US5196491A - Living cationic polymerization of alkyl vinyl ethers - Google Patents
Living cationic polymerization of alkyl vinyl ethers Download PDFInfo
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- US5196491A US5196491A US07/276,352 US27635288A US5196491A US 5196491 A US5196491 A US 5196491A US 27635288 A US27635288 A US 27635288A US 5196491 A US5196491 A US 5196491A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08F16/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
- C08F16/12—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
- C08F16/14—Monomers containing only one unsaturated aliphatic radical
- C08F16/16—Monomers containing no hetero atoms other than the ether oxygen
- C08F16/18—Acyclic compounds
Definitions
- This invention relates to a process for the living cationic polymerization of vinylic unsaturated compounds containing electron donating substitutes to polymers of narrow molecular weight distribution.
- EP 206, 756 discloses the use of complexes of Lewis acids and organic acids or esters as catalysts for the living polymerization of olefins and diolefins.
- JP J6 0228-509 discloses the preparation of polyalkenyl ethers by living polymerization using as catalysts iodine and optionally HI.
- U. S. Pat. No. 4,393,199 discloses a method of polymerizing monomers capable of cationic polymerization by using an adduct consisting of a preinitiator precursor and a catalyst, to react with the monomer and produce a polymer of low polydispersity.
- U. S. Pat. No. 4,696,988 discloses the use of HI/I 2 initiating systems to polymerize isopropenylphenyl glycidyl ethers. The use of CF 3 SO 3 H is shown to be ineffective.
- the present invention provides a process for the cationic polymerization of vinylic unsaturated compounds using a proton or carbenium or siliconium ion source, and/or Lewis acids; in combination with selected Lewis base.
- the present invention provides a process for the preparation of polymers by cationic polymerization of selected vinylic unsaturated compounds using a suitable initiator, examples of which include a combination of a proton source (HA) and a Lewis base (LB); HA, Lewis acid (LA) and LB; carbenium or siliconium ion source (CS) and LB or CS, LA and LB.
- HA include; CF 3 SO 3 H, H 2 SO 4 , FSO 3 H, HClO 4 , HCO 2 R (where R is C 1-4 alkyl), HOR, HSR, and H 2 O.
- LA include; BF 3 , RAlCl 2 , PF 5 , AsF 5 , and SbF 5 .
- LB tetrahydrofuran (THF), tetrahydrothiophene diisopropyl sulfide, or p-dioxane.
- Examples of carbenium and siliconium ion sources include; CF 3 SO 3 R, CF 3 SO 3 SiR 3 , R 2 CH(OR) 2 , R 2 C(OR) 3 and R 2 C(O)H, where R 2 is phenyl or C 1-6 alkyl and R is as defined above.
- the polymerization reaction proceeds according to the following formula:
- the monomers useful in the invention process include, but are not limited to, styrenes with para alkyl or alkoxy substiuents, where the alkyl or alkoxy groups contain C 1 to C 6 carbon atoms; alkyl vinyl ethers or aralkyl vinyl ethers, where the alkyl groups contain one to twenty carbon atoms, and optionally contain halogen atoms such as chlorine, fluorine or bromine, or ether linkages; and N-vinylcarbazole.
- the monomer is a, C 1 to C 6 alkyl vinyl ether. Most preferred are methyl vinyl ether, ethyl vinyl ether, n-butyl vinyl ether, or isobutyl vinyl ether.
- the monomers used herein are either known compounds or can be prepared by known methods.
- a monomer is polymerized in a suitable solvent, preferably dichloromethane or hexane, in an inert gas atmosphere, with precautions being taken to exclude water, except when water is deliberately added as part of the initiator system, at temperatures of about -80° C. to about 0° C. Pressure is not critical, but atmospheric pressure is preferred.
- Preferred HA's, LA's and CS's include; FSO 3 H, SbF 5 , CF 3 SO 3 Si(CH 3 ) 3 , BF 3 , CF 3 SO 3 H, PhC(O)H, PhCH(OCH 3 ) 2 .
- a Lewis base is a necessary component of the catalyst system in order to obtain a narrow molecular weight distribution (MWD) polymer, indicative of a living polymerization. It is believed that the polymer products of this invention are examples of living cationic polymerization, as evidenced by the dependence of M n on [M] o /[I] o and the narrow MWD of the products. Because the polymers of this invention are living, they can be used to prepare block copolymers.
- MWD molecular weight distribution
- Lewis bases used in the process of this invention are CH 3 SR 1 , where R 1 is a straight chain C 1-4 alkyl, (CH 3 CH 2 ) 2 S, (CH 3 CH 2 CH 2 ) 2 S, CH 3 CH 2 SH, (CH 3 ) 2 SSCH 2 SCH 3 , CH 3 SCH 2 CH 2 SCH 3 , diisopropyl sulfide, p-dioxane, or tetrahydrofuran.
- Preferred Lewis bases are (CH 3 ) 2 S, (CH 3 CH 2 ) 2 S, CH 3 CH 2 SH, (CH 3 S) 2 CH 2 , tetrahydrothiophene or (CH 3 ) 2 SO.
- the molar ratio of the Lewis base to the initiator should be greater than 6, although ratios as low as 1.1 may be used.
- the MWD decreases with an increase of [LB]/[Initiator].
- the polymers of this invention generally have a narrow molecular weight distribution.
- the polydispersity is in the range of about 1.0 to about 2.4.
- the polymers of this invention are useful for coatings, sealing materials, and adhesives.
- temperatures are in degrees Celsius unless otherwise specified.
- Molecular weights (weight M w and number M n average) were determined by gel permeation chromatography (GPC); polydispersity, D, is given by the ratio of M w /M n .
- the most preferred embodiments are represented by examples: 1, 3, 4, 17, 23, and 25.
- the vinyl ethers used were purified by stirring for 48 h with KOH pellets, followed by refuxing over CaH 2 , and finally distillation from CaH 2 . This procedure was repeated a minimum of three times. Methylene chloride (EM Science, 99.9%) and hexane (Phillips, Spectro Grade) were refluxed over CaH 2 and distilled from CaH 2 ; this procedure was repeated a minumum of three times. Sometimes hexane was purified by distillation from a solution containing living polystyrene. Dioxane (Baker, Baker-Analyzed) was used after drying over molecular sieves.
- Tetrahydrofuran (EM Science, 99.9%) was used after distillation over sodium-potassium alloy. Methyl sulfide (Aldrich, gold label, anhydrous, 99+%), ethyl sulfide (Aldrich, 98%), n-propyl sulfide (Aldrich, 97%), isopropyl sulfide (Aldrich, 98%), bis(methylthio)methane (Aldrich, 99+%), ethanethiol (Aldrich, 97%), tetrahydrothiophene (Aldrich, 99%) benzaldehyde (Aldrich, 99+%) benzaldehyde dimethyl acetal (Aldrich, 99%), DMSO (Aldrich, gold label, anhydrous, 99+%), fluorosulfonic acid (Columbia, distilled), trifluoromethanesulfonic acid (
- the initiator solution was injected in one portion into the cooled solution of the monomer and Lewis base. The rest of the procedure was the same as Method A.
- Results shown in Tables 1 and 2 are for the preferred Lewis bases. Results of polymerizations under inoperative conditions for producing living polymers are shown in Tables 3 and 4.
- Isobutyl vinyl ether was polymerized by Me 3 SiT f (0.90 mmol) in the presence of Me 2 S (30 mmol) using CH 2 Cl 2 as solvent at a reaction temperature of -30° C. using Experimental Method B described above. Quantitative yields of polymers were obtained. The results of these experiments are shown in Table 6, A-H. A similar series was done with triflic acid initiator; the results of these experiments are shown in Table 6, I-N.
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Abstract
This invention relates to a process for the living cationic polymerization of vinylic unsaturated compounds containing electron donating substituents resulting in polymers of narrow molecular weight distribution.
Description
This invention relates to a process for the living cationic polymerization of vinylic unsaturated compounds containing electron donating substitutes to polymers of narrow molecular weight distribution.
Living polymerization allows for the synthesis of new polymers and oligomers with specialized structures. A number of recent advances have occurred in polymerization by cationic mechanisms to yield living polymers, where it was previously thought that obtaining living characteristics was unlikely, except for a few ring-opening polymerization systems, due to the reactivity or instability of the ions involved.
T. Higashimura and M. Sawamoto; Adv. Polym. Sci., 1984, 62, 50-94, review the attempts at living cationic polymerization of vinyl monomers and state that until recently it was considered "beyond our reach." They teach away from using oxo acids, such as sulfonic acids, because they believe that the acid derived counterions react with the propagating cations and thereby terminate the polymerization. For example, they show in Table 11 that dimer instead of polymer is produced when p-methoxystyrene is reacted with either CH3 SO3 H or CF3 SO3 H. They disclose the use of an HI/I2 initiating system to polymerize isobutyl vinyl ether in n-hexane. They claim this polymerization system to be the first example of living cationic polymerization of vinyl compounds.
M. Miyamoto, M. Sawamoto, and T. Higashimura; Macromol., 1984, 17, 265-268, show that living polymerization of isobutylvinyl ether using HI/I2, I2, or HI as initiators, does not occur in a polar solvent such as CH2 Cl2.
S. Aoshima and T. Higashimura; Polym. Bull., 1986, 15, 417-423, disclose the use of esters as Lewis base modifiers for EtAlCl2. These systems are used as initiators for the living cationic polymerization of vinyl ethers.
T. Higashimura, Y. Kishimoto, and S. Aoshima, Polym. Bull., 1987, 18, 111-115, disclose the use of an EtAlCl2 /dioxane (basic compound) initiating system for the living cationic polymerization of vinyl monomers. A small amount of water is added to the initiating system.
R. Faust and J. P. Kennedy; Polym. Bull., 1986, 15, 317-323, describe the living carbocationic polymerizations of isobutene using initiating complexes of organic esters with Lewis acids.
EP 206, 756, discloses the use of complexes of Lewis acids and organic acids or esters as catalysts for the living polymerization of olefins and diolefins.
JP J6 0228-509, discloses the preparation of polyalkenyl ethers by living polymerization using as catalysts iodine and optionally HI.
U. S. Pat. No. 4,393,199 discloses a method of polymerizing monomers capable of cationic polymerization by using an adduct consisting of a preinitiator precursor and a catalyst, to react with the monomer and produce a polymer of low polydispersity.
U. S. Pat. No. 4,696,988 discloses the use of HI/I2 initiating systems to polymerize isopropenylphenyl glycidyl ethers. The use of CF3 SO3 H is shown to be ineffective.
It is difficult to predict which initiator/Lewis base combinations will result in a living cationic polymerization of a vinyl monomer. For example, S. Aoshima and T. Higashimura, op. cit., show that living polymerizations of 2-vinyloxyethyl benzoate and 2-vinyloxyethyl methacrylate monomers, where the ester functioning as a Lewis base is incorporated within its structure, can be conducted using EtAlCl2 but not with BF3 OEt2.
The present invention provides a process for the cationic polymerization of vinylic unsaturated compounds using a proton or carbenium or siliconium ion source, and/or Lewis acids; in combination with selected Lewis base.
The present invention provides a process for the preparation of polymers by cationic polymerization of selected vinylic unsaturated compounds using a suitable initiator, examples of which include a combination of a proton source (HA) and a Lewis base (LB); HA, Lewis acid (LA) and LB; carbenium or siliconium ion source (CS) and LB or CS, LA and LB. Examples of HA include; CF3 SO3 H, H2 SO4, FSO3 H, HClO4, HCO2 R (where R is C1-4 alkyl), HOR, HSR, and H2 O. Examples of LA include; BF3, RAlCl2, PF5, AsF5, and SbF5. When the HA used is weakly acidic, e. g. HCO2 R, HOR, HSR, or H2 O, a Lewis acid is necessary for polymerization to occur. Examples of LB include; CH3 SR1, where R1 is a straight chain C1-4 alkyl, (CH3 CH2)2 S, (CH3 CH2 CH2)2 S, CH3 CH2 SH, (CH3)2 SO, CH3 SCH2 SCH3, CH3 SCH2 CH2 SCH3, tetrahydrofuran (THF), tetrahydrothiophene diisopropyl sulfide, or p-dioxane. Examples of carbenium and siliconium ion sources (CS) include; CF3 SO3 R, CF3 SO3 SiR3, R2 CH(OR)2, R2 C(OR)3 and R2 C(O)H, where R2 is phenyl or C1-6 alkyl and R is as defined above.
The polymerization reaction proceeds according to the following formula:
nCH.sub.2 ═C(X)H+n.sup.I HA+n.sup.II LA+n.sup.III LB+n.sup.IV CS
where n.sup.(I-IV) denotes the proportions of the number of moles of reactants; n=1-200, nI =0-1, nII =0-10, nIII =1-50, and nIV =0-1 with the proviso that nI +nIV =1; and X is an electron donating group such as a C1-6 alkoxy group.
The monomers useful in the invention process include, but are not limited to, styrenes with para alkyl or alkoxy substiuents, where the alkyl or alkoxy groups contain C1 to C6 carbon atoms; alkyl vinyl ethers or aralkyl vinyl ethers, where the alkyl groups contain one to twenty carbon atoms, and optionally contain halogen atoms such as chlorine, fluorine or bromine, or ether linkages; and N-vinylcarbazole. Preferably the monomer is a, C1 to C6 alkyl vinyl ether. Most preferred are methyl vinyl ether, ethyl vinyl ether, n-butyl vinyl ether, or isobutyl vinyl ether. The monomers used herein are either known compounds or can be prepared by known methods.
In the invention process, a monomer is polymerized in a suitable solvent, preferably dichloromethane or hexane, in an inert gas atmosphere, with precautions being taken to exclude water, except when water is deliberately added as part of the initiator system, at temperatures of about -80° C. to about 0° C. Pressure is not critical, but atmospheric pressure is preferred. Preferred HA's, LA's and CS's include; FSO3 H, SbF5, CF3 SO3 Si(CH3)3, BF3, CF3 SO3 H, PhC(O)H, PhCH(OCH3)2. A Lewis base is a necessary component of the catalyst system in order to obtain a narrow molecular weight distribution (MWD) polymer, indicative of a living polymerization. It is believed that the polymer products of this invention are examples of living cationic polymerization, as evidenced by the dependence of Mn on [M]o /[I]o and the narrow MWD of the products. Because the polymers of this invention are living, they can be used to prepare block copolymers. Lewis bases used in the process of this invention are CH3 SR1 , where R1 is a straight chain C1-4 alkyl, (CH3 CH2)2 S, (CH3 CH2 CH2)2 S, CH3 CH2 SH, (CH3)2 SSCH2 SCH3, CH3 SCH2 CH2 SCH3, diisopropyl sulfide, p-dioxane, or tetrahydrofuran. Preferred Lewis bases are (CH3)2 S, (CH3 CH2)2 S, CH3 CH2 SH, (CH3 S)2 CH2, tetrahydrothiophene or (CH3)2 SO. Preferably, the molar ratio of the Lewis base to the initiator should be greater than 6, although ratios as low as 1.1 may be used. The MWD decreases with an increase of [LB]/[Initiator].
The polymers of this invention generally have a narrow molecular weight distribution. The polydispersity is in the range of about 1.0 to about 2.4.
The polymers of this invention are useful for coatings, sealing materials, and adhesives.
In the following embodiments of the invention, temperatures are in degrees Celsius unless otherwise specified. Molecular weights (weight Mw and number Mn average) were determined by gel permeation chromatography (GPC); polydispersity, D, is given by the ratio of Mw /Mn.
The most preferred embodiments are represented by examples: 1, 3, 4, 17, 23, and 25.
The vinyl ethers used were purified by stirring for 48 h with KOH pellets, followed by refuxing over CaH2, and finally distillation from CaH2. This procedure was repeated a minimum of three times. Methylene chloride (EM Science, 99.9%) and hexane (Phillips, Spectro Grade) were refluxed over CaH2 and distilled from CaH2 ; this procedure was repeated a minumum of three times. Sometimes hexane was purified by distillation from a solution containing living polystyrene. Dioxane (Baker, Baker-Analyzed) was used after drying over molecular sieves. Tetrahydrofuran (EM Science, 99.9%) was used after distillation over sodium-potassium alloy. Methyl sulfide (Aldrich, gold label, anhydrous, 99+%), ethyl sulfide (Aldrich, 98%), n-propyl sulfide (Aldrich, 97%), isopropyl sulfide (Aldrich, 98%), bis(methylthio)methane (Aldrich, 99+%), ethanethiol (Aldrich, 97%), tetrahydrothiophene (Aldrich, 99%) benzaldehyde (Aldrich, 99+%) benzaldehyde dimethyl acetal (Aldrich, 99%), DMSO (Aldrich, gold label, anhydrous, 99+%), fluorosulfonic acid (Columbia, distilled), trifluoromethanesulfonic acid (fluka, purum, >98%), boron trifluoride-methyl sulfide complex (Aldrich), trimethylsilyl triflate (Aldrich, 99%), Magic acid (Aldrich, 25%, 4FSO3 H.SbF5), and oleum (Baker, 20%) were used without further purification.
To a three-necked RB flask, which had been oven-dried, equipped with magnetic stirring, a dropping funnel, and under an argon atmosphere, was added solvent in varying amounts depending on the monomer solution concentration, such that the total solvent volume equaled 120-125 mL. The solvent was then cooled to the indicated temperature, and a solution of an initiator consisting of a proton source (HA), or HA and a Lewis acid, or a carbenium or siliconium ion source, or a carbenium ion source and a Lewis acid, and Lewis base was added, followed by stirring for 10-15 min. All of the monomer was added dropwise to this solution of an initiator and Lewis base. Stirring was continued for 3-15 h when using CH2 Cl2 as solvent and for 6-24 h when using hexane as solvent. The living polymerization was quenched by adding a chilled solution of a 10% t-butylamine/methanol solution. The polymer was isolated by stripping solvent (120-125 mL).
The initiator solution was injected in one portion into the cooled solution of the monomer and Lewis base. The rest of the procedure was the same as Method A.
Results shown in Tables 1 and 2 are for the preferred Lewis bases. Results of polymerizations under inoperative conditions for producing living polymers are shown in Tables 3 and 4.
TABLE 1
__________________________________________________________________________
Ex. Reaction Lewis
No.
Solvent
Method
Temp. Initiator
Mmol
Base Mmol
__________________________________________________________________________
1 CH.sub.2 Cl.sub.2
A -30° C.
Me.sub.3 SiT.sub.f.sup.a
0.9 Me.sub.2 S
30
2 " " " " " " "
3 Hexane
" " " " " "
4 CH.sub.2 Cl.sub.2
" " " " " "
5 " " " T.sub.f H
" " 7.2
6 " " " Me.sub.3 SiT.sub.f
" Et.sub.2 S
15
7 " " " T.sub.f H
" " "
8 " " " " " Me.sub.2 SO
8.0
9 " " -60° C.
" " " 7.2
10 Hexane
B -5 to 0° C.
EtAlCl.sub.2
1.0 Me.sub.2 S
60
H.sub.2 O
0.83
11 CH.sub.2 Cl.sub.2
A -30° C.
BF.sub.3.Me.sub.2 S
0.94
" 26
MeOH 1.0
12 " " " BF.sub.3.Me.sub.2 S
0.94
" "
H.sub.2 O
0.50
13 " " " BF.sub.3.Me.sub.2 S
0.94
" "
HOAc 1.0
14 " " " BF.sub.3.Me.sub.2 S
0.94
" "
PhCH(OMe).sub.2
1.0
15 " " " BF.sub.3.Me.sub.2 S
0.94
EtSH.sup.b
4.5
16 " " -70° C.
T.sub.f H
1.8 (CH.sub.3 S).sub.2 CH.sub.2
3.7
17 " B -30° C.
BF.sub.3 Et.sub.2 O
5 Me.sub.2 S
30
PhC(O)H
1.0
18 " " -30° C.
T.sub.f H
1.0 (n-Pr).sub.2 S
30
19 " " " " 1.0 (iso-Pr).sub.2 S
16.7
20 " " " BF.sub.3 OEt.sub.2
1.0 Dioxane
15
PhCH(OMe).sub.2
0.7
21 " " 0° C.
BF.sub.3 OEt.sub.2
1.0 " "
PhCH(OMe).sub.2
0.7
22 " " -30° C.
BF.sub.3 OEt.sub.2
7 THF 42
PhCH(OMe).sub.2
0.7
23 " " " BF.sub.3 OEt.sub.2
14 Me.sub.2 S
42
PhCH(OMe).sub.2
0.7
24 " " " FSO.sub.3 H
1.0 " 30
25 " " " FSO.sub.3 H.
1.0 " 26
SbF.sub.5
26 " " " H.sub.2 SO.sub.4
0.8 " 10
SO.sub.3
0.2
27 " " " T.sub.f H
0.68
Tetrahydro
17.0
thiophene
28 " " " T.sub.f H
25 Me.sub.2 S
133
__________________________________________________________________________
.sup.a T.sub.f = CF.sub.3 SO.sub.3
.sup.b EtSH serves a dual function as a Lewis base and as a proton source
TABLE 2
______________________________________
Ex. R of Product
No. RO--CH═CH.sub.2 Mmol
Yield -- M.sub.w
-- M.sub.n
-- M.sub.w /-- M.sub.n
______________________________________
1 Isobutyl 65 6.76 g 6750 6640 1.02
2 " 130 13.43 13800 11700 1.18
3 " 260 5.76 10100 9340 1.08
4 " 130 13.60 17700 16800 1.05
5 " " 13.29 10100 8290 1.22
6 " " 14.22 14400 11400 1.26
7 " " 13.56 13600 11100 1.24
8 " " 14.30 7420 4650 1.60
9 Ethyl " 10.1 5090 3100 1.64
10 Isobutyl 65 5.83 15600 12900 1.21
11 " " 6.89 2830 1350 2.10
12 " " 6.19 9340 7690 1.21
13 " " 6.18 3390 2820 1.20
14 " " 6.78 6190 4820 1.28
15 " " 6.67 3270 2250 1.45
16 Ethyl 260 19.67 27700 19200 1.44
17 Isobutyl 61 6.82 13700 13400 1.02
18 " 65 6.72 12400 7860 1.58
19 " " 6.66 14100 7260 1.95
20 " 61 6.41 21200 9100 2.34
21 " " 6.31 23000 9740 2.37
22 " " 6.18 19900 9810 2.03
23 " " 6.84 9120 9280 0.98
24 " " 6.38 6440 3790 1.70
25 " " 6.58 3860 3670 1.05
26 " " 5.98 717 408 1.75
27 " " 6.26 8180 7470 1.10
28 Methyl 550 30.8 1190 1030 1.16
______________________________________
TABLE 3
__________________________________________________________________________
Exper-
iment Reaction Lewis
No. Solvent
Method
Temp.
Initiator
Mmol
Base Mmol
__________________________________________________________________________
1 CH.sub.2 Cl.sub.2
A -30 T.sub.f H
0.9 p-Dithiane
2.7
2 " " " " " (i-Pr).sub.2 S
7.2
3 " " 0 " " Pyridine Oxide
1.0
4 " " -30 T.sub.f H
" Ph.sub.2 SO
3.6
5 " " " " " CH.sub.3 CO.sub.2 Et
15.0
6 " " " " " CH.sub.3 CN
"
7 " " " " " PhCO.sub.2 Et
"
8 " " " Me.sub.3 SiT.sub.f
1.80
p-Dioxane
60
9 " " " " " CH.sub.3 I
15.0
10 " " " " " Me.sub.3 CI
"
__________________________________________________________________________
TABLE 4
______________________________________
Experi-
ment R of Product
No. RO--CH═CH.sub.2 Mmol
Yield -- M.sub.w
-- M.sub.m
-- M.sub.w /-- M.sub.n
______________________________________
1 i-Bu 130 13.45 35100 1930 18.2
2 " " 13.18 27900 3520 7.94
3 " " 13.46 18200 2590 7.00
4 " " 13.32 12700 745 17.1
5 " " 13.94 18900 2560 7.40
6 " " 13.02 17400 2430 7.16
7 " " 14.37 20100 2470 8.16
8 " " 13.54 34300 5150 6.66
9 " 65 7.33 32100 3390 9.47
10 " " 7.19 33100 5840 5.67
______________________________________
The MWD was found to be dependent on the [LB]/[Initiator] ratio. Results of experiments for the polymerization of isobutyl vinyl ether in the presence of (CH3)2 S that demonstrated this are shown in Table 5. Experiments A-G were run under the following conditions: I=Tf H (0.90 mmol), solvent=CH2 Cl2, reaction temperature=-30° C., yields yields-quantitative. Experiments H-O were run under the following conditions: I=Me3 SiTf (0.90 mmol), solvent=CH2 Cl2, reaction temperature=-30° C., yields-quantitative.
TABLE 5 ______________________________________ -- M.sub.w /-- M.sub.n Dependence on [LB]/[I] Experiment [LB]/[I] -- M.sub.w /-- M.sub.n ______________________________________ A 2 1.74 B " 1.79 C 4 1.58 D 8 1.32 E " 1.34 F 16.7 1.23 G " 1.21 H 0 5.62 I " 7.71 J 4 1.56 K " 1.68 L 16.7 1.38 M " 1.33 N 33.3 1.18 O " 1.20 ______________________________________
Isobutyl vinyl ether was polymerized by Me3 SiTf (0.90 mmol) in the presence of Me2 S (30 mmol) using CH2 Cl2 as solvent at a reaction temperature of -30° C. using Experimental Method B described above. Quantitative yields of polymers were obtained. The results of these experiments are shown in Table 6, A-H. A similar series was done with triflic acid initiator; the results of these experiments are shown in Table 6, I-N.
TABLE 6
______________________________________
Dependence of M.sub.n on [M].sub.o /[I].sub.o
Experiment
[M].sub.o /[I].sub.o
-- M.sub.n (calc).sup.1
-- M.sub.n
-- M.sub.w /-- M.sub.n
______________________________________
A 36.1 3615 7440 1.03
B " " 9390 1.06
C 72.2 7231 13600 1.09
D " " 17900 1.11
E 108.3 10846 23100 1.14
F " " 32600 1.09
G 144.4 14462 46600 1.15
H " " 43800 1.15
I 32.5 3255 1740 1.08
J " " 1950 1.07
K 65 6510 4160 1.04
L " " 4300 1.0
M 97.5 9765 6520 1.04
N " " 6130 1.12
______________________________________
.sup.1 --M.sub.n (calc) = [M].sub.o M.sub.1
Reaction time: .sup.a 1 h, .sup.b 2 h, .sup.c 3 h.
The addition of H2 O to the isobutyl vinyl ether/Me3 SiTf /Me2 S/CH2 Cl2 polymerization system resulted in a decrease of Mw and an increase of Mw /Mn. Water was completely consumed in a very efficient chain transfer to monomer reaction as can be seen from the fact that Mn =Mn (calc)=Mo /([Me3 SiTf ]o +[H2 O]). l
The effect of ethanol is similar. These results indicate that polyalkyl vinyl ethers having controlled Mw and Mw /Mn in the range of 1.1-1.5, can be obtained by controlling the [Me3 SiTf ]/[H2 O] ratio.
TABLE 7
______________________________________
Effect of Added Water
Exper-
[H.sub.2 O]
[Me.sub.3 SiT.sub.f ] +
-- M.sub.n 10.sup.4
iment (mmol) [H.sub.2 O] (mmol)
(calc)
-- M.sub.n
-- M.sub.w /-- M.sub.n
(1/-- M.sub.n)
______________________________________
A -- 0.9 7234 7510 1.04 1.33
B -- " " 9370 1.03 1.07
C 0.9 1.8 3617 3590 1.27 2.79
D " " " 3810 1.25 2.62
E 1.8 2.7 2422 2340 1.42 4.27
F " " " 1810 1.90 5.52
G 3.6 4.5 1607 1360 2.86 7.35
H " " " 1060 2.86 9.43
______________________________________
Although preferred embodiments of the invention have been illustrated and described hereinabove, it is to be understood that there is no intent to limit the invention to the precise constructions herein described. Rather, it is to be further understood that the right is reserved to all changes and modifications coming within the scope of the invention as defined by the appended claims.
Claims (20)
1. A process for the living cationic polymerization of vinylic unsaturated monomers containing electronic donating substituents, comprising contacting said vinylic unsaturated monomers under polymerizing conditions at a temperature of about -80° C. to about 0° C. in a suitable solvent, in the presence of an initiating combination consisting essentially of a Lewis base selected from the group consisting of CH3 SR1, wherein: R1 is straight chain C1 to alkyl; (CH3 CH2)2 S; (CH3 CH2 CH2)2 S; (CH3)2 SSCH2 SCH3 ; CH3 CH2 SH; (CH3)2 SO; CH3 SCH2 SCH3 ; CH3 SCH2 CH2 SCH3 ; tetrahydrothiophene: tetrahydrofuran: diisopropyl sulfide: and p-dioxane, and a second component selected from: a proton source; a proton source and a Lewis acid; a carbenium or siliconium ion source; and a carbenium or siliconium ion source and a Lewis acid; provided that when the Lewis base is dioxane, the Lewis acid RAICL2, where R is C1 to C4 alkyl, is not present.
2. The process of claim 1 wherein the initiating combination is a proton source and a Lewis base.
3. The process of claim 1 wherein the initiating combination is a proton source, Lewis acid and a Lewis base.
4. The process of claim 1 wherein the initiating combination is a carbenium ion or siliconium ion source and a Lewis base.
5. The process of claim 4 wherein the initiating combination is a siliconium ion source and a Lewis base.
6. The process of claim 4 wherein the initiating combination is a carbenium ion source and a Lewis base.
7. The process of claim 1 wherein the initiating combination is a carbenium or siliconium ion source, a Lewis acid and a Lewis base.
8. The process of claim 1 or 2 or 3 or 4 or 5 or 6 or 7 wherein the product is a living polymer.
9. The process of claim 8 where the vinylic unsaturated monomers are selected from the group of monomers consisting of styrenes with para alkyl or alkoxy groups containing C1 to C6 carbon atoms, alkyl vinyl ethers or aralkyl vinyl ethers, where the alkyl groups can contain one to twenty carbon atoms, and optionally halogen atoms or ether linkages, and N-vinyl carbazole.
10. The process of claim 8 wherein the monomer used is selected from the group consisting of methyl vinyl ether, ethyl vinyl ether, n-butyl vinyl ether, or isobutyl vinyl ether.
11. The process of claim 9 or claim 10 wherein the solvent is selected from the group comprising dichloromethane or hexane.
12. The process of claim 11 carried on in an inert gas atmosphere.
13. The process of claim 12 carried on in a water free atmosphere.
14. The process of claim 12 carried out in the presence of water.
15. The process of claim 13 or claim 14 conducted at atmospheric pressure.
16. The process of claim 15 wherein the molar ratio of the Lewis base to the initiator is in excess of 6 to 1.
17. The process of claim 2 wherein the proton source is selected from the group consisting of CF3 SO3 H, H2 SO4, FSO3 H, and HClO4.
18. The process of claim 3 wherein the proton source is selected from the group consisting of HCO2 R (where R is C1 -C4 alkyl), HOR, HSR and H2 O and the Lewis acid is selected from the group consisting of BF3, RAlCl2, PF5 and SbF5.
19. The process of claim 17 or claim 18 wherein the Lewis Base is selected from the group consisting of CH3 SR1, wherein: R1 is straight chain C1 to C4 alkyl; (CH3 CH2)2 S; (CH3 CH2 CH2)2 S; (CH3)2 SSCH2 SCH3 ; CH3 CH2 SH; (CH3)2 SO; CH3 SCH2 SCH3 : CH3 SCH2 CH2 SCH3 ; tetrahydrothiophene; tetrahydrofuran; diisopropyl sulfide; and p-dioxane.
20. The process of claim 4 wherein the carbenium and siliconium ion sources are selected from the group consisting of CF3 SO3 R, CF3 SO3 SiR3, R2 CH(OR)2, R2 C(OR)3 and R2 C(O)H, where R2 is phenyl or C1 -C6 alkyl, and R is as defined in claim 18.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/276,352 US5196491A (en) | 1988-11-25 | 1988-11-25 | Living cationic polymerization of alkyl vinyl ethers |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/276,352 US5196491A (en) | 1988-11-25 | 1988-11-25 | Living cationic polymerization of alkyl vinyl ethers |
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| US5196491A true US5196491A (en) | 1993-03-23 |
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| US07/276,352 Expired - Fee Related US5196491A (en) | 1988-11-25 | 1988-11-25 | Living cationic polymerization of alkyl vinyl ethers |
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| US5399641A (en) * | 1994-01-10 | 1995-03-21 | Dow Corning Corporation | Method of controlling the polymerization of acrylates |
| US5399631A (en) * | 1992-06-04 | 1995-03-21 | Idemitsu Kosan Co., Ltd. | Polyvinyl ether compound |
| WO1996014345A1 (en) * | 1994-11-08 | 1996-05-17 | Cornell Research Foundation, Inc. | Hyperbranched copolymers from ab monomers and c monomers |
| WO1996014346A1 (en) * | 1994-11-08 | 1996-05-17 | Cornell Research Foundation, Inc. | Hyperbranched polymers from ab monomers |
| US5889128A (en) * | 1997-04-11 | 1999-03-30 | Massachusetts Institute Of Technology | Living olefin polymerization processes |
| WO2011060293A1 (en) * | 2009-11-12 | 2011-05-19 | Ndsu Research Foundation | Polymers derived from plant oil |
| US9382352B2 (en) | 2009-11-12 | 2016-07-05 | Ndsu Research Foundation | Polymers derived from plant oil |
| US9487420B2 (en) | 2012-05-18 | 2016-11-08 | Ndsu Research Foundation | Vegetable oil-based polymers for nanoparticle surface modification |
| US9631040B2 (en) | 2012-05-18 | 2017-04-25 | Ndsu Research Foundation | Functionalized amphiphilic plant-based polymers |
| US9834626B2 (en) | 2013-01-15 | 2017-12-05 | Ndsu Research Foundation | Plant oil-based materials |
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Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5399631A (en) * | 1992-06-04 | 1995-03-21 | Idemitsu Kosan Co., Ltd. | Polyvinyl ether compound |
| US5399641A (en) * | 1994-01-10 | 1995-03-21 | Dow Corning Corporation | Method of controlling the polymerization of acrylates |
| WO1996014345A1 (en) * | 1994-11-08 | 1996-05-17 | Cornell Research Foundation, Inc. | Hyperbranched copolymers from ab monomers and c monomers |
| WO1996014346A1 (en) * | 1994-11-08 | 1996-05-17 | Cornell Research Foundation, Inc. | Hyperbranched polymers from ab monomers |
| US5663260A (en) * | 1994-11-08 | 1997-09-02 | Cornell Research Foundation, Inc. | Hyperbranched copolymers from AB monomers and C monomers |
| US20040138324A1 (en) * | 1997-04-11 | 2004-07-15 | Massachusetts Institute Of Technology | Living olefin polymerization processes |
| US6316555B1 (en) | 1997-04-11 | 2001-11-13 | Massachusetts Institute Of Technology | Living olefin polymerization processes |
| US6610806B2 (en) | 1997-04-11 | 2003-08-26 | Massachusetts Institute Of Technology | Living olefin polymerization processes |
| US5889128A (en) * | 1997-04-11 | 1999-03-30 | Massachusetts Institute Of Technology | Living olefin polymerization processes |
| US20050187345A1 (en) * | 1997-04-11 | 2005-08-25 | Massachusetts Institute Of Technology | Living olefin polymerization processes |
| US7135544B2 (en) | 1997-04-11 | 2006-11-14 | Massachusetts Institute Of Technology | Living olefin polymerization processes |
| WO2011060293A1 (en) * | 2009-11-12 | 2011-05-19 | Ndsu Research Foundation | Polymers derived from plant oil |
| US9382352B2 (en) | 2009-11-12 | 2016-07-05 | Ndsu Research Foundation | Polymers derived from plant oil |
| US9487420B2 (en) | 2012-05-18 | 2016-11-08 | Ndsu Research Foundation | Vegetable oil-based polymers for nanoparticle surface modification |
| US9631040B2 (en) | 2012-05-18 | 2017-04-25 | Ndsu Research Foundation | Functionalized amphiphilic plant-based polymers |
| US9834626B2 (en) | 2013-01-15 | 2017-12-05 | Ndsu Research Foundation | Plant oil-based materials |
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