutica que contiene un compuesto de fórmula (I), donde dicha composición es un comprimido o cápsula, o una formulación para aplicaciones tópicas. Estas composiciones son de utilidad para reducir la secreción de sebo (como seborrea, caspa, piel o cabello graso, cabello cano), como también para prevenir el acné.Process for the preparation of the (all-E) -3,7-dimethyl-9- [3,5-dimethyl-2- (nonyloxy) -phenyl] -2,4,6,8-nonatetranoic acid compound with formula (I ) represented in Figure 1, and their pharmaceutically acceptable salts and pharmaceutically acceptable hydrolyzable esters, which comprises reacting a compound of formula (II) represented in Figure 2, where Ph is phenyl and X- is an anion, under the conditions of a Witting reaction with a compound of formula (III) represented in figure 3; and if desired, hydrolyzing the alkyl ester group to obtain the carboxylic acid of formula (I). Also included is a process as described for the preparation of a pharmaceutical composition containing a compound of formula (I), wherein said composition is a tablet or capsule, or a formulation for topical applications. These compositions are useful for reducing the secretion of sebum (such as seborrhea, dandruff, oily skin or hair, gray hair), as well as for preventing acne.

UY23707A 1993-01-06 1993-12-31 PROCEDURE FOR THE PREPARATION OF NONATETRAENOIC ACID DERIVATIVES UY23707A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/001,144 US5369126A (en) 1993-01-06 1993-01-06 Nonatetraenoic acid derivative for use in treating acne

Publications (1)

Publication Number Publication Date
UY23707A1 true UY23707A1 (en) 1994-06-05

Family

ID=21694605

Family Applications (1)

Application Number Title Priority Date Filing Date
UY23707A UY23707A1 (en) 1993-01-06 1993-12-31 PROCEDURE FOR THE PREPARATION OF NONATETRAENOIC ACID DERIVATIVES

Country Status (24)

Country Link
US (1) US5369126A (en)
EP (1) EP0606614B1 (en)
JP (1) JP2563158B2 (en)
KR (1) KR940018351A (en)
CN (1) CN1098086A (en)
AT (1) ATE150442T1 (en)
AU (1) AU668239B2 (en)
BR (1) BR9400020A (en)
CA (1) CA2110336A1 (en)
CZ (1) CZ2194A3 (en)
DE (1) DE69309029T2 (en)
DK (1) DK0606614T3 (en)
ES (1) ES2099894T3 (en)
FI (1) FI940040A7 (en)
GR (1) GR3023582T3 (en)
HU (1) HUT65945A (en)
IL (1) IL108246A (en)
MX (1) MX9400200A (en)
NO (1) NO180534C (en)
NZ (1) NZ250581A (en)
PL (1) PL301783A1 (en)
TW (1) TW247311B (en)
UY (1) UY23707A1 (en)
ZA (1) ZA939805B (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU4233297A (en) * 1996-08-23 1998-03-06 Arch Development Corporation Identification of activators and inhibitors of sebum formation
US6294188B1 (en) 1998-07-09 2001-09-25 Aviana Biopharm Inc. Methods involving changing the constitutive and stimulated secretions of the local reproductive system of women
CN104087445B (en) * 2009-09-18 2018-03-02 埃科莱布美国股份有限公司 Non- trans fats, aliphatic acid and opacifier stain are handled with chelating agent
US20140014137A1 (en) 2009-09-18 2014-01-16 Ecolab Usa Inc. Treatment of non-trans fats with acidic tetra sodium l-glutamic acid, n, n-diacetic acid (glda)
US10253281B2 (en) 2012-08-20 2019-04-09 Ecolab Usa Inc. Method of washing textile articles
PT3250670T (en) 2015-01-29 2020-05-29 Ecolab Usa Inc Composition and method for treatment of stains in textiles

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4648996A (en) * 1984-07-27 1987-03-10 Hoffmann-La Roche Inc. Phenyl substituted-2,4,6,8-nonatetraenoic acid
ZA854828B (en) * 1984-07-27 1986-03-26 Hoffmann La Roche Phenyl nonatetraenoic acid derivatives

Also Published As

Publication number Publication date
ATE150442T1 (en) 1997-04-15
JPH06234698A (en) 1994-08-23
IL108246A (en) 1997-06-10
AU668239B2 (en) 1996-04-26
HUT65945A (en) 1994-08-29
NZ250581A (en) 1995-12-21
NO940034L (en) 1994-07-07
BR9400020A (en) 1994-08-16
EP0606614B1 (en) 1997-03-19
KR940018351A (en) 1994-08-16
MX9400200A (en) 1994-07-29
CA2110336A1 (en) 1994-07-07
HU9400001D0 (en) 1994-05-30
JP2563158B2 (en) 1996-12-11
FI940040L (en) 1994-07-07
FI940040A7 (en) 1994-07-07
ZA939805B (en) 1994-07-06
ES2099894T3 (en) 1997-06-01
EP0606614A1 (en) 1994-07-20
IL108246A0 (en) 1994-04-12
DE69309029T2 (en) 1997-10-30
CN1098086A (en) 1995-02-01
AU5243293A (en) 1994-07-14
NO180534C (en) 1997-05-07
PL301783A1 (en) 1994-07-11
NO940034D0 (en) 1994-01-05
DK0606614T3 (en) 1997-09-22
GR3023582T3 (en) 1997-08-29
TW247311B (en) 1995-05-11
US5369126A (en) 1994-11-29
NO180534B (en) 1997-01-27
FI940040A0 (en) 1994-01-05
DE69309029D1 (en) 1997-04-24
CZ2194A3 (en) 1994-07-13

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