US2794037A - Nonspreading lubricant - Google Patents
Nonspreading lubricant Download PDFInfo
- Publication number
- US2794037A US2794037A US413474A US41347454A US2794037A US 2794037 A US2794037 A US 2794037A US 413474 A US413474 A US 413474A US 41347454 A US41347454 A US 41347454A US 2794037 A US2794037 A US 2794037A
- Authority
- US
- United States
- Prior art keywords
- lubricant
- nonspreading
- spread
- oil
- friction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000314 lubricant Substances 0.000 title description 7
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- KGYYLUNYOCBBME-UHFFFAOYSA-M 4-fluoro-2-phenyl-4-(4-propylcyclohexyl)cyclohexa-1,5-diene-1-carboxylate Chemical compound C1CC(CCC)CCC1C1(F)C=CC(C([O-])=O)=C(C=2C=CC=CC=2)C1 KGYYLUNYOCBBME-UHFFFAOYSA-M 0.000 description 2
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 229960002446 octanoic acid Drugs 0.000 description 2
- 241000231739 Rutilus rutilus Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 229910052594 sapphire Inorganic materials 0.000 description 1
- 239000010980 sapphire Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B31/00—Bearings; Point suspensions or counter-point suspensions; Pivot bearings; Single parts therefor
- G04B31/08—Lubrication
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M3/00—Liquid compositions essentially based on lubricating components other than mineral lubricating oils or fatty oils and their use as lubricants; Use as lubricants of single liquid substances
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/287—Partial esters
- C10M2207/289—Partial esters containing free hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/06—Instruments or other precision apparatus, e.g. damping fluids
Definitions
- a spread resistant lubricant comprising alpha-phenyl, gamma-caprylate glycerol, characterized by having a pour point of 40 F., a coefficient of friction of .08, a good resistance to spread and a low evaporation rate.
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
NUNSPREADING LUBRICANT Joseph S. Martin, .lr., Lancaster, Pa., assignor to Hamilton Watch Company, Lancaster, Pa.
No Drawing. Application March 1, 1954, Serial No. 413,474
1 Claim. ((1260-4105) This invention relates to a new composition of matter to be used as a lubricant for clocks, watches or other delicate instruments.
In the lubrication of fine instruments, such as clocks, watches and meters, one of the main problems is to retain the oil at the bearing, it being a tendency of the oil to spread over the metal and dissipate itself. As it is impossible to enclose these bearings to prevent the spread of the lubricant, an oil which has spread resistant properties is highly desirable.
It is the object of the present invention to provide an oil which is spread resistant and which, with this feature, retains other desirable qualities.
It is a still further object of the present invention to provide a lubricant made from the reaction product of caprylic acid and glycidyl phenyl ether.
It is a still further object of the present invention to provide a lubricant which will have a good viscosity, a pour point at -40 F. or below, which has resistance to spread, a low evaporation rate and a steel against sapphire coefiicient of friction in the neighborhood of .08.
The mono-ester reaction product of caprylic acid and glycidyl phenyl ether possesses the above qualifications. The preparation of this material is as follows:
States Patent 2,794,037 Patented May 28, 1957 "ice Kinematic viscosity F., centistokes--- 30 Pour point, F Minus 40 Refractive index 25 C 1.4935 Specific gravity 25/25 C 1.040 Resistance to spreading Good Evaporation rate Low Coefiicient of friction 0.080
What is claimed is:
A spread resistant lubricant, comprising alpha-phenyl, gamma-caprylate glycerol, characterized by having a pour point of 40 F., a coefficient of friction of .08, a good resistance to spread and a low evaporation rate.
References Cited in the file of this patent UNITED STATES PATENTS 2,191,039 Dickey Feb. 20, 1940 2,250,265 Kapp et a1. July 22, 1941 2,351,025 Marple June 13, 1944 2,534,611 Martin Dec. 19, 1950 2,559,171 Roach July 3, 1951 FOREIGN PATENTS 716,086 Great Britain Sept. 29, 1954
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US413474A US2794037A (en) | 1954-03-01 | 1954-03-01 | Nonspreading lubricant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US413474A US2794037A (en) | 1954-03-01 | 1954-03-01 | Nonspreading lubricant |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2794037A true US2794037A (en) | 1957-05-28 |
Family
ID=23637360
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US413474A Expired - Lifetime US2794037A (en) | 1954-03-01 | 1954-03-01 | Nonspreading lubricant |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2794037A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3312722A (en) * | 1963-03-13 | 1967-04-04 | Lever Brothers Ltd | Higher fatty acid esters of ether and thioether glycerols |
| US3972914A (en) * | 1973-03-22 | 1976-08-03 | L'oreal | Novel derivatives of glycerol |
| WO2008052378A3 (en) * | 2006-11-02 | 2008-08-14 | Rolex Sa | Timepiece |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2191039A (en) * | 1938-12-16 | 1940-02-20 | Eastman Kodak Co | Yarn conditioning process and composition therefor |
| US2250265A (en) * | 1938-07-27 | 1941-07-22 | Nat Oil Prod Co | Lubricant |
| US2351025A (en) * | 1944-06-13 | Preparation of aryl ethers of | ||
| US2534611A (en) * | 1949-02-12 | 1950-12-19 | Hamilton Watch Co | Watch oil |
| US2559171A (en) * | 1946-01-04 | 1951-07-03 | Gen Mills Inc | Unsaturated ether esters |
| GB716086A (en) * | 1951-12-21 | 1954-09-29 | Standard Oil Dev Co | Improvements in or relating to synthetic lubricants |
-
1954
- 1954-03-01 US US413474A patent/US2794037A/en not_active Expired - Lifetime
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2351025A (en) * | 1944-06-13 | Preparation of aryl ethers of | ||
| US2250265A (en) * | 1938-07-27 | 1941-07-22 | Nat Oil Prod Co | Lubricant |
| US2191039A (en) * | 1938-12-16 | 1940-02-20 | Eastman Kodak Co | Yarn conditioning process and composition therefor |
| US2559171A (en) * | 1946-01-04 | 1951-07-03 | Gen Mills Inc | Unsaturated ether esters |
| US2534611A (en) * | 1949-02-12 | 1950-12-19 | Hamilton Watch Co | Watch oil |
| GB716086A (en) * | 1951-12-21 | 1954-09-29 | Standard Oil Dev Co | Improvements in or relating to synthetic lubricants |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3312722A (en) * | 1963-03-13 | 1967-04-04 | Lever Brothers Ltd | Higher fatty acid esters of ether and thioether glycerols |
| US3972914A (en) * | 1973-03-22 | 1976-08-03 | L'oreal | Novel derivatives of glycerol |
| WO2008052378A3 (en) * | 2006-11-02 | 2008-08-14 | Rolex Sa | Timepiece |
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