US3667231A - Hydrazine decomposition process using metal promoters - Google Patents
Hydrazine decomposition process using metal promoters Download PDFInfo
- Publication number
- US3667231A US3667231A US651323A US3667231DA US3667231A US 3667231 A US3667231 A US 3667231A US 651323 A US651323 A US 651323A US 3667231D A US3667231D A US 3667231DA US 3667231 A US3667231 A US 3667231A
- Authority
- US
- United States
- Prior art keywords
- monopropellant
- mixture
- oxidizing agent
- hydrazine
- percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 20
- 239000002184 metal Substances 0.000 title claims abstract description 20
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 title claims description 18
- 238000000034 method Methods 0.000 title claims description 12
- 238000000354 decomposition reaction Methods 0.000 title description 10
- 239000007800 oxidant agent Substances 0.000 claims abstract description 16
- 239000000843 powder Substances 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims description 18
- 150000003839 salts Chemical class 0.000 claims description 8
- 150000001450 anions Chemical class 0.000 claims description 4
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 claims description 4
- ICIWUVCWSCSTAQ-UHFFFAOYSA-M iodate Chemical compound [O-]I(=O)=O ICIWUVCWSCSTAQ-UHFFFAOYSA-M 0.000 claims description 4
- HDZGCSFEDULWCS-UHFFFAOYSA-N monomethylhydrazine Chemical compound CNN HDZGCSFEDULWCS-UHFFFAOYSA-N 0.000 claims description 4
- 239000003999 initiator Substances 0.000 abstract description 5
- 230000002195 synergetic effect Effects 0.000 abstract description 4
- 239000007787 solid Substances 0.000 abstract description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000003380 propellant Substances 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000012286 potassium permanganate Substances 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000011358 absorbing material Substances 0.000 description 1
- 238000003421 catalytic decomposition reaction Methods 0.000 description 1
- 239000011872 intimate mixture Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B33/00—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06C—DETONATING OR PRIMING DEVICES; FUSES; CHEMICAL LIGHTERS; PYROPHORIC COMPOSITIONS
- C06C9/00—Chemical contact igniters; Chemical lighters
Definitions
- HYDRAZINE DECOMPOSITION PROCESS USING METAL PROMOTERS Inventors: Theodore N. Hubbuch, Florence; James A. Murfree, Jr.; William A. Duncan, both of Huntsville; Billy J. Sandlin, Athens; Henry A. Nappier, Laceys Spring, all of Ala.
- the principal object of this invention is to provide a gas generation scheme that utilizes metal powders as synergistic promoters.
- Another object of this invention is to improve the buming rates and lower the ignition delay in propellant decompositions using a liquid monopropellant.
- a dry mixture of aluminum powder and potassium permanganate and similar mixtures of metals and oxidizing agents are used as initiators in gas generators utilizing hydrazine and similar fuels which undergo exothermal decomposition to release gas.
- the monopropellant must be of an exothcrmally decomposing type so that when decomposed, it liberates heat which raises the temperature of the absorbing material or bed such that the exotherrnal decomposition of the monopropellant is maintained thermally even after the oxidizing agent has been consumed.
- the mixture is incorporated in a suitable carrier bed made of an inert porous support material such as porous firebrick.
- a suitable carrier bed made of an inert porous support material such as porous firebrick.
- the finely divided metal powder may be manganese, aluminum, zinc or iron, and mixtures thereof.
- Thermit (trademark for an equal mixture by weight of ferric oxide and powdered metallic aluminum) and other iron oxide and aluminum mixtures are especially desirable.
- the oxidizing agent is a finely divided inorganic oxidizing salt.
- the anion portion of said salt is permanganate, iodate, dichromate or hyperchlorite. Of course, mixtures thereof may be employed.
- the proportion of the finely divided metal powder in the intimate mixture of the metal and oxidizing agent should be from about 10 percent to about 30 percent by weight. Preferably, for best results, it should be about 20 percent.
- the exotherrnally decomposing monopropellant in the propellant composition is preferably hydrazine or a hydrazinetype (e.g. monomethylhydrazine or l,l-dimethylhydrazine) fuel. Mixtures thereof may also be desirable.
- the monopropellant must be exotherrnally decomposing to sustain the reaction after the metal powder and oxidizing agent are expended. Note, however, that although almost any type of exothermally decomposing monopropellant may be used, not every oxidizing agent mentioned above will work with every exothermally decomposing monopropellant. In particular, tassium permanganate will not work with l, l-dirnethyl ydrazine. Accordingly, the tenn suitable oxidizing agent is defined herein to mean a workable oxidizing agent for the particular monopropellant chosen.
- the process of gas generation comprising: providing an inert porous support material; supporting a mixture of inorganic oxidizing agent and finely divided metal powder in said inert porous support material, said oxidizing agent being a finely divided salt, said salt having as its anion portion permanganate, iodate, dichromate or hyperchlorite, said metal powder being manganese, magnesium, aluminum, zinc or iron; and, bringing an exothermally decomposing monopropellant selected from hydrazine, monomethylhydrazine or l,ldimethyhydrazine into contact with said inert porous support material and said mixture to cause said monopropellant and said mixture to react with the liberation of heat and gas and thereby heat said inert porous support material to a temperature sufficient to maintain decomposition of said monopropellant afier said suitable oxidizing agent and said metal powder are expended.
- monopropellant selected from hydrazine, monomethylhydrazine or l,ldimethy
- said suitable oxidizing agent is a finely divided salt, said salt having as its anion portion iodate, dichromate or hyperchlorite.
- metal powder comprises from about 10 percent to about 30 percent by weight of said mixture.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
Abstract
The use of metal powders as synergistic promoters for solid oxidizing agents (initiators) for gas generators.
Description
United States Patent Hubbuch et al.
[451 June 6,1972
HYDRAZINE DECOMPOSITION PROCESS USING METAL PROMOTERS Inventors: Theodore N. Hubbuch, Florence; James A. Murfree, Jr.; William A. Duncan, both of Huntsville; Billy J. Sandlin, Athens; Henry A. Nappier, Laceys Spring, all of Ala.
Assignee: The United States of America as represented by the Secretary of the Army Filed: July 5, 1967 Appl. No.: 651,323
U.S. Cl..'. ..60/2l8, 60/219, 60/220,
149/36 Int. Cl. ..C06d 5/04, C06d 5/10 Field of Search ..60/218, 219, 220; 149/36 6/1966 Kaufman .....60/220 7/1967 Kaufman ..60/220 Primary Examiner-Benjamin R. Padgett Attorney-Harry M. Saragovitz, Edward J. Kelly, Herbert Berl and Elihu L. Turetsky ABSTRACT The use of metal powders as synergistic promoters for solid oxidizing agents (initiators) for gas generators.
5 Claims, No Drawings HYDRAZINE DECOMPOSITION PROCESS USING METAL PROMOTERS BACKGROUND OF THE INVENTION There is considerable interest in the rocket propulsion industry in the development and use of liquid monopropellant gas generators.- Although the majority of work in this field has been in catalytic decomposition schemes, recent attention has been focused on schemes of gas generation utilizing a liquid mono-propellant with an initiator and an inert porous bed or support as more particularly disclosed in copending application Ser. No. 651,654, filed July 5, 1967. In these schemes, the monopropellant reacts with the initiator to start decomposition, generate heat, and heat the support which, when heated, thermally sustains the decomposition. Applicants have learned that this gas generation scheme can be improved by using metal powders as synergistic promoters.
Accordingly, the principal object of this invention is to provide a gas generation scheme that utilizes metal powders as synergistic promoters.
Another object of this invention is to improve the buming rates and lower the ignition delay in propellant decompositions using a liquid monopropellant.
SUMMARY OF THE INVENTION In accordance with this invention, it has been discovered that bringing hydrazine into contact with a dry mixture of aluminum powder and potassium permanganate results in a rapid and vigorous chemical reaction releasing heat and light.
DESCRIPTION OF THE PREFERRED EMBODIMENTS A dry mixture of aluminum powder and potassium permanganate and similar mixtures of metals and oxidizing agents are used as initiators in gas generators utilizing hydrazine and similar fuels which undergo exothermal decomposition to release gas. Although almost any type of exothermally decomposing fuel may be used, the monopropellant must be of an exothcrmally decomposing type so that when decomposed, it liberates heat which raises the temperature of the absorbing material or bed such that the exotherrnal decomposition of the monopropellant is maintained thermally even after the oxidizing agent has been consumed.
The mixture is incorporated in a suitable carrier bed made of an inert porous support material such as porous firebrick. Thus, when the monopropellant enters the carrier bed, the rapid vigorous reaction between the monopropellant and the mixture (incorporated in the bed) heats the bed to a temperature sufficient to maintain the exotherrnal decomposition of the monopropellant after the metal powder and oxidizing agent are expended.
The finely divided metal powder may be manganese, aluminum, zinc or iron, and mixtures thereof. Thermit (trademark for an equal mixture by weight of ferric oxide and powdered metallic aluminum) and other iron oxide and aluminum mixtures are especially desirable.
The oxidizing agent is a finely divided inorganic oxidizing salt. Preferably, the anion portion of said salt is permanganate, iodate, dichromate or hyperchlorite. Of course, mixtures thereof may be employed.
The proportion of the finely divided metal powder in the intimate mixture of the metal and oxidizing agent should be from about 10 percent to about 30 percent by weight. Preferably, for best results, it should be about 20 percent.
The exotherrnally decomposing monopropellant in the propellant composition is preferably hydrazine or a hydrazinetype (e.g. monomethylhydrazine or l,l-dimethylhydrazine) fuel. Mixtures thereof may also be desirable. The monopropellant must be exotherrnally decomposing to sustain the reaction after the metal powder and oxidizing agent are expended. Note, however, that although almost any type of exothermally decomposing monopropellant may be used, not every oxidizing agent mentioned above will work with every exothermally decomposing monopropellant. In particular, tassium permanganate will not work with l, l-dirnethyl ydrazine. Accordingly, the tenn suitable oxidizing agent is defined herein to mean a workable oxidizing agent for the particular monopropellant chosen.
Various other modifications and variations of this invention may be employed by those skilled in the art in the light of the above teachings, which modifications and variations are still within the spirit and scope of this invenu'on.
We claim:
1. The process of gas generation comprising: providing an inert porous support material; supporting a mixture of inorganic oxidizing agent and finely divided metal powder in said inert porous support material, said oxidizing agent being a finely divided salt, said salt having as its anion portion permanganate, iodate, dichromate or hyperchlorite, said metal powder being manganese, magnesium, aluminum, zinc or iron; and, bringing an exothermally decomposing monopropellant selected from hydrazine, monomethylhydrazine or l,ldimethyhydrazine into contact with said inert porous support material and said mixture to cause said monopropellant and said mixture to react with the liberation of heat and gas and thereby heat said inert porous support material to a temperature sufficient to maintain decomposition of said monopropellant afier said suitable oxidizing agent and said metal powder are expended.
2. The process of claim 1 wherein said monopropellant is hydrazine or monomethylhydrazine.
3. The process of claim 1 wherein said suitable oxidizing agent is a finely divided salt, said salt having as its anion portion iodate, dichromate or hyperchlorite.
4. The process of claim 3 wherein said metal powder comprises from about 10 percent to about 30 percent by weight of said mixture.
5. The process of claim 4 wherein said metal powder comprises about 20 percent by weight of said mixture.
Claims (4)
- 2. The process of claim 1 wherein said monopropellant is hydrazine or monomethylhydrazine.
- 3. The process of claim 1 wherein said suitable oxidizing agent is a finely divided salt, said salt having as its anion portion iodate, dichromate or hyperchlorite.
- 4. The process of claim 3 wherein said metal powder comprises from about 10 percent to about 30 percent by weight of said mixture.
- 5. The process of claim 4 wherein said metal powder comprises about 20 percent by weight of said mixture.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US65132367A | 1967-07-05 | 1967-07-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3667231A true US3667231A (en) | 1972-06-06 |
Family
ID=24612447
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US651323A Expired - Lifetime US3667231A (en) | 1967-07-05 | 1967-07-05 | Hydrazine decomposition process using metal promoters |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US3667231A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4517798A (en) * | 1983-05-31 | 1985-05-21 | The United States Of America As Represented By The Secretary Of The Army | Porous catalytic metal plate degeneration bed in a gas generator |
| US4620415A (en) * | 1983-09-29 | 1986-11-04 | Rocket Research Company | Method for initiating decomposition of hydrazine fuels |
| US5727368A (en) * | 1996-03-28 | 1998-03-17 | Wernimont; Eric J. | Hybrid motor system with a consumable catalytic bed a composition of the catalytic bed and a method of using |
| US5861106A (en) * | 1997-11-13 | 1999-01-19 | Universal Propulsion Company, Inc. | Compositions and methods for suppressing flame |
| US8801878B1 (en) | 2007-07-17 | 2014-08-12 | The United States Of America As Represented By The Secretary Of The Navy | Lead-free pyrotechnic and primary explosive compositions containing metal iodates |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2925709A (en) * | 1949-02-12 | 1960-02-23 | Kellogg M W Co | Decomposition of hydrazine |
| US3083527A (en) * | 1960-10-10 | 1963-04-02 | Phillips Petroleum Co | Hybrid rocket propulsion process |
| US3257802A (en) * | 1964-03-13 | 1966-06-28 | Martin H Kaufman | Method of hybrid high specific impulse propulsion using lithium-polyethylene solid with chlorine containing oxidizers |
| US3331203A (en) * | 1965-06-24 | 1967-07-18 | Martin H Kaufman | Hydrazine propulsive method using lithium and ammonium perchlorate with metal |
-
1967
- 1967-07-05 US US651323A patent/US3667231A/en not_active Expired - Lifetime
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2925709A (en) * | 1949-02-12 | 1960-02-23 | Kellogg M W Co | Decomposition of hydrazine |
| US3083527A (en) * | 1960-10-10 | 1963-04-02 | Phillips Petroleum Co | Hybrid rocket propulsion process |
| US3257802A (en) * | 1964-03-13 | 1966-06-28 | Martin H Kaufman | Method of hybrid high specific impulse propulsion using lithium-polyethylene solid with chlorine containing oxidizers |
| US3331203A (en) * | 1965-06-24 | 1967-07-18 | Martin H Kaufman | Hydrazine propulsive method using lithium and ammonium perchlorate with metal |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4517798A (en) * | 1983-05-31 | 1985-05-21 | The United States Of America As Represented By The Secretary Of The Army | Porous catalytic metal plate degeneration bed in a gas generator |
| US4620415A (en) * | 1983-09-29 | 1986-11-04 | Rocket Research Company | Method for initiating decomposition of hydrazine fuels |
| US5727368A (en) * | 1996-03-28 | 1998-03-17 | Wernimont; Eric J. | Hybrid motor system with a consumable catalytic bed a composition of the catalytic bed and a method of using |
| US5861106A (en) * | 1997-11-13 | 1999-01-19 | Universal Propulsion Company, Inc. | Compositions and methods for suppressing flame |
| US6019177A (en) * | 1997-11-13 | 2000-02-01 | Universal Propulsion Co., Inc. | Methods for suppressing flame |
| US8801878B1 (en) | 2007-07-17 | 2014-08-12 | The United States Of America As Represented By The Secretary Of The Navy | Lead-free pyrotechnic and primary explosive compositions containing metal iodates |
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