USRE31412E - Pressure-and-heat-sensitive copying paper - Google Patents
Pressure-and-heat-sensitive copying paper Download PDFInfo
- Publication number
- USRE31412E USRE31412E US06/153,660 US15366080A USRE31412E US RE31412 E USRE31412 E US RE31412E US 15366080 A US15366080 A US 15366080A US RE31412 E USRE31412 E US RE31412E
- Authority
- US
- United States
- Prior art keywords
- diethylaminofluoran
- methyl
- heat
- copying paper
- sensitive copying
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- -1 fluoran compound Chemical class 0.000 claims abstract description 13
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 12
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 8
- 150000002367 halogens Chemical group 0.000 claims abstract description 8
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims abstract description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 6
- 239000001257 hydrogen Substances 0.000 claims abstract description 6
- 150000002431 hydrogen Chemical group 0.000 claims abstract description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 3
- FWQHNLCNFPYBCA-UHFFFAOYSA-N fluoran Chemical compound C12=CC=CC=C2OC2=CC=CC=C2C11OC(=O)C2=CC=CC=C21 FWQHNLCNFPYBCA-UHFFFAOYSA-N 0.000 claims description 19
- 101100434170 Oryza sativa subsp. japonica ACR2.1 gene Proteins 0.000 claims 1
- 101100386054 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) CYS3 gene Proteins 0.000 abstract 1
- 101150035983 str1 gene Proteins 0.000 abstract 1
- 239000000047 product Substances 0.000 description 79
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 66
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 63
- 150000001875 compounds Chemical class 0.000 description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 34
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 33
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 30
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 25
- 239000002244 precipitate Substances 0.000 description 24
- 239000007864 aqueous solution Substances 0.000 description 22
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 22
- 235000011121 sodium hydroxide Nutrition 0.000 description 21
- 238000002360 preparation method Methods 0.000 description 18
- 239000004927 clay Substances 0.000 description 17
- FQNKTJPBXAZUGC-UHFFFAOYSA-N 2-[4-(diethylamino)-2-hydroxybenzoyl]benzoic acid Chemical compound OC1=CC(N(CC)CC)=CC=C1C(=O)C1=CC=CC=C1C(O)=O FQNKTJPBXAZUGC-UHFFFAOYSA-N 0.000 description 16
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 16
- 239000000843 powder Substances 0.000 description 15
- 238000010992 reflux Methods 0.000 description 15
- 239000011347 resin Substances 0.000 description 15
- 229920005989 resin Polymers 0.000 description 15
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 11
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 11
- 239000013078 crystal Substances 0.000 description 11
- 235000019441 ethanol Nutrition 0.000 description 11
- 229910052740 iodine Inorganic materials 0.000 description 11
- 239000011630 iodine Substances 0.000 description 11
- 229910000027 potassium carbonate Inorganic materials 0.000 description 11
- 239000000975 dye Substances 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 239000000243 solution Substances 0.000 description 5
- HVBSAKJJOYLTQU-UHFFFAOYSA-N 4-aminobenzenesulfonic acid Chemical compound NC1=CC=C(S(O)(=O)=O)C=C1 HVBSAKJJOYLTQU-UHFFFAOYSA-N 0.000 description 4
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 108010010803 Gelatin Proteins 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- 229920000159 gelatin Polymers 0.000 description 3
- 239000008273 gelatin Substances 0.000 description 3
- 235000019322 gelatine Nutrition 0.000 description 3
- 235000011852 gelatine desserts Nutrition 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- QBELEDRHMPMKHP-UHFFFAOYSA-N 1-bromo-2-chlorobenzene Chemical compound ClC1=CC=CC=C1Br QBELEDRHMPMKHP-UHFFFAOYSA-N 0.000 description 2
- NHDODQWIKUYWMW-UHFFFAOYSA-N 1-bromo-4-chlorobenzene Chemical compound ClC1=CC=C(Br)C=C1 NHDODQWIKUYWMW-UHFFFAOYSA-N 0.000 description 2
- CFPZDVAZISWERM-UHFFFAOYSA-N 4-bromo-1,2-dichlorobenzene Chemical compound ClC1=CC=C(Br)C=C1Cl CFPZDVAZISWERM-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- 229920000084 Gum arabic Polymers 0.000 description 2
- 241000978776 Senegalia senegal Species 0.000 description 2
- 239000000205 acacia gum Substances 0.000 description 2
- 235000010489 acacia gum Nutrition 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- XVAIDCNLVLTVFM-UHFFFAOYSA-N methacetin Chemical compound COC1=CC=C(NC(C)=O)C=C1 XVAIDCNLVLTVFM-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229950000244 sulfanilic acid Drugs 0.000 description 2
- QTKIQLNGOKOPOE-UHFFFAOYSA-N 1,1'-biphenyl;propane Chemical group CCC.C1=CC=CC=C1C1=CC=CC=C1 QTKIQLNGOKOPOE-UHFFFAOYSA-N 0.000 description 1
- SWJPEBQEEAHIGZ-UHFFFAOYSA-N 1,4-dibromobenzene Chemical compound BrC1=CC=C(Br)C=C1 SWJPEBQEEAHIGZ-UHFFFAOYSA-N 0.000 description 1
- DZHFFMWJXJBBRG-UHFFFAOYSA-N 1-bromo-3,5-dichlorobenzene Chemical compound ClC1=CC(Cl)=CC(Br)=C1 DZHFFMWJXJBBRG-UHFFFAOYSA-N 0.000 description 1
- JRGGUPZKKTVKOV-UHFFFAOYSA-N 1-bromo-3-chlorobenzene Chemical compound ClC1=CC=CC(Br)=C1 JRGGUPZKKTVKOV-UHFFFAOYSA-N 0.000 description 1
- WQFYAGVHZYFXDO-UHFFFAOYSA-N 2'-anilino-6'-(diethylamino)-3'-methylspiro[2-benzofuran-3,9'-xanthene]-1-one Chemical compound C=1C(N(CC)CC)=CC=C(C2(C3=CC=CC=C3C(=O)O2)C2=C3)C=1OC2=CC(C)=C3NC1=CC=CC=C1 WQFYAGVHZYFXDO-UHFFFAOYSA-N 0.000 description 1
- GLELQLHCSRTFFD-UHFFFAOYSA-N 2-[4-(dimethylamino)-2-hydroxybenzoyl]benzoic acid Chemical compound OC1=CC(N(C)C)=CC=C1C(=O)C1=CC=CC=C1C(O)=O GLELQLHCSRTFFD-UHFFFAOYSA-N 0.000 description 1
- OVXVQBCRONSPDC-UHFFFAOYSA-N 2-bromo-1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Br)=C1 OVXVQBCRONSPDC-UHFFFAOYSA-N 0.000 description 1
- UQRLKWGPEVNVHT-UHFFFAOYSA-N 3,5-dichloroaniline Chemical compound NC1=CC(Cl)=CC(Cl)=C1 UQRLKWGPEVNVHT-UHFFFAOYSA-N 0.000 description 1
- PNPCRKVUWYDDST-UHFFFAOYSA-N 3-chloroaniline Chemical compound NC1=CC=CC(Cl)=C1 PNPCRKVUWYDDST-UHFFFAOYSA-N 0.000 description 1
- OZFQMHJKAODEON-UHFFFAOYSA-N 4-bromo-1-chloro-2-methylbenzene Chemical compound CC1=CC(Br)=CC=C1Cl OZFQMHJKAODEON-UHFFFAOYSA-N 0.000 description 1
- 101100177155 Arabidopsis thaliana HAC1 gene Proteins 0.000 description 1
- FKLJPTJMIBLJAV-UHFFFAOYSA-N Compound IV Chemical compound O1N=C(C)C=C1CCCCCCCOC1=CC=C(C=2OCCN=2)C=C1 FKLJPTJMIBLJAV-UHFFFAOYSA-N 0.000 description 1
- 101150108015 STR6 gene Proteins 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- HSMPSHPWCOOUJH-UHFFFAOYSA-N anilinyl Chemical compound [NH]C1=CC=CC=C1 HSMPSHPWCOOUJH-UHFFFAOYSA-N 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- DENRZWYUOJLTMF-UHFFFAOYSA-N diethyl sulfate Chemical compound CCOS(=O)(=O)OCC DENRZWYUOJLTMF-UHFFFAOYSA-N 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- CPJSUEIXXCENMM-UHFFFAOYSA-N phenacetin Chemical compound CCOC1=CC=C(NC(C)=O)C=C1 CPJSUEIXXCENMM-UHFFFAOYSA-N 0.000 description 1
- 239000011973 solid acid Substances 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/124—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components
- B41M5/132—Chemical colour-forming components; Additives or binders therefor
- B41M5/136—Organic colour formers, e.g. leuco dyes
- B41M5/145—Organic colour formers, e.g. leuco dyes with a lactone or lactam ring
- B41M5/1455—Organic colour formers, e.g. leuco dyes with a lactone or lactam ring characterised by fluoran compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
- B41M5/323—Organic colour formers, e.g. leuco dyes
- B41M5/327—Organic colour formers, e.g. leuco dyes with a lactone or lactam ring
- B41M5/3275—Fluoran compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
- C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
- C07D493/10—Spiro-condensed systems
Definitions
- the present invention relates to copying paper which is heat or pressure sensitive which contains a color former.
- a new series of fluoran compounds are provided which serve as a color former for this paper.
- the fluoran compounds of the invention are particularly useful for developing color in the copying paper having a green or black shade.
- the fluoran compounds have the general formula ##STR2## wherein R 1 is halogen; R 2 is hydrogen or methyl; R 3 is hydrogen, methyl or ethyl; each of R 4 is independently halogen or methyl; R 5 methyl or ethyl; and n is .Badd.0 or an integer from 1 to 4.
- Such fluroan compounds as (III) may be applied to the pressure-sensitive copying paper in a manner, for example, described in the Japanese Pat. No. 4,614/1971.
- a dye for the pressure-sensitive copying paper is generally applicable to the heat-sensitive copying paper in such a manner as is described in the Japanese Pat. No. 14,039/1970.
- the product (III) can also be applied to the heat-sensitive copying paper in a similar manner.
- the dye is used for the heat-sensitive copying paper, it is not used in microcapsules of gelatin etc., as in the case of the pressure-sensitive copying paper.
- fluroan compounds not only are very useful as the dye for heat-sensitive copying paper but also have a high practical value as the dye for pressure-sensitive copying paper.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Color Printing (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Heat Sensitive Colour Forming Recording (AREA)
Abstract
A heat or pressure sensitive copying paper is provided containing a fluoran compound as a color former, said color being developed in said heat or pressure sensitive copying paper through the application of heat or pressure, said fluoran compound being of the formula ##STR1## wherein R1 is halogen; R2 is hydrogen or methyl; R3 is hydrogen, methyl or ethyl; each of R4 is independently halogen or methyl; R5 is methyl or ethyl; and n is 0 or an integer from 1 to 4.
Description
The present invention relates to copying paper which is heat or pressure sensitive which contains a color former.
According to a second aspect of the invention, a new series of fluoran compounds are provided which serve as a color former for this paper.
The fluoran compounds of the invention are particularly useful for developing color in the copying paper having a green or black shade. The fluoran compounds have the general formula ##STR2## wherein R1 is halogen; R2 is hydrogen or methyl; R3 is hydrogen, methyl or ethyl; each of R4 is independently halogen or methyl; R5 methyl or ethyl; and n is .Badd.0 or an integer from 1 to 4.
Such fluroan compounds as (III) may be applied to the pressure-sensitive copying paper in a manner, for example, described in the Japanese Pat. No. 4,614/1971. Also a dye for the pressure-sensitive copying paper is generally applicable to the heat-sensitive copying paper in such a manner as is described in the Japanese Pat. No. 14,039/1970. The product (III) can also be applied to the heat-sensitive copying paper in a similar manner. However, when the dye is used for the heat-sensitive copying paper, it is not used in microcapsules of gelatin etc., as in the case of the pressure-sensitive copying paper. Instead, it is used in a powdery state after being pulverized with a color coupler, so that particularly great importance is attached to the stability of the dye itself. For example, 2-anilino-6-diethylaminofluoran (compound IV, developing into a green color) and 2-anilino-3-methyl-6-diethylaminofluoran (compound V, developing into a black color), disclosed in Belgian Pat. No. 744,705, are known as the dyes for pressure-sensitive copying paper that singly develop into a green or black color: ##STR3## But they have not enough stability to make themselves suitable for heat-sensitive copying paper. That is, when these dyes are pulverized in an aqueous solution of PVA and, then, mixed with bisphenol A ect., in accordance with the method of the Patent No. 14,039/1970, to prepare a coating material for the heat-sensitive copying paper, the coating material itself develops into a green or black color (hereinafter called "self color development") at this stage already. It is therefore very difficult to make any heat-sensitive copying paper of practical value. In the course of our study to solve the defect of self color development, it was found that self color development could be perfectly prevented by introducing one or more halogens into an anilino radical as shown in the general formula (III). It was also found that the introduction of halogen produces a very useful dye by improving light and water resistance of the color which is developed and by suppressing the sublimation.
These fluroan compounds not only are very useful as the dye for heat-sensitive copying paper but also have a high practical value as the dye for pressure-sensitive copying paper.
Now the present invention is further illustrated by the following specific example:
25 g of aceto-p-phenetidide, 36.6 g of p-chlorobromobenzene, 10 g of potassium carbonate, 0.7 g of copper powder and a small quantity of iodine were heated under reflux for 48 hours, and then, after addition of 12 g of potassium hydroxide and 60 ml of ethyl alcohol, further heated under reflux for 20 hours. The product was discharged into water, and the precipitate was filtered off and distilled in vacuo. Then 28.7 g (83 percent of theoretical yield) of 4-chloro-4'-ethoxydiphenylamine (VII) was obtained, and it was found to be white crystals (b.p. 185° to 190° C./4 ,Jg, m.p. 56° to 57° C.).
From the following analysis result, it was confirmed that the product was .[.C13 H12 ClNO.]. .Iadd.C14 H14 ClNO.Iaddend..
______________________________________
C H N
______________________________________
Theoretical .[. 66.90 5.14 5.91 .].
.Iadd.67.88.Iaddend.
.Iadd.5.66.Iaddend.
.Iadd.5.66.Iaddend.
Found 66.00 5.12 5.95
______________________________________
Then 10 g of the compound (VII), 13.4 g of 4-diethylamino-2-hydroxy-2'-carboxybenzophenone (VIII) and 70 g of concentrated sulfuric acid were stirred at ordinary temperature for 48 hours. The product was discharged into 1 l of water, and the precipitate was filtered off, washed with an aqueous solution of caustic soda, and recrystallized with toluene. Then 11.8 g (55.5 percent of theoretical yield) of 2-p-chloroanilino-6-diethylaminofluoran (VI) was obtained. The product was a slightly colored powder (m.p. 210° to 213° C.) and developed a green color in the presence of a member selected from a group consisting of clay, resin, bisphenol A and the like.
From the following analysis result, it was confirmed that the product was C30 H25 ClN2 O3.
______________________________________
C H N
______________________________________
Theoretical 72.50 5.04 5.64
Found 73.10 5.11 5.38
______________________________________
64 g of m-chloroaniline, 55 g of hydroquinone and 1 g of sulfanilic acid were allowed to react with each other at 200° C. for 20 hours, and the product was dissolved in an aqueous solution of caustic soda and the filtered. The filtrate was made acidic with acetic acid, and the precipitate was distilled in vacuo. Then 35 g (31.8 percent of theoretical yield) of 3-chloro-4'-hydroxydiphenylamine (X) was obtained, and it was found to be yellow crystals (b.p. 245° to 247° C./11 mmHg, m.p. 96° to 98° C.).
From the following analysis result, it was confirmed that the product was C12 H10 ClNO.
______________________________________
C H N
______________________________________
Theoretical 65.60 4.56 6.38
Found 65.20 4.70 6.38
______________________________________
Then 14.1 g of the compound (X), 18.5 g of the compound (VIII) and 90 g of concentrated sulfuric acid were stirred at ordinary temperature for 48 hours. The product was discharged into 1 l of water, and the precipitate was filtered off, washed with an aqueous solution of caustic soda, and recrystallized with toluene. Then 13 g (40.8 percent of theoretical yield) of 2-m-chloroanilino-6-diethylaminofluoran (IX) was obtained. The product was a pale-purple powder (m.p. 186° to 187° C.) and developed a green color in the presence of clay or resin and a black color in the presence of bisphenol A.
From the following analysis result, it was confirmed that the product was C30 H25 ClN2 O3.
______________________________________
C H N
______________________________________
Theoretical 72.50 5.04 5.64
Found 71.94 4.97 5.47
______________________________________
From the following analysis result, it was confirmed that the product was C13 H12 ClNO.
______________________________________
C H N
______________________________________
Theoretical 66.90 5.14 5.91
Found 67.20 5.21 6.01
______________________________________
Then 10 g of the compound (XII), 13.4 g of the compound (VIII) and 50 g of concentrated sulfuric acid were stirred at ordinary temperature for 48 hours. The product was discharged into 1 l of water, and the precipitate was filtered off, washed with an aqueous solution of caustic soda, and recrystallized with toluene. Then 12.6 g (59.2 percent of theoretical yield) of 2-o-chloroanilino-6-diethylaminofluoran (XI) was obtained. The product was a pale-pink powder .[.m.p. 178° to 180° C.]. .Iadd.m.p. 212.5° to 213.5° C..Iaddend. and developed a black color in the presence of clay and bisphenol A and a green color in the presence of resin.
From the following analysis result, it was confirmed that the product was C30 H25 ClN2 O3.
______________________________________
C H N
______________________________________
Theoretical 72.50 5.04 5.64
Found 73.00 5.05 5.48
______________________________________
28 g of 3,5-dichloroaniline, 19 g of hydroquinone and 0.3 g of sulfanilic acid were allowed to react with each other at 200° C. for 20 hours, and the product was dissolved in the solution of 10 g of caustic soda in 200 ml of water and then filtered. The filtrate was added with 26.3 g of dimethylsulfuric acid, heated under reflux for 5 hours, and then cooled. The precipitate was filtered off and distilled in vacuo. Then 35 g (76 percent of theoretical yield) of 3,5-dichloro-4'-methoxydiphenylamine (XIV) was obtained, and it was found to be yellow crystals (b.p. 226° to 230° C./4 mm Hg, m.p. 106° to 107° C.).
From the following analysis result, it was confirmed that the product was C13 H11 Cl2 NO.
______________________________________
C H N
______________________________________
Theoretical 58.21 4.10 5.22
Found 57.20 3.95 5.12
______________________________________
Then 15 g of the compound (XIV), 17.6 g of the compound (VIII) and 100 g of concentrated sulfuric acid were condensed by stirring at ordinary temperature for 48 hours. The product was discharged into 1 l of water, and the precipitate was filtered off, washed with an aqueous solution of caustic soda, and recrystallized with toluene. Then 18 g (60.5 percent of theoretical yield) of 2-(3',5'-dichloroanilino)-6-diethylaminofluoran (XIII) was obtained. The product developed a green color in the presence of resin and a black color in the presence of clay and bisphenol A.
From the following analysis result, it was confirmed that the product was C30 H24 Cl2 N2 O3.
______________________________________
C H N
______________________________________
Theoretical 67.80 4.52 5.28
Found 68.20 4.59 5.10
______________________________________
33 g of p-acetanisidide, 68 g of 3,4-dichlorobromobenzene, 16 g of potassium carbonate, 1.5 g of copper powder and a small quantity of iodine were heated under reflux for 48 hours, and then, after addition of 16 g of potassium hydroxide and 100 ml of ethyl alcohol, further heated under reflux for 20 hours. The product was discharged into water, and the precipitate was filtered off and distilled in vacuo. Then 39 g (73 percent of theoretical yield) of 3,4-dichloro-4'-methoxydiphenylamine (XVI) was obtained, and it was found to be pale-yellow crystals (b.p. 228° to 232° C./4 mmHg, m.p. 101° to 102° C.).
From the following analysis result, it was confirmed that the product was C13 H11 Cl2 NO.
______________________________________
C H N
______________________________________
Theoretical 58.21 4.10 5.22
Found 58.15 3.99 5.16
______________________________________
Then 30 g of the compound (XVI), 35 g of the compound (VIII) and 175 g of concentrated sulfuric acid were stirred at ordinary temperature for 48 hours to cause a condensation reaction. The product was discharged into 1 l of water, and the precipitate was filtered off, washed with an aqueous solution of caustic soda, and recrystallized with toluene. Then 30.8 g (51.8 percent of theoretical yield) of 2-(3',4'-dichloroanilino)-6-diethylaminofluoran (XV) was obtained. The product was slightly colored powder (m.p. 189° to 190° C.), and developed a black color in the presence of clay, a green color with resin, and a blackish green color with bisphenol A.
From the following analysis result, it was confirmed that the product was C30 H24 Cl2 N2 O3.
______________________________________
C H N
______________________________________
Theoretical 67.80 4.52 5.28
Found 68.00 4.54 5.20
______________________________________
40 g of 3-methyl-p-acetanisidide (Beilstein, Supplement No. 1, vol. 13, p. 223), 51.5 g of p-chlorobromobenzene, 17.5 g of potassium carbonate, 1 g of copper powder and a small quantity of iodine were allowed to react with each other at 200° C. for 40 hours, and then, after addition of 20 g of potassium hydroxide and 100 ml of ethyl alcohol, further heated under reflux for 24 hours. The product was discharged into water, extracted with 200 ml of benzene, and distilled in vacuo. Then 48.2 g (87.3 percent of theoretical yield) of 2-methyl-4-methoxy-4'-chlorodiphenylamine (XVIII) was obtained, and it was found to be a yellow viscous liquid (b.p. 185° to 187° C./3 mmHg).
From the following analysis result, it was confirmed that the product was C14 H14 ClNO.
______________________________________
C H N
______________________________________
Theoretical 67.88 5.66 5.66
Found 67.40 5.42 5.45
______________________________________
Then 24.75 g of the compound (XVIII) 31.3 g of the compound (VIII) and 150 g of concentrated sulfuric acid were stirred at ordinary temperature for 40 hours. The product was discharged into 700 ml of water, and the precipitate was filtered off, washed with an aqueous solution of caustic soda, and recrystallized with 600 ml of toluene. Then 41.3 g (80.8 percent of theoretical yield) of 2-p-chloroanilino-3-methyl-6-diethylaminofluoran (XVII) was obtained. The product was a pale-yellow powder (m.p. 212° to 213° C.), and developed a black color in the presence of clay, resin and bisphenol A respectively.
From the following analysis result, it was confirmed that the product was C31 H27 ClN2 O3.
______________________________________
C H N
______________________________________
Theoretical 72.87 5.29 5.48
Found 73.93 5.35 5.31
______________________________________
54.5 g of 3-methyl-p-acetanisidide, 70 g of m-chlorobromobenzene, 25 g of potassium carbonate, 1 g of copper powder and a small quantity of iodine were allowed to react with each other at 220° C. for 24 hours, and then, after addition of 27 g of potassium hydroxide and 150 ml of ethanol, further heated under reflux for 20 hours. The product was discharged into water, and the precipitate was filtered off and distilled in vacuo. Then 61 g (81 percent of theoretical yield) of 2-methyl-4-methoxy-3'-chlorodiphenylamine (XX) was obtained, and it was found to be pale-yellow crystals (b.p. 153° to 154° C./3 mmHg, m.p. 75° to 77° C.).
From the following analysis result, it was confirmed that the product was C14 H14 ClNO.
______________________________________
C H N
______________________________________
Theoretical 67.88 5.66 5.66
Found 67.20 5.38 5.41
______________________________________
Then 24.75 g of the compound (XX), 31.3 g of the compound (VIII) and 150 g of concentrated sulfuric acid were stirred at ordinary temperature for 48 hours. The product was discharged into 1 l of water. And the precipitate was filtered off, washed with an aqueous solution of caustic soda, and recrystallized with 300 ml of toluene and 4 g of activated charcoal. Then 27.5 g (53.8 percent of theoretical yield) of 2-m-chloroanilino-3-methyl-6-diethylaminofluoran (XIX) was obtained. The product was a white powder (m.p. 211° to 212° C.), and developed a black color in the presence of clay, resin and bisphenol A, respectively. From the following analysis result, it was confirmed that the product was C31 H27 ClN2 O3.
______________________________________
C H N
______________________________________
Theoretical 72.87 5.29 5.48
Found 73.64 5.11 5.27
______________________________________
42.5 g of 3-methyl-p-acetanisidide, 50 g of o-chlorobromobenzene, 18 g of potassium carbonate, 1 g of copper powder and a small quantity of iodine were allowed to react with each other at 220° C. for 24 hours, and then, after addition of 30 g of potassium hydroxide and 100 ml of ethyl alcohol, further heated under reflux for 20 hours. The product was discharged into water, and the precipitate was filtered off and distilled in vacuo. Then 46.9 g (80 percent of theoretical yield) of 2-methyl-4-methoxy-2'-chlorodiphenylamine (XXII) was obtained, and it was found to be yellow crystals (m.p. 90° to 91° C., b.p. 165° to 170° C./3 mmHg).
From the following analysis result, it was confirmed that the product was C14 H14 ClNO.
______________________________________
C H N
______________________________________
Theoretical
67.88 5.66 5.66
Found 67.05 5.56 5.68
______________________________________
Then 17 g of the compound (XXII), 21.5 g of the compound (VIII) and 120 g of concentrated sulfuric acid were stirred at ordinary temperature for 40 hours. The product was discharged into 500 ml of water, and the precipitate was filtered off, washed with an aqueous solution of caustic soda, and recrystallized with 350 ml of toluene. Then 21 g (59.8 percent of theoretical yield) of 2-o-chloroanilino-3-methyl-6-diethylaminofluoran (XXI) was obtained. The product was a slightly colored powder (m.p. 192° to 193° C.).
From the following analysis result, it was confirmed that the product was .[.C13 H27 ClN2 O3 .]. .Iadd.C31 H27 ClN2 O3.Iaddend..
______________________________________
C H N
______________________________________
Theoretical
72.87 5.29 5.48
Found 72.91 5.23 5.25
______________________________________
18.95 g of 3-methyl-p-acetanisidide, 25 g of p-dibromobenzene, 9 g of potassium carbonate, 0.5 g of copper powder and a small quantity of iodine were allowed to react with each other at 220° C. for 20 hours, and then, after addition of 20 g of potassium hydroxide and 100 ml of ethyl alcohol, further heated under reflux for 22 hours. The product was discharged into water, extracted with 100 ml of toluene, and distilled in vacuo. Then 11.5 g (37.2 percent of theoretical yield) of 2-methyl-4-methoxy-4'-bromodiphenylamine (XXIV) was obtained, and it was found to be a yellow viscous liquid (b.p. 195° to 200° C./4 mmHg).
From the following analysis result, it was confirmed that the product was C14 H14 BrNO.
______________________________________
C H N
______________________________________
Theoretical
59.57 4.79 4.79
Found 59.91 4.88 4.75
______________________________________
Then 5 g of the compound (XXIV), 5.36 g of the compound (VIII) and 35 g of concentrated sulfuric acid were stirred at ordinary temperature for 40 hours, and the product was discharged into 200 ml of water. The precipitate was filtered off, washed with an aqueous solution of caustic soda, and recrystallized with 100 ml of toluene. Then 6.9 g (72.6 percent of theoretical yield) of 2-p-bromoanilino-3-methyl-6-diethylaminofluoran (XXIII) was obtained. The product was a slightly colored powder, and developed a black color in the presence of clay, resin and a bisphenol A respectively.
From the following analysis result, it was confirmed that the product was C31 H27 BrN2 O3.
______________________________________
C H N
______________________________________
Theoretical
67.03 4.86 5.05
Found 67.82 4.64 4.95
______________________________________
40 g of 3-methyl-p-acetanisidide, 50 g of 3-methyl-4-chlorobromobenzene, 17.5 g of potassium carbonate, 1 g of copper powder and a small quantity of iodine were allowed to react with each other at 210° C. for 24 hours, and then, after addition of 20 g. of potassium hydroxide and 100 ml of ethyl alcohol, further heated under reflux for 20 hours. The product was discharged into water, and the precipitate was filtered off and distilled in vacuo. The 48.7 g (83.4 percent of theoretical yield) of 2,3'-dimethyl-4-methoxy-4'-chlorodiphenylamine (XXVI) was obtained, and it was found to be pale-yellow crystals (b.p. 200° to 205° C./4 mmHg, m.p. 86° to 87° C.).
From the following analysis result, it was confirmed that the product was C15 H16 ClNO.
______________________________________
C H N
______________________________________
Theoretical
68.83 6.12 5.35
Found 68.16 6.04 5.22
______________________________________
Then 26.15 g of the compound (XXVI), 31.3 g of the compound (VIII) and 150 g of concentrated sulfuric acid were stirred at ordinary temperature for 40 hours, and the product was discharged into 1 l of water. The precipitate was filtered off, washed with an aqueous solution of caustic soda, and recrystallized with 600 ml of toluene. The 40.1 g (65 percent of theoretical yield) of 2-(3'-methyl-4'-chloroanilino)-3-methyl-6-diethylaminofluoran (XXV) was obtained. The product was a slightly colored powder (m.p. 148° to 150° C.) and developed a black color in the presence of clay, resin and bisphenol A, respectively.
From the following analysis result, it was confirmed that the product was C32 H29 ClN2 O3.C7 H8.
______________________________________
C H N
______________________________________
Theoretical
75.91 6.00 4.54
Found 75.03 5.54 4.52
______________________________________
40 g of 3-methyl-p-acetanisidide, 55.5 g of 3,5-dichlorobromobenzene, 17.5 g of potassium carbonate, 1 g of copper powder and a small quantity of iodine were allowed to react with each other for 24 hours, and then, after addition of 20 g of potassium hydroxide and 100 ml of ethyl alcohol, further heated under reflux for 20 hours. The product was discharged into water, and the precipitate was filtered off and distilled in vacuo. Then 44 g (69.8 percent of theoretical yield) of 2-methyl-4-methoxy-3',5'-dichlorodiphenylamine (XXVIII) was obtained, and it was found to be pale-yellow crystals (b.p. 192° to 193° C./4 mmHg, m.p. 104° to 106° C.).
From the following analysis result, it was confirmed that the product was C14 H13 Cl2 NO.
______________________________________
C H N
______________________________________
Theoretical
59.57 4.61 4.96
Found 59.86 4.74 4.97
______________________________________
Then 28.2 g of the compound (XXVIII) 31.3 g of the compound (VIII) and 150 g of concentrated sulfuric acid were stirred at ordinary temperature for 24 hours, and the product was discharged into 1 l of water. The precipitate was filtered off, washed with an aqueous solution of caustic soda, and recrystallized with 700 ml of toluene. Then 41.7 g (76.5 percent of theoretical yield) of 2-(3',5'-dichloroanilino)-3-methyl-6-diethylaminofluoran (XXVII) was obtained. The product was a white powder (m.p. 224° to 225° C.) and developed a purple color in the presence of clay and a brown color in the presence of resin and bisphenol A, respectively.
From the following analysis result, it was confirmed that the product was C31 H26 Cl2 N2 O3.
______________________________________
C H N
______________________________________
Theoretical
68.26 4.77 5.14
Found 67.86 4.68 4.89
______________________________________
18 g of 3-methyl-p-acetanisidide, 25 g of 3,4-dichlorobromobenzene, 8 g of potassium carbonate, 0.5 g of copper powder and a small quantity of iodine were allowed to react with each other at 200° C. for 24 hours, and then, after addition of 10 g of potassium hydroxide and 50 ml of ethanol, further heated under reflux for 22 hours. The product was discharged into water, extracted with 100 ml of toluene, and distilled in vacuo. Then 19 g (66.9 percent of theoretical yield) of 2-methyl-4-methoxy-3',4'-dichlorodiphenylamine (XXX) was obtained, and it was found to be yellow crystals (b.p. 203° to 210° C./3 mmHg, m.p. 80° to 90° C.).
From the following analysis result, it was confirmed that the product was C14 H13 Cl2 NO.
______________________________________
C H N
______________________________________
Theoretical
59.57 4.61 4.96
Found 57.63 4.32 4.92
______________________________________
Then 18 g of the compound (XXX), 20 g of the compound (VIII) and 100 g of concentrated sulfuric acid were stirred at ordinary temperature for 44 hours, and the product was discharged into 500 ml of water. The precipitate was filtered off, washed with an aqueous solution of caustic soda, and recrystallized with 400 ml of toluene. Then 23.7 g (68 percent of theoretical yield) of 2-(3',4'-dichloroanilino)-3-methyl-6-diethylaminofluoran (XXIX) was obtained. The product was a slightly colored powder (m.p. 190° to 191° C.) and developed a purple color in the presence of clay and a black color in the presence of resin and bisphenol A, respectively.
From the following analysis result, it was confirmed that the product was C31 H26 Cl2 N2 O3.
______________________________________
C H N
______________________________________
Theoretical
68.26 4.77 5.14
Found 66.95 4.34 4.83
______________________________________
30 g of p-acetophenetidide, 45.5 g of 2,5-dichlorobromobenzene, 13 g of potassium carbonate, 1 g of copper powder and a small quantity of iodine were allowed to react with each other at 210° C. for 24 hours, and then, after addition of 15 g of potassium hydroxide and 75 ml of ethanol, further heated under reflux for 20 hours. The product was discharged into water, extracted with 150 ml of toluene, and distilled in vacuo. Then 33.1 g (70 percent of theoretical yield) of 2,5-dichloro-4'-ethoxydiphenylamine (XXXII) was obtained, and it was found to be a yellow viscous liquid (b.p. 190° to 195° C./4 mmHg).
From the following analysis result, it was confirmed that the product was C14 H13 Cl2 NO.
______________________________________
C H N
______________________________________
Theoretical
59.57 4.61 4.96
Found 59.73 4.64 4.98
______________________________________
Then 10 g of the compound (XXXII), 11.1 g of the compound (VIII) and 75 g of concentrated sulfuric acid were stirred at ordinary temperature for 40 hours, and the product was discharged into 500 ml of water. The precipitate was filtered off, washed with an aqueous solution of caustic soda, and recrystallized with 200 ml of toluene. Then 10.5 g (55.8 percent of theoretical yield) of 2-(2',5'-dichloroanilino)-6-diethylaminofluoran (XXXI) was obtained. The product was a white powder (m.p. 184° to 185° C.) and developed a black color in the presence of clay and bisphenol A, respectively, and a green color in the presence of resin.
From the following analysis result, it was confirmed that the product was C30 H24 Cl2 N2 O3.
______________________________________
C H N
______________________________________
Theoretical
67.80 4.52 5.28
Found 67.65 4.50 5.30
______________________________________
10 g of the compound (VII, see EXAMPLE 1) and 6.5 g of dimethylsulfuric acid were allowed to react with each other at 90° C. for 20 hours, and then, after addition of 60 g of a 10 percent aqueous solution of caustic soda, further heated under stirring for 1 hour. The product was extracted with 50 ml of toluene and distilled in vacuo. Then 8.8 g (83.2 percent of theoretical yield) of 4-ethoxy-4'-chloro-N-methyl-diphenylamine (XXXIV) was obtained, and it was found to be pale-yellow crystals (b.p. 185° to 188° C./4 mmHg, m.p. 56° to 57° C.).
From the following analysis result, it was confirmed that the product was C15 H16 ClNO.
______________________________________
C H N
______________________________________
Theoretical
68.83 6.12 5.35
Found 68.64 6.10 5.27
______________________________________
Then 7 g of the compound (XXXIV), 8.9 g of the compound (VIII) and 60 g of concentrated sulfuric acid were stirred at ordinary temperature for 48 hours, and the product was discharged into 500 ml of water. The precipitate was filtered off, washed with an aqueous solution of caustic soda, and recrystallized with 120 ml of toluene. Then 10.5 g (71 percent of theoretical yield) of 2-(4'-chloro-N-methylanilino)-6-diethylaminofluoran (XXXIII) was obtained. The product was a white powder (m.p. 189° to 190° C.) and developed a green color in the presence of clay, resin and bisphenol A, respectively.
From the following analysis result, it was confirmed that the product was C31 H27 ClN2 O3.
______________________________________
C H N
______________________________________
Theoretical
72.87 5.29 5.48
Found 72.43 5.16 5.36
______________________________________
10 g of the compound (VII, see EXAMPLE 1) and 10 g of diethylsulfuric acid were allowed to react with each other at 90° C. for 17 hours, and then, after addition of 50 g of a 10 percent aqueous solution of caustic soda, further heated under stirring for 1 hour. The product was extracted with 50 ml of toluene and distilled in vacuo. Then 7.3 g (65.5 percent of theoretical yield) of 4-ethoxy-4'-chloro-N-ethyldiphenylamine (XXXVI) was obtained, and it was found to be white crystals (b.p. 187° to 190° C./6 mmHg, m.p. 61° to 62° C.).
From the following analysis result, it was confirmed that the product was C16 H18 ClNO.
______________________________________
C H N
______________________________________
Theoretical
69.69 6.53 5.08
Found 69.71 6.48 5.02
______________________________________
Then 5 g of the compound (XXXVI), 5.7 g of the compound (VIII) and 40 g of concentrated sulfuric acid were stirred at ordinary temperature for 44 hours, and the product was discharged into 500 ml of water. The precipitate was filtered off, washed with an aqueous solution of caustic soda, and recrystallized with 100 ml of toluene. Then 4 g (42.1 percent of theoretical yield) of 2-(4'-chloro-N-ethylanilino)-6-diethylaminofluroan (XXXV) was obtained. The product was a white powder (m.p. 156° to 158° C.) and developed a green color in the presence of clay, resin and bisphenol A respectively.
From the following analysis result, it was confirmed that the product was C32 H29 ClN2 O3.
______________________________________
C H N
______________________________________
Theoretical
73.21 5.53 5.34
Found 72.98 5.52 5.26
______________________________________
11.45 g of the compound (XXVI, see EXAMPLE 10), 12.5 g of 4-dimethylamino-2-hydroxy-2'-carboxybenzophenone and 70 g of concentrated sulfuric acid were stirred at ordinary temperature for 40 hours, and the product was discharged into 1 l of water. The precipitate was filtered off, washed with aqueous solution of caustic soda, and recrystallized with 200 ml of toluene. Then 15.8 g (72.5 percent of theoretical yield) of 2-(4'-chloro-3'-methylanilino)-3-methyl-6-dimethylaminofluoran (XXXVII) was obtained. The product was a white powder (m.p. 215° to 216° C.) and developed a black color in the presence of clay, resin and bisphenol A.
From the following analysis result, it was confirmed that the product was C30 H25 ClN2 O3.
______________________________________
C H N
______________________________________
Theoretical
72.50 5.04 5.64
Found 72.70 5.09 5.47
______________________________________
5 g of 2-p-chloroanilino-6-diethylaminofluoran (VI, Example 1) is heated with 120 g of mono-isopropyl biphenyl up to 100° C. and dissolved into the latter, and then emulsified together with a solution of 25 g of gum arabic in 400 ml of water. Next, a solution of 25 g of gelatin in 400 ml of water is added to complete the emulsification, and acetic acid is added to adjust so as to obtain pH 4. At this time, liquid films of gelatin/gum arabic are formed around oil drops containing fluoran compound. 500 ml of water is added to the emulsion, and then it is cooled to below 10° C. 5 ml of 37 percent formalin solution is added to cure the films. A solution of 10% caustic soda is added to adjust so as to obtain pH 9, and the temperature is slowly restored to room temperature. The suspension thus obtained is applied to the under surface of upper leaf, and it is dried. Meanwhile, solid acid such as active clay, phenol compound, etc. is applied to the upper surface of lower leaf.
When copying is carried out by means of the upper leaf and lower leaf prepared by the above-mentioned method, the lower leaf which has active clay or phenol compound on its upper surface rapidly develops green color.
35 G of 2-p-chloroanilino-3-methyl-6-diethylamino fluoran (XVII, Example 6), 150 g of 10 weight percent polyvinyl alcohol aqueous solution, and 65 g of water are ground and mixed for an hour. (A liquid).
Meanwhile, 35 g of bisphenol A, 150 g of 10 weight percent polyvinyl alcohol aqueous solution, and 65 g of water are ground and mixed for an hour. (B liquid)
Next, 3 weight parts of A liquid and 67 weight parts of B liquied are mixed and disparsed, and then applied to paper.
When the heat-sensitive copying paper thus prepared is added heat partially by means of a thermal pen or an exothermic head, it rapidly develops black color.
Claims (2)
- 4..]. .[.2. A heat or pressure sensitive copying paper of claim 1 wherein said fluoran is 2-p-chloroanilino-6-diethylaminofluoran..]. .[.3. A heat or pressure sensitive copying paper of claim 1 wherein said fluoran is 2-m-chloroanilino-6-diethylaminofluoran..]. .[.4. A heat or pressure sensitive copying paper of claim 1 wherein said fluoran is 2-o-chloroanilino-6-diethylaminofluoran..]. .[.5. A heat or pressure sensitive copying paper of claim 1 wherein said fluoran is 2-(3',5'-dichloroanilino)-6-diethylaminofluoran..]. .[.6. A heat or pressure sensitive copying paper of claim 1 wherein said fluoran is 2-(3',4'-dichloroanilino)-6-diethylaminofluoran..]. .[.7. A heat or pressure sensitive copying paper of claim 1 wherein said fluoran is 2-p-chloroanilino-3-methyl-6-diethylaminofluoran..]. .[.8. A heat or pressure sensitive copying paper of claim 1 wherein said fluoran is 2-m-chloroanilino-3-methyl-6-diethylaminofluoran..]. .[.9. A heat or pressure sensitive copying paper of claim 1 wherein said fluoran is
- 2-o-chloroanilino-3-methyl-6-diethylaminofluoran..]. .[.10. A heat or pressure sensitive copying paper of claim 1 wherein said fluoran is 2-p-bromoanilino-3-methyl-6-diethylaminofluoran..]. .[.11. A heat or pressure sensitive copying paper of claim 1 wherein said fluoran is 2-(4'-chloro-3'-methylanilino)-3-methyl-6-diethylaminofluoran..]. .[.12. A heat or pressure sensitive copying paper of claim 1 wherein said fluoran is 2-(3',5'-dichloroanilino)-3- methyl-6-diethylaminofluoran..]. .[.13. A heat or pressure sensitive copying paper of claim 1 wherein said fluoran is 2-(3',4'-dichloroanilino)-3-methyl-6-diethylaminofluoran..]. .[.14. A heat or pressure sensitive copying paper of claim 1 wherein said fluoran is 2-(2',5'-dichloroanilino)-6-diethylaminofluoran..]. .[.15. A heat or pressure sensitive copying paper of claim 1 wherein said fluoran is 2-(4'-chloro-N-methylanilino)-6-diethylaminofluoran..]. .[.16. A heat or pressure sensitive copying paper of claim 1 wherein said fluoran is 2-(4'-chloro-N-ethylanilino)-6-diethylaminofluoran..]. .[.17. A heat or pressure sensitive copying paper of claim 1 wherein said fluoran is 2-(4'-chloro-3-'-methylanilino)-3-methyl-6-dimethylaminofluoran..]. .[.18. A heat sensitive copying paper of claim 1..]. .[.19. A pressure sensitive copying paper of claim 1..]. .Iadd. 20. A heat or pressure sensitive copying paper containing a fluoran compound as a color former, said color being developed in said heat or pressure sensitive copying paper through the application of heat or pressure, said fluoran compound being selected from the group consisting of 2-m-chloroanilino-6-diethylaminofluoran; 2-o-chloroanilino-6-diethylaminofluoran; 2-(3',5'-dichloroanilino)-6-diethylaminofluoran; 2-(3',4'-dichloroanilino)-6-diethylaminofluoran; 2-p-chloroanilino-3-methyl-6-diethylaminofluoran; 2-m-chloroanilino-3-methyl-6-diethylaminofluoran; 2-o-chloroanilino-3-methyl-6-diethylaminofluoran; 2-p-bromoanilino-3-methyl-6-diethylaminofluoran; 2-(4'-chloro-3'-methylanilino)-3-methyl-6-diethylaminofluoran; 2-(3',5'-dichloroanilino)-3-methyl-6-diethylaminofluoran; 2-(3',4'-dichloroanilino)-3-methyl-6-diethylaminofluoran; 2-(2',5'-dichloroanilino)-6-diethylaminofluoran; 2-(4'-chloro-N-methylanilino)-6-diethylaminofluoran; 2-(4'-chloro-N-ethylanilino)-6-diethylaminofluoran and 2-(4'-chloro-3'-methylanilino)3-methyl-6-dimethylaminofluoran. .Iaddend..Iadd. 21. A heat sensitive copying paper containing a fluoran compound as a color former, said color being developed in said heat sensitive copying paper through the application of heat, said fluoran compound being 2-m-chloroanilino-6-diethylaminofluoran. .Iaddend..Iadd. 22. A heat sensitive copying paper containing a fluoran compound as a color former, said color being developed in said heat sensitive copying paper through the application of heat, said fluoran compound being 2-o-chloroanilino-6-diethylaminofluoran. .Iaddend.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP47077081A JPS4934526A (en) | 1972-08-01 | 1972-08-01 | |
| JP47-77081 | 1972-08-01 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US384304A Reissue US3920510A (en) | 1972-08-01 | 1973-07-31 | Pressure-and-heat-sensitive copying paper |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| USRE31412E true USRE31412E (en) | 1983-10-11 |
Family
ID=13623817
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US384304A Expired - Lifetime US3920510A (en) | 1972-08-01 | 1973-07-31 | Pressure-and-heat-sensitive copying paper |
| US06/153,660 Expired - Lifetime USRE31412E (en) | 1972-08-01 | 1980-05-27 | Pressure-and-heat-sensitive copying paper |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US384304A Expired - Lifetime US3920510A (en) | 1972-08-01 | 1973-07-31 | Pressure-and-heat-sensitive copying paper |
Country Status (2)
| Country | Link |
|---|---|
| US (2) | US3920510A (en) |
| JP (1) | JPS4934526A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4927802A (en) | 1988-12-09 | 1990-05-22 | Ppg Industries, Inc. | Pressure-sensitive multi-part record unit |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4156682A (en) * | 1973-10-05 | 1979-05-29 | Sumitomo Chemical Company, Limited | Fluoran compounds and recording sheet containing them |
| JPS5953193B2 (en) * | 1978-02-15 | 1984-12-24 | 神崎製紙株式会社 | heat sensitive recording material |
| US4287264A (en) * | 1980-03-07 | 1981-09-01 | Labelon Corporation | Heat sensitive coating |
| US4515971A (en) * | 1980-03-31 | 1985-05-07 | Hilton-Davis Chemical Co. | 5'/6'-Carboxyfluorans and derivatives thereof |
| JPS6053069B2 (en) * | 1980-09-17 | 1985-11-22 | 保土谷化学工業株式会社 | Fluoran compounds |
| US4524373A (en) * | 1982-02-24 | 1985-06-18 | Kanzaki Paper Manufacturing Co., Ltd. | Fluoran derivatives as new compounds, process for preparing the same and recording system utilizing the same as colorless chromogenic material |
| JPS58162663A (en) * | 1982-03-19 | 1983-09-27 | Fuji Photo Film Co Ltd | Fluoran derivative and recording material using the same |
| JPS591297A (en) * | 1982-06-29 | 1984-01-06 | Mita Ind Co Ltd | Black heat-sensitive recording element |
| JPS592890A (en) * | 1982-06-30 | 1984-01-09 | Mita Ind Co Ltd | Black-color heat-sensitive recording material |
| JPS59136349A (en) * | 1983-01-25 | 1984-08-04 | Yamada Kagaku Kogyo Kk | Fluoran and color-developing recording material |
| JPS59190891A (en) * | 1983-04-14 | 1984-10-29 | Hodogaya Chem Co Ltd | Thermal recording material |
| US5166350A (en) * | 1989-06-10 | 1992-11-24 | Ciba-Geigy Corporation | Process for the manufacture of fluoran compounds |
| US5284816A (en) * | 1992-11-19 | 1994-02-08 | Eastman Kodak Company | Two-sided thermal printing system |
| US5693374A (en) | 1994-06-23 | 1997-12-02 | Fuji Photo Film Co., Ltd. | Alpha-resorcyclic acid ester derivatives and recording materials using the same |
| US6127084A (en) * | 1998-10-23 | 2000-10-03 | Cycolor, Inc. | Photosensitive material employing microcapsules containing a hygroscopic polymer in the internal phase |
| US6037094A (en) * | 1998-10-23 | 2000-03-14 | Cycolor, Inc. | Photosensitive material employing microcapsules and superabsorbent polymer |
| US6638678B2 (en) | 2001-11-20 | 2003-10-28 | Hsbc Bank Usa | Method for improving sensitometric response of photosensitive imaging media employing microcapsules |
| US6964836B2 (en) | 2002-03-15 | 2005-11-15 | Eastman Kodak Company | Photosensitive microcapsules containing a synthetic viscosity modifier in the continuous phase |
| US7108190B2 (en) * | 2003-02-28 | 2006-09-19 | Appleton Papers Inc. | Token array and method employing authentication tokens bearing scent formulation information |
| US6932602B2 (en) * | 2003-04-22 | 2005-08-23 | Appleton Papers Inc. | Dental articulation kit and method |
| US20060063125A1 (en) * | 2003-04-22 | 2006-03-23 | Hamilton Timothy F | Method and device for enhanced dental articulation |
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|---|---|---|---|---|
| DE2049503A1 (en) | 1969-10-08 | 1971-04-22 | Fuji Photo Film Co , Ltd . Kanagawa (Japan) | Process for the production of fluoran compounds |
| DE2150666A1 (en) | 1970-10-12 | 1972-04-13 | Kanzaki Paper Mfg Co Ltd | Fluoran compounds, process for their preparation and their use in recording materials |
| US3669712A (en) * | 1969-06-27 | 1972-06-13 | Fuji Photo Film Co Ltd | Pressure-sensitive copying papers |
| US3681390A (en) * | 1970-11-16 | 1972-08-01 | Ncr Co | Dialkylamino fluoran chromogenic compounds |
| US3746562A (en) * | 1970-11-16 | 1973-07-17 | Ncr | Mark forming record materials |
| US3764369A (en) * | 1969-01-21 | 1973-10-09 | Ncr | Pressure sensitive recording unit |
-
1972
- 1972-08-01 JP JP47077081A patent/JPS4934526A/ja active Pending
-
1973
- 1973-07-31 US US384304A patent/US3920510A/en not_active Expired - Lifetime
-
1980
- 1980-05-27 US US06/153,660 patent/USRE31412E/en not_active Expired - Lifetime
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|---|---|---|---|---|
| US3764369A (en) * | 1969-01-21 | 1973-10-09 | Ncr | Pressure sensitive recording unit |
| US3669712A (en) * | 1969-06-27 | 1972-06-13 | Fuji Photo Film Co Ltd | Pressure-sensitive copying papers |
| DE2049503A1 (en) | 1969-10-08 | 1971-04-22 | Fuji Photo Film Co , Ltd . Kanagawa (Japan) | Process for the production of fluoran compounds |
| DE2150666A1 (en) | 1970-10-12 | 1972-04-13 | Kanzaki Paper Mfg Co Ltd | Fluoran compounds, process for their preparation and their use in recording materials |
| US3825561A (en) * | 1970-10-12 | 1974-07-23 | Sumitomo Chemical Co | Fluoran compounds |
| US3681390A (en) * | 1970-11-16 | 1972-08-01 | Ncr Co | Dialkylamino fluoran chromogenic compounds |
| US3746562A (en) * | 1970-11-16 | 1973-07-17 | Ncr | Mark forming record materials |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4927802A (en) | 1988-12-09 | 1990-05-22 | Ppg Industries, Inc. | Pressure-sensitive multi-part record unit |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS4934526A (en) | 1974-03-30 |
| US3920510A (en) | 1975-11-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| AS | Assignment |
Owner name: ESCO COMPANY LIMITED PARTNERSHIP, MICHIGAN Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:APPLETON PAPERS INC.;REEL/FRAME:005866/0144 Effective date: 19910614 |