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US2438366A - Drying of textile materials - Google Patents

Drying of textile materials Download PDF

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Publication number
US2438366A
US2438366A US648816A US64881646A US2438366A US 2438366 A US2438366 A US 2438366A US 648816 A US648816 A US 648816A US 64881646 A US64881646 A US 64881646A US 2438366 A US2438366 A US 2438366A
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US
United States
Prior art keywords
fabric
cord
rubber
drying
steam
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US648816A
Inventor
Illingworth James William
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dunlop Rubber Co Ltd
Original Assignee
Dunlop Rubber Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dunlop Rubber Co Ltd filed Critical Dunlop Rubber Co Ltd
Application granted granted Critical
Publication of US2438366A publication Critical patent/US2438366A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/06Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2321/00Characterised by the use of unspecified rubbers

Definitions

  • My present invention relates to the drying of textile materials such as fabrics, cords and yarns which have been treated or impregnated with aqueous preparations, particularly with aqueous dispersions of adhesive materials for bonding rubber to fabrics, cords or yarns.
  • Adhesive materials of the above types may comprise dispersions of plastics or plastic-forming reagents which may also contain some dispersed rubber.
  • suflicient water may be quickly evaporated and reduced to a point where the adhesive material is no longer tacky.
  • the treated fabric is subjected to the action of superheated steam.
  • the steam may be either at atmospheric or superatmospheric pressure or might in some cases be somewhat below atmospheric pressure. Preferably, however, the steam is at atmospheric pressure.
  • a two-fold 1100 denier viscous rayon cord treated with an aqueous preparation or dispersion of adhesive materials of about total solids is passed upwards at the rate of 120 yards per minute through a vertically disposed tube 1 foot long and an internal diameter of 2% inches and having an aperture of inch diameter at the bottom and an aperture of ,inch diameter at the top for the passage of the cord.
  • the water content of the cord on entering the tube after treatment with the aqueous dispersion or preparation may be about 50%, and after emergence from the tube the water content is about 20%, in which condition it may be handled or passed over rollers without risk of sticking.
  • the method is applicable to any cord or fabric treated with an aqueous preparation or dispersion of an adhesive for rubber to textiles.
  • the dispersion may contain a quantity of rubber, such as natural or artificial latex, together with dispersed resins, or it may contain merely a dispersion of resin or resin-forming reagents.
  • aqueous preparations or dispersions are as. follows:
  • the rubber Will include compounding solids.
  • nolic resin forming reagents and subjecting said
  • the specific resins are given only by way of example as it will be understood that their function is a mechanical one, namely to adhere to the fabric or cord or yarn, and also to the rubber with which the fabric, or cord, or yarn is to be impregnated or coated and, therefore, to act as an adhesive.
  • phenol formaldehyde or phenolic resins might be employed either with or without rubber.
  • the resin, or mixture of resins, should be one that will act as an eifective adhesive between the rubber and the textile material.
  • a viscose rayon woven cord which comprises a plurality of parallel cords of viscose rayon held in parallel arrangement by comparatively weak weft threads at intervals larger than the distance between the cords may be treated with any of the above aqueous dispersions and is then dried by the passage vertically through steam introduced at 140 C. into a 3 inch slot having a height of 4 feet and 6 inches and a breadth somewhat greater than the width of the woven cord.
  • the Woven cord After emergence from the upper end of the slot the Woven cord is sufficiently dried to handle without sticking and may be batched in rolls for storage until required without risk of subsequent sticking.
  • the woven cord may be further dried by passage around heated metal rollers without risk of sticking to the surface of the rollers.
  • fabrics impregnated with an aqueous dispersion of an adhesive may be quickly dried sufiiciently for handling, thus enabling large quantities of the fabric to be prepared in apparatus of limited dimensions.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Description

Patented Mar. 23, 1948 UNITED STATES PATENT OFFICE DRYING OF TEXTILE MATERIALS comp any No Drawing. Application February 19, 1946, Serial No. 648,816. In Great Britain April '1, 1943 Section 1, Public Law 690, August 8, 1946 Patent expires February 11, 1964 6 Claims. 1
This invention is a continuation in part of my copending application Ser. No. 553,481, filed September 9, 1944, now abandoned.
My present invention relates to the drying of textile materials such as fabrics, cords and yarns which have been treated or impregnated with aqueous preparations, particularly with aqueous dispersions of adhesive materials for bonding rubber to fabrics, cords or yarns.
Adhesive materials of the above types may comprise dispersions of plastics or plastic-forming reagents which may also contain some dispersed rubber.
Whencords, yarns or fabrics are treated or impregnated with an aqueous dispersion of the above type, whether it contains rubber or not. the resulting coating is tacky until a substantial amount of the water has been evaporated. It cannot, therefore, be handled or passed over rollers until a sufficient amount of the water has been evaporated as, for example, until the water content is reduced below 20%.
The evaporation of water from a tacky aqueous dispersion of the above type in an atmosphere of air is relatively slow and it therefore requires a tall or lengthy drying chamber in which the fabric, cord or yarn may be suspended for a sufiicient time .to permit the evaporation or, if the space is limited the drying must be correspondingly slow.
In my present invention I provide a method whereby suflicient water may be quickly evaporated and reduced to a point where the adhesive material is no longer tacky.
In my present invention the treated fabric is subjected to the action of superheated steam. The steam may be either at atmospheric or superatmospheric pressure or might in some cases be somewhat below atmospheric pressure. Preferably, however, the steam is at atmospheric pressure.
When the impregnated or treated fabric, yarn or cord is drawn through the superheated steam the water content of the aqueous material is immediately vaporized, that is, within a fraction of a second. Consequently, the cord, fabric or yarn may be passed through a steam chamber of limited length at a high speed.
As an illustrative example a two-fold 1100 denier viscous rayon cord treated with an aqueous preparation or dispersion of adhesive materials of about total solids is passed upwards at the rate of 120 yards per minute through a vertically disposed tube 1 foot long and an internal diameter of 2% inches and having an aperture of inch diameter at the bottom and an aperture of ,inch diameter at the top for the passage of the cord.
Steam at atmospheric pressure and at a temperature of C. is introduced into the tube at the same time by way of an inlet near the bottom of the tube.
The water content of the cord on entering the tube after treatment with the aqueous dispersion or preparation may be about 50%, and after emergence from the tube the water content is about 20%, in which condition it may be handled or passed over rollers without risk of sticking.
It will be understood that the above specific figures are given merely by way of example and that in any case a treatment of the impregnated.v or treated fabric'with superheated steam will reduce the moisturecontent of the fabric in'a short time to whatever degree is required to render the fabric non-tacky.
After the cord emerges from the top end of the tube .further drying may take place and after a passage of about 3 feet in the air the cord is,
wound on a bobbin.
The method is applicable to any cord or fabric treated with an aqueous preparation or dispersion of an adhesive for rubber to textiles. The dispersion may contain a quantity of rubber, such as natural or artificial latex, together with dispersed resins, or it may contain merely a dispersion of resin or resin-forming reagents.
Examples of aqueous preparations or dispersions are as. follows:
In the above examples the rubber Will include compounding solids.
nolic resin forming reagents and subjecting said The specific resins are given only by way of example as it will be understood that their function is a mechanical one, namely to adhere to the fabric or cord or yarn, and also to the rubber with which the fabric, or cord, or yarn is to be impregnated or coated and, therefore, to act as an adhesive.
For example instead of formaldehyde and resorcinol, phenol formaldehyde or phenolic resins might be employed either with or without rubber. The resin, or mixture of resins, should be one that will act as an eifective adhesive between the rubber and the textile material.
As a example of a textile cord or fabric a viscose rayon woven cord which comprises a plurality of parallel cords of viscose rayon held in parallel arrangement by comparatively weak weft threads at intervals larger than the distance between the cords may be treated with any of the above aqueous dispersions and is then dried by the passage vertically through steam introduced at 140 C. into a 3 inch slot having a height of 4 feet and 6 inches and a breadth somewhat greater than the width of the woven cord.
After emergence from the upper end of the slot the Woven cord is sufficiently dried to handle without sticking and may be batched in rolls for storage until required without risk of subsequent sticking. The woven cord may be further dried by passage around heated metal rollers without risk of sticking to the surface of the rollers.
Through the above invention, therefore, fabrics impregnated with an aqueous dispersion of an adhesive may be quickly dried sufiiciently for handling, thus enabling large quantities of the fabric to be prepared in apparatus of limited dimensions.
What I claim is? 1. The process of treating tire fabrics which comprises impregnating the fabric with an aqueous dispersion of rubber hydrocarbons and phenolic resin forming reagents and subjecting said fabric for a fraction of a second to dry steam at fabric to dry steam at substantially atmospheric pressure and at a temperature of about C. for a time sufficient to reduce the water content to 20% of the fabric.
3. The process of treating tire fabrics which comprises impregnating the fabric with an aqueous dispersion of rubber hydrocarbons and phenolic resin forming reagents and subjecting said fabric to dry steam at substantially atmospheric pressure to reduce the water content of said fabric to about 20%.
4. The process of treating tire fabrics which comprises impregnating'the fabric with an aqueous dispersion of a composition adhesive to rubber and to fabric and comprisingphenolic resin forming reagents and subjecting said fabric for a fraction of a second to dry steam at substantially atmospheric pressureat a temperature of about 140 C.
5. The process of treating-tire fabrics which comprises impregnating the fabric with an aqueous dispersion of a composition adhesive to rubber and to fabric and comprising phenolic resin forming reagents and subjecting said fabric to dry steam at substantially atmospheric pressure and at a temperature of about 140 C. for a time suflicient to reduce the water content to 20% of the fabric. l
6. The process of treating tirefabrics which comprises impregnating the fabric with an aqueous dispersion of a composition adhesive to rubber and to fabric and comprising'phenolic resin forming reagents and subjecting: said fabric to dry steam at substantially atmospheric pressure to reduce the water content of said fabric to 20%. 1 2 V JAMES ILLINGWORTH.
' REFERENCES CITED The following references are of record inithe file of this patent;
UNITED STATES PATENTS
US648816A 1943-04-01 1946-02-19 Drying of textile materials Expired - Lifetime US2438366A (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2583220A (en) * 1948-12-24 1952-01-22 Dewey And Almy Chem Comp Process of leveling and drying coatings with steam
US2687446A (en) * 1951-04-25 1954-08-24 Dewey And Almy Chem Comp Battery separator
US2879824A (en) * 1955-08-10 1959-03-31 Firestone Tire & Rubber Co Coated tubeless tire chafer strip
US3136654A (en) * 1958-11-18 1964-06-09 Fmc Corp Manufacture of coated material
US3292273A (en) * 1963-02-20 1966-12-20 Celotex Corp Apparatus for drying coatings
US3294570A (en) * 1963-10-31 1966-12-27 Basf Ag Optical brightening of materials of synthetic polyesters and polyamides
US3772070A (en) * 1971-04-05 1973-11-13 Burlington Industries Inc Applying antistatic finish on synthetic textiles
US3916044A (en) * 1970-12-21 1975-10-28 Collins & Aikman Corp Method for improving the flame retardancy of synthetic linear polyesters
US3920865A (en) * 1969-03-29 1975-11-18 Degussa Process of hydrophorizing highly dispersed metal or metalloid oxides
US4007304A (en) * 1972-03-23 1977-02-08 The Dow Chemical Company Method for coating surfaces

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US986032A (en) * 1910-05-26 1911-03-07 Plymouth Rubber Company Apparatus for treating adhesive-coated fabric.
US1310867A (en) * 1919-07-22 denmark
US2119261A (en) * 1935-07-27 1938-05-31 Bernard R Andrews Method of drying synthetic fiber
US2299786A (en) * 1936-12-09 1942-10-27 Tootal Broadhurst Lee Co Ltd Process of treating textile materials
US2354426A (en) * 1940-10-17 1944-07-25 Firestone Tire & Rubber Co Method of making composite articles

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1310867A (en) * 1919-07-22 denmark
US986032A (en) * 1910-05-26 1911-03-07 Plymouth Rubber Company Apparatus for treating adhesive-coated fabric.
US2119261A (en) * 1935-07-27 1938-05-31 Bernard R Andrews Method of drying synthetic fiber
US2299786A (en) * 1936-12-09 1942-10-27 Tootal Broadhurst Lee Co Ltd Process of treating textile materials
US2354426A (en) * 1940-10-17 1944-07-25 Firestone Tire & Rubber Co Method of making composite articles

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2583220A (en) * 1948-12-24 1952-01-22 Dewey And Almy Chem Comp Process of leveling and drying coatings with steam
US2687446A (en) * 1951-04-25 1954-08-24 Dewey And Almy Chem Comp Battery separator
US2879824A (en) * 1955-08-10 1959-03-31 Firestone Tire & Rubber Co Coated tubeless tire chafer strip
US3136654A (en) * 1958-11-18 1964-06-09 Fmc Corp Manufacture of coated material
US3292273A (en) * 1963-02-20 1966-12-20 Celotex Corp Apparatus for drying coatings
US3294570A (en) * 1963-10-31 1966-12-27 Basf Ag Optical brightening of materials of synthetic polyesters and polyamides
US3920865A (en) * 1969-03-29 1975-11-18 Degussa Process of hydrophorizing highly dispersed metal or metalloid oxides
US3916044A (en) * 1970-12-21 1975-10-28 Collins & Aikman Corp Method for improving the flame retardancy of synthetic linear polyesters
US3772070A (en) * 1971-04-05 1973-11-13 Burlington Industries Inc Applying antistatic finish on synthetic textiles
US4007304A (en) * 1972-03-23 1977-02-08 The Dow Chemical Company Method for coating surfaces

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