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US936637A - Method of coating metallic surfaces. - Google Patents

Method of coating metallic surfaces. Download PDF

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Publication number
US936637A
US936637A US43554608A US1908435546A US936637A US 936637 A US936637 A US 936637A US 43554608 A US43554608 A US 43554608A US 1908435546 A US1908435546 A US 1908435546A US 936637 A US936637 A US 936637A
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US
United States
Prior art keywords
metal
zinc
coated
coating
metallic surfaces
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US43554608A
Inventor
Charles J Kirk
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Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to US43554608A priority Critical patent/US936637A/en
Application granted granted Critical
Publication of US936637A publication Critical patent/US936637A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C24/00Coating starting from inorganic powder
    • C23C24/02Coating starting from inorganic powder by application of pressure only
    • C23C24/04Impact or kinetic deposition of particles
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C10/00Solid state diffusion of only metal elements or silicon into metallic material surfaces
    • C23C10/28Solid state diffusion of only metal elements or silicon into metallic material surfaces using solids, e.g. powders, pastes
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C10/00Solid state diffusion of only metal elements or silicon into metallic material surfaces
    • C23C10/60After-treatment
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/02Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • C23C2/026Deposition of sublayers, e.g. adhesion layers or pre-applied alloying elements or corrosion protection

Definitions

  • metals have been coated with zinc, tin,- and other metals by passing the metal .to be coated through a molten bath ofthe metal of which the coating is composed.
  • Metals have also been coated by depositing the zinc or other metal electrolytically and they have also been coated by what is known as the sherardizi'ngprocess I will now describe my Invention so that others skilled in the art may employ the same.
  • zinc flue dust contains-about ten per cent. of oxid of zinc
  • the flue dust may be mixed with water or oils and powdered charcoal to form a liquid or semi-liquid mass of paint or compound'which is then applied-to the surface of the metal to be sherardized either by dipping the metal in a bath of the compound or the same.
  • the metal so painted or coated is then placed in a muflle and subjected to heat the necessary length of time after which the plosion and the metal is withdrawn and allowed to cool.
  • this sherardized-surface forms a base upon which tin, zinc, or other metal may be deposited by passing the sherardized metal through a molten bath of the metal used to formthe coating, and owing to its peculiar qualities it causes an adhesion or amalgamation of the molten zinc, tin, or other metal far greater than would exist between the original surface of the metal and such coating, so much so that a coating having new and characteristic properties is produced on the surface of the sherardized metal.
  • the second step of my process therefore consists in dipping the sherardized metal in a molten bath of zinc, tin, or other metal in the usual manner employed in galvanizing, tinning and coating metals in a molten bath.
  • the excess of molten metal may. be wiped off in the usual manner.
  • the metal when so removed from the bath is ready for use or it may be subjected to various polishing and finishing steps well'known in the art.
  • the advantages of my invention are that as by the sherardizing step an amalgamation of the zinc, and the metal to be coated, takes place, so in the dipping step an amalgamation of the sherardized surface and the metal composing the molten bath takes place, producing a durable,amalgamated surface on the metal to be protected.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Coating With Molten Metal (AREA)
  • Powder Metallurgy (AREA)

Description

- muflie maybe opened without danger of ex-'-' CHARLES J. KIRK, OF CASTLE; PENNSYLVANIA.
A METHOD OF COATING METALLIC SURFACES.
No Drawing.
Specification of Letters latent.
Patented Oct. 12, 1909.
- Application filed May 28, 1908. Serial No.435,5 46.
To all whom it may concern:
Be it known that I, CHARLES J. KIRK, of
New Castle, in the county of Lawrence and State of Pennsylvania, have invented a certain new and useful Improvement in.
the metal to be protected with zinc flue-dust and then depositinga 'metal on the surface produced by. the amalgamation of the zinc flue dust.
Heretofore metals have been coated with zinc, tin,- and other metals by passing the metal .to be coated through a molten bath ofthe metal of which the coating is composed. Metals have also been coated by depositing the zinc or other metal electrolytically and they have also been coated by what is known as the sherardizi'ngprocess I will now describe my Invention so that others skilled in the art may employ the same.
In the practice of my invention I first sherardize the metal to be coated. This may be done by packing the metal to be coated'inwhat is known as zinc flue dust, which contains-about ten per cent. of oxid of zinc, and then placin the metal and the zinc flue dustin a suita le muflie from which the airis excluded and then subjecting it to heat for a suflicient length of time to. cause an amalgamation of the zinc with the metal to be coated. The mufiie is then allowed to cool and the sherardized metalis withdrawn. Or the flue dust may be mixed with water or oils and powdered charcoal to form a liquid or semi-liquid mass of paint or compound'which is then applied-to the surface of the metal to be sherardized either by dipping the metal in a bath of the compound or the same. The metal so painted or coated is then placed in a muflle and subjected to heat the necessary length of time after which the plosion and the metal is withdrawn and allowed to cool. I have-discovered that this sherardized-surface forms a base upon which tin, zinc, or other metal may be deposited by passing the sherardized metal through a molten bath of the metal used to formthe coating, and owing to its peculiar qualities it causes an adhesion or amalgamation of the molten zinc, tin, or other metal far greater than would exist between the original surface of the metal and such coating, so much so that a coating having new and characteristic properties is produced on the surface of the sherardized metal. The second step of my process therefore consists in dipping the sherardized metal in a molten bath of zinc, tin, or other metal in the usual manner employed in galvanizing, tinning and coating metals in a molten bath. As the metal is wlthdrawn from the bath the excess of molten metal may. be wiped off in the usual manner. The metal when so removed from the bath is ready for use or it may be subjected to various polishing and finishing steps well'known in the art.
The advantages of my invention are that as by the sherardizing step an amalgamation of the zinc, and the metal to be coated, takes place, so in the dipping step an amalgamation of the sherardized surface and the metal composing the molten bath takes place, producing a durable,amalgamated surface on the metal to be protected.
Having thus described my invention, what I claim and desire to secure byLetters Patent is:
sisting in sherardizing the metal to form a primarycoating and then dipping. the article so treated in abath of molten metal capable with the primary coating. by painting the surface of the metal with M. ARTHUR KELLEn,
M. A. EARTH.
1. The method of protecting metal, con-'
US43554608A 1908-05-28 1908-05-28 Method of coating metallic surfaces. Expired - Lifetime US936637A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US43554608A US936637A (en) 1908-05-28 1908-05-28 Method of coating metallic surfaces.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US43554608A US936637A (en) 1908-05-28 1908-05-28 Method of coating metallic surfaces.

Publications (1)

Publication Number Publication Date
US936637A true US936637A (en) 1909-10-12

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US43554608A Expired - Lifetime US936637A (en) 1908-05-28 1908-05-28 Method of coating metallic surfaces.

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3332800A (en) * 1962-10-29 1967-07-25 Nat Res Corp Method for producing a superconductor comprising a niobium-tin alloy coating
US4390377A (en) * 1981-01-12 1983-06-28 Hogg James W Novel continuous, high speed method of galvanizing and annealing a continuously travelling low carbon ferrous wire

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3332800A (en) * 1962-10-29 1967-07-25 Nat Res Corp Method for producing a superconductor comprising a niobium-tin alloy coating
US4390377A (en) * 1981-01-12 1983-06-28 Hogg James W Novel continuous, high speed method of galvanizing and annealing a continuously travelling low carbon ferrous wire

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