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US2382674A - Method of making images on metal plates - Google Patents

Method of making images on metal plates Download PDF

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Publication number
US2382674A
US2382674A US456372A US45637242A US2382674A US 2382674 A US2382674 A US 2382674A US 456372 A US456372 A US 456372A US 45637242 A US45637242 A US 45637242A US 2382674 A US2382674 A US 2382674A
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US
United States
Prior art keywords
image
rays
plate
metal plates
zinc
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US456372A
Inventor
Cyril J Staud
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eastman Kodak Co
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Eastman Kodak Co
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Filing date
Publication date
Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co
Priority to US456372A priority Critical patent/US2382674A/en
Application granted granted Critical
Publication of US2382674A publication Critical patent/US2382674A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/20Exposure; Apparatus therefor
    • G03F7/2037Exposure with X-ray radiation or corpuscular radiation, through a mask with a pattern opaque to that radiation
    • G03F7/2039X-ray radiation

Definitions

  • This invention relates to a method of makin images on metal plates, more particularly useful as a step in the making of relief images in zinc plates by a process involving etching through a relief image.
  • the plates are coated with a gelatin or albumen layer sensitized with potassium dichromate and exposed under a negative carried on clear glass or film, the exposure being prolonged because of low sensitivity of the material.
  • the metal plate I usually of zinc, can be coated with an unhardened, photographic gelatino silver halide emulsion layer 2 in any suitable way.
  • a most convenient method is by means of a transfer film from which the emulsion layer alone is stripped and transferred to the metal plate.
  • Such a film and a method for transferring it are disclosed in the patent of Gale F. Nadeau, No. 2,326,048, of August 3, 1943, and the pending application of Victor N. Gioseffi, Serial No. 452,928, filed July 30, 1942.
  • a line negative or half-tone screen glass negative 3 bearing a layer 4 containing a silver image.
  • plates I and 3 are shown as slightly spaced. This is then exposed to X-rays from tube 5 which pass in succession through the negative or image, the zinc plate and the photographic emulsion. Because of the greater density to X-rays of silver than zinc, an image is formed in the sensitive layer. This is developed in a tanning developer, of a well known type, and the unaffected and still unhardened gelatin washed off in warm water leaving a gelatin relief image. Other known means of obtaining the relief image could be used.
  • a relief image oh a zinc plate that comprises coating one surface thereof with an unhardened, sensitive, gelatinosilver halide layer, placing on the other side of the zinc plate a support transparent to X-rays and carrying a silver photographic image, passing X-rays through said image and said zinc plate to the sensitive layer to form a latent image therein, developing said latent image in a developer that acts to tan the gelatin and washing oif the untanned gelatin to form a relief image.

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  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Photosensitive Polymer And Photoresist Processing (AREA)

Description

C. J. STAUD METHOD OF MAKING IMAGES ON METAL PLATES Filed Aug. 27, 1942 K l 1 GLASS PLATE 3 LAYERW/7'H :K' I I '41 SILVER/MAG? wvsm. HATE SENSITIVE LAYER A T'TORNE YS Patented Aug. 14, 1945 METHOD OF MAKING IMAGES N METAL PLATES Cyril J. Stand, Rochester, N. Y., assignor to Eastman Kodak Company, Rochester, N. Y., a corporation of New Jersey Application August 27, 1942, Serial No. 456,372
2 Claims.
This invention relates to a method of makin images on metal plates, more particularly useful as a step in the making of relief images in zinc plates by a process involving etching through a relief image.
Ordinarily the plates are coated with a gelatin or albumen layer sensitized with potassium dichromate and exposed under a negative carried on clear glass or film, the exposure being prolonged because of low sensitivity of the material.
It is well known that in making gelatin relief images on glass, it is customary and desirable that exposures be made through the support, thus hardening the gelatin nearest to the support preliminary to washing off the unaffected soft gelatin. This has not been possible with an opaque metal plate, and it has accordingly been necessary that the exposure be prolonged to make certain that exposure at all points is complete. This restricts the latitude of exposure and tends to obliterate detail.
I propose to overcome this difiiculty by utilizing X-rays to make exposures through the zinc plate and through a metal image having a greater opacity to X-rays than the metal of the plate.
Reference is made to the diagrammatic figure of the accompanying drawing.
The metal plate I, usually of zinc, can be coated with an unhardened, photographic gelatino silver halide emulsion layer 2 in any suitable way. A most convenient method is by means of a transfer film from which the emulsion layer alone is stripped and transferred to the metal plate. Such a film and a method for transferring it are disclosed in the patent of Gale F. Nadeau, No. 2,326,048, of August 3, 1943, and the pending application of Victor N. Gioseffi, Serial No. 452,928, filed July 30, 1942.
Against the back or unsensitized surface of the zinc plate is placed a line negative or half-tone screen glass negative 3 bearing a layer 4 containing a silver image. For the sake of clearness, plates I and 3 are shown as slightly spaced. This is then exposed to X-rays from tube 5 which pass in succession through the negative or image, the zinc plate and the photographic emulsion. Because of the greater density to X-rays of silver than zinc, an image is formed in the sensitive layer. This is developed in a tanning developer, of a well known type, and the unaffected and still unhardened gelatin washed off in warm water leaving a gelatin relief image. Other known means of obtaining the relief image could be used.
This process depends on the fact that absorption of X-rays by silver is many times that of zinc. To maintain the difierential the zinc plate would be no thicker than practical requirements necessitate. The silver image could be converted by known methods to uranium, platinum, or gold, which would ive even greater differential absorption than silver; and hence, greater contrast in the resultant image and, of course, other metals, readily permeable to X-rays, could be used instead of zinc, where suitable for the process proposed.
Further control of contrast could be obtained by selection of suitable voltages on the X-ray tube. In general, moderate voltages are most suitable.
What I claim as new and desire to secure by Letters Patent of the United States is:
1. The method of making a relief image on a metal plate that comprises coating one surface of said plate with a sensitive layer, placing on the other side of the metal plate a layer transparent to X-rays carrying an image consisting of a metal more absorptive of X-rays than is the metal of the plate, passing X-rays through said image and the metal plate to the sensitive layer and processing the sensitive layer to form a relief image therefrom.
2. The method of making a relief image oh a zinc plate that comprises coating one surface thereof with an unhardened, sensitive, gelatinosilver halide layer, placing on the other side of the zinc plate a support transparent to X-rays and carrying a silver photographic image, passing X-rays through said image and said zinc plate to the sensitive layer to form a latent image therein, developing said latent image in a developer that acts to tan the gelatin and washing oif the untanned gelatin to form a relief image.
CYRIL J. STAUD.
US456372A 1942-08-27 1942-08-27 Method of making images on metal plates Expired - Lifetime US2382674A (en)

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US456372A US2382674A (en) 1942-08-27 1942-08-27 Method of making images on metal plates

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2748288A (en) * 1953-10-01 1956-05-29 Rca Corp Electron photography plate construction
US3447924A (en) * 1965-08-16 1969-06-03 Charles J Trzyna Aligning method
US3743842A (en) * 1972-01-14 1973-07-03 Massachusetts Inst Technology Soft x-ray lithographic apparatus and process
US3925677A (en) * 1974-04-15 1975-12-09 Bell Telephone Labor Inc Platinum oxide lithographic masks
US4440493A (en) * 1980-05-14 1984-04-03 Canon Kabushiki Kaisha Printing apparatus

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2748288A (en) * 1953-10-01 1956-05-29 Rca Corp Electron photography plate construction
US3447924A (en) * 1965-08-16 1969-06-03 Charles J Trzyna Aligning method
US3743842A (en) * 1972-01-14 1973-07-03 Massachusetts Inst Technology Soft x-ray lithographic apparatus and process
US3925677A (en) * 1974-04-15 1975-12-09 Bell Telephone Labor Inc Platinum oxide lithographic masks
US4440493A (en) * 1980-05-14 1984-04-03 Canon Kabushiki Kaisha Printing apparatus

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