US3779791A - Method of heating paper - Google Patents
Method of heating paper Download PDFInfo
- Publication number
- US3779791A US3779791A US00174987A US3779791DA US3779791A US 3779791 A US3779791 A US 3779791A US 00174987 A US00174987 A US 00174987A US 3779791D A US3779791D A US 3779791DA US 3779791 A US3779791 A US 3779791A
- Authority
- US
- United States
- Prior art keywords
- paper
- percent
- weight
- paperboard
- impregnated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims description 7
- 238000010438 heat treatment Methods 0.000 title abstract description 5
- 229920001515 polyalkylene glycol Polymers 0.000 claims description 12
- 239000000123 paper Substances 0.000 abstract description 21
- 239000011087 paperboard Substances 0.000 abstract description 10
- 229920001223 polyethylene glycol Polymers 0.000 abstract description 10
- 239000002202 Polyethylene glycol Substances 0.000 abstract description 6
- 230000001954 sterilising effect Effects 0.000 abstract description 5
- 239000000835 fiber Substances 0.000 abstract description 4
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 4
- 229920001451 polypropylene glycol Polymers 0.000 abstract description 3
- 239000000463 material Substances 0.000 description 10
- 239000000203 mixture Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920001281 polyalkylene Polymers 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- PPTYJKAXVCCBDU-UHFFFAOYSA-N Rohypnol Chemical compound N=1CC(=O)N(C)C2=CC=C([N+]([O-])=O)C=C2C=1C1=CC=CC=C1F PPTYJKAXVCCBDU-UHFFFAOYSA-N 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 239000008135 aqueous vehicle Substances 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 235000008429 bread Nutrition 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 229940117927 ethylene oxide Drugs 0.000 description 1
- 238000012376 hot air sterilization Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000036512 infertility Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- -1 polyethylenes Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/53—Polyethers; Polyesters
Definitions
- a sheet consisting predominantly or entirely of cellulose, like paper or paperboard may be heated safely to high temperatures of, for instance, 200C, if it is, in accordance with the present invention, made to contain 2 to 25 percent by weight of polyalkylene glycols, based on the weight of the untreated paper or paperboard.
- Polyalkylene glycols in the sense of the invention, are understood to be compounds produced by polyaddition of alkylene oxides, in the simplest case ethyleneoxide. This produces a linear polyether carrying terminal hydroxyl groups and having the formula HOC H ACH OC,,H CH O1-i, wherein a is 1 or 2, and b is an integer selected to make the molecular weight of the polyalkylene glycol 1000 to 6000.
- polyalkylene glycols In selecting the most suitable polyalkylene glycols, different factors are taken into consideration. These polyalkylene glycols should evaporate as little as possible at the high temperatures to which they are exposed. On the other hand, they must permit easy processing, i.e., they must be capable ofimpregnating the paper adequately using an aqueous vehicle. This presupposes that they have sufficient solubility in water. All these requirements have been shown to be best satisfied by the polyethylene glycols, but that the polypropylene glycols are also suitable.
- the temperature resistance of the polyalkylene glycols which is particularly important in view of the principal application, is related to their molecular weights.
- the production of paper or paperboard according to the invention contemplates using polyalkylene glycols having a molecular weight of from about 1000 to 6000, b in the above formula being about 21 to particularly suitable are polyethylene glycols with molecular weights between 2000 and 4000. Mixtures of polyethylene glycols of different molecular weights, such as, for instance, the commercially available Polyglykol 2000 and 4000 are preferably used.
- the accompanying table lists the properties of papers with different contents of polyethylene glycol and their properties of mechanical strength such as fracture load and breaking load, before heating and after having them heated to a temperature of 180C for 40 minutes and a temperature of 200C.for one hour. An untreated and unheated control was also tested.
- Nonsterile bandages were wrapped in the heatresistant paper so produced in such a way as to enclose them with one layer of paper.
- This sterilization package was sterilized by hot air in a circulating-air drying cabinet for 40 minutes at 180C. Then, the package was stored under non-sterile conditions for 14 days, and a sterility test was made. This test indicated that the bandage material remained completely sterile.
- a method of sterilizing a sheet-like body of paper or paperboard essentially consisting of cellulosic fibers without essential loss of strength and flexibility which comprises heating said body to a temperature of at least l80C for a period of 40 minutes while said body is impregnated with 2 to 25 percent of polyethylenes glycol based on the weight of the untreated body, said polyvsaid polyalkylene glycol.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paper (AREA)
- Bakery Products And Manufacturing Methods Therefor (AREA)
Abstract
Paper and paperboard essentially consisting of cellulosic fibers may be heated to temperatures greatly in excess of 100*C, as during dry sterilization, without becoming brittle or disintegrating, when impregnated with 2 percent to 25 percent of polyethyleneglycol of molecular weight 1,000 to 6,000 or polypropylene glycol. The impregnated paper is sterilized by heating to temperature of at least 180*C for a period of 40 minutes.
Description
United States Patent [191 Ploetz et a1.
[ 1 Dec. 18, 1973 METHOD OF HEATING PAPER [75] Inventors: Theodor Ploetz, Hoesel; Edeltraud Solich, Viersen, both of Germany [73] Assignee: Feldmuhle Anlagen-und Produktionsgesellschaft mit beschrankter Haftung, Duesselforf-Oberkassel, Germany 221 Filed: Aug. 25, 1971 211 Appl. No.: 174,987
Related US. Application Data [63] Continuation-impart of Ser. No. 837,879, June 30,
1969, abandoned.
[30] Foreign Application Priority Data July 5, 1968 Germany P 17 61 775.3
[52] US. Cl 21/58, 21/2, 21/D1G. 4, 1 17/62,117/119.6 1 1 7/154 [51] Int. Cl A611 13/00 [58] Field 01 Search 117/62, 119.6, 154; 162/158, 159, 164, 168, 169; 21/DIG. 4, 2, 58
[56] References Cited UNITED STATES PATENTS R24,01I 5/1955 Ericks 117/154 X 2,629,674 2/1953 Ericks 117/140 2,629,701 2/1953 Ericks 117/154 X 3,499,823 3/1970 Croon et a1... 162/158 3,661,633 5/1972 Moren 117/119.6 X 3,676,055 7/1972 Smith l17/119.6 X
FOREIGN PATENTS OR APPLICATIONS 657,196 2/1963 Canada 1-62/158 Primary Examiner-William D. Martin Assistant Examiner--M. R. Lusignan Attorneyl(ilman & Berman [5 7] ABSTRACT 4 Claims, N0 Drawings clusively of cellulosic fibers such as groundwood pulp and is used not only as a substrate for printed and written matter, but also is used widely as packaging material. Cellulosic fibers and wood pulp become discolored when heated to temperatures greatly in excess of 100C., become brittle, and suffer a great decrease of mechanical strength so as to be no longer useful as wrapping material, and, ultimately, completely disintegrate.
Since papers and paperboards, however, are materials capable of inexpensive mass production, there is an urgent demand for a paper or paperboard material that can resist temperatures of 200C and more without essential loss of strength and flexibility. Such heat resistance is particularly required of so-called sterilization papers. In order to kill all germs and bacteria with certainty, the art has recently moved increasingly from conventional steam sterilization to hot-air sterilization; this means that the material in which surgical instruments, and the like are wrapped must withstand a temperature of about 180C for at least 40 minutes. Yet, currently available papers exposed to such extreme conditions lose their flexibility and strength. There is a need for heat-resistant paper or paperboard in other technical applications too; for instance, for baking purposes. The tendency is to increase efficiency, to bake the material such as bread and cake directly in the wrapper in which the product is to be sold.
Surprisingly, it has been found that a sheet consisting predominantly or entirely of cellulose, like paper or paperboard, may be heated safely to high temperatures of, for instance, 200C, if it is, in accordance with the present invention, made to contain 2 to 25 percent by weight of polyalkylene glycols, based on the weight of the untreated paper or paperboard.
Polyalkylene glycols, in the sense of the invention, are understood to be compounds produced by polyaddition of alkylene oxides, in the simplest case ethyleneoxide. This produces a linear polyether carrying terminal hydroxyl groups and having the formula HOC H ACH OC,,H CH O1-i, wherein a is 1 or 2, and b is an integer selected to make the molecular weight of the polyalkylene glycol 1000 to 6000.
In selecting the most suitable polyalkylene glycols, different factors are taken into consideration. These polyalkylene glycols should evaporate as little as possible at the high temperatures to which they are exposed. On the other hand, they must permit easy processing, i.e., they must be capable ofimpregnating the paper adequately using an aqueous vehicle. This presupposes that they have sufficient solubility in water. All these requirements have been shown to be best satisfied by the polyethylene glycols, but that the polypropylene glycols are also suitable.
The temperature resistance of the polyalkylene glycols, which is particularly important in view of the principal application, is related to their molecular weights. The production of paper or paperboard according to the invention contemplates using polyalkylene glycols having a molecular weight of from about 1000 to 6000, b in the above formula being about 21 to particularly suitable are polyethylene glycols with molecular weights between 2000 and 4000. Mixtures of polyethylene glycols of different molecular weights, such as, for instance, the commercially available Polyglykol 2000 and 4000 are preferably used.
Even though, in some cases, such small additions of polyalkylene glycol as, for instance, 2 percent by weight, are sufficient to give the paper the required high temperature resistance, the addition of 7 to 15 percent by weight of polyalkylene glycol is preferred. When using an amount of only 2 percent by weight, the tear strength remains good after heating to a temperature of 180C for 40 minutes, but some paper has a certain brittleness which makes it less suitable as wrapping material. In the preferred range of 7 to l5percent by weight, a sufficiently high pliability of the material is assured. With very high percentages of polyalkylene glycol, some of it may be melted out.
The accompanying table lists the properties of papers with different contents of polyethylene glycol and their properties of mechanical strength such as fracture load and breaking load, before heating and after having them heated to a temperature of 180C for 40 minutes and a temperature of 200C.for one hour. An untreated and unheated control was also tested.
The method of the invention is described in the following example.
EXAMPLE A wood-free untreated paper having a weight of 40 g/m was, after calendering, passed through an impregnating tank containing a liquid of the following composition:
g polyethylene glycol of molecular weight 2000,
150 g polyethylene glycol of molecular weight 4000 dissolved in 700 g of water. The material, completely impregnated with this solution, was freed of excess solution by being guided between two rolls and subsequently dried in the air. 11 percent by weight of the mixture of polyethylene glycol remaind in the paper.
Nonsterile bandages were wrapped in the heatresistant paper so produced in such a way as to enclose them with one layer of paper. This sterilization package was sterilized by hot air in a circulating-air drying cabinet for 40 minutes at 180C. Then, the package was stored under non-sterile conditions for 14 days, and a sterility test was made. This test indicated that the bandage material remained completely sterile.
While the impregnating composition described above produced the desired pick-up of polyalkylene by the paper base employed with the equipment available, those skilled in the art will readily adjust the amount and nature of the diluent if any, to suit specific materials and processing conditions. Similarly the degree of polymerization of the polyalkylene may be chosen according to processing convenience. While all tested types of paper and paperboard could be impregnated satisfactorily with mixtures of polyethylene glycols having respectivemolecular weights of about2000 and 92 224990.? s frastit i n m st igs cific requirements, produces thesame results. Polypropylene glycol of similar molecular weight may replace some or all of the polyethylene glycol.
TABLE I Fracture load Breaking load Polyglycol content Basis Porosity of the paper, weight (Bendtsen) Cross Machine I Cross Machine percent by weight Treatment g /m 2 ml./min. direction direction direction direction 40 340 3. 26 2. 64 5, 430 4, 400 2.5 40 min/180 C 40 380 2.76 2.2 4,600 3,670 1 hr./200 C 40 2.75 2.07 4,580 3, 450 41 320 3.17 2. 41 5,150 3, 920 TL 7 a a. 40 "rim/180 C 40.5 370 2.7 2.18 4,450 3, 590 l inn/200 C r 40. 2. 69 2. 04 4, 420 3, 360 t 43 200 3. 22 2. 40 4, 990 3, 720 I0 40 min/180 (J. 42 310 2.39 1.81 3,790 2,870 l 1112/200 (L 42 2.12 1.78 3,360 2,820 47 180 3. 02 2. 48 4, 280 3, 520 20 40 mlIl./180 44 320 1.56 1.26 2,360 1,910 1 hr./200 C 44 1. 43 1.26 2,170 1,910 53 Very slimy; strong development of vapors 3G 40 min./l 44 irritating the mucous membranes, when 1 hr./200 C. 44 e e 0 (untrcated) 39 300 3. 92 2. 95 6,700 5,040
NOTE.--P0rosity according to Bendtsen at 10 cm.'-/l50 mm. water column. Tension test (fracture load, breaking load): DIN 53112 (test strip l5 100 mm.).
While the invention has been described with particular reference toa specific embodiment, it is to be understood that it is not limited thereto, but is to be construed broadly and restricted solely by the scope of the appended claims.
What is claimed is:
l. A method of sterilizing a sheet-like body of paper or paperboard essentially consisting of cellulosic fibers without essential loss of strength and flexibility which comprises heating said body to a temperature of at least l80C for a period of 40 minutes while said body is impregnated with 2 to 25 percent of polyethylenes glycol based on the weight of the untreated body, said polyvsaid polyalkylene glycol.
4. A method as set forth in claim 2, wherein said temperature is approximately 200C.
Claims (3)
- 2. A method as set forth in claim 1, wherein said molecular weight is between 2000 and 4000.
- 3. A method as set forth in claim 1, wherein said sheet-like body is impregnated with 7 to 15 percent of said polyalkylene glycol.
- 4. A method as set forth in claim 2, wherein said temperature is approximately 200*C.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19681761775 DE1761775A1 (en) | 1968-07-05 | 1968-07-05 | Flat structures resistant to high temperatures |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3779791A true US3779791A (en) | 1973-12-18 |
Family
ID=5696704
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US00174987A Expired - Lifetime US3779791A (en) | 1968-07-05 | 1971-08-25 | Method of heating paper |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3779791A (en) |
| BE (1) | BE735646A (en) |
| DE (1) | DE1761775A1 (en) |
| FR (1) | FR2012346A1 (en) |
| GB (1) | GB1284604A (en) |
| NL (1) | NL6909693A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3903335A (en) * | 1973-04-27 | 1975-09-02 | Mardon Flexible Packaging Ltd | Heat sealed package |
| EP0261832A1 (en) * | 1986-09-08 | 1988-03-30 | Mitsui Petrochemical Industries, Ltd. | Synthetic pulp and absorbent comprising the same |
| US5563394A (en) * | 1990-01-12 | 1996-10-08 | Hitachi, Ltd. | Cash transaction machine and method |
| US5578281A (en) * | 1993-08-27 | 1996-11-26 | Hitachi, Ltd. | Cash transaction machine |
| US5626821A (en) * | 1990-01-12 | 1997-05-06 | Hitachi, Ltd. | Cash transaction machine |
| US5626822A (en) * | 1990-01-12 | 1997-05-06 | Hitachi, Ltd. | Cash transaction machine and method therefor |
| WO2001018310A1 (en) * | 1999-09-08 | 2001-03-15 | Clariant Finance (Bvi) Limited | Surface finishing of paper or board, and agent for this purpose |
| US20030155089A1 (en) * | 2001-12-31 | 2003-08-21 | Kimberly-Clark Worldwide, Inc. | Process for manufacturing a cellulosic paper product exhibiting reduced malodor |
| US20050006043A1 (en) * | 2003-07-09 | 2005-01-13 | The Procter & Gamble Company | Fibrous structure comprising a fiber flexibilizing agent system |
| US20090188637A1 (en) * | 2008-01-28 | 2009-07-30 | Eric Chan | Soft tissue paper having a polyhydroxy compound and lotion applied onto a surface thereof |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3900327A (en) * | 1973-10-12 | 1975-08-19 | Hooker Chemicals Plastics Corp | Flame retardant cellulosic materials |
| EP0018961B1 (en) * | 1979-05-04 | 1983-07-20 | Rockwool Aktiebolaget | Carrier material |
| DE3631835A1 (en) * | 1986-09-19 | 1988-03-24 | Kaemmerer Gmbh | METHOD FOR PRODUCING YELLOW-RESISTANT PAPER, IN PARTICULAR AGAINST HEAT |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US24011A (en) * | 1859-05-17 | Improvement in soap | ||
| US2629674A (en) * | 1949-07-07 | 1953-02-24 | Upson Co | Method for treating cellulose and product thereof |
| US2629701A (en) * | 1949-05-27 | 1953-02-24 | Upson Co | Compositions containing esters of a glycol and polycarboxylic acids and the treatment of cellulose therewith |
| CA657196A (en) * | 1963-02-05 | General Mills | Reagent for formation improvement of paper | |
| US3499823A (en) * | 1965-08-24 | 1970-03-10 | Mo Och Domsjoe Ab | Method of inhibiting the formation of fiber-knots in paper pulp and product |
| US3661633A (en) * | 1963-12-11 | 1972-05-09 | Rolf Erhard Moren | Process and composition for impregnating wood and wood products |
| US3676055A (en) * | 1970-08-31 | 1972-07-11 | Richard Daniel Smith | Preserving cellulosic materials through treatment with alkylene oxides |
-
1968
- 1968-07-05 DE DE19681761775 patent/DE1761775A1/en active Pending
-
1969
- 1969-06-24 NL NL6909693A patent/NL6909693A/xx unknown
- 1969-07-01 FR FR6922217A patent/FR2012346A1/fr not_active Withdrawn
- 1969-07-04 BE BE735646D patent/BE735646A/xx unknown
- 1969-07-07 GB GB34208/69A patent/GB1284604A/en not_active Expired
-
1971
- 1971-08-25 US US00174987A patent/US3779791A/en not_active Expired - Lifetime
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US24011A (en) * | 1859-05-17 | Improvement in soap | ||
| CA657196A (en) * | 1963-02-05 | General Mills | Reagent for formation improvement of paper | |
| US2629701A (en) * | 1949-05-27 | 1953-02-24 | Upson Co | Compositions containing esters of a glycol and polycarboxylic acids and the treatment of cellulose therewith |
| US2629674A (en) * | 1949-07-07 | 1953-02-24 | Upson Co | Method for treating cellulose and product thereof |
| US3661633A (en) * | 1963-12-11 | 1972-05-09 | Rolf Erhard Moren | Process and composition for impregnating wood and wood products |
| US3499823A (en) * | 1965-08-24 | 1970-03-10 | Mo Och Domsjoe Ab | Method of inhibiting the formation of fiber-knots in paper pulp and product |
| US3676055A (en) * | 1970-08-31 | 1972-07-11 | Richard Daniel Smith | Preserving cellulosic materials through treatment with alkylene oxides |
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3903335A (en) * | 1973-04-27 | 1975-09-02 | Mardon Flexible Packaging Ltd | Heat sealed package |
| EP0261832A1 (en) * | 1986-09-08 | 1988-03-30 | Mitsui Petrochemical Industries, Ltd. | Synthetic pulp and absorbent comprising the same |
| AU606352B2 (en) * | 1986-09-08 | 1991-02-07 | Mitsui Chemicals, Inc. | Synthetic pulp and absorbent comprising the same |
| US5563394A (en) * | 1990-01-12 | 1996-10-08 | Hitachi, Ltd. | Cash transaction machine and method |
| US5626821A (en) * | 1990-01-12 | 1997-05-06 | Hitachi, Ltd. | Cash transaction machine |
| US5626822A (en) * | 1990-01-12 | 1997-05-06 | Hitachi, Ltd. | Cash transaction machine and method therefor |
| US5578281A (en) * | 1993-08-27 | 1996-11-26 | Hitachi, Ltd. | Cash transaction machine |
| US20050167064A1 (en) * | 1999-09-08 | 2005-08-04 | Clariant Finance (Bvi) Limited | Surface finishing of paper or board, and agent for this purpose |
| US20040149408A1 (en) * | 1999-09-08 | 2004-08-05 | Clariant Finance (Bvi) Limited | Surface finshing of paper or board, and agent for this purpose |
| US6872282B1 (en) | 1999-09-08 | 2005-03-29 | Clariant Finance (Bvi) Limited | Surface finishing of paper or board |
| WO2001018310A1 (en) * | 1999-09-08 | 2001-03-15 | Clariant Finance (Bvi) Limited | Surface finishing of paper or board, and agent for this purpose |
| RU2261300C2 (en) * | 1999-09-08 | 2005-09-27 | Клариант Файненс (Бви) Лимитед | Method for surface finishing of paper or cardboard and agent for effectuating the same |
| US20030155089A1 (en) * | 2001-12-31 | 2003-08-21 | Kimberly-Clark Worldwide, Inc. | Process for manufacturing a cellulosic paper product exhibiting reduced malodor |
| US7297228B2 (en) * | 2001-12-31 | 2007-11-20 | Kimberly-Clark Worldwide, Inc. | Process for manufacturing a cellulosic paper product exhibiting reduced malodor |
| US20050006043A1 (en) * | 2003-07-09 | 2005-01-13 | The Procter & Gamble Company | Fibrous structure comprising a fiber flexibilizing agent system |
| US7377997B2 (en) * | 2003-07-09 | 2008-05-27 | The Procter & Gamble Company | Fibrous structure comprising a fiber flexibilizing agent system |
| US20090188637A1 (en) * | 2008-01-28 | 2009-07-30 | Eric Chan | Soft tissue paper having a polyhydroxy compound and lotion applied onto a surface thereof |
| US7972475B2 (en) * | 2008-01-28 | 2011-07-05 | The Procter & Gamble Company | Soft tissue paper having a polyhydroxy compound and lotion applied onto a surface thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| GB1284604A (en) | 1972-08-09 |
| BE735646A (en) | 1969-12-16 |
| NL6909693A (en) | 1970-01-07 |
| DE1761775A1 (en) | 1971-10-14 |
| FR2012346A1 (en) | 1970-03-20 |
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