US2111300A - Monoazo-dyestuffs and their manufacture - Google Patents
Monoazo-dyestuffs and their manufacture Download PDFInfo
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- US2111300A US2111300A US120617A US12061737A US2111300A US 2111300 A US2111300 A US 2111300A US 120617 A US120617 A US 120617A US 12061737 A US12061737 A US 12061737A US 2111300 A US2111300 A US 2111300A
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- dyestuffs
- ethyl
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- 238000004519 manufacturing process Methods 0.000 title description 12
- 150000003254 radicals Chemical class 0.000 description 35
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 30
- 238000004043 dyeing Methods 0.000 description 24
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 20
- 229910052739 hydrogen Inorganic materials 0.000 description 20
- 239000001257 hydrogen Substances 0.000 description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 19
- -1 acyl radical Chemical class 0.000 description 18
- 125000001424 substituent group Chemical group 0.000 description 18
- 125000000217 alkyl group Chemical group 0.000 description 16
- 239000000975 dye Substances 0.000 description 16
- 229960001413 acetanilide Drugs 0.000 description 15
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 15
- 239000000243 solution Substances 0.000 description 15
- 230000008878 coupling Effects 0.000 description 14
- 238000010168 coupling process Methods 0.000 description 14
- 238000005859 coupling reaction Methods 0.000 description 14
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 14
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 13
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 13
- 150000002431 hydrogen Chemical group 0.000 description 12
- 239000000047 product Substances 0.000 description 12
- 244000172533 Viola sororia Species 0.000 description 11
- 125000004672 ethylcarbonyl group Chemical group [H]C([H])([H])C([H])([H])C(*)=O 0.000 description 11
- 229920002678 cellulose Polymers 0.000 description 10
- 229940093499 ethyl acetate Drugs 0.000 description 10
- 235000019439 ethyl acetate Nutrition 0.000 description 10
- 239000000843 powder Substances 0.000 description 10
- 229920002955 Art silk Polymers 0.000 description 9
- 150000001298 alcohols Chemical class 0.000 description 9
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 8
- 230000000875 corresponding effect Effects 0.000 description 8
- 229930195733 hydrocarbon Natural products 0.000 description 8
- 150000002430 hydrocarbons Chemical class 0.000 description 8
- 150000002576 ketones Chemical class 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 239000000725 suspension Substances 0.000 description 8
- 150000008049 diazo compounds Chemical class 0.000 description 7
- MBDUIEKYVPVZJH-UHFFFAOYSA-N 1-ethylsulfonylethane Chemical compound CCS(=O)(=O)CC MBDUIEKYVPVZJH-UHFFFAOYSA-N 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- 238000007792 addition Methods 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- 239000001913 cellulose Chemical class 0.000 description 6
- 229910052736 halogen Inorganic materials 0.000 description 6
- 150000002367 halogens Chemical class 0.000 description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 6
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 6
- 125000004673 propylcarbonyl group Chemical group 0.000 description 6
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 6
- FYXJXUMICYGRKV-UHFFFAOYSA-N 2-[(2-amino-5-nitrophenyl)methylsulfonylmethyl]-4-nitroaniline Chemical compound NC1=CC=C([N+]([O-])=O)C=C1CS(=O)(=O)CC1=CC([N+]([O-])=O)=CC=C1N FYXJXUMICYGRKV-UHFFFAOYSA-N 0.000 description 5
- AKQXCFXXDJUGRM-UHFFFAOYSA-N N-(nitrosulfamoyl)nitramide Chemical compound [N+](=O)([O-])NS(=O)(=O)N[N+](=O)[O-] AKQXCFXXDJUGRM-UHFFFAOYSA-N 0.000 description 5
- FZERHIULMFGESH-UHFFFAOYSA-N N-phenylacetamide Chemical compound CC(=O)NC1=CC=CC=C1 FZERHIULMFGESH-UHFFFAOYSA-N 0.000 description 5
- TUCNEACPLKLKNU-UHFFFAOYSA-N acetyl Chemical compound C[C]=O TUCNEACPLKLKNU-UHFFFAOYSA-N 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 4
- 235000005811 Viola adunca Nutrition 0.000 description 4
- 240000009038 Viola odorata Species 0.000 description 4
- 235000013487 Viola odorata Nutrition 0.000 description 4
- 235000002254 Viola papilionacea Nutrition 0.000 description 4
- 125000004442 acylamino group Chemical group 0.000 description 4
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- VQTGUFBGYOIUFS-UHFFFAOYSA-N nitrosylsulfuric acid Chemical compound OS(=O)(=O)ON=O VQTGUFBGYOIUFS-UHFFFAOYSA-N 0.000 description 4
- 239000001632 sodium acetate Substances 0.000 description 4
- 235000017281 sodium acetate Nutrition 0.000 description 4
- KWAXPNSWICZXMJ-UHFFFAOYSA-N 2-[(2-amino-3,5-dinitrophenyl)methylsulfonylmethyl]-4,6-dinitroaniline Chemical compound C1=C([N+]([O-])=O)C=C([N+]([O-])=O)C(N)=C1CS(=O)(=O)CC1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1N KWAXPNSWICZXMJ-UHFFFAOYSA-N 0.000 description 3
- SMEGJBVQLJJKKX-HOTMZDKISA-N [(2R,3S,4S,5R,6R)-5-acetyloxy-3,4,6-trihydroxyoxan-2-yl]methyl acetate Chemical compound CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@@H](O1)O)OC(=O)C)O)O SMEGJBVQLJJKKX-HOTMZDKISA-N 0.000 description 3
- 229940081735 acetylcellulose Drugs 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000006193 diazotization reaction Methods 0.000 description 3
- 125000004674 methylcarbonyl group Chemical group CC(=O)* 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 235000010288 sodium nitrite Nutrition 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- 150000001555 benzenes Chemical class 0.000 description 2
- 229920002301 cellulose acetate Polymers 0.000 description 2
- 229920003086 cellulose ether Polymers 0.000 description 2
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000004922 lacquer Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- ORFSSYGWXNGVFB-UHFFFAOYSA-N sodium 4-amino-6-[[4-[4-[(8-amino-1-hydroxy-5,7-disulfonaphthalen-2-yl)diazenyl]-3-methoxyphenyl]-2-methoxyphenyl]diazenyl]-5-hydroxynaphthalene-1,3-disulfonic acid Chemical compound COC1=C(C=CC(=C1)C2=CC(=C(C=C2)N=NC3=C(C4=C(C=C3)C(=CC(=C4N)S(=O)(=O)O)S(=O)(=O)O)O)OC)N=NC5=C(C6=C(C=C5)C(=CC(=C6N)S(=O)(=O)O)S(=O)(=O)O)O.[Na+] ORFSSYGWXNGVFB-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- ZYECOAILUNWEAL-NUDFZHEQSA-N (4z)-4-[[2-methoxy-5-(phenylcarbamoyl)phenyl]hydrazinylidene]-n-(3-nitrophenyl)-3-oxonaphthalene-2-carboxamide Chemical compound COC1=CC=C(C(=O)NC=2C=CC=CC=2)C=C1N\N=C(C1=CC=CC=C1C=1)/C(=O)C=1C(=O)NC1=CC=CC([N+]([O-])=O)=C1 ZYECOAILUNWEAL-NUDFZHEQSA-N 0.000 description 1
- YKYIFUROKBDHCY-ONEGZZNKSA-N (e)-4-ethoxy-1,1,1-trifluorobut-3-en-2-one Chemical group CCO\C=C\C(=O)C(F)(F)F YKYIFUROKBDHCY-ONEGZZNKSA-N 0.000 description 1
- RUFPHBVGCFYCNW-UHFFFAOYSA-N 1-naphthylamine Chemical compound C1=CC=C2C(N)=CC=CC2=C1 RUFPHBVGCFYCNW-UHFFFAOYSA-N 0.000 description 1
- QPKNFEVLZVJGBM-UHFFFAOYSA-N 2-aminonaphthalen-1-ol Chemical class C1=CC=CC2=C(O)C(N)=CC=C21 QPKNFEVLZVJGBM-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 241000779819 Syncarpia glomulifera Species 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 125000006231 alkoxy propyl group Chemical group 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- DENRZWYUOJLTMF-UHFFFAOYSA-N diethyl sulfate Chemical compound CCOS(=O)(=O)OCC DENRZWYUOJLTMF-UHFFFAOYSA-N 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 239000005457 ice water Substances 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- PEMGGJDINLGTON-UHFFFAOYSA-N n-(3-aminophenyl)acetamide Chemical class CC(=O)NC1=CC=CC(N)=C1 PEMGGJDINLGTON-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000001739 pinus spp. Substances 0.000 description 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 125000001174 sulfone group Chemical group 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 125000001302 tertiary amino group Chemical group 0.000 description 1
- 229940036248 turpentine Drugs 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B29/00—Monoazo dyes prepared by diazotising and coupling
- C09B29/06—Monoazo dyes prepared by diazotising and coupling from coupling components containing amino as the only directing group
- C09B29/08—Amino benzenes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
- C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
- C09B62/54—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring the reactive group being an epoxy or halohydrin group
- C09B62/58—Azo dyes
Definitions
- R represents an alkyl group such as methyl
- Ac represents a substituted or unsubstituted acyl radical such as HCO-, CH3CO-, C2H5CO, C3H7CO--, C11H23CO--, C2I-Li--OHCO
- R1 represents a group such as methyl, ethyl, propyl, butyl
- R2 represents hydrogen or one of the groups represented by R1, R1 and R2 being the same or different in the case of tertiary substituted N- atoms.
- the azo component may contain any other desired substituents subject, of course, to the condition that such substituents do not destroy the capacity for coupling and do not impart solubility in water to the dyestuffs.
- the new dyestuffs have in general a very good solubility in alcohols, ketones, hydrocarbons such as petroleum, paraffin or benzine, oils, waxes and in the various modern solvents and their mixtures. It has been found that it is possible to adapt in large degree the solubility properties to the various purposes of application by suitable choice of the acid residue of the acylaminogroup.
- Some of the new dyestuffs are distinguished by a very good solubility in cellulose esters and cellulose ethers.
- the new dyestuffs By means of the new dyestuffs it is possible to produce violet to green-blue shades dischargeable to pure white, such as have hitherto been obtained only with coupling components of the aminonaphthalene and aminonaphthol series.
- the dyestuffs prepared with these components are practically without application especially for dyeing acetyl-cellulose owing to their exceedingly unsatisfactory fastness to light.
- the new coupling components used in the present invention thus fill an important gap especially in the construction of violet to blue acetyl cellulose dyestuffs which are fast to light.
- the dyestuffs of the present invention include new dyestuffs which are distinguished by blue shades which are considerably displaced towards green and could not hitherto be obtained by means of hitherto known aZo-components of the benzene series.
- the acylamino group contained in the coupling components of the new dyestuffs proves to be the substituent which causes in most marked degree the hitherto known displacement of the shade towards blue or green. Consequently, the shades of all the new dyestuffs having the acylamino-group in ortho-position to the azo-group are displaced towards the blue end of the spectrum to a greater extent than those of the quite analogously constructed dyestuffs containing other substituents such as alkyl or alkoxy in said. position.
- the constitution of the acid radical in the acylamino-group has itself practically no eifect on the shade; this is of great importance in the production of the new dyestufis which are to be adapted to various different solvents and emulsifying agents, since the solubility properties are dependent on the acyl group and can be varied by variation of this group without affecting the shade.
- Example 1 21.6 parts of 5-nitro-2-aminophenylmethylsulphone are diazotized in the usual manner with the required proportion of nitrosylsulphuric acid.
- diazotization is finished the mixture is poured into a large quantity of ice-water and the diluted diazo solution is filtered if necessary. The clear solution is allowed to run into an aqueous solution of 28.2 parts of -ethoxy-B-diw-hydroxyethylamino-1-acetanilide.
- the formation of the dyestuff can be accelerated by neutralization of the strongly acid reaction towards Congo by addition of sodium acetate.
- the insoluble dyestuff which has precipitated is filtered and washed until neutral.
- dry is a dark powder which is soluble in organic solvents such as alcohol, acetone or ethyl-acetate to blue solutions. In the form of a suspension it dyes acetate artificial silk pure blue shades which can be discharged to white.
- the azo-component used in this example can be made by heating 4-ethoxy-3-amino-1-acetanilide with a hydroxyethylating agent such as glycol-chlorhydrin with addition of an acidbinding agent such as calcium carbonate, magnesium carbonate or sodium carbonate.
- a hydroxyethylating agent such as glycol-chlorhydrin
- an acidbinding agent such as calcium carbonate, magnesium carbonate or sodium carbonate.
- Example 2 21.6 parts of 5-nitro-2-aminophenylmethylsulphone are diazotized in the usual manner with a nitrosylsulphuric acid corresponding with 6.9 parts of sodium nitrite, and the mixture is poured on to ice and then coupled with an aqueous solution of 28.2 parts of 4-methoxy-3-(ethyl-B,' -dihydroxypropyl)-amino-1-acetanilide. The formation of the dyestuff is completed by the addition of sodium acetate and the dyestuff is isolated in the usual manner and dried. It is a dark powder which dissolves in acetone or ethylacetate to a blue solution, and in the form of a suspension yields blue shades on acetate artificial silk.
- a similar dyestuff is obtained by using as diazocomponent the corresponding ethylsulphone.
- Example 3 A diazo-compound prepared in the usual manner from 21.6 parts of 5-nitro-2-aminophenylmethylsulphone is combined with an aqeuous solution of 26.8 parts of 4-methoxy-3-di-w-hy droxyethyl-amino l acetanilide. Coupling is completed by the addition of sodium acetate and the dyestuff which has precipitated is isolated in the usual manner and dried. It is a dark powder which is soluble in acetone or ethyl-acetate to a blue solution, and in the form of a suspension dyes acetate artificial silk blue shades.
- Example 4 A diazo-solution prepared in the usual manner from 21.6 parts of 5-nitro-2-aminophenylmethylsulphone is coupled with an aqueous solution of 23.8 parts of 3-di-w-hydroxyethylamino-l-acetanilide. When coupling is finished the dyestufi is separated by filtering, washed until neutral and dried. It is a dark powder which is soluble in acetone or ethyl-acetate to a red-violet solution, and in the form of a suspension dyes acetate artificial silk violet shades which can be discharged to a pure white.
- 3-di-w-hydroxyethylamino-l-acetanilide can be made by the action of glycol-chlorhydrin on 3- amino-l-acetanilide in the presence of an acidbinding agent.
- the base is very easily soluble in water and in alcohol and crystallizes in the form of colourless prisms of melting point 119 C.
- Example 5 26.1 parts of 2-amlno-3,5-dinitro-l-phenylmethylsulphone are diazotized in concentrated sulphuric acid with a nitrosylsulphuric acid corre sponding with 6.9 parts of sodium nitrite.
- diazotization is finished the diazotization mixture is filtered and allowed to run in a thin stream into an ice-cold aqueous solution of 26.6 parts of 4-ethoxy-3 (ethyl awhydroxyethyl) -amino-1-acetanilide while well stirring.
- the whole is filtered and the dyestuff washed until neutral and. dried.
- the new dyestufi is a dark powder which is soluble in acetone or ethyl-acetate to a green-blue solution.
- acetate artificial silk fast green-blue shades which have a particularly beautiful colour by evening light and can be discharged to a pure white.
- 4-ethoxy-3- (ethyl w hydroxyethyl) -amino-1- acetanilide can be obtained by mono-hydroxyethylating 4 ethoxy 3 amino-l-acetanilide in known manner and ethylating directly by means of diethyl-sulphate the intermediate product without isolating it.
- the 4-ethoxy-3-(ethyl-w hydroxyethyl) -amino-1-acetanilide is thus obtained in an aqueous solution which can be further used directly.
- Example 6 26.1 parts of 2-amino-3.5-dinitro-1-phenylmethylsulphone are diazotized in known manner and the diazo-compound is coupled in an ice-cold aqueous solution with 23.8 parts of 3-di-w-hy droxyethylamino 1 acetanilide.
- the dyestuff formed is isolated in the usual manner. When dried it is a dark powder which is soluble in acetone or ethyl-acetate to a blue-violet solution, and in the form of a suspension dyes acetate artificia-l silk fast blue-violet shades which can be discharged to a pure white.
- a dyestuff having similar properties is obtained if the corresponding ethylsulphone is used.
- Example 7 26.1 parts of 2-amino-3,5-dinitro1-phenylmethylsulphone are diazotized with nitrosylsulphuric acid corresponding with 6.9- parts of sodium nitrite and the diazo-compound is coupled with an ice-cold aqueous alcoholic solution of 28.2 parts of 4-ethoxy-3-di-w-hydroxyethylamino-l-acetanilide. By the addition of sodium acetate coupling is completed and the formed dyestuff precipitated.
- Dyestuifs of analogous properties are obtained if instead of the 2-amino-3,5-dinitro-l-phenylmethylor -ethylsulphones or Examples 5-7 there are employed the 2-amino-3-halogen-5-nitro-1- phenylalkylsulphones such as 2-amino-3-chloro- 5-nitro-l-phenylmethylor -ethylsulphone.
- acetyl-group in the acetyl-metaphenylenediamine derivatives used in the above examples there may, of course, be present other acyl-residues such as are indicated in the foregoing description.
- Formyl and lactyl derivatives are in general suitable in the case of dyestuffs for dyeing cellulose esters, whether in the form of textiles, films, masses or lacquers.
- acylresidues such as lauryl and so on, are suitable in the case of dyestuffs for colouring fats, oils, waxes, turpentine, benzine and so on, whilst dyestuffs from urea or urethane derivatives are freely soluble in lower alcohols or similar organic solvents or mixtures thereof.
- the azo' component may contain other nuclear substituents in the free positions, provided that they do not inhibit the coupling and impart solubility to the dyestuffs; particularly the position 4 of the 1,3-acyldiamines is favourable and from the substituents the alkoxy groups like methand ethoxy are the best suitable.
- a process for the manufacture of monoazodyestuffs comprising combining a diazo-compound of a nitro-amino-sulphone of the general formula X- -SO2R N02 in which X represents a radical selected from the group consisting of hydrogen, a nitro group and halogen, and
- R. represents a lower alkyl group, with a monoacyl-meta-phenylenediamine of the following general formula NH-Ac in which Ac represents an acyl radical selected from the group consisting of HCO, CHsCO-, C2H5CO, C3H7CO--, C11H23CO and C2H4OHCO,
- X represents a radical selected from the group consisting of hydrogen, a nitro group and halogen
- R represents a lower alkyl group
- a mono-acyl-meta-phenylenediamine of the following general formula 1 IHAc in which Ac represents an acyl radical selected from the group consisting of HCO,CI-I3CO-, C2H5CO, C3H7CO, C11H23CO and R1 and R2 represent the same monovalent organic radicals, the other free positions of the azocomponent containing also nuclear substituents provided that they do not inhibit the coupling and impart solubility in water to the dyestuffs.
- a process for the manufacture of monoazodyi estuffs comprising combining a diazo-compound of a nitro-amino-sulphone of the general formula lTTHz 1 1 0; in which X represents a radical selected from the group consisting of hydrogen, a nitro group and halogen, and R represents a lower alkyl group,
- Ac represents an acyl radical selected from the group consisting of HCO-, CH3CO, C2H5CO, C3H7CO-, C11H23CO and C2H4OHCO
- R1 and R2 represent different monovalent organic radicals
- a process for the manufacture of monoazodyestuffs comprising combining a diazo-compound of a nitro-amino-sulphone of the general formula in which X represents a radical selected from the group consisting of hydrogen, a nitro group and halogen, and
- R represents a lower alkyl group
- R2 represents a radical selected from the group consisting of hydrogen and the said group from which R1 is selected, the other free positions of the azo-component containing also nuclear substituents provided that they do not inhibit the coupling and impart solubility in water to the dyestuffs.
- a process for the manufacture of monoazodyestuffs comprising combining a dia-zo-compound of a nitro-amino-sulphone of the genera1 formula l N: in Which X represents a radical selected from the group consisting of hydrogen, a nitro group and halogen, and
- R represents a lower alkyl group
- a mono-acyl-meta-phenylenediamine of the following general formula I IHAc in which Ac represents an acyl radical selected from the group consisting of HCO, CH3CO-, C2H5CO, C3H7CO-, C11H23CO and R1 and R2 represent difierent radicals selected from the group consisting of methyl, ethyl, propyl, butyl, w-hydroxyethyl, B -dihydroxypropyl, B-hydroxy- -chloropropyl, fi-hydroXyalkoxypropyl, epoxypropyl, polyhydroxy alkyl radicals of the sugar series, a phenyl group, the other free positions of the azo-component containing also nuclear substituents provided that they do not inhibit the coupling and impart solubility in water to the dyestuffs.
- Ac represents an acyl radical selected from the group consisting of HCO, CH3CO-, C2H5CO, C3H7CO-, C
- a process for the manufacture of monoazodyestuffs comprising combining diazotized -nitro-2-aminophenylmethylsulphone with 4-methoxy 3 (ethyl -p,' -dihydroxypropyl) amino-lacetanilide.
- a process for the manufacture of monoazodyestuffs comprising combining diazotized 5-nitro-2-aminophenylmethylsulphone with 4-methoxy-3-di-w-hydroxyethylamino-l-acetanilide.
- a process for the manufacture of monoazodyestuffs comprising combining diazotized 2-amino-3,5-dinitro-l-phenylmethylsulphone with 3- di-w-hydroxyethylamino-l-acetanilide.
- Ac represents an acyl radical selected from the group consisting of HCO-, CH3CO-, C2H5CO, C3I-I7CO, C11I-I23CO and R1 represents a monovalent organic radical, and
- R2 represents a radical selected from the group consisting of hydrogen and monovalent organic radicals, the three free positions in the acyldiamino-nucleus being occupied by any other substituent, said dyestuffs being insoluble in water and dyeing alcohols, ketones, hydrocarbons and cellulose derivatives violet to greenblue shades, the dyeings on fibres being dischargeable to white.
- the azo-dyestuffs of the general formula R1 X N NO1 N N- s 02R r m-Ac in which X represents a radical selected from the group consisting of hydrogen, a nitro group and halo- R represents a lower alkyl group,
- Ac represents an acyl radical selected from the R1 and R2 represent the same monovalent organic radicals, the three free positions in the acyl-diamino-nucleus being occupied by any other substituent, said dyestuffs being insoluble in water and dyeing alcohols, ketones, hydrocarbons and cellulose derivatives violet to greenblue shades, the dyeings on fibres being dischargeable to white.
- the azo-dyestuffs of the general formula R1 NOPQN N R2 s 03R NH-Ac in which X represents a radical selected from the group consisting of hydrogen, a nitro group and halo- R represents a lower alkyl group,
- Ac represents an acyl radical selected from the group consisting of HCO, CH3CO, C2H5CO-, C3H7CO C11H23CO- and R1 and R2 represent different monovalent organic radicals, the three free positions in the acyldiamino-nucleus being occupied by any other substituent, said dyestuffs being insoluble in water and dyeing alcohols, ketones, hydrocarbons and celulose derivatives violet to greenblue shades, the dyeings on fibres being dischargeable to white.
- a to-dyestuffs of the general formula X represents a radical selected from the group consisting of hydrogen, a nitro group and halo- R represents a lower alkyl group
- Ac represents an acyl radical selected from the group consisting of HCO-, CH3CO, C2H5CO, CsI-I'zCO-, C11H2sCO-- and R1 represents a radical selected from the group consisting of methyl, ethyl, propyl, butyl, w-hydroxyethyl, [3,v-dihydroxypropyl, e-hydroxy-vchloropropyl, ,Ei-hydroxy-y-alkompropyl, epoxypropyl, polyhydroxyalkyl radicals of the sugar series, a phenyl group,
- R2 represents a radical selected from the group consisting of hydrogen and the said group from which R1 is selected, the three free positions in the acyl-diamino-nucleus being occupied by any other substituent, said dyestuffs being insoluble in water and dyeing alcohols, ketones, hydrocarbons and cellulose derivatives violet to green-blue shades, the dyeings on fibres being dischargeable to white.
- Ac represents an acyl radical selected from the group consisting of I-ICO-, CHsCO, C2H5CO, C3H7CO, C11H23CO and R1 and R2 each represent the same radicals selected from the group consisting of methyl, ethyl, propyl, butyl, w-hydroxyethyl, p -dihydroxypropyl, ,6-hydroxy-' -chloropropyl, ,c-hydroxy-y-alkoxypropyl, epoxypropyl, polyhydroxyalkyl radicals of the sugar series, a phenyl group, the three free positions in the acyl-diamino-nucleus being occupied by any other substituent, said dyestufis being insoluble in water and dyeing alcohols, ketones, hydrocarbons and cellulose derivatives violet to greenblue shades, the dyeings on fibres being dischargeable to white.
- Ac represents an acyl radical selected from the group consisting of I-ICO-, CH3CO, C2H5CO, CsI-I'zCO-, C11H23CO- and R1 and R2 represent different radicals selected from the group consisting of methyl, ethyl, propyl, butyl, w-hydroxyethyl, j8,'y-dihydroxypropyl, fi-hydroxy-v-chloropropyl, p-hydroxyy-alkoxypropyl, epoxypropyl, polyhydroxyalkyl radicals of the sugar series, a phenyl group, the three free positions in the acyl-diaminonucleus being occupied by any other substituent, said dyestuffs being insoluble in water and dyeing alcohols, ketones, hydrocarbons and cellulose derivatives violet to green-blue shades, the dyeings on fibres being dischargeable to white.
- R represents a lower alkyl group
- R1 and R2 represent radicals selected from the group of lower alkyl and hydroxyalkyl radicals
- Y represents any substituent not imparting solubility in water, said dyestufis being insoluble in water and dyeing alcohols, ketones, hydrocarbons and cellulose derivatives violet to greenblue shades, the dyeings on fibres being dischargeable to white. 16.
- X represents a radical selected from the group consisting of hydrogen and a nitro group
- R represents a lower alkyl radical selected from the group of methyl and ethyl
- R1 and R2 represent same or difierent radicals selected from the group of methyl, ethyl, w-hY- droxyethyl, pp -dihydroxypropyl,
- Y represents a member of the group consisting of H, methoxy and ethoxy. 18.
- OCH the azo-dyestuffs of the formula OCH:
- R is selected from the group consisting of methyl and ethyl, being dark powders insoluble in water, soluble in acetone and in ethyl-acetate to blue solutions and dyeing acetate silk blue shades, the dyeings being dischargeable to White.
- I CHzCHaOH CH2CH2OH NOa- N N I S 02R NHC 0 CH3 in which R is selected from the group consisting of methyl and ethyl, being dark powders insoluble in water and soluble in acetone and in ethylacetate to blue solutions and dyeing acetate silk blue shades, the dyeings being dischargeable to white.
- the azo-dyestufis of the formula in which R is selected from the group consisting of methyl and ethyl being dark powders insoluble in water and soluble in acetone and in ethylacetate to blue-violet solutions and dyeing acetate silk blue-violet shades, the dyeings being dischargeable to white.
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Description
Patented Mar. 15, 1938 PATENT OFFICE MONOAZO-DYESTUFFS AND THEIR MANUFACTURE Emil Senn, Riehen, near Basel, Switzerland, assignor to firm J. R. Geigy S. A., Basel, Switzerland No Drawing. Application January 14, 1937, Se-
rial No. 120,617. In Great Britain February 10,
20 Claims.
According to this invention valuable new violet to green-blue monoazo-dyestuffs insoluble in water are made by combining a diazo-compound.
of a nitro-amino-sulphone of the general formula in which X represents hydrogen, a nitro group or halogen,
and R represents an alkyl group such as methyl,
ethyl, butyl and so on, with a mono-asylmeta-phenylenediamine of the following general formula I THAc In the last named formula Ac represents a substituted or unsubstituted acyl radical such as HCO-, CH3CO-, C2H5CO, C3H7CO--, C11H23CO--, C2I-Li--OHCO, R1 represents a group such as methyl, ethyl, propyl, butyl,
w-hydroxyethyl, B, -dihydroxypropy1, p-hydroxy- 'y chloropropyl, B hydroxy 'y alkoxypropyl, epoXy-propyl, or a polyhydroxylalkyl radical of the sugar series, a phenyl group and so on, and
' R2 represents hydrogen or one of the groups represented by R1, R1 and R2 being the same or different in the case of tertiary substituted N- atoms.
The azo component may contain any other desired substituents subject, of course, to the condition that such substituents do not destroy the capacity for coupling and do not impart solubility in water to the dyestuffs.
The new dyestuffs have in general a very good solubility in alcohols, ketones, hydrocarbons such as petroleum, paraffin or benzine, oils, waxes and in the various modern solvents and their mixtures. It has been found that it is possible to adapt in large degree the solubility properties to the various purposes of application by suitable choice of the acid residue of the acylaminogroup.
Some of the new dyestuffs are distinguished by a very good solubility in cellulose esters and cellulose ethers.
They may either be dissolved in.
lacquers prepared with these substances or they may be used, after they have been brought into a fine state of subdivision by suitable additions, for dyeing textiles, films or shaped masses according to the suspension method.
By means of the new dyestuffs it is possible to produce violet to green-blue shades dischargeable to pure white, such as have hitherto been obtained only with coupling components of the aminonaphthalene and aminonaphthol series. However, the dyestuffs prepared with these components are practically without application especially for dyeing acetyl-cellulose owing to their exceedingly unsatisfactory fastness to light. The new coupling components used in the present invention thus fill an important gap especially in the construction of violet to blue acetyl cellulose dyestuffs which are fast to light.
Hitherto blue shades capable of being discharged and having good fastness properties could be produced on acetate artificial silk only with dyestufis from 1-diazo-6-halogen-2,4-dinitrobenzenes and a few selected coupling components of the benzene series, such as alkyl-whydroxyalkyl-cresidines. With these dyestuffs there were obtained at the best reddish-blue shades having the great disadvantage that they suffered considerable change towards red under artificial light. The production of blue dischargeable acetate artificial silk dyestuffs whose pure blue shades are not altered in artificial light but remain unchanged in tint and purity is therefore an object much to be desired. These requirements are fulfilled to a large extent, and in some cases practically completely, by the dyestuffs of the present invention. They include new dyestuffs which are distinguished by blue shades which are considerably displaced towards green and could not hitherto be obtained by means of hitherto known aZo-components of the benzene series.
The use of mono-acyl-meta-phenylenediamines and their homologues and substitution products capable of being coupled as azo-components for making yellow to orange dyestuffs for dyeing cellulose esters and ethers has already been proposed in U. S. Patent No. 1,692,493. However, all the dyestuffs of this patent contain a free amino-group which can be diazotized and used for the production of developing dyestuffs on the fibre. From these dyestuffs the dyestufis of the present invention diifer in that they contain a secondary or tertiary amino-group in para-posi tion to the azo-group. The acylamino group contained in the coupling components of the new dyestuffs proves to be the substituent which causes in most marked degree the hitherto known displacement of the shade towards blue or green. Consequently, the shades of all the new dyestuffs having the acylamino-group in ortho-position to the azo-group are displaced towards the blue end of the spectrum to a greater extent than those of the quite analogously constructed dyestuffs containing other substituents such as alkyl or alkoxy in said. position. The constitution of the acid radical in the acylamino-group has itself practically no eifect on the shade; this is of great importance in the production of the new dyestufis which are to be adapted to various different solvents and emulsifying agents, since the solubility properties are dependent on the acyl group and can be varied by variation of this group without affecting the shade.
The following examples illustrate the inven tion, the parts being by weight.
Example 1 21.6 parts of 5-nitro-2-aminophenylmethylsulphone are diazotized in the usual manner with the required proportion of nitrosylsulphuric acid. When diazotization is finished the mixture is poured into a large quantity of ice-water and the diluted diazo solution is filtered if necessary. The clear solution is allowed to run into an aqueous solution of 28.2 parts of -ethoxy-B-diw-hydroxyethylamino-1-acetanilide. The formation of the dyestuff can be accelerated by neutralization of the strongly acid reaction towards Congo by addition of sodium acetate. After the formation of the dyestuii is finished the insoluble dyestuff which has precipitated is filtered and washed until neutral. When dry it is a dark powder which is soluble in organic solvents such as alcohol, acetone or ethyl-acetate to blue solutions. In the form of a suspension it dyes acetate artificial silk pure blue shades which can be discharged to white.
The azo-component used in this example can be made by heating 4-ethoxy-3-amino-1-acetanilide with a hydroxyethylating agent such as glycol-chlorhydrin with addition of an acidbinding agent such as calcium carbonate, magnesium carbonate or sodium carbonate. When recrystallized from water the new base forms small colourless needless of melting point 131 C Example 2 21.6 parts of 5-nitro-2-aminophenylmethylsulphone are diazotized in the usual manner with a nitrosylsulphuric acid corresponding with 6.9 parts of sodium nitrite, and the mixture is poured on to ice and then coupled with an aqueous solution of 28.2 parts of 4-methoxy-3-(ethyl-B,' -dihydroxypropyl)-amino-1-acetanilide. The formation of the dyestuff is completed by the addition of sodium acetate and the dyestuff is isolated in the usual manner and dried. It is a dark powder which dissolves in acetone or ethylacetate to a blue solution, and in the form of a suspension yields blue shades on acetate artificial silk.
A similar dyestuff is obtained by using as diazocomponent the corresponding ethylsulphone.
Example 3 A diazo-compound prepared in the usual manner from 21.6 parts of 5-nitro-2-aminophenylmethylsulphone is combined with an aqeuous solution of 26.8 parts of 4-methoxy-3-di-w-hy droxyethyl-amino l acetanilide. Coupling is completed by the addition of sodium acetate and the dyestuff which has precipitated is isolated in the usual manner and dried. It is a dark powder which is soluble in acetone or ethyl-acetate to a blue solution, and in the form of a suspension dyes acetate artificial silk blue shades.
A similar dyestufi is obtained if the corresponding ethylsulphone is used.
Example 4 A diazo-solution prepared in the usual manner from 21.6 parts of 5-nitro-2-aminophenylmethylsulphone is coupled with an aqueous solution of 23.8 parts of 3-di-w-hydroxyethylamino-l-acetanilide. When coupling is finished the dyestufi is separated by filtering, washed until neutral and dried. It is a dark powder which is soluble in acetone or ethyl-acetate to a red-violet solution, and in the form of a suspension dyes acetate artificial silk violet shades which can be discharged to a pure white.
A similar dyestufi is obtained if the corresponding ethylsulphone is used.
3-di-w-hydroxyethylamino-l-acetanilide can be made by the action of glycol-chlorhydrin on 3- amino-l-acetanilide in the presence of an acidbinding agent. The base is very easily soluble in water and in alcohol and crystallizes in the form of colourless prisms of melting point 119 C.
Example 5 26.1 parts of 2-amlno-3,5-dinitro-l-phenylmethylsulphone are diazotized in concentrated sulphuric acid with a nitrosylsulphuric acid corre sponding with 6.9 parts of sodium nitrite. When diazotization is finished the diazotization mixture is filtered and allowed to run in a thin stream into an ice-cold aqueous solution of 26.6 parts of 4-ethoxy-3 (ethyl awhydroxyethyl) -amino-1-acetanilide while well stirring. When formation of the dyestuif is completeed the whole is filtered and the dyestuff washed until neutral and. dried. The new dyestufi is a dark powder which is soluble in acetone or ethyl-acetate to a green-blue solution. In the form of a suspension it dyes acetate artificial silk fast green-blue shades which have a particularly beautiful colour by evening light and can be discharged to a pure white.
A similar dyestuif is obtained if the corresponding ethylsulphone is used.
4-ethoxy-3- (ethyl w hydroxyethyl) -amino-1- acetanilide can be obtained by mono-hydroxyethylating 4 ethoxy 3 amino-l-acetanilide in known manner and ethylating directly by means of diethyl-sulphate the intermediate product without isolating it. The 4-ethoxy-3-(ethyl-w hydroxyethyl) -amino-1-acetanilide is thus obtained in an aqueous solution which can be further used directly.
Example 6 26.1 parts of 2-amino-3.5-dinitro-1-phenylmethylsulphone are diazotized in known manner and the diazo-compound is coupled in an ice-cold aqueous solution with 23.8 parts of 3-di-w-hy droxyethylamino 1 acetanilide. The dyestuff formed is isolated in the usual manner. When dried it is a dark powder which is soluble in acetone or ethyl-acetate to a blue-violet solution, and in the form of a suspension dyes acetate artificia-l silk fast blue-violet shades which can be discharged to a pure white.
A dyestuff having similar properties is obtained if the corresponding ethylsulphone is used.
Example 7 26.1 parts of 2-amino-3,5-dinitro1-phenylmethylsulphone are diazotized with nitrosylsulphuric acid corresponding with 6.9- parts of sodium nitrite and the diazo-compound is coupled with an ice-cold aqueous alcoholic solution of 28.2 parts of 4-ethoxy-3-di-w-hydroxyethylamino-l-acetanilide. By the addition of sodium acetate coupling is completed and the formed dyestuff precipitated. When dried it is a dark powder which is soluble in acetone or ethyl-acetate to a green-blue solution, and in the form of a suspension dyes acetate artificial silk green-blue .shades having a particularly beautiful evening colour.
Dyestuifs of analogous properties are obtained if instead of the 2-amino-3,5-dinitro-l-phenylmethylor -ethylsulphones or Examples 5-7 there are employed the 2-amino-3-halogen-5-nitro-1- phenylalkylsulphones such as 2-amino-3-chloro- 5-nitro-l-phenylmethylor -ethylsulphone.
If instead of the methylor ethyl-sulphones used in the foregoing examples there are used sulphones having higher alkyl-groups such as butyl and so on, similar dyestuffs are obtained In the alkylated amino-group in the coupling components there may be present instead of a 3,w-hydro$;yethyl, ethyl-fl,'y-dihydroxypropyl or ethyl-whydroxyethyl-group, any of the groups indicated in the general description or, although only once, hydrogen; all possible combinations of these substituents may be used. In this manner the shade and also in some cases the solubility can be influenced. For making dyestuifs for acetate artificial silk it is to be recommended that at least one hydroxyalkyl-group should be present, for this group has a very favourable influence on the afiinity for acetyl cellulose or the solubility in the cellulose ester derivative.
Instead of the acetyl-group in the acetyl-metaphenylenediamine derivatives used in the above examples, there may, of course, be present other acyl-residues such as are indicated in the foregoing description. Formyl and lactyl derivatives are in general suitable in the case of dyestuffs for dyeing cellulose esters, whether in the form of textiles, films, masses or lacquers. Higher acylresidues, such as lauryl and so on, are suitable in the case of dyestuffs for colouring fats, oils, waxes, turpentine, benzine and so on, whilst dyestuffs from urea or urethane derivatives are freely soluble in lower alcohols or similar organic solvents or mixtures thereof.
The azo' component may contain other nuclear substituents in the free positions, provided that they do not inhibit the coupling and impart solubility to the dyestuffs; particularly the position 4 of the 1,3-acyldiamines is favourable and from the substituents the alkoxy groups like methand ethoxy are the best suitable.
What I claim is:
1. A process for the manufacture of monoazodyestuffs comprising combining a diazo-compound of a nitro-amino-sulphone of the general formula X- -SO2R N02 in which X represents a radical selected from the group consisting of hydrogen, a nitro group and halogen, and
R. represents a lower alkyl group, with a monoacyl-meta-phenylenediamine of the following general formula NH-Ac in which Ac represents an acyl radical selected from the group consisting of HCO, CHsCO-, C2H5CO, C3H7CO--, C11H23CO and C2H4OHCO,
in which X represents a radical selected from the group consisting of hydrogen, a nitro group and halogen, and
R represents a lower alkyl group,
with a mono-acyl-meta-phenylenediamine of the following general formula 1 IHAc in which Ac represents an acyl radical selected from the group consisting of HCO,CI-I3CO-, C2H5CO, C3H7CO, C11H23CO and R1 and R2 represent the same monovalent organic radicals, the other free positions of the azocomponent containing also nuclear substituents provided that they do not inhibit the coupling and impart solubility in water to the dyestuffs.
3. A process for the manufacture of monoazodyi estuffs comprising combining a diazo-compound of a nitro-amino-sulphone of the general formula lTTHz 1 1 0; in which X represents a radical selected from the group consisting of hydrogen, a nitro group and halogen, and R represents a lower alkyl group,
with a mono-acyl-meta-phenylenediamine of the following general formula NH-Ac in which Ac represents an acyl radical selected from the group consisting of HCO-, CH3CO, C2H5CO, C3H7CO-, C11H23CO and C2H4OHCO, and R1 and R2 represent different monovalent organic radicals, the other free positions of the azocomponent containing also nuclear substituents provided that they do not inhibit the coupling and impart solubility in water to the dyestuffs.
4. A process for the manufacture of monoazodyestuffs comprising combining a diazo-compound of a nitro-amino-sulphone of the general formula in which X represents a radical selected from the group consisting of hydrogen, a nitro group and halogen, and
R represents a lower alkyl group,
with a monoacyl-1neta-phenylenediamine of the following general formula NH-Ac in which Ac represents an acyl radical selected from the group consisting of HCO--, CH3CO, C2H5CO, C3H7CO, C11H23CO and R1 represents a radical selected from the group consisting of methyl, ethyl, propyl, butyl, whydroxyethyl, ,8,' -dihydroxypropyl, B-hydroxy-y-chloropropyl, p-hydroxy- -alkoxypropyl, epoxypropyl, polyhydroxyalkyl radicals of the sugar series, a phenyl group,
R2 represents a radical selected from the group consisting of hydrogen and the said group from which R1 is selected, the other free positions of the azo-component containing also nuclear substituents provided that they do not inhibit the coupling and impart solubility in water to the dyestuffs.
5. A process for the manufacture of monoazodyestuffs comprising combining a dia-zo-compound of a nitro-amino-sulphone of the genera1 formula l N: in Which X represents a radical selected from the group consisting of hydrogen, a nitro group and halogen, and
R represents a lower alkyl group,
with a mono-acyl-meta-phenylenediamine of the following general formula I IHAc in which Ac represents an acyl radical selected from the group consisting of HCO, CH3CO-, C2H5CO, C3H7CO-, C11H23CO and R1 and R2 represent difierent radicals selected from the group consisting of methyl, ethyl, propyl, butyl, w-hydroxyethyl, B -dihydroxypropyl, B-hydroxy- -chloropropyl, fi-hydroXyalkoxypropyl, epoxypropyl, polyhydroxy alkyl radicals of the sugar series, a phenyl group, the other free positions of the azo-component containing also nuclear substituents provided that they do not inhibit the coupling and impart solubility in water to the dyestuffs.
6. A process for the manufacture of monoazodyestuffs comprising combining diazotized -nitro-2-aminophenylmethylsulphone with 4-methoxy 3 (ethyl -p,' -dihydroxypropyl) amino-lacetanilide.
'7. A process for the manufacture of monoazodyestuffs comprising combining diazotized 5-nitro-2-aminophenylmethylsulphone with 4-methoxy-3-di-w-hydroxyethylamino-l-acetanilide.
8. A process for the manufacture of monoazodyestuffs comprising combining diazotized 2-amino-3,5-dinitro-l-phenylmethylsulphone with 3- di-w-hydroxyethylamino-l-acetanilide.
9. As new products, the azo-dyestufis of the general formula in which X represents a radical selected from the group consisting of hydrogen, a nitro group and halo- R represents a lower alkyl group,
Ac represents an acyl radical selected from the group consisting of HCO-, CH3CO-, C2H5CO, C3I-I7CO, C11I-I23CO and R1 represents a monovalent organic radical, and
R2 represents a radical selected from the group consisting of hydrogen and monovalent organic radicals, the three free positions in the acyldiamino-nucleus being occupied by any other substituent, said dyestuffs being insoluble in water and dyeing alcohols, ketones, hydrocarbons and cellulose derivatives violet to greenblue shades, the dyeings on fibres being dischargeable to white.
10. As new products, the azo-dyestuffs of the general formula R1 X N NO1 N=N- s 02R r m-Ac in which X represents a radical selected from the group consisting of hydrogen, a nitro group and halo- R represents a lower alkyl group,
Ac represents an acyl radical selected from the R1 and R2 represent the same monovalent organic radicals, the three free positions in the acyl-diamino-nucleus being occupied by any other substituent, said dyestuffs being insoluble in water and dyeing alcohols, ketones, hydrocarbons and cellulose derivatives violet to greenblue shades, the dyeings on fibres being dischargeable to white.
11. As new products, the azo-dyestuffs of the general formula R1 NOPQN=N R2 s 03R NH-Ac in which X represents a radical selected from the group consisting of hydrogen, a nitro group and halo- R represents a lower alkyl group,
Ac represents an acyl radical selected from the group consisting of HCO, CH3CO, C2H5CO-, C3H7CO C11H23CO- and R1 and R2 represent different monovalent organic radicals, the three free positions in the acyldiamino-nucleus being occupied by any other substituent, said dyestuffs being insoluble in water and dyeing alcohols, ketones, hydrocarbons and celulose derivatives violet to greenblue shades, the dyeings on fibres being dischargeable to white.
12. As new products, the a to-dyestuffs of the general formula X represents a radical selected from the group consisting of hydrogen, a nitro group and halo- R represents a lower alkyl group,
Ac represents an acyl radical selected from the group consisting of HCO-, CH3CO, C2H5CO, CsI-I'zCO-, C11H2sCO-- and R1 represents a radical selected from the group consisting of methyl, ethyl, propyl, butyl, w-hydroxyethyl, [3,v-dihydroxypropyl, e-hydroxy-vchloropropyl, ,Ei-hydroxy-y-alkompropyl, epoxypropyl, polyhydroxyalkyl radicals of the sugar series, a phenyl group,
R2 represents a radical selected from the group consisting of hydrogen and the said group from which R1 is selected, the three free positions in the acyl-diamino-nucleus being occupied by any other substituent, said dyestuffs being insoluble in water and dyeing alcohols, ketones, hydrocarbons and cellulose derivatives violet to green-blue shades, the dyeings on fibres being dischargeable to white.
13. As new products, the azo-dyestuffs of the general formula in which X represents a radical selected from the group consisting of hydrogen, a nitro group and halo- R represents a lower alkyl group,
Ac represents an acyl radical selected from the group consisting of I-ICO-, CHsCO, C2H5CO, C3H7CO, C11H23CO and R1 and R2 each represent the same radicals selected from the group consisting of methyl, ethyl, propyl, butyl, w-hydroxyethyl, p -dihydroxypropyl, ,6-hydroxy-' -chloropropyl, ,c-hydroxy-y-alkoxypropyl, epoxypropyl, polyhydroxyalkyl radicals of the sugar series, a phenyl group, the three free positions in the acyl-diamino-nucleus being occupied by any other substituent, said dyestufis being insoluble in water and dyeing alcohols, ketones, hydrocarbons and cellulose derivatives violet to greenblue shades, the dyeings on fibres being dischargeable to white.
14. As new products, the azo-dyestuffs of the general formula in which X represents a radical selected from the group consisting of hydrogen, a nitro group and halo- R represents a lower alkyl group,
Ac represents an acyl radical selected from the group consisting of I-ICO-, CH3CO, C2H5CO, CsI-I'zCO-, C11H23CO- and R1 and R2 represent different radicals selected from the group consisting of methyl, ethyl, propyl, butyl, w-hydroxyethyl, j8,'y-dihydroxypropyl, fi-hydroxy-v-chloropropyl, p-hydroxyy-alkoxypropyl, epoxypropyl, polyhydroxyalkyl radicals of the sugar series, a phenyl group, the three free positions in the acyl-diaminonucleus being occupied by any other substituent, said dyestuffs being insoluble in water and dyeing alcohols, ketones, hydrocarbons and cellulose derivatives violet to green-blue shades, the dyeings on fibres being dischargeable to white.
15. As new products, the a o-dyestuffs of the formula in which X represents a radical selected from the group consisting of hydrogen and a nitro group,
R represents a lower alkyl group,
R1 and R2 represent radicals selected from the group of lower alkyl and hydroxyalkyl radicals,
Y represents any substituent not imparting solubility in water, said dyestufis being insoluble in water and dyeing alcohols, ketones, hydrocarbons and cellulose derivatives violet to greenblue shades, the dyeings on fibres being dischargeable to white. 16. As new products, the azodyestuifs of the formula 1 X -N I I S 2R NH-C O CE:
in which X represents a radical selected from the group consisting of hydrogen and a nitro group,
R represents a lower alkyl radical selected from the group of methyl and ethyl,
,. R1 and R2 represent same or difierent radicals selected from the group of methyl, ethyl, w-hY- droxyethyl, pp -dihydroxypropyl,
Y represents a member of the group consisting of H, methoxy and ethoxy. 18. As new products, the azo-dyestuffs of the formula OCH:
CHzOHCHzOH NO: N=N
I OH 802R NHC O CH:
in which R is selected from the group consisting of methyl and ethyl, being dark powders insoluble in water, soluble in acetone and in ethyl-acetate to blue solutions and dyeing acetate silk blue shades, the dyeings being dischargeable to White.
19. As new products the azo-dyestuffs of the formula OCH:
I CHzCHaOH CH2CH2OH NOa- N=N I S 02R NHC 0 CH3 in which R is selected from the group consisting of methyl and ethyl, being dark powders insoluble in water and soluble in acetone and in ethylacetate to blue solutions and dyeing acetate silk blue shades, the dyeings being dischargeable to white.
20. As new products the azo-dyestufis of the formula in which R is selected from the group consisting of methyl and ethyl, being dark powders insoluble in water and soluble in acetone and in ethylacetate to blue-violet solutions and dyeing acetate silk blue-violet shades, the dyeings being dischargeable to white.
EMIL SENN.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2111300X | 1936-02-10 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2111300A true US2111300A (en) | 1938-03-15 |
Family
ID=10898742
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US120617A Expired - Lifetime US2111300A (en) | 1936-02-10 | 1937-01-14 | Monoazo-dyestuffs and their manufacture |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2111300A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2420008A (en) * | 1941-07-25 | 1947-05-06 | British Celanese | Disazo dyes containing higher acylamino group |
| US2559787A (en) * | 1945-07-20 | 1951-07-10 | Celanese Corp | Colored cellulose esters and ethers |
| US2971953A (en) * | 1957-12-11 | 1961-02-14 | Ciba Ltd | Water-insoluble azo-dyestuffs |
| US3139438A (en) * | 1958-05-19 | 1964-06-30 | Ici Ltd | Copper phthalocyanine dyestuffs containing (3'-chloro-2'-hydroxypropoxyphenyl) sulfamyl groups |
| US3284437A (en) * | 1963-10-25 | 1966-11-08 | Hoechst Ag | Water-insoluble monoazo-dyestuffs |
| US3342804A (en) * | 1963-02-15 | 1967-09-19 | Sandoz Ltd | Monoazo dyes |
| US3406164A (en) * | 1965-01-14 | 1968-10-15 | Sandoz Ltd | Disperse dyes of the monoazo series |
| DE2460668A1 (en) * | 1973-12-21 | 1975-07-03 | Sandoz Ag | MONOAZO DYES, THEIR PRODUCTION AND USE |
-
1937
- 1937-01-14 US US120617A patent/US2111300A/en not_active Expired - Lifetime
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2420008A (en) * | 1941-07-25 | 1947-05-06 | British Celanese | Disazo dyes containing higher acylamino group |
| US2559787A (en) * | 1945-07-20 | 1951-07-10 | Celanese Corp | Colored cellulose esters and ethers |
| US2971953A (en) * | 1957-12-11 | 1961-02-14 | Ciba Ltd | Water-insoluble azo-dyestuffs |
| US3139438A (en) * | 1958-05-19 | 1964-06-30 | Ici Ltd | Copper phthalocyanine dyestuffs containing (3'-chloro-2'-hydroxypropoxyphenyl) sulfamyl groups |
| US3342804A (en) * | 1963-02-15 | 1967-09-19 | Sandoz Ltd | Monoazo dyes |
| US3398137A (en) * | 1963-02-15 | 1968-08-20 | Sandoz Ltd | 2-methylsulphonyl-4-nitro-2'-acylamino-4'-dialkylamino-1, 1'-azobenzene dyes |
| US3284437A (en) * | 1963-10-25 | 1966-11-08 | Hoechst Ag | Water-insoluble monoazo-dyestuffs |
| US3406164A (en) * | 1965-01-14 | 1968-10-15 | Sandoz Ltd | Disperse dyes of the monoazo series |
| US3428622A (en) * | 1965-01-14 | 1969-02-18 | Sandoz Ag | Water-insoluble phenyl azo phenyl dyes |
| DE2460668A1 (en) * | 1973-12-21 | 1975-07-03 | Sandoz Ag | MONOAZO DYES, THEIR PRODUCTION AND USE |
| US4013636A (en) * | 1973-12-21 | 1977-03-22 | Sandoz Ltd. | N,n-diethyl-4-(2,4-dinitro-6-alkylsulfonylphenylazo)-2-alkoxy-5-alkyl-carbonylaminoanilines |
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