[go: up one dir, main page]

US3037920A - Indicator system for sacrificial anodes - Google Patents

Indicator system for sacrificial anodes Download PDF

Info

Publication number
US3037920A
US3037920A US737572A US73757258A US3037920A US 3037920 A US3037920 A US 3037920A US 737572 A US737572 A US 737572A US 73757258 A US73757258 A US 73757258A US 3037920 A US3037920 A US 3037920A
Authority
US
United States
Prior art keywords
tank
ammeter
anode
current
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US737572A
Inventor
Leslie F Vixler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Patrol Valve Co
Original Assignee
Patrol Valve Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Patrol Valve Co filed Critical Patrol Valve Co
Priority to US737572A priority Critical patent/US3037920A/en
Application granted granted Critical
Publication of US3037920A publication Critical patent/US3037920A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F13/00Inhibiting corrosion of metals by anodic or cathodic protection
    • C23F13/02Inhibiting corrosion of metals by anodic or cathodic protection cathodic; Selection of conditions, parameters or procedures for cathodic protection, e.g. of electrical conditions
    • C23F13/06Constructional parts, or assemblies of cathodic-protection apparatus
    • C23F13/08Electrodes specially adapted for inhibiting corrosion by cathodic protection; Manufacture thereof; Conducting electric current thereto
    • C23F13/22Monitoring arrangements therefor

Definitions

  • This invention relates to hot water heater and storage tanks in which a so-called sacrificial anode is employed to protect the interior surfaces of the tank from corrosion by galvanic action between the anode and the tank.
  • the invention is directed to methods and apparatus for controlling the galvanic action and for indicating the condition of the anode during its active life.
  • the invention relates to new tank and anode assemblies including an indicator for visually showing the galvanic activity of an anode in the tank while the assembly is in use and, optionally, also including an additional electrical resistance element in the metallic portion of the electrical circuit for limiting the galvanic current flow, according to the conductivity of the water, to a current value no greater than that required to protect the tank from internal corrosion.
  • the invention also relates to special ammeters and their use in connection with the tank and anode assemblies and to improve anode mounting structures particularly adapted for use where an ammeter is included in the metallic portion of the electrical circuit.
  • galvanic protection of the interior metal surfaces of hot water heater and storage tanks may be accomplished by mounting inside the tank, a metal element that is anodic, i.e., more electropositive or less noble, relative to the interior metal surface of the tank, and that is termed an anode or sacrificial anode.
  • This anode is electrically connected to the tank by a metallic circuit of relatively low electrical resistance, conventionally by a direct metallic connector by which the anode is suspended in the tank.
  • the anode is also electrically connected to the interior surface of the tank through the water, which connection provides much greater resistance to the flow of electrical current therethrough than does the metallic circuit.
  • the anode is commonly referred to as a sacrificial anode, as noted above.
  • galvanic protection of the tank ceases, and the anode must be replaced before this occurs if continuing protection of the tank is to be maintained.
  • the anode is normally not visible, and its condition is normally determinable only by emptying the tank and removing the anode for inspection. This is troublesome and is often reglected, resulting in premature tank failures from internal corrosion.
  • the galvanic current flowing through the anodetank circuit may be greater than needed to provide adequate tank protection, or it may be less than needed for 7 above.
  • the galvanic current is greater than needed, the rate of anode consumption is excessive, and some convenient means for reducing the current induced by a given tank and anode assembly is desirable in order to prolong the life of the anode. If the galvanic current is less than needed, the only remedy is to alter the anode arrangement so as to increase the anode surface area, as by using an anode having a larger surface or by using more than one anode to achieve the same effect.
  • the use of a plurality of anodes has the advantage of enabling the anode surfaces to be better distributed as regards their spacing from welded joints and other critical portions of the tank interior where corrosion tends to be concentrated, since the current flowing to various points on the tank interior varies inversely with the length (resistance) of the water path from those critical points on the tank surface to the nearest anode surface.
  • This consideration makes it desirable in some cases, particularly in large diameter tanks, to employ a plurality of anodes even though the resulting total galvanic current, and consequent rate of anode consumption, becomes much greater than necessary. This accentuates the need for a convenient way in which to control the total galvanic currents induced in a given apparatus by waters of varying conductivity.
  • the objects of the present invention are to provide improved tank and anode assemblies which either eliminate or, at least, reduce each of the problems discussed More specifically, the objects of the invention are: to provide convenient means for limiting the galvanic current so as to permit greater flexibility of tankanode designs for obtaining maximum tank protection without an excessive rate of anode consumption; to provide simple and reliable means for indicating the condition of an anode or set of anodes in a tank while the tank is in use; and to provide means associated with the electrical circuit of a tank-anode assembly which will enable the tank manufacturer to determine whether or not his customer has permitted the tank to remain in use after the protective galvanic current (due to anode consumption) has dropped below a safe value, whereby the manufacturer may safely offer longer guarantees of tank life conditioned upon proper maintenance of anodes by his customers.
  • FIGURE 1 is a vertical sectional view of a multiple anode Water heater and storage tank assembly embodying the present invention, the section being taken as indicated by the line 11 in FIG. 2;
  • FIG. 2 is a horizontal sectional view of the assembly of FIG. 1, the section being taken as indicated by the line 2-2 in FIG. 1;
  • FIG. 3 is a fragmentary, vertical sectional view of the assembly of FIG. 1, on an enlarged scale, the section being taken as indicated by the line 3-3 in FIG. 2;
  • FIG. 4 is a fragmentary elevation on an enlarged scale of the assembly of FIG. 1 taken as indicated by the line 44 in FIG. 3.
  • FIG. 5 is an enlarged, front, elevational view of an ammeter that is mounted in the assembly of FIGS. 1-3.
  • FIG. 6 is a side view of the ammeter of FIG. 4, taken as indicated by the line 6-6 of FIG. 5 (but rotated 90 for convenience), with a portion of the ammeter case broken away to show certain interior structure, the mounting panel for the ammeter also being shown in section in a position to receive the ammeter and being shown in phantom outline with the ammeter in position to be screwed to the panel, one of a pair of mounting screws for this purpose also being shown.
  • FIG. 7 is a view similar to FIG. 6, but with the ammeter moved into its mounted position in theaperture of the mounting panel.
  • FIG. 8 is a fragmentary, vertical sectional view,-on an enlarged scale, of the structure for mounting of the upper end of an anode on thetop wall of the tank in the assem bly of FIGS. 1-3, the plane of the section being taken as indicated by the line 88 in-FIG. 2;
  • FIG. 9 is a vertical sect-ion'alview of a modified em- 7 bodiment of the invention in which a single anode is mounted in a water heater tank, the tank jacket and heating mechanism being omitted for simplicity;
  • FIG; 10 is an enlarged fragmentary view, in vertical supported on three legs 18 (only two being shown) be tween which a drip tray 19 may be mounted.
  • a combustion zone 21 above the burner 17 is surrounded by a lower are secured.
  • a collection zone 23 for combustion products is surrounded by an upper extension 24 of the tank side wall.
  • the top wall 14 of the tank forms the bottom of the collection zone, and an apertured plate 26 forms the top wall of the collection zone.
  • Hot, gaseous, combustion products from the burner 17 pam from the combustion zone 21, upwardly through four header conduits 27, and into the collection zone 23, from where they pass out of the apparatus through a flue pipe 28 communicating with the central aperture of the plate 26.
  • each anode 30 is preferably a rod of magnesium alloy for use in a lined or unlined tank It ⁇ of steel, galvanized steel, aluminum, or other metal or alloy to which the magnesium alloy is anodic.
  • each magnesium anode 30 is preferably formed around a core wire 31 which extends from top to bottom through the magnesium alloy rod in surface-to-surface electrical contact therewith.
  • the core wire should be of a metal that is more noble than the metal of the anode. It may suitably be steel or aluminum, for example.
  • each anode is of reduced diameter and is externally threaded, leaving an annular shoulder 33 for engagement by an annular washer 34 of electrically insulating material surrounding the upper end 32 of the anode.
  • the threaded upper end 32 of the anode is screwed into an internally threaded insulating sleeve 36 molded and retained by a flange 37 in the bore of a fitting 38 having an enlarged head 39 shaped to be turned by a wrench.
  • the thickness of the sleeve 36 is sufficient to leave a substantial clearance space 35 between the flange 37 and the anode.
  • the cap 38 is screwed onto the anode until the flange 36 thereof engages and compresses the washer 34 to provide a watertight seal and thereby support the anode insulated therefrom by the washer 34, air space 35, and sleeve 36.
  • the cap 38 which may be provided with a sealing washer 40, if desired, is externally threaded and screwed into an internally threaded ring 41 projecting snugly through an aperture in the top wall 14 of the tank and having an outer flange 42 engaging the top wall of the tank about the aperture therethrough.
  • a watertight joint between the ring 41 and the top wall of the tank is provided by an external and an internal peripheral weld as indicated in FIG. 8.
  • the cap 38' with an anode 30 threaded therein, may be mounted as described and removed for replacement of the anode when needed. Also, the anode may thus be suspended by its upper end from the top wall 14 of the tank while being electrically insulated therefrom. Each anode 39 is mounted as described.
  • the current flowing through the ammeter 47 is then carried by a second low resistance conductor 48 from a secondterminal of the ammeter to a low resistanceconnector plug 49 (suitably made of brass and insulated from the tank 10 as V hereinafter described), and thence through the plug 49 to the inside of the tank, at which point the current is divided 'betwen three parallel, low resistance conductors 50 that respectively connect the plug 49 to the core wire 31 at the lower ends of the three anodes 3%.
  • a closed metallic circuit is provided for the galvanic current from the anodes 30 through the water in the tank to the tank itself, from the tank through the ammeter 47,
  • the ammeter 47 constantly registers the total galvanic current from the three anodes 30 to the tank 10.
  • the conductor 44 from the tank to the ammeter 47 may be permanently soldered at one end to its ammeter terminal and be soldered at its opposite end to a pushin connector or the like adapted to be removably snapped into a socket in the tank contact.
  • the conductor 48 from the ammeter may be permanently soldered at one end to its ammeter terminal and be soldered at its opposite end to a push-in connector or the like adapted to be removably snapped into the plug 49.
  • the three conductors 50 from the plug 49 to the anodes 30 may be permanently soldered to the lower ends of the three anodes, respectively.
  • the opposite ends of these conductors may have push-in connectors or the like soldered thereto and adapted to be removably snapped into sockets in the inner end of the plug 49.
  • Access to the interior of the shell 11 and to the interior of the tank 10, for purposes of initial assembly of the electrical circuit and for service incident to the replacement of anodes, may be provided through access openings that are normally closed by a shell closure plate 51 and a tank closure plate 61.
  • the shell closure plate 51 is preferably also used as a mounting panel for the ammeter 47 and may be secured in place by a plurality of rigid hooks and spring clips.
  • the rigid hooks may include two or more S shaped members 52 (only one being shown) distributed along and welded to the inner surface of the closure plate 51 and hooked over the lower edge of the opening in the shell 11.
  • the spring clips preferably include two clips 53 spaced apart a few inches along, and welded to, the inner surface of the closure plate 51, as shown in FIG. 4.
  • the clips 53 may be of a cam actuated type which will be cammed downwardly when pressed inwardly against the upper edge of the opening in the shell 11, and which will then snap back to lock the closure plate firmly in place, as shown in FIG. 3, so as to resist prying this closure plate off from the outside.
  • To remove this closure plate it will then be necessary first to remove the a'mmeter 47 by removing its mounting screws 54, the purpose of this being explained hereinafter. Then one may reach through the opening in the closure plate 51 and forcibly pull the clips 53 downwardly against their spring action, while also pulling outwardly on the upper portion of the closure plate 51, to tilt the plate outwardly until the clips 53 are disengaged. Thereupon the closure plate can be lifted upwardly and outwardly to disengage the hooks 52 and free the closure plate for removal.
  • a thickening and stiffening bar 55 may be welded along the upper edge of the access opening in the shell 11 if desired.
  • the tank closure plate 61 may be removably mounted on a flange 62 about the tank access opening by a suitable number of bolts 63 (two being shown), with an electrically insulating gasket plate 64 disposed between the closure plate and the mounting flange and covering the inner surface of the closure plate.
  • the plug 49 is mounted in the tank closure plate 61 and is electrically insulated therefrom. As shown in FIG. 3, an opening through this closure plate may be lined with an electrically insulating gasket sleeve 66. If desired, the gaskets 64 and 66 may be integral and be molded onto the closure plate.
  • the plug 49' may be externally threaded and have an outer head adapted to overlie and seal against an outer flange on the gasket sleeve 66, and it may be secured in place by an internal nut overlying and sealing against the gasket plate 64. In this manner water leakage around the plug 49 may be reliably prevented while also electrically insulating the plug 49 from the closure plate 61 and from the tank 10. Also, initial assembly and disassembly for servicing may readily be accomplished in an obvious manner.
  • the ammeter 47 for the purposes of the present invention, preferably has a non-linear response to variations in current where a needle type indicator is used.
  • the lower third of the scale (designated A in FIG. 5) may cover the range from O to only 20 milliamperes and the upper two-thirds of the scale (divided into parts designated B and C in FIG. 5) may cover the range from 20 to 120 milliamperes.
  • the upper two-thirds of the scale (divided into parts designated B and C in FIG. 5) may cover the range from 20 to 120 milliamperes.
  • the maximum galvanic current may be limited by the resistance of the circuit to about milliamperes (corresponding to about 2.0 milliamperes per square foot of tank surface), and the desirable minimum current may be about 55 milliamperes (corresponding to about 1 ma./ sq. ft. of tank surface).
  • This range may be that represented by the segment C of the scale in FIG. -5 and be the desired operating range.
  • the segment B may cover a range down to about 20 milliamperes (corresponding to about 0.4 ma./sq. ft. of tank surface) representing a danger point below which the current must not be permitted to drop. It is contemplated that this may be made a condition in the manufacturers warranty.
  • the range represented by the segment A of the scale in FIG. 5 will then drop from 20 milliamperes to zero.
  • the ammeter 47 is provided with means for blocking movement of an indicator needle 70 in either direction past the division line between segments A and B of the scale on the ammeter dial or face 71 when the ammeter has been demounted from its mounting panel.
  • This means may comprise an elongated leaf spring 72 having one end welded or otherwise secured against the back side of a mounting flange 73 of the ammeter case, as best shown in FIG. 6.
  • the spring is normally biased to extend at an angle away from the back side of the flange 73 on which it is mounted, and to extend inwardly into the ammeter case 74 through an aperture 75.
  • the opposite end of the spring 72 may have a small diameter wire 76 soldered thereto and extending transversely therefrom through a small aperture 77 in the ammeter dial or face 71.
  • the wire 76 may project in a straight line through the ammeter dial 71 and beyond the plane in which the needle 70 swings; then be bent approximately through a right angle so as to extend generally parallel to the dial 71 to a point directly opposite the division line on the dial between segments A and B of the ammeter scale; -and then be bent again approximately through a right angle to provide a free end portion extending toward the dial and into the path of the needle 70 at the division line between scale segments A and B.
  • the free end portion of the wire 76 when the ammeter is demounted, will provide an obstruction to movement of the needle 70 in either direction past the division line between scale segments A and B.
  • the panel engages the leaf spring 72, depresses it against the flange 73 of the ammeter case, and moves the wire 76 to shift its free end portion out of the path of the needle 70.
  • the needle obstructing mechanism just described will hold the needle 70 on either the high or low side of the division line between scale segments A and B when the arnsmeter is demounted, according to where the needle was at the time of demount-ing.
  • the method of utilizing the described needle-blocking mechanism is as follows:
  • the customer using the water heater and storage tank may be instructed that anodes must be replaced when the needle 70 of the ammeter has moved from scale zone C into scale zone B and before it reaches scale zone A on the ammeter dial.
  • the instructions for replacing anodes may specify that the first step in replacing anodes after draining the tank 11) is to demount the ammeter 47 While it is still electrically connected in the anode circuit. This releases the leaf spring 72 and traps the needle on the high or low side of the division line between-scale segments A and B.
  • the instructions may specify, as the next steps, that the conductors 44 and 48 be disconnected from the tank and from the plug 49 so as to free the ammeter for return to the manufacturer for inspection, the closure plate 61 be removed, the anode wires 50- be disconnected from the plug 49, and the anodes 30 be removed from the tank for replacement.
  • the manufacturers warranty of the tank 10 may be conditioned upon timely replacement of anodes and upon compliance with his service instructions.
  • the ammeter 47 By mounting the ammeter 47 on the shell closure plate 51 and locking the shell closure plate onto the shell as shown in the drawing and described above, the prescribed order of steps can be reasonably assured.
  • the ammeter must be removed before the closure plate 51 can be removed or anything done to break the anode circuit, thus trapping the ammeter needle and showing whether or not the galvanic current had first dropped below the critical danger point.
  • the manufacturer can be reasonably sure that he receives a correct indication of whether or not the customer broke a condition of the manufacturers warranty by delaying too long before replacing the old anodes. With this protection, the tank manufacturer may advantageously guarantee a longer life for his tanks and educate his customers to use care in the maintenance of the tanks, with consequent advantages to both.
  • FIGS. 9 and 10 illustrate a modified embodiment of the invention which is particularly suitable for relatively small tanks in which a single anode provides sufficient tank protection.
  • a single anode provides sufficient tank protection.
  • no outer tank shell or burner, etc. have been shown, and the connection of an ammeter A into the anode circuit has been shown somewhat diagrammatically. It is to be understood, however, that the ammeter should be suitably mounted and connected as a part of the complete assembly, as in FIGS. 1-3', by utilizing any suitable ammeter mounting structure.
  • the ammeter A is provided with a mechanism for holding or blocking the ammeter indicator, such as that illustrated in FIGS. 7, for holding the indicator on one side or the other of a scale point separating a safe current range from an unsafe one.
  • FIGS. 9 The principal purpose of FIGS. 9 and is to illustrate a modified construction for supporting an anode and'connecting it electrically to the ammeter without running conductor wires inside the tank.
  • a tank 80 may have an inwardly directed flange 81 about an opening through the top wall thereof, and an anode-supporting fitting 82 may be removably threaded into the flange 81 with an anode 84 depending from the fitting.
  • the connection between the anode 84 and fitting 82 is shown in vertical section in FIG. 10.
  • the fitting 82 may have a longitudinal bore of large diameter over its lower portion with an inwardly directed, annular, sleeve-retaining flange 86 about the lower end of this bore.
  • An electrically insulating and sealing sleeve 87 is formed in this bore, as by molding it therein, the sleeve being substantially thicker than the retaining flange 86 and being internally threaded.
  • a reduced diameter upper end portion 88 of the anode 84 is externally threaded and provides a shoulder 39 for seating an electrically insulating and sealing washer 91.
  • the upper end portion 88 of the anode is screwed into the sleeve 87 so as to be supported thereby in physically spaced relationship with the fitting 82, while compressing the washer 91 between the shoulder 89 of the anode and the sleeve-retaining flange 86 of the fitting.
  • the anode is insulated from the fitting 82 and from the tank 89 and leakage around the anode is prevented by two electrically insulating seals made by the sleeve 87 and the washer 91.
  • the upper portion of the fitting 82 may have a bore of smaller diameter therethrough and be internally threaded to receive a plug 92.
  • the lower end portion of the plug 92 may have a hollow bore lined with an elastic insulating sleeve 93.
  • a metal sleeve 94 is forced into the elastic sleeve 93 to compress it radially and hold both of the sleeves 93 and 94 in place in the plug 92.
  • the central portion of the plug 92 may have a hollow bore of slightly reduced diameter for receiving a resistor 96 of appropriate electrical resistance.
  • the upper end portion of the plug 92 may have a still smaller bore therethrough for an insulated electrical conductor 97 that is connected to one terminal of the resistor 96 and passes out of the upper end of the plug 92.
  • the opposite end of the resistor 96 is connected to an electrical conductor 98 that projects through and slightly beyond the lower end of the metal sleeve 94 and is soldered thereto by a button of solder 99 constituting a second terminal for the resistor that is electrically insulated from the plug 92 by the insulating sleeve 93.
  • a core wire 101 in the anode 84 preferably projects upwardly a short distance beyond the upper end of the anode for positioning a helical spring 102, of low electrical resistance, in spaced relationship with the inner walls of the metal fitting 82.
  • the resistor 96 is preassembled in the plug 92 by inserting it into the lower end of the plug with its conductors 97 and 98 attached, and then inserting the insulating sleeve 93 and metal sleeve 94. Thereupon the solder button 99 is applied to complete this preassembled unit. If desired, the upper end'of this assembly may be closed about the conductor 97 by filling the cavity in the plug 92 above the resistor 96 with a sealing wax or the like (not shown). Such preassembled units may be made and stocked with diifer'ent resistors mounted therein, units having the proper resistance being selected for installation to limit the maximum galvanic current as required by waters of different electrical conductivity.
  • the resistance of the resistor 96 may desirably be virtually zero, and the resistor may function strictly as a conductor; or the resistor 96 and conductor 98 may be eliminated and the conductor 97 connected directly to the solder button 99.
  • the insulated conductor 97 is connected through an easily replaceable resistor 96 to the anode 84.
  • a galvanic circuit is completed with the metallic connections of the ammeter to the tank and to the anode being entirely accessible from outside the tank and sealed from direct contact with the water in the tank.
  • FIGS. 9 and 10 may be used in multiple anode tanks, if desired, and is particularly useful in any installation where it is considered advantageous to dispense with an access opening into the tank.
  • the general arrangement of FIGS. 1-8 may be used for a single anode installation, as well as for a multiple anode installation utilizing any desired number of anodes.
  • a method of aflording a continuous galvanic protection to the interior surfaces of a metal water storage tank during use of said tank comprising the steps of mounting within a metal water storage tank a sacrificial metal anode that is anodic with respect to the metal of the interior of said tank, mounting on said tank an ammeter having a current responsive indicator movable along a path of travel in proportion to the current passing through the ammeter over the current range to which the ammeter is responsive, electrically connecting said ammeter in series relation between said tank and said anode so that movement of said indicator along its path of travel will indicate the progressive stages of decomposition of said anode, providing said ammeter with stop means operative when said ammeter is demounted from said tank to hold said indicator against movement past a location along its path of travel corresponding to a predetermined minimum galvanic current, and demounting said ammeter from said tank to render said step means operative before electrically disconnecting it for replacement of said anode.
  • a method of affording galvanic protection of the interior surfaces of a metal water storage tank during the use of said tank comprising the steps of mounting within a metal water storage tank a sacrificial metal anode that is anodic with respect to the metal of the interior of said tank, detachably mounting on the exterior of said tank an ammeter having an indicator movable along a path of travel in proportion to the current passing through the ammeter over the current range to which the ammeter is normally responsive, electrically connecting said ammeter inseries relation between said tank and said anode so that movement of said indicator along its path of travel will indicate progressive stages of decomposition of said anode, blocking movement of said indicator in either direction past a predetermined location in its path of travel when demounting said ammeter from said tank, electrically disconnecting said ammeter, and replacing said anode.
  • a water storage tank assembly comprising a metal water storage tank and a sacrificial metal anode within the tank that is anodic with respect to the metal of the interior of the tank, the combination therewith of: means mounting the anode on the wall of the tank, said mounting means including means electrically insulating the anode from the tank, an ammeter mounted on the exterior of the tank and including a current responsive indicator mounted for movement along a path of travel in proportion to the current passing through the ammeter over a current range to which the ammeter is normally responsive, conductors electrically connecting the ammeter in series between the tank and the anode, and means mounted on the ammeter and operative when the ammeter is demounted from the tank for restraining movement of said indicator past a point corresponding to a predetermined minimum galvanic current.
  • a water storage tank assembly comprising a metal water storage tank and a sacrificial anode within the tank that is anodic with respect to the metal of the interior of the tank, the combination therewith of: means mounting the anode on a wall of the tank, said mounting means including means electrically insulating the anode from the tank, an ammeter mounted on the exterior of the tank and including a current responsive indicator mounted for movement along a path of travel in proportion to the current passing through the ammeter over the current range to which the ammeter is normally responsive, electrical conductors connecting the ammeter in series between the tank and the anode, and means mounted on the ammeter for movement into the path of travel of said indicator at a predetermined location in said path in response to demounting the ammeter from said tank for blocking movement of the indicator past said location in either direction.
  • a water storage tank assembly comprising a metal water storage tank and a sacrificial metal anode within the tank that is anodic with respect to the metal of the interior of the tank, the combination therewith of: means mounting the anode on the wall of the tank, said mounting means including means electrically insulating the anode from the tank, an ammeter mounted on the exterior of the tank and including a current-responsive indicator mounted for movement along a path of travel in proportion to the current passing through the ammeter over the current range to which the ammeter is normally respon sive, electrical conductors connecting the ammeter in series between the tank and the anode and stop means mounted on the ammeter for normally blocking movement of said indicator past a predetermined location along its path of travel in either direction, said stop means including means responsive to mounting engagement of said ammeter with said tank for rendering said stop means inoperative.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Prevention Of Electric Corrosion (AREA)

Description

June 5, 1962 L. F. VlXLER 3,037,920
INDICATOR SYSTEM FOR SACRIFICIAL ANODES Filed May 26, 1958 3 Sheets-Sheet l FIG I v I 5l\ E 28 A 63 1 26 1 54 x 55 44 I 3 'L L g I 03 J u N INVENTOR.
LESLIE F VIXLER ATTORNEYS June 5, 1962 F. VIXLER 3,037,920
INDICATOR SYSTEM FOR SACRIFICIAL ANODES Filed May 26, 1958 5 Sheets-Sheet 2 1 M 73 76 i f MW u i! l INVENTOR.
LESLIE F VIXLER BY??? AQMMVJMM ATTORNEYS L. F. VIXLER 3,037,920-
INDICATOR SYSTEM FOR SACRIFICIAL ANODES v June 5, 1962 3 Sheets-Sheet 3 Filed May 26, 1958 INVENTOR.
ATTORNEYS BYLESL/E F V/XLER FIG 8 FIG. 9
United States Patent Ofifice 3,037,920 Patented June 5, 1962 Ohio Filed May 26, 1958, Ser. No. 737,572 5 Claims. (Cl. 204-148) This invention relates to hot water heater and storage tanks in which a so-called sacrificial anode is employed to protect the interior surfaces of the tank from corrosion by galvanic action between the anode and the tank. The invention is directed to methods and apparatus for controlling the galvanic action and for indicating the condition of the anode during its active life.
More particularly, the invention relates to new tank and anode assemblies including an indicator for visually showing the galvanic activity of an anode in the tank while the assembly is in use and, optionally, also including an additional electrical resistance element in the metallic portion of the electrical circuit for limiting the galvanic current flow, according to the conductivity of the water, to a current value no greater than that required to protect the tank from internal corrosion. The invention also relates to special ammeters and their use in connection with the tank and anode assemblies and to improve anode mounting structures particularly adapted for use where an ammeter is included in the metallic portion of the electrical circuit.
In accordance with common practice, galvanic protection of the interior metal surfaces of hot water heater and storage tanks may be accomplished by mounting inside the tank, a metal element that is anodic, i.e., more electropositive or less noble, relative to the interior metal surface of the tank, and that is termed an anode or sacrificial anode. This anode is electrically connected to the tank by a metallic circuit of relatively low electrical resistance, conventionally by a direct metallic connector by which the anode is suspended in the tank. When the tank is full of water, the anode is also electrically connected to the interior surface of the tank through the water, which connection provides much greater resistance to the flow of electrical current therethrough than does the metallic circuit. Since the anode is electropositive relative to the interior metal surface of the tank, galvanic electrical current is induced which may be considered as flowing around a closed circuit from the anode, through the water to the interior surface of the tank, and through the low resistance etallic connection from the tank back to the anode. The anode is slowly consumed by this galvanic action, whereas the interior metal surface of the tank is protected from corrosion thereby, the consumed metal of the anode forming a reaction product with dissolved material in the water, which reaction product generally is quite insoluble and is largely deposited on the walls of the tank to which the galvanic current flows.
Because the tank is protected at the expense of the anode, the anode is commonly referred to as a sacrificial anode, as noted above. When the anode is entirely consumed as described, galvanic protection of the tank ceases, and the anode must be replaced before this occurs if continuing protection of the tank is to be maintained. However, the anode is normally not visible, and its condition is normally determinable only by emptying the tank and removing the anode for inspection. This is troublesome and is often reglected, resulting in premature tank failures from internal corrosion.
Depending upon the electrical conductivity of the water in the tank, the galvanic current flowing through the anodetank circuit may be greater than needed to provide adequate tank protection, or it may be less than needed for 7 above.
this purpose. If the galvanic current is greater than needed, the rate of anode consumption is excessive, and some convenient means for reducing the current induced by a given tank and anode assembly is desirable in order to prolong the life of the anode. If the galvanic current is less than needed, the only remedy is to alter the anode arrangement so as to increase the anode surface area, as by using an anode having a larger surface or by using more than one anode to achieve the same effect.
Since the character of water supplies throughout the country varies over a considerable range, there has long been a need for a convenient way in which to control, at least to a susbtantial degree, the galvanic currents induced by waters of different conductivity. This is required in some instances to maintain a high enough current for adequate tank protection, but is generally desired to prevent excessive current and rate of anode deterioration.
The use of a plurality of anodes has the advantage of enabling the anode surfaces to be better distributed as regards their spacing from welded joints and other critical portions of the tank interior where corrosion tends to be concentrated, since the current flowing to various points on the tank interior varies inversely with the length (resistance) of the water path from those critical points on the tank surface to the nearest anode surface. This consideration makes it desirable in some cases, particularly in large diameter tanks, to employ a plurality of anodes even though the resulting total galvanic current, and consequent rate of anode consumption, becomes much greater than necessary. This accentuates the need for a convenient way in which to control the total galvanic currents induced in a given apparatus by waters of varying conductivity.
Particularly in the case of large and expensive, industrial water tanks designed to last for many years, when suitably protected, the above considerations make it important not only to limit the galvanic current induced so as to secure maximum anode life, but also to facilitate determining when anodes in the tanks have been consumed to the point where they should be replaced. These problems have an important bearing on the ability of water tank manufacturers to guarantee the life of their product, since the life will depend upon the rate of anode deterioration and the diligence of the customer in promptly replacing consumed anodes. Also, the manufacturer normally has no way of knowing how long a customers tank may have been neglected and retained in use after the anodes have been consumed to the point where protection of the tank is inadequate. Thus, tank life guarantees have generally been limited to a period of time not greatly exceeding the expected effective life of the anode or anodes contained in a tank at the time of its original installation.
The objects of the present invention are to provide improved tank and anode assemblies which either eliminate or, at least, reduce each of the problems discussed More specifically, the objects of the invention are: to provide convenient means for limiting the galvanic current so as to permit greater flexibility of tankanode designs for obtaining maximum tank protection without an excessive rate of anode consumption; to provide simple and reliable means for indicating the condition of an anode or set of anodes in a tank while the tank is in use; and to provide means associated with the electrical circuit of a tank-anode assembly which will enable the tank manufacturer to determine whether or not his customer has permitted the tank to remain in use after the protective galvanic current (due to anode consumption) has dropped below a safe value, whereby the manufacturer may safely offer longer guarantees of tank life conditioned upon proper maintenance of anodes by his customers.
In accomplishing the foregoing objectives, greater tank life at minimum original cost may be assured, accidental neglect causing premature tank failures may be more easily avoided, and neglect as acause of premature tank failures may be more readily detected.
' These objects and advantages of the invention are accomplished in accordance with the inventionrby providing a resistor element in the galvanic circuit having an electrical resistance selected to maintain the proper galvanic current, the resistor elementpreferably being interchangeable with similar elements of different resistance values; by providing an ammeter in the galvanic circuit which will continuously indicate the magnitude of the galvanic current and thereby show when replacement of anodes is required; and by providing a special ammeter for the above purpose which, once the galvanic current has dropped below a safe minimum on which a tank life guarantee may be based, will provide the manufacturer with knowledge of this fact and of the fact that the customers own neglect has voided the guarantee.
The foregoing objects, advantages, and features of the invention and presently preferred embodiments thereof will be more fully understood from the following detailed description of such embodiments of the invention, and from the accompanying drawings in which:
FIGURE 1 is a vertical sectional view of a multiple anode Water heater and storage tank assembly embodying the present invention, the section being taken as indicated by the line 11 in FIG. 2;
FIG. 2 is a horizontal sectional view of the assembly of FIG. 1, the section being taken as indicated by the line 2-2 in FIG. 1;
FIG. 3 is a fragmentary, vertical sectional view of the assembly of FIG. 1, on an enlarged scale, the section being taken as indicated by the line 3-3 in FIG. 2;
FIG. 4 is a fragmentary elevation on an enlarged scale of the assembly of FIG. 1 taken as indicated by the line 44 in FIG. 3.
FIG. 5 is an enlarged, front, elevational view of an ammeter that is mounted in the assembly of FIGS. 1-3.
FIG. 6 is a side view of the ammeter of FIG. 4, taken as indicated by the line 6-6 of FIG. 5 (but rotated 90 for convenience), with a portion of the ammeter case broken away to show certain interior structure, the mounting panel for the ammeter also being shown in section in a position to receive the ammeter and being shown in phantom outline with the ammeter in position to be screwed to the panel, one of a pair of mounting screws for this purpose also being shown.
FIG. 7 is a view similar to FIG. 6, but with the ammeter moved into its mounted position in theaperture of the mounting panel.
FIG. 8 is a fragmentary, vertical sectional view,-on an enlarged scale, of the structure for mounting of the upper end of an anode on thetop wall of the tank in the assem bly of FIGS. 1-3, the plane of the section being taken as indicated by the line 88 in-FIG. 2;
FIG. 9 is a vertical sect-ion'alview of a modified em- 7 bodiment of the invention in which a single anode is mounted in a water heater tank, the tank jacket and heating mechanism being omitted for simplicity; and
FIG; 10 is an enlarged fragmentary view, in vertical supported on three legs 18 (only two being shown) be tween which a drip tray 19 may be mounted. A combustion zone 21 above the burner 17 is surrounded by a lower are secured.
A collection zone 23 for combustion products is surrounded by an upper extension 24 of the tank side wall. The top wall 14 of the tank forms the bottom of the collection zone, and an apertured plate 26 forms the top wall of the collection zone. Hot, gaseous, combustion products from the burner 17 pam from the combustion zone 21, upwardly through four header conduits 27, and into the collection zone 23, from where they pass out of the apparatus through a flue pipe 28 communicating with the central aperture of the plate 26.
Inside the tank 10 are mounted three sacrificial anodes 30 of identical design. Each anode 30 is preferably a rod of magnesium alloy for use in a lined or unlined tank It} of steel, galvanized steel, aluminum, or other metal or alloy to which the magnesium alloy is anodic. Referrin g to FIG. 8, as well as to FIGJI, each magnesium anode 30 is preferably formed around a core wire 31 which extends from top to bottom through the magnesium alloy rod in surface-to-surface electrical contact therewith.
The core wire should be of a metal that is more noble than the metal of the anode. It may suitably be steel or aluminum, for example.
The upper end 32 of each anode is of reduced diameter and is externally threaded, leaving an annular shoulder 33 for engagement by an annular washer 34 of electrically insulating material surrounding the upper end 32 of the anode. The threaded upper end 32 of the anode is screwed into an internally threaded insulating sleeve 36 molded and retained by a flange 37 in the bore of a fitting 38 having an enlarged head 39 shaped to be turned by a wrench. The thickness of the sleeve 36 is sufficient to leave a substantial clearance space 35 between the flange 37 and the anode.
The cap 38 is screwed onto the anode until the flange 36 thereof engages and compresses the washer 34 to provide a watertight seal and thereby support the anode insulated therefrom by the washer 34, air space 35, and sleeve 36. The cap 38, which may be provided with a sealing washer 40, if desired, is externally threaded and screwed into an internally threaded ring 41 projecting snugly through an aperture in the top wall 14 of the tank and having an outer flange 42 engaging the top wall of the tank about the aperture therethrough. A watertight joint between the ring 41 and the top wall of the tank is provided by an external and an internal peripheral weld as indicated in FIG. 8.
As will be apparent, the cap 38', with an anode 30 threaded therein, may be mounted as described and removed for replacement of the anode when needed. Also, the anode may thus be suspended by its upper end from the top wall 14 of the tank while being electrically insulated therefrom. Each anode 39 is mounted as described.
Electrical contact between the anodes 30 and the tank 10, of course, is maintained by the water in the tank, which constitutes an electrolyte normally having a relatively high resistance. The galvanic current flowing from the anodes to the tank through the water in the tank is carried by a low resistance conductor 44 (FIG. 3) con necting a tank contact 46 to one terminal of an ammeter 47 mounted externally of the tank 10. The current flowing through the ammeter 47 is then carried by a second low resistance conductor 48 from a secondterminal of the ammeter to a low resistanceconnector plug 49 (suitably made of brass and insulated from the tank 10 as V hereinafter described), and thence through the plug 49 to the inside of the tank, at which point the current is divided 'betwen three parallel, low resistance conductors 50 that respectively connect the plug 49 to the core wire 31 at the lower ends of the three anodes 3%. Thus, a closed metallic circuit is provided for the galvanic current from the anodes 30 through the water in the tank to the tank itself, from the tank through the ammeter 47,
and back to the anodes through the plug 49. As a result, the ammeter 47 constantly registers the total galvanic current from the three anodes 30 to the tank 10.
The conductor 44 from the tank to the ammeter 47 may be permanently soldered at one end to its ammeter terminal and be soldered at its opposite end to a pushin connector or the like adapted to be removably snapped into a socket in the tank contact. The conductor 48 from the ammeter may be permanently soldered at one end to its ammeter terminal and be soldered at its opposite end to a push-in connector or the like adapted to be removably snapped into the plug 49. The three conductors 50 from the plug 49 to the anodes 30 may be permanently soldered to the lower ends of the three anodes, respectively. The opposite ends of these conductors may have push-in connectors or the like soldered thereto and adapted to be removably snapped into sockets in the inner end of the plug 49.
Access to the interior of the shell 11 and to the interior of the tank 10, for purposes of initial assembly of the electrical circuit and for service incident to the replacement of anodes, may be provided through access openings that are normally closed by a shell closure plate 51 and a tank closure plate 61. The shell closure plate 51 is preferably also used as a mounting panel for the ammeter 47 and may be secured in place by a plurality of rigid hooks and spring clips. The rigid hooks may include two or more S shaped members 52 (only one being shown) distributed along and welded to the inner surface of the closure plate 51 and hooked over the lower edge of the opening in the shell 11. The spring clips preferably include two clips 53 spaced apart a few inches along, and welded to, the inner surface of the closure plate 51, as shown in FIG. 4. The clips 53 may be of a cam actuated type which will be cammed downwardly when pressed inwardly against the upper edge of the opening in the shell 11, and which will then snap back to lock the closure plate firmly in place, as shown in FIG. 3, so as to resist prying this closure plate off from the outside. To remove this closure plate, it will then be necessary first to remove the a'mmeter 47 by removing its mounting screws 54, the purpose of this being explained hereinafter. Then one may reach through the opening in the closure plate 51 and forcibly pull the clips 53 downwardly against their spring action, while also pulling outwardly on the upper portion of the closure plate 51, to tilt the plate outwardly until the clips 53 are disengaged. Thereupon the closure plate can be lifted upwardly and outwardly to disengage the hooks 52 and free the closure plate for removal. A thickening and stiffening bar 55 may be welded along the upper edge of the access opening in the shell 11 if desired.
The tank closure plate 61 may be removably mounted on a flange 62 about the tank access opening by a suitable number of bolts 63 (two being shown), with an electrically insulating gasket plate 64 disposed between the closure plate and the mounting flange and covering the inner surface of the closure plate.
The plug 49 is mounted in the tank closure plate 61 and is electrically insulated therefrom. As shown in FIG. 3, an opening through this closure plate may be lined with an electrically insulating gasket sleeve 66. If desired, the gaskets 64 and 66 may be integral and be molded onto the closure plate. The plug 49' may be externally threaded and have an outer head adapted to overlie and seal against an outer flange on the gasket sleeve 66, and it may be secured in place by an internal nut overlying and sealing against the gasket plate 64. In this manner water leakage around the plug 49 may be reliably prevented while also electrically insulating the plug 49 from the closure plate 61 and from the tank 10. Also, initial assembly and disassembly for servicing may readily be accomplished in an obvious manner.
In order to limit the galvanic current to a suitable value for adequate tank protection, it may be desirable to increase the resistance of the metallic conductor portion of the closed galvanic current circuit. This may readily be done by using an ammeter having a high enough internal resistance for this purpose. Alternatively, additional resistance may be inserted at any desired point in this part of the circuit in series with the ammeter.
The ammeter 47, for the purposes of the present invention, preferably has a non-linear response to variations in current where a needle type indicator is used. For example, the lower third of the scale (designated A in FIG. 5) may cover the range from O to only 20 milliamperes and the upper two-thirds of the scale (divided into parts designated B and C in FIG. 5) may cover the range from 20 to 120 milliamperes. For a tank and anode arrangement of the type illustrated in FIGS. 1-3, having, for example, about 55 square feet of exposed galvanized steel tank surface, the maximum galvanic current may be limited by the resistance of the circuit to about milliamperes (corresponding to about 2.0 milliamperes per square foot of tank surface), and the desirable minimum current may be about 55 milliamperes (corresponding to about 1 ma./ sq. ft. of tank surface). This range may be that represented by the segment C of the scale in FIG. -5 and be the desired operating range. The segment B may cover a range down to about 20 milliamperes (corresponding to about 0.4 ma./sq. ft. of tank surface) representing a danger point below which the current must not be permitted to drop. It is contemplated that this may be made a condition in the manufacturers warranty. The range represented by the segment A of the scale in FIG. 5 will then drop from 20 milliamperes to zero.
Accordingly, an ammeter reading dropping into the range of zone A is an occurrence which the manufacturer will wish to be informed of so that he will know that he has been relieved of responsibility under his warranty by the neglect of the customer. To this end, the ammeter 47 is provided with means for blocking movement of an indicator needle 70 in either direction past the division line between segments A and B of the scale on the ammeter dial or face 71 when the ammeter has been demounted from its mounting panel. This means may comprise an elongated leaf spring 72 having one end welded or otherwise secured against the back side of a mounting flange 73 of the ammeter case, as best shown in FIG. 6. As shown, the spring is normally biased to extend at an angle away from the back side of the flange 73 on which it is mounted, and to extend inwardly into the ammeter case 74 through an aperture 75. The opposite end of the spring 72 may have a small diameter wire 76 soldered thereto and extending transversely therefrom through a small aperture 77 in the ammeter dial or face 71. The wire 76 may project in a straight line through the ammeter dial 71 and beyond the plane in which the needle 70 swings; then be bent approximately through a right angle so as to extend generally parallel to the dial 71 to a point directly opposite the division line on the dial between segments A and B of the ammeter scale; -and then be bent again approximately through a right angle to provide a free end portion extending toward the dial and into the path of the needle 70 at the division line between scale segments A and B.
As will be apparent from the foregoing, the free end portion of the wire 76, when the ammeter is demounted, will provide an obstruction to movement of the needle 70 in either direction past the division line between scale segments A and B. However, when the ammeter is mounted on its mounting panel 51, as shown in FIG. 7, the panel engages the leaf spring 72, depresses it against the flange 73 of the ammeter case, and moves the wire 76 to shift its free end portion out of the path of the needle 70. When the ammeter is demounted again, the
wire 76 will again move into the path of the needle 70. Thus, the needle obstructing mechanism just described will hold the needle 70 on either the high or low side of the division line between scale segments A and B when the arnsmeter is demounted, according to where the needle was at the time of demount-ing.
The method of utilizing the described needle-blocking mechanism is as follows: The customer using the water heater and storage tank may be instructed that anodes must be replaced when the needle 70 of the ammeter has moved from scale zone C into scale zone B and before it reaches scale zone A on the ammeter dial. The instructions for replacing anodes may specify that the first step in replacing anodes after draining the tank 11) is to demount the ammeter 47 While it is still electrically connected in the anode circuit. This releases the leaf spring 72 and traps the needle on the high or low side of the division line between-scale segments A and B. The instructions may specify, as the next steps, that the conductors 44 and 48 be disconnected from the tank and from the plug 49 so as to free the ammeter for return to the manufacturer for inspection, the closure plate 61 be removed, the anode wires 50- be disconnected from the plug 49, and the anodes 30 be removed from the tank for replacement. The manufacturers warranty of the tank 10 may be conditioned upon timely replacement of anodes and upon compliance with his service instructions.
By mounting the ammeter 47 on the shell closure plate 51 and locking the shell closure plate onto the shell as shown in the drawing and described above, the prescribed order of steps can be reasonably assured. The ammeter must be removed before the closure plate 51 can be removed or anything done to break the anode circuit, thus trapping the ammeter needle and showing whether or not the galvanic current had first dropped below the critical danger point. By also requiring return of the ammeter as a condition to the purchase of replacement anodes, the manufacturer can be reasonably sure that he receives a correct indication of whether or not the customer broke a condition of the manufacturers warranty by delaying too long before replacing the old anodes. With this protection, the tank manufacturer may advantageously guarantee a longer life for his tanks and educate his customers to use care in the maintenance of the tanks, with consequent advantages to both.
FIGS. 9 and 10 illustrate a modified embodiment of the invention which is particularly suitable for relatively small tanks in which a single anode provides sufficient tank protection. For simplicity, no outer tank shell or burner, etc., have been shown, and the connection of an ammeter A into the anode circuit has been shown somewhat diagrammatically. It is to be understood, however, that the ammeter should be suitably mounted and connected as a part of the complete assembly, as in FIGS. 1-3', by utilizing any suitable ammeter mounting structure.
1 Preferably, the ammeter A is provided with a mechanism for holding or blocking the ammeter indicator, such as that illustrated in FIGS. 7, for holding the indicator on one side or the other of a scale point separating a safe current range from an unsafe one. The principal purpose of FIGS. 9 and is to illustrate a modified construction for supporting an anode and'connecting it electrically to the ammeter without running conductor wires inside the tank. a a i 'As shown in FIGS. 9 and 10, a tank 80 may have an inwardly directed flange 81 about an opening through the top wall thereof, and an anode-supporting fitting 82 may be removably threaded into the flange 81 with an anode 84 depending from the fitting. The connection between the anode 84 and fitting 82 is shown in vertical section in FIG. 10. 9
Referring to FIG. 10, the fitting 82 may have a longitudinal bore of large diameter over its lower portion with an inwardly directed, annular, sleeve-retaining flange 86 about the lower end of this bore. An electrically insulating and sealing sleeve 87 is formed in this bore, as by molding it therein, the sleeve being substantially thicker than the retaining flange 86 and being internally threaded. A reduced diameter upper end portion 88 of the anode 84 is externally threaded and provides a shoulder 39 for seating an electrically insulating and sealing washer 91. The upper end portion 88 of the anode is screwed into the sleeve 87 so as to be supported thereby in physically spaced relationship with the fitting 82, while compressing the washer 91 between the shoulder 89 of the anode and the sleeve-retaining flange 86 of the fitting. Thus, the anode is insulated from the fitting 82 and from the tank 89 and leakage around the anode is prevented by two electrically insulating seals made by the sleeve 87 and the washer 91.
The upper portion of the fitting 82 may have a bore of smaller diameter therethrough and be internally threaded to receive a plug 92. The lower end portion of the plug 92 may have a hollow bore lined with an elastic insulating sleeve 93. A metal sleeve 94 is forced into the elastic sleeve 93 to compress it radially and hold both of the sleeves 93 and 94 in place in the plug 92. The central portion of the plug 92 may have a hollow bore of slightly reduced diameter for receiving a resistor 96 of appropriate electrical resistance. The upper end portion of the plug 92 may have a still smaller bore therethrough for an insulated electrical conductor 97 that is connected to one terminal of the resistor 96 and passes out of the upper end of the plug 92. The opposite end of the resistor 96 is connected to an electrical conductor 98 that projects through and slightly beyond the lower end of the metal sleeve 94 and is soldered thereto by a button of solder 99 constituting a second terminal for the resistor that is electrically insulated from the plug 92 by the insulating sleeve 93.
In this case, a core wire 101 in the anode 84 preferably projects upwardly a short distance beyond the upper end of the anode for positioning a helical spring 102, of low electrical resistance, in spaced relationship with the inner walls of the metal fitting 82. After the anode is threaded into the lower end of the fitting 82, the spring 102 is dropped into place through the upper end of the fitting, and the plug 92 is then threaded into the upper end thereof to compress the spring between the end of the anode and the solder button 99. v
The resistor 96 is preassembled in the plug 92 by inserting it into the lower end of the plug with its conductors 97 and 98 attached, and then inserting the insulating sleeve 93 and metal sleeve 94. Thereupon the solder button 99 is applied to complete this preassembled unit. If desired, the upper end'of this assembly may be closed about the conductor 97 by filling the cavity in the plug 92 above the resistor 96 with a sealing wax or the like (not shown). Such preassembled units may be made and stocked with diifer'ent resistors mounted therein, units having the proper resistance being selected for installation to limit the maximum galvanic current as required by waters of different electrical conductivity. Where the resistance of the ammeter A is high enough for this purpose, the resistance of the resistor 96 may desirably be virtually zero, and the resistor may function strictly as a conductor; or the resistor 96 and conductor 98 may be eliminated and the conductor 97 connected directly to the solder button 99.
Thus, the insulated conductor 97 is connected through an easily replaceable resistor 96 to the anode 84. By connecting the conductor 97 to one terminal of the ammeter A, and by connecting the other terminal of the ammeter through a conductor 103 to any suitable electrical contact on a wall of the tank 80, a galvanic circuit is completed with the metallic connections of the ammeter to the tank and to the anode being entirely accessible from outside the tank and sealed from direct contact with the water in the tank. a I
As will be apparent, the anode mounting structure of FIGS. 9 and 10 may be used in multiple anode tanks, if desired, and is particularly useful in any installation where it is considered advantageous to dispense with an access opening into the tank. Similarly, of course, the general arrangement of FIGS. 1-8 may be used for a single anode installation, as well as for a multiple anode installation utilizing any desired number of anodes.
From the foregoing description of illustrative embodiments of the present invention, it will be apparent that simple and effective means have been provided for achieving the various objects and advantages of the invention. It will also be apparent that many equivalents of the specific structures disclosed may be employed while utilizing the essential features and principles of the invention. Accordingly, the invention is intended to include all such equivalents.
Having described my invention. I claim:
1. A method of aflording a continuous galvanic protection to the interior surfaces of a metal water storage tank during use of said tank comprising the steps of mounting within a metal water storage tank a sacrificial metal anode that is anodic with respect to the metal of the interior of said tank, mounting on said tank an ammeter having a current responsive indicator movable along a path of travel in proportion to the current passing through the ammeter over the current range to which the ammeter is responsive, electrically connecting said ammeter in series relation between said tank and said anode so that movement of said indicator along its path of travel will indicate the progressive stages of decomposition of said anode, providing said ammeter with stop means operative when said ammeter is demounted from said tank to hold said indicator against movement past a location along its path of travel corresponding to a predetermined minimum galvanic current, and demounting said ammeter from said tank to render said step means operative before electrically disconnecting it for replacement of said anode.
2. A method of affording galvanic protection of the interior surfaces of a metal water storage tank during the use of said tank comprising the steps of mounting within a metal water storage tank a sacrificial metal anode that is anodic with respect to the metal of the interior of said tank, detachably mounting on the exterior of said tank an ammeter having an indicator movable along a path of travel in proportion to the current passing through the ammeter over the current range to which the ammeter is normally responsive, electrically connecting said ammeter inseries relation between said tank and said anode so that movement of said indicator along its path of travel will indicate progressive stages of decomposition of said anode, blocking movement of said indicator in either direction past a predetermined location in its path of travel when demounting said ammeter from said tank, electrically disconnecting said ammeter, and replacing said anode.
3. In a water storage tank assembly comprising a metal water storage tank and a sacrificial metal anode within the tank that is anodic with respect to the metal of the interior of the tank, the combination therewith of: means mounting the anode on the wall of the tank, said mounting means including means electrically insulating the anode from the tank, an ammeter mounted on the exterior of the tank and including a current responsive indicator mounted for movement along a path of travel in proportion to the current passing through the ammeter over a current range to which the ammeter is normally responsive, conductors electrically connecting the ammeter in series between the tank and the anode, and means mounted on the ammeter and operative when the ammeter is demounted from the tank for restraining movement of said indicator past a point corresponding to a predetermined minimum galvanic current.
4. In a water storage tank assembly comprising a metal water storage tank and a sacrificial anode within the tank that is anodic with respect to the metal of the interior of the tank, the combination therewith of: means mounting the anode on a wall of the tank, said mounting means including means electrically insulating the anode from the tank, an ammeter mounted on the exterior of the tank and including a current responsive indicator mounted for movement along a path of travel in proportion to the current passing through the ammeter over the current range to which the ammeter is normally responsive, electrical conductors connecting the ammeter in series between the tank and the anode, and means mounted on the ammeter for movement into the path of travel of said indicator at a predetermined location in said path in response to demounting the ammeter from said tank for blocking movement of the indicator past said location in either direction.
5. In a water storage tank assembly comprising a metal water storage tank and a sacrificial metal anode within the tank that is anodic with respect to the metal of the interior of the tank, the combination therewith of: means mounting the anode on the wall of the tank, said mounting means including means electrically insulating the anode from the tank, an ammeter mounted on the exterior of the tank and including a current-responsive indicator mounted for movement along a path of travel in proportion to the current passing through the ammeter over the current range to which the ammeter is normally respon sive, electrical conductors connecting the ammeter in series between the tank and the anode and stop means mounted on the ammeter for normally blocking movement of said indicator past a predetermined location along its path of travel in either direction, said stop means including means responsive to mounting engagement of said ammeter with said tank for rendering said stop means inoperative.
References Cited in the file of this patent UNITED STATES PATENTS 2,150,836 Lamb Mar. 14, 1939 2,308,687 Harrison Jan. 19, 1943 2,486,871 Osterheld Nov. 1, 1949 2,508,171 Kaufman May 16, 1950 2,568,594 Robinson Sept. 18, 1951 2,656,314 Osterheld Oct. 20, 1953 FOREIGN PATENTS 412,322 Canada May 4, 1943

Claims (1)

1. A METHOD OF AFFORDING A CONTINUOUS GALVANIC PROTECTION TO THE INTERIOR SURFACES OF A METAL WATER STORAGE TANK DURING USE OF SAID TANK COMPRISING THE STEPS OF MOUNTING WITHIN A METAL WATER STORAGE TANK A SACRIFICIAL METAL ANODE THAT IS ANODIC WITH RESPECT TO THE METAL OF THE INTERIOR OF SAID TANK, MOUNTING ON SAID TANK AN AMMETER HAVING A CURRENT RESPONSIVE INDICATOR MOVABLE ALONG A PATH OF TRAVEL IN PROPORTION TO THE CURRENT PASSING THROUGH THE AMMETER OVER THE CURRENT RANGE TO WHICH THE AMMETER IS RESPONSIVE, ELECTRICALLY CONNECTING SAID AMMETER IN SERIES RELATION BETWEEN SAID TANK AND SAID ANODE SO THAT MOVEMENT OF SAID INDICATOR ALONG ITS PATH OF TRAVEL WILL INDICATE THE PROGRESSIVE STAGES OF DECOMPOSITION OF SAID ANODE, PROVIDING SAID AMMETER WITH STOP MEANS OPERATIVE WHEN SAID AMMETER IS DEMOUNTED FROM SAID TANK TO HOLD SAID INDICATOR AGAINST MOVEMENT PAST A LOCATION ALONG ITS PATH OF TRAVEL CORRESPONDING TO A PREDETERMINED MINIMUM GALVANIC CURRENT, AND DEMOUNTING SAID AMMETER FROM SAID TANK TO RENDER SAID STOP MEANS OPERATIVE BEFORE ELECTRICALLY DISCONNECTING IT FOR REPLACEMENT OF SAID ANODE.
US737572A 1958-05-26 1958-05-26 Indicator system for sacrificial anodes Expired - Lifetime US3037920A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US737572A US3037920A (en) 1958-05-26 1958-05-26 Indicator system for sacrificial anodes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US737572A US3037920A (en) 1958-05-26 1958-05-26 Indicator system for sacrificial anodes

Publications (1)

Publication Number Publication Date
US3037920A true US3037920A (en) 1962-06-05

Family

ID=24964424

Family Applications (1)

Application Number Title Priority Date Filing Date
US737572A Expired - Lifetime US3037920A (en) 1958-05-26 1958-05-26 Indicator system for sacrificial anodes

Country Status (1)

Country Link
US (1) US3037920A (en)

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3135677A (en) * 1961-02-02 1964-06-02 Thermo Craft Electric Corp Durable anode protective system
US3254012A (en) * 1962-07-20 1966-05-31 Concrete Thermal Casings Inc Method of cathodically protecting heat-insulated pipes
US3406103A (en) * 1965-05-21 1968-10-15 Pittsburgh Plate Glass Co Method and apparatus for monitoring lining damage of alkali metal chlorate bipolar cells
US3806797A (en) * 1971-05-28 1974-04-23 K Harvey Devices for testing the acid or alkaline content of liquids
US4087742A (en) * 1975-07-21 1978-05-02 Canadian Gas Research Institute Hot water heater corrosion detector probe
US5897755A (en) * 1997-01-31 1999-04-27 Carsonite International Corporation Cathodic protection test station
US6220200B1 (en) 1998-12-02 2001-04-24 Carsonite International Line marker with locking mechanism
US6611133B2 (en) 2000-02-28 2003-08-26 Atlantic Professional Services Inc. Anode rod depletion indicator
EP1431420A1 (en) * 2002-12-19 2004-06-23 A.Georgios Tsagadas Sensor that detects the deterioration of sacrificial Anodes used for protection against erosion.
US20050150279A1 (en) * 2004-01-08 2005-07-14 Taber Bruce E. Pressure-based fluid corrosion/erosion protection apparatus and associated methods
US20080164334A1 (en) * 2004-09-27 2008-07-10 A.O. Smith Holding Company Water storage device having a powered anode
US20090056644A1 (en) * 2007-08-28 2009-03-05 Andrew William Phillips Storage-type water heater having tank condition monitoring features
US20090179025A1 (en) * 2008-01-14 2009-07-16 Aos Holding Company Resistor anode assembly
US20140218006A1 (en) * 2013-02-06 2014-08-07 General Electric Company Water heater anode rod depletion sensing
US20140218005A1 (en) * 2013-02-06 2014-08-07 General Electric Company Anode depletion sensor hardware circuit
US9267209B2 (en) 2013-03-15 2016-02-23 A. O. Smith Corporation Sacrificial anode control
US9803887B2 (en) 2013-06-24 2017-10-31 Rheem Manufacturing Company Cathodic corrosion and dry fire protection apparatus and methods for electric water heaters
US20220364767A1 (en) * 2019-10-29 2022-11-17 Radtech, Llc Sacrificial anode and method for determining anode health for water heater early warning system
US11674717B2 (en) 2017-12-21 2023-06-13 Rheem Manufacturing Company Water heater operation monitoring and notification
EP4403670A3 (en) * 2022-11-29 2025-04-23 Vaillant GmbH Device for a metallic water container, use of the device and water container of a heat pump system

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2150836A (en) * 1937-02-27 1939-03-14 Weston Electrical Instr Corp Electrical measuring instrument
US2308687A (en) * 1936-05-20 1943-01-19 Brown Instr Co Measuring instrument
CA412322A (en) * 1943-05-04 J. Macdougall Archibald Water heating equipment protection against corrosion
US2486871A (en) * 1945-05-28 1949-11-01 Mcgraw Electric Co Anticorrosion unit
US2508171A (en) * 1948-08-19 1950-05-16 Westinghouse Electric Corp Electrode construction
US2568594A (en) * 1949-01-26 1951-09-18 Dow Chemical Co Galvanic anode assembly
US2656314A (en) * 1947-05-28 1953-10-20 Mcgraw Electric Co Corrosion preventing means

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA412322A (en) * 1943-05-04 J. Macdougall Archibald Water heating equipment protection against corrosion
US2308687A (en) * 1936-05-20 1943-01-19 Brown Instr Co Measuring instrument
US2150836A (en) * 1937-02-27 1939-03-14 Weston Electrical Instr Corp Electrical measuring instrument
US2486871A (en) * 1945-05-28 1949-11-01 Mcgraw Electric Co Anticorrosion unit
US2656314A (en) * 1947-05-28 1953-10-20 Mcgraw Electric Co Corrosion preventing means
US2508171A (en) * 1948-08-19 1950-05-16 Westinghouse Electric Corp Electrode construction
US2568594A (en) * 1949-01-26 1951-09-18 Dow Chemical Co Galvanic anode assembly

Cited By (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3135677A (en) * 1961-02-02 1964-06-02 Thermo Craft Electric Corp Durable anode protective system
US3254012A (en) * 1962-07-20 1966-05-31 Concrete Thermal Casings Inc Method of cathodically protecting heat-insulated pipes
US3406103A (en) * 1965-05-21 1968-10-15 Pittsburgh Plate Glass Co Method and apparatus for monitoring lining damage of alkali metal chlorate bipolar cells
US3806797A (en) * 1971-05-28 1974-04-23 K Harvey Devices for testing the acid or alkaline content of liquids
US4087742A (en) * 1975-07-21 1978-05-02 Canadian Gas Research Institute Hot water heater corrosion detector probe
US5897755A (en) * 1997-01-31 1999-04-27 Carsonite International Corporation Cathodic protection test station
US6220200B1 (en) 1998-12-02 2001-04-24 Carsonite International Line marker with locking mechanism
US20040051514A1 (en) * 2000-02-28 2004-03-18 Kean James G. Anode rod depletion indicator
US6903540B2 (en) 2000-02-28 2005-06-07 Atlantic Professional Services Inc. Anode rod depletion indicator
US6611133B2 (en) 2000-02-28 2003-08-26 Atlantic Professional Services Inc. Anode rod depletion indicator
EP1431420A1 (en) * 2002-12-19 2004-06-23 A.Georgios Tsagadas Sensor that detects the deterioration of sacrificial Anodes used for protection against erosion.
US20050150279A1 (en) * 2004-01-08 2005-07-14 Taber Bruce E. Pressure-based fluid corrosion/erosion protection apparatus and associated methods
US20080164334A1 (en) * 2004-09-27 2008-07-10 A.O. Smith Holding Company Water storage device having a powered anode
US8162232B2 (en) * 2004-09-27 2012-04-24 Aos Holding Company Water storage device having a powered anode
US8068727B2 (en) 2007-08-28 2011-11-29 Aos Holding Company Storage-type water heater having tank condition monitoring features
US20090056644A1 (en) * 2007-08-28 2009-03-05 Andrew William Phillips Storage-type water heater having tank condition monitoring features
US20090179025A1 (en) * 2008-01-14 2009-07-16 Aos Holding Company Resistor anode assembly
US8023807B2 (en) 2008-01-14 2011-09-20 Aos Holding Company Resistor anode assembly
US20140218006A1 (en) * 2013-02-06 2014-08-07 General Electric Company Water heater anode rod depletion sensing
US20140218005A1 (en) * 2013-02-06 2014-08-07 General Electric Company Anode depletion sensor hardware circuit
US9267209B2 (en) 2013-03-15 2016-02-23 A. O. Smith Corporation Sacrificial anode control
US9803887B2 (en) 2013-06-24 2017-10-31 Rheem Manufacturing Company Cathodic corrosion and dry fire protection apparatus and methods for electric water heaters
US10837673B2 (en) 2013-06-24 2020-11-17 Rheem Manufacturing Company Cathodic corrosion and dry fire protection apparatus and methods for electric water heaters
US11698209B2 (en) 2013-06-24 2023-07-11 Rheem Manufacturing Company Cathodic corrosion and dry fire protection apparatus and methods for electric water heaters
US11674717B2 (en) 2017-12-21 2023-06-13 Rheem Manufacturing Company Water heater operation monitoring and notification
US12203684B2 (en) 2017-12-21 2025-01-21 Rheem Manufacturing Company Water heater operation monitoring and notification
US20220364767A1 (en) * 2019-10-29 2022-11-17 Radtech, Llc Sacrificial anode and method for determining anode health for water heater early warning system
US11525603B2 (en) * 2019-10-29 2022-12-13 Radtech, Llc Sacrificial anode and method for determining anode health for water heater early warning system
EP4403670A3 (en) * 2022-11-29 2025-04-23 Vaillant GmbH Device for a metallic water container, use of the device and water container of a heat pump system

Similar Documents

Publication Publication Date Title
US3037920A (en) Indicator system for sacrificial anodes
US4848616A (en) Electric immersion heating unit with readily removable and replaceable galvanic current control resistor
US8319626B1 (en) Alarm system for hot water heaters
US11698209B2 (en) Cathodic corrosion and dry fire protection apparatus and methods for electric water heaters
US4255747A (en) Sump pump level warning device
US2568594A (en) Galvanic anode assembly
US2486871A (en) Anticorrosion unit
JPH0695032B2 (en) Liquid level monitor
US2508171A (en) Electrode construction
US2723340A (en) Corrosion resistant immersion heater
US2811629A (en) Aquarium heating and indicating device
US2358981A (en) Corrosion preventing device
US4136001A (en) Non-sacrificial anode and water heater construction
US3056738A (en) Impressed current cathodic protection system
US1719932A (en) Tank vent
CA1066664A (en) Segmented sacrificial anode attachment to water heating element
US2058370A (en) Scale preventer
JP3442729B2 (en) Electrode level gauge
JPS6196294A (en) Method of monitoring operation of steam trap
US3339638A (en) Corrosion arrestor for fire extinguisher
US2128418A (en) Indicator
CN208504347U (en) A kind of steam boiler pressure sensor
US2106019A (en) Electric water heater
CN215815702U (en) Temperature control switch for fire-fighting ventilation pipe
US2783353A (en) Corrosion preventing mount for electric water heaters