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US2396100A - Electric contact - Google Patents

Electric contact Download PDF

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Publication number
US2396100A
US2396100A US492917A US49291743A US2396100A US 2396100 A US2396100 A US 2396100A US 492917 A US492917 A US 492917A US 49291743 A US49291743 A US 49291743A US 2396100 A US2396100 A US 2396100A
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US
United States
Prior art keywords
lead
gold
thallium
electric contact
contact
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US492917A
Inventor
Franz R Hensel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Duracell Inc USA
Original Assignee
PR Mallory and Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by PR Mallory and Co Inc filed Critical PR Mallory and Co Inc
Priority to US492917A priority Critical patent/US2396100A/en
Application granted granted Critical
Publication of US2396100A publication Critical patent/US2396100A/en
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Expired - Lifetime legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01HELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H1/00Contacts
    • H01H1/02Contacts characterised by the material thereof
    • H01H1/021Composite material
    • H01H1/023Composite material having a noble metal as the basic material

Definitions

  • the contact alloys may contain:
  • the preferred contact materials for most uses contain:
  • the alloys can also be made by powder etallurgical methods, consisting in mixing the powders, pressing same and then sintering them at a temperature where the ingredients diffuse into each other. In certain cases, it may be advisable to mix oxide powders of the lead and thallium with the gold base material and then carry out the sintering in a reducing atmosphere. In certain cases it may be advisable to retain a certain percentage of oxides in the alloy and for such applications the sintering may be carried out in a neutral or oxidizing atmosphere.
  • Contacts 01 the present invention find application in various electric devices, such as relays, voltage regulators, meters, gauges, telephone relays, thermostatic applications, sliding contacts and brush applications where certain anti-friction properties are required.
  • These contacts have-the advantages of tarnish resistance and thereby low contact resistance. They can be operated at low pressures both in The presence of lead and thallium in the percentages covered by the present invention, provides a finely distributed phase which, during the operation of the contacts, tends to form a non-wettingoxide'. The percentages of this oxide are so calculated that they will hardly afiect thecontact resistance but will greatly decrease the sticking tendencies of the contacts. Due to. the fact that the goldthallium and gold-lead systems are eutectic compositions, th metals lead and thallium are present in elementary form or metal compounds. The
  • An electric contact formed of a gold base alloy containing 0.1 to 15% of metal selected from the group consisting of lead and thallium.
  • An electric contact composed of 0.1 to 15% of metal selected irom the group consisting of lead and thallium, balance substantially all gold, said contact being characterized by low contact resistance and the presence of a finely distributed 3 phase formed predominantly of the lead or thallium capable of decreasing the sticking tendency of. the contact.
  • An electric contact composed of 0.5 to 5% of metal selected from the group consisting oi lead

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Composite Materials (AREA)
  • Materials Engineering (AREA)
  • Contacts (AREA)

Description

Marcia 5', 1946 FJR. HENSEL 2,396,100
ELECTRIC CONTACT Filed June so, 1945 /ELECTRIC cowmcr FORMED OFGOLD BASE ALLOY CONTAINING LEAD OR THHLLIUM llrronNc-vs Patented Mar. 5, 1946 ELECTRIC CONTACT Franz It. Hensel, Indianapolis, Ind., asslgnor to P. R. Mallory & Co., Inc., Indianapolis, Ind., a corporation of Delaware Application June 30, 1943, Serial No. 492,917
3 Claims.
This invention relates to electric contacts. An object of the invention is to improve electric contact compositions.
The present invention contemplates an electric contact formed of a gold base alloy containins lead or thallium. s,
The contact alloys may contain:
. Per cent by weight Lead, thallium or lead and thallium 0.1 to 15 Gold or gold base alloys-.. Balance The gold used may be either pure gold or one of the carat golds. These consist of gold-base alloys containing additions of silver, copper or other metals such as nickel, zinc, palladium, platinum or manganese. A table or carat gold is given in Metals Handbook (American Society for Metals, Cleveland, Ohio) 1939 edition, page 1507. It is contemplated that silver or copper may be present in the metal composition from traces to 20%, and hence are sometimes present in proportions still higher than would be present if carat golds were used in making the compositions.
The preferred contact materials for most uses contain:
7 Per cent by weight Lead, thallium or lead and thallium 0.5 to 5 Gold Balance Examples of suitable specific contact materials are:
The contact alloys can be made by conventional alloying methods, as by melting the ingredients and thallium, balance gold.
FRANZ R. HENBEL.
v D. C. and A. C. circuits.
The alloys can also be made by powder etallurgical methods, consisting in mixing the powders, pressing same and then sintering them at a temperature where the ingredients diffuse into each other. In certain cases, it may be advisable to mix oxide powders of the lead and thallium with the gold base material and then carry out the sintering in a reducing atmosphere. In certain cases it may be advisable to retain a certain percentage of oxides in the alloy and for such applications the sintering may be carried out in a neutral or oxidizing atmosphere.
Contacts 01 the present invention find application in various electric devices, such as relays, voltage regulators, meters, gauges, telephone relays, thermostatic applications, sliding contacts and brush applications where certain anti-friction properties are required.
These contacts have-the advantages of tarnish resistance and thereby low contact resistance. They can be operated at low pressures both in The presence of lead and thallium in the percentages covered by the present invention, provides a finely distributed phase which, during the operation of the contacts, tends to form a non-wettingoxide'. The percentages of this oxide are so calculated that they will hardly afiect thecontact resistance but will greatly decrease the sticking tendencies of the contacts. Due to. the fact that the goldthallium and gold-lead systems are eutectic compositions, th metals lead and thallium are present in elementary form or metal compounds. The
distribution, therefore, of the non-wetting con-' stituent is microscopically fine. During the operation of the contacts, and particularly during the arc stage, a slight oxidationoi these microscopical particles prevents welding of the contacts because gold areas which might be momentarily fused will have no chance to flow together, thereby iorming a large enough molten pool to cause sticking.
While specific embodiments oi the invention have been described, it is intended to cover the 5 invention broadly within the spirit and scope or the appended claims.
What is claimed is:
1. An electric contact formed of a gold base alloy containing 0.1 to 15% of metal selected from the group consisting of lead and thallium.
2. An electric contact composed of 0.1 to 15% of metal selected irom the group consisting of lead and thallium, balance substantially all gold, said contact being characterized by low contact resistance and the presence of a finely distributed 3 phase formed predominantly of the lead or thallium capable of decreasing the sticking tendency of. the contact.
3. An electric contact composed of 0.5 to 5% of metal selected from the group consisting oi lead
US492917A 1943-06-30 1943-06-30 Electric contact Expired - Lifetime US2396100A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2539298A (en) * 1945-07-28 1951-01-23 Mallory & Co Inc P R Electrical contact of an internally oxidized composition
US2655466A (en) * 1942-12-30 1953-10-13 Standard Oil Dev Co Process for shutting-down catalytic apparatus employed for the conversion of hydrocarbons
DE1190199B (en) * 1957-09-27 1965-04-01 Siemens Ag Use of an alloy based on silver and / or copper as a material for electrical contacts
DE1234397B (en) * 1954-11-20 1967-02-16 Duerrwaechter E Dr Doduco Use of gold and / or silver alloys as a material for electrical contacts and processes for making contacts

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2655466A (en) * 1942-12-30 1953-10-13 Standard Oil Dev Co Process for shutting-down catalytic apparatus employed for the conversion of hydrocarbons
US2539298A (en) * 1945-07-28 1951-01-23 Mallory & Co Inc P R Electrical contact of an internally oxidized composition
DE1234397B (en) * 1954-11-20 1967-02-16 Duerrwaechter E Dr Doduco Use of gold and / or silver alloys as a material for electrical contacts and processes for making contacts
DE1190199B (en) * 1957-09-27 1965-04-01 Siemens Ag Use of an alloy based on silver and / or copper as a material for electrical contacts

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