US2171082A - Metallic abrasive - Google Patents
Metallic abrasive Download PDFInfo
- Publication number
- US2171082A US2171082A US246759A US24675938A US2171082A US 2171082 A US2171082 A US 2171082A US 246759 A US246759 A US 246759A US 24675938 A US24675938 A US 24675938A US 2171082 A US2171082 A US 2171082A
- Authority
- US
- United States
- Prior art keywords
- alloy
- chromium
- molybdenum
- abrasive
- per cent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 11
- 229910045601 alloy Inorganic materials 0.000 description 11
- 239000000956 alloy Substances 0.000 description 11
- 239000011651 chromium Substances 0.000 description 9
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 8
- 229910052804 chromium Inorganic materials 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 7
- 229910052750 molybdenum Inorganic materials 0.000 description 7
- 239000011733 molybdenum Substances 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 239000003082 abrasive agent Substances 0.000 description 6
- 238000007792 addition Methods 0.000 description 5
- 238000005275 alloying Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 229910052759 nickel Inorganic materials 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 3
- 229910052720 vanadium Inorganic materials 0.000 description 3
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- QMQXDJATSGGYDR-UHFFFAOYSA-N methylidyneiron Chemical compound [C].[Fe] QMQXDJATSGGYDR-UHFFFAOYSA-N 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 229910001339 C alloy Inorganic materials 0.000 description 1
- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 239000013528 metallic particle Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24C—ABRASIVE OR RELATED BLASTING WITH PARTICULATE MATERIAL
- B24C11/00—Selection of abrasive materials or additives for abrasive blasts
Definitions
- This invention relates to metal abrasives, and more particularly to improved alloy compositions which are especially adapted for use as abrasives.
- This application is a division of prior 5 application Serial No. 141,804, filed May 10, 1937, which latter application is a continuation in part of earlier application Serial No. 100,386,
- a suitable material for metal cleaning and/or cutting should present a high impact resistance as well as a high crushing strength.
- a very efiective blasting material of this general type may be 40 produced by utilizing a ferrous base and advantageously modifying its characteristics to render it eflicacious for the purpose by the simple expedient of incorporating relatively minor amounts of alloying compounds.
- Avery efiective abrasive material may be made 1 by utilizing as a base material an iron-carbon alloy. To this may be added, as for example in the ladle, predetermined quantities of chromium and other components to produce an alloy having the following composition:
- this alloy is a representative one, that is to say,.the percentage of the beneficial. alloying ingredients stated above are not critical.
- the chromium content maybe varied from approximately 0.75% to 3% or more and the molybdenum addition correspondingly varied.
- the molybdenum is utilized in the approximate ratio of 1 part of molybdenum to 5 parts of chromium.
- the crushing strength of the abrasive can markedly be improved by incorporating small amountsof nickel in the alloy.
- nickel When nickel is utilized, the amount of chromium may be somewhat reduced.
- a typical example of a nickel containing alloy producible under the invention is:
- carbon content may be varied over a wide range; the three per cent compositions being given merely as indicating a relatively high carbon ferrous base alloy.
- the percentages ofthe manganese, silicon, sulphur and phosphorous similarly are susceptible of wide variation.
- An abrasive material characterized by a high impact resistance and. crushing strength comprising a high carbon ferrous base alloy containing substantially 3% of carbon, substantially 0.5% of manganese, substantially 1.5% of silicon, substantially 0.1% of sulphur, substantially 0.4% of phosphorous, from 0.1 to 1.5 per cent of chromium; from 0.1 to 3 per cent nickel; and from 0.1 to 0.6 per cent 'of molybdenum, the balance being iron.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Polishing Bodies And Polishing Tools (AREA)
Description
John a Ervin, Ann Arbor, Mich.
" No Drawing. Original application May 10, 1937,
Serial No. 141,804. Divided and this application December 19, 1938, Serial No. 246,759
1 Claim.
This invention relates to metal abrasives, and more particularly to improved alloy compositions which are especially adapted for use as abrasives. This application is a division of prior 5 application Serial No. 141,804, filed May 10, 1937, which latter application is a continuation in part of earlier application Serial No. 100,386,
filed September 11, 1936. I
As is known, discrete metal particles have been employed in the industries as abrasive cleaning and cutting material-.
The peculiarly rigorous conditions to which such material is subjected during use impose diflicultly attainable criteria upon these products. For example, for someuses, as for cutting steels by impelling metallic particles at tremendous velocities from centrifugal machines, a high degree of hardness is desirable. For this use it has been suggested to use tungsten carbide particles. While such material is exceptionally hard, it is nevertheless very expensive. Furthermore, it is short-lived. Such a product is relatively brittle and under the terrific impact, involved in its use, it rapidly breaks down to an undesirable powdery form.
Similarly, other factors come into play. Thus, a suitable material for metal cleaning and/or cutting should present a high impact resistance as well as a high crushing strength. The correlation of these several and physical characteristics to produce a material having the optimum desirable characteristics is diflicult to achieve.
It is also to be observed that due to the nature '5 of the use of this material, great quantities are used and consequently the price factor is a further limitation.
It has been discovered that a very efiective blasting material of this general type may be 40 produced by utilizing a ferrous base and advantageously modifying its characteristics to render it eflicacious for the purpose by the simple expedient of incorporating relatively minor amounts of alloying compounds.
5 Considered more specifically, it has been found that minor additions of chromium and molybdenum or. vanadium to typical high carbon iron alloys produces most effective metallic blast ma-:
terial.
50 These alloying components advantageously and markedly modify the impact resistance and crushing strength of the base alloy and thus give a product possessing these desirable characteristics. An important factor is the marked modi- 5 fication of the material by the addition of relatively minor, and hence inexpensive,lamounts of the alloying ingredients. v
As explained in prior application Serial No. 100,386, it was found that additions of proportioned amounts of chromium and vanadium to 5 iron greatly increases the impact resistance. Similarly, as explained in that application, it was ascertained that the addition of properly proportioned amounts of molybdenum and nickel markedly improved the crushing strength of iron, thus rendering .the resulting alloy particularly efiective as an abrasive material.
As a result of further experimentation, it has now been found that improved abrasive material of this type can be produced when utilizing few alloying constituents. It has been found, for example, that for this particular use, molybdenum and vanadium have a relative action, and either may be used, together with the chromium to confer on the ferrous base alloy the desirable characteristics 'of high impact resistance and crushing strength. I
Theinvention will be more readily comprehended from a consideration of typical compu- I tations.
Avery efiective abrasive material may be made 1 by utilizing as a base material an iron-carbon alloy. To this may be added, as for example in the ladle, predetermined quantities of chromium and other components to produce an alloy having the following composition:
Per cent C 3.0 Mn 0.5 Si 1.5 S 0.1 P 0.4: CI' 1-0 M0 0.2 Fe-remainder. 40
It will be appreciated, of course, that this alloy is a representative one, that is to say,.the percentage of the beneficial. alloying ingredients stated above are not critical. Thus the chromium content maybe varied from approximately 0.75% to 3% or more and the molybdenum addition correspondingly varied. In the improved alloys, the molybdenum is utilized in the approximate ratio of 1 part of molybdenum to 5 parts of chromium.
The crushing strength of the abrasive can markedly be improved by incorporating small amountsof nickel in the alloy. When nickel is utilized, the amount of chromium may be somewhat reduced. A typical example of a nickel containing alloy producible under the invention is:
Per cent Si 1.5 S n1 P; 0.4
Cr 0.1-1 5 Ni 0.1-3 0 M0 0.1-0 6 Fe-rmainder.
It will be understood that the carbon content may be varied over a wide range; the three per cent compositions being given merely as indicating a relatively high carbon ferrous base alloy. The percentages ofthe manganese, silicon, sulphur and phosphorous similarly are susceptible of wide variation.
While improved compositions have been described, it is to be understood that these are merely given as examples to explain the underlying principles of the invention, and not limiting the scope of the invention to these specific compositions.
I claim:
An abrasive material characterized by a high impact resistance and. crushing strength comprisinga high carbon ferrous base alloy containing substantially 3% of carbon, substantially 0.5% of manganese, substantially 1.5% of silicon, substantially 0.1% of sulphur, substantially 0.4% of phosphorous, from 0.1 to 1.5 per cent of chromium; from 0.1 to 3 per cent nickel; and from 0.1 to 0.6 per cent 'of molybdenum, the balance being iron.
JOHN F. ERV'IN.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US246759A US2171082A (en) | 1937-05-10 | 1938-12-19 | Metallic abrasive |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US141804A US2145757A (en) | 1937-05-10 | 1937-05-10 | Metallic abrasive material |
| US246759A US2171082A (en) | 1937-05-10 | 1938-12-19 | Metallic abrasive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2171082A true US2171082A (en) | 1939-08-29 |
Family
ID=26839465
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US246759A Expired - Lifetime US2171082A (en) | 1937-05-10 | 1938-12-19 | Metallic abrasive |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2171082A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3370934A (en) * | 1967-06-05 | 1968-02-27 | Ball Brothers Co Inc | Iron alloy |
| US4124413A (en) * | 1974-03-18 | 1978-11-07 | Toyota Jidosha Kogyo Kabushiki Kaisha | Wear and pitting resistant cast iron |
-
1938
- 1938-12-19 US US246759A patent/US2171082A/en not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3370934A (en) * | 1967-06-05 | 1968-02-27 | Ball Brothers Co Inc | Iron alloy |
| US4124413A (en) * | 1974-03-18 | 1978-11-07 | Toyota Jidosha Kogyo Kabushiki Kaisha | Wear and pitting resistant cast iron |
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