US20230313637A1 - Bismuth and cement method of abandoning a well and means of real time verification of the bismuth and cement placement process - Google Patents
Bismuth and cement method of abandoning a well and means of real time verification of the bismuth and cement placement process Download PDFInfo
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- US20230313637A1 US20230313637A1 US18/042,063 US202118042063A US2023313637A1 US 20230313637 A1 US20230313637 A1 US 20230313637A1 US 202118042063 A US202118042063 A US 202118042063A US 2023313637 A1 US2023313637 A1 US 2023313637A1
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- Prior art keywords
- tubing
- bismuth
- abandoning
- annulus
- well
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- Abandoned
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- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B33/00—Sealing or packing boreholes or wells
- E21B33/10—Sealing or packing boreholes or wells in the borehole
- E21B33/13—Methods or devices for cementing, for plugging holes, crevices or the like
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- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B33/00—Sealing or packing boreholes or wells
- E21B33/10—Sealing or packing boreholes or wells in the borehole
- E21B33/13—Methods or devices for cementing, for plugging holes, crevices or the like
- E21B33/14—Methods or devices for cementing, for plugging holes, crevices or the like for cementing casings into boreholes
- E21B33/16—Methods or devices for cementing, for plugging holes, crevices or the like for cementing casings into boreholes using plugs for isolating cement charge; Plugs therefor
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B33/00—Sealing or packing boreholes or wells
- E21B33/10—Sealing or packing boreholes or wells in the borehole
- E21B33/12—Packers; Plugs
- E21B33/1208—Packers; Plugs characterised by the construction of the sealing or packing means
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B36/00—Heating, cooling or insulating arrangements for boreholes or wells, e.g. for use in permafrost zones
- E21B36/04—Heating, cooling or insulating arrangements for boreholes or wells, e.g. for use in permafrost zones using electrical heaters
Definitions
- offshore structures may comprise production platforms which are either steel or concrete structures resting on the seabed or floating platforms. Numerous conduits are connected to these offshore structures to carry the various fluids being gas, oil or water etc., which are necessary for the production of oil and/or gas from the well.
- a typical production well will comprise a number of tubular conduits arranged concentrically with respect to each.
- the method of abandoning the well which is presently known in the art involves the separate sealing of each of the concentric conduits which requires a large number of sequential steps.
- the first step is to seal the first central conduit usually by means of cement or other suitable sealant.
- the first annular channel between the first and second conduits is then sealed and the first central conduit is then cut above the seal and the cut section is removed from the well.
- a method of abandoning a well by using a tool to puncture holes in the tubing and the casing outside it to gain access to the annulus immediately outside it, and the annulus outside it (annulus A & B)
- the hole could puncture by mechanical means
- the hole could puncture by explosive means
- the hole could puncture by a laser means
- the hole could puncture by thermite plasma means
- a tool to heat the inside of the tubing using a thermite heat source is provided.
- a tool to heat the inside of the tubing using a electrical heat trace heat source to heat the inside of the tubing using a electrical heat trace heat source
- bismuth beads are deposited on the heat source
- bismuth beads are conveyed in a container above the heat source
- bismuth beads are deposited from surface using gravity
- the bismuth may be cast onto the heating element and conveyed into the well by the heating element
- bismuth beads melt around the heat source, and flow out of the holes punched into the tubing.
- the bismuth solidifies quickly as it drops down the outside of the tube, and eventually forms a solid platform in the annulus A
- the bismuth retains more heat and can convey this heat to the casing outside it.
- bismuth the fluid bismuth can enter the holes in the next casing and form a platform in the annulus B
- the column of bismuth provides positive weight to enable all the annulus to fill evenly by the U Tube effect
- the well can have permanent metal to metal seals placed at any desired depth in the well, in any number of annulus, provided the annulus can be penetrated.
- additional holes maybe punched into the tubing above the bismuth metal to metal seal and cement circulated and positioned above the metal-to-metal seal inside the tubing and annulus A and annulus B
- a disposable chock (flow restrictor) is deployed inside the tubing before cement is circulated thus ensuring the controlled placement of the cement and eliminating U tubing which can have a serious detrimental effect of the final cement slurry placement
- the disposable choke can be gravity deployed
- the disposable choke could be deployed on a metal clad fibre optic cable.
- the choke area is formed by the OD of the tool and ID of the tubing in the well
- the disposable fibre optic cable could provide distributed sensor feedback of the cement process
- the disposable fibre optic cable could provide distributed temperature feedback of the cement process
- the disposable fibre optic cable could provide distributed acoustic feedback of the cement process, providing both cement bond and cement density measurements
- At least one disposable batterypowered acoustic transmitters could be combined with the metal clad fibre
- the tool housing containing the acoustic transmitter could include a heater and bismuth to make a metal-to-metal seal inside the housing once the cement has set
- the fibre optic cable could have a shear release mechanism to enable the fibre optic cable above the cement to be retrieved back to surface, so only a small portion is consumed, and the rest can be used for a future operation
- FIG. 1 is a section side view of a well with the 1st operation of a metal-to-metal seal placed inside the tubing and first annulus outside the tubing.
- FIG. 2 is a section side view of a well with the 2nd operation of a metal to metal seal placed inside the tubing and first annulus outside the tubing
- FIG. 3 is a section side view of a well with the 3rd step of the operation of a metal-to-metal seal placed inside the tubing and first annulus outside the tubing.
- FIG. 4 is a section side view of a well with the 4th step of the operation of a metal-to-metal seal placed inside the tubing and first annulus outside the tubing.
- FIG. 5 is a section side view of a well with the final step of the operation of a metal-to-metal seal placed inside the tubing and first annulus outside the tubing.
- FIG. 6 is a section side view of a well with the 1st operation of a metal-to-metal seal placed inside the tubing and first and second annulus outside the tubing.
- FIG. 7 is a section side view of a well with the 2nd operation of a metal to metal seal placed inside the tubing and first and second annulus outside the tubing.
- FIG. 8 is a section side view of a well with the 3rd step of the operation of a metal-to-metal seal placed inside the tubing and first and second annulus outside the tubing.
- FIG. 9 is a section side view of a well with the 4th step of the operation of a metal-to-metal seal placed inside the tubing and first and second annulus outside the tubing.
- FIG. 10 is a section side view of a well with the 5th step of the operation of a metal-to-metal seal placed inside the tubing and first and second annulus outside the tubing.
- FIG. 11 is a section side view of a well with the final operation of a metal-to-metal seal placed inside the tubing and first and second annulus outside the tubing.
- FIG. 12 is a section side view of a well describing a 2 nd embodiment of the invention with the 1st operation of a metal-to-metal seal placed inside the tubing above the reservoir.
- FIG. 13 is a section side view of a well shown in FIG. 12 with the 2nd operation of a metal-to-metal seal placed inside the tubing above the reservoir.
- FIG. 14 is a section side view of a well shown in FIG. 13 with the 3rd operation of a metal-to-metal seal placed inside the tubing above the reservoir and the conveyance tool being pulled out of the hole
- FIG. 15 is a section side view of a well with the 1st operation (setting a bridge plug) of a metal-to-metal seal placed inside the tubing and annulus A
- FIG. 16 is a section side view of a well with the 2nd operation (puncturing the tubing) of a metal to metal seal placed inside the tubing and annulus A
- FIG. 17 is a section side view of a well with the 3rd step of the operation (placing molten bismuth in the tubing and annulus A) of a metal-to-metal seal placed inside the tubing and annulus A.
- FIG. 18 is a section side view of a well with the 4th step of the operation (placing molten bismuth in the tubing and annulus A) of a metal-to-metal seal placed inside the tubing and first annulus outside the tubing.
- FIG. 19 is a section side view of a well with the 5th step of the operation (placing molten bismuth in the tubing and annulus A) of a metal-to-metal seal placed inside the tubing and first annulus outside the tubing.
- FIG. 20 is a section side view of a well with the 6th step of the operation (perforating above the bismuth) of a metal-to-metal seal placed inside the tubing and first annulus outside the tubing.
- FIG. 21 is a section side view of a well with the 7th step of the operation (installing a disposable choke and disposable sensor system to verify the cement plug placement) of a metal-to-metal seal placed inside the tubing and first annulus outside the tubing.
- FIG. 22 is a section side view of the well with detail A of FIG. 21 , showing the disposable choke and disposable acoustic transmitter
- FIG. 23 is a section YY plan view from FIG. 22 showing the flow choke area created between the tubing ID and the disposable choke OD
- FIG. 24 is a section XX plan view from FIG. 22 showing the flow non-choke area created between the tubing ID and the disposable choke OD
- FIG. 25 is a calculation of the pressure drop for a single choke are for a typical cement density and placement flow rate and the pressure drop if 30 chokes are used
- FIG. 26 is a section side view of the well with detail B of FIG. 21 , showing the disposable fibre optic cable and disposable battery powered acoustic transmitter before cementing
- FIG. 27 is a section side view of the well with detail B of FIG. 21 , showing the disposable fibre optic cable and disposable acoustic transmitter after cementing and the internals of the tool sealed with molten bismuth
- FIG. 28 is a section side view of a well with the final step of the operation (cement placed on top of the bismuth plug with a disposable sensing system set in the cement) of a metal-to-metal seal placed inside the tubing and first annulus outside the tubing.
- FIG. 29 is a section side view of a well with the 1st operation (set bridge plug) of a 3rd type of hybrid metal-to-metal and cement seal placed inside the tubing and annulus A and annulus B
- FIG. 30 is a section side view of a well with the 2nd operation (perforate the tubing and casing) of a 3rd type of hybrid metal-to-metal and cement seal placed inside the tubing and annulus A and annulus B
- FIG. 31 is a section side view of a well with the 3rd operation (deploy heater and bismuth and place molten bismuth in tubing and annulus a and b) of a 3rd type of hybrid metal-to-metal and cement seal placed inside the tubing and annulus A and annulus B
- FIG. 32 is a similar view to FIG. 31 showing a further sequence in the molten bismuth placement of the 3rd operation.
- FIG. 33 is a similar view to FIG. 32 showing a further sequence in the molten bismuth placement of the 3rd operation.
- FIG. 34 is a similar view to FIG. 33 showing the molten bismuth placement of the 3rd operation completed
- FIG. 35 is a section side view of a well with the 4th operation (perforating above the bismuth plug and placing a disposable choke and sensor array in the tubing to monitor and verify the cement placement) of a 3rd type of hybrid metal-to-metal and cement seal placed inside the tubing and annulus A and annulus B
- FIG. 36 is the completion of the 4th operation, cement plug placement completed in tubing and annulus A and B, and the fibre optic cable disconnected from the disposable portion left in the cement plug.
- FIGS. 1 to 5 there is shown a typical platform type well arrangement, with a surface casing 1 combining as a riser 2 to the wellhead deck 3 of the platform 4 . This is cemented in place from its shoe 5 to the mud line 6 .
- the method shown will seal the well while requiring no material to be removed from the well
- the first seal 400 is required above the reservoir and is achieved using a tool string and method described in complete detail in PCT/GB2021/051434
- Operation 1 is to run a bridge plug 30 to provide a base for the subsequent operations
- Operation 2 is to run a tubing hole puncturing tool 29 to make holes 31 the tubing 9 above the bridge plug 30 . Note that operation 1 and 2 could be combined into a single operation. Note that this tool and its operation is described in more detail in PCT/GB2021/051431
- Operation 3 is to run a heating tool 28 to above the bridge plug.
- This heating tool could be thermite based or electrical heat element Note that this tool and its operation is described in more detail in GB2017031.2
- Operation 4 is to deposit bismuth beads 32 [the bismuth in the figures is bit difficult to see—might be better if possible to illustrate it in a more visible way, perhaps with heavier hatching] onto the heating element from the housing above the heater, as the bismuth melts it flows out of the perforations 31 and on the low side of the perforations below the heating tool, the bismuth quickly solidifies 33 eventually forming a solid base at the low side of the perforations
- the bismuth As the upper side of the tubing above the perforations is also adjacent to the heating tool the bismuth is still above its melting point, and the bismuth has approximately ten times the specific gravity of the fluid in the well, the bismuth flows through the perforations 31 into the annulus 35 to form an equal column of bismuth both inside the tubing 34 and in the annulus 35
- the bismuth balances while it is still liquid the result is a solid plug of bismuth, both inside the tubing and inside the annulus of equal height. As it cools and returns to a solid state it expands by approx. 3% and thus squeezes between the casing 7 and the outside of the tubing 9 , and the bismuth inside the tubing exerts an outward force on the internal surface of the tubing.
- FIGS. 6 to 11 there is shown a sequence to seal the tubing ID 37 , annulus A 38 and annulus B 39 .
- Operation 1 is to run a bridge plug 40 to provide a base for the subsequent operations.
- Operation 2 is to run a tubing hole puncturing tool 41 to make holes 42 in the tubing 9 and the casing 43 outside it above the bridge plug 40 . Note that operation 1 and 2 could be combined into a single operation. Note that this tool and its operation is described in more detail in GB2015346.6, where it is necessary to puncture the casing beyond the tubing
- Operation 3 is to run a heating tool 44 to above the bridge plug.
- This heating tool could be thermite based or electrical heat element, or a combination
- Operation 4 is to deposit bismuth beads 45 onto the heating element 44 , as the bismuth melts it flows out of the perforations 42 and on the low side of the perforations, the bismuth quickly solidifies 46 eventually forming a solid base in the annulus A 47 . As more bismuth displaces the fluid in the annulus, more heat is transferred to the casing 48 outside it. As the heating is transferred to the bismuth in the first annulus A its flows into annulus B 49 where it quickly solidifies and forms a solid base 50 on the low side of the perforations for the liquid bismuth to be supported on top of it.
- the liquid bismuth is between approximately 7-10 times the density of the liquid in annulus A and B. and provides the hydrostatic force to displace the liquid bismuth into the annulus A and B, as more bismuth flows into the annulus A and B more heat is transferred to the annulus A and B, resulting in easier flow of the bismuth into both annuli, resulting in the top level of the molten bismuth approximately equalising in height across the tubing ID and annuli in a similar way to the previously described steps.
- FIGS. 12 to 14 there is shown a typical platform type well arrangement, with a surface casing 101 combining as a riser 102 to the wellhead deck 103 of the platform 104 . This is cemented in place from its shoe 105 to the mud line 106 .
- the method shown will seal the well while requiring no material to be removed from the well
- Operation 1 is to run a bridge plug 120 to provide a base for the subsequent operations.
- Operation 2 is to run a heating tool 121 on a wireline 170 to above the bridge plug.
- This heating tool could be thermite based or electrical heat element, or a combination Note that this tool and its operation is described in more detail in PCT/GB2021/051434
- Operation 3 is to deposit bismuth beads 122 onto the heating element, as the bismuth melts it forms a molten mass around the heating tool. Temperature sensors in the heating tool will provide feedback that the bismuth is at the uniform temperature and the heating tool can be removed 123 back to surface. On cool down the bismuth solidifies and forms a solid metal to metal seal 124 above the bridge plug
- Operation 1 is to run a bridge plug 130 to provide a base for the subsequent operations
- Operation 2 is to run a tubing hole puncturing tool 129 to make holes 131 the tubing 109 above the bridge plug 130
- Operation 3 is to run a heating tool 128 to above the bridge plug.
- This heating tool could be thermite based or electrical heat element, or a combination of both.
- Operation 4 is to deposit bismuth beads 132 onto the heating element, as the bismuth melts it flows out of the perforations and on the low side of the perforations, below the heating element the bismuth quickly solidifies 133 eventually forming a base 172 .
- the bismuth As the upper side of the perforations is adjacent to the heating tool the bismuth is still above its melting point, the bismuth with approximately 10 times the specific gravity of the fluid in the well, flows through the holes 131 to form an equal column of bismuth both inside the tubing 134 and in the annulus 135
- the bismuth below the perforation 172 is sufficient to form a base but does not have a good pressure containment quality.
- the bismuth above the perforation and which was a fully molten mass forms a very high-quality metal to metal seal and hence an excellent pressure barrier ( 134 , 135 ).
- Operation 5 is to is to run a tubing hole puncturing tool 173 to make holes 300 in the tubing 109 above the bismuth plug 134 inside the tubing.
- Operation 6 is to install a disposable choke 200 on a metal clad fibre optic cable 201 , the fibre optic cable provides real time distributed sensing in its simplest form distributed temperature, so will verify the cement setting process in the tubing 302 and the annulus 301 and will also accurately show the exact top of cement 303 .
- the choke is a hollow tube 202 , with the metal clad fibre attached to its nose 203 . Inside the nose could also be a battery powered acoustic transmitter 204 and the fibre optic cable can also act as an acoustic receiver so it could also provide a cement bond and cement density measurement during and at the end of the cement setting process.
- Disposable transmitters 205 could be distributed along the metal clad fibre.
- the inside of the acoustic transmitter will be bismuth 210 and a nichrome wire heating element wire 304 embedded inside the bismuth, the lithium battery 211 which is used to power the acoustic transmitter 205 also after a set period of time (24-48 hrs) heats up the bismuth, which melts and forms a solid barrier 212 inside the tool housing 213 .
- Operation 6 is to circulate cement down the tubing, and into the annulus to form a balanced cement plug 136 inside the tubing and annulus 135 .
- FIGS. 29 to 36 there is shown a sequence to seal.
- the tubing ID 137 , annulus A 138 and annulus B 139 there is shown a sequence to seal.
- Operation 1 is to run a bridge plug 140 to provide a base for the subsequent operations.
- Operation 2 is to run a tubing hole puncturing tool 141 to make holes 142 in the tubing 119 and the casing 143 outside it above the bridge plug 140
- Operation 3 is to run a heating tool 144 to above the bridge plug.
- This heating tool could be thermite based or electrical heat element
- Operation 4 is to deposit bismuth beads 145 onto the heating element, as the bismuth melts it flows out of the perforations 142 and on the low side of the perforations, the bismuth quickly solidifies 146 eventually forming a solid base in the annulus A 147 . As more bismuth displaces the fluid in the annulus, more heat is transferred to the casing 148 outside it. As the heating is transferred to the bismuth in the first annulus A its flows into annulus B 149 where it quickly solidifies and forms a solid base 150 for the liquid bismuth to be supported on.
- the liquid bismuth is between 7 - 10 times the density of the liquid in annulus A and B.
- the column in the tubing 151 provides the hydrostatic force to displace the liquid bismuth in the annulus A and B, as more bismuth flows into the annulus A and B more heat is transferred to the annulus A and B, resulting in easier flow of the bismuth into both annuli.
- Operation 5 is to run a tubing hole puncturing tool to make holes 160 in the tubing 109 and the casing 143 outside it above the bismuth plug set in operation 4 .
- a disposable choke 200 is deployed on a section of disposable metal clad fibre optic cable 201 with also disposable distributed battery powered acoustic transmitters 204 , as described earlier are to ensure the controlled placement of cement slurry and then to verify the quality of cement and cement setting process by a combination of temperature and acoustic measurements.
- cement slurry can be circulated down the tubing into the annulus A and annulus B to form a balanced plug 161 .
- it could be circulated down one of the annuli to minimise the effect of U tubing if no choke is used.
- the disposable portion of the metal clad fibre optic cable 162 can be left in the well, and a shear release 163 can ensure the reliable separation of the metal clad fibre optic cable, and the recovered metal clad fibre 164 can be reused on a future job.
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Abstract
Description
- This patent application is the national stage entry of International Patent Application No. PCT/GB2021/052193, filed on Aug. 23, 2021, and published as WO 2022/038387 A1 on Feb. 24, 2022, and claims priority to Great Britain patent applications 2013067.0 filed on Aug. 21, 2020, and 2014019.0 filed on Sep. 7, 2020, the disclosures of all of which are hereby incorporated by reference in their entireties.
- Over the past 20 years or so a large number of offshore structures have been constructed which are now or will soon be exhausted and will need to be abandoned. These offshore structures may comprise production platforms which are either steel or concrete structures resting on the seabed or floating platforms. Numerous conduits are connected to these offshore structures to carry the various fluids being gas, oil or water etc., which are necessary for the production of oil and/or gas from the well.
- In abandoning a well, consideration has to be given to the potential environmental threat from the abandoned well for many years in the future.
- In the case of offshore structure there is usually no rig derrick in place which can be used to perform the required well abandonment procedure. Therefore, it is typically necessary to install a new derrick or alternatively a mobile derrick can be positioned above the well. This requirement adds considerable expense to the task of abandoning the offshore well, compared to a land based well.
- A typical production well will comprise a number of tubular conduits arranged concentrically with respect to each. The method of abandoning the well which is presently known in the art involves the separate sealing of each of the concentric conduits which requires a large number of sequential steps.
- In the abandonment method known in the art the first step is to seal the first central conduit usually by means of cement or other suitable sealant. The first annular channel between the first and second conduits is then sealed and the first central conduit is then cut above the seal and the cut section is removed from the well.
- The second annular channel between the second and third conduits is then sealed and the second conduit cut above the seal and the cut section is removed from the well.
- This process is repeated until all the conduits are removed. The number of separate steps required is typically very large indeed and the number of separate operations is five times the number of conduits to be removed. This adds considerably to the cost of the well abandonment due to the time taken and the resources required at the well head.
- It is the purpose of the present invention to provide a method of abandoning a well which avoids the disadvantageous and numerous operations which are required by the existing known methods. This will greatly reduce the costs of safely abandoning a well. It is a further objective of the invention to provide a method of abandoning a well without the requirement of a rig which involves significant expense particularly in subsea based wells.
- According to the present invention there is provided a method of abandoning a well, by using a tool to puncture holes in the tubing to gain access to the annulus immediately outside it (annulus A)
- According to a further aspect of the invention there is provided a method of abandoning a well, by using a tool to puncture holes in the tubing and the casing outside it to gain access to the annulus immediately outside it, and the annulus outside it (annulus A & B)
- According to a further aspect of the invention, the hole could puncture by mechanical means
- According to a further aspect of the invention, the hole could puncture by explosive means
- According to a further aspect of the invention, the hole could puncture by a laser means
- According to a further aspect of the invention, the hole could puncture by thermite plasma means
- According to a further aspect of the invention, there is provided a tool to heat the inside of the tubing
- According to a further aspect of the invention, there is provided a tool to heat the inside of the tubing using a thermite heat source
- According to a further aspect of the invention, there is provided a tool to heat the inside of the tubing using a electrical heat trace heat source
- According to a further aspect of the invention, bismuth beads are deposited on the heat source
- According to a further aspect of the invention, bismuth beads are conveyed in a container above the heat source
- According to a further aspect of the invention, bismuth beads are deposited from surface using gravity
- According to a further aspect of the invention the bismuth may be cast onto the heating element and conveyed into the well by the heating element
- According to a further aspect of the invention, bismuth beads melt around the heat source, and flow out of the holes punched into the tubing.
- According to a further aspect of the invention the bismuth solidifies quickly as it drops down the outside of the tube, and eventually forms a solid platform in the annulus A
- According to a further aspect of the invention, as the fluid is displaced in the annulus, the bismuth retains more heat and can convey this heat to the casing outside it.
- According to a further aspect of the invention, bismuth the fluid bismuth can enter the holes in the next casing and form a platform in the annulus B
- According to a further aspect of the invention, the column of bismuth provides positive weight to enable all the annulus to fill evenly by the U Tube effect
- According to a further aspect of the invention the well can have permanent metal to metal seals placed at any desired depth in the well, in any number of annulus, provided the annulus can be penetrated.
- According to a further aspect of the invention, when the heat source is removed, as the steel tubulars cools they slightly contract, whereas as the bismuth cools it expands, thereby energising the metal to metal seal.
- According to a further aspect of the invention additional holes maybe punched into the tubing above the bismuth metal to metal seal and cement circulated and positioned above the metal-to-metal seal inside the tubing and annulus A and annulus B
- According to a further aspect of the invention a disposable chock (flow restrictor) is deployed inside the tubing before cement is circulated thus ensuring the controlled placement of the cement and eliminating U tubing which can have a serious detrimental effect of the final cement slurry placement
- According to a further aspect of the invention the disposable choke can be gravity deployed
- According to a further aspect of the invention the disposable choke could be deployed on a metal clad fibre optic cable.
- According to a further aspect of the invention the choke area is formed by the OD of the tool and ID of the tubing in the well
- According to a further aspect of the invention the disposable fibre optic cable could provide distributed sensor feedback of the cement process
- According to a further aspect of the invention the disposable fibre optic cable could provide distributed temperature feedback of the cement process
- According to a further aspect of the invention in combination with disposable acoustic transmitters the disposable fibre optic cable could provide distributed acoustic feedback of the cement process, providing both cement bond and cement density measurements
- According to a further aspect of the invention at least one disposable batterypowered acoustic transmitters could be combined with the metal clad fibre
- According to a further aspect of the invention the tool housing containing the acoustic transmitter could include a heater and bismuth to make a metal-to-metal seal inside the housing once the cement has set
- According to a further aspect of the invention the fibre optic cable could have a shear release mechanism to enable the fibre optic cable above the cement to be retrieved back to surface, so only a small portion is consumed, and the rest can be used for a future operation
- The following is a more detailed description of an embodiment according to invention by reference to the following drawings in which:
-
FIG. 1 is a section side view of a well with the 1st operation of a metal-to-metal seal placed inside the tubing and first annulus outside the tubing. -
FIG. 2 is a section side view of a well with the 2nd operation of a metal to metal seal placed inside the tubing and first annulus outside the tubing -
FIG. 3 is a section side view of a well with the 3rd step of the operation of a metal-to-metal seal placed inside the tubing and first annulus outside the tubing. -
FIG. 4 is a section side view of a well with the 4th step of the operation of a metal-to-metal seal placed inside the tubing and first annulus outside the tubing. -
FIG. 5 is a section side view of a well with the final step of the operation of a metal-to-metal seal placed inside the tubing and first annulus outside the tubing. -
FIG. 6 is a section side view of a well with the 1st operation of a metal-to-metal seal placed inside the tubing and first and second annulus outside the tubing. -
FIG. 7 is a section side view of a well with the 2nd operation of a metal to metal seal placed inside the tubing and first and second annulus outside the tubing. -
FIG. 8 is a section side view of a well with the 3rd step of the operation of a metal-to-metal seal placed inside the tubing and first and second annulus outside the tubing. -
FIG. 9 is a section side view of a well with the 4th step of the operation of a metal-to-metal seal placed inside the tubing and first and second annulus outside the tubing. -
FIG. 10 is a section side view of a well with the 5th step of the operation of a metal-to-metal seal placed inside the tubing and first and second annulus outside the tubing. -
FIG. 11 is a section side view of a well with the final operation of a metal-to-metal seal placed inside the tubing and first and second annulus outside the tubing. -
FIG. 12 is a section side view of a well describing a 2nd embodiment of the invention with the 1st operation of a metal-to-metal seal placed inside the tubing above the reservoir. -
FIG. 13 is a section side view of a well shown inFIG. 12 with the 2nd operation of a metal-to-metal seal placed inside the tubing above the reservoir. -
FIG. 14 is a section side view of a well shown inFIG. 13 with the 3rd operation of a metal-to-metal seal placed inside the tubing above the reservoir and the conveyance tool being pulled out of the hole -
FIG. 15 is a section side view of a well with the 1st operation (setting a bridge plug) of a metal-to-metal seal placed inside the tubing and annulus A -
FIG. 16 is a section side view of a well with the 2nd operation (puncturing the tubing) of a metal to metal seal placed inside the tubing and annulus A -
FIG. 17 is a section side view of a well with the 3rd step of the operation (placing molten bismuth in the tubing and annulus A) of a metal-to-metal seal placed inside the tubing and annulus A. -
FIG. 18 is a section side view of a well with the 4th step of the operation (placing molten bismuth in the tubing and annulus A) of a metal-to-metal seal placed inside the tubing and first annulus outside the tubing. -
FIG. 19 is a section side view of a well with the 5th step of the operation (placing molten bismuth in the tubing and annulus A) of a metal-to-metal seal placed inside the tubing and first annulus outside the tubing. -
FIG. 20 is a section side view of a well with the 6th step of the operation (perforating above the bismuth) of a metal-to-metal seal placed inside the tubing and first annulus outside the tubing. -
FIG. 21 is a section side view of a well with the 7th step of the operation (installing a disposable choke and disposable sensor system to verify the cement plug placement) of a metal-to-metal seal placed inside the tubing and first annulus outside the tubing. -
FIG. 22 is a section side view of the well with detail A ofFIG. 21 , showing the disposable choke and disposable acoustic transmitter -
FIG. 23 is a section YY plan view fromFIG. 22 showing the flow choke area created between the tubing ID and the disposable choke OD -
FIG. 24 is a section XX plan view fromFIG. 22 showing the flow non-choke area created between the tubing ID and the disposable choke OD -
FIG. 25 is a calculation of the pressure drop for a single choke are for a typical cement density and placement flow rate and the pressure drop if 30 chokes are used -
FIG. 26 is a section side view of the well with detail B ofFIG. 21 , showing the disposable fibre optic cable and disposable battery powered acoustic transmitter before cementing -
FIG. 27 is a section side view of the well with detail B ofFIG. 21 , showing the disposable fibre optic cable and disposable acoustic transmitter after cementing and the internals of the tool sealed with molten bismuth -
FIG. 28 is a section side view of a well with the final step of the operation (cement placed on top of the bismuth plug with a disposable sensing system set in the cement) of a metal-to-metal seal placed inside the tubing and first annulus outside the tubing. -
FIG. 29 is a section side view of a well with the 1st operation (set bridge plug) of a 3rd type of hybrid metal-to-metal and cement seal placed inside the tubing and annulus A and annulus B -
FIG. 30 is a section side view of a well with the 2nd operation (perforate the tubing and casing) of a 3rd type of hybrid metal-to-metal and cement seal placed inside the tubing and annulus A and annulus B -
FIG. 31 is a section side view of a well with the 3rd operation (deploy heater and bismuth and place molten bismuth in tubing and annulus a and b) of a 3rd type of hybrid metal-to-metal and cement seal placed inside the tubing and annulus A and annulus B -
FIG. 32 is a similar view toFIG. 31 showing a further sequence in the molten bismuth placement of the 3rd operation. -
FIG. 33 is a similar view toFIG. 32 showing a further sequence in the molten bismuth placement of the 3rd operation. -
FIG. 34 is a similar view toFIG. 33 showing the molten bismuth placement of the 3rd operation completed -
FIG. 35 is a section side view of a well with the 4th operation (perforating above the bismuth plug and placing a disposable choke and sensor array in the tubing to monitor and verify the cement placement) of a 3rd type of hybrid metal-to-metal and cement seal placed inside the tubing and annulus A and annulus B -
FIG. 36 is the completion of the 4th operation, cement plug placement completed in tubing and annulus A and B, and the fibre optic cable disconnected from the disposable portion left in the cement plug. - Referring to
FIGS. 1 to 5 there is shown a typical platform type well arrangement, with asurface casing 1 combining as ariser 2 to thewellhead deck 3 of the platform 4. This is cemented in place from itsshoe 5 to themud line 6. - Inside this is an
intermediate size casing 7 which goes from the wellhead to just above thereservoir 8, in most cases the liner would be cemented across the reservoir, however in this example theproduction tubing 9 has been cemented 10 across the reservoir; the abandonment method described herein is applicable to both instances. This has then been perforated 11 to enable the reservoir fluids to flow to surface via the production tubing. - At the end of commercial production, it is necessary to abandon the well, traditionally this has required all the tubing and casing to be removed from the well to enable long cement plugs to be placed inside the resulting open hole. This is extremely expensive and time consuming.
- The method shown will seal the well while requiring no material to be removed from the well
- The
first seal 400 is required above the reservoir and is achieved using a tool string and method described in complete detail in PCT/GB2021/051434 - The next operations are the main focus for this application
-
Operation 1 is to run abridge plug 30 to provide a base for the subsequent operations -
Operation 2 is to run a tubinghole puncturing tool 29 to makeholes 31 thetubing 9 above thebridge plug 30. Note that 1 and 2 could be combined into a single operation. Note that this tool and its operation is described in more detail in PCT/GB2021/051431operation -
Operation 3 is to run aheating tool 28 to above the bridge plug. This heating tool could be thermite based or electrical heat element Note that this tool and its operation is described in more detail in GB2017031.2 - Operation 4 is to deposit bismuth beads 32 [the bismuth in the figures is bit difficult to see—might be better if possible to illustrate it in a more visible way, perhaps with heavier hatching] onto the heating element from the housing above the heater, as the bismuth melts it flows out of the
perforations 31 and on the low side of the perforations below the heating tool, the bismuth quickly solidifies 33 eventually forming a solid base at the low side of the perforations - As the upper side of the tubing above the perforations is also adjacent to the heating tool the bismuth is still above its melting point, and the bismuth has approximately ten times the specific gravity of the fluid in the well, the bismuth flows through the
perforations 31 into theannulus 35 to form an equal column of bismuth both inside thetubing 34 and in theannulus 35 - When the heating tool is removed, the bismuth balances while it is still liquid the result is a solid plug of bismuth, both inside the tubing and inside the annulus of equal height. As it cools and returns to a solid state it expands by approx. 3% and thus squeezes between the
casing 7 and the outside of thetubing 9, and the bismuth inside the tubing exerts an outward force on the internal surface of the tubing. - Referring to
FIGS. 6 to 11 there is shown a sequence to seal thetubing ID 37,annulus A 38 andannulus B 39. -
Operation 1 is to run abridge plug 40 to provide a base for the subsequent operations. -
Operation 2 is to run a tubinghole puncturing tool 41 to makeholes 42 in thetubing 9 and thecasing 43 outside it above thebridge plug 40. Note that 1 and 2 could be combined into a single operation. Note that this tool and its operation is described in more detail in GB2015346.6, where it is necessary to puncture the casing beyond the tubingoperation -
Operation 3 is to run aheating tool 44 to above the bridge plug. This heating tool could be thermite based or electrical heat element, or a combination - Operation 4 is to deposit
bismuth beads 45 onto theheating element 44, as the bismuth melts it flows out of theperforations 42 and on the low side of the perforations, the bismuth quickly solidifies 46 eventually forming a solid base in theannulus A 47. As more bismuth displaces the fluid in the annulus, more heat is transferred to thecasing 48 outside it. As the heating is transferred to the bismuth in the first annulus A its flows into annulus B 49 where it quickly solidifies and forms asolid base 50 on the low side of the perforations for the liquid bismuth to be supported on top of it. - The liquid bismuth is between approximately 7-10 times the density of the liquid in annulus A and B. and provides the hydrostatic force to displace the liquid bismuth into the annulus A and B, as more bismuth flows into the annulus A and B more heat is transferred to the annulus A and B, resulting in easier flow of the bismuth into both annuli, resulting in the top level of the molten bismuth approximately equalising in height across the tubing ID and annuli in a similar way to the previously described steps.
- The result is a solid plug of bismuth, both inside the tubing 52 and inside the annulus A 53 and the
Annulus B 54. As it cools and returns to a solid state it expands by approx. 3% and thus squeezes between thesurface casing 1 and theintermediate casing 7, andintermediate casing 7 and the outside of thetubing 9, and the bismuth inside the tubing exerts an outward force on the internal surface of thetubing 9. - Referring to
FIGS. 12 to 14 there is shown a typical platform type well arrangement, with asurface casing 101 combining as ariser 102 to thewellhead deck 103 of theplatform 104. This is cemented in place from itsshoe 105 to themud line 106. - Inside this is an
intermediate size casing 107 which goes from the wellhead to just above thereservoir 108, in most cases the liner would be cemented across the reservoir, however in this example theproduction tubing 109 has been cemented 110 across the reservoir. This has then been perforated 111 to enable the reservoir fluids to flow to surface via the production tubing. - As previously discussed, at the end of commercial production, it is necessary to abandon the well, traditionally this has required all the tubing and casing to be removed from the well to enable long cement plugs to be placed inside the resulting open hole. This is extremely expensive and time consuming.
- The method shown will seal the well while requiring no material to be removed from the well
-
Operation 1 is to run abridge plug 120 to provide a base for the subsequent operations. -
Operation 2 is to run a heating tool 121 on awireline 170 to above the bridge plug. This heating tool could be thermite based or electrical heat element, or a combination Note that this tool and its operation is described in more detail in PCT/GB2021/051434 -
Operation 3 is to depositbismuth beads 122 onto the heating element, as the bismuth melts it forms a molten mass around the heating tool. Temperature sensors in the heating tool will provide feedback that the bismuth is at the uniform temperature and the heating tool can be removed 123 back to surface. On cool down the bismuth solidifies and forms a solid metal tometal seal 124 above the bridge plug - Referring to
FIGS. 15 to 28 ; -
Operation 1 is to run abridge plug 130 to provide a base for the subsequent operations -
Operation 2 is to run a tubinghole puncturing tool 129 to makeholes 131 thetubing 109 above thebridge plug 130 -
Operation 3 is to run aheating tool 128 to above the bridge plug. This heating tool could be thermite based or electrical heat element, or a combination of both. - Operation 4 is to deposit
bismuth beads 132 onto the heating element, as the bismuth melts it flows out of the perforations and on the low side of the perforations, below the heating element the bismuth quickly solidifies 133 eventually forming abase 172. - As the upper side of the perforations is adjacent to the heating tool the bismuth is still above its melting point, the bismuth with approximately 10 times the specific gravity of the fluid in the well, flows through the
holes 131 to form an equal column of bismuth both inside thetubing 134 and in theannulus 135 - The bismuth below the
perforation 172 is sufficient to form a base but does not have a good pressure containment quality. The bismuth above the perforation and which was a fully molten mass forms a very high-quality metal to metal seal and hence an excellent pressure barrier (134,135). - The result is a solid plug of bismuth, both inside the tubing and inside the annulus. As it cools and returns to a solid state it expands by approx. 3% and thus squeezes between the
casing 107 and the outside of thetubing 109, and the bismuth inside the tubing exerts an outward force on the internal surface of the tubing -
Operation 5 is to is to run a tubinghole puncturing tool 173 to makeholes 300 in thetubing 109 above thebismuth plug 134 inside the tubing. -
Operation 6 is to install adisposable choke 200 on a metal clad fibreoptic cable 201, the fibre optic cable provides real time distributed sensing in its simplest form distributed temperature, so will verify the cement setting process in thetubing 302 and theannulus 301 and will also accurately show the exact top ofcement 303. The choke is ahollow tube 202, with the metal clad fibre attached to itsnose 203. Inside the nose could also be a battery poweredacoustic transmitter 204 and the fibre optic cable can also act as an acoustic receiver so it could also provide a cement bond and cement density measurement during and at the end of the cement setting process.Disposable transmitters 205 could be distributed along the metal clad fibre. The inside of the acoustic transmitter will bebismuth 210 and a nichrome wireheating element wire 304 embedded inside the bismuth, thelithium battery 211 which is used to power theacoustic transmitter 205 also after a set period of time (24-48 hrs) heats up the bismuth, which melts and forms asolid barrier 212 inside thetool housing 213. - On the outside of the
choke tube 202 arediscs 213, when the OD of thedisc 306 is adjacent to thetubing ID 305 it provides theflow restriction area 206, to ensure the flow path does not get plugged, it is relatively speaking quite alarge area 214, in thiscase 2 sq inches (13 cm2), which generates about 20 psi pressure drop at the flow rate and density of a typical plug placement, by using many of the choke discs 213 a very significant back pressure is generated which ensures the controlled placement of thecement slurry 208 described below. -
Operation 6 is to circulate cement down the tubing, and into the annulus to form abalanced cement plug 136 inside the tubing andannulus 135. - Referring to
FIGS. 29 to 36 there is shown a sequence to seal. thetubing ID 137,annulus A 138 andannulus B 139. -
Operation 1 is to run abridge plug 140 to provide a base for the subsequent operations. -
Operation 2 is to run a tubinghole puncturing tool 141 to makeholes 142 in thetubing 119 and thecasing 143 outside it above thebridge plug 140 -
Operation 3 is to run aheating tool 144 to above the bridge plug. This heating tool could be thermite based or electrical heat element - Operation 4 is to deposit
bismuth beads 145 onto the heating element, as the bismuth melts it flows out of theperforations 142 and on the low side of the perforations, the bismuth quickly solidifies 146 eventually forming a solid base in theannulus A 147. As more bismuth displaces the fluid in the annulus, more heat is transferred to thecasing 148 outside it. As the heating is transferred to the bismuth in the first annulus A its flows intoannulus B 149 where it quickly solidifies and forms asolid base 150 for the liquid bismuth to be supported on. - The liquid bismuth is between 7-10 times the density of the liquid in annulus A and B. The column in the
tubing 151 provides the hydrostatic force to displace the liquid bismuth in the annulus A and B, as more bismuth flows into the annulus A and B more heat is transferred to the annulus A and B, resulting in easier flow of the bismuth into both annuli. - The result is a solid plug of bismuth, both inside the
tubing 152 and inside theannulus A 153 and theannulus B 154. As it cools and returns to a solid state it expands by approx. 3% and thus squeezes between thesurface casing 101 and theintermediate casing 107, andintermediate casing 107 and the outside of thetubing 109, and the bismuth inside the tubing exerts an outward force on the internal surface of thetubing 109. -
Operation 5 is to run a tubing hole puncturing tool to makeholes 160 in thetubing 109 and thecasing 143 outside it above the bismuth plug set in operation 4. - A
disposable choke 200 is deployed on a section of disposable metal clad fibreoptic cable 201 with also disposable distributed battery poweredacoustic transmitters 204, as described earlier are to ensure the controlled placement of cement slurry and then to verify the quality of cement and cement setting process by a combination of temperature and acoustic measurements. - Then cement slurry can be circulated down the tubing into the annulus A and annulus B to form a
balanced plug 161. Alternatively, it could be circulated down one of the annuli to minimise the effect of U tubing if no choke is used. - After monitoring the cement temperature, at a suitable time after the cement operation, the disposable portion of the metal clad fibre
optic cable 162 can be left in the well, and ashear release 163 can ensure the reliable separation of the metal clad fibre optic cable, and the recovered metal cladfibre 164 can be reused on a future job.
Claims (26)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB2013067.0A GB202013067D0 (en) | 2020-08-21 | 2020-08-21 | New sequence for well abandonment |
| GB2013067.0 | 2020-08-21 | ||
| GBGB2014019.0A GB202014019D0 (en) | 2020-09-07 | 2020-09-07 | Hybrid bismuth and cement method of abandoning a well |
| GB2014019.0 | 2020-09-07 | ||
| PCT/GB2021/052193 WO2022038387A1 (en) | 2020-08-21 | 2021-08-23 | Bismuth and cement method of abandoning a well and means of real time verification of the bismuth and cement placement process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US20230313637A1 true US20230313637A1 (en) | 2023-10-05 |
Family
ID=77821959
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US18/042,063 Abandoned US20230313637A1 (en) | 2020-08-21 | 2021-08-23 | Bismuth and cement method of abandoning a well and means of real time verification of the bismuth and cement placement process |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20230313637A1 (en) |
| AU (1) | AU2021328716A1 (en) |
| CA (1) | CA3190007A1 (en) |
| GB (1) | GB2612000B (en) |
| NO (1) | NO20230202A1 (en) |
| WO (1) | WO2022038387A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20250320790A1 (en) * | 2024-04-12 | 2025-10-16 | Saudi Arabian Oil Company | Eutectic alloy system for concentric casing string cement repair |
| US12540527B1 (en) * | 2025-01-28 | 2026-02-03 | Saudi Arabian Oil Company | Methods for sealing leaks in oil and gas wells |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US12305484B2 (en) * | 2022-11-01 | 2025-05-20 | Halliburton Energy Services, Inc. | Pre-positioning a meltable seal for plug and abandonment |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3208530A (en) * | 1964-09-14 | 1965-09-28 | Exxon Production Research Co | Apparatus for setting bridge plugs |
| US20030132224A1 (en) * | 2000-03-30 | 2003-07-17 | Canitron Systems, Inc. | Oil and gas well alloy squeezing method and apparatus |
| US7152657B2 (en) * | 2001-06-05 | 2006-12-26 | Shell Oil Company | In-situ casting of well equipment |
| US20070051514A1 (en) * | 2005-09-08 | 2007-03-08 | La Rovere Thomas A | Method and apparatus for well casing repair and plugging utilizing molten metal |
| US20100263876A1 (en) * | 2009-04-21 | 2010-10-21 | Frazier W Lynn | Combination down hole tool |
| US20160123110A1 (en) * | 2011-03-01 | 2016-05-05 | Conocophillips Company | Well plug and abandonment choke insert |
| WO2018063829A1 (en) * | 2016-09-30 | 2018-04-05 | Conocophillips Company | Tool for metal plugging or sealing of casing |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060144591A1 (en) * | 2004-12-30 | 2006-07-06 | Chevron U.S.A. Inc. | Method and apparatus for repair of wells utilizing meltable repair materials and exothermic reactants as heating agents |
| GB2566374B (en) * | 2016-09-30 | 2022-02-23 | Halliburton Energy Services Inc | System and method of producing foamed cement in a laboratory environment |
| GB2577935B (en) * | 2018-10-12 | 2020-12-16 | Equinor Energy As | Permanent plug and abandonment plug established and verified with overdisplaced cement in A-annulus |
| CA3179905A1 (en) * | 2020-04-30 | 2021-11-04 | Wellstrom As | Method and apparatus for plugging |
-
2021
- 2021-08-23 US US18/042,063 patent/US20230313637A1/en not_active Abandoned
- 2021-08-23 WO PCT/GB2021/052193 patent/WO2022038387A1/en not_active Ceased
- 2021-08-23 NO NO20230202A patent/NO20230202A1/en unknown
- 2021-08-23 AU AU2021328716A patent/AU2021328716A1/en not_active Abandoned
- 2021-08-23 CA CA3190007A patent/CA3190007A1/en active Pending
- 2021-08-23 GB GB2302207.2A patent/GB2612000B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3208530A (en) * | 1964-09-14 | 1965-09-28 | Exxon Production Research Co | Apparatus for setting bridge plugs |
| US20030132224A1 (en) * | 2000-03-30 | 2003-07-17 | Canitron Systems, Inc. | Oil and gas well alloy squeezing method and apparatus |
| US7152657B2 (en) * | 2001-06-05 | 2006-12-26 | Shell Oil Company | In-situ casting of well equipment |
| US20070051514A1 (en) * | 2005-09-08 | 2007-03-08 | La Rovere Thomas A | Method and apparatus for well casing repair and plugging utilizing molten metal |
| US20100263876A1 (en) * | 2009-04-21 | 2010-10-21 | Frazier W Lynn | Combination down hole tool |
| US20160123110A1 (en) * | 2011-03-01 | 2016-05-05 | Conocophillips Company | Well plug and abandonment choke insert |
| WO2018063829A1 (en) * | 2016-09-30 | 2018-04-05 | Conocophillips Company | Tool for metal plugging or sealing of casing |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20250320790A1 (en) * | 2024-04-12 | 2025-10-16 | Saudi Arabian Oil Company | Eutectic alloy system for concentric casing string cement repair |
| US12473797B2 (en) * | 2024-04-12 | 2025-11-18 | Saudi Arabian Oil Company | Eutectic alloy system for concentric casing string cement repair |
| US12540527B1 (en) * | 2025-01-28 | 2026-02-03 | Saudi Arabian Oil Company | Methods for sealing leaks in oil and gas wells |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2021328716A1 (en) | 2023-03-16 |
| CA3190007A1 (en) | 2022-02-24 |
| GB202302207D0 (en) | 2023-04-05 |
| GB2612000A (en) | 2023-04-19 |
| NO20230202A1 (en) | 2023-03-01 |
| WO2022038387A1 (en) | 2022-02-24 |
| GB2612000B (en) | 2025-07-30 |
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