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US5551453A - Process for the temporary reshaping of keratinous fibres - Google Patents

Process for the temporary reshaping of keratinous fibres Download PDF

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Publication number
US5551453A
US5551453A US08/357,030 US35703094A US5551453A US 5551453 A US5551453 A US 5551453A US 35703094 A US35703094 A US 35703094A US 5551453 A US5551453 A US 5551453A
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US
United States
Prior art keywords
fibres
gas
process according
oil
keratinous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
US08/357,030
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English (en)
Inventor
Jean-Michel Sturla
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LOreal SA
Original Assignee
LOreal SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LOreal SA filed Critical LOreal SA
Assigned to L'OREAL reassignment L'OREAL ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: STURLA, JEAN-MICHEL
Application granted granted Critical
Publication of US5551453A publication Critical patent/US5551453A/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/04Preparations for permanent waving or straightening the hair
    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D7/00Processes of waving, straightening or curling hair
    • A45D7/06Processes of waving, straightening or curling hair combined chemical and thermal
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form

Definitions

  • the present invention relates to an improved process for the treatment of keratinous fibres, preferably human keratinous fibres and especially hair, for the purpose of obtaining a non-permanent reshaping and/or restoration of shape of the fibres, especially in the form of a setting.
  • the process of the invention is usable in the field of professional hairdressing, beauty and cosmetic salons, and the like. It relates still more specifically to a process employing water vapour and special treatment substances.
  • the term "setting” is known to denote the simple operation which consists of giving the hair an non-permanent and temporary set (generally wavy, such as ringlets, curls and the like) which vanishes instantaneously when the hair is wetted again, especially when the latter is subjected to the action of washing with water or with shampoos.
  • the "setting” process differs from a so-called permanent reshaping operation, during which genuine chemical treatments and/or conversions (reduction/oxidation) have to be carried out on the keratinous fibres, the final shape imposed on the hair becoming no longer sensitive (or remaining only very Slightly sensitive) to the above-mentioned external agents.
  • the most common technique for carrying out setting (or non-permanent reshaping) of hair consists in first placing previously wetted or still wet hair under tension (with traditional supports of the setting curler or roller type, and the like), in then drying the hair thus placed under tension under a salon hair dryer heating to a temperature ranging from 30° C. to 60° C. for a time which can vary from 20 to 60 minutes depending on the bulk of the hair to be dried, in thereafter removing the means for placing under tension used above from the hair thus dried, and lastly in putting the finishing touches to the hair with a comb in order to obtain the hairstyle with the desired final shape.
  • Another, less common, process consists of using the old so-called curling tongs or styling tongs technique (lock of wet hair coiled around a metal core and taken by the latter to more than 100° C. for at least 20 seconds); this latter technique is little used nowadays by professional hairdressers, since it achieves results which are considered on the whole to be unsatisfactory and uneven owing to the fact, in particular, that the hair is subjected to widely differing temperatures according to whether it is in actual contact with the heating core or, on the contrary, some distance away from the latter.
  • the aim of the present invention is, in particular, to solve the above problems.
  • the object of the present invention is to provide a new treatment process suitable for the non-permanent reshaping of keratinous fibres, preferably human keratinous fibres, and especially hair, which makes it possible to obtain curling of high quality.
  • Another object of the present invention is to provide a process as above which enables, in addition, this curling to be preserved on a long-lasting basis (retention).
  • Yet another object of the invention is to provide a process as above that makes it possible to obtain keratinous fibres which are reshaped non-permanently while displaying exceptional cosmetic properties of softness and smoothness.
  • the present invention thus provides a new process suitable for the non-permanent reshaping and/or restoration of shape of keratinous fibres, preferably human keratinous fibres, and especially hair.
  • This process comprises the steps of (a) contacting said fibres, said fibres being maintained under mechanical tension (rollers, curlers or the like) and having had applied thereto a composition containing at least one oil, with a gas containing water vapour, said gas having a temperature of at least 75° C., for a time not exceeding 2 minutes to non-permanently reshape said fibres, (b) cooling said fibres after said contacting step, and (c) removing the mechanical tension which was applied to said fibres.
  • the process according to the invention is preferably applicable to any human keratinous substance in general, in particular eyelashes, moustaches, and hairs generally, as well as to non-human keratinous fibres, for example, the hair of show dogs.
  • the gas used in the process of the present invention preferably contains at least 1% by volume of water vapour.
  • the carrier gas can contain solvent vapour, as well as gases such as oxygen or nitrogen, mixtures of gases such as air or alternatively other vapourizable compounds.
  • solvents which can advantageously be used for the production of vapour water/solvent mixtures
  • cosmetically acceptable organic solvents such as, for example, alcohols such as ethanol, isopropanol, benzyl alcohol and phenylethyl alcohol, or glycols or glycol ethers such as, for example, ethylene glycol and its monomethyl, monoethyl and monobutyl ethers, propylene glycol, butylene glycol, dipropylene glycol and also alkyl ethers such as diethylene glycol monobutyl ether.
  • alcohols such as ethanol, isopropanol, benzyl alcohol and phenylethyl alcohol
  • glycols or glycol ethers such as, for example, ethylene glycol and its monomethyl, monoethyl and monobutyl ethers, propylene glycol, butylene glycol, dipropylene glycol and also alkyl ethers such as diethylene glycol monobutyl ether.
  • the gas preferably consists either exclusively or chiefly of water vapour, or of a mixture of water and air.
  • the temperature of the gas is preferably above or equal to 85° C., and more preferably ranges from 85° C. to 150° C., approximately. The temperature can also range from 75° C. to less than 100° C.
  • the time of contact between the hot treatment gas and the fibre should be brief, and should preferably not exceed 2 minutes.
  • the gas is brought into contact with the fibre for a time ranging from 0.01 second to 30 seconds, more preferably from 1 to 20 seconds, and still more preferably from 1 to 10 seconds.
  • the application of the gas may be repeated several times on the same fibre, each operation being carried out on the basis of a time as stated above.
  • a preferred embodiment of the process according to the invention consists in first applying to the hair a composition consisting partly or completely of oil, it being possible for this application to be carried out before, during or after the customary operation of placing the locks of hair under tension in a shape corresponding to the final shape desired for these latter, e.g., ringlets.
  • This operation may be carried out by any suitable means known per se, in particular a mechanical means, for maintaining hair under tension, such as, for example, tubular bodies, rollers, curlers and the like.
  • the locks thus impregnated with oil are then subjected briefly to the action of water vapour according to the conditions mentioned above, and are then cooled, preferably rapidly, for example by passing a stream of air at room temperature over or through them and/or by drawing a stream of ambient air through the coiled locks.
  • the mechanical means which maintained the locks under tension and in the desired shape throughout the whole treatment is removed from the hair, resulting in locks or a head of hair displaying, for example, attractive, even and soft ringlets.
  • the hair is put under mechanical tension as described above and a composition consisting partly or completely of oil is applied to the hair simultaneously with a gas containing water vapour, as described above.
  • the locks of hair thus treated are then cooled, preferably rapidly, by a method as set forth above, and finally, the mechanical means which maintained the locks under tension and in the desired shape throughout the whole treatment is removed from the hair, resulting here also in locks or a head of hair displaying, for example, attractive, even and soft ringlets.
  • a hot gas comprising water vapour can be done using any apparatus known per se and designed for this purpose.
  • an apparatus such as the one described in French Patent Application FR-A-2,273,492, and in U.S. Pat. No. 4,166,473, the disclosures of which were incorporated by reference above, or any other equivalent apparatus, which is, in effect, particularly suitable in the present case as it provides steady and homogeneous selective treatment of the fibres without risk of overheating and with integrated post-treatment cooling.
  • oil is understood here to mean any fat which is liquid at room temperature and insoluble in water and which has hydrophobic character, having a mineral, animal, vegetable or synthetic origin. Further, as defined herein, oil does not include silicone oil.
  • isoparaffins such as, for example, those corresponding to the formula: ##STR1## where n ranges from 2 to 16. These isoparaffins may be used alone or mixed with other isoparaffins of higher molecular weights, especially those of the formula above and for which n is greater than or equal to 18, and preferably ranges from 18 to 40.
  • esters such as ethyl and isopropyl palmitates, 2-ethylhexyl palmitate, 2-octyldecyl palmitate, alkyl myristates such as isopropyl, butyl, cetyl or 2-octyldodecyl myristate, hexyl stearate, butyl stearate, dioctyl malate, hexyl laurate, 2-hexyldecyl laurate and isononyl isononanoate,
  • fatty acids and triglycerides of fatty acids such as triglycerides of octanoic and decanoic acids, cetyl ricinoleate, stearyl octanoate, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, linoleic acid, linolenic acid and isostearic acid,
  • fatty alcohols such as cetyl alcohol, stearyl alcohol and oleyl alcohol
  • fluorinated oils such as perfluoro polyethers and the fluorohydrocarbon oils described, in particular, in Patent Application WO 93/11103, the entire disclosure of which is hereby incorporated by reference,
  • hydrocarbon oils such as, for example, liquid paraffin (such as that sold under the name MARCOL 82 by the company ESSO), paraffin oils and isohexadecane may be mentioned in particular.
  • Liquid paraffin and paraffin oils can be the same oils, but their viscosities may be different.
  • oils Among animal oils, squalane and whale, seal, menhaden, halibut-liver, cod-liver, tuna, tallow, ox, horse, sheep, mink, turtle and otter oils may be mentioned in particular.
  • oils of vegetable origin almond, groundnut, wheat-germ, linseed, apricot-kernel, nut, palm, pistachio, sesame, poppy-seed, pine, castor, soya-bean, avocado, safflower, coconut, hazelnut, olive, grape-pip, blackcurrent-pip, sunflower, rapeseed, cade, maize-germ, peach-kernel, coffee, jojoba, argan, evening-primrose, borage, cotton-seed, shea, shorea and macadamia oils and essential oils may be mentioned as examples.
  • Preferred oils according to the invention are mineral oils, especially liquid paraffin (paraffin oil), and synthetic oils, especially isoparaffins.
  • the oils may be employed on their own, but it is preferable to use compositions containing such oils in a cosmetically acceptable vehicle.
  • the oils can thus be either solubilized or made into dispersions or (micro)emulsions in aqueous media or organic media or alternatively aqueous-organic media.
  • suitable organic solvents monohydric alcohols or polyols (ethanol, isopropanol, glycerol, benzyl alcohol, glycols), acetone, polyol ethers, hydrocarbons, esters, dimethoxymethane or alternatively volatile silicones may be mentioned in particular.
  • the content of oil(s) in the compositions can vary within very wide limits, and can range, for example, from 0.01% to 50%, and preferably from 0.1 to 10%, by weight relative to the whole of the composition.
  • compositions can take any form customarily used in the field of hair-care compositions for topical use, such as, for example, more or less thickened or gelled liquid, cream, mousse, lotion, gel, paste, emulsion, aerosol or any other suitable form.
  • the oil-based compositions can thus, and generally speaking, contain all the various traditional additives which are used in the field of the preparation of hair-care compositions for topical use, and can be chosen, for example, from UV screening agents, thickening agents, penetrating agents, antioxidants, sequestering agents, opacifying agents, buffers, surfactants chosen from nonionic surfactants such as alkyl polyglycosides, cationic surfactants, anionic surfactants and amphoteric surfactants, solubilizing agents, emollients, colorants, perfumes and preservatives.
  • the oil-based compositions used in the context of the present invention which are hence intended for application to hair, preferably have a pH ranging from 3 to 11. If necessary, this pH may be adjusted to the desired value by adding, as appropriate, either standard alkalinizing agents or standard acidifying agents which are known to be cosmetically acceptable.
  • This composition was packaged in a pump bottle dispensing 0.15 ml doses per spraying.
  • the initial length L 0 (in cm) of the lock of hair was first measured before the vapour treatment (length measured between the roots and the ends on the vertically suspended lock); in the same way, the length L 1 of this same lock was measured immediately after the treatment had ended; and lastly the length L 2 of this lock was measured 48 hours after the treatment.
  • This composition was packaged in a pump bottle dispensing 0.15 ml doses per spraying.
  • This composition was packaged in a pump bottle dispensing 0.15 ml doses per spraying.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Birds (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)
  • Peptides Or Proteins (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Materials For Medical Uses (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Orthopedics, Nursing, And Contraception (AREA)
US08/357,030 1993-12-22 1994-12-16 Process for the temporary reshaping of keratinous fibres Expired - Fee Related US5551453A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9315477 1993-12-22
FR9315477A FR2713920B1 (fr) 1993-12-22 1993-12-22 Procédé de déformation temporaire des fibres kératiniques humaines.

Publications (1)

Publication Number Publication Date
US5551453A true US5551453A (en) 1996-09-03

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Family Applications (1)

Application Number Title Priority Date Filing Date
US08/357,030 Expired - Fee Related US5551453A (en) 1993-12-22 1994-12-16 Process for the temporary reshaping of keratinous fibres

Country Status (12)

Country Link
US (1) US5551453A (pt)
EP (1) EP0659395B1 (pt)
JP (1) JP2549993B2 (pt)
AT (1) ATE180964T1 (pt)
BR (1) BR9405068A (pt)
CA (1) CA2137900C (pt)
DE (1) DE69418980T2 (pt)
ES (1) ES2134914T3 (pt)
FR (1) FR2713920B1 (pt)
HU (1) HUT71389A (pt)
PL (1) PL306406A1 (pt)
RU (1) RU94044526A (pt)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001082881A1 (en) * 2000-04-28 2001-11-08 Ceramide Co., Ltd. Perming compositions and perming method by using the same
US20010055577A1 (en) * 2000-04-19 2001-12-27 Kao Corporation Method of treating hair
US6479205B1 (en) * 1994-10-28 2002-11-12 Indigo N.V. Imaging apparatus and toner therefor
US20100212179A1 (en) * 2007-08-21 2010-08-26 Heidi Schmid Hair care appliance and method of using same
US20100258141A1 (en) * 2009-04-03 2010-10-14 Laurence Paul Method for treating keratinous fibers using steam
US20100307528A1 (en) * 2007-10-03 2010-12-09 L'oreal Method For Treating The Hair Using Steam
US20100307525A1 (en) * 2008-12-16 2010-12-09 Maxime De Boni Permanent reshaping process using a heating mechanical tensioning device
US8800163B2 (en) 2007-08-21 2014-08-12 Heidi Schmid Hair care appliance and method of using same
US20210345748A1 (en) * 2018-10-02 2021-11-11 L'oreal Hair treatment method
US12053072B2 (en) 2018-10-02 2024-08-06 L'oreal Hair treatment process
US12274340B2 (en) 2017-12-22 2025-04-15 Seb S.A. Hair treatment apparatus with steam containment

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2938190B1 (fr) * 2008-11-07 2011-01-07 Oreal Procede de traitement de la chevelure comprenant l'application d'une source de vapeur et d'un polymere cationique non colorant, non derive d'un sucre ou d'une silicone
FR2938189B1 (fr) * 2008-11-07 2010-12-31 Oreal Procede de traitement de la chevelure comprenant l'application d'une source de vapeur et d'une molecule non colorante, non polymerique, contenant au moins un motif cationique
FR3075579B1 (fr) 2017-12-22 2020-01-03 L'oreal Procede de traitement des fibres capillaires
FR3075576B1 (fr) 2017-12-22 2021-08-27 Seb Sa Appareil de traitement de la chevelure a l'etancheite amelioree

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB405219A (en) * 1933-09-14 1934-02-01 Charles Arnao Company Inc Improvements in apparatus for applying vapours to the hair and scalp
FR775645A (fr) * 1933-09-14 1935-01-05 Marchant Hills And Company Ltd Perfectionnements aux appareils d'application de vapeurs sur les cheveux et le cuir chevelu
US3809098A (en) * 1972-10-02 1974-05-07 Procter & Gamble Hair setting process
FR2273492A1 (fr) * 1974-06-10 1976-01-02 Oreal Nouveau procede de mise en plis et de traitement des cheveux et appareillage pour la mise en oeuvre de ce procede
US3932611A (en) * 1974-08-21 1976-01-13 Mccarthur Connie M Hair dressing cosmetic
US4078147A (en) * 1975-09-10 1978-03-07 The Nisshin Oil Mills, Ltd. Hydroxy acid esters of higher alcohols
US4488564A (en) * 1980-12-19 1984-12-18 L'oreal Oily composition intended for the treatment of keratin substances and the skin
US4610261A (en) * 1982-08-16 1986-09-09 L'oreal Process for treating the hair and in particular the tips of the hair and device for carrying out the said process
US5110318A (en) * 1988-04-06 1992-05-05 Altobelli Rocco F Composition and method for coloring and conditioning hair
WO1993011103A1 (fr) * 1991-12-04 1993-06-10 L'oreal Composes hydro-fluoro-carbones, leur utilisation dans des compositions cosmetiques, leur procede de preparation et les compositions cosmetiques en comportant

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB405219A (en) * 1933-09-14 1934-02-01 Charles Arnao Company Inc Improvements in apparatus for applying vapours to the hair and scalp
FR775645A (fr) * 1933-09-14 1935-01-05 Marchant Hills And Company Ltd Perfectionnements aux appareils d'application de vapeurs sur les cheveux et le cuir chevelu
US3809098A (en) * 1972-10-02 1974-05-07 Procter & Gamble Hair setting process
FR2273492A1 (fr) * 1974-06-10 1976-01-02 Oreal Nouveau procede de mise en plis et de traitement des cheveux et appareillage pour la mise en oeuvre de ce procede
US4166473A (en) * 1974-06-10 1979-09-04 L'oreal Method and apparatus for setting hair
US3932611A (en) * 1974-08-21 1976-01-13 Mccarthur Connie M Hair dressing cosmetic
US4078147A (en) * 1975-09-10 1978-03-07 The Nisshin Oil Mills, Ltd. Hydroxy acid esters of higher alcohols
US4488564A (en) * 1980-12-19 1984-12-18 L'oreal Oily composition intended for the treatment of keratin substances and the skin
US4610261A (en) * 1982-08-16 1986-09-09 L'oreal Process for treating the hair and in particular the tips of the hair and device for carrying out the said process
EP0201622A2 (fr) * 1982-08-16 1986-11-20 L'oreal Procédé de traitement des cheveux, et notamment de leurs pointes
US5110318A (en) * 1988-04-06 1992-05-05 Altobelli Rocco F Composition and method for coloring and conditioning hair
WO1993011103A1 (fr) * 1991-12-04 1993-06-10 L'oreal Composes hydro-fluoro-carbones, leur utilisation dans des compositions cosmetiques, leur procede de preparation et les compositions cosmetiques en comportant

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Derwent Abstract No. 009503418 of PCT Appl. WO 93/11103, Jun. 10, 1993. *

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6479205B1 (en) * 1994-10-28 2002-11-12 Indigo N.V. Imaging apparatus and toner therefor
US20030059701A1 (en) * 1994-10-28 2003-03-27 Benzion Landa Imaging apparatus and improved toner therefor
US20030068570A1 (en) * 1994-10-28 2003-04-10 Benzion Landa Imaging apparatus and improved toner therefor
US20080056779A1 (en) * 1994-10-28 2008-03-06 Benzion Landa Imaging Apparatus and Improved Toner Therefor
US7354691B2 (en) 1994-10-28 2008-04-08 Hewlett-Packard Development Company, L.P. Imaging apparatus and improved toner therefor
US7647008B2 (en) 1994-10-28 2010-01-12 Hewlett-Packard Indigo B.V. Imaging apparatus and improved toner therefor
US7678525B2 (en) * 1994-10-28 2010-03-16 Hewlett-Packard Development Company, L.P. Imaging apparatus and improved toner therefor
US20010055577A1 (en) * 2000-04-19 2001-12-27 Kao Corporation Method of treating hair
WO2001082881A1 (en) * 2000-04-28 2001-11-08 Ceramide Co., Ltd. Perming compositions and perming method by using the same
US8800163B2 (en) 2007-08-21 2014-08-12 Heidi Schmid Hair care appliance and method of using same
US8136263B2 (en) * 2007-08-21 2012-03-20 Heidi Schmid Hair care appliance and method of using same
US20100212179A1 (en) * 2007-08-21 2010-08-26 Heidi Schmid Hair care appliance and method of using same
US20100307528A1 (en) * 2007-10-03 2010-12-09 L'oreal Method For Treating The Hair Using Steam
US20100307525A1 (en) * 2008-12-16 2010-12-09 Maxime De Boni Permanent reshaping process using a heating mechanical tensioning device
US8517034B2 (en) * 2008-12-16 2013-08-27 L'oreal Permanent reshaping process using a heating mechanical tensioning device
US9113689B2 (en) 2008-12-16 2015-08-25 L'oreal Permanent reshaping process using a heating mechanical tensioning device
US20100258141A1 (en) * 2009-04-03 2010-10-14 Laurence Paul Method for treating keratinous fibers using steam
US9603429B2 (en) 2009-04-03 2017-03-28 L'oreal Method for treating keratinous fibers using steam
US12274340B2 (en) 2017-12-22 2025-04-15 Seb S.A. Hair treatment apparatus with steam containment
US20210345748A1 (en) * 2018-10-02 2021-11-11 L'oreal Hair treatment method
US12053072B2 (en) 2018-10-02 2024-08-06 L'oreal Hair treatment process
US12201207B2 (en) * 2018-10-02 2025-01-21 L'oreal Hair treatment method

Also Published As

Publication number Publication date
PL306406A1 (en) 1995-06-26
EP0659395B1 (fr) 1999-06-09
DE69418980D1 (de) 1999-07-15
HUT71389A (en) 1995-11-28
CA2137900C (fr) 1999-11-16
CA2137900A1 (fr) 1995-06-23
JP2549993B2 (ja) 1996-10-30
JPH0824035A (ja) 1996-01-30
ES2134914T3 (es) 1999-10-16
RU94044526A (ru) 1996-10-20
ATE180964T1 (de) 1999-06-15
DE69418980T2 (de) 1999-10-07
FR2713920B1 (fr) 1996-01-26
EP0659395A1 (fr) 1995-06-28
FR2713920A1 (fr) 1995-06-23
BR9405068A (pt) 1995-10-17

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