US3598169A - Method and apparatus for casting directionally solidified discs and the like - Google Patents
Method and apparatus for casting directionally solidified discs and the like Download PDFInfo
- Publication number
- US3598169A US3598169A US807637A US3598169DA US3598169A US 3598169 A US3598169 A US 3598169A US 807637 A US807637 A US 807637A US 3598169D A US3598169D A US 3598169DA US 3598169 A US3598169 A US 3598169A
- Authority
- US
- United States
- Prior art keywords
- mold
- extension
- cavity
- chill
- seed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 18
- 238000005266 casting Methods 0.000 title claims description 15
- 230000012010 growth Effects 0.000 claims description 18
- 239000000956 alloy Substances 0.000 claims description 16
- 229910045601 alloy Inorganic materials 0.000 claims description 16
- 238000010438 heat treatment Methods 0.000 claims description 16
- 238000001816 cooling Methods 0.000 claims description 6
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- 238000009413 insulation Methods 0.000 claims description 4
- 230000003247 decreasing effect Effects 0.000 claims description 2
- 230000001737 promoting effect Effects 0.000 claims description 2
- 238000007711 solidification Methods 0.000 abstract description 6
- 230000008023 solidification Effects 0.000 abstract description 6
- 230000001939 inductive effect Effects 0.000 abstract description 2
- 238000012986 modification Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 210000001787 dendrite Anatomy 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 230000000284 resting effect Effects 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D27/00—Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
- B22D27/04—Influencing the temperature of the metal, e.g. by heating or cooling the mould
- B22D27/045—Directionally solidified castings
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B11/00—Single-crystal growth by normal freezing or freezing under temperature gradient, e.g. Bridgman-Stockbarger method
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B29/00—Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
- C30B29/10—Inorganic compounds or compositions
- C30B29/52—Alloys
Definitions
- 3,260,505 to VerSnyder describes the casting'of directionally solidified parts with a particular orientation of the crystalline growth with respect to the longitudinal axis of the part.
- FIG. 1 is a vertical sectional view paratus embodying the invention.
- FIG. 2 is a fragmentary sectional view similar to a portion of partially schematic of ap FIG. 1 showinga modification.
- FIG. 3 is a schematic view showing the dendritic orientation.
- FIG. 4 is a vertical sectionalview ofa complete turbine disc including blades.
- FIG. 5 is a fragmentary sectional view along line 5-5 of FIG.
- FIG. 6 is a view similar to FIG. 1 ofanother modification.
- FIG. 7 is a horizontal sectional view of the modification of FIG. 6.
- FIG. 8' is a vertical sectional view similar to FIG. 6 of another modification.
- FIG. 9 is a fragmentary horizontal view through the mold of FIG. 8.
- the apparatus includes a chill plate 10 supporting a mold 12, the latter having a relatively large horizontal dimension, and shown as a mold for producing a disc. Atone side of the mold an axial projection 14 extends downwardly to engage the chill plate, and an upwardly extending axial projection 16 provides a filling opening for the mold.
- the mold is shown as a split-shell mold, being in two parts 120 and 12b although a single piece shell mold may be utilized.- The mold may be enclosed in part by insulation 18 around the axial extension 14 and the disc forming portion is covered 1 from the periphery inwardly by insulation 20 that decreases in thickness toward the center of the disc.
- Annular heating coils 22 and 24 are positioned above and below the mold adjacent to the axial projections. and other heating coils 26 and 28 are periphery and concentric to the coils 22 and 24.
- a heating coil 30 surrounds the periphery of the mold, as shown.
- the mold is positioned within a heating chamber, not shown, to raise the temperature of the entire mold above the melting point of the alloy to be poured and, when adequate heating is accomplished, the molten alloy, su-
- the radial thermal gradient thus produced causes radial growth of the dendrites in the peripheral vertical columnar grains extending upwardly from the axial portion 14 and the radial competition between the several orientations of dendrites in the several rains will result in the radially oriented grains growing the fastest and producing substantially radially arranged dendrites in the entire disc.
- the radial thermal gradient produces the radial growth within the disc in the same way that the vertically oriented grains outgrow the other grains in the axial portion 14. This effect is described in the US. Pat. No. 3,260,505 to VerSnyder. Grain growth occuring in this manner produces an radial orientation and tangential orientation.
- the axially extending portion 14' ofa mold 12' which is otherwise arranged as in FIG. 1 has a seed 36 therein resting on the chill plate.
- This seed is made up of wedges 38 each having the desired orientation for the portion of the disc extending outwardly therefrom.
- the seed wedges cause vertical dendritic growth with each of the several seed wedges providing the desired horizontal orientation for the adjacent portion of the cast disc.
- FIG. 3 The resulting orientation is shown in FIG. 3 where the seed 36 is made up of wedges, for example, as shown, theseed is made up of eight wedges each of 45 and each having the orientation indicated.
- the result is a disc made up of interacting dendritic growths producing approximately a radial and a tangential orientation. Use of many more wedge elements will disc.
- the controlled radial thermal gradient provided by the structure of FIG. 1 permits controlled grain growth through the entire disc to its periphery.
- FIGS. 4 and 5 One particular article that may prove particularly useful in a casting of this character is representedby FIGS. 4 and 5.
- a mold 40 defining a disc-shaped cavity 42, and having the downwardly extending axial projection 44 corresponding to the extension 14 of FIG. 1.
- Projecting outwardly from the periphery of the mold 40 are blade formingprojeccavities 48 communicating above described.
- the disc and blades for a turbine disc may all be cast in a single piece with the preferred orientation of the grain growth in the disc and with the desired radial orientation in the blades for the desired strength characteristics.
- the number of seed wedges would be selected to insure the precise radial grain growth in the blades.
- the seed used would have possibly one wedge for each two blades, the-orientation of the several wedges being carefully selected for precise radial grain growth.
- FIGS. 6 and 7 Another alternative is shown in FIGS. 6 and 7 where the mold is made up of individual mold elements 50 extending precisely radial grain'distribution within the v radially outward from a central casting cavity 52 surrounding a vertical cylindrical chill 54.
- the chill 54 is surrounded by seed segments 56, one for each mold element 50 and these segments establish the direction of the grain growth in each mold.
- the grain growth proceeds radially outward in each mold 50 and its connecting mold passage 58, with the temperature gradient in a radial direction controlled by the central chill and the use of annular heating coils as in FIG. 1.
- This controlled thermal gradient which will produce directionally solidified alloy in each mold element 50 with the direction of the grains radial in each cast article, is described in U.S. Pat. No. 3,260,505 to VerSnyder above referred to.
- the cast articles are represented as turbine blades and would be cast from the type of high temperature alloy of which several examples are given in the VerSnyder patent.
- FIG. 8 An alternate proposed method of producing discs, with or without integral blades, is shown in FIG. 8 in which the mold 60 has an annular disc cavity 62 and surrounds a central vertical cylindrical chill 64.
- the periphery of the mold may have recesses 66 therein for forming the individual blades on the periphery of the disc when the cast article is intended as a bladed turbine disc.
- a ring 68 of individual seed segments 70, each of directionally solidified material with properly oriented grains surrounds the chill at the disc level to control the directional orientation of the grain growth in the disc.
- annular heat control coils similar to those in FIG. 1 are used here to produce the desired radial thermal gradient. By using the appropriate number of seed segments the precise radial grain growth desired may be obtained throughout the disc and into the individual blades.
- Apparatus for casting relatively flat articles with a selected grain orientation including a chill plate, a mold hav' ing an article-shaped cavity and a centrally located downward extension forming a vertically positioned cavity communicating with said first cavity and opening onto the chill plate, and a plurality of heating means adjacent to the mold and arranged on top and bottom of the article cavity and in steps outwardly from the downward extension to the remote edge of the mold to establish a thermal gradient radially outward from the extension toward the remote edge ofthe mold.
- Apparatus as in claim I in which a seed having multiple orientations is placed on the chill plate and within the extension.
- the method of casting discs and the like including the step of providing a mold having an article forming cavity and a downward extension thereon forming a vertical cavity communicating with said first cavity and open at the bottom, providing a chill plate on which the downward extension rests, heating the mold to a point above the melting point of the al loy, pouring the alloy into the mold, cooling the chill plate to remove heat from the alloy, and cooling the mold in steps radially outward from the extension thereby providing a radially outward thermal gradient from the downward extension of the mold to the outer periphery of the mold laterally remote therefrom.
- the extension is located centrally of the cavity, and the step of cooling the mold in steps radially outward produces a radial thermal gradient horizontally from the central extension to the periphery of the annulus thereby promoting a radial grain growth horizontally in the mold.
- Apparatus for casting relatively flat articles with a selected grain orientation including a chill, a mold defining a ring-shaped cavity, one surface of which is defined by the chill, and a plurality of annular heating means adjacent to the mold and arranged in steps radially outward outwardly from the axis of the ring and on opposite sides thereof to establish a thermal gradient from the axis to the periphery of the mold.
- Apparatus as in claim 11 in which the chill is a cylinder extending axially of and surrounded by the mold.
- Apparatus as in claim 11 in which the cavity defines a plurality of radially extending article forming cavities all communicating with a central cavity in contact with the chill.
- Apparatus as in claim 11 in which the chill is a vertically extending centrally located chill surrounded by the mold, and in which a seed made up of properly oriented segments surrounds the chill within the cavity.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Molds, Cores, And Manufacturing Methods Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US80763769A | 1969-03-13 | 1969-03-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3598169A true US3598169A (en) | 1971-08-10 |
Family
ID=25196848
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US807637A Expired - Lifetime US3598169A (en) | 1969-03-13 | 1969-03-13 | Method and apparatus for casting directionally solidified discs and the like |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3598169A (de) |
| JP (1) | JPS4815134B1 (de) |
| CA (1) | CA926737A (de) |
| DE (1) | DE2010570B2 (de) |
| FR (1) | FR2041073B1 (de) |
| GB (1) | GB1264053A (de) |
| SE (1) | SE348960B (de) |
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2242111A1 (de) * | 1971-09-15 | 1973-03-22 | United Aircraft Corp | Verfahren und vorrichtung zum giessen von gegenstaenden mit gerichtet erstarrtem gefuege |
| US3729050A (en) * | 1971-08-10 | 1973-04-24 | Howmet Corp | Refractory support for shell molds |
| US3858641A (en) * | 1971-02-12 | 1975-01-07 | Minnesota Mining & Mfg | Metal casting in thin walled molds |
| US4016829A (en) * | 1973-02-26 | 1977-04-12 | Hitachi, Ltd. | Apparatus for crystal growth |
| US4096025A (en) * | 1974-02-21 | 1978-06-20 | The United States Of America As Represented By The Secretary Of The Army | Method of orienting seed crystals in a melt, and product obtained thereby |
| DE2949446A1 (de) * | 1978-12-13 | 1980-06-26 | United Technologies Corp | Verfahren und form fuer epitaxiale erstarrung |
| US4213497A (en) * | 1978-08-21 | 1980-07-22 | General Electric Company | Method for casting directionally solidified articles |
| US4240495A (en) * | 1978-04-17 | 1980-12-23 | General Motors Corporation | Method of making cast metal turbine wheel with integral radial columnar grain blades and equiaxed grain disc |
| US4289570A (en) * | 1978-12-13 | 1981-09-15 | United Technologies Corporation | Seed and method for epitaxial solidification |
| EP0066971A3 (de) * | 1981-06-08 | 1983-03-16 | Trw Inc. | Verfahren zum Giessen eines Gegenstandes |
| US4469160A (en) * | 1981-12-23 | 1984-09-04 | United Technologies Corporation | Single crystal solidification using multiple seeds |
| US4499155A (en) * | 1983-07-25 | 1985-02-12 | United Technologies Corporation | Article made from sheet having a controlled crystallographic orientation |
| US4605452A (en) * | 1981-12-14 | 1986-08-12 | United Technologies Corporation | Single crystal articles having controlled secondary crystallographic orientation |
| US4659288A (en) * | 1984-12-10 | 1987-04-21 | The Garrett Corporation | Dual alloy radial turbine rotor with hub material exposed in saddle regions of blade ring |
| US4804311A (en) * | 1981-12-14 | 1989-02-14 | United Technologies Corporation | Transverse directional solidification of metal single crystal articles |
| US4813470A (en) * | 1987-11-05 | 1989-03-21 | Allied-Signal Inc. | Casting turbine components with integral airfoils |
| US4850419A (en) * | 1982-09-01 | 1989-07-25 | Trw Inc. | Method of casting a one-piece wheel |
| US5061154A (en) * | 1989-12-11 | 1991-10-29 | Allied-Signal Inc. | Radial turbine rotor with improved saddle life |
| US5292385A (en) * | 1991-12-18 | 1994-03-08 | Alliedsignal Inc. | Turbine rotor having improved rim durability |
| FR2734188A1 (fr) * | 1982-09-28 | 1996-11-22 | Snecma | Procede de fabrication de pieces monocristallines |
| US5611389A (en) * | 1980-12-30 | 1997-03-18 | Societe Nationale D'etude Et De Construction De Moterus D'aviation S.N.E.C.M.A. | Procedure for the fabrication of crystalline blades |
| US5730582A (en) * | 1997-01-15 | 1998-03-24 | Essex Turbine Ltd. | Impeller for radial flow devices |
| US20100206510A1 (en) * | 2008-06-24 | 2010-08-19 | Garlock Robert M | Method and apparatus for casting metal articles |
| FR3141083A1 (fr) * | 2022-10-21 | 2024-04-26 | Safran | Procédé de fabrication par moulage d’un disque aubagé monobloc |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4074340A (en) * | 1976-10-18 | 1978-02-14 | Vitramon, Incorporated | Trimmable monolithic capacitors |
| JPS56110645U (de) * | 1980-01-25 | 1981-08-27 | ||
| JPS593621U (ja) * | 1982-06-29 | 1984-01-11 | 株式会社村田製作所 | チツプ型圧電振動部品 |
| JPS60123122A (ja) * | 1983-12-07 | 1985-07-01 | Murata Mfg Co Ltd | チップ型圧電共振部品とその製造方法 |
| AT387167B (de) * | 1986-08-11 | 1988-12-12 | Vaillant Gmbh | Verfahren zum vorheizen einer druckgiessform |
| EP0506608B1 (de) * | 1991-03-26 | 1996-12-27 | Sulzer Innotec Ag | Vorrichtung zur Herstellung von gerichtet erstarrten Gussstücken |
| EP1284310A1 (de) * | 2001-08-13 | 2003-02-19 | Siemens Aktiengesellschaft | Verfahren zur Herstellung eines einkristallinen Bauteils komplexer Formstruktur |
| JP5754636B2 (ja) * | 2011-08-04 | 2015-07-29 | 株式会社不二越 | ゲルマニウムの溶融成形方法及び装置 |
| JP5861928B2 (ja) * | 2012-01-30 | 2016-02-16 | 株式会社不二越 | ゲルマニウムの溶融成形方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2791813A (en) * | 1954-10-28 | 1957-05-14 | James K Delano | Apparatus and method for growing crystals having a controlled internal junction structure |
| US3373795A (en) * | 1965-08-10 | 1968-03-19 | Trw Inc | Gating of unshrouded airfoils to permit directional solidification |
| US3405220A (en) * | 1965-07-16 | 1968-10-08 | United Aircraft Corp | Induction electric mold heater |
| US3515205A (en) * | 1968-03-20 | 1970-06-02 | United Aircraft Corp | Mold construction forming single crystal pieces |
-
1969
- 1969-03-13 US US807637A patent/US3598169A/en not_active Expired - Lifetime
-
1970
- 1970-01-14 CA CA072162A patent/CA926737A/en not_active Expired
- 1970-02-26 FR FR7007996A patent/FR2041073B1/fr not_active Expired
- 1970-03-06 SE SE02982/70A patent/SE348960B/xx unknown
- 1970-03-06 DE DE19702010570 patent/DE2010570B2/de not_active Withdrawn
- 1970-03-09 GB GB01115/70A patent/GB1264053A/en not_active Expired
- 1970-03-11 JP JP45021162A patent/JPS4815134B1/ja active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2791813A (en) * | 1954-10-28 | 1957-05-14 | James K Delano | Apparatus and method for growing crystals having a controlled internal junction structure |
| US3405220A (en) * | 1965-07-16 | 1968-10-08 | United Aircraft Corp | Induction electric mold heater |
| US3373795A (en) * | 1965-08-10 | 1968-03-19 | Trw Inc | Gating of unshrouded airfoils to permit directional solidification |
| US3515205A (en) * | 1968-03-20 | 1970-06-02 | United Aircraft Corp | Mold construction forming single crystal pieces |
Cited By (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3858641A (en) * | 1971-02-12 | 1975-01-07 | Minnesota Mining & Mfg | Metal casting in thin walled molds |
| US3729050A (en) * | 1971-08-10 | 1973-04-24 | Howmet Corp | Refractory support for shell molds |
| DE2242111A1 (de) * | 1971-09-15 | 1973-03-22 | United Aircraft Corp | Verfahren und vorrichtung zum giessen von gegenstaenden mit gerichtet erstarrtem gefuege |
| US4016829A (en) * | 1973-02-26 | 1977-04-12 | Hitachi, Ltd. | Apparatus for crystal growth |
| US4096025A (en) * | 1974-02-21 | 1978-06-20 | The United States Of America As Represented By The Secretary Of The Army | Method of orienting seed crystals in a melt, and product obtained thereby |
| US4240495A (en) * | 1978-04-17 | 1980-12-23 | General Motors Corporation | Method of making cast metal turbine wheel with integral radial columnar grain blades and equiaxed grain disc |
| US4213497A (en) * | 1978-08-21 | 1980-07-22 | General Electric Company | Method for casting directionally solidified articles |
| DE2949446A1 (de) * | 1978-12-13 | 1980-06-26 | United Technologies Corp | Verfahren und form fuer epitaxiale erstarrung |
| US4289570A (en) * | 1978-12-13 | 1981-09-15 | United Technologies Corporation | Seed and method for epitaxial solidification |
| US5611389A (en) * | 1980-12-30 | 1997-03-18 | Societe Nationale D'etude Et De Construction De Moterus D'aviation S.N.E.C.M.A. | Procedure for the fabrication of crystalline blades |
| EP0066971A3 (de) * | 1981-06-08 | 1983-03-16 | Trw Inc. | Verfahren zum Giessen eines Gegenstandes |
| US4605452A (en) * | 1981-12-14 | 1986-08-12 | United Technologies Corporation | Single crystal articles having controlled secondary crystallographic orientation |
| US4804311A (en) * | 1981-12-14 | 1989-02-14 | United Technologies Corporation | Transverse directional solidification of metal single crystal articles |
| US4469160A (en) * | 1981-12-23 | 1984-09-04 | United Technologies Corporation | Single crystal solidification using multiple seeds |
| US4850419A (en) * | 1982-09-01 | 1989-07-25 | Trw Inc. | Method of casting a one-piece wheel |
| FR2734188A1 (fr) * | 1982-09-28 | 1996-11-22 | Snecma | Procede de fabrication de pieces monocristallines |
| US4499155A (en) * | 1983-07-25 | 1985-02-12 | United Technologies Corporation | Article made from sheet having a controlled crystallographic orientation |
| US4659288A (en) * | 1984-12-10 | 1987-04-21 | The Garrett Corporation | Dual alloy radial turbine rotor with hub material exposed in saddle regions of blade ring |
| US4813470A (en) * | 1987-11-05 | 1989-03-21 | Allied-Signal Inc. | Casting turbine components with integral airfoils |
| US5061154A (en) * | 1989-12-11 | 1991-10-29 | Allied-Signal Inc. | Radial turbine rotor with improved saddle life |
| US5292385A (en) * | 1991-12-18 | 1994-03-08 | Alliedsignal Inc. | Turbine rotor having improved rim durability |
| US5730582A (en) * | 1997-01-15 | 1998-03-24 | Essex Turbine Ltd. | Impeller for radial flow devices |
| US20100206510A1 (en) * | 2008-06-24 | 2010-08-19 | Garlock Robert M | Method and apparatus for casting metal articles |
| US7958928B2 (en) | 2008-06-24 | 2011-06-14 | Pcc Airfoils, Inc. | Method and apparatus for casting metal articles |
| FR3141083A1 (fr) * | 2022-10-21 | 2024-04-26 | Safran | Procédé de fabrication par moulage d’un disque aubagé monobloc |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2010570B2 (de) | 1972-05-10 |
| FR2041073B1 (de) | 1974-05-03 |
| GB1264053A (en) | 1972-02-16 |
| JPS4815134B1 (de) | 1973-05-12 |
| FR2041073A1 (de) | 1971-01-29 |
| SE348960B (de) | 1972-09-18 |
| CA926737A (en) | 1973-05-22 |
| DE2010570A1 (de) | 1970-09-24 |
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