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US3864094A - Fuel composition - Google Patents

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Publication number
US3864094A
US3864094A US351138A US35113873A US3864094A US 3864094 A US3864094 A US 3864094A US 351138 A US351138 A US 351138A US 35113873 A US35113873 A US 35113873A US 3864094 A US3864094 A US 3864094A
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US
United States
Prior art keywords
fuel
coal
lignite
fragments
cryogenically
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US351138A
Inventor
Harry B Locketz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cryogenic Recycling International Inc
Original Assignee
Cryogenic Recycling International Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cryogenic Recycling International Inc filed Critical Cryogenic Recycling International Inc
Priority to US351138A priority Critical patent/US3864094A/en
Application granted granted Critical
Publication of US3864094A publication Critical patent/US3864094A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L5/00Solid fuels
    • C10L5/40Solid fuels essentially based on materials of non-mineral origin
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L5/00Solid fuels
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

Definitions

  • coal both anthracite and bituminous, was the most common fuel for heating and energy conversion systems.
  • Oil and natural gas have replaced coal in many fuel applications.
  • coalburning systems At the present time there still exist many coalburning systems.
  • One problem faced by the operators of these systems is that coal is considered to be a dirty fuel in that it can produce dense smoke, particulate matter and other environmentally undesirable emissions.
  • substitute fuels are being sought which have the same heat value as coal and which are environmentally desirable.
  • Another object of this invention is to provide an environmentally desirable fuel which will meet the current strict air-pollution emission requirements.
  • Yet another object is to provide a fuel which can be used in existing systems without conversion thereof.
  • a fuel product (1 which can be used in existing coal-burning installations without conversion thereof, (2) which, when burned, has low-pollution emission characteristics, and (3) which has a heat value substantially equivalent to that of coal.
  • This fuel consists essentially of lignite and cryogenically reclaimed rubber tire fragments.
  • Lignite is a naturally occurring material, which can be characterized as a brownish-black coal intermediate between peat and bituminous coal.
  • This combination of lignite and cryogenically reclaimed rubber tire fragments produces a fuel product having a heat value substantially equivalent to that of coal and which has low emission characteristics.
  • the fuel is an admixture of a coal-like material, lignite, and cryogenically reclaimed rubber tire fragments.
  • Lignite sometimes referred to as brown coal, is a material which is said to be intermediate peat and bituminous coal and has the texture of the original wood distinct on its surface. It has a heat value lower than that of anthracite or bituminous coal and is believed to have lower pollution emmissions. Moreover, it is believed that there are extensive reserves of lignite.
  • cryogenically reclaimed rubber tire fragments are mixed with the lignite.
  • the fragments being in large part carbon, have a higher heat value than the lignite and therefore may be added in amounts effective to raise the heat value of the mixture to that approximately equivalent to the anthracite or bituminous coal.
  • cryogenically reclaimed rubber tire fragments are produced by a process in which rubber tire scraps, (i.e. complete tires or parts thereof) are exposed to a cryogenic temperature for a time sufficient to lower the temperature of the scrap to a point at which the rubber in the scraps exhibits brittle fracture characteristics which is less than about F.
  • the embrittled scraps are then transferred to a mill in which the scraps are struck with a force sufficient to shatter them into small fragments.
  • the tire scraps are exposed to temperatures approximately equivalent to that of liquid nitrogen (i.e. 320F.) and then transferred to a rotary hammer mill for fragmentation.
  • About 95% of the fragments produced by this process are less than one quarter inch square and are substantially pure rubber from the tread of the tire or from the tire carcass.
  • the tire cords (fabric, metal or glass) from the carcass can be separated from the rubber fragments.
  • the rubber fragments are added to the lignite in amounts sufficient to raise the heat value of the mixture to a level substantially equivalent to the anthracite or bituminous coal.
  • the fuel product consists essentially, in weight percent, of to 92% lignite and 8% to 15% cryogenically reclaimed rubber fragments.
  • a specific fuel product composition which is suitable for use in most coal-burning installations consists, in weight percent, of lignite and 10% rubber fragments.
  • This fuel may be used in large coal-burning installations, such as electricity generating plants, which use enormous quantities of coal and which have been characterized as extreme polluters.
  • An improved combustible fuel product for use in coal-burning heating systems, characterized by a heat value substantially equivalent to coal so as to permit substitution thereof in said heating systems, which burns with low emissions so as to reduce polluting discharges, and consists essentially of lignite and cryogenically reclaimed rubber tire fragments in an amount effective to adjust the heat value of the fuel to substantially the heat value of the substituted for coal, said fragments being obtained by exposing rubber tire scraps to cryogenic temperatures so as to embrittle the rubber therein and striking said embrittled tire so as to shatter said tire into fragments of a size sufficiently small for use as a fuel.
  • a fuel as in claim I which consists essentially, in weight percent, of: between about 85% and 92% lignite and 8% and 15% cryogenically reclaimed rubber tire fragments.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

An improved combustible fuel product for use in coal-burning heating systems, which fuel has a heat value substantially equivalent to that of coal and exhibits low pollution emissions. The fuel consists essentially of lignite (or brown coal) and cryogenically reclaimed rubber tire fragments. In the preferred range, the fuel consists in weight percent of between 85% and 92% lignite and between 8% and 15% cryogenically reclaimed tire fragments.

Description

United States Patent [191 [111 3,864,094
Locketz Feb. 4, 1975 [5 FUEL COMPOSITION 2,009,463 7/1935 Windecker 44/15 R Inventor: Harry B. Locke, La Crosse, Wis 2,811,427 10/1957 Lykken 44/10 R [73] Assignee: Cryogenic Recycling International primary Dees -i Lacrosse, Attorney, Agent, or Firm-Lettvin, Pigott & Gerstman [22] Filed: Apr. 16, 1973 21 Appl. No.: 351,138 [571 ABSTRACT An improved combustible fuel product for use in coal- 521 U.S. Cl 44/1 44/10 D burning mating system, which fuel has a heat value 51 Int. Cl e101 5/00 substantially equivalent that Of and exhibits [58] Field of Search 44/1 R l G 10 R 10 D low pollution emissions. The fuel consists essentially 44/15 R of lignite (or brown coal) and cryogenically reclaimed rubber tire fragments. In the preferred range, the fuel [56] References Cited consists in weight percent of between 85% and 92% lignite and between 8% and 15% cryogenically re- UNITED STATES PATENTS claimed tire fragments. 1,863,517 6/1932 White 44/1 R 9/1933 Brown et al 44/1 R 3 Claims, N0 Drawings 1 FUEL COMPOSITION BACKGROUND OF THE INVENTION This invention relates to improved fuel products for use in coal-burning heating systems.
At one time coal, both anthracite and bituminous, was the most common fuel for heating and energy conversion systems. For reasons of economy and convenience, Oil and natural gas have replaced coal in many fuel applications.
At the present time there still exist many coalburning systems. One problem faced by the operators of these systems is that coal is considered to be a dirty fuel in that it can produce dense smoke, particulate matter and other environmentally undesirable emissions. For these reasons, substitute fuels are being sought which have the same heat value as coal and which are environmentally desirable.
Recently there has been much publicity about the energy crisis where the cost of natural gas and oil has been rising and the reserves thereof have been diminishing. The reserves of coal are quite large and, in view Of the rising gas and oil prices, coal is once again being reviewed as a possible fuel.
It is therefore an object of this invention to provide an inexpensive coal-base fuel which can be used in present coal-burning installations, which fuel has a heat value comparable to that of the coal originally intended for use in the system.
Another object of this invention is to provide an environmentally desirable fuel which will meet the current strict air-pollution emission requirements.
Yet another object is to provide a fuel which can be used in existing systems without conversion thereof.
These and other objects will become apparent from the following description and appended claims.
SUMMARY OF THE INVENTION There is provided by virtue of this invention a fuel product: (1 which can be used in existing coal-burning installations without conversion thereof, (2) which, when burned, has low-pollution emission characteristics, and (3) which has a heat value substantially equivalent to that of coal. This fuel consists essentially of lignite and cryogenically reclaimed rubber tire fragments. Lignite is a naturally occurring material, which can be characterized as a brownish-black coal intermediate between peat and bituminous coal. This combination of lignite and cryogenically reclaimed rubber tire fragments produces a fuel product having a heat value substantially equivalent to that of coal and which has low emission characteristics.
DESCRIPTION OF THE PREFERRED EMBODIMENT The fuel is an admixture of a coal-like material, lignite, and cryogenically reclaimed rubber tire fragments.
Lignite, sometimes referred to as brown coal, is a material which is said to be intermediate peat and bituminous coal and has the texture of the original wood distinct on its surface. It has a heat value lower than that of anthracite or bituminous coal and is believed to have lower pollution emmissions. Moreover, it is believed that there are extensive reserves of lignite.
In order to raise the heat value of the fuel product above that of the lignite itself, cryogenically reclaimed rubber tire fragments are mixed with the lignite. The fragments, being in large part carbon, have a higher heat value than the lignite and therefore may be added in amounts effective to raise the heat value of the mixture to that approximately equivalent to the anthracite or bituminous coal.
cryogenically reclaimed rubber tire fragments are produced by a process in which rubber tire scraps, (i.e. complete tires or parts thereof) are exposed to a cryogenic temperature for a time sufficient to lower the temperature of the scrap to a point at which the rubber in the scraps exhibits brittle fracture characteristics which is less than about F. The embrittled scraps are then transferred to a mill in which the scraps are struck with a force sufficient to shatter them into small fragments. Normally, the tire scraps are exposed to temperatures approximately equivalent to that of liquid nitrogen (i.e. 320F.) and then transferred to a rotary hammer mill for fragmentation. About 95% of the fragments produced by this process are less than one quarter inch square and are substantially pure rubber from the tread of the tire or from the tire carcass. The tire cords (fabric, metal or glass) from the carcass can be separated from the rubber fragments.
As indicated above, the rubber fragments are added to the lignite in amounts sufficient to raise the heat value of the mixture to a level substantially equivalent to the anthracite or bituminous coal. In the preferred embodiments, the fuel product consists essentially, in weight percent, of to 92% lignite and 8% to 15% cryogenically reclaimed rubber fragments. A specific fuel product composition which is suitable for use in most coal-burning installations consists, in weight percent, of lignite and 10% rubber fragments.
This fuel may be used in large coal-burning installations, such as electricity generating plants, which use enormous quantities of coal and which have been characterized as extreme polluters.
It will be appreciated that numerous changes and modifications can be made to the embodiment described herein without departing from the spirit and scope of this invention.
What is claimed and desired to be secured by Letters Patent of the United States is:
1. An improved combustible fuel product, for use in coal-burning heating systems, characterized by a heat value substantially equivalent to coal so as to permit substitution thereof in said heating systems, which burns with low emissions so as to reduce polluting discharges, and consists essentially of lignite and cryogenically reclaimed rubber tire fragments in an amount effective to adjust the heat value of the fuel to substantially the heat value of the substituted for coal, said fragments being obtained by exposing rubber tire scraps to cryogenic temperatures so as to embrittle the rubber therein and striking said embrittled tire so as to shatter said tire into fragments of a size sufficiently small for use as a fuel.
2. A fuel as in claim I which consists essentially, in weight percent, of: between about 85% and 92% lignite and 8% and 15% cryogenically reclaimed rubber tire fragments.
3. A fuel as in claim I wherein said cryogenically reclaimed fragments is present in an amount approximately equal to 10%.

Claims (2)

  1. 2. A fuel as in claim 1 which consists essentially, in weight percent, of: between about 85% and 92% lignite and 8% and 15% cryogenically reclaimed rubber tire fragments.
  2. 3. A fuel as in claim 1 wherein said cryogenically reclaimed fragments is present in an amount approximately equal to 10%.
US351138A 1973-04-16 1973-04-16 Fuel composition Expired - Lifetime US3864094A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4402275A (en) * 1980-09-04 1983-09-06 Arbed S.A. Process for the continuous blowing of fine-particled reducing agents consisting predominantly of mineral coal into a shaft furnace
US5220107A (en) * 1987-10-19 1993-06-15 United Technologies Corporation Process for the preparation of solid rocket propellant and other solid explosives for thermal disposal or reclamation
US5487762A (en) * 1995-02-01 1996-01-30 Calgon Corporation Method of minimizing deposits when firing tire derived fuels
US5552093A (en) * 1989-06-05 1996-09-03 Lee; David E. Process for the removal of a solid rocket propellant from a rocket motor case

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1863517A (en) * 1931-06-22 1932-06-14 White William Dawson Smudge brick
US1926578A (en) * 1932-02-23 1933-09-12 William Crowell Artificial fuel and method of producing same
US2009463A (en) * 1932-07-27 1935-07-30 Windecker Robert Erwin Manufacture of fuel briquettes
US2811427A (en) * 1952-09-08 1957-10-29 Henry G Lykken Lignite fuel

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1863517A (en) * 1931-06-22 1932-06-14 White William Dawson Smudge brick
US1926578A (en) * 1932-02-23 1933-09-12 William Crowell Artificial fuel and method of producing same
US2009463A (en) * 1932-07-27 1935-07-30 Windecker Robert Erwin Manufacture of fuel briquettes
US2811427A (en) * 1952-09-08 1957-10-29 Henry G Lykken Lignite fuel

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4402275A (en) * 1980-09-04 1983-09-06 Arbed S.A. Process for the continuous blowing of fine-particled reducing agents consisting predominantly of mineral coal into a shaft furnace
US5220107A (en) * 1987-10-19 1993-06-15 United Technologies Corporation Process for the preparation of solid rocket propellant and other solid explosives for thermal disposal or reclamation
US5552093A (en) * 1989-06-05 1996-09-03 Lee; David E. Process for the removal of a solid rocket propellant from a rocket motor case
US5487762A (en) * 1995-02-01 1996-01-30 Calgon Corporation Method of minimizing deposits when firing tire derived fuels

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