US998007A - Explosive. - Google Patents
Explosive. Download PDFInfo
- Publication number
- US998007A US998007A US60115111A US1911601151A US998007A US 998007 A US998007 A US 998007A US 60115111 A US60115111 A US 60115111A US 1911601151 A US1911601151 A US 1911601151A US 998007 A US998007 A US 998007A
- Authority
- US
- United States
- Prior art keywords
- explosive
- parts
- agglutinant
- collodion
- glycerin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002360 explosive Substances 0.000 title description 23
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 18
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 12
- 235000011187 glycerol Nutrition 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- ZPTVNYMJQHSSEA-UHFFFAOYSA-N 4-nitrotoluene Chemical compound CC1=CC=C([N+]([O-])=O)C=C1 ZPTVNYMJQHSSEA-UHFFFAOYSA-N 0.000 description 7
- 150000002823 nitrates Chemical class 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 239000003513 alkali Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 4
- 239000012286 potassium permanganate Substances 0.000 description 4
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 3
- 229910002651 NO3 Inorganic materials 0.000 description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000004200 deflagration Methods 0.000 description 2
- 238000004880 explosion Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 235000010333 potassium nitrate Nutrition 0.000 description 2
- 239000004323 potassium nitrate Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- AQDKZPFDOWHRDZ-UHFFFAOYSA-N 2-methyl-6-nitrophenol Chemical compound CC1=CC=CC([N+]([O-])=O)=C1O AQDKZPFDOWHRDZ-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- MHWLNQBTOIYJJP-UHFFFAOYSA-N mercury difulminate Chemical compound [O-][N+]#C[Hg]C#[N+][O-] MHWLNQBTOIYJJP-UHFFFAOYSA-N 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B47/00—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase
- C06B47/14—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase comprising a solid component and an aqueous phase
Definitions
- the object of the-present invention is a highexplosive consisting substantially of a mixture of nitrates and aluminum powder, to which an agglutinant can be added.
- composition of the explosive is as follows:
- an agglutinant is employed in proportions of 10- to 20 per cent, said a'gglutinant having preferably the following composition:
- the nitrates After having been perfectly dried, are ground finely and mixed with the aluminum powder, and the whole is stirred until a uniform composition is obtained.
- the agglutinant when it is required, is added in the proportion of about 10% and the whole is mixed thoroughly.
- the explosive thus obtained can be utilized in forming the charge of perforating projectiles, mine grenades and can be employed for industrial uses.
- the particular advantages of the explosive thus composed are the following: (a) Itis. composed of matters which do not react-together, thus insuring the greatest stability;. (b) it can, remain for a long time 'at a temperature variable between to C. even for several months Without undergoing alterations of any kind, As soon as the temperature of 98100 is reached, the sublimation of the ammoniacal salts begins; at 160 it melts and at a higher temperature it dries up. (0) By raising the temperature suddenly above 450, the decomposition and drying up of the explosive is produced causing neither explosion (d) When the explosive thus prepared is compressed, it can be worked at the lathe, with the chisel and the file without any precaution.
- the explosive can be struck with iron on iron without any danger of deflagration or decomposition.
- the power of the explosive measured in the Trauzl lead varies from 700 to 950 cubic centimeters with 15 gr. explosive. To produce the explosion a detonator of fulminate of mercury must be employed.
- An explosive consisting of alkali nitrates and aluminum powder and containing an agglutinant consisting of mononitrotoluol, glycerin, collodion, and an oxygenbearing substance.
- An explosive consisting of alkali n1- trates and aluminum powder and containing about 10 per cent. of an agglutinant consisting of mononitrotoluol, glycerin, collodion,
- An explosive consisting of alkali nitrates and aluminum powder and containing an agglutinant consisting of substantially 75 glycerin, 15 parts-collodion, and 3 parts of- I an oxygen-bearing substance.
- An explosive consisting of substantially 85 parts of alkali nitrates and 15 parts of aluminum powder and containing an ag lutinant consisting of mononitrotoluol, yoand an oxygen-bearing substance.
- An explosive consisting of substantially. 85 parts of alkali nitrates and 15 parts aluminum powder and containing about 10 per cent. of an agglutinant consisting of substantially 75 parts mononitrotoluol, 5 parts glycerin, 15 parts collodion, and 3 parts potassium permanganate.
- Anexplosive comprising 80-85 parts ammonium nitrate, 15 parts aluminum powder, and containing about 10 per cent.
- an agglutinant consisting of mononitrotoluol, gylcerin, collodion, substance.
- An explosive consisting of 80 parts ammonium nitrate, 5 parts potassium nitrate,
- An explosive consisting of 80 parts amnitrate, potassium nitrate, aluminum 'powparts glycerin, 15 parts collodion,
- an agglutinant consisting of mononitrov toluol, glycerin, collodion, and potassium permanganate, and an inert substance in admixture therewith.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Description
onrrn ROBERTO IMPERIALI, or NAPLES, ITALY.
EXPLOSIVE.
Nd Drawing.
To all whom it may concern:
Beit known that I-,--R0BERT0 IMPERIALI, a subject of the King of Italy, residing at Naples, in the Kingdom of Italy, have invented certain new and useful Improvements in Explosives, of which the following is a specification.
The object of the-present invention is a highexplosive consisting substantially of a mixture of nitrates and aluminum powder, to which an agglutinant can be added.
The composition of the explosive is as follows:
Nitrate of ammonium-" 80 arts in wei ht p ,7 )9 Nitrate of potassium o In order to correct the hygroscopieity-of the nitrate of ammonium, and to increase the sensibility of the explosive, an agglutinant is employed in proportions of 10- to 20 per cent, said a'gglutinant having preferably the following composition:
Mononitrotolu-ol 7 5 parts in weight Glycerin 5 a v 77 COllOdion' 15 :1 vv
Potassium permanganate 3 As to the different components, of which? thesemixtures consist, it is remarked that in the composition of the explosive thelperthe glycerin can be increased or diminished according to the consistency to be given to the paste. It should be further remarked that the addition of the agglutinant is not absolutely necessary, and that the mixture of the nitrates with the powder of aluminum, or of the ammonium nitrate only with thepowder of aluminum is suflicient for constituting a perfect explosive. The agglutinant, by cementing the incoherent powders, renders the explosive thus prepared more fit for certain manipulations.
When it is desired to diminish the intensity of the explosive it will be convenient to add to the above mentioned mixtures inert substances, such as, for instance, the fossil Specification of Letters Patent.
'nor deflagration.
Patented July 18, 1911.
Application filed January 6, 1911. Serial No. 601,151.
flour in proportions of 2 to 10 per cent. of the mixture, according to the circumstances.
For the preparationthe nitrates, after having been perfectly dried, are ground finely and mixed with the aluminum powder, and the whole is stirred until a uniform composition is obtained. To the mixture thus obtained, the agglutinant, when it is required, is added in the proportion of about 10% and the whole is mixed thoroughly. The explosive thus obtained can be utilized in forming the charge of perforating projectiles, mine grenades and can be employed for industrial uses.
The particular advantages of the explosive thus composed are the following: (a) Itis. composed of matters which do not react-together, thus insuring the greatest stability;. (b) it can, remain for a long time 'at a temperature variable between to C. even for several months Without undergoing alterations of any kind, As soon as the temperature of 98100 is reached, the sublimation of the ammoniacal salts begins; at 160 it melts and at a higher temperature it dries up. (0) By raising the temperature suddenly above 450, the decomposition and drying up of the explosive is produced causing neither explosion (d) When the explosive thus prepared is compressed, it can be worked at the lathe, with the chisel and the file without any precaution. (e) The explosive can be struck with iron on iron without any danger of deflagration or decomposition. (f) The power of the explosive measured in the Trauzl lead varies from 700 to 950 cubic centimeters with 15 gr. explosive. To produce the explosion a detonator of fulminate of mercury must be employed.
I claim;
1. An explosive consisting of alkali nitrates and aluminum powder and containing an agglutinant consisting of mononitrotoluol, glycerin, collodion, and an oxygenbearing substance.
'2. An explosive consisting of alkali n1- trates and aluminum powder and containing about 10 per cent. of an agglutinant consisting of mononitrotoluol, glycerin, collodion,
and potassium permanganate.
3. An explosive consisting of alkali nitrates and aluminum powder and containing an agglutinant consisting of substantially 75 glycerin, 15 parts-collodion, and 3 parts of- I an oxygen-bearing substance.
erin, collodion,
p 4. An explosive consisting of substantially 85 parts of alkali nitrates and 15 parts of aluminum powder and containing an ag lutinant consisting of mononitrotoluol, yoand an oxygen-bearing substance.
5. An explosive consisting of substantially. 85 parts of alkali nitrates and 15 parts aluminum powder and containing about 10 per cent. of an agglutinant consisting of substantially 75 parts mononitrotoluol, 5 parts glycerin, 15 parts collodion, and 3 parts potassium permanganate.
6. Anexplosive comprising 80-85 parts ammonium nitrate, 15 parts aluminum powder, and containing about 10 per cent. ,pf an agglutinant consisting of mononitrotoluol, gylcerin, collodion, substance.
7. An explosive consisting of 80 parts ammonium nitrate, 5 parts potassium nitrate,
parts of mononitrotoluol, 5 parts and an oxygen-bearing- 15 parts aluminum powder, and containing an agglutinant consisting of mononitrotoluol, glycerin,,collodion, and an oxygenbearing substance.
8. An explosive consisting of 80 parts amnitrate, potassium nitrate, aluminum 'powparts glycerin, 15 parts collodion,
der, an agglutinant consisting of mononitrov toluol, glycerin, collodion, and potassium permanganate, and an inert substance in admixture therewith.
I In testimony whereof I hereunto affix my signature in the presence of two witnesses.
ROBERTO IMPERIALL Witnesses:
PIETRO CALzoNI, LEFEERN LABSOIETTA.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US60115111A US998007A (en) | 1911-01-06 | 1911-01-06 | Explosive. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US60115111A US998007A (en) | 1911-01-06 | 1911-01-06 | Explosive. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US998007A true US998007A (en) | 1911-07-18 |
Family
ID=3066337
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US60115111A Expired - Lifetime US998007A (en) | 1911-01-06 | 1911-01-06 | Explosive. |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US998007A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080245252A1 (en) * | 2007-02-09 | 2008-10-09 | Alliant Techsystems Inc. | Non-toxic percussion primers and methods of preparing the same |
| US20100116385A1 (en) * | 2005-03-30 | 2010-05-13 | Alliant Techsystems Inc. | Methods of forming a sensitized explosive and a percussion primer |
| US20110100246A1 (en) * | 2006-03-02 | 2011-05-05 | Alliant Techsystems Inc. | Percussion primers comprising a primer composition and ordnance including the same |
| US8202377B2 (en) | 2007-02-09 | 2012-06-19 | Alliant Techsystems Inc. | Non-toxic percussion primers and methods of preparing the same |
| US8206522B2 (en) | 2010-03-31 | 2012-06-26 | Alliant Techsystems Inc. | Non-toxic, heavy-metal free sensitized explosive percussion primers and methods of preparing the same |
| US8540828B2 (en) | 2008-08-19 | 2013-09-24 | Alliant Techsystems Inc. | Nontoxic, noncorrosive phosphorus-based primer compositions and an ordnance element including the same |
| US8641842B2 (en) | 2011-08-31 | 2014-02-04 | Alliant Techsystems Inc. | Propellant compositions including stabilized red phosphorus, a method of forming same, and an ordnance element including the same |
-
1911
- 1911-01-06 US US60115111A patent/US998007A/en not_active Expired - Lifetime
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8460486B1 (en) | 2005-03-30 | 2013-06-11 | Alliant Techsystems Inc. | Percussion primer composition and systems incorporating same |
| US20100116385A1 (en) * | 2005-03-30 | 2010-05-13 | Alliant Techsystems Inc. | Methods of forming a sensitized explosive and a percussion primer |
| US8282751B2 (en) | 2005-03-30 | 2012-10-09 | Alliant Techsystems Inc. | Methods of forming a sensitized explosive and a percussion primer |
| US20110100246A1 (en) * | 2006-03-02 | 2011-05-05 | Alliant Techsystems Inc. | Percussion primers comprising a primer composition and ordnance including the same |
| US9199887B2 (en) | 2006-03-02 | 2015-12-01 | Orbital Atk, Inc. | Propellant compositions including stabilized red phosphorus and methods of forming same |
| US8524018B2 (en) | 2006-03-02 | 2013-09-03 | Alliant Techsystems Inc. | Percussion primers comprising a primer composition and ordnance including the same |
| US8454769B2 (en) | 2007-02-09 | 2013-06-04 | Alliant Techsystems Inc. | Non-toxic percussion primers and methods of preparing the same |
| US20080245252A1 (en) * | 2007-02-09 | 2008-10-09 | Alliant Techsystems Inc. | Non-toxic percussion primers and methods of preparing the same |
| US8454770B1 (en) | 2007-02-09 | 2013-06-04 | Alliant Techsystems Inc. | Non-toxic percussion primers and methods of preparing the same |
| US8202377B2 (en) | 2007-02-09 | 2012-06-19 | Alliant Techsystems Inc. | Non-toxic percussion primers and methods of preparing the same |
| US8192568B2 (en) | 2007-02-09 | 2012-06-05 | Alliant Techsystems Inc. | Non-toxic percussion primers and methods of preparing the same |
| US8540828B2 (en) | 2008-08-19 | 2013-09-24 | Alliant Techsystems Inc. | Nontoxic, noncorrosive phosphorus-based primer compositions and an ordnance element including the same |
| US8470107B2 (en) | 2010-03-31 | 2013-06-25 | Alliant Techsystems Inc. | Non-toxic, heavy-metal free explosive percussion primers and methods of preparing the same |
| US8206522B2 (en) | 2010-03-31 | 2012-06-26 | Alliant Techsystems Inc. | Non-toxic, heavy-metal free sensitized explosive percussion primers and methods of preparing the same |
| US8641842B2 (en) | 2011-08-31 | 2014-02-04 | Alliant Techsystems Inc. | Propellant compositions including stabilized red phosphorus, a method of forming same, and an ordnance element including the same |
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