US2992125A - Sheet material having a decorative appearance - Google Patents
Sheet material having a decorative appearance Download PDFInfo
- Publication number
- US2992125A US2992125A US78372758A US2992125A US 2992125 A US2992125 A US 2992125A US 78372758 A US78372758 A US 78372758A US 2992125 A US2992125 A US 2992125A
- Authority
- US
- United States
- Prior art keywords
- sheet
- sheet material
- iridescent
- plastic deformation
- appearance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 title claims description 23
- 239000004033 plastic Substances 0.000 claims description 16
- 229920005989 resin Polymers 0.000 claims description 8
- 239000011347 resin Substances 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 230000000087 stabilizing effect Effects 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 230000008016 vaporization Effects 0.000 claims description 4
- 238000000034 method Methods 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 230000006641 stabilisation Effects 0.000 description 5
- 238000011105 stabilization Methods 0.000 description 5
- 239000002966 varnish Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 3
- 230000008033 biological extinction Effects 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920002799 BoPET Polymers 0.000 description 1
- 239000005041 Mylar™ Substances 0.000 description 1
- 239000004959 Rilsan Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 150000002605 large molecules Chemical class 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000010363 phase shift Effects 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44F—SPECIAL DESIGNS OR PICTURES
- B44F1/00—Designs or pictures characterised by special or unusual light effects
- B44F1/08—Designs or pictures characterised by special or unusual light effects characterised by colour effects
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C3/00—Processes, not specifically provided for elsewhere, for producing ornamental structures
- B44C3/02—Superimposing layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44F—SPECIAL DESIGNS OR PICTURES
- B44F1/00—Designs or pictures characterised by special or unusual light effects
- B44F1/02—Designs or pictures characterised by special or unusual light effects produced by reflected light, e.g. matt surfaces, lustrous surfaces
- B44F1/04—Designs or pictures characterised by special or unusual light effects produced by reflected light, e.g. matt surfaces, lustrous surfaces after passage through surface layers, e.g. pictures with mirrors on the back
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44F—SPECIAL DESIGNS OR PICTURES
- B44F1/00—Designs or pictures characterised by special or unusual light effects
- B44F1/08—Designs or pictures characterised by special or unusual light effects characterised by colour effects
- B44F1/14—Iridescent effects
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
- Y10T428/24364—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.] with transparent or protective coating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
- Y10T428/31681—Next to polyester, polyamide or polyimide [e.g., alkyd, glue, or nylon, etc.]
Definitions
- This material is characterized in that it is constituted by a base sheet made of a flexible polymerized plastic material coated with a reflecting, for instance metallic, layer which is preferably covered with a varnish and offers surface unevennesses capable of imparting to the reflected light rays phase changess and which hereby bring about the extinction of some waves lengths in relation to the incidence angle of these rays and give to the surface a iridescent appearance similar to the appearance of the Newton interference rings which may be observed on the oil puddles.
- the invention is also related with a process for the making of this material which consists in submitting a sheet of flexible polymerized material having a high limit of plastic deformation to an elongation in the zone of said plastic deformation, covering these sheets with a layer of a reflecting metallic material, preferably by an evaporation in an evacuated atmosphere and annealing the sheets before or after the coating to give them a iridescent appearance.
- the sizes of such unevennesses are such that the light rays, reflected and difiused by the surface, offer, in relation to each other, alteration of direction and phase shifts bringing about by interference the extinction of some Wave lengths in relation to the angle of incidence of these rays.
- the sheets of plastic material for instance of polyamide resin and particularly of Rilsan or of polyester resin and particularly of Mylar, having for instance a thickness ranging about 5 mm.
- a metal preferably of aluminium is first subjected to an elongation in the zone of permanent deformation and at least up to but not greater than its point of plastic deformation, then coated with a reflecting layer by the volatilization of a metal preferably of aluminium, in an evacuated atmosphere and, to end, stabilized by exposure to a temperature ranging from to C. in a suitable container; or by exposure to a suitable radiation process or any natural or artificial ageing process.
- the sheets are then covered with a layer of a transparent, eventually colored varnish, which in same time allows to embellish the color formed by the reflecting surface to be improved, particularly by imparting to this surface a guilded or copper-colored-tint.
- the drying of the varnish and the stabilization of the plastic material may be performed in one single step.
- the stabilization of the plastic material is preferably carried out after the plating, thus allowing to obtain with the utmost security the interference colors since the micro-unevennesses formed at the surface of the plastic material during the stabilization reverberate at the surface of the matallic layer which is only a few microns thick. Nevertheless, by taking suitreverberate at the surface of the metallic layer which is deposited by a volatilization in a vacuum chamber from equalizing the unevennesses, it is also possible to carry on the stabilization before the plating immediately after the elongation process.
- a method of making sheet material having an iridescent ornamental appearance which comprises providing a sheet of resin material having a relatively thin thickness, and elongating the resultant resin sheet at least up to but not greater than its point of plastic deformation, thereafter applying a reflecting layer of metal thereover by vaporizing and condensing metal thereon under vacuum conditions, and stabilizing the sheet by subjecting the same to a temperature between about 120 to 150 C.
- Sheet material having an iridescent ornamental appearance made in accordance with the method defined in claim 1.
- a method of making sheet material having an iridescent ornamental appearance which comprises providing a sheet of resin material having a relatively thin thickness, and elongating the resultant resin sheet at least up to but not greater than its point of plastic deformation, thereafter applying a reflecting layer of aluminum metal thereover by vaporizing and condensing aluminum metal thereon under vacuum conditions, and stabilizing the sheet by subjecting the same to a temperature between about 120 to 150 C.
- a method of making sheet material having an iridescent ornamental appearance which comprises providing a sheet of resin material having a relatively thin thickness, and on the order of 3/ 100 mm, and elongating the resultant resin sheet at least up to but not greater than its point of plastic deformation, thereafter applying a reflecting layer of metal thereover by vaporizing and condensing metal thereon under vacuum conditions, stabilizing the sheet by subjecting the same to a temperature between about 120 to 150 C., and applying a protecting transparent coating over said stabilizedsheet.
- A-methodof-making sheet material having'an iridescent ornamental appearance which comprises providing a sheet of resin material having a relatively thin thickness, and onthe order of 3/100 mm, and elongating the resultanfresin'sheet atleast up to but not greater than its point of plastic deformation, thereafter applying a reflecting layer of aluminum metal thereover by vaporizingand condensing aluminum metal thereon under vacuum conditions, and stabilizing the sheet by subjecting the same to a temperature between about 120 to150'C.
Landscapes
- Laminated Bodies (AREA)
Description
United States Patent 2,992,125 SHEET MATERIAL HAVING A DECORATIVE APPEARANCE Geraud Antoine Jean Fustier, Lyon, France, assignor to Society J. Bocuze & 'Cie, Lyon, France, a corporation of France No Drawing. Filed Dec. 30, 1958, Ser. No. 783,727 Claims priority, application France Jan. 9, 1958 5 Claims. (Cl. 117-7) The present invention relates to a sheet material having a special decorative appearance and adapted to a wide variety of applications from the packing and the conditioning of various products, the making of ribbons or wreaths and also of wall coatings and ornamentations of any kind. This material is characterized in that it is constituted by a base sheet made of a flexible polymerized plastic material coated with a reflecting, for instance metallic, layer which is preferably covered with a varnish and offers surface unevennesses capable of imparting to the reflected light rays phase changements and which hereby bring about the extinction of some waves lengths in relation to the incidence angle of these rays and give to the surface a iridescent appearance similar to the appearance of the Newton interference rings which may be observed on the oil puddles.
The invention is also related with a process for the making of this material which consists in submitting a sheet of flexible polymerized material having a high limit of plastic deformation to an elongation in the zone of said plastic deformation, covering these sheets with a layer of a reflecting metallic material, preferably by an evaporation in an evacuated atmosphere and annealing the sheets before or after the coating to give them a iridescent appearance.
The iridescent appearance of the sheets thus obtained which can be compared with the interference colors of the Newtons rings which may be observed on oil puddles, seems to be attributable to microscopic surface unevennesses created on the sheet of plastic material in which the large molecules elongated and submitted to strains on account of the elongation are later released by a stabilization operation and form on the reflecting surface mirco-unevennesses similar to' a difiraction lattice.
The sizes of such unevennesses are such that the light rays, reflected and difiused by the surface, offer, in relation to each other, alteration of direction and phase shifts bringing about by interference the extinction of some Wave lengths in relation to the angle of incidence of these rays.
Two alternatives of the process according to the invention are illustrated by the following flow diagrams:
Polyamid or Polyamid or Polyester Polyester film base film base Elongation up Elongation up to the limit of to the limit of plastic deformation plastic deformation Vacuum Vacuum Metalizing Metalizing lhermic stabilizing Application of treatment protective varnish 2,992,125 Patented July 11, 1961 "ice Drying of the varnish According to a preferred embodiment of the invention, the sheets of plastic material, for instance of polyamide resin and particularly of Rilsan or of polyester resin and particularly of Mylar, having for instance a thickness ranging about 5 mm. are first subjected to an elongation in the zone of permanent deformation and at least up to but not greater than its point of plastic deformation, then coated with a reflecting layer by the volatilization of a metal preferably of aluminium, in an evacuated atmosphere and, to end, stabilized by exposure to a temperature ranging from to C. in a suitable container; or by exposure to a suitable radiation process or any natural or artificial ageing process.
In order to protect the reflecting layer, the sheets are then covered with a layer of a transparent, eventually colored varnish, which in same time allows to embellish the color formed by the reflecting surface to be improved, particularly by imparting to this surface a guilded or copper-colored-tint. In such a case, the drying of the varnish and the stabilization of the plastic material may be performed in one single step.
As above mentioned, the stabilization of the plastic material is preferably carried out after the plating, thus allowing to obtain with the utmost security the interference colors since the micro-unevennesses formed at the surface of the plastic material during the stabilization reverberate at the surface of the matallic layer which is only a few microns thick. Nevertheless, by taking suitreverberate at the surface of the metallic layer which is deposited by a volatilization in a vacuum chamber from equalizing the unevennesses, it is also possible to carry on the stabilization before the plating immediately after the elongation process.
What is claimed is:
1. A method of making sheet material having an iridescent ornamental appearance which comprises providing a sheet of resin material having a relatively thin thickness, and elongating the resultant resin sheet at least up to but not greater than its point of plastic deformation, thereafter applying a reflecting layer of metal thereover by vaporizing and condensing metal thereon under vacuum conditions, and stabilizing the sheet by subjecting the same to a temperature between about 120 to 150 C.
2. Sheet material having an iridescent ornamental appearance made in accordance with the method defined in claim 1.
*3. A method of making sheet material having an iridescent ornamental appearance which comprises providing a sheet of resin material having a relatively thin thickness, and elongating the resultant resin sheet at least up to but not greater than its point of plastic deformation, thereafter applying a reflecting layer of aluminum metal thereover by vaporizing and condensing aluminum metal thereon under vacuum conditions, and stabilizing the sheet by subjecting the same to a temperature between about 120 to 150 C.
4. A method of making sheet material having an iridescent ornamental appearance which comprises providing a sheet of resin material having a relatively thin thickness, and on the order of 3/ 100 mm, and elongating the resultant resin sheet at least up to but not greater than its point of plastic deformation, thereafter applying a reflecting layer of metal thereover by vaporizing and condensing metal thereon under vacuum conditions, stabilizing the sheet by subjecting the same to a temperature between about 120 to 150 C., and applying a protecting transparent coating over said stabilizedsheet.
5. A-methodof-making sheet material having'an iridescent ornamental appearance Which comprises providing a sheet of resin material having a relatively thin thickness, and onthe order of 3/100 mm, and elongating the resultanfresin'sheet atleast up to but not greater than its point of plastic deformation, thereafter applying a reflecting layer of aluminum metal thereover by vaporizingand condensing aluminum metal thereon under vacuum conditions, and stabilizing the sheet by subjecting the same to a temperature between about 120 to150'C.,
and applying a protecting transparent coating over said stabilized sheet.
(References Citedxtinithe fileioftthis .patent UNITED :STATES i. PATENTS
Claims (1)
1. A METHOD OF MAKING SHEET MATERIAL HAVING AN IRIDESCENT ORNAMENTAL APPEARANCE WHICH COMPRISES PROVIDING A SHEET OF RESIN MATERIAL HAVING A RELATIVELY THIN THICKNESS, AND ELONGATING THE RESULTANT RESIN SHEET AT LEAST UP TO BUT NOT GREATER THAN ITS POINT OF PLASTIC DEFORMATION, THEREAFTER APPLYING A REFLECTING LAYER OF METAL THEREOVER BY VAPORIZING AND CONDENSING METAL THEREON UNDER VACUUM CONDITIONS, AND STABILIZING THE SHEET BY SUBJECTING THE SAME TO A TEMPERATURE BETWEEN ABOUT 120 TO 150*C.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR755473A FR1301253A (en) | 1958-01-09 | 1958-01-09 | Decorative plastic sheet material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2992125A true US2992125A (en) | 1961-07-11 |
Family
ID=8705450
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US78372758 Expired - Lifetime US2992125A (en) | 1958-01-09 | 1958-12-30 | Sheet material having a decorative appearance |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US2992125A (en) |
| FR (1) | FR1301253A (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3212917A (en) * | 1962-01-03 | 1965-10-19 | Ibm | Electroless plating procedure |
| US3244224A (en) * | 1961-12-18 | 1966-04-05 | Nat Res Corp | Space vehicle insulation |
| US4015049A (en) * | 1974-05-09 | 1977-03-29 | Toa Nenryo Kogyo Kabushiki Kaisha | Metal coated unsaturated carboxylic acid modified polyolefin article and method of making same |
| US4407871A (en) * | 1980-03-25 | 1983-10-04 | Ex-Cell-O Corporation | Vacuum metallized dielectric substrates and method of making same |
| US4431711A (en) * | 1980-03-25 | 1984-02-14 | Ex-Cell-O Corporation | Vacuum metallizing a dielectric substrate with indium and products thereof |
| US4713143A (en) * | 1987-04-16 | 1987-12-15 | Davidson Textron Inc. | Etching of vacuum metallized indium |
| US5284679A (en) * | 1992-11-16 | 1994-02-08 | Davidson Textron Inc. | Method for making bright trim articles |
| US5290625A (en) * | 1992-05-22 | 1994-03-01 | Davidson Textron Inc. | System for making bright aluminum parts |
| US5464661A (en) * | 1994-05-25 | 1995-11-07 | Davidson Textron Inc. | Reduced solvent island coating system |
| US5468518A (en) * | 1994-05-25 | 1995-11-21 | Davidson Textron Inc. | Combined primer/basecoat island coating system |
| US5558909A (en) * | 1996-01-17 | 1996-09-24 | Textron Automotive Interiors, Inc. | Apparatus and method for vacuum-metallizing articles with significant deposition onto three-dimensional surfaces |
| US6416847B1 (en) | 1995-08-25 | 2002-07-09 | Textron Automotive Company Inc. | Cross-linking top coat for metallic island coating systems |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2558113B1 (en) * | 1984-01-17 | 1988-07-29 | Nicollet Hugues Sa | PROCESS FOR OBTAINING ANY PATTERN OF METALLIC APPEARANCE, AND SHEET MATERIAL COMPRISING SUCH A PATTERN |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2689802A (en) * | 1954-09-21 | - layers -to reflecting metal | ||
| US2740732A (en) * | 1951-07-16 | 1956-04-03 | Sprague Electric Co | Process of bonding a metal film to a thermoplastic sheet and resulting product |
| US2776598A (en) * | 1951-04-13 | 1957-01-08 | Charles P Dreyer | Mirror having a dichroic layer |
| US2865787A (en) * | 1955-03-09 | 1958-12-23 | Heberlein Patent Corp | Process for producing color effects on textile and other sheet-like material and products therefrom |
| US2930106A (en) * | 1957-03-14 | 1960-03-29 | American Felt Co | Gaskets |
-
1958
- 1958-01-09 FR FR755473A patent/FR1301253A/en not_active Expired
- 1958-12-30 US US78372758 patent/US2992125A/en not_active Expired - Lifetime
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2689802A (en) * | 1954-09-21 | - layers -to reflecting metal | ||
| US2776598A (en) * | 1951-04-13 | 1957-01-08 | Charles P Dreyer | Mirror having a dichroic layer |
| US2740732A (en) * | 1951-07-16 | 1956-04-03 | Sprague Electric Co | Process of bonding a metal film to a thermoplastic sheet and resulting product |
| US2865787A (en) * | 1955-03-09 | 1958-12-23 | Heberlein Patent Corp | Process for producing color effects on textile and other sheet-like material and products therefrom |
| US2930106A (en) * | 1957-03-14 | 1960-03-29 | American Felt Co | Gaskets |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3244224A (en) * | 1961-12-18 | 1966-04-05 | Nat Res Corp | Space vehicle insulation |
| US3212917A (en) * | 1962-01-03 | 1965-10-19 | Ibm | Electroless plating procedure |
| US4015049A (en) * | 1974-05-09 | 1977-03-29 | Toa Nenryo Kogyo Kabushiki Kaisha | Metal coated unsaturated carboxylic acid modified polyolefin article and method of making same |
| US4407871A (en) * | 1980-03-25 | 1983-10-04 | Ex-Cell-O Corporation | Vacuum metallized dielectric substrates and method of making same |
| US4431711A (en) * | 1980-03-25 | 1984-02-14 | Ex-Cell-O Corporation | Vacuum metallizing a dielectric substrate with indium and products thereof |
| US4713143A (en) * | 1987-04-16 | 1987-12-15 | Davidson Textron Inc. | Etching of vacuum metallized indium |
| US5384161A (en) * | 1992-05-22 | 1995-01-24 | Davidson Textron Inc. | System for making bright aluminum parts |
| US5290625A (en) * | 1992-05-22 | 1994-03-01 | Davidson Textron Inc. | System for making bright aluminum parts |
| US5284679A (en) * | 1992-11-16 | 1994-02-08 | Davidson Textron Inc. | Method for making bright trim articles |
| US5464661A (en) * | 1994-05-25 | 1995-11-07 | Davidson Textron Inc. | Reduced solvent island coating system |
| US5468518A (en) * | 1994-05-25 | 1995-11-21 | Davidson Textron Inc. | Combined primer/basecoat island coating system |
| US6416847B1 (en) | 1995-08-25 | 2002-07-09 | Textron Automotive Company Inc. | Cross-linking top coat for metallic island coating systems |
| US6440541B1 (en) | 1995-08-25 | 2002-08-27 | Textron Automotive Company Inc. | Top coat for metallic island coating system |
| US5558909A (en) * | 1996-01-17 | 1996-09-24 | Textron Automotive Interiors, Inc. | Apparatus and method for vacuum-metallizing articles with significant deposition onto three-dimensional surfaces |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1301253A (en) | 1962-08-17 |
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