US2535794A - Method of preparing ferrous metal objects for the application of synthetic resins - Google Patents
Method of preparing ferrous metal objects for the application of synthetic resins Download PDFInfo
- Publication number
- US2535794A US2535794A US724248A US72424847A US2535794A US 2535794 A US2535794 A US 2535794A US 724248 A US724248 A US 724248A US 72424847 A US72424847 A US 72424847A US 2535794 A US2535794 A US 2535794A
- Authority
- US
- United States
- Prior art keywords
- dichromate
- ferrous metal
- acid
- solution
- application
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052751 metal Inorganic materials 0.000 title claims description 19
- 239000002184 metal Substances 0.000 title claims description 19
- 238000000034 method Methods 0.000 title claims description 15
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 title claims description 11
- 229920003002 synthetic resin Polymers 0.000 title description 4
- 239000000057 synthetic resin Substances 0.000 title description 4
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 claims description 14
- 239000002253 acid Substances 0.000 claims description 10
- 238000000576 coating method Methods 0.000 claims description 9
- 229920001568 phenolic resin Polymers 0.000 claims description 9
- 239000011248 coating agent Substances 0.000 claims description 8
- 238000007598 dipping method Methods 0.000 claims description 7
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 6
- 229910052783 alkali metal Inorganic materials 0.000 claims description 5
- 238000005530 etching Methods 0.000 claims description 4
- 239000005011 phenolic resin Substances 0.000 claims description 3
- 150000001340 alkali metals Chemical class 0.000 claims description 2
- 229910000831 Steel Inorganic materials 0.000 description 7
- 239000010959 steel Substances 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- -1 dichromate ions Chemical class 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 239000001117 sulphuric acid Substances 0.000 description 4
- 235000011149 sulphuric acid Nutrition 0.000 description 4
- 239000003513 alkali Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- 239000003518 caustics Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 210000003298 dental enamel Anatomy 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 239000002966 varnish Substances 0.000 description 2
- JHWIEAWILPSRMU-UHFFFAOYSA-N 2-methyl-3-pyrimidin-4-ylpropanoic acid Chemical compound OC(=O)C(C)CC1=CC=NC=N1 JHWIEAWILPSRMU-UHFFFAOYSA-N 0.000 description 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- OXLBLZDGMWMXSM-UHFFFAOYSA-N dioxido(dioxo)chromium;iron(3+) Chemical compound [Fe+3].[Fe+3].[O-][Cr]([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Cr]([O-])(=O)=O OXLBLZDGMWMXSM-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 229910001447 ferric ion Inorganic materials 0.000 description 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Substances O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 1
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000005488 sandblasting Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
- B05D7/16—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies using synthetic lacquers or varnishes
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/24—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing hexavalent chromium compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31942—Of aldehyde or ketone condensation product
Definitions
- This invention relates to a method of treating steel surfaces to prepare them for the application of oil-free synthetic resins, and more particularly for the application of oil-free phenol-formaldehyde resins.
- a common method of preparation is to apply a sand blast or its equivalent; the sand blasting process, however, involves the human element to such an extent that it is not always uniform and the present method gives a process which may be mechanically controlled and produces better and more uniform results than the sand blast treatment.
- the steel or other ferrous metal surfaces are cleaned of any adhering grease by a suitable grease solvent.
- a suitable grease solvent This is preferably a 3 to 5% solution of caustic alkali at a temperature of 15 to 80 C. Ordinarily two to fifteen minutes treatment is required, depending upon the surface condition ofv the steel.
- the metal is washed free of alkali and is then etched with a suitable acid to produce a clean crystalline appearance. This may be accomplished by first dipping the metal in a solution of hydrochloric acid of 15 to 38% concentration at a temperature of 25 to 90 C. for 3 to 30 minutes. A minute period is usually satisfactory in 30% hydrochloric acid at 75 C.
- the metal is then rinsed in water and dipped momentarily in a 1% solution of alkali metal dlchromate.
- This dichromate solution should contain a small proportion of added alkali material, suitably sodium carbonate in amounts from 1 to 2% of the dichromate may be used.
- the percentage of dichromate may be reduced slightly, or it may be increased somewhat, but increasing the amount of the material does not add to the effectiveness of the process.
- the effect of the acid dip is to create a thin film of a ferric salt on the surface of the metal.
- the ferric ions on the surface of the metal react with the dichromate ions forming ferric chromate, which is insoluble under the conditions and adheres to the metal in the form of a thin, invisible, probably monomolecular coating.
- the metal may be dipped into" to 70% nitric acid at room temperature (17 C.) for onehalf to four minutes, followed by a dip, after cleaning, in 15 to 75% sulphuric acid.
- the sulphuric acid is maintained at 25 to 90 C. and immersion may be from 1 to 15 minutes.
- the metal is treated as before in a dichromate solution.
- Steel or other similar ferrous meal materials when treated in this manner may be Water rinsed and dried at relatively high temperatures without any oxidation which will interfere with the adherence of a synthetic varnish or enamel. The surface will not rust for periods of twentyfour hours or even somewhat longer.
- the steel surface when so prepared has remarkable adherence to synthetic varnishes and enamels, such as phenolic, either urea or formaldehyde, alkyd, vinyl and chlorinated rubber type.
- synthetic varnishes and enamels such as phenolic, either urea or formaldehyde, alkyd, vinyl and chlorinated rubber type.
- the surface is especially adherent to oilfree phenol formaldehyde resins of the type disclosed in Hempel Patent No. 2,198,939. Those resins are applied by spraying or dipping while in the liquid A stage, and then are baked to the infusible, hard C stage.
- a steel sheet was immersed in a 5% solution of caustic maintained at a temperature of C. and held therein for five minutes. It was then washed in Water and dipped for twelve minutes in a solution of 25% sulphuric acid maintained at 75 C. It was then rinsed and dipped in a 1% solution of sodium dichromate containing sodium. carbonate in an amount approximately 2% of the dichromate. It was immediately removed from this bath, rinsed in water while still wet from the dichromate soltuion and dried. It was then coated with an oil-free phenol formaldehyde resin of the type disclosed in Hempel Patent No. 2,198,939.
- the method which comprises etching a ferrous metal object with an acid, removing the acid, dipping the object in a dilute solution of alkali metal dichromate, removing the object therefrom, washing the object while still wet from the dichromate solution and drying it and then baking an oil-free phenolic resin coating thereon.
- the method which comprises etching a ferrous metal object with an acid chosen from the class consisting of hydrochloric, esulphuric and nitric acids, removing the acid, dipping the object in an approximately 1% solution of alkali metal dichromate to which has been added :80- dium carbonate in an amount of 1 to 2% 0f the dichromate, washing the object in water'while still wet from the dichromate solution and drying it, applying a protective coating of an oil-'.free ;.phenol:-formaldehyde resin in the A-stage:1to thelobiectsan'd then baking the coating thereon.
- an acid chosen from the class consisting of hydrochloric, esulphuric and nitric acids
- a ferrous metal object havingharbakedrphenolic resin coating thereon prepared by'themethod of claim 1.
- a ferrous metal object having a bakedphw nolic resin coating thereon prepared by the meth- 20 red ofclaim 2.
- a ferrous metal object having a baked, oil-o free phenol-formaldehyde resin coating thereon prepared by the method of claim 4.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Treatment Of Metals (AREA)
Description
Patented Dec. 26, 1950 METHOD OF PREPARING FERROUS METAL OBJECTS FOR THE'APPLICATIQN OF SYN THETIC RESIN S Charles Henry Hempel, Manitowoc, Wis., assignor to Heresite & Chemical Company, a corporation of Wisconsin ,No Drawing. Application January 24, 1947,
Serial No. 724,248
8 Claims. (01. 148-6.2)
This invention relates to a method of treating steel surfaces to prepare them for the application of oil-free synthetic resins, and more particularly for the application of oil-free phenol-formaldehyde resins.
It has been recognized that phenol-formaldehyde type coatings, when oil-free, cannot be applied to unprepared steel surfaces.
A common method of preparation is to apply a sand blast or its equivalent; the sand blasting process, however, involves the human element to such an extent that it is not always uniform and the present method gives a process which may be mechanically controlled and produces better and more uniform results than the sand blast treatment.
In carrying out the present process, the steel or other ferrous metal surfaces are cleaned of any adhering grease by a suitable grease solvent. This is preferably a 3 to 5% solution of caustic alkali at a temperature of 15 to 80 C. Ordinarily two to fifteen minutes treatment is required, depending upon the surface condition ofv the steel. After cleaning the metal is washed free of alkali and is then etched with a suitable acid to produce a clean crystalline appearance. This may be accomplished by first dipping the metal in a solution of hydrochloric acid of 15 to 38% concentration at a temperature of 25 to 90 C. for 3 to 30 minutes. A minute period is usually satisfactory in 30% hydrochloric acid at 75 C.
The metal is then rinsed in water and dipped momentarily in a 1% solution of alkali metal dlchromate. This dichromate solution should contain a small proportion of added alkali material, suitably sodium carbonate in amounts from 1 to 2% of the dichromate may be used.
The percentage of dichromate may be reduced slightly, or it may be increased somewhat, but increasing the amount of the material does not add to the effectiveness of the process.
The effect of the acid dip is to create a thin film of a ferric salt on the surface of the metal. Upon dipping the metal into the dichromate solution, the ferric ions on the surface of the metal react with the dichromate ions forming ferric chromate, which is insoluble under the conditions and adheres to the metal in the form of a thin, invisible, probably monomolecular coating.
Instead of the use of the hydrochloric acid bath the metal may be dipped into" to 70% nitric acid at room temperature (17 C.) for onehalf to four minutes, followed by a dip, after cleaning, in 15 to 75% sulphuric acid. The sulphuric acid is maintained at 25 to 90 C. and immersion may be from 1 to 15 minutes. After removal from the sulphuric acid the metal is treated as before in a dichromate solution.
Steel or other similar ferrous meal materials when treated in this manner may be Water rinsed and dried at relatively high temperatures without any oxidation which will interfere with the adherence of a synthetic varnish or enamel. The surface will not rust for periods of twentyfour hours or even somewhat longer.
The steel surface when so prepared has remarkable adherence to synthetic varnishes and enamels, such as phenolic, either urea or formaldehyde, alkyd, vinyl and chlorinated rubber type. The surface is especially adherent to oilfree phenol formaldehyde resins of the type disclosed in Hempel Patent No. 2,198,939. Those resins are applied by spraying or dipping while in the liquid A stage, and then are baked to the infusible, hard C stage.
As a specific example of the invention, a steel sheet was immersed in a 5% solution of caustic maintained at a temperature of C. and held therein for five minutes. It was then washed in Water and dipped for twelve minutes in a solution of 25% sulphuric acid maintained at 75 C. It was then rinsed and dipped in a 1% solution of sodium dichromate containing sodium. carbonate in an amount approximately 2% of the dichromate. It was immediately removed from this bath, rinsed in water while still wet from the dichromate soltuion and dried. It was then coated with an oil-free phenol formaldehyde resin of the type disclosed in Hempel Patent No. 2,198,939.
Iclaim:
1. The method which comprises etching a ferrous metal object with an acid, removing the acid, dipping the object in a dilute solution of alkali metal dichromate, removing the object therefrom, washing the object while still wet from the dichromate solution and drying it and then baking an oil-free phenolic resin coating thereon.
2. The method set forth in claim 1, in which the synthetic resin is a phenol formaldehyde resin.
3. The method for preparing a ferrous metal object for the application of a phenolic resin coating which comprises etching the object with an acid, removing the acid, dipping the object in an approximately 1% solution of alkali metal dichromate to which has been added sodium carbonate in an amount of 1 to 2% of the dichromate, re-
-' moving the object therefrom, washing the oblect in water while still wet from the dichromate solution and then drying the object.
4. The method which comprises etching a ferrous metal object with an acid chosen from the class consisting of hydrochloric, esulphuric and nitric acids, removing the acid, dipping the object in an approximately 1% solution of alkali metal dichromate to which has been added :80- dium carbonate in an amount of 1 to 2% 0f the dichromate, washing the object in water'while still wet from the dichromate solution and drying it, applying a protective coating of an oil-'.free ;.phenol:-formaldehyde resin in the A-stage:1to thelobiectsan'd then baking the coating thereon.
5. A ferrous metal object havingharbakedrphenolic resin coating thereon prepared by'themethod of claim 1.
6. A ferrous metal object having a bakedphw nolic resin coating thereon prepared by the meth- 20 red ofclaim 2.
1:7. Aferrouslmetalobjectpreparedzbyethemethocl'o'f claimfi.
removing the object therefrom,
8. A ferrous metal object having a baked, oil-o free phenol-formaldehyde resin coating thereon prepared by the method of claim 4.
CHARLES HENRY HEMPEL,
TREFERE1\1'.CES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS Number Name Date 12,114,151 ..Romi g Apr. 12, 1938 2498,9359 .LHempel Apr. 30, 1940 2288;182 :Curtin June 30, 1942 2,314,565 .Thompson Mar. 23, 1943 1 21315564 "Thompson et a1 Apr. 6, 1943 "2, i20,134 Hem'pel et a1. May 6, 1947 FOREIGN PATENTS ,Number Country :Date
" 799,695 ,France :Apr. 1aI-rl 1936
Claims (1)
1. THE METHOD WHICH COMPRISES ETCHING A FERROUS METAL OBJECT WITH AN ACID, REMOVING THE ACID, DIPPING HTE OBJECT IN A DILUTE SOLUTION OF ALKALI METAL DICHROMATE, REMOVING THE OBJECT THEREFROM, WASHING THE OBJECT WHILE STILL WET FROM THE DICHROMATE SOLUTION AND DRYIN GIT AND THEN BAKING AN OIL-FREE PHENOLIC RESIN COATING THEREON.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US724248A US2535794A (en) | 1947-01-24 | 1947-01-24 | Method of preparing ferrous metal objects for the application of synthetic resins |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US724248A US2535794A (en) | 1947-01-24 | 1947-01-24 | Method of preparing ferrous metal objects for the application of synthetic resins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2535794A true US2535794A (en) | 1950-12-26 |
Family
ID=24909653
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US724248A Expired - Lifetime US2535794A (en) | 1947-01-24 | 1947-01-24 | Method of preparing ferrous metal objects for the application of synthetic resins |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2535794A (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2620265A (en) * | 1950-09-28 | 1952-12-02 | Kaiser Aluminium Chem Corp | Composition for treating aluminum and aluminum alloys |
| US2718485A (en) * | 1953-07-21 | 1955-09-20 | Paul P Heinley | Method of bonding mechanical elements |
| US2768103A (en) * | 1952-03-18 | 1956-10-23 | Heintz Mfg Co | Method for coating metals |
| US2768104A (en) * | 1952-03-25 | 1956-10-23 | Heintz Mfg Co | Method for coating iron |
| US2773623A (en) * | 1954-06-01 | 1956-12-11 | Heintz Mfg Co | Corrosion resistant coated steel members and method of making |
| US2777785A (en) * | 1953-07-30 | 1957-01-15 | Heintz Mfg Co | Composition for and method of treating metals as well as the treated product |
| US2811471A (en) * | 1954-05-10 | 1957-10-29 | Connecticut Hard Rubber Co | Polytrifluorochloroethylene-coated aluminum |
| US2837443A (en) * | 1954-07-26 | 1958-06-03 | Eagle Picher Co | Method of porcelain enameling |
| US2853406A (en) * | 1956-04-17 | 1958-09-23 | Kelsey Hayes Co | Metal coating |
| US2887367A (en) * | 1956-11-13 | 1959-05-19 | Ford Motor Co | Resist etching |
| US2895389A (en) * | 1954-09-16 | 1959-07-21 | Reliance Steel Prod Co | Coatings for the traffic bearing surfaces of grating |
| US3036934A (en) * | 1958-03-17 | 1962-05-29 | Bethlehem Steel Corp | Coated article and method of making same |
| US3351421A (en) * | 1965-05-14 | 1967-11-07 | Lockheed Aircraft Corp | Method for treatment of corrosion |
| US5956816A (en) * | 1998-03-18 | 1999-09-28 | Mccrink; David J. | Elastomer coating for buttons, and method therefor |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR799695A (en) * | 1935-03-21 | 1936-06-17 | Pneumatiques Dunlop | Method of temporary protection against rust of stripped surfaces of ferrous metals |
| US2114151A (en) * | 1935-07-09 | 1938-04-12 | American Chem Paint Co | Art of finishing ferrous metal |
| US2198939A (en) * | 1939-09-25 | 1940-04-30 | Heresite & Chemical Company | Pigmented material |
| US2288182A (en) * | 1939-04-06 | 1942-06-30 | Curtin Howe Corp | Container manufacture |
| US2314565A (en) * | 1940-05-29 | 1943-03-23 | Parker Rust Proof Co | Coated ferrous article and method of making the same |
| US2315564A (en) * | 1941-03-27 | 1943-04-06 | Parker Rust Proof Co | Art of coating and fabricating steel articles |
| US2420134A (en) * | 1943-10-18 | 1947-05-06 | Heresite & Chemical Company | Coating composition comprising phenol-formaldehyde resin in a mixture of solvents |
-
1947
- 1947-01-24 US US724248A patent/US2535794A/en not_active Expired - Lifetime
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR799695A (en) * | 1935-03-21 | 1936-06-17 | Pneumatiques Dunlop | Method of temporary protection against rust of stripped surfaces of ferrous metals |
| US2114151A (en) * | 1935-07-09 | 1938-04-12 | American Chem Paint Co | Art of finishing ferrous metal |
| US2288182A (en) * | 1939-04-06 | 1942-06-30 | Curtin Howe Corp | Container manufacture |
| US2198939A (en) * | 1939-09-25 | 1940-04-30 | Heresite & Chemical Company | Pigmented material |
| US2314565A (en) * | 1940-05-29 | 1943-03-23 | Parker Rust Proof Co | Coated ferrous article and method of making the same |
| US2315564A (en) * | 1941-03-27 | 1943-04-06 | Parker Rust Proof Co | Art of coating and fabricating steel articles |
| US2420134A (en) * | 1943-10-18 | 1947-05-06 | Heresite & Chemical Company | Coating composition comprising phenol-formaldehyde resin in a mixture of solvents |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2620265A (en) * | 1950-09-28 | 1952-12-02 | Kaiser Aluminium Chem Corp | Composition for treating aluminum and aluminum alloys |
| US2768103A (en) * | 1952-03-18 | 1956-10-23 | Heintz Mfg Co | Method for coating metals |
| US2768104A (en) * | 1952-03-25 | 1956-10-23 | Heintz Mfg Co | Method for coating iron |
| US2718485A (en) * | 1953-07-21 | 1955-09-20 | Paul P Heinley | Method of bonding mechanical elements |
| US2777785A (en) * | 1953-07-30 | 1957-01-15 | Heintz Mfg Co | Composition for and method of treating metals as well as the treated product |
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| US2895389A (en) * | 1954-09-16 | 1959-07-21 | Reliance Steel Prod Co | Coatings for the traffic bearing surfaces of grating |
| US2853406A (en) * | 1956-04-17 | 1958-09-23 | Kelsey Hayes Co | Metal coating |
| US2887367A (en) * | 1956-11-13 | 1959-05-19 | Ford Motor Co | Resist etching |
| US3036934A (en) * | 1958-03-17 | 1962-05-29 | Bethlehem Steel Corp | Coated article and method of making same |
| US3351421A (en) * | 1965-05-14 | 1967-11-07 | Lockheed Aircraft Corp | Method for treatment of corrosion |
| US5956816A (en) * | 1998-03-18 | 1999-09-28 | Mccrink; David J. | Elastomer coating for buttons, and method therefor |
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