[go: up one dir, main page]

US20180195016A1 - Gasoline compositions with improved octane number - Google Patents

Gasoline compositions with improved octane number Download PDF

Info

Publication number
US20180195016A1
US20180195016A1 US15/742,129 US201615742129A US2018195016A1 US 20180195016 A1 US20180195016 A1 US 20180195016A1 US 201615742129 A US201615742129 A US 201615742129A US 2018195016 A1 US2018195016 A1 US 2018195016A1
Authority
US
United States
Prior art keywords
gasoline
octane
gasoline composition
methyl
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US15/742,129
Other languages
English (en)
Inventor
Sébastien NICOLAS
Fernanda GRIGOLETTO
MARTINS Sergio
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhodia Poliamida e Especialidades Ltda
Original Assignee
Rhodia Poliamida e Especialidades Ltda
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia Poliamida e Especialidades Ltda filed Critical Rhodia Poliamida e Especialidades Ltda
Assigned to RHODIA POLIAMIDA E ESPECIALIDADES S.A. reassignment RHODIA POLIAMIDA E ESPECIALIDADES S.A. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: NICOLAS, SÉBASTEIN, MARTINS, SERGIO, GRIGOLETTO, Fernanda
Publication of US20180195016A1 publication Critical patent/US20180195016A1/en
Abandoned legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
    • C10L1/1855—Cyclic ethers, e.g. epoxides, lactides, lactones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/10—Use of additives to fuels or fires for particular purposes for improving the octane number
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/04—Organic compounds
    • C10L2200/0407—Specifically defined hydrocarbon fractions as obtained from, e.g. a distillation column
    • C10L2200/0438—Middle or heavy distillates, heating oil, gasoil, marine fuels, residua
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L2270/00—Specifically adapted fuels
    • C10L2270/02—Specifically adapted fuels for internal combustion engines
    • C10L2270/023—Specifically adapted fuels for internal combustion engines for gasoline engines

Definitions

  • the various refinery streams blended to make gasoline have different characteristics. Some important streams are:
  • a further object of the invention is to propose a metal free non-toxic octane booster additive for octane adjustment of gasoline compositions which is effective at low dosage.
  • the metal-free gasoline composition of the invention comprises at least one gasoline fuel and from 0.05 to 1% by weight of an octane booster additive comprising at least one compound of formula I below:
  • R 3 is H, a linear or branched alkyl, a cycloalkyl or a C( ⁇ O)R 4 group, with R 4 being a linear or branched C1-C4 alkyl or a C5-C6 cycloalkyl.
  • R 3 is H or a C( ⁇ O)R 4 group, with R 4 being methyl, ethyl, isopropyl, n-propyl, isobutyl, n-butyl or tert-butyl.
  • R1 is methyl
  • R2 is phenyl
  • R3 is H
  • the compound is commercially available, for example under the name Augeo® Film HB. This compound can be synthesized by reaction between glycerol and acetophenone, under well-known classical conditions.
  • R1 and R2 are methyl and R3 is a C( ⁇ O)R4 group, with R4 being methyl.
  • the compound is commercially available, for example under the name Augeo® ACT. This compound can be synthesized by transesterification of Solketal with an alkyl acetate under well-known classical conditions.
  • This blend preferably comprises Augeo® Clean Multi and Augeo® Clean Plus, in a weight ratio from about 30:70 to 70:30, and even more preferably 50:50.
  • Another advantageous blend comprises Augeo® Clean Plus and Augeo® ACT, in a weight ratio from 30:70 to 70:30, and even more preferably 60:40.
  • the octane booster additive of the gasoline according to the invention can further comprise esters of C1-C6 carboxylic acids and/or ketones such as butyl acetate, propyl acetate, Methyl Isobutyl Ketone and Methyl Ethyl Ketone, advantageously ethyl acetate.
  • esters of C1-C6 carboxylic acids and/or ketones such as butyl acetate, propyl acetate, Methyl Isobutyl Ketone and Methyl Ethyl Ketone, advantageously ethyl acetate.
  • the molar ratio of compound of formula I/esters of C1-C6 carboxylic acids and/or ketones, and in particular the molar ratio of compound of formula I/ethyl acetate can be from 30:70 to 100:0, preferably from 50:50 to 95:5.
  • Augeo® SL191 which is commercially available, was added in the concentrations indicated below, and the octane numbers were measured according with the standard already mentioned.
  • the table VII below indicates the results obtained.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
US15/742,129 2015-07-06 2016-07-05 Gasoline compositions with improved octane number Abandoned US20180195016A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
PCT/IB2015/001131 WO2017006142A1 (en) 2015-07-06 2015-07-06 Gasoline compositions with improved octane number
IBPCT/IB2015/001131 2015-07-06
PCT/IB2016/000959 WO2017006169A1 (en) 2015-07-06 2016-07-05 Gasoline compositions with improved octane number

Publications (1)

Publication Number Publication Date
US20180195016A1 true US20180195016A1 (en) 2018-07-12

Family

ID=53724385

Family Applications (1)

Application Number Title Priority Date Filing Date
US15/742,129 Abandoned US20180195016A1 (en) 2015-07-06 2016-07-05 Gasoline compositions with improved octane number

Country Status (8)

Country Link
US (1) US20180195016A1 (es)
EP (1) EP3320059B1 (es)
CN (1) CN107849469B (es)
AR (1) AR105274A1 (es)
BR (1) BR112017027947B8 (es)
ES (1) ES2902059T3 (es)
UY (1) UY36770A (es)
WO (2) WO2017006142A1 (es)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109852444B (zh) * 2019-03-15 2021-01-29 山东聚兴新材料科技有限公司 一种汽油辛烷值提升剂的制备方法
CN109852443B (zh) * 2019-03-15 2021-01-29 山东聚兴新材料科技有限公司 一种汽油辛烷值提升剂及其制备方法

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1145930A (en) * 1967-12-22 1969-03-19 Exxon Research Engineering Co Liquid fuel composition
US4179553A (en) * 1978-11-03 1979-12-18 The Firestone Tire & Rubber Company Polyphosphazene polymers containing cyclic ketal substituents
US4390345A (en) 1980-11-17 1983-06-28 Somorjai Gabor A Fuel compositions and additive mixtures for reducing hydrocarbon emissions
JP2007509189A (ja) * 2003-06-24 2007-04-12 ミッキル アルジャーン コーセメーカー， 燃料内において、特にディーゼル燃料、ガソリン燃料およびナタネ油メチルエステル内において、添加物として使用される酸素含有物の製造方法
US8419810B2 (en) * 2004-02-24 2013-04-16 IFP Energies Nouvelles Method for producing biofuels, transforming triglycerides into at least two biofuel families: fatty acid monoesters and ethers and/or soluble glycerol acetals
WO2006084048A1 (en) * 2005-02-02 2006-08-10 Jalin Technologies, Llc Bio-diesel fuel and manufacture of same
RU2365617C1 (ru) * 2008-05-28 2009-08-27 Учреждение Российской Академии Наук Институт Биохимической Физики Им. Н.М. Эмануэля Ран (Ибхф Ран) Октаноповышающая добавка к бензину
EP2298851B1 (en) 2008-05-28 2014-10-08 Emanuel Institute of Biochemical Physics of Russian Academy of Sciences (IBCP RAS) Gasoline automobile fuel comprising agent for increasing the octane number
ITMI20120570A1 (it) * 2012-04-06 2013-10-07 Eni Spa Composizioni di carburante comprendenti derivati idrofobici della glicerina
CN103351907B (zh) * 2013-06-24 2015-07-08 黄河三角洲京博化工研究院有限公司 一种非金属抗爆剂及其制备方法
EP2977433A1 (fr) * 2014-07-24 2016-01-27 Rhodia Opérations Dérivés acétals cycliques à titre d'additifs anti-suies pour un carburant d'aviation

Also Published As

Publication number Publication date
WO2017006169A1 (en) 2017-01-12
ES2902059T3 (es) 2022-03-24
AR105274A1 (es) 2017-09-20
EP3320059B1 (en) 2021-10-13
WO2017006142A1 (en) 2017-01-12
EP3320059A1 (en) 2018-05-16
BR112017027947B1 (pt) 2021-12-07
BR112017027947A2 (pt) 2018-08-28
CN107849469B (zh) 2021-09-24
CN107849469A (zh) 2018-03-27
UY36770A (es) 2017-01-31
BR112017027947B8 (pt) 2023-04-18

Similar Documents

Publication Publication Date Title
Badia et al. New octane booster molecules for modern gasoline composition
US6767372B2 (en) Aviation gasoline containing reduced amounts of tetraethyl lead
RU2006126121A (ru) Состав и способ смешивания бензинов на терминалах
US20110023355A1 (en) Combustible Mixed Butanol Fuels
CA2712830A1 (en) Reduced rvp oxygenated gasoline composition and method
Di Girolamo et al. Octane enhancers
EP3320059B1 (en) Gasoline compositions with improved octane number
CN102449125B (zh) 燃料组合物及其用途
US11591532B2 (en) Lead-free gasoline blend
RU2605952C1 (ru) Альтернативное автомобильное топливо и способ его получения
CN111278955A (zh) 共混燃料的方法
RU2549179C1 (ru) Альтернативное автомобильное топливо
JP5383618B2 (ja) 過給エンジン用燃料組成物
Pirouzfar et al. Gasoline additives
RU2641108C1 (ru) Альтернативное топливо для автомобилей
NL2031739B1 (en) Fuel additive
WO2018122691A1 (en) Lead-free, oxygenated, high-octane gasoline blend
JP5383619B2 (ja) 過給エンジン用燃料組成物
US20100000483A1 (en) Gasoline compositions
Ali et al. Blending Properties of MTBE and Other Oxygenates in Gasoline
JP2010235902A (ja) ガソリン組成物
RU2605954C1 (ru) Альтернативное автомобильное топливо и способ его получения
Seddon Economics: Gasoline (petrol) additives-update
RU2337943C1 (ru) Кислородсодержащая добавка к автомобильным бензинам и способ ее приготовления
JP5214688B2 (ja) エタノール配合ガソリンの製造方法

Legal Events

Date Code Title Description
AS Assignment

Owner name: RHODIA POLIAMIDA E ESPECIALIDADES S.A., BRAZIL

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:NICOLAS, SEBASTEIN;GRIGOLETTO, FERNANDA;MARTINS, SERGIO;SIGNING DATES FROM 20180206 TO 20180326;REEL/FRAME:045477/0411

STPP Information on status: patent application and granting procedure in general

Free format text: RESPONSE TO NON-FINAL OFFICE ACTION ENTERED AND FORWARDED TO EXAMINER

STPP Information on status: patent application and granting procedure in general

Free format text: FINAL REJECTION MAILED

STPP Information on status: patent application and granting procedure in general

Free format text: RESPONSE AFTER FINAL ACTION FORWARDED TO EXAMINER

STPP Information on status: patent application and granting procedure in general

Free format text: NON FINAL ACTION MAILED

STPP Information on status: patent application and granting procedure in general

Free format text: RESPONSE TO NON-FINAL OFFICE ACTION ENTERED AND FORWARDED TO EXAMINER

STPP Information on status: patent application and granting procedure in general

Free format text: FINAL REJECTION MAILED

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION