US3892393A - Lance tip - Google Patents
Lance tip Download PDFInfo
- Publication number
- US3892393A US3892393A US330289A US33028973A US3892393A US 3892393 A US3892393 A US 3892393A US 330289 A US330289 A US 330289A US 33028973 A US33028973 A US 33028973A US 3892393 A US3892393 A US 3892393A
- Authority
- US
- United States
- Prior art keywords
- lance
- oxygen
- deflecting
- delivery tube
- conical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 43
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 43
- 239000001301 oxygen Substances 0.000 claims abstract description 43
- 239000012530 fluid Substances 0.000 claims abstract description 12
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 6
- 239000010949 copper Substances 0.000 claims description 6
- 229910000831 Steel Inorganic materials 0.000 abstract description 7
- 238000010521 absorption reaction Methods 0.000 abstract description 7
- 239000010959 steel Substances 0.000 abstract description 7
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 229910000805 Pig iron Inorganic materials 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 238000009628 steelmaking Methods 0.000 description 4
- 238000007670 refining Methods 0.000 description 3
- 125000006850 spacer group Chemical group 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 235000021028 berry Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000012809 cooling fluid Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000008570 general process Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- PSGAAPLEWMOORI-PEINSRQWSA-N medroxyprogesterone acetate Chemical compound C([C@@]12C)CC(=O)C=C1[C@@H](C)C[C@@H]1[C@@H]2CC[C@]2(C)[C@@](OC(C)=O)(C(C)=O)CC[C@H]21 PSGAAPLEWMOORI-PEINSRQWSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
- C21C5/28—Manufacture of steel in the converter
- C21C5/42—Constructional features of converters
- C21C5/46—Details or accessories
- C21C5/4606—Lances or injectors
Definitions
- 34 LM, m 3 F 266/41 manufacturing process Includes means for deflecting the oxygen flow Issuing from the lance, heat absorp- [56] Reierences Ci'ed tion means formed with the means for deflecting the oxygen flow, and heat absorption means associated UNITED STATES PATENTS with the circulating fluid disposed within the lance Berry 1 L
- the present invention obviates the burning of the 3,322,419 5/1967 Smith et al. H 266/34 L hfletofore known lance tips 3,334,885 8/1967 Taylor .1 266/34 L 3,337,203 8/1967 Smith et al.
- the present invention pertains to steel manufacturing processes and equipment. More particularly, the present invention pertains to oxygen steel-making processes and equipment. Even more particularly, the present invention pertains to lance tips for oxygen lances used in oxygen steel making processes.
- a jet of oxygen is blown at high pressure through a tube onto the surface of molten iron in a converter-type vessel.
- This tube is generally denoted in the trade as a lance.
- the present invention seeks to obviate this drawback in the prior art by providing a lance tip having an inherently longer useful time and therefore does not require such constant replacement.
- an oxygen lance is provided with a lance tip comprising means for deflecting the oxygen issuing from the lance and means for absorbing the heat generated about the lance tip.
- the means for deflecting the oxygen generally comprises a conical shaped member which is insertable within the lance and rigidly secured to the interior walls thereof. Proximate the apex the conical member is formed from any suitable steel. The remainder of the conical member is formed from copper.
- the present lance tip further includes heat absorption means which are fixedly secured to the lance at the lower most end thereof.
- the heat absorption means and the conical member define the lance tip hereof.
- the conical member be provided with heat absorption means disposed around the periphery thereof and which cooperates with the other heat absorption means to prevent burn out of the lance tip.
- FIG. I is a side elevation view, part in section, of a steel crucible deploying the oxygen lance
- FIG. 2 is a side view, part in section, of the lance tip of the present invention.
- FIG. 3 is a cross-sectional view along the line 33 of FIG. 2;
- FIG. 4 is a cross-sectional view along the line 4-4 of FIG. 2.
- the present invention pertains to oxygen steel making processes.
- a lance comprises an elongated tube member connected at one end to a source of oxygen under pressure.
- fluid circulation means which acts to cool the lance.
- the fluid circulation means generally employs water as the cooling fluid. In essence, therefore, the lance comprises the water circulation means circumferentially disposed about the oxygen delivery tube.
- FIG. 1 there is depicted therein the above-defined general process to which the present invention pertains.
- a crucible 10 containing molten pig iron 12.
- a lance 14 has oxygen issuing therefrom at the end 16 of the lance 14. It is at the end 16 in which the lance tip, generally indicated at 18, is deployed.
- the lance tip 18 of the present invention generally includes means for deflecting the oxygen issuing from the lance and denoted by the numeral 20.
- the lance tip further includes means 22 which absorb the heat generated about the lance end I6.
- the means 22 extends between the outer wall 24 of the lance and the oxygen delivery tube 26 disposed within the lance 14.
- the means for absorbing heat 22, such as ribs 23, are rigidly secured between the outer wall 24 and the oxygen delivery tube 26 by any suitable means such as welding, and the like. Because of its intended purpose in absorbing heat, the means 22 is preferably formed from copper.
- a plurality of ribs 22 are circumferentially disposed about the end [6 of the lance l4, and as shown in FIG. 4.
- the means 22 have the heat absorbed thereby absorbed by circulating fluid (not shown) which circulates within conduits 28 and 30 disposed within the lance 14.
- the fluid flows in the direction of the arrows as shown in FIG. 2.
- the fluid is water.
- the means 20 for deflecting the oxygen issuing from the end I6 generally comprises any suitable member 32 capable of deflecting the oxygen issuing from the end I6 from about 8 to 15 and preferably from about 8 to about I2".
- the member 32 is substantially disposed within the interior of the oxygen delivery tube 26 and is rigidly fixed thereto.
- the member 32 preferably comprises a conical member having its base 34 substantially co-planar with the end I6.
- the apex 36 extends and is disposed vertically upward from the base.
- a plurality of spacers 38 disposed proximate the apex 36 extend between the periphery of the member 32 and the interior wall of the tube 26.
- the spacers 38 have one end thereof rigidly affixed to the member 32 and their other end rigidly affixed to the interior wall of the tube 26 thereby providing rigid connection between the member 32 and the delivery tube 26.
- the spacers can be rigidly fixed at their respective ends to the member 32 and the tube 26 such as by welding or the like to provide the innerconnection.
- the area proximate the apex of the member be formed of any suitable steel while the area proximate the base be formed of copper for heat transfer purposes.
- the member 32 be provided with a plurality of projections 40 which extend from the apex to the base about the periphery of the member 32.
- the projections which are preferably formed of copper, further provide means for dissipating or absorbing the heat generated about the lance tip.
- the lance tip of the present invention affords a means whereby the heat generated about the lance tip is dissipated such that no burnout occurs thereat.
- the heretofore known devices, as hereinbefore noted because of their construction with minute orifices and the like are generally caused to burn out by the tremendous heat generated at the lance tip over a very short time period. Because there are no orifices or the like, and by the further provision of means for absorbing the heat. this prior art problem is now overcome.
- an oxygen lance of the type comprising an oxygen delivery tube having fluid circulation means circumferencially disposed therearound, a lance tip therefor, comprising in combination:
- Central means for deflecting the oxygen issuing from said lance, said means for deflecting the oxygen being affixed to said oxygen delivery tube, said means for deflecting the oxygen having a plurality of means for absorbing heat therefrom disposed about the periphery thereof and being formed therewith;
- At least one rib for absorbing the heat generated about the end of said lance.
- said rib being disposed within and extending from the outer wall of said fluid circulation means to said oxygen delivery tube;
- said means for deflecting the oxygen comprises a conical member and the area proximate the apex of the conical member is formed from steel and the area proximate the base of the conical member is formed from copper.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Carbon Steel Or Casting Steel Manufacturing (AREA)
- Treatment Of Steel In Its Molten State (AREA)
Abstract
A lance tip for use with an oxygen lance in a steel manufacturing process includes means for deflecting the oxygen flow issuing from the lance, heat absorption means formed with the means for deflecting the oxygen flow, and heat absorption means associated with the circulating fluid disposed within the lance. The present invention obviates the burning of the heretofore known lance tips.
Description
United States Patent Carroll et al. July 1, 1975 [5 1 LANCE TIP 3,346.190 10/1967 Shepherd 1, 266/34 L 3,350,080 10 I967 M 266 34 L [75] Inventors: John T. Carroll, New Boston; amen Nathan G. Harris, Wyandotte, both FOREIGN PATENTS OR APPLlCATlONS 0f Michv 45-32323 10/1970 Japan 266/34 L I I l,0O9.327 ll/l965 United Kingdom 1. [73] Assignee. John T. Carroll, N6 Boston, M1ch, 995,688 6/1965 United Kingdom u 266/34 L [22] Filed: Feb. 7, i973 Primary ExaminerGerald A. Dost [2]] Appl 330289 Attorney, Agent, or Firmlrving M. Weiner [52] U.S. Cl 266/34 L- 57 ABSTRACT {5i} Int. Cl. C2lc 7/00 A l f h l I [581 Field 61 Search... 239/132.3; 266/34 L. 34 LM, m 3 F 266/41 manufacturing process Includes means for deflecting the oxygen flow Issuing from the lance, heat absorp- [56] Reierences Ci'ed tion means formed with the means for deflecting the oxygen flow, and heat absorption means associated UNITED STATES PATENTS with the circulating fluid disposed within the lance Berry 1 L The present invention obviates the burning of the 3,322,419 5/1967 Smith et al. H 266/34 L hfletofore known lance tips 3,334,885 8/1967 Taylor .1 266/34 L 3,337,203 8/1967 Smith et al. 266/34 L 2 Claims, 4 Drawing Figures PBiTEHTFRJuu LANCE TIP BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention pertains to steel manufacturing processes and equipment. More particularly, the present invention pertains to oxygen steel-making processes and equipment. Even more particularly, the present invention pertains to lance tips for oxygen lances used in oxygen steel making processes.
2. Prior Art In recent years the application of pure oxygen in steel refining processes has lead to the emergence of new steel making processes. Generally, such processes include the use of almost pure oxygen which is blown onto the molten pig iron.
In the process under consideration herein a jet of oxygen is blown at high pressure through a tube onto the surface of molten iron in a converter-type vessel. This tube is generally denoted in the trade as a lance.
At the lower most end of the tube there is generally provided a lance tip from which oxygen issues out onto the surface of the molten pig iron.
Heretofore known lance tips have generally been deficient in one major regard. Because of the high temperatures associated with the refining processes, the tip has a tendency to burn thereby requiring almost constant replacement. This results in a plurality of disadvantages, such as down time, loss of useful production time, and the like.
The present invention, on the other hand, seeks to obviate this drawback in the prior art by providing a lance tip having an inherently longer useful time and therefore does not require such constant replacement.
SUMMARY OF THE INVENTION In accordance with the present invention an oxygen lance is provided with a lance tip comprising means for deflecting the oxygen issuing from the lance and means for absorbing the heat generated about the lance tip.
The means for deflecting the oxygen generally comprises a conical shaped member which is insertable within the lance and rigidly secured to the interior walls thereof. Proximate the apex the conical member is formed from any suitable steel. The remainder of the conical member is formed from copper.
The present lance tip further includes heat absorption means which are fixedly secured to the lance at the lower most end thereof.
The heat absorption means and the conical member define the lance tip hereof.
It is further contemplated that the conical member be provided with heat absorption means disposed around the periphery thereof and which cooperates with the other heat absorption means to prevent burn out of the lance tip.
For a more complete understanding of the present invention reference is made to the following detailed description and accompanying drawing. In the drawing like reference characters refer to like parts throughout the several views in which:
BRIEF DESCRIPTION OF THE DRAWING FIG. I is a side elevation view, part in section, of a steel crucible deploying the oxygen lance;
FIG. 2 is a side view, part in section, of the lance tip of the present invention;
FIG. 3 is a cross-sectional view along the line 33 of FIG. 2; and
FIG. 4 is a cross-sectional view along the line 4-4 of FIG. 2.
DESCRIPTION OF THE PREFERRED EMBODIMENTS As hereinbefore noted the present invention pertains to oxygen steel making processes. Generally speaking, such processes provide for a crucible which contains therein molten pig iron. In refining molten pig iron oxygen is delivered thereto through a lance. As is generally known in the art, a lance comprises an elongated tube member connected at one end to a source of oxygen under pressure. Circumferentially disposed around the oxygen tube is fluid circulation means which acts to cool the lance. The fluid circulation means generally employs water as the cooling fluid. In essence, therefore, the lance comprises the water circulation means circumferentially disposed about the oxygen delivery tube.
Now, with reference to the drawing, and in particular FIG. 1, there is depicted therein the above-defined general process to which the present invention pertains. As shown therein, a crucible 10 containing molten pig iron 12. A lance 14 has oxygen issuing therefrom at the end 16 of the lance 14. It is at the end 16 in which the lance tip, generally indicated at 18, is deployed.
Referring now to FIGS. 2 through 4, there is shown therein the lance tip 18 of the present invention. The lance tip generally includes means for deflecting the oxygen issuing from the lance and denoted by the numeral 20. The lance tip further includes means 22 which absorb the heat generated about the lance end I6. The means 22 extends between the outer wall 24 of the lance and the oxygen delivery tube 26 disposed within the lance 14. The means for absorbing heat 22, such as ribs 23, are rigidly secured between the outer wall 24 and the oxygen delivery tube 26 by any suitable means such as welding, and the like. Because of its intended purpose in absorbing heat, the means 22 is preferably formed from copper. Preferably a plurality of ribs 22 are circumferentially disposed about the end [6 of the lance l4, and as shown in FIG. 4.
The means 22 have the heat absorbed thereby absorbed by circulating fluid (not shown) which circulates within conduits 28 and 30 disposed within the lance 14. The fluid flows in the direction of the arrows as shown in FIG. 2. Generally the fluid is water. Thus, by the disposition of the ribs and the circulating fluid the temperature at the end of the tube is maintained at a minimal level.
The means 20 for deflecting the oxygen issuing from the end I6 generally comprises any suitable member 32 capable of deflecting the oxygen issuing from the end I6 from about 8 to 15 and preferably from about 8 to about I2". The member 32 is substantially disposed within the interior of the oxygen delivery tube 26 and is rigidly fixed thereto.
As shown in FIG. 2, the member 32 preferably comprises a conical member having its base 34 substantially co-planar with the end I6. The apex 36 extends and is disposed vertically upward from the base.
A plurality of spacers 38 disposed proximate the apex 36 extend between the periphery of the member 32 and the interior wall of the tube 26. The spacers 38 have one end thereof rigidly affixed to the member 32 and their other end rigidly affixed to the interior wall of the tube 26 thereby providing rigid connection between the member 32 and the delivery tube 26. The spacers can be rigidly fixed at their respective ends to the member 32 and the tube 26 such as by welding or the like to provide the innerconnection.
It is generally contemplated by the present invention that the area proximate the apex of the member be formed of any suitable steel while the area proximate the base be formed of copper for heat transfer purposes.
It is also within the scope of the present invention that the member 32 be provided with a plurality of projections 40 which extend from the apex to the base about the periphery of the member 32. The projections, which are preferably formed of copper, further provide means for dissipating or absorbing the heat generated about the lance tip.
The lance tip of the present invention affords a means whereby the heat generated about the lance tip is dissipated such that no burnout occurs thereat. The heretofore known devices, as hereinbefore noted, because of their construction with minute orifices and the like are generally caused to burn out by the tremendous heat generated at the lance tip over a very short time period. Because there are no orifices or the like, and by the further provision of means for absorbing the heat. this prior art problem is now overcome.
We claim:
1. In an oxygen lance of the type comprising an oxygen delivery tube having fluid circulation means circumferencially disposed therearound, a lance tip therefor, comprising in combination:
Central means for deflecting the oxygen issuing from said lance, said means for deflecting the oxygen being affixed to said oxygen delivery tube, said means for deflecting the oxygen having a plurality of means for absorbing heat therefrom disposed about the periphery thereof and being formed therewith;
at least one rib for absorbing the heat generated about the end of said lance. said rib being disposed within and extending from the outer wall of said fluid circulation means to said oxygen delivery tube; and
said means for deflecting the oxygen comprises a conical member and the area proximate the apex of the conical member is formed from steel and the area proximate the base of the conical member is formed from copper.
2. The lance tip of claim I wherein the conical angle is from between 8 to 15 and the conical member is affixed to the oxygen delivery tube interiorly thereof.
Claims (2)
1. IN AN OXYGEN LANCE OF THE TYPE COMPRISING OXYGEN DELIVERY TUBE HAVING FLUID CIRCULATION MEANS CIRCUMFERENCIALLY DISPOSED THEREAROUND, A LANCE TIP THEREFOR, COMPRISING IN COMBINATION: CENTRAL MEANS FOR DEFLECTING THE OXYGEN ISSUING FROM SAID LANCE, SAID MEANS FOR DEFLECTING THE OXYGEN BEING AFFIXED TO SAID OXYGEN DELIVERY TUBE, SAID MEANS FOR DEFLECTING THE OXYGEN HAVING A PLURALITY OF MEANS FOR ABSORBING HEAT THEREFROM DISPOSED ABOUT THE PERIPHERY THEREOF AND BEING FORMED THEREWITH, AT LEAST ONE RIB FOR ABSORBING THE HEAT GENERATED ABOUT THE END OF SAID LANCE, SAID RIB BEING DISPOSED WITHIN AND EXTENDING FROM THE OUTER WALL OF SAID FLUID CIRCULATION MEANS TO SAID OXYGEN DELIVERY TUBE, AND MEMBER AND THE AREA PROXIMATE THE APEX OF TH CONICAL MEMBER IS FORMED FRM STEEL AND THE AREA PROXIMATE THE BASE OF THE CONICAL MEMBER IS FORMED FROM COPPER. SAID MEANS FOR DEFLECTING THE OXYGEN COMPRISES A CONICAL
2. The lance tip of claim 1 wherein the conical angle is from between 8* to 15* and the conical member is affixed to the oxygen delivery tube interiorly thereof.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US330289A US3892393A (en) | 1973-02-07 | 1973-02-07 | Lance tip |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US330289A US3892393A (en) | 1973-02-07 | 1973-02-07 | Lance tip |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3892393A true US3892393A (en) | 1975-07-01 |
Family
ID=23289097
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US330289A Expired - Lifetime US3892393A (en) | 1973-02-07 | 1973-02-07 | Lance tip |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US3892393A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4022447A (en) * | 1976-02-23 | 1977-05-10 | United States Steel Corporation | Supersonic nozzle for submerged tuyere oxygen steelmaking process |
| JP2008190854A (en) * | 2006-12-15 | 2008-08-21 | Technological Resources Pty Ltd | Apparatus for injecting gas into vessel |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3201104A (en) * | 1962-08-21 | 1965-08-17 | Walter V Berry | Oxygen lance for subsurface use |
| US3322419A (en) * | 1964-12-24 | 1967-05-30 | Union Carbide Corp | Oxygen jet devices |
| US3334885A (en) * | 1964-11-12 | 1967-08-08 | Armco Steel Corp | Oxygen lance with continuous wide angle conical oxygen jet |
| US3337203A (en) * | 1964-12-24 | 1967-08-22 | Union Carbide Corp | Oxygen lances |
| US3346190A (en) * | 1964-07-23 | 1967-10-10 | Nat Steel Corp | Apparatus and method for supplying gas to a high-temperature process |
| US3350080A (en) * | 1963-06-22 | 1967-10-31 | Manton Douglas Norman | Oxygen lance with helical cooling coil |
-
1973
- 1973-02-07 US US330289A patent/US3892393A/en not_active Expired - Lifetime
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3201104A (en) * | 1962-08-21 | 1965-08-17 | Walter V Berry | Oxygen lance for subsurface use |
| US3350080A (en) * | 1963-06-22 | 1967-10-31 | Manton Douglas Norman | Oxygen lance with helical cooling coil |
| US3346190A (en) * | 1964-07-23 | 1967-10-10 | Nat Steel Corp | Apparatus and method for supplying gas to a high-temperature process |
| US3334885A (en) * | 1964-11-12 | 1967-08-08 | Armco Steel Corp | Oxygen lance with continuous wide angle conical oxygen jet |
| US3322419A (en) * | 1964-12-24 | 1967-05-30 | Union Carbide Corp | Oxygen jet devices |
| US3337203A (en) * | 1964-12-24 | 1967-08-22 | Union Carbide Corp | Oxygen lances |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4022447A (en) * | 1976-02-23 | 1977-05-10 | United States Steel Corporation | Supersonic nozzle for submerged tuyere oxygen steelmaking process |
| JP2008190854A (en) * | 2006-12-15 | 2008-08-21 | Technological Resources Pty Ltd | Apparatus for injecting gas into vessel |
| US20110068522A1 (en) * | 2006-12-15 | 2011-03-24 | Tierney Eric | Apparatus for injecting gas into a vessel |
| US8012409B2 (en) | 2006-12-15 | 2011-09-06 | Technological Resources Pty. Limited | Apparatus for injecting gas into a vessel |
| AU2007254584B2 (en) * | 2006-12-15 | 2011-11-10 | Technological Resources Pty. Limited | Apparatus for injecting gas into a vessel |
| EP1944381A3 (en) * | 2006-12-15 | 2012-01-25 | Technological Resources Pty. Ltd. | Apparatus for injecting gas into a vessel |
| US8454888B2 (en) | 2006-12-15 | 2013-06-04 | Technological Resources Pty. Limited | Apparatus for injecting gas into a vessel |
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