US20170077231A1 - SiGe CMOS WITH TENSELY STRAINED NFET AND COMPRESSIVELY STRAINED PFET - Google Patents
SiGe CMOS WITH TENSELY STRAINED NFET AND COMPRESSIVELY STRAINED PFET Download PDFInfo
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- H10D30/60—Insulated-gate field-effect transistors [IGFET]
- H10D30/791—Arrangements for exerting mechanical stress on the crystal lattice of the channel regions
- H10D30/797—Arrangements for exerting mechanical stress on the crystal lattice of the channel regions being in source or drain regions, e.g. SiGe source or drain
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- H10D84/01—Manufacture or treatment
- H10D84/0123—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs
- H10D84/0126—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs the components including insulated gates, e.g. IGFETs
- H10D84/0165—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs the components including insulated gates, e.g. IGFETs the components including complementary IGFETs, e.g. CMOS devices
- H10D84/0193—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs the components including insulated gates, e.g. IGFETs the components including complementary IGFETs, e.g. CMOS devices the components including FinFETs
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- H10D84/038—Manufacture or treatment characterised by using material-based technologies using Group IV technology, e.g. silicon technology or silicon-carbide [SiC] technology using silicon technology, e.g. SiGe
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- H10D86/201—Integrated devices formed in or on insulating or conducting substrates, e.g. formed in silicon-on-insulator [SOI] substrates or on stainless steel or glass substrates the substrates comprising an insulating layer on a semiconductor body, e.g. SOI
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- H10D86/00—Integrated devices formed in or on insulating or conducting substrates, e.g. formed in silicon-on-insulator [SOI] substrates or on stainless steel or glass substrates
- H10D86/201—Integrated devices formed in or on insulating or conducting substrates, e.g. formed in silicon-on-insulator [SOI] substrates or on stainless steel or glass substrates the substrates comprising an insulating layer on a semiconductor body, e.g. SOI
- H10D86/215—Integrated devices formed in or on insulating or conducting substrates, e.g. formed in silicon-on-insulator [SOI] substrates or on stainless steel or glass substrates the substrates comprising an insulating layer on a semiconductor body, e.g. SOI comprising FinFETs
Definitions
- CMOS complementary metal oxide semiconductor
- Tensile strained silicon enhances electron mobility by lifting the conduction band degeneracies, reducing carrier scattering and increasing the population of carriers in sub-bands with lower transverse effective mass.
- Channel engineering using Si or s-Si for an NFET and compressive strained SiGe for a PFET is one option for realizing small geometry devices while meeting performance targets.
- the fabrication of transistors having a tensile strained silicon germanium (SiGe) channel, for n-type field effect transistors (NFETs), and a compressive strained SiGe channel, for p-type field effect transistors (PFETs), on the same common substrate would provide advantages and would be a desirable goal.
- the embodiments of this invention provide a method that comprises providing a Si substrate having an overlying layer of Si 1-x Ge x ; growing, over the layer of Si 1-x Ge x , a layer of Si in what will be an NFET region and a second layer of Si 1-x Ge x in what will be a PFET region; partitioning the layer of Si 1-x Ge x into a structure comprised of a first Si 1-x Ge x sub-layer disposed in the NFET region and into a second Si 1-x Ge x sub-layer disposed in the PFET region; annealing the structure to convert the first Si 1-x Ge x sub-layer and the overlying Si layer into a tensily strained Si 1-x Ge x intermixed layer and to convert the second Si 1-x Ge x sub-layer and the overlying second layer of Si 1-x Ge x into a compressively strained Si 1-x Ge x intermixed layer, where a value of x in the tens
- the embodiments of this invention provide a structure that comprises a substrate comprised of Si; a layer of dielectric material disposed on a surface of the substrate and a first transistor device disposed over the layer of dielectric material and a second transistor device disposed over the layer of dielectric material.
- the first transistor device is an NFET device having a tensily strained channel comprised of a first layer of intermixed Si 1-x Ge x
- the second transistor device is a PFET device having a compressively strained channel comprised of a second layer of intermixed Si 1-x Ge x
- a value of x in the first layer of intermixed Si 1-x Ge x is less than a value of x in the second layer of intermixed Si 1-x Ge x .
- the embodiments of this invention provide a structure that comprises NFET tensile strained CMOS transistors and PFET compressive strained CMOS transistors that are disposed on a common substrate.
- the structure is fabricated by a process that comprises providing a Si substrate having an overlying layer of Si 1-x Ge x ; growing, over the layer of Si 1-x Ge x , a layer of Si in what will be an NFET region and a second layer of Si 1-x Ge x in what will be a PFET region; partitioning the layer of Si 1-x Ge x into a structure comprised of a first Si 1-x Ge x sub-layer disposed in the NFET region and into a second Si 1-x Ge x sub-layer disposed in the PFET region; annealing the structure to convert the first Si 1-x Ge x sub-layer and the overlying Si layer into a tensily strained Si 1-x Ge x intermixed layer and to convert the second Si 1-x Ge x sub
- FIGS. 1-5 are each an enlarged cross-sectional view showing various initial, intermediate and completed or substantially completed structures that are fabricated in accordance with embodiments of this invention, wherein the various layer thicknesses and other dimensions are not necessarily drawn to scale. More specifically:
- FIG. 1 shows a starting structure (starting wafer) comprised of a Si substrate, an overlying BOX and a layer of strain relaxed Si 1-x Ge x ;
- FIG. 2 shows a result of performing patterned epitaxial growth processes that are used to grow, over the layer of strain relaxed Si 1-x Ge x , a layer of Si on what will be an NFET region and a layer of Si 1-x Ge x on what will be a PFET region, and that further shows the formation of a trench that partitions the layer of strain relaxed Si 1-x Ge x into a first Si 1-x Ge x sub-layer disposed in the NFET region and into a second Si 1-x Ge x sub-layer disposed in the PFET region;
- FIG. 3 shows a result of deposition of a capping layer and a performance of an anneal process that converts the first Si 1-x Ge x sub-layer and the overlying Si layer into a first Si 1-x Ge x intermixed layer and that simultaneously converts the second Si 1-x Ge x sub-layer and the overlying layer of Si 1-x Ge x into a second Si 1-x Ge x intermixed layer;
- FIG. 4 shows the structure of FIG. 3 after photolithographically defining fins and etching the first Si 1-x Ge x intermixed layer and the second Si 1-x Ge x intermixed layer to form an NFET fin and a PFET fin;
- FIG. 5 illustrates an alternate embodiment where planar CMOS transistors are formed in the first Si 1-x Ge x intermixed layer and in the second Si 1-x Ge x intermixed layer instead of the FinFET CMOS transistors shown in FIG. 4 .
- epitaxial growth and/or deposition and “epitaxially formed and/or grown” mean the growth of a semiconductor material on a deposition surface of a semiconductor material, in which the semiconductor material being grown has the same crystalline characteristics as the semiconductor material of the deposition surface.
- the chemical reactants provided by source gases are controlled and the system parameters are set so that the depositing atoms arrive at the deposition surface of the semiconductor substrate with sufficient energy to move around on the surface and orient themselves to the crystal arrangement of the atoms of the deposition surface. Therefore, an epitaxial semiconductor material has the same crystalline characteristics as the deposition surface on which it is formed.
- an epitaxial semiconductor material deposited on a ⁇ 100 ⁇ crystal surface will take on a ⁇ 100 ⁇ orientation.
- epitaxial growth and/or deposition processes are selective to forming on semiconductor surface, and do not deposit material on dielectric surfaces, such as silicon dioxide or silicon nitride surfaces.
- Examples of various epitaxial growth process apparatuses and methods that are suitable for use in implementing the embodiments of this invention can include, but are not limited to, chemical vapor deposition (CVD) such as, for example, rapid thermal chemical vapor deposition (RTCVD), atmospheric pressure chemical vapor deposition (APCVD), low pressure chemical vapor deposition (LPCVD) and ultra-high vacuum chemical vapor deposition (UHVCVD).
- CVD chemical vapor deposition
- RTCVD rapid thermal chemical vapor deposition
- APCVD atmospheric pressure chemical vapor deposition
- LPCVD low pressure chemical vapor deposition
- UHVCVD ultra-high vacuum chemical vapor deposition
- MBE molecular beam epitaxy
- LEPD low-energy plasma deposition
- the temperature for an epitaxial deposition process typically ranges from about 300° C. to about 900° C. Although higher temperature will typically result in faster deposition of the semiconductor material, the faster deposition may also result in crystal defects and film cracking.
- this invention can employ semiconductor on insulator (SOI) technology where a thin semiconductor layer, such as a layer of SiGe, is formed over an insulating layer, such as silicon oxide, which in turn is formed over a (bulk) substrate, such as a Si substrate.
- the insulating (dielectric) layer can be referred to as a buried oxide (BOX) layer or simply as a BOX.
- BOX buried oxide
- the SOI layer can be divided into active regions by shallow trench isolation (STI) which intersects the BOX and provides total isolation for active device regions formed in the SOI layer.
- STI shallow trench isolation
- fin structures can be defined in the SOI layer and sources and drains can be formed, for example, by ion implantation of N-type or P-type dopants into the fins.
- a FET channel region between a source/drain pair can be created so as to underlie a gate structure.
- SOI substrates such as a SiGe on insulator substrate
- a bulk (e.g., SiGe) substrate might be used,
- the embodiments of this invention pertain to a CMOS integrated circuit with SiGe channels for both NFETs and PFETs, wherein the NFETs are tensily strained and the PFETs are compressively strained.
- FIG. 1 shows a starting structure (starting wafer) that can be comprised of a Si substrate 10 of arbitrary thickness, an overlying layer of BOX 12 having an exemplary thickness in a range of about 10 nm-400 nm, and a layer 14 of strain relaxed Si 1-x Ge x (e.g., where x can have a value in a range of about 0.15 to about 0.40).
- the layer 14 of Si 1-x Ge x could have an exemplary thickness in a range of about 1 nm to about 20 nm, with about 4 nm being one suitable nominal value.
- the layer 14 of Si 1-x Ge x can be formed using, for example, Ge intermix or Ge thermal condensation processes with initial layers of Si and Ge (e.g., carried out at an exemplary temperature of about 1200° C.).
- the layer 14 of Si 1-x Ge x can also be formed using, for example, a wafer bonding process where the layer 14 of Si 1-x Ge x is disposed on a handle wafer and thermally bonded to the BOX 12 , followed by removal of the handle wafer and thinning, if needed, of the layer 14 of Si 1-x Ge x to the desired thickness.
- This can be accomplished by applying a mask to the surface of the layer 14 of Si 1-x Ge x in the PFET region and epitaxially growing the Si layer 16 upon the surface of the layer 14 of Si 1-x Ge x in the NFET region.
- the Si layer 16 can have an exemplary thickness in a range of about 10 nm to about 60 nm, with about 40 nm-50 nm being suitable nominal values.
- the thickness is preferably less that the critical thickness so as to minimize a presence of dislocation defects.
- This can be followed by applying a mask to a top surface of the Si layer 16 and then epitaxially growing the layer 18 of Si 1-x Ge x upon the surface of the layer 14 of Si 1-x Ge x in the PFET region. It should be noted that the layer 18 of Si 1-x Ge x could be grown prior to growing the layer of 16 of Si. In the layer 18 the value of x is greater than the value of x in the layer 14 of Si 1-x Ge x .
- the value of x in the layer 14 of Si 1-x Ge x is in the range of about 0.15 to about 0.40 then the value of x in the layer 18 of Si 1-x Ge x can be in a range of about 0.40 to about 0.70.
- the thickness of the layer 18 is preferably equal to or substantially equal to the thickness of the layer 16 .
- a trench 20 is formed to physically and electrically isolate the NFET region from PFET region.
- the trench 20 preferably extends downwards at least to the top surface of the BOX 12 .
- the trench 20 can be formed by partially masking the layers 16 and 18 and then etching the exposed semiconductor material.
- the trench 20 can be considered to partition the layer 14 of Si 1-x Ge x into a first Si i - x Ge x sub-layer 14 A that is disposed in the NFET region and into a second Si 1-x Ge x sub-layer 14 B that is disposed in the PFET region.
- FIG. 3 shows a result of deposition of a capping layer 22 , e.g., one composed of an oxide or a nitride, that fills the trench 20 , as well as the performance of a thermal anneal process (e.g., one conducted at an exemplary temperature of about 1000° C.) to mix the Si and the Ge.
- the anneal converts the first Si 1-x Ge x sub-layer 14 A and the overlying Si layer 16 into a first Si 1-x Ge x intermixed layer 16 A and simultaneously converts the second Si 1-x Ge x sub-layer 14 B and the overlying layer 18 of Si 1-x Ge x into a second Si 1-x Ge x intermixed layer 18 A.
- the final Ge percentage of the first Si 1-x Ge x intermixed layer 16 A is less than the original Ge percentage of the relaxed layer 14 of Si 1-x Ge x due to the dilution resulting from the presence of the Si layer 16 .
- the Ge concentration in the first Si 1-x Ge x intermixed layer 16 A could be about 0.05%. Due to the resulting difference in the lattice between the first Si 1-x Ge x intermixed layer 16 A and the Si substrate 10 the first Si 1-x Ge x intermixed layer 16 A is tensile strained.
- the final Ge percentage of the second Si 1-x Ge x intermixed layer 18 A is greater than the original Ge percentage of the relaxed layer 14 of Si 1-x Ge x due to the Ge enhancement resulting from the presence of the SiGe layer 18 that has the greater Ge percentage than the underlying second Si 1-x Ge x sub-layer 14 B. Due to the resulting difference in the lattice between the second Si 1-x Ge x intermixed layer 18 A and the Si substrate 10 the second Si 1-x Ge x intermixed layer 18 A is compressively strained.
- FIG. 4 shows the structure of FIG. 3 after photolithographically defining fins and etching the first Si 1-x Ge x intermixed layer 16 A and the second Si 1-x Ge x intermixed layer 18 A to form an NFET fin 24 A and a PFET fin 24 B.
- the capping layer 22 can first be removed and fin patterning masks applied or it can be patterned and selectively removed to leave portions where fins 24 A and 24 B are desired.
- the NFET fin 24 A is tensile strained and the PFET fin 24 B is compressively strained.
- the height of the fins 24 A, 24 B is comparable to the sum of the thicknesses of the layer 14 of Si 1-x Ge x (e.g., about 4 nm) and the thicknesses of the Si layer 16 and the Si 1-x Ge x layer 18 (e.g., 40 nm). If desired, and by example, the thicknesses of the first Si 1-x Ge x intermixed layer 16 A and the second Si 1-x Ge x intermixed layer 18 A can be adjusted prior to fin patterning to obtain a desired fin height for the fins 24 A and 24 B.
- the fins 24 A and 24 B can have a width governed by the width of the fin patterning mask, e.g., about 7 nm to about 14 nm (or greater).
- the fin length can have any desired value depending on the end use. Processing of the fins 24 A and 24 B can then continue in a conventional manner to form source/drains (S/Ds), gate structures, dielectric layer deposition(s) and vertical and horizontal metallization as needed for the final circuitry.
- S/Ds source/drains
- gate structures gate structures
- dielectric layer deposition(s) dielectric layer deposition(s)
- vertical and horizontal metallization as needed for the final circuitry.
- FIG. 5 illustrates an alternate embodiment where planar CMOS transistors are formed instead of the FinFET CMOS transistors shown in FIG. 4 .
- the first Si 1-x Ge x intermixed layer 16 A and the second Si 1-x Ge x intermixed layer 18 A are processed to fabricate a planar NFET 26 A and a planar PFET 26 B by forming source (S), channel (C) and drain (D) regions adjacent to the top surfaces.
- the surfaces can be implanted with suitable S/D dopants followed by other conventional processes to form S/D contacts, gate stack structures and contacts, dielectric layer deposition(s) and vertical and horizontal metallization as needed for the final circuitry.
- the S/Ds could be raised S/Ds.
- a STI 28 can be formed (if the capping layer material that fills the trench 20 is not retained) to electrically isolate the planar NFET device 26 A from the planar PFET device 26 B.
- the channel of the planar NFET 26 A is tensily strained and the channel of the planar PFET 26 B is compressively strained.
- both the FinFET device structures of FIG. 4 and the planar device structures of FIG. 5 can be formed on the same Si substrate 10 .
- a semiconductor structure can be formed over a substrate to comprise an NFET and a PFET, where both the NFET and the PFET have SiGe channels, where the NFET has a lower Ge % than the PFET, where the NFET SiGe is tensily strained and where the PFET SiGe is compressively strained.
- any one of the structures shown in FIGS. 1-5 could be viewed as an intermediate structure formed during the overall process of providing the semiconductor structure.
- transistor devices can be connected to metalized pads or other devices by conventional ultra-large-scale integration (ULSI) metalization and lithographic techniques.
- ULSI ultra-large-scale integration
- Integrated circuit dies can be fabricated with various devices such as a field-effect transistors, bipolar transistors, metal-oxide-semiconductor transistors, diodes, resistors, capacitors, inductors, etc.
- An integrated circuit in accordance with the present invention can be employed in applications, hardware, and/or electronic systems. Suitable hardware and systems in which such integrated circuits can be incorporated include, but are not limited to, personal computers, communication networks, electronic commerce systems, portable communications devices (e.g., cell phones), solid-state media storage devices, functional circuitry, etc. Systems and hardware incorporating such integrated circuits are considered part of this invention. Given the teachings of the invention provided herein, one of ordinary skill in the art will be able to contemplate other implementations and applications of the techniques of the invention.
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Abstract
Description
- The various embodiments of this invention relate generally to semiconductor devices and fabrication techniques and, more specifically, relate to the fabrication of complementary metal oxide semiconductor (CMOS) transistor devices comprised of SiGe.
- Tensile strained silicon (s-Si) enhances electron mobility by lifting the conduction band degeneracies, reducing carrier scattering and increasing the population of carriers in sub-bands with lower transverse effective mass. Channel engineering using Si or s-Si for an NFET and compressive strained SiGe for a PFET is one option for realizing small geometry devices while meeting performance targets. However, the fabrication of transistors having a tensile strained silicon germanium (SiGe) channel, for n-type field effect transistors (NFETs), and a compressive strained SiGe channel, for p-type field effect transistors (PFETs), on the same common substrate would provide advantages and would be a desirable goal.
- In a first aspect thereof the embodiments of this invention provide a method that comprises providing a Si substrate having an overlying layer of Si1-xGex; growing, over the layer of Si1-xGex, a layer of Si in what will be an NFET region and a second layer of Si1-xGex in what will be a PFET region; partitioning the layer of Si1-xGex into a structure comprised of a first Si1-xGex sub-layer disposed in the NFET region and into a second Si1-xGex sub-layer disposed in the PFET region; annealing the structure to convert the first Si1-xGex sub-layer and the overlying Si layer into a tensily strained Si1-xGex intermixed layer and to convert the second Si1-xGex sub-layer and the overlying second layer of Si1-xGex into a compressively strained Si1-xGex intermixed layer, where a value of x in the tensily strained Si1-xGex intermixed layer is less than a value of x in the compressively strained Si1-xGex intermixed layer; and forming a first transistor device in the NFET region and a second transistor device in the PFET region.
- In another aspect thereof the embodiments of this invention provide a structure that comprises a substrate comprised of Si; a layer of dielectric material disposed on a surface of the substrate and a first transistor device disposed over the layer of dielectric material and a second transistor device disposed over the layer of dielectric material. In the structure the first transistor device is an NFET device having a tensily strained channel comprised of a first layer of intermixed Si1-xGex, and the second transistor device is a PFET device having a compressively strained channel comprised of a second layer of intermixed Si1-xGex. In the structure a value of x in the first layer of intermixed Si1-xGex is less than a value of x in the second layer of intermixed Si1-xGex.
- In yet another aspect thereof the embodiments of this invention provide a structure that comprises NFET tensile strained CMOS transistors and PFET compressive strained CMOS transistors that are disposed on a common substrate. The structure is fabricated by a process that comprises providing a Si substrate having an overlying layer of Si1-xGex; growing, over the layer of Si1-xGex, a layer of Si in what will be an NFET region and a second layer of Si1-xGex in what will be a PFET region; partitioning the layer of Si1-xGex into a structure comprised of a first Si1-xGex sub-layer disposed in the NFET region and into a second Si1-xGex sub-layer disposed in the PFET region; annealing the structure to convert the first Si1-xGex sub-layer and the overlying Si layer into a tensily strained Si1-xGex intermixed layer and to convert the second Si1-xGex sub-layer and the overlying second layer of Si1-xGrex into a compressively strained Si1-xGex intermixed layer, where a value of x in the tensily strained Si1-xGex intermixed layer is less than a value of x in the compressively strained Si1-xGex intermixed layer; and forming a first transistor device in the NFET region and a second transistor device in the PFET region.
-
FIGS. 1-5 are each an enlarged cross-sectional view showing various initial, intermediate and completed or substantially completed structures that are fabricated in accordance with embodiments of this invention, wherein the various layer thicknesses and other dimensions are not necessarily drawn to scale. More specifically: -
FIG. 1 shows a starting structure (starting wafer) comprised of a Si substrate, an overlying BOX and a layer of strain relaxed Si1-xGex; -
FIG. 2 shows a result of performing patterned epitaxial growth processes that are used to grow, over the layer of strain relaxed Si1-xGex, a layer of Si on what will be an NFET region and a layer of Si1-xGex on what will be a PFET region, and that further shows the formation of a trench that partitions the layer of strain relaxed Si1-xGex into a first Si1-xGex sub-layer disposed in the NFET region and into a second Si1-xGex sub-layer disposed in the PFET region; -
FIG. 3 shows a result of deposition of a capping layer and a performance of an anneal process that converts the first Si1-xGex sub-layer and the overlying Si layer into a first Si1-xGex intermixed layer and that simultaneously converts the second Si1-xGex sub-layer and the overlying layer of Si1-xGex into a second Si1-xGex intermixed layer; -
FIG. 4 shows the structure ofFIG. 3 after photolithographically defining fins and etching the first Si1-xGex intermixed layer and the second Si1-xGex intermixed layer to form an NFET fin and a PFET fin; and -
FIG. 5 illustrates an alternate embodiment where planar CMOS transistors are formed in the first Si1-xGex intermixed layer and in the second Si1-xGex intermixed layer instead of the FinFET CMOS transistors shown inFIG. 4 . - The word “exemplary” is used herein to mean “serving as an example, instance, or illustration.” Any embodiment described herein as “exemplary” is not necessarily to be construed as preferred or advantageous over other embodiments. All of the embodiments described in this Detailed Description are exemplary embodiments provided to enable persons skilled in the art to make or use the invention and not to limit the scope of the invention which is defined by the claims.
- The terms “epitaxial growth and/or deposition” and “epitaxially formed and/or grown” mean the growth of a semiconductor material on a deposition surface of a semiconductor material, in which the semiconductor material being grown has the same crystalline characteristics as the semiconductor material of the deposition surface. In an epitaxial deposition process, the chemical reactants provided by source gases are controlled and the system parameters are set so that the depositing atoms arrive at the deposition surface of the semiconductor substrate with sufficient energy to move around on the surface and orient themselves to the crystal arrangement of the atoms of the deposition surface. Therefore, an epitaxial semiconductor material has the same crystalline characteristics as the deposition surface on which it is formed. For example, an epitaxial semiconductor material deposited on a {100} crystal surface will take on a {100} orientation. In some embodiments, epitaxial growth and/or deposition processes are selective to forming on semiconductor surface, and do not deposit material on dielectric surfaces, such as silicon dioxide or silicon nitride surfaces.
- Examples of various epitaxial growth process apparatuses and methods that are suitable for use in implementing the embodiments of this invention can include, but are not limited to, chemical vapor deposition (CVD) such as, for example, rapid thermal chemical vapor deposition (RTCVD), atmospheric pressure chemical vapor deposition (APCVD), low pressure chemical vapor deposition (LPCVD) and ultra-high vacuum chemical vapor deposition (UHVCVD). Other suitable epitaxial growth processes can include, but are not limited to, molecular beam epitaxy (MBE) and low-energy plasma deposition (LEPD). The temperature for an epitaxial deposition process typically ranges from about 300° C. to about 900° C. Although higher temperature will typically result in faster deposition of the semiconductor material, the faster deposition may also result in crystal defects and film cracking.
- In at least one embodiment thereof this invention can employ semiconductor on insulator (SOI) technology where a thin semiconductor layer, such as a layer of SiGe, is formed over an insulating layer, such as silicon oxide, which in turn is formed over a (bulk) substrate, such as a Si substrate. The insulating (dielectric) layer can be referred to as a buried oxide (BOX) layer or simply as a BOX. For a single BOX SOI wafer the SOI layer can be divided into active regions by shallow trench isolation (STI) which intersects the BOX and provides total isolation for active device regions formed in the SOI layer. For FinFET devices fin structures can be defined in the SOI layer and sources and drains can be formed, for example, by ion implantation of N-type or P-type dopants into the fins. A FET channel region between a source/drain pair can be created so as to underlie a gate structure.
- It is pointed out that while certain aspects and embodiments of this invention can be employed with SOI substrates, such as a SiGe on insulator substrate, in some further embodiments a bulk (e.g., SiGe) substrate might be used,
- The embodiments of this invention pertain to a CMOS integrated circuit with SiGe channels for both NFETs and PFETs, wherein the NFETs are tensily strained and the PFETs are compressively strained.
-
FIG. 1 shows a starting structure (starting wafer) that can be comprised of aSi substrate 10 of arbitrary thickness, an overlying layer ofBOX 12 having an exemplary thickness in a range of about 10 nm-400 nm, and alayer 14 of strain relaxed Si1-xGex (e.g., where x can have a value in a range of about 0.15 to about 0.40). Thelayer 14 of Si1-xGex could have an exemplary thickness in a range of about 1 nm to about 20 nm, with about 4 nm being one suitable nominal value. Thelayer 14 of Si1-xGex can be formed using, for example, Ge intermix or Ge thermal condensation processes with initial layers of Si and Ge (e.g., carried out at an exemplary temperature of about 1200° C.). Thelayer 14 of Si1-xGex can also be formed using, for example, a wafer bonding process where thelayer 14 of Si1-xGex is disposed on a handle wafer and thermally bonded to theBOX 12, followed by removal of the handle wafer and thinning, if needed, of thelayer 14 of Si1-xGex to the desired thickness. -
FIG. 2 shows a result of performing patterned epitaxial growth processes that are used to grow alayer 16 of Si on what will be an NFET region and to grow alayer 18 of Si1-xGex (e.g., x=0.50) on what will be a PFET region. This can be accomplished by applying a mask to the surface of thelayer 14 of Si1-xGex in the PFET region and epitaxially growing theSi layer 16 upon the surface of thelayer 14 of Si1-xGex in the NFET region. TheSi layer 16 can have an exemplary thickness in a range of about 10 nm to about 60 nm, with about 40 nm-50 nm being suitable nominal values. The thickness is preferably less that the critical thickness so as to minimize a presence of dislocation defects. This can be followed by applying a mask to a top surface of theSi layer 16 and then epitaxially growing thelayer 18 of Si1-xGex upon the surface of thelayer 14 of Si1-xGex in the PFET region. It should be noted that thelayer 18 of Si1-xGex could be grown prior to growing the layer of 16 of Si. In thelayer 18 the value of x is greater than the value of x in thelayer 14 of Si1-xGex. For example, if the value of x in thelayer 14 of Si1-xGex is in the range of about 0.15 to about 0.40 then the value of x in thelayer 18 of Si1-xGex can be in a range of about 0.40 to about 0.70. The thickness of thelayer 18 is preferably equal to or substantially equal to the thickness of thelayer 16. - A
trench 20 is formed to physically and electrically isolate the NFET region from PFET region. Thetrench 20 preferably extends downwards at least to the top surface of theBOX 12. Thetrench 20 can be formed by partially masking the 16 and 18 and then etching the exposed semiconductor material. Thelayers trench 20 can be considered to partition thelayer 14 of Si1-xGex into a first Sii-xGexsub-layer 14A that is disposed in the NFET region and into a second Si1-xGex sub-layer 14B that is disposed in the PFET region. -
FIG. 3 shows a result of deposition of acapping layer 22, e.g., one composed of an oxide or a nitride, that fills thetrench 20, as well as the performance of a thermal anneal process (e.g., one conducted at an exemplary temperature of about 1000° C.) to mix the Si and the Ge. The anneal converts the first Si1-xGexsub-layer 14A and theoverlying Si layer 16 into a first Si1-xGex intermixedlayer 16A and simultaneously converts the second Si1-xGex sub-layer 14B and theoverlying layer 18 of Si1-xGex into a second Si1-xGex intermixedlayer 18A. In the NFET region the final Ge percentage of the first Si1-xGex intermixedlayer 16A is less than the original Ge percentage of therelaxed layer 14 of Si1-xGex due to the dilution resulting from the presence of theSi layer 16. For example, and assuming the various layer thicknesses and Ge concentrations noted above, the Ge concentration in the first Si1-xGex intermixedlayer 16A could be about 0.05%. Due to the resulting difference in the lattice between the first Si1-xGex intermixedlayer 16A and theSi substrate 10 the first Si1-xGex intermixedlayer 16A is tensile strained. In the PFET region the final Ge percentage of the second Si1-xGex intermixedlayer 18A is greater than the original Ge percentage of therelaxed layer 14 of Si1-xGex due to the Ge enhancement resulting from the presence of theSiGe layer 18 that has the greater Ge percentage than the underlying second Si1-xGex sub-layer 14B. Due to the resulting difference in the lattice between the second Si1-xGex intermixedlayer 18A and theSi substrate 10 the second Si1-xGex intermixedlayer 18A is compressively strained. -
FIG. 4 shows the structure ofFIG. 3 after photolithographically defining fins and etching the first Si1-xGex intermixedlayer 16A and the second Si1-xGex intermixedlayer 18A to form anNFET fin 24A and aPFET fin 24B. Thecapping layer 22 can first be removed and fin patterning masks applied or it can be patterned and selectively removed to leave portions where 24A and 24B are desired. Thefins NFET fin 24A is tensile strained and thePFET fin 24B is compressively strained. The height of the 24A, 24B is comparable to the sum of the thicknesses of thefins layer 14 of Si1-xGex (e.g., about 4 nm) and the thicknesses of theSi layer 16 and the Si1-xGex layer 18 (e.g., 40 nm). If desired, and by example, the thicknesses of the first Si1-xGex intermixedlayer 16A and the second Si1-xGex intermixedlayer 18A can be adjusted prior to fin patterning to obtain a desired fin height for the 24A and 24B. Thefins 24A and 24B can have a width governed by the width of the fin patterning mask, e.g., about 7 nm to about 14 nm (or greater). The fin length can have any desired value depending on the end use. Processing of thefins 24A and 24B can then continue in a conventional manner to form source/drains (S/Ds), gate structures, dielectric layer deposition(s) and vertical and horizontal metallization as needed for the final circuitry.fins -
FIG. 5 illustrates an alternate embodiment where planar CMOS transistors are formed instead of the FinFET CMOS transistors shown inFIG. 4 . In this embodiment the first Si1-xGex intermixedlayer 16A and the second Si1-xGex intermixedlayer 18A are processed to fabricate aplanar NFET 26A and aplanar PFET 26B by forming source (S), channel (C) and drain (D) regions adjacent to the top surfaces. For example, the surfaces can be implanted with suitable S/D dopants followed by other conventional processes to form S/D contacts, gate stack structures and contacts, dielectric layer deposition(s) and vertical and horizontal metallization as needed for the final circuitry. In some embodiments the S/Ds could be raised S/Ds. ASTI 28 can be formed (if the capping layer material that fills thetrench 20 is not retained) to electrically isolate theplanar NFET device 26A from theplanar PFET device 26B. In this embodiment the channel of theplanar NFET 26A is tensily strained and the channel of theplanar PFET 26B is compressively strained. It can be noted that in some embodiments both the FinFET device structures ofFIG. 4 and the planar device structures ofFIG. 5 can be formed on thesame Si substrate 10. - In view of the foregoing description of the exemplary embodiments of this invention it can be realized that a semiconductor structure can be formed over a substrate to comprise an NFET and a PFET, where both the NFET and the PFET have SiGe channels, where the NFET has a lower Ge % than the PFET, where the NFET SiGe is tensily strained and where the PFET SiGe is compressively strained.
- It is noted that any one of the structures shown in
FIGS. 1-5 could be viewed as an intermediate structure formed during the overall process of providing the semiconductor structure. - It is to be understood that although the exemplary embodiments discussed above with reference to
FIGS. 1-5 can be used on common variants of the FET device including, e.g., FET devices with multi-fingered FIN and/or gate structures and FET devices of varying gate width and length. Moreover, transistor devices can be connected to metalized pads or other devices by conventional ultra-large-scale integration (ULSI) metalization and lithographic techniques. - Integrated circuit dies can be fabricated with various devices such as a field-effect transistors, bipolar transistors, metal-oxide-semiconductor transistors, diodes, resistors, capacitors, inductors, etc. An integrated circuit in accordance with the present invention can be employed in applications, hardware, and/or electronic systems. Suitable hardware and systems in which such integrated circuits can be incorporated include, but are not limited to, personal computers, communication networks, electronic commerce systems, portable communications devices (e.g., cell phones), solid-state media storage devices, functional circuitry, etc. Systems and hardware incorporating such integrated circuits are considered part of this invention. Given the teachings of the invention provided herein, one of ordinary skill in the art will be able to contemplate other implementations and applications of the techniques of the invention.
- The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the singular forms “a”, “an” and “the” are intended to include the plural forms as well, unless the context clearly indicates otherwise. It will be further understood that the terms “comprises” and/or “comprising,” when used in this specification, specify the presence of stated features, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, and/or groups thereof.
- The corresponding structures, materials, acts, and equivalents of all means or step plus function elements in the claims below are intended to include any structure, material, or act for performing the function in combination with other claimed elements as specifically claimed. The description of the present invention has been presented for purposes of illustration and description, but is not intended to be exhaustive or limited to the invention in the form disclosed. Many modifications and variations will be apparent to those of ordinary skill in the art without departing from the scope and spirit of the invention. The embodiment was chosen and described in order to best explain the principles of the invention and the practical application, and to enable others of ordinary skill in the art to understand the invention for various embodiments with various modifications as are suited to the particular use contemplated. As such, various modifications and adaptations may become apparent to those skilled in the relevant arts in view of the foregoing description, when read in conjunction with the accompanying drawings and the appended claims. As but some examples, the use of other similar or equivalent semiconductor fabrication processes, including deposition processes and etching processes may be used by those skilled in the art. Further, the exemplary embodiments are not intended to be limited to only those materials, insulators, Ge concentrations, layer thicknesses and the like that were specifically disclosed above. Any and all such and similar modifications of the teachings of this invention will still fall within the scope of this invention.
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