US2805770A - Method of beneficiating multicomponent ore - Google Patents
Method of beneficiating multicomponent ore Download PDFInfo
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- US2805770A US2805770A US382918A US38291853A US2805770A US 2805770 A US2805770 A US 2805770A US 382918 A US382918 A US 382918A US 38291853 A US38291853 A US 38291853A US 2805770 A US2805770 A US 2805770A
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- 238000000034 method Methods 0.000 title claims description 38
- 238000000926 separation method Methods 0.000 claims description 74
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 29
- 239000011707 mineral Substances 0.000 claims description 29
- 238000002156 mixing Methods 0.000 claims description 16
- 239000012141 concentrate Substances 0.000 description 102
- 239000000463 material Substances 0.000 description 83
- 239000002245 particle Substances 0.000 description 69
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 36
- 229910019142 PO4 Inorganic materials 0.000 description 30
- 239000010452 phosphate Substances 0.000 description 30
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 30
- 235000010755 mineral Nutrition 0.000 description 28
- 239000000203 mixture Substances 0.000 description 28
- 230000005686 electrostatic field Effects 0.000 description 24
- 239000000615 nonconductor Substances 0.000 description 19
- 239000000377 silicon dioxide Substances 0.000 description 18
- 239000007787 solid Substances 0.000 description 16
- 230000004044 response Effects 0.000 description 13
- 238000012216 screening Methods 0.000 description 12
- 230000008569 process Effects 0.000 description 8
- 239000010442 halite Substances 0.000 description 7
- 235000002639 sodium chloride Nutrition 0.000 description 7
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 6
- 239000001103 potassium chloride Substances 0.000 description 6
- 235000011164 potassium chloride Nutrition 0.000 description 6
- 238000011084 recovery Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000004020 conductor Substances 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 229940072033 potash Drugs 0.000 description 3
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 3
- 235000015320 potassium carbonate Nutrition 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 238000003556 assay Methods 0.000 description 2
- 239000002801 charged material Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000002198 insoluble material Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000002367 phosphate rock Substances 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
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- 239000013078 crystal Substances 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000005188 flotation Methods 0.000 description 1
- 239000010436 fluorite Substances 0.000 description 1
- 210000003918 fraction a Anatomy 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
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- 238000002360 preparation method Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
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- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C7/00—Separating solids from solids by electrostatic effect
- B03C7/003—Pretreatment of the solids prior to electrostatic separation
Definitions
- This invention relates to an electrostatic method of beneficiating ore materials. More particularly, it relates to the concentration of multicomponent ore materials reducible to an unlocked granular form. Still more particularly it relates to the recovery by electrostatic separation of relatively pure components of nonmetallic materials such as phosphate, silica, sylvite, feldspar, fluorspar, and the like.
- Electrostatic beneficiation of minerals has been practiced in a number of forms. lized to separate conductors from nonconductors. Apparatus utilizing corona discharge, or using a rotating roll, which is one of a pair of electrodes, are examples of equipment for this type of operation.
- a second system utilizable for separation of conductors from conductors and nonconductors from nonconductors has been the selective reagentizing of materials so that they may be processed as though the separation were one of removing conductors from nonconductors.
- Electrostatic separation has been applied in still a third form to separate nonconductors. In the latter system, the nonconductors are selectively induced to accept a positive or a negative charge and then are separated as freely-falling bodies drawn in the direction of one or the other of the electrodes being maintained at a high impressed difference of potential.
- the method of the instant invention is based upon the discovery that ore concentrates which exhibit poor charging characteristics and, therefore, are not subject to any appreciable upgrading by subsequent passes through electrostatic fields may be caused to charge to an extent restoring response to electrostatic fields by tribo-electrification in the presence of a mechanically removable material of work function difierent from the ore component exhibiting the insufiicient charging for electrostatic field response.
- work function different from the ore component is meant the, characteristic of exchanging electrons with the ore component whereby the ore component exhibits a definite charge.
- Materials which receive electrons are generally referred to as having a higher work function than the doner material.
- Applicant does not wish to be bound by theory, but includes equivalent applications by which ore components exhibiting insufiicient charge for effecting separation are, by contact with a removable material, caused to show a response to electrostatic fields warranting additional passes for further ore concentration.
- the nonconductor material of work function different from the ore component to be concentrated and separable from the ore by means of differences of shape, differences in size, specific gravity, or other utilizable distinguishing characteristics is mixed with said ore concentrate which initially or subsequently shows substantially no response to electrostatic separation.
- the mixture of ore and coarse nonconductor material is agitated either in the presence of or in the absence of an electrostatic field and the further concentration thereof efliected before or after separation of the added coarse granular material.
- the process involves mixing into either a phosphate concentrate, a silica tail concentrate or other fraction a predetermined quantity of the minor component of the fraction having a size appreciably larger than the largest particles of the material being subjected to electrostatic beneficiation.
- a phosphate concentrate granular silica is added to an electrostatically prepared phosphate concentrate and the mixture agitated thoroughly in a dry state to induce the particles selectively to be electrically charged by tribo-electrification.
- the addition agent may be either phosphate pebbles or hard rock phosphate of a proper size.
- the phosphate ore concentrate and coarse silica are agitated in a mixer Whose material of construction has a work function different from either the phosphate or the silica.
- the charged mixture is screened to effect separation of silica upon a particle size basis.
- the phosphate ore concentrate is then passed through additional electrostatic separations to obtain a phosphate product of high purity.
- the method of beneficiating phosphatic ore comprises mixing dry concentrate with a predetermined amount of a recycle stream of coarse silica of an average particle size larger than the largest particles of concentrate, electrostatically separating the mixture, recovering at least a concentrate portion and a tailing portion, and screening the coarse silica from. appropriate fractions for recycle to the system, if such screening is not made before electrostatic separation.
- the particle s'ize will fall in a range between about -14 mesh'and about 325 mesh.
- the multicomponent material, freed as individual particles, is next dried. Thismay be accomplished either by direct or indirect heating; for example, by contacting a bed of granular material with hot gases, as in a rotary kiln, tunnel dryer, electric'oven, or the like. In the dryer the solids are raised to an elevated temperature, the temperature for such ores as-sylvinitebeing in. excess of about 675 F. the temperature being that which conditions the ore for charging and separation, while ores such as phosphate need only be raised to a temperature in excess of the optimum for separation.
- a suitable mixer such as a rotating cylinder, a paddle mixer, or the like, partially or wholly, of metal construction, such as iron, steel, copper, copper alloys, and the like.
- a material may beof suchrnature as toimpart toxphosphate a charge of greater to state, therefore, that combinations of ingredients or ingredients plus material of the mixer where the mixer may act as a donor element should result in the charging of the concentrate material whereby particles of one kind are given a charge and particles of another type acquire a charge of different character or dififerent magnitude such that they may be effectively separated by passage through an electrostatic separating unit.
- Ingcneral it is preferred tooperateat a total impressed difference of potcntial' in the range of about 50,000 volts to about 250,000 volts.
- This voltage should be maintained at a high direct voltage potential substantially free of alternating current components, i. e., filtered D. C. current should'be low in theso-called A. C. ripple.
- a steady and relativelyinexpensive supply of D. C. voltage may also be obtained by the use of such equipment as radio frequency power supply.
- the dried material isconveyed to.
- a chargingstation 12 where the particles-are induced to take on an electricalcharge, as by passage over a grounded contact surface of .graphite, lead, zinc,.aluminum,.copper, tin, and the like.
- trostatic separation unit- 13 whichamay consist of one or more stages of electrostatic separation.
- the intermediate concentrate 15 is commingled with coarse material, such as silica, of a particle size appreciably larger than that of the largest particle of, the concentrateat .the mixerelectron recharging: station 16.
- the mixed and charged material issuing fromgstationlti'in the preferred embodiment of the invention is conveyed to: screening station 17 where the coarse material, such as silica, is removed.
- the said coarse material is returned by conveyor 18 to coarse material storage .19- pending recycling todhe mixerrecharging station 16.
- the charged concentrate is then passed with or Without reheating to an electrostatici separation unit 20.
- the intermediate concentrate 15 is commingled with coarse material, such as silica, of a particle size appreciably larger than that of the concentrate at the mixer-charging station 16.
- coarse material such as silica
- the mixed and charged material issuing from station 16 is moved by conveyor 25 to electrostatic separation unit 20.
- electrostatic separation unit 20 Upon passage through one or more stages of electrostatic separation, at least two products, and usually three prodnets are collected; namely, a predominantly concentrate fraction 21, a middling fraction 22, and a predominantly tail component fraction 23.
- Each of these fractions, or only some, may be conveyed to a screening station 26, depending upon the nature of the coarse material where the coarse material may be separated, if desired. If the coarse, material is to be recycled, it is returned to storage station 19 by conveyor 27.
- Materials which may be either concentrate or tail, or both, collected individually, are segregated for storage or for further processing.
- Example 1 Florida phosphate ore was washed to produce a lowgrade Florida phosphate pebble ore having a B. P. L. content of approximately 30%.
- the pebble material had a particle size in the range of about 14 and about 200 mesh. This material was dried at a temperature of approximately 225 F.
- the pebble material was passed while hot through four stages of electrostatic separation at which time a concentrate was produced constituting approximately 20% by weight of the feed and having approximately 73.5% B. P. L. content and approximately 8% of insoluble material.
- the intermediate concentrate was segregated into two portions for comparative tests. Upon passage of the first portion through a fifth stage of electrostatic separation under identical electrostatic conditions as was maintained previously, a concentrate and tail was produced of substantially identical analyses showing that no effective separation was being accomplished.
- the second portion of the intermediate concentrate was mixed with 20% by weight of coarse silica of a particle size of about +10 mesh.
- the mixture was then agitated in an iron paddle mixer allowing the mixture a retention period of about twenty minutes.
- the coarse silica was recovered by seiving the mixture on a 10 mesh Tyler standard screen.
- the concentrate passing through the screen was delivered at a rate of approximately one ton per hour per linear foot of electrode through a fifth stage of electrostatic separation.
- the concentrate recovered had approximately 78% B. P. L. content and approximately 2.5% of insoluble material.
- This concentrate constituted a recovery of approximately 70% of the original phosphate content as premium grade pebble material.
- the middling phosphte stream which was to be recycled accounted for approximately 17% of the phosphate content of the original phosphate pebble material.
- a comparison of the results is as follows:
- the separation effected in the fifth stage produces a premium grade phosphate and, by a recycling system for the high B. P. L. content tail, an approximately recovery of the phosphate can be effected as this high-grade product.
- Example II Slime-bearing sylvinite ore from the Carlsbad section of New Mexico was crushed and then comm-inuted in a hammer mill. The comminuted ore was screened to produce a fraction containing particles in the range between about 14 mesh and about 200 mesh size. This granular sylvinite feed was heated to approximately 800 F. Heating when the solids attained this temperature, was continued for about five minutes. The material was then removed from the heating unit and cooled to approximately 375 F. The particles were delivered to a feed hopper and cascaded downwardly through a vibratory cast-iron trough. The granular material differentially charged, halite charged positively, and sylvite charged negatively, cooled to about 225 F.
- the electrodes had a difference of potential of approximately 100,000 volts impressed thereon giving a field gradient of approximately 10,000 volts per inch of distance between oppositely charged electrodes.
- a concentrate was recovered. This concentrate was split into two portions. The first portion was reheated for one hour in an oven held at approximately 800 F. This reheated portion was screened to remove +28 mesh size material and then was passed through an electrostatic unit identical to that used for the first or rougher separation.
- the second portion of this sylvite concentrate was mixed with halite crystalline material of a particle size of about 14 mesh.
- This mixture containing a 2 to 1 ratio by weight of second portion of the concentrate and added halite was heated to 800 F. in the same manner as the first portion of the concentrate.
- the reheated mixture during cooling was agitated in a stirring mixer.
- the agitated mixture was then screened to remove the added material and then was passed through the same electrostatic unit as was used for separation of the first portion of the concentrate.
- a method of beneficiating ore which comprises subjecting a multicomponent mineral ore feed to at least one electrostatic separation, mixing with the desired component fraction produced by said separations a predetermined quantity of solid particles of material of work function different from the mineral component being concentrated, agitating the mixture whereby the material in the fraction is induced selectively to accept an electrical charge, and subjecting the charged ore fraction to additional electrostatic separation.
- a method of beneficiating ore which comprises subjecting a nonconductor multicomponent mineral ore feed to atleast one electrostatic separation, mixing with the concentrate produced by said separations a predetermined quantity of solid particles of material of work function different from the mineral component being concentrated and agitating the mixture whereby the concentrate is induced selectively to accept an electrical charge, and subjecting the charged ore concentrate, material to additional electrostatic separation.
- a method of *beneficiating ore which comprises subjecting a 'rnulticomponent,nonconductor mineral ore feed to at least one electrostatic separation, adding to the concentrate produced a predetermined quantity of solid particles of material of workwfunction different from the mineral component being concentrated, agitating the mixture under conditions to effect tribo-electrifica-tion, and subjecting the charged ore concentrate material to electrostatic separation.
- electrostatic separation mixing with the concentrate producedta predetermin'ed'quantity of solid particles ofmaterial of work function different from the mineral ,component being concentrated and agitating the/mixture whereby the concentrate is induced selectively to accept an electrical charge, separating the, added material from the ore concentrate, and subjecting the charged ore concentrate material to additional electrostatic separation.
- a method of heneficiating ore which comprises subjecting a nonconduc-tor mineral ore feed to at least one. electrostatic separation, mixing with the concentrate produced a predetermined quantity of solid particles of material of work functions different from the mineralcomponent being concentrated whereby the concentrate is induced selectively to accept an electrical charge, segregating the added material by mechanical means, and subjecting the charged concentrate to the attractive and repulsive forces of one or more electrostatic fields.
- a method of beneficiating ore which comprises subjecting 'a nonconductor mineral ore feedhaving a particle size range between about 14 mesh and about 325 mesh to at least one electrostatic separation, mixing with the concentrate produced by said separations a predetermined quantity of solid particles of material of work function different from the, mineral component being concentrated having a particle size larger than the largest particle of the ore feed and agitating the mixture whereby the concentrate is induced selectively to accept an electrical charge, and subjecting the charged ore concentrate ma solid particles of material of work function diflerent from the mineral component being concentrated and having a particle size range between about 4- mesh and about 10 mesh, and subjecting thecharged ore concentrate material to further electrostatic separation.
- a method of .beneficiating ore which comprises subjecting a nonconductor mineral ore feed having -a particle size range between about 14 mesh and about 200 mesh to at leastone electrostatic separation, mixing with the concentrate produced a predetermined quantity of solid particles of material having a particle size range between about 4 mesh and about 10 mesh and of work function different from the mineral component being conentrated, screening the mixture to recover the material having a particle size range betwen about4 mesh and about 10 mesh, and sub: jecting the charged ore concentrate material to further electrostatic separation.
- a method of beneficiating ore which comprises subjecting a nonconductor mineral ore feed having a particle size in the range between about 14 mesh and about 200 mesh to at least one electrostatic separation,
- a method of .beneficiating ore which comprises subjecting a relatively uniform particle size nonconductor mineral ore feed to at least one electrostatic separation in an electrostatic field having a field gradient in the range between about 3,000 volts per inch andabout 15,000 volts perinch of distance separating electrodes, mixing with the concentrate produced by said separations a predetermined quantity of 'solid particles of material of different physical characteristics and of work function dilferent from the mineral component being concentrated whereby the concentrate is induced selectively to accept an electrical charge, and'subjecting the charged ore concentrate material to additional electrostatic separation.
- a method ofbeneficiating phosphate ore which comprises subjecting a raw phosphate feed having a particle size range between about 14 mesh and about 200 mesh to'at least one electrostatic separation, adding to the concentrate produced silica having a particle size range between'about 4 and about 10 mesh, agitating the mixture under conditions to efiiect tribe-electrification, screening the coarsesil'ica from the agitated mixture, and subjecting the charged phosphate material to further electrostatic separation.
- a method of beneficiating potash ore which comprises subjecting potash ore having a particle size range between about 14 mesh and about 200 mesh to at least one electrostatic separation, adding to the concentrate produced halite material having a particle size larger than about 14 mesh, agitating the mixture under conditions to effect tribo-electrification, screening the coarse halite material from the agitated mixture, and subjecting the c-hargedpotash concentrate to further electrostatic separation.
- a method of beneficiating electrostatically prepared ore concentrates which exhibit substantially no response to an electrostaticfield due to loss of charge during electrostatic separation which comprises mixing with said concentrate a predetermined quantity of solid particles of material of work function different from the mineral component being concentrated whereby the concentrate is induced selectively to accept an electrical charge, and subjecting the charged ore concentrate material to additional electrostatic separation.
- a method of beneficiating electrostatically prepared iore concentrates which exhibit substantially no response to an electrostatic .field due to loss of charge during electrostatic separation which comprises adding to the concentrate a predetermined-quantity of solidparticlcs of material of work function different from the mineral component being concentrated, agitating the mixture under conditions to effect tribo-electrification, and subjecting the charged ore concentrate material to electrostatic separation.
- a method of beneficiating electrostatically prepared ore concentrates which exhibit substantially no response to an electrostatic field due to loss of charge during electrostatic separation which comprises mixing with the concentrate a predetermined quantity of solid particles of material of Work function different from the mineral component being concentrated whereby the concentrate is induced. selectively to accept an electrical charge, segregating the added material by mechanical means, and subjecting the charged concentrate to the attractive and repulsive forces of one or more electrostatic fields.
- a method of beneficiating electrostatically prepared ore concentrates having a particle size range of between about 14 mesh and about 200 mesh which exhibit substantially no response to an electrostatic field due to loss of charges during electrostatic separations which comprises mixing with the concentrate a predetermined quantity of solid particles of material of work function different from the mineral component being concentrated and having a particle size range between about 4 mesh and about mesh, and subjecting the charged ore concentrate material to further electrostatic separation.
- a method of beneficiating electrostatically prepared ore concentrates which exhibit substantially no response to an electrostatic field due to loss of charges during electrostatic separation which comprises mixing with the concentrate a predetermined quantity of solid particles of material of work function different from the mineral component being concentrated and agitating the mixture whereby the concentrate is induced selectively to accept an electrical charge, and subjecting the charged ore concentrate material to additional electrostatic separation in an electrostatic field having a field gradient in the range between about 3,000 volts per inch and about 15,000 volts per inch of distance separating electrodes.
- a method of beneficiating electrostatically prepared ore concentrates having a particle size in the range between about 14 mesh and about 200 mesh and which exhibit substantially no response to an electrostatic field due to loss of charges during electrostatic separation which comprises mixing with the concentrate a predetermined quantity of solid particles of material of work function different from the mineral component being concentrated, screening the mixture to recover the nonconductor material having a particle size range between about 4 mesh and about 10 mesh, and subjecting the charged ore concentrate material to at least one electrostatic separation as freely-falling bodies, and collecting at least a concentrate fraction and a tail fraction in the vicinity of the lower portions of the electrodes bounding said electrostatic field.
- a method of beneficiating electrostatically prepared Florida phosphate ore concentrates having a particle size range between about 14 mesh and about 200 mesh and which exhibit substantially no response to an electrostatic field due to loss of charges during electrostatic separation which comprises adding to the concentrate silica having a particle size range between about 4 'mesh and about 10 mesh, agitating the mixture under conditions to eflfect tribo-electrification screening the coarse silica from the agitated mixture, and subjecting the charged ore concentrate material to further electrostatic separation.
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- Electrostatic Separation (AREA)
Description
J. E. LAWVER 2,805,770
METHOD OF BENEFICIATING MULTICOMPONENT ORE Sept 10, 1957 Filed Sept. 29, 1955' TAl L 14 1N VEN TOR. yam 6 3100% SCREENING L m FR E mm 7. M A 2 Au mR SA w w I E 2 H mm x 7 w WW a 8 WW, T o cl c N WW I m M m ma A E om L C R T D C CR R S EA m u I. I M d |l. A T
INTERMEDIATE CONCENTRATE l5 SCREEN ED MATERlAL nited States Patent fiice 2,805,770 Patented Sept. 10, 195? METHOD OF BENEFICIATING MULTICOMPONENT ORE James E. Lawver, Lakewood, Col0., assignor to International Minerals & Chemical Corporation, a corpora tion of New York Application September 29, 1953, Serial No. 382,918
20 Claims. (Cl. 209-127) This invention relates to an electrostatic method of beneficiating ore materials. More particularly, it relates to the concentration of multicomponent ore materials reducible to an unlocked granular form. Still more particularly it relates to the recovery by electrostatic separation of relatively pure components of nonmetallic materials such as phosphate, silica, sylvite, feldspar, fluorspar, and the like.
Electrostatic beneficiation of minerals has been practiced in a number of forms. lized to separate conductors from nonconductors. Apparatus utilizing corona discharge, or using a rotating roll, which is one of a pair of electrodes, are examples of equipment for this type of operation. A second system utilizable for separation of conductors from conductors and nonconductors from nonconductors has been the selective reagentizing of materials so that they may be processed as though the separation were one of removing conductors from nonconductors. Electrostatic separation has been applied in still a third form to separate nonconductors. In the latter system, the nonconductors are selectively induced to accept a positive or a negative charge and then are separated as freely-falling bodies drawn in the direction of one or the other of the electrodes being maintained at a high impressed difference of potential.
When separating nonconductors by the last outlined system, many mineral ores, after concentration to a greater or lesser degree, exhibit weak or incomplete charging as proven by the reaching of a stage wherein the ore particles, or some components thereof, show little or no tendency for movement in response to an electrostatic field. Treatment of such ore concentrates in the manner initially utilized to induce charging, such as by contacting a grounded donor plate, or introducing thermal energy and the like, as well as combinations thereof, have failed to render the concentrates sufiiciently responsive to an electrostatic field to effect recovery of concentrates of the desired higher component content.
It is a primary object of the instant invention to provide a process for the recovery of concentrates of a high degree of purity.
It is a further object of the instant invention to pro vide a process wherein the use of reagents such as are commonly employed in flotation processes is eliminated.
It is still a further object to provide a method whereby electrically inactive ore concentrates are again rendered responsive to an electrostatic field.
It is a further object of the instant invention to provide a simplified separation method for nonmetallic ore material.
It is a still further object to provide a process wherein charged coarse grains of a material capable of exchanging electrons through contact potential means with the components of a concentrate is recirculated to improve the charging of ore particles, and is thenremoved by methods other than electrostatic separation.
It has been commonly uti- These and other objects of the novel method will be more fully understood from the following description.
The method of the instant invention is based upon the discovery that ore concentrates which exhibit poor charging characteristics and, therefore, are not subject to any appreciable upgrading by subsequent passes through electrostatic fields may be caused to charge to an extent restoring response to electrostatic fields by tribo-electrification in the presence of a mechanically removable material of work function difierent from the ore component exhibiting the insufiicient charging for electrostatic field response.
By the terminology work function different from the ore component is meant the, characteristic of exchanging electrons with the ore component whereby the ore component exhibits a definite charge. Materials which receive electrons are generally referred to as having a higher work function than the doner material. Applicant does not wish to be bound by theory, but includes equivalent applications by which ore components exhibiting insufiicient charge for effecting separation are, by contact with a removable material, caused to show a response to electrostatic fields warranting additional passes for further ore concentration.
In carrying out this novel method, the nonconductor material of work function different from the ore component to be concentrated and separable from the ore by means of differences of shape, differences in size, specific gravity, or other utilizable distinguishing characteristics, is mixed with said ore concentrate which initially or subsequently shows substantially no response to electrostatic separation. The mixture of ore and coarse nonconductor material is agitated either in the presence of or in the absence of an electrostatic field and the further concentration thereof efliected before or after separation of the added coarse granular material.
As applied to the electrostatic beneficiation of phosphate ores, the process involves mixing into either a phosphate concentrate, a silica tail concentrate or other fraction a predetermined quantity of the minor component of the fraction having a size appreciably larger than the largest particles of the material being subjected to electrostatic beneficiation. In the case of phosphate concentrates, granular silica is added to an electrostatically prepared phosphate concentrate and the mixture agitated thoroughly in a dry state to induce the particles selectively to be electrically charged by tribo-electrification. In the case of electrostatically prepared middling fractions from an electrostatic phosphate concentration operation; the addition agent may be either phosphate pebbles or hard rock phosphate of a proper size. When electrostatically treating potash ore such as sylvinite, coarse granular halite crystals would be mixed with sylvite concentrates.
In the preferred embodiment, the phosphate ore concentrate and coarse silica are agitated in a mixer Whose material of construction has a work function different from either the phosphate or the silica. The charged mixture is screened to effect separation of silica upon a particle size basis. The phosphate ore concentrate is then passed through additional electrostatic separations to obtain a phosphate product of high purity.
When the process is placed on a continuous basis, the method of beneficiating phosphatic ore comprises mixing dry concentrate with a predetermined amount of a recycle stream of coarse silica of an average particle size larger than the largest particles of concentrate, electrostatically separating the mixture, recovering at least a concentrate portion and a tailing portion, and screening the coarse silica from. appropriate fractions for recycle to the system, if such screening is not made before electrostatic separation.
In the preliminary treatment of ores prior to any passage through electrostatic fields, the ore is treated so as to have a reasonable uniform particle size; In the case of Florida phosphate pebble ore, the operationyis purely one of washing to frec the phosphatepebblcs of matrix and thensizing to produce a'fractio'n in therange of about 14 mesh to about 200 mesh; Only Florida phosphate pebblesof +l 4meshsize are subjected to any the grinding operation in the preparation of feeds which are to be subjected tobenefication treatments. On the other hand, phosphate ores from other regions, and other nonconductor mineral ores; require grinding'to the economic liberation stage torfreeing or'unl-ockingthe undesired ore components. Different types of materialbeing fed toan electrostatic'fieldwill have different particle sizes,
but in general the particle s'ize will fall in a range between about -14 mesh'and about 325 mesh. Some of the differenttypesof materialshavingasomewhat shorter range of particle size as, for-example, washer debris, phosphate, or fines, have a particle size in the range between about 14 mesh and about 150 mesh whereas, the fines from low-grade pebble grinding operations often have a par ticle size in the range of about 150 mesh to about 325 mesh.
The multicomponent material, freed as individual particles, is next dried. Thismay be accomplished either by direct or indirect heating; for example, by contacting a bed of granular material with hot gases, as in a rotary kiln, tunnel dryer, electric'oven, or the like. In the dryer the solids are raised to an elevated temperature, the temperature for such ores as-sylvinitebeing in. excess of about 675 F. the temperature being that which conditions the ore for charging and separation, while ores such as phosphate need only be raised to a temperature in excess of the optimum for separation. After heating, the ore is induced selectively to accept an electrical charge, .either during the cooling down period or after cooling to the optimum temperature "for separation, by such contact potential methods asstrong agitation under particle to particle contact conditions or so-called'tribo=electrification or by particle to donor element contact with or .without the donor being grounded to the earth.
Charged'material is fed as freely-falling bodiesbetween electrodes held at a high difference of potential. After one or moreelectrostatic separations, the ore concentrates begin to exhibit an appreciable reduction in response to the forces acting in an electrostatic field even though they still are maintained at an elevated temperature and are subjected to donor element contact. When this stage of concentration is reached, the particles are treated in accordance with this invention in order to make them again approach their initial activity. Phosphate concentrates, for example, which have become inactive, are-then mixed. with coarse silica having .a particle size in the range between about 4 mesh and about 10 mesh, the preferred silica material being relatively uniform in size. The recharging of the ore concentrate-addedcomponent of different work-function mixture may then be accomplished by intimately contacting=onesanother in' a suitable mixer. By intimate contact, the particles exchange electrons and thereby materials of different nature acquire either a positive or a negative charge. Recharging is preferably carriedoutina suitable mixer, such as a rotating cylinder, a paddle mixer, or the like, partially or wholly, of metal construction, such as iron, steel, copper, copper alloys, and the like.
.Mixtures of materials respond differently depending upon the relative work functions ofthe materials of the concentrate and the added-component of different work function, and therefore, generalizations applicable in all situations are difiicult to setforth. A material may beof suchrnature as toimpart toxphosphate a charge of greater to state, therefore, that combinations of ingredients or ingredients plus material of the mixer where the mixer may act as a donor element should result in the charging of the concentrate material whereby particles of one kind are given a charge and particles of another type acquire a charge of different character or dififerent magnitude such that they may be effectively separated by passage through an electrostatic separating unit.
In the preferred embodiment, after intimate contacting, the added material is segregated by screening. The now charged concentrate is next subjected to one or more passes through electrostatic fields as freely-falling bodies, i. e., in a path normally not in contact with the electrodes. In both the initial stages of separation and the final stages of separation, the strength of the electrostatic field which will effectively alter the path of particle movement varies withthe average particle size of the feed to the separatorunit. The. field gradient in such operations may vary from 3,000 volts per inch of distance between electrodesin' separating material of relatively fine particle size to 15,000 volts per inch of distance separating electrodes for beneticiationof' coarser particles. In all such discussion of field strength, it' must be borne in mind that corona discharges which ionize air are to be.
avoided. Ingcneral, it is preferred tooperateat a total impressed difference of potcntial' in the range of about 50,000 volts to about 250,000 volts. This voltage should be maintained at a high direct voltage potential substantially free of alternating current components, i. e., filtered D. C. current should'be low in theso-called A. C. ripple. A steady and relativelyinexpensive supply of D. C. voltage may also be obtained by the use of such equipment as radio frequency power supply.
The invention will be more fully understood from the following description taken in conjunction with the attached flow sheet, it being understood that the foregoing fiow sheet illustrates but onemethod of taking advantage of the invention, i'. e.,. processing of phosphate concentrate, and that other equiv-alentmethods will be obvious, i. e., processing of desired component fractions, such as tail fractions, middling fractions, etc.
Referring to the flow sheet for phosphate beneficiation, ore of a mesh size in .the range between about 14 mesh and about 200 meshpasses fromstorage bin 10 to a heating station 11 where the. ore material is: raised to a temperature in the range :betweenabout 200 F and about 350 F. or even up to about. 500 F. Preferably while still hot, the dried material isconveyed to. a chargingstation 12 where the particles-are induced to take on an electricalcharge, as by passage over a grounded contact surface of .graphite, lead, zinc,.aluminum,.copper, tin, and the like. trostatic separation unit- 13 whichamay consist of one or more stages of electrostatic separation. At separation unit 13 there is produced a throw-away .tail fraction 14 and an intermediate concentrate 15'. The intermediate concentrate 15 is commingled with coarse material, such as silica, of a particle size appreciably larger than that of the largest particle of, the concentrateat .the mixerelectron recharging: station 16. The mixed and charged material issuing fromgstationlti'in the preferred embodiment of the invention is conveyed to: screening station 17 where the coarse material, such as silica, is removed. The said coarse material is returned by conveyor 18 to coarse material storage .19- pending recycling todhe mixerrecharging station 16. The charged concentrate is then passed with or Without reheating to an electrostatici separation unit 20. Upon passage through one or more stages ofelectrostatic separation, at least two products, and usually .three products, are collected; namely, a final concentrate. fraction 21,; a middling fraction 22,which generally is recycled; to recortenanornponent therefrom, and a tail fractionlzfla The charged feed is next delivered to an 0166.
In an alternative mode of operation, the intermediate concentrate 15 is commingled with coarse material, such as silica, of a particle size appreciably larger than that of the concentrate at the mixer-charging station 16. The mixed and charged material issuing from station 16 is moved by conveyor 25 to electrostatic separation unit 20. Upon passage through one or more stages of electrostatic separation, at least two products, and usually three prodnets are collected; namely, a predominantly concentrate fraction 21, a middling fraction 22, and a predominantly tail component fraction 23. Each of these fractions, or only some, may be conveyed to a screening station 26, depending upon the nature of the coarse material where the coarse material may be separated, if desired. If the coarse, material is to be recycled, it is returned to storage station 19 by conveyor 27. Materials which may be either concentrate or tail, or both, collected individually, are segregated for storage or for further processing.
The following examples are given to illustrate an application of the instant novel process to Florida phosphate rock and to sylvinite ore and are not to be construed as limiting the invention thereto.
Example 1 Florida phosphate ore was washed to produce a lowgrade Florida phosphate pebble ore having a B. P. L. content of approximately 30%. The pebble material had a particle size in the range of about 14 and about 200 mesh. This material was dried at a temperature of approximately 225 F. The pebble material was passed while hot through four stages of electrostatic separation at which time a concentrate was produced constituting approximately 20% by weight of the feed and having approximately 73.5% B. P. L. content and approximately 8% of insoluble material. These separations were each effected by passage of feed material at a rate of approximately one ton per hour per linear foot of electrode between feet long electrodes spaced approximately 9 inches apart and having a difference of potential impressed thereon such that the field gradient was approximately 10,000 volts per inch of distance separating the electrodes.
The intermediate concentrate was segregated into two portions for comparative tests. Upon passage of the first portion through a fifth stage of electrostatic separation under identical electrostatic conditions as was maintained previously, a concentrate and tail was produced of substantially identical analyses showing that no effective separation was being accomplished.
The second portion of the intermediate concentrate was mixed with 20% by weight of coarse silica of a particle size of about +10 mesh. The mixture was then agitated in an iron paddle mixer allowing the mixture a retention period of about twenty minutes. The coarse silica was recovered by seiving the mixture on a 10 mesh Tyler standard screen. The concentrate passing through the screen was delivered at a rate of approximately one ton per hour per linear foot of electrode through a fifth stage of electrostatic separation. The concentrate recovered had approximately 78% B. P. L. content and approximately 2.5% of insoluble material. This concentrate constituted a recovery of approximately 70% of the original phosphate content as premium grade pebble material. The middling phosphte stream which was to be recycled accounted for approximately 17% of the phosphate content of the original phosphate pebble material. A comparison of the results is as follows:
As can be seen from the above comparison, the separation effected in the fifth stage produces a premium grade phosphate and, by a recycling system for the high B. P. L. content tail, an approximately recovery of the phosphate can be effected as this high-grade product.
Example II Slime-bearing sylvinite ore from the Carlsbad section of New Mexico was crushed and then comm-inuted in a hammer mill. The comminuted ore was screened to produce a fraction containing particles in the range between about 14 mesh and about 200 mesh size. This granular sylvinite feed was heated to approximately 800 F. Heating when the solids attained this temperature, was continued for about five minutes. The material was then removed from the heating unit and cooled to approximately 375 F. The particles were delivered to a feed hopper and cascaded downwardly through a vibratory cast-iron trough. The granular material differentially charged, halite charged positively, and sylvite charged negatively, cooled to about 225 F. during delivery and was allowed to drop between vertical electrodes at a rate of approximately 2000 pounds per hour per foot of horizontal electrode breadth. The electrodes had a difference of potential of approximately 100,000 volts impressed thereon giving a field gradient of approximately 10,000 volts per inch of distance between oppositely charged electrodes. In the first pass through the electrodes, a concentrate was recovered. This concentrate was split into two portions. The first portion was reheated for one hour in an oven held at approximately 800 F. This reheated portion was screened to remove +28 mesh size material and then was passed through an electrostatic unit identical to that used for the first or rougher separation.
The second portion of this sylvite concentrate was mixed with halite crystalline material of a particle size of about 14 mesh. This mixture containing a 2 to 1 ratio by weight of second portion of the concentrate and added halite was heated to 800 F. in the same manner as the first portion of the concentrate. The reheated mixture during cooling was agitated in a stirring mixer. The agitated mixture was then screened to remove the added material and then was passed through the same electrostatic unit as was used for separation of the first portion of the concentrate.
The assay of the various concentrates shows that addition of coarse halite to the sylvinite rougher concentrate improves the separation. These assays are as follows:
In each case the recovery of KCl in the final concentrate was 55% of the weight of sylvite in the rougher concentrate used as feed material to the last separation.
This application is a continuation-impart of application Serial No. 222,690, filed April 24, 1951, now abandoned.
Having thus fully described and illustrated the character of the invention, what is desired to be secured and claimed by Letters Patent is:
1. A method of beneficiating ore which comprises subjecting a multicomponent mineral ore feed to at least one electrostatic separation, mixing with the desired component fraction produced by said separations a predetermined quantity of solid particles of material of work function different from the mineral component being concentrated, agitating the mixture whereby the material in the fraction is induced selectively to accept an electrical charge, and subjecting the charged ore fraction to additional electrostatic separation.
2. A method of beneficiating ore which comprises subjecting a nonconductor multicomponent mineral ore feed to atleast one electrostatic separation, mixing with the concentrate produced by said separations a predetermined quantity of solid particles of material of work function different from the mineral component being concentrated and agitating the mixture whereby the concentrate is induced selectively to accept an electrical charge, and subjecting the charged ore concentrate, material to additional electrostatic separation.
3. A method of *beneficiating ore which comprises subjecting a 'rnulticomponent,nonconductor mineral ore feed to at least one electrostatic separation, adding to the concentrate produced a predetermined quantity of solid particles of material of workwfunction different from the mineral component being concentrated, agitating the mixture under conditions to effect tribo-electrifica-tion, and subjecting the charged ore concentrate material to electrostatic separation.
4. A method Ofbeneficiating ore which comprisessubjecting a nonconductor mineral ore feed to at least .one
electrostatic separation, mixing with the concentrate producedta predetermin'ed'quantity of solid particles ofmaterial of work function different from the mineral ,component being concentrated and agitating the/mixture whereby the concentrate is induced selectively to accept an electrical charge, separating the, added material from the ore concentrate, and subjecting the charged ore concentrate material to additional electrostatic separation.
5. A method of heneficiating ore which comprises subjecting a nonconduc-tor mineral ore feed to at least one. electrostatic separation, mixing with the concentrate produced a predetermined quantity of solid particles of material of work functions different from the mineralcomponent being concentrated whereby the concentrate is induced selectively to accept an electrical charge, segregating the added material by mechanical means, and subjecting the charged concentrate to the attractive and repulsive forces of one or more electrostatic fields.
6. A method of beneficiating ore which comprises subjecting 'a nonconductor mineral ore feedhaving a particle size range between about 14 mesh and about 325 mesh to at least one electrostatic separation, mixing with the concentrate produced by said separations a predetermined quantity of solid particles of material of work function different from the, mineral component being concentrated having a particle size larger than the largest particle of the ore feed and agitating the mixture whereby the concentrate is induced selectively to accept an electrical charge, and subjecting the charged ore concentrate ma solid particles of material of work function diflerent from the mineral component being concentrated and having a particle size range between about 4- mesh and about 10 mesh, and subjecting thecharged ore concentrate material to further electrostatic separation.
8. A method of .beneficiating ore which comprises subjecting a nonconductor mineral ore feed having -a particle size range between about 14 mesh and about 200 mesh to at leastone electrostatic separation, mixing with the concentrate produced a predetermined quantity of solid particles of material having a particle size range between about 4 mesh and about 10 mesh and of work function different from the mineral component being conentrated, screening the mixture to recover the material having a particle size range betwen about4 mesh and about 10 mesh, and sub: jecting the charged ore concentrate material to further electrostatic separation.
9. A method of beneficiating ore which comprises subjecting a nonconductor mineral ore feed having a particle size in the range between about 14 mesh and about 200 mesh to at least one electrostatic separation,
mixing with the concentrate produced a predetermined quantitycf soild particles ofmaterial of work function ditferentirom the mineral component being concentrated and having a particle size in the range between about 4 mesh and about 10 mesh, screening the mixture to recover the material having a particle size between about 4 meshand about 10 mesh, subjecting the charged ore concentrate material to electrostatic separations as freelyfalling bodies, and collecting at least aconcentrate fraction and a tail fraction in the vicinity of the lower portions of the electrodes bounding said electrostatic field.
10., A process as in claim 9 wherein the concentrate fraction is screened to recover the beneficiated ore fraction.
11. A method of .beneficiating ore which comprises subjecting a relatively uniform particle size nonconductor mineral ore feed to at least one electrostatic separation in an electrostatic field having a field gradient in the range between about 3,000 volts per inch andabout 15,000 volts perinch of distance separating electrodes, mixing with the concentrate produced by said separations a predetermined quantity of 'solid particles of material of different physical characteristics and of work function dilferent from the mineral component being concentrated whereby the concentrate is induced selectively to accept an electrical charge, and'subjecting the charged ore concentrate material to additional electrostatic separation.
12. A method ofbeneficiating phosphate ore which comprises subjecting a raw phosphate feed having a particle size range between about 14 mesh and about 200 mesh to'at least one electrostatic separation, adding to the concentrate produced silica having a particle size range between'about 4 and about 10 mesh, agitating the mixture under conditions to efiiect tribe-electrification, screening the coarsesil'ica from the agitated mixture, and subjecting the charged phosphate material to further electrostatic separation.
13. A method of beneficiating potash ore which comprises subjecting potash ore having a particle size range between about 14 mesh and about 200 mesh to at least one electrostatic separation, adding to the concentrate produced halite material having a particle size larger than about 14 mesh, agitating the mixture under conditions to effect tribo-electrification, screening the coarse halite material from the agitated mixture, and subjecting the c-hargedpotash concentrate to further electrostatic separation.
14. A method of beneficiating electrostatically prepared ore concentrates which exhibit substantially no response to an electrostaticfield due to loss of charge during electrostatic separation which comprises mixing with said concentrate a predetermined quantity of solid particles of material of work function different from the mineral component being concentrated whereby the concentrate is induced selectively to accept an electrical charge, and subjecting the charged ore concentrate material to additional electrostatic separation.
15. A method of beneficiating electrostatically prepared iore concentrates which exhibit substantially no response to an electrostatic .field due to loss of charge during electrostatic separation which comprises adding to the concentrate a predetermined-quantity of solidparticlcs of material of work function different from the mineral component being concentrated, agitating the mixture under conditions to effect tribo-electrification, and subjecting the charged ore concentrate material to electrostatic separation.
16. A method of beneficiating electrostatically prepared ore concentrates which exhibit substantially no response to an electrostatic field due to loss of charge during electrostatic separation which comprises mixing with the concentrate a predetermined quantity of solid particles of material of Work function different from the mineral component being concentrated whereby the concentrate is induced. selectively to accept an electrical charge, segregating the added material by mechanical means, and subjecting the charged concentrate to the attractive and repulsive forces of one or more electrostatic fields.
17. A method of beneficiating electrostatically prepared ore concentrates having a particle size range of between about 14 mesh and about 200 mesh which exhibit substantially no response to an electrostatic field due to loss of charges during electrostatic separations which comprises mixing with the concentrate a predetermined quantity of solid particles of material of work function different from the mineral component being concentrated and having a particle size range between about 4 mesh and about mesh, and subjecting the charged ore concentrate material to further electrostatic separation.
18. A method of beneficiating electrostatically prepared ore concentrates which exhibit substantially no response to an electrostatic field due to loss of charges during electrostatic separation which comprises mixing with the concentrate a predetermined quantity of solid particles of material of work function different from the mineral component being concentrated and agitating the mixture whereby the concentrate is induced selectively to accept an electrical charge, and subjecting the charged ore concentrate material to additional electrostatic separation in an electrostatic field having a field gradient in the range between about 3,000 volts per inch and about 15,000 volts per inch of distance separating electrodes.
'19. A method of beneficiating electrostatically prepared ore concentrates having a particle size in the range between about 14 mesh and about 200 mesh and which exhibit substantially no response to an electrostatic field due to loss of charges during electrostatic separation which comprises mixing with the concentrate a predetermined quantity of solid particles of material of work function different from the mineral component being concentrated, screening the mixture to recover the nonconductor material having a particle size range between about 4 mesh and about 10 mesh, and subjecting the charged ore concentrate material to at least one electrostatic separation as freely-falling bodies, and collecting at least a concentrate fraction and a tail fraction in the vicinity of the lower portions of the electrodes bounding said electrostatic field.
20. A method of beneficiating electrostatically prepared Florida phosphate ore concentrates having a particle size range between about 14 mesh and about 200 mesh and which exhibit substantially no response to an electrostatic field due to loss of charges during electrostatic separation which comprises adding to the concentrate silica having a particle size range between about 4 'mesh and about 10 mesh, agitating the mixture under conditions to eflfect tribo-electrification screening the coarse silica from the agitated mixture, and subjecting the charged ore concentrate material to further electrostatic separation.
References Cited in the file of this patent UNITED STATES PATENTS Edison Mar. 15, 1904 Johnson Apr. 23, 1940 OTHER REFERENCES
Claims (1)
1.A METHOD OF BENEFICIATING ORE WHICH COMPRISES SUBJECTING A MULTICOMPONENT MINERAL ORE FEED TO AT LEAST ONE ELECTROSTATIC SEPARATION, MIXING WITH THE DESIRED COMPONENT FRACTION PRODUCED BY SAID SEPARATIONS A PREDE-
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US382918A US2805770A (en) | 1953-09-29 | 1953-09-29 | Method of beneficiating multicomponent ore |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US382918A US2805770A (en) | 1953-09-29 | 1953-09-29 | Method of beneficiating multicomponent ore |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2805770A true US2805770A (en) | 1957-09-10 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US382918A Expired - Lifetime US2805770A (en) | 1953-09-29 | 1953-09-29 | Method of beneficiating multicomponent ore |
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| US (1) | US2805770A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2997171A (en) * | 1958-06-02 | 1961-08-22 | Int Minerals & Chem Corp | Method for beneficiating potash materials |
| US3407930A (en) * | 1963-06-27 | 1968-10-29 | Sames Sa De Machines Electrost | Method and apparatus for the electrostatic sorting of granular materials |
| US6681938B1 (en) * | 2001-06-12 | 2004-01-27 | The United States Of America As Represented By The United States Department Of Energy | Device and method for separating minerals, carbon and cement additives from fly ash |
| US9227849B2 (en) | 2012-07-24 | 2016-01-05 | Bio Techno Terra, LLC | Systems and methods for processing sylvinite and carnallite ores |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US754756A (en) * | 1903-05-29 | 1904-03-15 | Thomas A Edison | Process of separating ores from magnetic gangue. |
| US2197865A (en) * | 1938-05-02 | 1940-04-23 | Ritter Products Corp | Process of concentrating phosphate bearing minerals |
-
1953
- 1953-09-29 US US382918A patent/US2805770A/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US754756A (en) * | 1903-05-29 | 1904-03-15 | Thomas A Edison | Process of separating ores from magnetic gangue. |
| US2197865A (en) * | 1938-05-02 | 1940-04-23 | Ritter Products Corp | Process of concentrating phosphate bearing minerals |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2997171A (en) * | 1958-06-02 | 1961-08-22 | Int Minerals & Chem Corp | Method for beneficiating potash materials |
| US3407930A (en) * | 1963-06-27 | 1968-10-29 | Sames Sa De Machines Electrost | Method and apparatus for the electrostatic sorting of granular materials |
| US6681938B1 (en) * | 2001-06-12 | 2004-01-27 | The United States Of America As Represented By The United States Department Of Energy | Device and method for separating minerals, carbon and cement additives from fly ash |
| US9227849B2 (en) | 2012-07-24 | 2016-01-05 | Bio Techno Terra, LLC | Systems and methods for processing sylvinite and carnallite ores |
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