US2032322A - Flux-coated electrode - Google Patents
Flux-coated electrode Download PDFInfo
- Publication number
- US2032322A US2032322A US71984634A US2032322A US 2032322 A US2032322 A US 2032322A US 71984634 A US71984634 A US 71984634A US 2032322 A US2032322 A US 2032322A
- Authority
- US
- United States
- Prior art keywords
- silicate
- flux
- metal
- coating
- electrode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 230000004907 flux Effects 0.000 title description 4
- 239000011248 coating agent Substances 0.000 description 12
- 238000000576 coating method Methods 0.000 description 12
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 11
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- 238000003466 welding Methods 0.000 description 9
- 239000004615 ingredient Substances 0.000 description 7
- YDZQQRWRVYGNER-UHFFFAOYSA-N iron;titanium;trihydrate Chemical compound O.O.O.[Ti].[Fe] YDZQQRWRVYGNER-UHFFFAOYSA-N 0.000 description 7
- 229910052782 aluminium Inorganic materials 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 229910052618 mica group Inorganic materials 0.000 description 6
- 239000010445 mica Substances 0.000 description 5
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 5
- 239000004115 Sodium Silicate Substances 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 150000001340 alkali metals Chemical class 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 239000010433 feldspar Substances 0.000 description 4
- 229910052911 sodium silicate Inorganic materials 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 235000019353 potassium silicate Nutrition 0.000 description 3
- 239000002893 slag Substances 0.000 description 3
- 239000002023 wood Substances 0.000 description 3
- 229910000616 Ferromanganese Inorganic materials 0.000 description 2
- 229920000084 Gum arabic Polymers 0.000 description 2
- 239000004111 Potassium silicate Substances 0.000 description 2
- 235000010489 acacia gum Nutrition 0.000 description 2
- 239000000205 acacia gum Substances 0.000 description 2
- -1 feldspar or mica Chemical compound 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 229910052913 potassium silicate Inorganic materials 0.000 description 2
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- 244000171897 Acacia nilotica subsp nilotica Species 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 241001595840 Margarites Species 0.000 description 1
- 101100236442 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) mak-5 gene Proteins 0.000 description 1
- 241000978776 Senegalia senegal Species 0.000 description 1
- 229910052656 albite Inorganic materials 0.000 description 1
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 description 1
- 230000027455 binding Effects 0.000 description 1
- 229910052626 biotite Inorganic materials 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- YGANSGVIUGARFR-UHFFFAOYSA-N dipotassium dioxosilane oxo(oxoalumanyloxy)alumane oxygen(2-) Chemical compound [O--].[K+].[K+].O=[Si]=O.O=[Al]O[Al]=O YGANSGVIUGARFR-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011872 intimate mixture Substances 0.000 description 1
- JCDAAXRCMMPNBO-UHFFFAOYSA-N iron(3+);oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Ti+4].[Ti+4].[Fe+3].[Fe+3] JCDAAXRCMMPNBO-UHFFFAOYSA-N 0.000 description 1
- 229910052659 labradorite Inorganic materials 0.000 description 1
- 239000011018 labradorite Substances 0.000 description 1
- 229910052629 lepidolite Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 229910052630 margarite Inorganic materials 0.000 description 1
- 229910052627 muscovite Inorganic materials 0.000 description 1
- 229910052657 oligoclase Inorganic materials 0.000 description 1
- 229910052652 orthoclase Inorganic materials 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052628 phlogopite Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/36—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
- B23K35/3601—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest with inorganic compounds as principal constituents
- B23K35/3607—Silica or silicates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/294—Coated or with bond, impregnation or core including metal or compound thereof [excluding glass, ceramic and asbestos]
- Y10T428/2951—Metal with weld modifying or stabilizing coating [e.g., flux, slag, producer, etc.]
- Y10T428/2953—Titanium compound in coating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/294—Coated or with bond, impregnation or core including metal or compound thereof [excluding glass, ceramic and asbestos]
- Y10T428/2951—Metal with weld modifying or stabilizing coating [e.g., flux, slag, producer, etc.]
- Y10T428/2955—Silicic material in coating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
- Y10T428/31714—Next to natural gum, natural oil, rosin, lac or wax
Definitions
- posited metal is liquid anduntil it has solidified and cooled.
- the ilmenite alone or (usually) the aluminum-bearing silicate alone is not friable, and tends in general to yield a slag 50 which is hard to remove, even withsodium silicate present
- the co-presence of the ilmenite and the aluminum-bearing alkali-metal or alkalineearth silicate, such as feldspar or mica makes a resultant 'slag which is quite friable and easily '55 removable.
- I may and desirably do provide other ingredie'nts in the coating.
- the chief among these is an organic material, such as wood ur.
- I Others may be ferro-manganese and gum afrabic; 5
- Fig. 1 is an elevation of such a coated welding electrode, partly broken away to show 10 a longitudinal section; and Fig. 2 is a cross-section of such coated welding electrode, on the line 2-2 of Fig. 1.
- the metallic wire or rod Ill usually a ferrous wire or rod of desired composi- 15 tion, is covered for all or the greater part of its length by a coating II; and this coating is made of the mixture of ilmenite and an aluminumbearing alkali-metal or alkaline-earth silicate,
- binder silicate such as sodium silicate
- wood flour a binder silicate
- ferro-manganese a binder silicate
- gum arabic a binder silicate
- the ilmenite which is an iron titanate is suitably reduced to a powder, for intimate mixing with the other ingredients used.
- the aluminum-bearing silicate is also reduced to'a powder, as by grinding, for intimate mixture with the other ingredients. It is most conveniently either feldspar or mica; but other aluminum-bearing alkali-metal or alkaline-earth silicates may be used, such as feldspathoids, zeolites, or epidotes.
- Various feldspars may be used, such as orthoclase, 'albite, oligoclase and labradorite; and various micas, such as biotite, muscovite, lepidolite, margarite, phlogopite, etc.
- the binder silicate is desirably either sodium silicate or potassium silicate; desirably in' the form of water glass if sodium silicate is used, or of the analogous substance if potassium silicate is used.
- the ilmenite and the aluminum-bearing silicate may each vary from 10% to of the whole formed by these three desirably added in the coating. It has a multiple has several functions. Among these are that it helps in the binding action, and also helps in furnishing the carbonaceous gases. It usually is present in relatively small amount, such as 2% to 15% of the total weight of ilmenite and the silicates.
- Percent Ilmenite 10 to 40 Aluminum-bearing alkali-metal or alkaline-earth silicate (such as feldspar or mica) 10 to 40 Sodium silicate (dry basis) 20 to 60 Wood flour 10 to Farm-manganese 5 to 15 Gum arabic 1120 5
- the ingredients are suitably mixed in the desired proportions, and applied to the electrode core in any suitable manner, as by being extruded thereon.
- the rod which has thus been coated is. suitably dried,
- the electrode is found not only to work with reverse polarity, or when it is connected to the positive side of the circuit, but also to work quite .well on fstraight polarity", or when it is connected to the negative side of the circuit-a versatility of operation which is unusual.
- a weld-rod having a coating containing 11- menite, mica, and a binder silicate, with each of the first two forming from 10% to 40% of the total of the three.
- a weld-rod having a coating containing 11- menite, mica, and a binder silicate, with each of the first two forming substantially one-fourth of the total of the three.
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Nonmetallic Welding Materials (AREA)
Description
Feb. 25, 1936. JUDY 2,032,322
FLUX COATED ELECTRODE Filed April 10, 1934 lzmenz' (e,
la Furor mz'm, and aodiwm flame; aeaw'rady wz' wvadfldz farmin44; and 1m ezmz'a.
PRU L Patented Feb. 25, 1936 UNITED STATES FLUX-COATED ELECTRODE Paul R. Judy, Muncie, Ind., assignor .to Indiana Steel & Wire Company, Muncie, Ind., a corporation of Indiana Application April 10,1934, Serial No. "#9346 2 Claims. (01. 219-s) It is the object of my invention to, produce a flux-coated electrode or weld-rod in which the flux-coating not only facilitates the welding operation and protects the welding during its mak- 5 ing and'forms only an easily removable slag, but also one in which such flux coating is made of readily obtainable and inexpensive materials.
In arc welding, as is well known, it is desirable to protect the molten metal both while it is being transferred from the electrode to the work and while the deposited metal is solidifying and C001? ing; and to provide in the coating the necessary ingredients to accomplish this purpose To protect during the solidifying and cooling, it is desirable to provide on the molten metal a thin.
film of protective material, and to have this film substantially continuous and unbroken until the metal has solidified and'cooled; but to have the film of such character that when the whole is cold such film is quite friable and easily removable. By maintaining the film unbroken while the weld-metal is liquid, unevenness of the surface and of the boundary of the weld is in large measure avoided. While the same materials 5 which protect the deposited metal also serve to some extent to protect the metal as it is being deposited from the electrode, this latter protection may be more effectively obtained by providing a non-oxidizing gaseous envelope for the metal as it is being deposited; and this gaseous envelope can be obtained by providing in' the weld-rod coating an organic material, such as 45 tain an unbroken protective film while the de-.
posited metal is liquid anduntil it has solidified and cooled. Although either the ilmenite alone or (usually) the aluminum-bearing silicate alone is not friable, and tends in general to yield a slag 50 which is hard to remove, even withsodium silicate present, the co-presence of the ilmenite and the aluminum-bearing alkali-metal or alkalineearth silicate, such as feldspar or mica, makes a resultant 'slag which is quite friable and easily '55 removable.
In addition to these three fundamental ingredients, I may and desirably do provide other ingredie'nts in the coating. The chief among these is an organic material, such as wood ur.
I Others may be ferro-manganese and gum afrabic; 5
but they are relatively secondary.
The accompanying drawing shows a coated welding electrode or weld-rod embodying my' invention: Fig. 1 is an elevation of such a coated welding electrode, partly broken away to show 10 a longitudinal section; and Fig. 2 is a cross-section of such coated welding electrode, on the line 2-2 of Fig. 1.
In such drawing, the metallic wire or rod Ill, usually a ferrous wire or rod of desired composi- 15 tion, is covered for all or the greater part of its length by a coating II; and this coating is made of the mixture of ilmenite and an aluminumbearing alkali-metal or alkaline-earth silicate,
with a binder silicate (such as sodium silicate), 20 desirably with wood flour, ferro-manganese, and gum arabic also present, asdescribed above.
The ilmenite, which is an iron titanate is suitably reduced to a powder, for intimate mixing with the other ingredients used. a 25 The aluminum-bearing silicate is also reduced to'a powder, as by grinding, for intimate mixture with the other ingredients. It is most conveniently either feldspar or mica; but other aluminum-bearing alkali-metal or alkaline-earth silicates may be used, such as feldspathoids, zeolites, or epidotes. Various feldspars may be used, such as orthoclase, 'albite, oligoclase and labradorite; and various micas, such as biotite, muscovite, lepidolite, margarite, phlogopite, etc.
The binder silicate is desirably either sodium silicate or potassium silicate; desirably in' the form of water glass if sodium silicate is used, or of the analogous substance if potassium silicate is used.
These three ingredients may vary widely in their relative proportions. The ilmenite and the aluminum-bearing silicate may each vary from 10% to of the whole formed by these three desirably added in the coating. It has a multiple has several functions. Among these are that it helps in the binding action, and also helps in furnishing the carbonaceous gases. It usually is present in relatively small amount, such as 2% to 15% of the total weight of ilmenite and the silicates.
I give below an example of a coating mixture which I have found very effective, and which embodies all of the ingredients discussed above, although not all of them are necessary:
Percent Ilmenite 10 to 40 Aluminum-bearing alkali-metal or alkaline-earth silicate (such as feldspar or mica) 10 to 40 Sodium silicate (dry basis) 20 to 60 Wood flour 10 to Farm-manganese 5 to 15 Gum arabic 1120 5 In making the coating mixture, the ingredients are suitably mixed in the desired proportions, and applied to the electrode core in any suitable manner, as by being extruded thereon. The rod which has thus been coated is. suitably dried,
and is used in the usual manner of welding elecf trodes. It can be effectively used in all positions,
not only in the so-called down-handwelding, in which the work is below the electrode, but also for welding on vertical surfaces and in overhead welding. Also, the electrode is found not only to work with reverse polarity, or when it is connected to the positive side of the circuit, but also to work quite .well on fstraight polarity", or when it is connected to the negative side of the circuit-a versatility of operation which is unusual.
I claim as my invention:---
1. A weld-rod having a coating containing 11- menite, mica, and a binder silicate, with each of the first two forming from 10% to 40% of the total of the three.
2. A weld-rod having a coating containing 11- menite, mica, and a binder silicate, with each of the first two forming substantially one-fourth of the total of the three.
PAUL R. JUDY.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US71984634 US2032322A (en) | 1934-04-10 | 1934-04-10 | Flux-coated electrode |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US71984634 US2032322A (en) | 1934-04-10 | 1934-04-10 | Flux-coated electrode |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2032322A true US2032322A (en) | 1936-02-25 |
Family
ID=24891589
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US71984634 Expired - Lifetime US2032322A (en) | 1934-04-10 | 1934-04-10 | Flux-coated electrode |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2032322A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050189337A1 (en) * | 2004-03-01 | 2005-09-01 | L'air Liquide, Societe Anonyme A Directoire Et Conseil De Surveillance Pour L'etude Et L'exploita | Coated electrode with low fume emission and low hexavalent chromium for welding stainless steels |
-
1934
- 1934-04-10 US US71984634 patent/US2032322A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050189337A1 (en) * | 2004-03-01 | 2005-09-01 | L'air Liquide, Societe Anonyme A Directoire Et Conseil De Surveillance Pour L'etude Et L'exploita | Coated electrode with low fume emission and low hexavalent chromium for welding stainless steels |
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