US3929611A - Electrodepositing of aluminum - Google Patents
Electrodepositing of aluminum Download PDFInfo
- Publication number
- US3929611A US3929611A US489997A US48999774A US3929611A US 3929611 A US3929611 A US 3929611A US 489997 A US489997 A US 489997A US 48999774 A US48999774 A US 48999774A US 3929611 A US3929611 A US 3929611A
- Authority
- US
- United States
- Prior art keywords
- aluminum
- ether
- bath
- hydride
- ethyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 44
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 43
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 46
- 238000000034 method Methods 0.000 claims abstract description 28
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims abstract description 26
- 230000004913 activation Effects 0.000 claims abstract description 12
- -1 ethyl ether Chemical compound 0.000 claims abstract description 12
- 229910052987 metal hydride Inorganic materials 0.000 claims abstract description 11
- 150000004681 metal hydrides Chemical class 0.000 claims abstract description 11
- 239000012280 lithium aluminium hydride Substances 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims abstract description 10
- 229910052751 metal Inorganic materials 0.000 claims abstract description 6
- 239000002184 metal Substances 0.000 claims abstract description 6
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims abstract description 5
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims abstract description 5
- 238000007747 plating Methods 0.000 claims description 36
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 claims description 10
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 5
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims description 5
- SIAPCJWMELPYOE-UHFFFAOYSA-N lithium hydride Chemical compound [LiH] SIAPCJWMELPYOE-UHFFFAOYSA-N 0.000 claims description 5
- 229910000103 lithium hydride Inorganic materials 0.000 claims description 5
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 claims description 5
- DLRJIFUOBPOJNS-UHFFFAOYSA-N phenetole Chemical compound CCOC1=CC=CC=C1 DLRJIFUOBPOJNS-UHFFFAOYSA-N 0.000 claims description 5
- PZHIWRCQKBBTOW-UHFFFAOYSA-N 1-ethoxybutane Chemical compound CCCCOCC PZHIWRCQKBBTOW-UHFFFAOYSA-N 0.000 claims description 4
- 238000004070 electrodeposition Methods 0.000 claims description 4
- 125000001495 ethyl group Chemical class [H]C([H])([H])C([H])([H])* 0.000 claims description 4
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims description 3
- 238000009713 electroplating Methods 0.000 claims description 2
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 claims description 2
- 230000000737 periodic effect Effects 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 239000000243 solution Substances 0.000 description 19
- 229910010082 LiAlH Inorganic materials 0.000 description 6
- 241001156002 Anthonomus pomorum Species 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 150000004678 hydrides Chemical class 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 229910000975 Carbon steel Inorganic materials 0.000 description 2
- 239000010962 carbon steel Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000002659 electrodeposit Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012457 nonaqueous media Substances 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/42—Electroplating: Baths therefor from solutions of light metals
- C25D3/44—Aluminium
Definitions
- This invention relates to electroplating of aluminum from non-aqueous solutions and to a bath for this purpose.
- Plating processes and solutions for electrodeposition of aluminum are known such as'disclosed in Brenner et al. U.S. Pat. No. 2,651,608 upon which this invention is an improvement.
- the solution in Brenner includes anydrous aluminum chloride with 4 molar concentration as the maximum.
- the procedures described in said patent and literature were generally complex and involve using various substrate activation solutions which introduce deleterious contaminants into the plating solution so as to shorten the use ful life thereof by decomposing (through chemical reaction) the relatively expensive hydride in the bath.
- These described procedures also required different activation procedures and/or activation solutions for each metal substrate and were generally not oriented for production purposes. 3
- One of the objects of the invention is to provide a process and bath for producing usable deposits of aluminum on metal.
- Another of the objects of the invention is to provide a bath that is usable for long periods of time without changing or deterioration.
- the process includes plating from a non-aqueous bath having a mixture which includes anhydrous aluminum chloride in a much higher concentration than previously used.
- a molar concentration of at least 4.25 molar through saturation is efficacious with the optimum being between 4.25 to 4.50 molar.
- the bath also has an ether and a metal hydride as set forth hereafter. Ferric chloride or an equivalent iron source also can be added.
- the ether preferably is ethyl ether but ethyl n-butyl ether, a mixture of ethyl and butyl ethers, anisole, phenetole, and di-phenyl ether also can be used.
- the metal hydride preferably is lithium aluminum hydride but lithium hydride and aluminumhydride also can be used.
- the articles can be plated without the complex surface activation of the prior art.
- the article can be degreased if needed and then anodically etched in the bath for k to minutes at current densities of k to 10 amperes per dm.
- the plating can be carried out in an increased range of current density, such as 5 amps/sq ft. to over 100 amps/sq.ft.
- ferric chloride or an equivalent source of iron can be added to the bath which will improve the throwing power of the aluminum plating solution.
- the standard plating solution of Brenner U.S. Pat. No. 2,651,608 has a boiling point of 50 55C. as compared to the increased concentration of aluminum chloride of the present invention which raises the boiling point to 60 65C.
- EXAMPLE I Plating Solution Composition AlCl 4.73 Moles/liter LiAlH 0.41 Moles/liter FeCl (anhydrous) l gram/liter Ethyl ether solvent Plating on Titanium 1. No pretreatment/activation; degrease only if necessary.
- anhydrous aluminum chloride enables the use of simple, universal activation procedures for various metal substrates and, more importantly, permits substrate activation within the aluminum plating solution which eliminates contamination of the plating solution from external activation solutions.
- the plating solution of the invention results in an extremely long use life and exhibits excellent regenerative properties; is insensitive to high impurity levels (e.g., in plating aluminum onto titanium, Brenner uses two plating baths such that the titanium impurity from deplating is confined to one bath); the high aluminum chloride concentration minimizes treeing or excessive buildup at high current density areas; the reduced vapor pressure and increased boiling point of the higher concentration plating solution provide an additional safety feature; and an increased usable range of plating current density (5 amps/sq.ft.) Is attained.
- high impurity levels e.g., in plating aluminum onto titanium, Brenner uses two plating baths such that the titanium impurity from deplating is confined to one bath
- the high aluminum chloride concentration minimizes treeing or excessive buildup at high current density areas
- the reduced vapor pressure and increased boiling point of the higher concentration plating solution provide an additional safety feature
- Aluminum deposit improved, but still poor, still somewhat brittle.
- anisole, phenetole, and di-phenyl ether and a metal hydride selected from the group consisting of lithium hydride, lithium aluminum hydride and aluminum hydride.
- a non-aqueous plating bath for plating aluminum by electrodeposition on bare metal without activation comprising anhydrous aluminum chloride at from 4.25 molar to saturation; an ether selected from the group consisting of a mixture of ethyl and butyl ether, anisole, phenetole, ethyl n-butyl ether, di-phenyl ether and ethyl ether; and a metal hydride selected from the group consisting of lithium hydride, lithium aluminum hydride and aluminum hydride.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Abstract
A method and bath for electrodepositing aluminum directly onto metal without the necessity of activation of the surface thereof wherein the bath is a mixture of anhydrous aluminum chloride at from 4.25 molar to saturation, an ether, such as ethyl ether, and a metal hydride, such as lithium aluminum hydride. Also an agent for improvement of the throwing power, such as ferric chloride, can be used.
Description
United States Patent [191 Hess [ 1 Dec. 30, 1975 [54] ELECTRODEPOSITING OF ALUMINUM [75] Inventor: Irving J. Hess, Philadelphia, Pa.
[73] Assignee: Ametek, Inc., New York, NY.
[22] Filed: July 19, 1974 [21] Appl. No.: 489,997
[52] US. Cl 204/14 N [51] Int. Cl. C25D l/00 [58] Field of Search 204/14 R, 14 N, 39
[56] References Cited UNITED STATES PATENTS 2,651,608 9/1953 Brenner 204/14 N OTHER PUBLICATIONS Journal of the Electrochemical Society, June, 1952,
v01. 99, No. 6, pp. 234-244. Plating, Sept., 1969, pp. 1027-1037.
Primary Examiner-T. M. Tufariello Attorney, Agent, or FirmSmythe & Moore [57] ABSTRACT 13 Claims, No Drawings ELECTRODEPOSITING OF ALUMINUM This invention relates to electroplating of aluminum from non-aqueous solutions and to a bath for this purpose.
Plating processes and solutions for electrodeposition of aluminum are known such as'disclosed in Brenner et al. U.S. Pat. No. 2,651,608 upon which this invention is an improvement. The solution in Brenner includes anydrous aluminum chloride with 4 molar concentration as the maximum. There also is a discussion of the subject in the article entitled A Hydride Bath for the Electrodeposition of Aluminum" b'y Couch and Brenner appearing in the Journal of the Electrochemical Society, Volume 99, No. 6, Pp. 234 to 244. The procedures described in said patent and literature were generally complex and involve using various substrate activation solutions which introduce deleterious contaminants into the plating solution so as to shorten the use ful life thereof by decomposing (through chemical reaction) the relatively expensive hydride in the bath. These described procedures also required different activation procedures and/or activation solutions for each metal substrate and were generally not oriented for production purposes. 3
One of the objects of the invention is to provide a process and bath for producing usable deposits of aluminum on metal.
Another of the objects of the invention is to provide a bath that is usable for long periods of time without changing or deterioration.
In one aspect of the invention, the process includes plating from a non-aqueous bath having a mixture which includes anhydrous aluminum chloride in a much higher concentration than previously used. A molar concentration of at least 4.25 molar through saturation is efficacious with the optimum being between 4.25 to 4.50 molar. The bath also has an ether and a metal hydride as set forth hereafter. Ferric chloride or an equivalent iron source also can be added.
The ether preferably is ethyl ether but ethyl n-butyl ether, a mixture of ethyl and butyl ethers, anisole, phenetole, and di-phenyl ether also can be used.
The metal hydride preferably is lithium aluminum hydride but lithium hydride and aluminumhydride also can be used.
The articles can be plated without the complex surface activation of the prior art. The article can be degreased if needed and then anodically etched in the bath for k to minutes at current densities of k to 10 amperes per dm. The plating can be carried out in an increased range of current density, such as 5 amps/sq ft. to over 100 amps/sq.ft.
Also ferric chloride or an equivalent source of iron can be added to the bath which will improve the throwing power of the aluminum plating solution.
The standard plating solution of Brenner U.S. Pat. No. 2,651,608 has a boiling point of 50 55C. as compared to the increased concentration of aluminum chloride of the present invention which raises the boiling point to 60 65C.
It has been found that at the high current density end of the plate, treeing is less for the present invention and better coverage is obtained at low current density. Barrel plated parts have been satisfactorily plated at an average current density of 5 amps/sq.ft.
Polarity also can be advantageously reversed.
' The following are specific examples of procedures in a bath of the present invention.
EXAMPLE I Plating Solution Composition AlCl 4.73 Moles/liter LiAlH 0.41 Moles/liter FeCl (anhydrous) l gram/liter Ethyl ether solvent Plating on Titanium 1. No pretreatment/activation; degrease only if necessary.
2. Anodic etch in bath (separate etch bath not recommended) at 10 ampslsqft. for 2-3 minutes (typically for 8 inches X 18 inches barrel loads).
3. Rapid current reversal to make parts cathodic.
4. Plate at 10 ampslsqft. with no restriction on current density.
EXAMPLE [I Plating Solution Composition AlCl 4.28 Moles/liter LiAll-L, 0.40 Moles/liter Ethyl ether solvent Plating on Carbon Steel EXAMPLE III Plating Solution Composition AlCl 4.37 Moles/liter LiAll-l 0.40 Moles/liter Ethyl ether solvent Plating on Stainless Steel 1. No pretreatment/activation; degrease only if necessary.
2. Anodic etch in bath (separate etch bath not recommended) at 10 ampslsqft. for 2-3 minutes (typically for 8 inches X 18 inches barrel loads).
3. Rapid current reversal to make parts cathodic.
4. Plate at 10 amps/sq.ft. with no restriction on current density.
Summarizing, the increased concentration of anhydrous aluminum chloride enables the use of simple, universal activation procedures for various metal substrates and, more importantly, permits substrate activation within the aluminum plating solution which eliminates contamination of the plating solution from external activation solutions.
The plating solution of the invention results in an extremely long use life and exhibits excellent regenerative properties; is insensitive to high impurity levels (e.g., in plating aluminum onto titanium, Brenner uses two plating baths such that the titanium impurity from deplating is confined to one bath); the high aluminum chloride concentration minimizes treeing or excessive buildup at high current density areas; the reduced vapor pressure and increased boiling point of the higher concentration plating solution provide an additional safety feature; and an increased usable range of plating current density (5 amps/sq.ft.) Is attained.
d. A 2.0 2.0X8.0 inch tank filled with aluminum plating solution to the 6.0 inch level was used. An 1 100 aluminum alloy sheet, l.OX5.0 inch immersed in the plating solution was used with a carbon steel cathode, also l.OX5.0 inch immersed in solution. All plating was performed at amps/sq.ft. current density for] hour for all specimens in both baths.
BATH LIFE TABLE OBSERVATIONS OF QUALITY OF ALUMINUM DEPOSIT CUMULATIVE No. of RUNS BRENNER TYPE BATH BATH OF PRESENT INVENTION A comparison of bath life between a fresh Brenner Good, ductile aluminum Good aluminum, but slightly gray at comers (high current density areas) aluminum deposit still acceptable but somewhat gray in appearance with dark gray coloration at comers Good, ductile aluminum Dark gray coloration at corners Dark gray coloration at comers Deposit covered with vertical gray streaks, very brittle. Added 0.1 M LiAlI-l prior to start of 27th run.
Acceptable aluminum, definitely below quality of original deposit.
Dark gray coloration at comers Deposit dark, brittle, added 0.1 M LiAlH. prior to start of 32nd run.
Aluminum deposit improved, but still poor, still somewhat brittle.
Dark gray coloration at corners. Added 0.] M LiAlI-L prior to start of 34th run.
Aluminum deposit dark and brittle. Added o.l M LiAlH, prior to start of 35th run.
Aluminum deposit still dark and brittle. Bath no longer corrected by hydride addition Good, ductile aluminum Good. ductile aluminum No visible change in aluminum quality No visible change in aluminum quality No visible change in aluminum quality Slight change in coloration (darkening) of aluminum deposit. Aluminum still acceptable; slightly brittle. Added 0.1
M LiAlH prior to start of 26th run.
Good, ductile aluminum Good, ductile aluminum No visible change in aluminum quality.
No visible change in aluminum quality.
No visible change in aluminum quality No visible change in aluminum quality Slight change in coloration of aluminum deposit. Aluminum still acceptable. Added 0.1 M LiAlH. prior to start of 35th run Good. ductile aluminum It will be understood that various details of constructype aluminum plating bath a. 3.0 M AlCl and 0.4 M LiAlI-I, dissolved in ethyl ether, and a fresh aluminum plating bath in accordance with the present invention b. 4.3 M AlCl and 0.4 M LiAlH dissolved in ethyl ether was made, and the results thereof are tabulated hereafter:
c. A small quantity (400 ml.) of plating solution was utilized rather than a larger volume so that the effect of impurity levels on the. quality of the electrodeposit would occur quickly.
anisole, phenetole, and di-phenyl ether; and a metal hydride selected from the group consisting of lithium hydride, lithium aluminum hydride and aluminum hydride.
2. The process as claimed in claim 1 wherein the ether is ethyl ether and the metal hydride is lithium aluminum hydride.
3. The process as claimed in claim 1 wherein the current density is from 0.5 to ampers per dm 4. The process as claimed in claim 2 wherein the current density is from 0.5 to 10 ampers per dm 5. The process as claimed in claim 3 wherein anhydrous iron chloride is added to improve the throwing power of the bath.
6. The process as claimed in claim 1 wherein periodic reverse currents are applied across the bath, the effective current being from 0.5 to 25 amperes per dm.
7. The process as claimed in claim 1 wherein the part to be plated is anodically etched.
8. The process as claimed in claim 7 wherein the etch is in the range of 10 amperes per square foot and 2 to 3 minutes.
9. The process as claimed in claim 1 wherein the anhydrous aluminum chloride is 4.50 molar.
10. A non-aqueous plating bath for plating aluminum by electrodeposition on bare metal without activation comprising anhydrous aluminum chloride at from 4.25 molar to saturation; an ether selected from the group consisting of a mixture of ethyl and butyl ether, anisole, phenetole, ethyl n-butyl ether, di-phenyl ether and ethyl ether; and a metal hydride selected from the group consisting of lithium hydride, lithium aluminum hydride and aluminum hydride.
11. The plating bath as claimed in claim 10 wherein the ether is ethyl ether and the metal hydride is lithium aluminum hydride.
12. The plating bath as claimed in claim 10 wherein anhydrous ferric chloride is added to improve the throwing power of the bath.
13. The process as claimed in claim 1 wherein the anhydrous aluminum chloride is from 4.25 to 4.50
molar.
Claims (13)
1. THE PROCESS OF ELECTROPLATING COMPRISING THE STEPS OF PLATING ALUMINUM FROM A NON-AQUEOUS PLATING BATH COMPRISING THE STEPS OF ELECTRODEPOSITING ALUMINUM FROM A BATH CONSISTING OF A MIXTURE OF ANHYDROUS ALUMINUM CHLORIDE AT FROM 4.25 MOLAR TO SATURATION; AND ETHER SELECTED FROM THE GROUP CONSISTING OF ETHYL ETHER, ETHYL N-BUTYL ETHER, A MIXTURE OF ETHYL AND BUTYL ETHERS, ANISOLE, PHENETOL, AND DI-PHENYL ETHER; AND A METAL HYDRIDE SELECTED FROM THE GROUP CONSISTING OF LITHIUM HYDRIDE, LITHIUM ALUMINUM HYDRIDE AND ALUMINUM HYDRIDE.
2. The process as claimed in claim 1 wherein the ether is ethyl ether and the metal hydride is lithium aluminum hydride.
3. The process as claimed in claim 1 wherein the current density is from 0.5 to 10 ampers per dm2.
4. The process as claimed in claim 2 wherein the current density is from 0.5 to 10 ampers per dm2.
5. The process as claimed in claim 3 wherein anhydrous iron chloride is added to improve the throwing power of the bath.
6. The process as claimed in claim 1 wherein periodic reverse currents are applied across the bath, the effective current being from 0.5 to 25 amperes per dm2.
7. The process as claimed in claim 1 wherein the part to be plated is anodically etched.
8. The process as claimed in claim 7 wherein the etch is in the range of 10 amperes per square foot and 2 to 3 minutes.
9. The process as claimed in claim 1 wherein the anhydrous aluminum chloride is 4.50 molar.
10. A non-aqueous plating bath for plating aluminum by electrodeposition on bare metal without activation comprising anhydrous aluminum chloride at from 4.25 molar to saturation; an ether selected from the group consisting of a mixture of ethyl and butyl ether, anisole, phenetole, ethyl n-butyl ether, di-phenyl ether and ethyl ether; and a metal hydride selected from the group consisting of lithium hydride, lithium aluminum hydride and aluminum hydride.
11. The plating bath as claimed in claim 10 wherein the ether is ethyl ether and the metal hydride is lithium aluminum hydride.
12. The plating bath as claimed in claim 10 wherein anhydrous ferric chloride is added to improve the throwing power of the bath.
13. The process as claimed in claim 1 wherein the anhydrous aluminum chloride is from 4.25 to 4.50 molar.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US489997A US3929611A (en) | 1974-07-19 | 1974-07-19 | Electrodepositing of aluminum |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US489997A US3929611A (en) | 1974-07-19 | 1974-07-19 | Electrodepositing of aluminum |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3929611A true US3929611A (en) | 1975-12-30 |
Family
ID=23946175
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US489997A Expired - Lifetime US3929611A (en) | 1974-07-19 | 1974-07-19 | Electrodepositing of aluminum |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US3929611A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4145261A (en) * | 1977-02-25 | 1979-03-20 | U.S. Philips Corporation | Electrolyte-liquid for the electrodeposition of aluminum |
| DE2920302A1 (en) * | 1978-05-22 | 1979-11-29 | Philips Nv | ELECTROLYTE LIQUID FOR GALVANIC SEPARATION OF ALUMINUM |
| DE2949104A1 (en) * | 1978-12-12 | 1980-06-26 | Philips Nv | METHOD FOR PRODUCING OBJECTS WITH A SUPER-SMOOTH ALUMINUM SURFACE |
| US4417954A (en) * | 1982-01-25 | 1983-11-29 | Siemens Aktiengesellschaft | Electrolyte for the electrodeposition of aluminum |
| EP0323520A4 (en) * | 1987-07-13 | 1989-09-19 | Nisshin Steel Co Ltd | Process for electroplating metal plate with aluminum. |
| EP2662478A4 (en) * | 2011-01-05 | 2017-08-09 | Dipsol Chemicals Co., Ltd. | Electrical aluminium or aluminium alloy fused salt plating bath having good throwing power, and electroplating method and pretreatment method using same |
| US11661665B2 (en) | 2020-04-30 | 2023-05-30 | The Boeing Company | Aluminum and aluminum alloy electroplated coatings |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2651608A (en) * | 1952-01-25 | 1953-09-08 | Brenner Abner | Electrodeposition of aluminum from nonaqueous solutions |
-
1974
- 1974-07-19 US US489997A patent/US3929611A/en not_active Expired - Lifetime
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2651608A (en) * | 1952-01-25 | 1953-09-08 | Brenner Abner | Electrodeposition of aluminum from nonaqueous solutions |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4145261A (en) * | 1977-02-25 | 1979-03-20 | U.S. Philips Corporation | Electrolyte-liquid for the electrodeposition of aluminum |
| DE2920302A1 (en) * | 1978-05-22 | 1979-11-29 | Philips Nv | ELECTROLYTE LIQUID FOR GALVANIC SEPARATION OF ALUMINUM |
| US4222827A (en) * | 1978-05-22 | 1980-09-16 | U.S. Philips Corporation | Electroplating solution for the electrodeposition of aluminium |
| DE2949104A1 (en) * | 1978-12-12 | 1980-06-26 | Philips Nv | METHOD FOR PRODUCING OBJECTS WITH A SUPER-SMOOTH ALUMINUM SURFACE |
| US4257854A (en) * | 1978-12-12 | 1981-03-24 | U.S. Philips Corporation | Method of producing objects with a supersmooth aluminum surface |
| US4417954A (en) * | 1982-01-25 | 1983-11-29 | Siemens Aktiengesellschaft | Electrolyte for the electrodeposition of aluminum |
| EP0323520A4 (en) * | 1987-07-13 | 1989-09-19 | Nisshin Steel Co Ltd | Process for electroplating metal plate with aluminum. |
| EP2662478A4 (en) * | 2011-01-05 | 2017-08-09 | Dipsol Chemicals Co., Ltd. | Electrical aluminium or aluminium alloy fused salt plating bath having good throwing power, and electroplating method and pretreatment method using same |
| US9926638B2 (en) * | 2011-01-05 | 2018-03-27 | Dipsol Chemicals Co., Ltd. | Aluminum or aluminum alloy molten salt electroplating bath having good throwing power, electroplating method using the bath, and pretreatment method of the bath |
| US10309025B2 (en) | 2011-01-05 | 2019-06-04 | Dipsol Chemicals Co., Ltd. | Aluminum or aluminum alloy molten salt electroplating bath having good throwing power, electroplating method using the bath, and pretreatment method of the bath |
| US11661665B2 (en) | 2020-04-30 | 2023-05-30 | The Boeing Company | Aluminum and aluminum alloy electroplated coatings |
| US12371807B2 (en) | 2020-04-30 | 2025-07-29 | The Boeing Company | Aluminum and aluminum alloy electroplated coatings |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US2446331A (en) | Electrodeposition of aluminum | |
| US2525942A (en) | Electrodepositing bath and process | |
| US2436316A (en) | Bright alloy plating | |
| USRE31508E (en) | Electrodeposition of chromium | |
| US4021315A (en) | Process for electrolytic coloring of the anodic oxide film on aluminum or aluminum base alloys | |
| GB2062010A (en) | Electroplating Bath and Process | |
| US2250556A (en) | Electrodeposition of copper and bath therefor | |
| US3929611A (en) | Electrodepositing of aluminum | |
| Yoshio et al. | High-rate plating of aluminium from the bath containing aluminium chloride and lithium aluminium hydride in tetrahydrofuran | |
| GB1562188A (en) | Chromium electroplating baths | |
| GB2179676A (en) | Zinc alloy electroplating | |
| US2990343A (en) | Chromium alloy plating | |
| US1993623A (en) | Electrodeposition of platinum metals | |
| US3511759A (en) | Method and electrolytes for electro-depositing black chromium | |
| US3788957A (en) | Electrodeposition of chromium | |
| US4439285A (en) | Trivalent chromium electrolyte and process employing neodymium reducing agent | |
| US4422908A (en) | Zinc plating | |
| US2809156A (en) | Electrodeposition of iron and iron alloys | |
| US3634205A (en) | Method of plating a uniform copper layer on an apertured printed circuit board | |
| US2763605A (en) | Electrodepositing aluminum | |
| US3706639A (en) | Rejuvenated chromium plating medium containing chromic compound | |
| JP2953474B2 (en) | Electrolytic treatment of aluminum and aluminum alloy | |
| US3920527A (en) | Self-regulating plating bath and method for electrodepositing chromium | |
| US3697392A (en) | Electrodeposition of nickel | |
| US3711384A (en) | Electrodeposition of nickel |