US3574319A - Paraffin control method - Google Patents
Paraffin control method Download PDFInfo
- Publication number
- US3574319A US3574319A US889327A US3574319DA US3574319A US 3574319 A US3574319 A US 3574319A US 889327 A US889327 A US 889327A US 3574319D A US3574319D A US 3574319DA US 3574319 A US3574319 A US 3574319A
- Authority
- US
- United States
- Prior art keywords
- crude oil
- asphaltic
- paraffin
- oil
- paraffin base
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/52—Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning
- C09K8/524—Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning organic depositions, e.g. paraffins or asphaltenes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S507/00—Earth boring, well treating, and oil field chemistry
- Y10S507/927—Well cleaning fluid
- Y10S507/929—Cleaning organic contaminant
- Y10S507/931—Organic contaminant is paraffinic
Definitions
- This invention relates to a method for preventing parafiin deposition in conveying and storage facilities of paraffin base oil. More particularly, the invention relates to the inhibition of paraffin deposition in an oil well production system by addition of certain wax crystal modifiers to a production stream of paraffin base oil.
- Prior art methods used to solve this problem have been either preventative or curative.
- Preventative technology includes such methods as addition of naphthalene and various other solvents or washes to clean up tubing, rods and pipes when they have become plugged. Such techniques have not been universally successful. In recent years some information has been published which shows that rods coated with polyethylene exhibit a resistance to fouling. Several cases have been described wherein fine particles of polyethylene are injected into the hole to prevent deposition of paraffin in the production tubing.
- I-Iot oil treatments and solvents have been used in an attempt to melt paraffin which has been deposited on the interior of lines in the production system. Scraping operations have been used to physically remove the deposits from piping and storage facilities.
- An object of this invention is to provide an improved method for preventing paraffin deposition in storage and conveying equipment associated with a producing oil well.
- this invention is an improved method for preventing paraffin deposition in a paraffin base crude oil conveying and storing system. It includes the steps of injecting an asphaltic crude oil into the paraffin base crude oil and commingling the asphaltic crude oil with the paraffin base crude oil.
- the asphaltic crude oil is injected continuously into the conveying and storage system. In certain other embodiments the asphaltic crude oil is injected periodically in slugs into the conveying and storage system.
- a method for preventing paraffin deposition in a system for producing paraffin base oil DESCRIPTION OF THE PREFERRED EMBODIMENT production pipe.
- the presence of the asp altic Oil in the paraffinic oil inhibits the deposition of paraffin during production and storage. If paraffin deposition has been no problem in the production tubing from the formation to the wellhead, then the location of injection of the asphaltic oil should be at some point upstream of anticipated or previously observed deposition. The injection of the asphaltic crude oil should inhibit subsequent precipitation of paraffin in any conveying or storage equipment.
- this deposition control is accomplished because of a crystalline state modification of the paraffin by the asphalt or by some specific physical or chemical property of the asphaltic crude oil. In other words, some degree of wax crystal modification is accomplished by the addition of the asphaltic crude oil.
- the asphaltic oil may act as a polar or film-forming agent on the metal surface in the production and storage equipment.
- said injection step includes continuously injecting said asphaltic crude oil into sa paraffin base production stream.
- said injection step includes periodically injecting said asphaltic crude oil into said paraffin base production stream.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
A method for controlling paraffin deposition in an oil production system and includes injecting an asphaltic crude oil into paraffin base crude oil production and storage facilities. The invention includes the steps of mixing the asphaltic crude oil with the paraffin base crude oil and producing the paraffin base oil to the surface.
Description
United States Patent 2,300,348 10/1942 Dana 166/304X 2,303,823 12/1942 Coberly... 252/83 2,765,850 10/1956 Allen l66/304X 3,051,653 8/1962 Skolaut et al. 252/83 3,276,519 10/1966 Knox et al 252/8.3X
3,481,870 12/1969 Cheng et a1 166/304X OTHER REFERENCES Reistle, C.E., Jr.: Paraffin and Congealing-Oil Problems, Bureau of Mines Bulletin 348, US Govt. Printing Office, Washington DC, 1932, pp. 10 and 1 1. Copy in 166- 304 Primary Examiner-Stephen J. Novosad Attorneys Eugene S. Coddou and Lee R, Larkin ABSTRACT: A method for controlling paraffin deposition in an oil production system and includes injecting an asphaltic crude oil into paraffin base crude oil production and storage facilities. The invention includes the steps of mixing the asphaltic crude oil with the paraffin base crude oil and producing the paraffin base oil to the surface.
PARAFFIN CONTROL METHOD BACKGROUND OF THE INVENTION 1. Field of the Invention This invention relates to a method for preventing parafiin deposition in conveying and storage facilities of paraffin base oil. More particularly, the invention relates to the inhibition of paraffin deposition in an oil well production system by addition of certain wax crystal modifiers to a production stream of paraffin base oil.
2. Description of the Prior Art In many parts of the world paraffin crude oils exist and are produced with resulting deposition of paraffin in the production tubing, surface lines and tanks. There are various remedies to inhibit or prevent this deposition, but none have been entirely satisfactory.
Prior art methods used to solve this problem have been either preventative or curative. Preventative technology includes such methods as addition of naphthalene and various other solvents or washes to clean up tubing, rods and pipes when they have become plugged. Such techniques have not been universally successful. In recent years some information has been published which shows that rods coated with polyethylene exhibit a resistance to fouling. Several cases have been described wherein fine particles of polyethylene are injected into the hole to prevent deposition of paraffin in the production tubing.
I-Iot oil treatments and solvents have been used in an attempt to melt paraffin which has been deposited on the interior of lines in the production system. Scraping operations have been used to physically remove the deposits from piping and storage facilities.
The expense associated with all of the prior art methods becomes very great as wells become deeper and the length of the downhole tubing becomes greater. The cost of chemicals and labor employed in such operations in prior arts is extremely burdensome and shows the need for an inexpensive improvement in these procedures.
SUMMARY OF THE INVENTION An object of this invention is to provide an improved method for preventing paraffin deposition in storage and conveying equipment associated with a producing oil well.
Briefly stated, this invention is an improved method for preventing paraffin deposition in a paraffin base crude oil conveying and storing system. It includes the steps of injecting an asphaltic crude oil into the paraffin base crude oil and commingling the asphaltic crude oil with the paraffin base crude oil. In certain embodiments, the asphaltic crude oil is injected continuously into the conveying and storage system. In certain other embodiments the asphaltic crude oil is injected periodically in slugs into the conveying and storage system.
In certain other embodiments a method for preventing paraffin deposition in a system for producing paraffin base oil DESCRIPTION OF THE PREFERRED EMBODIMENT production pipe. The presence of the asp altic Oil in the paraffinic oil inhibits the deposition of paraffin during production and storage. If paraffin deposition has been no problem in the production tubing from the formation to the wellhead, then the location of injection of the asphaltic oil should be at some point upstream of anticipated or previously observed deposition. The injection of the asphaltic crude oil should inhibit subsequent precipitation of paraffin in any conveying or storage equipment.
It is to be understood that the preferred asphaltic crude oil will produce no asphaltene precipitate when mixed with the paraffinic stream. 7, 7
It is believed that this deposition control is accomplished because of a crystalline state modification of the paraffin by the asphalt or by some specific physical or chemical property of the asphaltic crude oil. In other words, some degree of wax crystal modification is accomplished by the addition of the asphaltic crude oil. Another explanation for this phenomenon is that the asphaltic oil may act as a polar or film-forming agent on the metal surface in the production and storage equipment.
It is to be understood that the foregoing is generally illustrative of the invention, and that other alternatives and embodiments will become obvious to one skilled in the art after studying this description. The description, therefore, is to be construed as illustrative only of certain embodiments of the invention.
We claim:
1. In a method for preventing paraffin deposition in a paraffin base crude oil conveying system, the combination of steps comprising:
injecting an asphaltic crude oil into said paraffin base crude oil; and
commingling said asphaltic crude oil with said paraffin base crude oil prior to flowing of said mixture through said system.
2. The invention as claimed in claim 1 wherein; said asphaltic crude oil is a heavy asphaltic Wyoming crude oil.
3. The invention as claimed in claim 1 wherein; said asphaltic crude oil is injected continuously into said conveying system.
4. The invention as claimed in claim 1 wherein; said asphaltic crude oil is injected periodically in slugs into said conveying system.
5. In a method for preventing paraffin deposition in a system for producing paraffin base oil from an underground formation penetrated by a wellbore, the combination comprising:
conveying an asphaltic crude oil from a storage means to the annulus of a production pipe situated within said producing underground formation;
injecting said asphaltic crude oil into said paraffin base production stream;
commingling said added asphaltic crude oil with said paraffin base production stream; and
producing said paraffin base oil stream to the surface.
6. The invention as claimed in claim 5 wherein; said asphaltic crude oil is a heavy asphaltic Wyoming crude oil.
7. The invention as claimed in claim 5 wherein; said injection step includes continuously injecting said asphaltic crude oil into sa paraffin base production stream.
8. The invention as claimed in claim 5 wherein; said injection step includes periodically injecting said asphaltic crude oil into said paraffin base production stream.
Claims (6)
- 2. The invention as claimed in claim 1 wherein; said asphaltic crude oil is a heavy asphaltic Wyoming crude oil.
- 3. The invention as claimed in claim 1 wherein; said asphaltic crude oil is injected continuously into said conveying system.
- 4. The invention as claimed in claim 1 wherein; said asphaltic crude oil is injected periodically in slugs into said conveying system.
- 5. In a method for preventing paraffin deposition in a system for producing paraffin base oil from an underground formation penetrated by a wellbore, the combination comprising: conveying an asphaltic crude oil from a storage means to the annulus of a production pipe situated within said producing underground formation; injecting said asphaltic crude oil into said paraffin base production stream; commingling said added asphaltic crude oil with said paraffin base production stream; and producing said paraffin base oil stream to the surface.
- 6. The invention as claimed in claim 5 wherein; said asphaltic crude oil is a heavy asphaltic Wyoming crude oil.
- 7. The invention as claimed in claim 5 wherein; said injection step includes continuously injecting said asphaltic crude oil into sa paraffin base production stream. 8. The invention as claimed in claim 5 wherein; said injection step includes periodically injecting said asphaltic crude oil into said paraffin base production stream.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US88932769A | 1969-12-30 | 1969-12-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3574319A true US3574319A (en) | 1971-04-13 |
Family
ID=25394915
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US889327A Expired - Lifetime US3574319A (en) | 1969-12-30 | 1969-12-30 | Paraffin control method |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US3574319A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4756368A (en) * | 1986-01-13 | 1988-07-12 | Mitsubishi Jukogyo Kabushiki Kaisha | Method for drawing up special crude oil |
| US5139088A (en) * | 1989-09-06 | 1992-08-18 | Shell Oil Company | Method of inhibiting asphalt precipitation in an oil production well |
| US5891262A (en) * | 1997-01-21 | 1999-04-06 | Petroleo Brasileiro S.A.-Petrobras | On-line thermo-chemical process for the dewaxing of oil export pipelines |
| US20100108570A1 (en) * | 2008-11-06 | 2010-05-06 | Nath Cody W | Method for improving liquid yield in a delayed coking process |
| US20100307536A1 (en) * | 2009-06-04 | 2010-12-09 | Refined Technologies, Inc. | Process For Removing Hydrocarbons And Noxious Gasses From Reactors And Media-Packed Equipment |
| US20110056694A1 (en) * | 2009-09-10 | 2011-03-10 | Refined Technologies, Inc. | Methods For Removing Paraffinic Hydrocarbon Or Bitumen In Oil Producing Or Disposal Wells |
| RU2603866C1 (en) * | 2016-02-24 | 2016-12-10 | Публичное акционерное общество "Татнефть" им. В.Д. Шашина | Method of removing deposits from well equipped with bottom-hole pump |
| RU2603982C1 (en) * | 2016-02-24 | 2016-12-10 | Публичное акционерное общество "Татнефть" им. В.Д. Шашина | Method of removing deposits from well equipped with electric centrifugal pump |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2204967A (en) * | 1932-09-27 | 1940-06-18 | Shell Dev | Process for lowering the pour points of mineral oils |
| US2300348A (en) * | 1941-04-21 | 1942-10-27 | Frank E Dana | Method for cleaning oil wells |
| US2303823A (en) * | 1940-08-01 | 1942-12-01 | Kobe Inc | Method of preventing wax deposits in tubing |
| US2765850A (en) * | 1953-05-22 | 1956-10-09 | Texas Co | Production of formation-clogging liquid hydrocarbons |
| US3051653A (en) * | 1959-10-06 | 1962-08-28 | Halliburton Co | Paraffin control composition and method |
| US3276519A (en) * | 1963-05-29 | 1966-10-04 | Halliburton Co | Paraffin control method |
| US3481870A (en) * | 1964-09-28 | 1969-12-02 | Petrolite Corp | Composition and method for inhibiting the formation of in and removing from oil wells and pipelines deposits of paraffin and paraffinlike deposits |
-
1969
- 1969-12-30 US US889327A patent/US3574319A/en not_active Expired - Lifetime
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2204967A (en) * | 1932-09-27 | 1940-06-18 | Shell Dev | Process for lowering the pour points of mineral oils |
| US2303823A (en) * | 1940-08-01 | 1942-12-01 | Kobe Inc | Method of preventing wax deposits in tubing |
| US2300348A (en) * | 1941-04-21 | 1942-10-27 | Frank E Dana | Method for cleaning oil wells |
| US2765850A (en) * | 1953-05-22 | 1956-10-09 | Texas Co | Production of formation-clogging liquid hydrocarbons |
| US3051653A (en) * | 1959-10-06 | 1962-08-28 | Halliburton Co | Paraffin control composition and method |
| US3276519A (en) * | 1963-05-29 | 1966-10-04 | Halliburton Co | Paraffin control method |
| US3481870A (en) * | 1964-09-28 | 1969-12-02 | Petrolite Corp | Composition and method for inhibiting the formation of in and removing from oil wells and pipelines deposits of paraffin and paraffinlike deposits |
Non-Patent Citations (1)
| Title |
|---|
| Reistle, C.E., Jr.: Paraffin and Congealing-Oil Problems, Bureau of Mines Bulletin 348, U.S. Govt. Printing Office, Washington D.C., 1932, pp. 10 and 11. Copy in 166 304 * |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4756368A (en) * | 1986-01-13 | 1988-07-12 | Mitsubishi Jukogyo Kabushiki Kaisha | Method for drawing up special crude oil |
| US5139088A (en) * | 1989-09-06 | 1992-08-18 | Shell Oil Company | Method of inhibiting asphalt precipitation in an oil production well |
| US5891262A (en) * | 1997-01-21 | 1999-04-06 | Petroleo Brasileiro S.A.-Petrobras | On-line thermo-chemical process for the dewaxing of oil export pipelines |
| US20100108570A1 (en) * | 2008-11-06 | 2010-05-06 | Nath Cody W | Method for improving liquid yield in a delayed coking process |
| US20100307536A1 (en) * | 2009-06-04 | 2010-12-09 | Refined Technologies, Inc. | Process For Removing Hydrocarbons And Noxious Gasses From Reactors And Media-Packed Equipment |
| US8480812B2 (en) | 2009-06-04 | 2013-07-09 | Refined Technologies, Inc. | Process for removing hydrocarbons and noxious gasses from reactors and media-packed equipment |
| US20110056694A1 (en) * | 2009-09-10 | 2011-03-10 | Refined Technologies, Inc. | Methods For Removing Paraffinic Hydrocarbon Or Bitumen In Oil Producing Or Disposal Wells |
| RU2603866C1 (en) * | 2016-02-24 | 2016-12-10 | Публичное акционерное общество "Татнефть" им. В.Д. Шашина | Method of removing deposits from well equipped with bottom-hole pump |
| RU2603982C1 (en) * | 2016-02-24 | 2016-12-10 | Публичное акционерное общество "Татнефть" им. В.Д. Шашина | Method of removing deposits from well equipped with electric centrifugal pump |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Kokal et al. | Asphaltenes: the cholesterol of petroleum | |
| White et al. | A review of wax-formation/mitigation technologies in the petroleum industry | |
| US3574319A (en) | Paraffin control method | |
| US9862873B2 (en) | System for removing organic deposits | |
| Lightford et al. | Development and field use of a novel solvent-water emulsion for the removal of asphaltene deposits in fractured carbonate formations | |
| US3718586A (en) | Solvent for cleaning well bores,flowlines,etc. | |
| Akbar et al. | A comprehensive approach to solve asphaltene deposition problem in some deep wells | |
| Collins et al. | Sulphate removal for barium sulphate scale mitigation a deepwater subsea production system | |
| Yin et al. | Asphaltene deposition and chemical control in CO2 floods | |
| US3051653A (en) | Paraffin control composition and method | |
| Li et al. | A review: progress of diverter technology for oil and gas production applications in the past decade | |
| Suzuki | Precipitation of asphaltic sludge during acid stimulation treatment: cause, effect, and prevention | |
| Addison | Identification and treating of downhole organic deposits | |
| Giammancheri et al. | Scaling issues on horizontal multi-fractured wells: an alternative intervention approach with novel technologies for diversion and scale inhibition | |
| Ramones et al. | Removal of organic and inorganic scale from electric submersible pumps | |
| Thomas et al. | The use of coiled tubing during matrix acidizing of carbonate reservoirs | |
| Beyer et al. | Downhole emulsification for improving paraffinic crude production | |
| Castro | Demulsification treatment and removal of in-situ emulsion in heavy-oil reservoirs | |
| Alharith et al. | A Novel Approach for Near Wellbore Stimulation and Deposits Removal Utilizing Thermochemical Reaction | |
| Al Hinai et al. | Successful Application of Solvent to Treat Condensate Banking in High Pressure, High Temperature Deep Tight Gas Reservoirs | |
| Gutierrez et al. | Chemical stimulation pilot at a heavy-oil field: key considerations, workflow, and results | |
| Scott et al. | Development of a Downhole Scale Management Philosophy for Water Sensitive Reservoirs | |
| Ibrahim et al. | Thermochemical Solution for Removal of Organic Solids Deposit in and Around Wellbore and Production Tubing | |
| Becker Jr | Asphaltene: To Treat or Not | |
| Alabdulmohsin et al. | Underbalanced Coiled Tubing Mechanical De-Scaling Operations: A Case History for an Oil Well in Ghawar Field from Saudi Arabia |