US20170005188A1 - Internal spacer formation from selective oxidation for fin-first wire-last replacement gate-all-around nanowire fet - Google Patents
Internal spacer formation from selective oxidation for fin-first wire-last replacement gate-all-around nanowire fet Download PDFInfo
- Publication number
- US20170005188A1 US20170005188A1 US14/948,509 US201514948509A US2017005188A1 US 20170005188 A1 US20170005188 A1 US 20170005188A1 US 201514948509 A US201514948509 A US 201514948509A US 2017005188 A1 US2017005188 A1 US 2017005188A1
- Authority
- US
- United States
- Prior art keywords
- fin
- semiconductor
- sacrificial
- fin portions
- gate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/40—FETs having zero-dimensional [0D], one-dimensional [1D] or two-dimensional [2D] charge carrier gas channels
- H10D30/43—FETs having zero-dimensional [0D], one-dimensional [1D] or two-dimensional [2D] charge carrier gas channels having 1D charge carrier gas channels, e.g. quantum wire FETs or transistors having 1D quantum-confined channels
-
- H01L29/775—
-
- H01L29/0649—
-
- H01L29/0676—
-
- H01L29/42392—
-
- H01L29/66439—
-
- H01L29/66545—
-
- H01L29/78642—
-
- H01L29/78654—
-
- H01L29/78696—
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/01—Manufacture or treatment
- H10D30/014—Manufacture or treatment of FETs having zero-dimensional [0D] or one-dimensional [1D] channels, e.g. quantum wire FETs, single-electron transistors [SET] or Coulomb blockade transistors
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/01—Manufacture or treatment
- H10D30/021—Manufacture or treatment of FETs having insulated gates [IGFET]
- H10D30/024—Manufacture or treatment of FETs having insulated gates [IGFET] of fin field-effect transistors [FinFET]
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/60—Insulated-gate field-effect transistors [IGFET]
- H10D30/62—Fin field-effect transistors [FinFET]
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/60—Insulated-gate field-effect transistors [IGFET]
- H10D30/67—Thin-film transistors [TFT]
- H10D30/6728—Vertical TFTs
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/60—Insulated-gate field-effect transistors [IGFET]
- H10D30/67—Thin-film transistors [TFT]
- H10D30/6729—Thin-film transistors [TFT] characterised by the electrodes
- H10D30/673—Thin-film transistors [TFT] characterised by the electrodes characterised by the shapes, relative sizes or dispositions of the gate electrodes
- H10D30/6735—Thin-film transistors [TFT] characterised by the electrodes characterised by the shapes, relative sizes or dispositions of the gate electrodes having gates fully surrounding the channels, e.g. gate-all-around
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/60—Insulated-gate field-effect transistors [IGFET]
- H10D30/67—Thin-film transistors [TFT]
- H10D30/674—Thin-film transistors [TFT] characterised by the active materials
- H10D30/6741—Group IV materials, e.g. germanium or silicon carbide
- H10D30/6743—Silicon
- H10D30/6744—Monocrystalline silicon
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/60—Insulated-gate field-effect transistors [IGFET]
- H10D30/67—Thin-film transistors [TFT]
- H10D30/6757—Thin-film transistors [TFT] characterised by the structure of the channel, e.g. transverse or longitudinal shape or doping profile
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/60—Insulated-gate field-effect transistors [IGFET]
- H10D30/751—Insulated-gate field-effect transistors [IGFET] having composition variations in the channel regions
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D62/00—Semiconductor bodies, or regions thereof, of devices having potential barriers
- H10D62/10—Shapes, relative sizes or dispositions of the regions of the semiconductor bodies; Shapes of the semiconductor bodies
- H10D62/113—Isolations within a component, i.e. internal isolations
- H10D62/115—Dielectric isolations, e.g. air gaps
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D62/00—Semiconductor bodies, or regions thereof, of devices having potential barriers
- H10D62/10—Shapes, relative sizes or dispositions of the regions of the semiconductor bodies; Shapes of the semiconductor bodies
- H10D62/117—Shapes of semiconductor bodies
- H10D62/118—Nanostructure semiconductor bodies
- H10D62/119—Nanowire, nanosheet or nanotube semiconductor bodies
- H10D62/121—Nanowire, nanosheet or nanotube semiconductor bodies oriented parallel to substrates
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D62/00—Semiconductor bodies, or regions thereof, of devices having potential barriers
- H10D62/10—Shapes, relative sizes or dispositions of the regions of the semiconductor bodies; Shapes of the semiconductor bodies
- H10D62/117—Shapes of semiconductor bodies
- H10D62/118—Nanostructure semiconductor bodies
- H10D62/119—Nanowire, nanosheet or nanotube semiconductor bodies
- H10D62/122—Nanowire, nanosheet or nanotube semiconductor bodies oriented at angles to substrates, e.g. perpendicular to substrates
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D64/00—Electrodes of devices having potential barriers
- H10D64/01—Manufacture or treatment
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D64/00—Electrodes of devices having potential barriers
- H10D64/01—Manufacture or treatment
- H10D64/017—Manufacture or treatment using dummy gates in processes wherein at least parts of the final gates are self-aligned to the dummy gates, i.e. replacement gate processes
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D64/00—Electrodes of devices having potential barriers
- H10D64/01—Manufacture or treatment
- H10D64/018—Spacers formed inside holes at the prospective gate locations, e.g. holes left by removing dummy gates
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D64/00—Electrodes of devices having potential barriers
- H10D64/60—Electrodes characterised by their materials
- H10D64/66—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes
- H10D64/68—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes characterised by the insulator, e.g. by the gate insulator
- H10D64/691—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes characterised by the insulator, e.g. by the gate insulator comprising metallic compounds, e.g. metal oxides or metal silicates
Definitions
- the present invention relates to semiconductor devices, and more particularly, to nanowire field effect transistor (FET) devices.
- FET field effect transistor
- a field-effect transistor includes a source region, a drain region and a channel between the source and drain regions.
- a gate is formed over the channel and regulates electron flow through the channel between the source and drain regions.
- typical fabrication methods include first forming a semiconductor fin on an upper surface of a substrate, and subsequently etching a bottom portion of the fin to form a void that defines the semiconductor nanowire. In this manner, a gate electrode fills the void and wraps around all sides of the nanowire to form a gate-all-around nanowire FET. However, removal of the bottom portion reduces the overall dimensions of semiconductor material, which in turn decreases the current density provided by the nanowire.
- a semiconductor device includes a first source/drain region, a second source/drain region, and a gate region interposed between the first and second source/drain regions.
- At least one nanowire has a first end anchored to the first source/drain region and an opposing second end anchored to the second source/drain region such that the nanowire is suspended above the wafer in the gate region.
- At least one gate electrode is in the gate region. The gate electrode contacts an entire surface of the nanowire to define a gate-all-around configuration.
- At least one pair of oxidized spacers surrounds the at least one gate electrode to electrically isolate the at least one gate electrode from the first and second source/drain regions.
- a method of fabricating a nanowire field-effect transistor (FET) device comprises forming at least one stacked multi-semiconductor layer fin on an upper surface of a wafer.
- the at least one stacked multi-semiconductor layer fin including at least one semiconductor fin portion interposed between an opposing pair of sacrificial fin portions.
- the method further includes forming at least one dummy gate stack including a dummy gate on an upper surface of the at least one stacked multi-semiconductor layer fin.
- the method further includes etching the stacked multi-semiconductor layer fin while using the at least one dummy gate stack as a mask to preserve an underlying semiconductor fin portion and an underlying sacrificial fin portion.
- the method further includes forming oxidized spacers on sidewalls of the underlying sacrificial fin portions beneath the dummy gate.
- the method further includes removing the dummy gate to form trenches that expose the sacrificial fin portions and selectively etching the exposed sacrificial fin portions with respect to the oxidized spacers to form voids that define at least one nanowire of a nanowire FET device.
- FIGS. 1-11B are a series of cross-sectional diagrams illustrating a process flow of fabricating a nanowire FET device according to a non-limiting embodiment, in which:
- FIG. 1 is a first orientation of a starting semiconductor-on-insulator (SOI) wafer including a buried oxide (BOX) layer interposed between a bulk layer and an active SOI stack layer including an alternating series of sacrificial layers and active semiconductor layers;
- SOI semiconductor-on-insulator
- BOX buried oxide
- FIG. 2A illustrates the SOI wafer of FIG. 1 following a fin patterning process to pattern the active SOI layer and form stacked multi-semiconductor layer fins including an alternating series of sacrificial fin portions and active fin portions;
- FIG. 2B illustrates the SOI wafer of FIG. 2A in a second orientation
- FIG. 3A illustrates the SOI wafer of FIGS. 2A-2B in the first orientation following formation of dummy gates that surrounding the fins;
- FIG. 3B illustrates the SOI wafer of FIG. 3A in the second orientation
- FIG. 3C illustrates the SOI wafer of FIGS. 3A-3B in a third orientation
- FIG. 4A illustrates the SOI wafer of FIGS. 3A-3C in the first orientation after forming gate spacers on opposing sides of the dummy gates;
- FIG. 4B illustrates the SOI wafer of FIG. 4A in the third orientation
- FIG. 5A illustrates the SOI wafer of FIGS. 4A-4B following a selective reactive ion etch (RIE) process to remove sacrificial S/D regions from the fins and expose the underlying BOX layer while maintaining the sacrificial fin portions and the active fin portions located beneath the gate hardmasks and the gate spacers;
- RIE reactive ion etch
- FIG. 5B illustrates the SOI wafer of FIG. 5A in the third orientation
- FIG. 6A illustrates the SOI wafer of FIGS. 5A-5B in the first orientation following a selective oxidation process to form oxidized spacers on sidewalls of the sacrificial fin portions;
- FIG. 6B illustrates the SOI wafer of FIG. 6B in the third orientation
- FIG. 7A illustrates the SOI wafer of FIGS. 6A-6B in the first orientation after an epitaxial growth process is performed to form replacement S/D regions at locations previously occupied by the sacrificial S/D regions;
- FIG. 7B illustrates the SOI wafer of FIG. 7A in the third orientation
- FIG. 8A illustrates the SOI wafer of FIGS. 7A-7B in the first orientation after depositing an interlayer dielectric (ILD) material to fill the spaces between the fins and between the dummy gates;
- ILD interlayer dielectric
- FIG. 8B illustrates the SOI wafer of FIG. 8A in the third orientation
- FIG. 9A illustrates the SOI wafer of FIGS. 8A-8B in the first orientation after selectively removing the dummy gates to form trenches in the ILD material which define a nanowire channel region between the replacement S/D regions;
- FIG. 9B illustrates the SOI wafer of FIG. 9B in the third orientation
- FIG. 10A illustrates the SOI wafer of FIGS. 9A-9B in the first orientation after performing a selective etching process that removes the sacrificial fin portions and stops at the oxidized spacers to define suspended nanowires that are anchored to the replacement S/D regions;
- FIG. 10B illustrates the SOI wafer of FIG. 10A in the third orientation
- FIG. 11A illustrates the SOI wafer of FIGS. 10A-10B after forming replacement gates in the trenches surrounding the suspended nanowires
- FIG. 11B illustrates the SOI wafer of FIG. 11A in the third orientation.
- various embodiments provide gate-all-around nanowire field effect transistors (FETs) including oxidized spacers surrounding a respective metal gate electrode.
- the oxidized spacers are precisely located to isolate the metal gate electrode from respective source/drain regions of the nanowire FET.
- a method is provided that includes forming one or more stacked multi-layer semiconductor fins comprising a series of semiconductor fin portions and sacrificial fin portions. A selective oxidation process is then performed that forms oxidized spacers on sidewalls of the sacrificial fin portions. A replacement metal gate process is subsequently performed that forms a replacement metal gate resulting in a nanowire FET having source/drain regions that are self-aligned with the metal gate electrode.
- a starting wafer 100 extends along a first axis (X-axis) to define a length and a second axis (Z-axis) perpendicular the first axis to define a height (i.e., vertical thickness).
- the wafer 100 also extends along a third axis (e.g., Y-axis) to define a width.
- the starting wafer 100 is constructed as a semiconductor-on-insulator (SOI) wafer 100 .
- the SOI wafer 100 includes a buried oxide (BOX) layer 102 interposed between a bulk layer 104 and a SOI layer 106 .
- the bulk layer 104 is formed from, for example, silicon (Si)
- the BOX layer 102 is formed from, for example, silicon oxide (SiO 2 ).
- the BOX layer 102 has vertical thickness ranging from approximately 25 nanometers (nm) to approximately 500 nm.
- the SOI layer 106 is formed as a stack including an alternating series of sacrificial layers 108 and active semiconductor layers 110 on the bulk layer 104 . Although four layers are illustrated, it should be appreciated that the SOI stack 106 can include any number (n) of layers.
- a first sacrificial layer 108 is formed directly on an upper surface of the BOX layer 102
- a first active semiconductor layer 110 is formed on an upper surface of the first sacrificial layer 108 .
- the sacrificial layers 108 have a vertical thickness ranging, for example, from approximately 3 nm to approximately 20 nm.
- the active semiconductor layers 110 have a vertical thickness ranging, for example, from approximately 3 nm to approximately 20 nm.
- the sacrificial layers 108 are formed of a first semiconductor material and the active semiconductor layers 110 are formed of a second semiconductor material different from the first semiconductor material.
- the sacrificial layers 108 are formed from silicon germanium (SiGe), while the active semiconductor layers 110 are formed from silicon (Si).
- the sacrificial layers 108 are formed from Si, while the active semiconductor layers 110 are formed from SiGe.
- a SiGe layer is first epitaxially grown on an upper surface of an initial SOI layer (not shown). Thereafter, the SiGe layer is condensed using a thermal oxidation process, for example, that results in the Si in the SiGe layer being consumed (by the oxidation process) while the Ge is driven down into the initial SOI layer (not shown).
- a thermal oxidation process for example, that results in the Si in the SiGe layer being consumed (by the oxidation process) while the Ge is driven down into the initial SOI layer (not shown).
- the thermal oxidation process includes, for example, exposing the initial SiGe layer to a temperature of from about 900° Celsius (C.) to about 1,200° C., e.g., about 1,100° C. for a duration from about 5 minutes to about 15 minutes, in L 2 .
- a single initial SiGe layer 108 is formed on an upper surface of the BOX layer 102 as illustrated in FIG. 1 .
- a first active semiconductor layer 110 is epitaxially grown on an upper surface of the initial SiGe layer 108 .
- additional epitaxial growth processes can be performed to form the SOI layer 106 as a stack including an alternating series of sacrificial layers 108 and active semiconductor layers 110 as further illustrated in FIG. 1 .
- the alternating series of sacrificial layers 108 and active semiconductor layers 110 can be either relaxed or strained. For example, if grown to a certain thickness or with a low Ge concentration, the layers 108 / 110 will be relaxed due to dislocation defects. However, increasing the concentration of Ge, for example, may strain the alternating series of sacrificial layers 108 and active semiconductor layers 110 .
- the starting wafer 100 is illustrated following a fin patterning process to pattern one or more stacked multi-semiconductor layer fins 112 on an upper surface of the BOX layer 102 .
- the stacked multi-semiconductor layer fins 112 include at one or more active semiconductor fin portions 110 (i.e., active fin portions 110 ) interposed between an opposing pair of sacrificial fin portions 108 .
- a standard sidewall image transfer (SIT) process utilizing a patterned fin hardmask (not shown) formed on an upper surface of the upper-most active semiconductor layer 110 can be performed to form the stacked multi-semiconductor layer fins 112 as understood by one of ordinary skill in the art.
- SIT sidewall image transfer
- three stacked multi-semiconductor layer fins 112 are shown, it should be appreciated that more or less stacked multi-semiconductor layer fins 112 can be formed.
- fin hardmasks can be configured to have a pitch, i.e., a spatial frequency, of less than about 200 nm, for example, from about 10 nm to about 200 nm, with a preferred range of about 40 nm to about 50 nm, for example.
- the pitch should be as small as possible within patterning and processing limits.
- a pitch doubling technique such as a double patterning/double etching process, for example, can be used.
- a width of each fin hardmask can rage, for example, from about 5 nm to about 40 nm.
- the pitch/width of each fin hardmask determines a pitch/width of each nanowire (not shown in FIGS. 2A-2B .
- the resulting fins 112 are formed with a pitch, i.e., a spatial frequency, from about 10 nm to about 200 nm, e.g., with a preferred range of about 40 nm to about 50 nm, for example, and a width of less than about 40 nm, with a preferred range from about 5 nm to about 10 nm, for example.
- a pitch i.e., a spatial frequency
- the sacrificial fin portion 108 (e.g., the SiGe layer 108 ) may be thinner than the active fin portion 110 (e.g., the Si layer 110 ) following the fin etch. This is the result of the sacrificial fin layer 108 being etched laterally during the fin etch process. It should be appreciated, however, that other etching processes may allow the sacrificial fin portion 108 to be flush or approximately flush with the active fin portion 110 following the fin etch.
- one or more dummy gates 114 are formed surrounding the fins 112 .
- the dummy gates 114 are formed using various masking and etching process understood by one of ordinary skill in the art.
- a dummy gate material such as poly-silicon, for example, is first blanket deposited onto the wafer 100 using a low-pressure chemical vapor deposition (LPCVD) process to cover the fins 112 .
- LPCVD low-pressure chemical vapor deposition
- an oxide layer may be formed on the exposed surfaces of the fins 112 .
- the oxide layer may be formed on the fins 112 using thermal oxidation, for example, and may have a thickness ranging, for example, from about 2 nm to about 4 nm.
- the oxide layer is formed to provide an etch stop layer for the dummy gate removal process as understood by one of ordinary skill in the art.
- sacrificial source/drain (S/D) regions 116 of the fins 112 are defined on opposing sides of the dummy gates 114 as further illustrated in FIGS. 3B-3C .
- Gate hardmasks 115 are then formed on an upper surface of the dummy gate material as further illustrated in FIGS. 3A-3C .
- the gate hardmasks 115 are formed from a nitride material such as, for example, silicon nitride (SiN).
- a nitride material such as, for example, silicon nitride (SiN).
- SiN silicon nitride
- the gate hardmasks 115 can be formed by first blanket depositing a hardmask material (not shown) such as SiN, for example, onto the dummy gate material using, for example, chemical vapor deposition (CVD) or plasma etched chemical vapor deposition (PECVD), and then performing a gate patterning process.
- CVD chemical vapor deposition
- PECVD plasma etched chemical vapor deposition
- the patterning of the hardmask material corresponds to a desired location of the gates of the device.
- a resist film (not shown) is deposited on the hardmask material and patterned with the footprint and location of each of the gate hardmasks.
- RIE is used to form the gate hardmasks 115 , and therefore the resist film comprises a resist material combined with an electro-beam (e-beam) lithography process.
- the gate hardmasks 115 are used to pattern the dummy gate material into a plurality of individual dummy gates 114 as further illustrated in FIGS. 3A-3C .
- the dummy gates 114 can be patterned using a poly-silicon selective RIE around the gate hardmasks 115 as understood by one of ordinary skill in the art.
- gate spacers 118 are then formed on opposite sides of the dummy gates 114 .
- the gate spacers 118 are formed by first depositing a block nitride layer (not shown) onto the wafer 100 to cover the fins 112 .
- a resist film (not shown) is then deposited on the block nitride layer.
- the resist film is subsequently masked and patterned with a location and footprint of the gate spacers 118 as understood by one of ordinary skill in the art.
- a nitride-selective RIE for example, is then used to transfer the patterned footprint into the nitride layer to form the gate spacers 118 .
- a chlorine-based RIE process can be used to remove the sacrificial S/D regions 116 .
- the sacrificial S/D regions 116 are removed from the fins 112 .
- a RIE process selective to semiconductor material e.g., Si and SiGe
- the dummy gate stack e.g., the gate hardmasks 115 and gate spacers 118 formed on the dummy gate 114
- the dummy gate stack serve as a mask to preserve the underlying sacrificial fin portions 108 and the underlying active fin portions 110 .
- the upper surface of the wafer e.g., BOX layer 102
- the portion of the fins 112 e.g., the sacrificial fin portions and the active semiconductor portions located beneath the gate hardmasks 115 and the gate spacers 118 is preserved.
- removal of the sacrificial S/D regions 116 allows access to the sidewalls of the underlying sacrificial fin portions 108 and the underlying active fin portions 110 .
- the wafer 100 is illustrated after performing a selective oxidation process to form oxidized spacers 120 on sidewalls of the sacrificial fin portions.
- the oxide spacers 120 may serve as a stopping layer when etching away the sacrificial fin portions from the fins 112 to release the nanowires (not shown in FIGS. 6A-6B ) as discussed in greater detail below. That is, the direction of the etch used to remove the sacrificial fin portions is contained beneath the active semiconductor portions and is stopped from extending laterally beyond the oxide spacers 120 .
- the selective oxidation process to form the oxide spacers 120 may include, for example, a selective wet oxidation or selective dry oxidation. If a selective wet oxidation process is desired, a high-pressure steam oxidation process can be performed.
- the high-pressure steam oxidation includes performing the oxidation above an atmospheric pressure in a combined H 2 O/N-based environment at relatively low temperatures ranging, for example, from 500 degrees Celsius (° C.) to 700° C.
- a selective dry oxidation process is desired, a oxidation can be performed at atmospheric pressure, e.g., approximately 10,1325 pascals (Pa) (e.g., in an O 2 or O 2 /N 2 based environment at temperatures ranging, for example, from approximately 600° C. to approximately 800° C.
- the selective oxidation process can be time-based such that oxide spacers 120 having a desired thickness can be achieved.
- the thickness of the oxide spacers 120 can range, for example, from approximately 5 nm to approximately 7 nm. Additional etching processes can be performed to remove excess oxidation material from sidewalls of the active semiconductor portion (e.g., the Si portion). Accordingly, the oxide spacers 120 are formed having a thickness that is equal, or approximately equal, to a thickness of the gate spacers 120 , e.g., approximately 5 nm.
- an epitaxial growth process is performed to form replacement S/D regions 122 at locations previously occupied by the sacrificial S/D regions 116 .
- the replacement S/D regions 122 are grown from sidewalls of the active semiconductor portions (e.g., the Si portions) of the remaining fins 112 .
- the epitaxial material grows laterally until merging together, thereby forming the raised replacement S/D regions 122 having gate channel regions (i.e., the active semiconductor portions) formed therebetween as shown in FIGS. 7A-7B .
- the replacement S/D regions 122 are an in-situ doped epitaxially grown semiconductor material.
- the replacement source/drain regions comprise, for example, silicon (Si) doped with phosphorous (P).
- the replacement source/drain regions 122 comprise, for example, silicon germanium (SiGe) doped with boron (B).
- the epitaxy process used to form the replacement source and drain regions 122 may be carried out using vapor phase epitaxy (VPE), molecular beam epitaxy (MBE) or liquid phase epitaxy (LPE) with a gaseous or liquid precursor, such as, for example, silicon tetrachloride.
- an interlayer dielectric (ILD) material 124 is deposited onto the wafer 100 , filling the spaces between the fins 112 and between the dummy gates 114 .
- the ILD material 124 may include any suitable dielectric material such as, for example, silicon dioxide (SiO 2 ).
- the ILD material 124 is deposited using a high-density plasma (HDP).
- a chemical mechanical planarization (CMP) process is then used to planarize the ILD material 124 .
- the dummy gates 114 may be used as an etch stop such that any remaining gate hardmasks 115 are removed, and the upper surface of the ILD material 124 is flush with the upper surface of the dummy gates 114 as further illustrated in FIGS. 8A-8B .
- the dummy gates 114 are then removed following an etching process that is selective to the gate spacers 120 and the ILD material 124 .
- the dummy gates 114 are removed using a chemical etching process such as, for example, potassium hydroxide (KOH) etching, or RIE. Accordingly, removal of the dummy gates 114 results in a respective trench 126 being formed in the ILD material 124 .
- each trench 126 defines a nanowire channel region 128 between the replacement S/D regions 122 .
- the nanowire channels 128 have to be released from the fins 112 .
- the sacrificial fin portion 108 is removed from the fin 112 , resulting in a suspended nanowire (not shown in FIGS. 9A-9B ).
- a suspended nanowire not shown in FIGS. 9A-9B .
- multiple layers of suspended nanowire channels would be formed in this step. These multiple layers of nanowire channels are commonly referred to as a nanowire “mesh.”
- the sacrificial fin portions are removed from the fins 112 to define suspended nanowires 128 that are anchored to the replacement S/D regions 122 . More specifically, a chemical etchant can be employed that exploits the lower oxidation potential of the sacrificial fin portions (e.g., the SiGe fin portions) compared to the active semiconductor fin portions (e.g., the Si fin portions).
- etchants include, but are not limited to, a 1:2:3 mixture of HF:hydrogen peroxide (H 2 O 2 ):acetic acid (CH 3 COOH), or a mixture of sulfuric acid (H 2 SO 4 ) and H 2 O 2 .
- the sacrificial fin portions can be selectively removed using a dry etching process such as oxygen (O 2 ) plasma etching or plasma chemistries typically used for etching.
- O 2 oxygen
- the oxidized spacers 120 prevent the nanowire release from extending laterally into the replacement S/D regions 122 . Accordingly, the sacrificial fin portions are removed while the replacement S/D regions 122 are preserved.
- replacement gates 130 are subsequently formed in the trenches 126 surrounding the suspended nanowires 128 .
- the replacement gates 130 are formed by first lining the trenches 126 and suspended nanowires 128 with a gate dielectric film 132 .
- the gate dielectric film 132 is a high-k material, such as hafnium oxide (HfO 2 ) that is deposited using a conformal deposition process such as atomic layer deposition (ALD). In this manner, the oxide spacers 120 are interposed between the replacement source/drain regions 116 and the gate dielectric film 132 .
- the trenches 126 are filled with a gate material 130 that completely surrounds the suspended nanowires 128 .
- a CMP process is used to planarize the gate material deposited on the upper surface of the ILD material 124 and form replacement gate electrodes 130 , i.e., the replacement gates 130 .
- the oxidized spacers 120 serve to electrically isolate the replacement gate 130 from the replacement source/drain regions 116 .
- Suitable gate materials include, but are not limited to, one or more of polysilicon, a deposited metal(s), (such as titanium nitride (TiN)), and a hybrid stack of multiple materials such as metal polysilicon. Accordingly, at least one non-limiting embodiment provides a nanowire FET device including a plurality of nanotubes in a stacked arrangement to define a nanotube mesh that provides overall increased channel material compared to conventional nanowire FET devices. In this manner, the nanowire FET according to at least one embodiment of the invention provides increased current density compared to conventional nanowire FET devices.
- various embodiments of the invention provide a gate-all-around nanowire field effect transistors (FETs) including oxidized spacers surrounding a respective metal gate electrode.
- FETs gate-all-around nanowire field effect transistors
- the oxidized spacers are precisely located to protect replacement source/drain regions when releasing the nanowires during fabrication, while also serving to isolate the metal gate electrode from respective replacement source/drain regions.
- a method is provided that includes forming one or more stacked multi-layer semiconductor fins comprising a series of semiconductor fin portions and sacrificial fin portions. A selective oxidation process is then performed that forms oxidized spacers on sidewalls of the sacrificial fin portions.
- a replacement metal gate process is subsequently performed that forms a replacement metal gate process results in an nanowire FET having source/drain regions that are self-aligned with the metal gate electrode. Accordingly, a nanowire FET device is formed including a stacked nanotube mesh to provide overall increased channel material compared to conventional nanowire FET devices. In this manner, the nanowire FET according to at least one embodiment of the invention provides increased current density compared to conventional nanowire FET devices. Further, the internal oxidized spacer reduces parasitic capacitance, which will improve the power/performance of circuits built with these transistors compared to those without the internal spacer.
Landscapes
- Thin Film Transistor (AREA)
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
Abstract
A semiconductor device includes a first source/drain region a second source/drain region, and a gate region interposed between the first and second source/drain regions. At least one nanowire has a first end anchored to the first source/drain region and an opposing second end anchored to the second source/drain region such that the nanowire is suspended above the wafer in the gate region. At least one gate electrode is in the gate region. The gate electrode contacts an entire surface of the nanowire to define a gate-all-around configuration. At least one pair of oxidized spacers surrounds the at least one gate electrode to electrically isolate the at least one gate electrode from the first and second source/drain regions.
Description
- This application is a continuation of U.S. patent application Ser. No. 14/754,751, filed Jun. 30, 2015, the disclosure of which is incorporated by reference herein in its entirety.
- The present invention relates to semiconductor devices, and more particularly, to nanowire field effect transistor (FET) devices.
- A field-effect transistor (FET) includes a source region, a drain region and a channel between the source and drain regions. A gate is formed over the channel and regulates electron flow through the channel between the source and drain regions. Recent trends to reduce the size of FET devices have led to the development of gate-all-around nanowire channel field effect transistors (e.g., nanowire FETs). Nanowire FETs are expected to enable density scaling beyond current planar CMOS technology due to their superior electrostatic characteristics. There are, however, notable challenges related to fabricating gate-all-around nanowire FETs, especially at scaled dimensions. For instance, to increase layout density, the nanowires are placed close together and/or are stacked. Consequently, forming a gate surrounding the nanowires in this case is challenging.
- When forming a nanowire FET, typical fabrication methods include first forming a semiconductor fin on an upper surface of a substrate, and subsequently etching a bottom portion of the fin to form a void that defines the semiconductor nanowire. In this manner, a gate electrode fills the void and wraps around all sides of the nanowire to form a gate-all-around nanowire FET. However, removal of the bottom portion reduces the overall dimensions of semiconductor material, which in turn decreases the current density provided by the nanowire.
- According to at least one non-limiting embodiment of the present invention, a semiconductor device includes a first source/drain region, a second source/drain region, and a gate region interposed between the first and second source/drain regions. At least one nanowire has a first end anchored to the first source/drain region and an opposing second end anchored to the second source/drain region such that the nanowire is suspended above the wafer in the gate region. At least one gate electrode is in the gate region. The gate electrode contacts an entire surface of the nanowire to define a gate-all-around configuration. At least one pair of oxidized spacers surrounds the at least one gate electrode to electrically isolate the at least one gate electrode from the first and second source/drain regions.
- According to another non-limiting embodiment, a method of fabricating a nanowire field-effect transistor (FET) device comprises forming at least one stacked multi-semiconductor layer fin on an upper surface of a wafer. The at least one stacked multi-semiconductor layer fin including at least one semiconductor fin portion interposed between an opposing pair of sacrificial fin portions. The method further includes forming at least one dummy gate stack including a dummy gate on an upper surface of the at least one stacked multi-semiconductor layer fin. The method further includes etching the stacked multi-semiconductor layer fin while using the at least one dummy gate stack as a mask to preserve an underlying semiconductor fin portion and an underlying sacrificial fin portion. The method further includes forming oxidized spacers on sidewalls of the underlying sacrificial fin portions beneath the dummy gate. The method further includes removing the dummy gate to form trenches that expose the sacrificial fin portions and selectively etching the exposed sacrificial fin portions with respect to the oxidized spacers to form voids that define at least one nanowire of a nanowire FET device.
- Additional features are realized through the techniques of the present invention. Other embodiments are described in detail herein and are considered a part of the claimed invention. For a better understanding of the invention with the features, refer to the description and to the drawings.
- The subject matter which is regarded as the invention is particularly pointed out and distinctly claimed in the claims at the conclusion of the specification. The forgoing features are apparent from the following detailed description taken in conjunction with the accompanying drawings.
-
FIGS. 1-11B are a series of cross-sectional diagrams illustrating a process flow of fabricating a nanowire FET device according to a non-limiting embodiment, in which: -
FIG. 1 is a first orientation of a starting semiconductor-on-insulator (SOI) wafer including a buried oxide (BOX) layer interposed between a bulk layer and an active SOI stack layer including an alternating series of sacrificial layers and active semiconductor layers; -
FIG. 2A illustrates the SOI wafer ofFIG. 1 following a fin patterning process to pattern the active SOI layer and form stacked multi-semiconductor layer fins including an alternating series of sacrificial fin portions and active fin portions; -
FIG. 2B illustrates the SOI wafer ofFIG. 2A in a second orientation; -
FIG. 3A illustrates the SOI wafer ofFIGS. 2A-2B in the first orientation following formation of dummy gates that surrounding the fins; -
FIG. 3B illustrates the SOI wafer ofFIG. 3A in the second orientation; -
FIG. 3C illustrates the SOI wafer ofFIGS. 3A-3B in a third orientation; -
FIG. 4A illustrates the SOI wafer ofFIGS. 3A-3C in the first orientation after forming gate spacers on opposing sides of the dummy gates; -
FIG. 4B illustrates the SOI wafer ofFIG. 4A in the third orientation; -
FIG. 5A illustrates the SOI wafer ofFIGS. 4A-4B following a selective reactive ion etch (RIE) process to remove sacrificial S/D regions from the fins and expose the underlying BOX layer while maintaining the sacrificial fin portions and the active fin portions located beneath the gate hardmasks and the gate spacers; -
FIG. 5B illustrates the SOI wafer ofFIG. 5A in the third orientation; -
FIG. 6A illustrates the SOI wafer ofFIGS. 5A-5B in the first orientation following a selective oxidation process to form oxidized spacers on sidewalls of the sacrificial fin portions; -
FIG. 6B illustrates the SOI wafer ofFIG. 6B in the third orientation; -
FIG. 7A illustrates the SOI wafer ofFIGS. 6A-6B in the first orientation after an epitaxial growth process is performed to form replacement S/D regions at locations previously occupied by the sacrificial S/D regions; -
FIG. 7B illustrates the SOI wafer ofFIG. 7A in the third orientation; -
FIG. 8A illustrates the SOI wafer ofFIGS. 7A-7B in the first orientation after depositing an interlayer dielectric (ILD) material to fill the spaces between the fins and between the dummy gates; -
FIG. 8B illustrates the SOI wafer ofFIG. 8A in the third orientation; -
FIG. 9A illustrates the SOI wafer ofFIGS. 8A-8B in the first orientation after selectively removing the dummy gates to form trenches in the ILD material which define a nanowire channel region between the replacement S/D regions; -
FIG. 9B illustrates the SOI wafer ofFIG. 9B in the third orientation; -
FIG. 10A illustrates the SOI wafer ofFIGS. 9A-9B in the first orientation after performing a selective etching process that removes the sacrificial fin portions and stops at the oxidized spacers to define suspended nanowires that are anchored to the replacement S/D regions; -
FIG. 10B illustrates the SOI wafer ofFIG. 10A in the third orientation; -
FIG. 11A illustrates the SOI wafer ofFIGS. 10A-10B after forming replacement gates in the trenches surrounding the suspended nanowires; and -
FIG. 11B illustrates the SOI wafer ofFIG. 11A in the third orientation. - As described herein, various embodiments provide gate-all-around nanowire field effect transistors (FETs) including oxidized spacers surrounding a respective metal gate electrode. The oxidized spacers are precisely located to isolate the metal gate electrode from respective source/drain regions of the nanowire FET. According to an embodiment, a method is provided that includes forming one or more stacked multi-layer semiconductor fins comprising a series of semiconductor fin portions and sacrificial fin portions. A selective oxidation process is then performed that forms oxidized spacers on sidewalls of the sacrificial fin portions. A replacement metal gate process is subsequently performed that forms a replacement metal gate resulting in a nanowire FET having source/drain regions that are self-aligned with the metal gate electrode.
- A non-limiting nanowire FET fabrication process flow is described by way of a reference to
FIGS. 1-11B . As shown inFIG. 1 , a startingwafer 100 extends along a first axis (X-axis) to define a length and a second axis (Z-axis) perpendicular the first axis to define a height (i.e., vertical thickness). Although not illustrated inFIG. 1 , thewafer 100 also extends along a third axis (e.g., Y-axis) to define a width. According to a non-limiting embodiment, the startingwafer 100 is constructed as a semiconductor-on-insulator (SOI)wafer 100. TheSOI wafer 100 includes a buried oxide (BOX)layer 102 interposed between abulk layer 104 and aSOI layer 106. Thebulk layer 104 is formed from, for example, silicon (Si), and theBOX layer 102 is formed from, for example, silicon oxide (SiO2). TheBOX layer 102 has vertical thickness ranging from approximately 25 nanometers (nm) to approximately 500 nm. - The
SOI layer 106 is formed as a stack including an alternating series ofsacrificial layers 108 and active semiconductor layers 110 on thebulk layer 104. Although four layers are illustrated, it should be appreciated that theSOI stack 106 can include any number (n) of layers. In this manner, a firstsacrificial layer 108 is formed directly on an upper surface of theBOX layer 102, and a firstactive semiconductor layer 110 is formed on an upper surface of the firstsacrificial layer 108. Thesacrificial layers 108 have a vertical thickness ranging, for example, from approximately 3 nm to approximately 20 nm. Theactive semiconductor layers 110 have a vertical thickness ranging, for example, from approximately 3 nm to approximately 20 nm. - The
sacrificial layers 108 are formed of a first semiconductor material and theactive semiconductor layers 110 are formed of a second semiconductor material different from the first semiconductor material. For example, thesacrificial layers 108 are formed from silicon germanium (SiGe), while theactive semiconductor layers 110 are formed from silicon (Si). According to another example, thesacrificial layers 108 are formed from Si, while theactive semiconductor layers 110 are formed from SiGe. - Multiple epitaxial growth processes can be performed to form the
sacrificial layers 108 and the active semiconductor layers 110. To achieve a SiGesacrificial layer 108 directly on the upper surface of theBOX layer 102, for example, a SiGe layer is first epitaxially grown on an upper surface of an initial SOI layer (not shown). Thereafter, the SiGe layer is condensed using a thermal oxidation process, for example, that results in the Si in the SiGe layer being consumed (by the oxidation process) while the Ge is driven down into the initial SOI layer (not shown). The thermal oxidation process includes, for example, exposing the initial SiGe layer to a temperature of from about 900° Celsius (C.) to about 1,200° C., e.g., about 1,100° C. for a duration from about 5 minutes to about 15 minutes, in L2. In this manner, a singleinitial SiGe layer 108 is formed on an upper surface of theBOX layer 102 as illustrated inFIG. 1 . Subsequent to forming theinitial SiGe layer 108, a firstactive semiconductor layer 110 is epitaxially grown on an upper surface of theinitial SiGe layer 108. Thereafter, additional epitaxial growth processes can be performed to form theSOI layer 106 as a stack including an alternating series ofsacrificial layers 108 andactive semiconductor layers 110 as further illustrated inFIG. 1 . It should be appreciated that the alternating series ofsacrificial layers 108 andactive semiconductor layers 110 can be either relaxed or strained. For example, if grown to a certain thickness or with a low Ge concentration, thelayers 108/110 will be relaxed due to dislocation defects. However, increasing the concentration of Ge, for example, may strain the alternating series ofsacrificial layers 108 and active semiconductor layers 110. - Turning now to
FIGS. 2A-2B , the startingwafer 100 is illustrated following a fin patterning process to pattern one or more stackedmulti-semiconductor layer fins 112 on an upper surface of theBOX layer 102. The stackedmulti-semiconductor layer fins 112 include at one or more active semiconductor fin portions 110 (i.e., active fin portions 110) interposed between an opposing pair ofsacrificial fin portions 108. A standard sidewall image transfer (SIT) process utilizing a patterned fin hardmask (not shown) formed on an upper surface of the upper-mostactive semiconductor layer 110 can be performed to form the stackedmulti-semiconductor layer fins 112 as understood by one of ordinary skill in the art. Although three stackedmulti-semiconductor layer fins 112 are shown, it should be appreciated that more or less stackedmulti-semiconductor layer fins 112 can be formed. - By way of example only, fin hardmasks (not shown) can be configured to have a pitch, i.e., a spatial frequency, of less than about 200 nm, for example, from about 10 nm to about 200 nm, with a preferred range of about 40 nm to about 50 nm, for example. To maximize layout density and minimize parasitic capacitance, the pitch should be as small as possible within patterning and processing limits. To achieve pitches smaller than what can be defined by direct lithography, a pitch doubling technique such as a double patterning/double etching process, for example, can be used. According to an exemplary embodiment, a width of each fin hardmask can rage, for example, from about 5 nm to about 40 nm. The pitch/width of each fin hardmask determines a pitch/width of each nanowire (not shown in
FIGS. 2A-2B . - Thus, based on the pitch and width of the fin hardmasks, the resulting
fins 112 are formed with a pitch, i.e., a spatial frequency, from about 10 nm to about 200 nm, e.g., with a preferred range of about 40 nm to about 50 nm, for example, and a width of less than about 40 nm, with a preferred range from about 5 nm to about 10 nm, for example. - Further, the sacrificial fin portion 108 (e.g., the SiGe layer 108) may be thinner than the active fin portion 110 (e.g., the Si layer 110) following the fin etch. This is the result of the
sacrificial fin layer 108 being etched laterally during the fin etch process. It should be appreciated, however, that other etching processes may allow thesacrificial fin portion 108 to be flush or approximately flush with theactive fin portion 110 following the fin etch. - Referring now to
FIGS. 3A-3C , one ormore dummy gates 114 are formed surrounding thefins 112. Thedummy gates 114 are formed using various masking and etching process understood by one of ordinary skill in the art. For example, a dummy gate material (not shown) such as poly-silicon, for example, is first blanket deposited onto thewafer 100 using a low-pressure chemical vapor deposition (LPCVD) process to cover thefins 112. Prior to depositing the dummy gate material, an oxide layer may be formed on the exposed surfaces of thefins 112. The oxide layer may be formed on thefins 112 using thermal oxidation, for example, and may have a thickness ranging, for example, from about 2 nm to about 4 nm. The oxide layer is formed to provide an etch stop layer for the dummy gate removal process as understood by one of ordinary skill in the art. According to an embodiment, sacrificial source/drain (S/D)regions 116 of thefins 112 are defined on opposing sides of thedummy gates 114 as further illustrated inFIGS. 3B-3C . -
Gate hardmasks 115 are then formed on an upper surface of the dummy gate material as further illustrated inFIGS. 3A-3C . According to a non-limiting embodiment, thegate hardmasks 115 are formed from a nitride material such as, for example, silicon nitride (SiN). Although not illustrated, it is well-known by one of ordinary skill in the art that thegate hardmasks 115 can be formed by first blanket depositing a hardmask material (not shown) such as SiN, for example, onto the dummy gate material using, for example, chemical vapor deposition (CVD) or plasma etched chemical vapor deposition (PECVD), and then performing a gate patterning process. The patterning of the hardmask material corresponds to a desired location of the gates of the device. As understood by one of ordinary skill in the art, a resist film (not shown) is deposited on the hardmask material and patterned with the footprint and location of each of the gate hardmasks. In one example, RIE is used to form thegate hardmasks 115, and therefore the resist film comprises a resist material combined with an electro-beam (e-beam) lithography process. Next, thegate hardmasks 115 are used to pattern the dummy gate material into a plurality ofindividual dummy gates 114 as further illustrated inFIGS. 3A-3C . Thedummy gates 114 can be patterned using a poly-silicon selective RIE around thegate hardmasks 115 as understood by one of ordinary skill in the art. - Referring now to
FIGS. 4A-4B ,gate spacers 118 are then formed on opposite sides of thedummy gates 114. According to an exemplary embodiment, thegate spacers 118 are formed by first depositing a block nitride layer (not shown) onto thewafer 100 to cover thefins 112. A resist film (not shown) is then deposited on the block nitride layer. The resist film is subsequently masked and patterned with a location and footprint of thegate spacers 118 as understood by one of ordinary skill in the art. A nitride-selective RIE, for example, is then used to transfer the patterned footprint into the nitride layer to form thegate spacers 118. According to a non-limiting embodiment, a chlorine-based RIE process can be used to remove the sacrificial S/D regions 116. - Turning now to
FIGS. 5A-5B , the sacrificial S/D regions 116 are removed from thefins 112. According to an embodiment, a RIE process selective to semiconductor material (e.g., Si and SiGe) is performed to remove the sacrificial S/D regions 116 while the dummy gate stack (e.g., the gate hardmasks 115 andgate spacers 118 formed on the dummy gate 114) serve as a mask to preserve the underlyingsacrificial fin portions 108 and the underlyingactive fin portions 110. In this manner, the upper surface of the wafer (e.g., BOX layer 102) is re-exposed, while the portion of the fins 112 (e.g., the sacrificial fin portions and the active semiconductor portions) located beneath the gate hardmasks 115 and thegate spacers 118 is preserved. Further, removal of the sacrificial S/D regions 116 allows access to the sidewalls of the underlyingsacrificial fin portions 108 and the underlyingactive fin portions 110. - Referring to
FIGS. 6A-6B , thewafer 100 is illustrated after performing a selective oxidation process to form oxidizedspacers 120 on sidewalls of the sacrificial fin portions. Theoxide spacers 120 may serve as a stopping layer when etching away the sacrificial fin portions from thefins 112 to release the nanowires (not shown inFIGS. 6A-6B ) as discussed in greater detail below. That is, the direction of the etch used to remove the sacrificial fin portions is contained beneath the active semiconductor portions and is stopped from extending laterally beyond theoxide spacers 120. - The selective oxidation process to form the
oxide spacers 120 may include, for example, a selective wet oxidation or selective dry oxidation. If a selective wet oxidation process is desired, a high-pressure steam oxidation process can be performed. The high-pressure steam oxidation includes performing the oxidation above an atmospheric pressure in a combined H2O/N-based environment at relatively low temperatures ranging, for example, from 500 degrees Celsius (° C.) to 700° C. If a selective dry oxidation process is desired, a oxidation can be performed at atmospheric pressure, e.g., approximately 10,1325 pascals (Pa) (e.g., in an O2 or O2/N2 based environment at temperatures ranging, for example, from approximately 600° C. to approximately 800° C. - The selective oxidation process can be time-based such that
oxide spacers 120 having a desired thickness can be achieved. The thickness of theoxide spacers 120 can range, for example, from approximately 5 nm to approximately 7 nm. Additional etching processes can be performed to remove excess oxidation material from sidewalls of the active semiconductor portion (e.g., the Si portion). Accordingly, theoxide spacers 120 are formed having a thickness that is equal, or approximately equal, to a thickness of thegate spacers 120, e.g., approximately 5 nm. - Turning now to
FIGS. 7A-7B , an epitaxial growth process is performed to form replacement S/D regions 122 at locations previously occupied by the sacrificial S/D regions 116. The replacement S/D regions 122 are grown from sidewalls of the active semiconductor portions (e.g., the Si portions) of the remainingfins 112. In this manner, the epitaxial material grows laterally until merging together, thereby forming the raised replacement S/D regions 122 having gate channel regions (i.e., the active semiconductor portions) formed therebetween as shown inFIGS. 7A-7B . According to a non-limiting embodiment, the replacement S/D regions 122 are an in-situ doped epitaxially grown semiconductor material. When forming a NFET device, the replacement source/drain regions comprise, for example, silicon (Si) doped with phosphorous (P). When forming a PFET device, the replacement source/drain regions 122 comprise, for example, silicon germanium (SiGe) doped with boron (B). The epitaxy process used to form the replacement source and drainregions 122 may be carried out using vapor phase epitaxy (VPE), molecular beam epitaxy (MBE) or liquid phase epitaxy (LPE) with a gaseous or liquid precursor, such as, for example, silicon tetrachloride. - Referring now to
FIGS. 8A-8B , an interlayer dielectric (ILD)material 124 is deposited onto thewafer 100, filling the spaces between thefins 112 and between thedummy gates 114. TheILD material 124 may include any suitable dielectric material such as, for example, silicon dioxide (SiO2). According to an exemplary embodiment, theILD material 124 is deposited using a high-density plasma (HDP). A chemical mechanical planarization (CMP) process is then used to planarize theILD material 124. Thedummy gates 114 may be used as an etch stop such that any remaininggate hardmasks 115 are removed, and the upper surface of theILD material 124 is flush with the upper surface of thedummy gates 114 as further illustrated inFIGS. 8A-8B . - Referring to
FIGS. 9A-9B , thedummy gates 114 are then removed following an etching process that is selective to thegate spacers 120 and theILD material 124. According to a non-limiting embodiment, thedummy gates 114 are removed using a chemical etching process such as, for example, potassium hydroxide (KOH) etching, or RIE. Accordingly, removal of thedummy gates 114 results in arespective trench 126 being formed in theILD material 124. According to an exemplary embodiment, eachtrench 126 defines ananowire channel region 128 between the replacement S/D regions 122. As mentioned above, in order to form a gate electrode (e.g., a replacement gate described below) that surrounds thenanowire channels 128, thenanowire channels 128 have to be released from thefins 112. Namely, thesacrificial fin portion 108 is removed from thefin 112, resulting in a suspended nanowire (not shown inFIGS. 9A-9B ). In such a case, multiple layers of suspended nanowire channels would be formed in this step. These multiple layers of nanowire channels are commonly referred to as a nanowire “mesh.” - With reference now to
FIGS. 10A-10B , the sacrificial fin portions (previously designated as element 108) are removed from thefins 112 to define suspendednanowires 128 that are anchored to the replacement S/D regions 122. More specifically, a chemical etchant can be employed that exploits the lower oxidation potential of the sacrificial fin portions (e.g., the SiGe fin portions) compared to the active semiconductor fin portions (e.g., the Si fin portions). Examples of such etchants include, but are not limited to, a 1:2:3 mixture of HF:hydrogen peroxide (H2O2):acetic acid (CH3COOH), or a mixture of sulfuric acid (H2SO4) and H2O2. Alternatively, the sacrificial fin portions can be selectively removed using a dry etching process such as oxygen (O2) plasma etching or plasma chemistries typically used for etching. As mentioned above, the oxidizedspacers 120 prevent the nanowire release from extending laterally into the replacement S/D regions 122. Accordingly, the sacrificial fin portions are removed while the replacement S/D regions 122 are preserved. - Turning to
FIGS. 11A-11B ,replacement gates 130 are subsequently formed in thetrenches 126 surrounding the suspendednanowires 128. Thereplacement gates 130 are formed by first lining thetrenches 126 and suspendednanowires 128 with agate dielectric film 132. According to an exemplary embodiment, thegate dielectric film 132 is a high-k material, such as hafnium oxide (HfO2) that is deposited using a conformal deposition process such as atomic layer deposition (ALD). In this manner, theoxide spacers 120 are interposed between the replacement source/drain regions 116 and thegate dielectric film 132. - Next, the
trenches 126 are filled with agate material 130 that completely surrounds the suspendednanowires 128. Once thetrenches 126 are filled with thegate material 130, a CMP process is used to planarize the gate material deposited on the upper surface of theILD material 124 and formreplacement gate electrodes 130, i.e., thereplacement gates 130. In this manner, asemiconductor device 100 having a gate-all-around configuration is formed. Moreover, the oxidizedspacers 120 serve to electrically isolate thereplacement gate 130 from the replacement source/drain regions 116. Suitable gate materials include, but are not limited to, one or more of polysilicon, a deposited metal(s), (such as titanium nitride (TiN)), and a hybrid stack of multiple materials such as metal polysilicon. Accordingly, at least one non-limiting embodiment provides a nanowire FET device including a plurality of nanotubes in a stacked arrangement to define a nanotube mesh that provides overall increased channel material compared to conventional nanowire FET devices. In this manner, the nanowire FET according to at least one embodiment of the invention provides increased current density compared to conventional nanowire FET devices. - As described above, various embodiments of the invention provide a gate-all-around nanowire field effect transistors (FETs) including oxidized spacers surrounding a respective metal gate electrode. The oxidized spacers are precisely located to protect replacement source/drain regions when releasing the nanowires during fabrication, while also serving to isolate the metal gate electrode from respective replacement source/drain regions. According to an embodiment, a method is provided that includes forming one or more stacked multi-layer semiconductor fins comprising a series of semiconductor fin portions and sacrificial fin portions. A selective oxidation process is then performed that forms oxidized spacers on sidewalls of the sacrificial fin portions. A replacement metal gate process is subsequently performed that forms a replacement metal gate process results in an nanowire FET having source/drain regions that are self-aligned with the metal gate electrode. Accordingly, a nanowire FET device is formed including a stacked nanotube mesh to provide overall increased channel material compared to conventional nanowire FET devices. In this manner, the nanowire FET according to at least one embodiment of the invention provides increased current density compared to conventional nanowire FET devices. Further, the internal oxidized spacer reduces parasitic capacitance, which will improve the power/performance of circuits built with these transistors compared to those without the internal spacer.
- The descriptions of the various embodiments of the present invention have been presented for purposes of illustration, but are not intended to be exhaustive or limited to the embodiments disclosed. Many modifications and variations will be apparent to those of ordinary skill in the art without departing from the scope and spirit of the described embodiments. The terminology used herein was chosen to best explain the principles of the embodiments, the practical application or technical improvement over technologies found in the marketplace, or to enable others of ordinary skill in the art to understand the embodiments disclosed herein.
- The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the singular forms “a”, “an” and “the” are intended to include the plural forms as well, unless the context clearly indicates otherwise. It will be further understood that the terms “comprises” and/or “comprising,” when used in this specification, specify the presence of stated features, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one more other features, integers, steps, operations, element components, and/or groups thereof.
- The corresponding structures, materials, acts, and equivalents of all means or step plus function elements in the claims below are intended to include any structure, material, or act for performing the function in combination with other claimed elements as specifically claimed. The description of the present invention has been presented for purposes of illustration and description, but is not intended to be exhaustive or limited to the invention in the form disclosed. Many modifications and variations will be apparent to those of ordinary skill in the art without departing from the scope and spirit of the invention. The embodiment was chosen and described in order to best explain the principles of the inventive teachings and the practical application, and to enable others of ordinary skill in the art to understand the invention for various embodiments with various modifications as are suited to the particular use contemplated.
- The flow diagrams depicted herein are just one example. There may be many variations to this diagram or the operations described therein without departing from the spirit of the invention. For instance, the operations may be performed in a differing order or operations may be added, deleted or modified. All of these variations are considered a part of the claimed invention.
- While various embodiments have been described, it will be understood that those skilled in the art, both now and in the future, may make various modifications which fall within the scope of the claims which follow. These claims should be construed to maintain the proper protection for the invention first described.
Claims (11)
1. A method of fabricating a nanowire field-effect transistor (FET) device, the method comprising:
forming at least one stacked multi-semiconductor layer fin on an upper surface of a wafer, the at least one stacked multi-semiconductor layer fin including at least one semiconductor fin portion interposed between an opposing pair of sacrificial fin portions;
forming at least one dummy gate stack including a dummy gate on an upper surface of the at least one stacked multi-semiconductor layer fin;
etching the stacked multi-semiconductor layer fin while using the at least one dummy gate stack as a mask to preserve an underlying semiconductor fin portion and an underlying sacrificial fin portion;
forming oxidized spacers on sidewalls of the underlying sacrificial fin portions beneath the dummy gate; and
removing the dummy gate to form trenches that expose the sacrificial fin portions and selectively etching the exposed sacrificial fin portions with respect to the oxidized spacers to form voids that define at least one nanowire of a nanowire FET device.
2. The method of claim 1 , further comprising forming replacement source/drain regions on opposing sides of the at least one stacked multi-semiconductor layer fin such that the oxidized spacers are interposed between the underlying sacrificial fin portions and the replacement source/drain regions.
3. The method of claim 2 , further comprising depositing a metal gate material in the voids to surround all surfaces of the at least one nanowire to form a gate-all-around configuration such that the oxidized spacers electrically isolate the metal gate material from the replacement source/drain regions.
4. The method of claim 2 , wherein the at least one semiconductor fin portion includes a plurality of semiconductor fin portions and a plurality of sacrificial fin portions stacked in alternating series arrangement with respect to one another, and
wherein the sacrificial fin portions are selectively removed to form corresponding voids that define a plurality of vertically arranged nanowires that are separated from one another by a respective void.
5. The method of claim 2 , wherein the at least one active fin portion comprises silicon (Si) and the sacrificial fin portions comprises silicon germanium (SiGe).
6. The method of claim 5 , wherein forming the oxidized spacers comprises oxidizing the underlying sacrificial fin portions to form the oxidized spacers comprising silicon germanium oxide (SiGeO).
7. The method of claim 6 , wherein the oxidizing comprises performing a dry oxidation on the underlying sacrificial fin portions to convert the sidewalls of the underlying sacrificial fin portions into the oxidized spacers.
8. The method of claim 6 , wherein the oxidizing comprises performing a wet oxidation on the underlying sacrificial fin portions to convert the sidewalls of the underlying sacrificial fin portions into the oxidized spacers.
9. The method of claim 1 , wherein forming the stacked multi-semiconductor layer fin further comprises:
forming a stack of alternating semiconductor layers and sacrificial layers on a wafer; and
patterning the stack to form the at least one stacked multi-semiconductor layer fin.
10. The method of claim 9 , wherein the wafer is a bulk semiconductor wafer, wherein the at least one stacked multi-semiconductor layer fin is on an upper surface of the bulk semiconductor wafer.
11. The method of claim 9 , wherein the wafer is a semiconductor-on-insulator (SOI) wafer including a buried oxide layer interposed between a SOI layer and a bulk layer, and wherein the at least one stacked multi-semiconductor layer fin is on an upper surface of the buried oxide layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14/948,509 US10170609B2 (en) | 2015-06-30 | 2015-11-23 | Internal spacer formation from selective oxidation for Fin-first wire-last replacement gate-all-around nanowire FET |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14/754,751 US10170608B2 (en) | 2015-06-30 | 2015-06-30 | Internal spacer formation from selective oxidation for fin-first wire-last replacement gate-all-around nanowire FET |
| US14/948,509 US10170609B2 (en) | 2015-06-30 | 2015-11-23 | Internal spacer formation from selective oxidation for Fin-first wire-last replacement gate-all-around nanowire FET |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US14/754,751 Continuation US10170608B2 (en) | 2015-06-30 | 2015-06-30 | Internal spacer formation from selective oxidation for fin-first wire-last replacement gate-all-around nanowire FET |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| US20170005188A1 true US20170005188A1 (en) | 2017-01-05 |
| US10170609B2 US10170609B2 (en) | 2019-01-01 |
Family
ID=57684012
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US14/754,751 Active US10170608B2 (en) | 2015-06-30 | 2015-06-30 | Internal spacer formation from selective oxidation for fin-first wire-last replacement gate-all-around nanowire FET |
| US14/948,509 Active US10170609B2 (en) | 2015-06-30 | 2015-11-23 | Internal spacer formation from selective oxidation for Fin-first wire-last replacement gate-all-around nanowire FET |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US14/754,751 Active US10170608B2 (en) | 2015-06-30 | 2015-06-30 | Internal spacer formation from selective oxidation for fin-first wire-last replacement gate-all-around nanowire FET |
Country Status (1)
| Country | Link |
|---|---|
| US (2) | US10170608B2 (en) |
Cited By (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9887264B2 (en) * | 2015-12-10 | 2018-02-06 | International Business Machines Corporation | Nanowire field effect transistor (FET) and method for fabricating the same |
| US20180090570A1 (en) * | 2015-10-07 | 2018-03-29 | Taiwan Semiconductor Manufacturing Company, Ltd. | Strained Nanowire CMOS Device and Method of Forming |
| US20180138291A1 (en) * | 2016-11-14 | 2018-05-17 | Tokyo Electron Limited | Method of forming gate spacer for nanowire fet device |
| US20180175036A1 (en) * | 2015-11-16 | 2018-06-21 | Taiwan Semiconductor Manufacturing Company, Ltd. | Multi-Gate Device and Method of Fabrication Thereof |
| CN108288584A (en) * | 2017-01-09 | 2018-07-17 | 三星电子株式会社 | The production method of nanometer sheet transistor spacer including interior spacer |
| WO2018195428A1 (en) * | 2017-04-20 | 2018-10-25 | Micromaterials Llc | Selective formation of silicon-containing spacer |
| EP3404701A1 (en) * | 2017-05-15 | 2018-11-21 | IMEC vzw | A method for defining a channel region in a vertical transistor device |
| CN108878293A (en) * | 2017-05-15 | 2018-11-23 | Imec 非营利协会 | The method for being used to form the column in vertical transistor devices |
| US10170485B2 (en) * | 2017-05-24 | 2019-01-01 | International Business Machines Corporation | Three-dimensional stacked junctionless channels for dense SRAM |
| US10367061B1 (en) | 2018-03-30 | 2019-07-30 | International Business Machines Corporation | Replacement metal gate and inner spacer formation in three dimensional structures using sacrificial silicon germanium |
| EP3660922A1 (en) * | 2018-11-27 | 2020-06-03 | IMEC vzw | A method of forming a stack of insulated cmos devices |
| US10818490B2 (en) * | 2017-12-15 | 2020-10-27 | Applied Materials, Inc. | Controlled growth of thin silicon oxide film at low temperature |
| US10818777B2 (en) * | 2017-10-30 | 2020-10-27 | Taiwan Semiconductor Manufacturing Co., Ltd. | Method of manufacturing a semiconductor device and a semiconductor device |
| US10867866B2 (en) * | 2017-10-30 | 2020-12-15 | Taiwan Semiconductor Manufacturing Co., Ltd. | Semiconductor device and manufacturing method thereof |
| US20210066473A1 (en) * | 2019-02-21 | 2021-03-04 | Taiwan Semiconductor Manufacturing Company, Ltd. | Methods of fabricating semiconductor devices having gate-all-around structure with inner spacer last process |
| US10998423B2 (en) * | 2015-09-25 | 2021-05-04 | Intel Corporation | Fabrication of multi-channel nanowire devices with self-aligned internal spacers and SOI FinFETs using selective silicon nitride capping |
| US11018032B2 (en) | 2017-08-18 | 2021-05-25 | Applied Materials, Inc. | High pressure and high temperature anneal chamber |
| CN112993011A (en) * | 2019-12-17 | 2021-06-18 | 台湾积体电路制造股份有限公司 | Semiconductor structure and forming method thereof |
| US11110383B2 (en) | 2018-08-06 | 2021-09-07 | Applied Materials, Inc. | Gas abatement apparatus |
| US11177128B2 (en) * | 2017-09-12 | 2021-11-16 | Applied Materials, Inc. | Apparatus and methods for manufacturing semiconductor structures using protective barrier layer |
| US11227797B2 (en) | 2018-11-16 | 2022-01-18 | Applied Materials, Inc. | Film deposition using enhanced diffusion process |
| US11361978B2 (en) | 2018-07-25 | 2022-06-14 | Applied Materials, Inc. | Gas delivery module |
| US11462417B2 (en) | 2017-08-18 | 2022-10-04 | Applied Materials, Inc. | High pressure and high temperature anneal chamber |
| US20220328653A1 (en) * | 2021-04-07 | 2022-10-13 | Taiwan Semiconductor Manufacturing Company Ltd. | Etch selectivity control for epitaxy process window enlargement in semiconductor devices |
| US11527421B2 (en) | 2017-11-11 | 2022-12-13 | Micromaterials, LLC | Gas delivery system for high pressure processing chamber |
| US11581183B2 (en) | 2018-05-08 | 2023-02-14 | Applied Materials, Inc. | Methods of forming amorphous carbon hard mask layers and hard mask layers formed therefrom |
| US11610773B2 (en) | 2017-11-17 | 2023-03-21 | Applied Materials, Inc. | Condenser system for high pressure processing system |
| US11705337B2 (en) | 2017-05-25 | 2023-07-18 | Applied Materials, Inc. | Tungsten defluorination by high pressure treatment |
| US11749555B2 (en) | 2018-12-07 | 2023-09-05 | Applied Materials, Inc. | Semiconductor processing system |
| US20230299175A1 (en) * | 2022-03-16 | 2023-09-21 | Taiwan Semiconductor Manufacturing Company, Ltd. | Gate spacer and formation method thereof |
| US20230335586A1 (en) * | 2022-04-19 | 2023-10-19 | Taiwan Semiconductor Manufacturing Company, Ltd. | Method and structure for gate-all-around devices |
| US11881411B2 (en) | 2018-03-09 | 2024-01-23 | Applied Materials, Inc. | High pressure annealing process for metal containing materials |
| US11901222B2 (en) | 2020-02-17 | 2024-02-13 | Applied Materials, Inc. | Multi-step process for flowable gap-fill film |
| US12198951B2 (en) | 2017-03-10 | 2025-01-14 | Applied Materials, Inc. | High pressure wafer processing systems and related methods |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10283638B2 (en) * | 2015-08-03 | 2019-05-07 | Samsung Electronics Co., Ltd. | Structure and method to achieve large strain in NS without addition of stack-generated defects |
| US10096673B2 (en) * | 2016-02-17 | 2018-10-09 | International Business Machines Corporation | Nanowire with sacrificial top wire |
| US9653289B1 (en) | 2016-09-19 | 2017-05-16 | International Business Machines Corporation | Fabrication of nano-sheet transistors with different threshold voltages |
| WO2018063403A1 (en) * | 2016-09-30 | 2018-04-05 | Intel Corporation | Art trench spacers to enable fin release for non-lattice matched channels |
| US10756174B2 (en) | 2017-04-26 | 2020-08-25 | Taiwan Semiconductor Manufacturing Co., Ltd. | Multiple-stacked semiconductor nanowires and source/drain spacers |
| TWI769245B (en) * | 2017-04-27 | 2022-07-01 | 日商東京威力科創股份有限公司 | Method for fabricating nfet and pfet nanowire devices |
| KR102353931B1 (en) | 2017-09-13 | 2022-01-21 | 삼성전자주식회사 | Semiconductor device and method for manufacturing the same |
| US10453752B2 (en) * | 2017-09-18 | 2019-10-22 | Taiwan Semiconductor Manufacturing Co., Ltd. | Method of manufacturing a gate-all-around semiconductor device |
| US10424482B2 (en) | 2017-12-19 | 2019-09-24 | International Business Machines Corporation | Methods and structures for forming a tight pitch structure |
| US10559675B2 (en) | 2017-12-21 | 2020-02-11 | International Business Machines Corporation | Stacked silicon nanotubes |
| US10446664B1 (en) | 2018-03-20 | 2019-10-15 | International Business Machines Corporation | Inner spacer formation and contact resistance reduction in nanosheet transistors |
| US20230402529A1 (en) * | 2022-06-13 | 2023-12-14 | Electronics And Telecommunications Research Institute | Semiconductor device and method of manufacturing the same |
| US20240355876A1 (en) * | 2023-04-20 | 2024-10-24 | Intel Corporation | Nanoribbon-based transistor with uniform oxide |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7892945B2 (en) * | 2009-02-17 | 2011-02-22 | International Business Machines Corporation | Nanowire mesh device and method of fabricating same |
| US8753942B2 (en) * | 2010-12-01 | 2014-06-17 | Intel Corporation | Silicon and silicon germanium nanowire structures |
| US8901607B2 (en) * | 2013-01-14 | 2014-12-02 | Taiwan Semiconductor Manufacturing Company, Ltd. | Semiconductor device and fabricating the same |
| US9252275B2 (en) * | 2011-12-23 | 2016-02-02 | Intel Corporation | Non-planar gate all-around device and method of fabrication thereof |
| US9716091B2 (en) * | 2010-10-13 | 2017-07-25 | Taiwan Semiconductor Manufacturing Company, Ltd. | Fin field effect transistor |
| US9847391B1 (en) * | 2017-04-05 | 2017-12-19 | Globalfoundries Inc. | Stacked nanosheet field-effect transistor with diode isolation |
| US9853132B2 (en) * | 2015-11-13 | 2017-12-26 | International Business Machines Corporation | Nanosheet MOSFET with full-height air-gap spacer |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5963817A (en) | 1997-10-16 | 1999-10-05 | International Business Machines Corporation | Bulk and strained silicon on insulator using local selective oxidation |
| US7923337B2 (en) | 2007-06-20 | 2011-04-12 | International Business Machines Corporation | Fin field effect transistor devices with self-aligned source and drain regions |
| US8084308B2 (en) | 2009-05-21 | 2011-12-27 | International Business Machines Corporation | Single gate inverter nanowire mesh |
| US8716797B2 (en) * | 2009-11-03 | 2014-05-06 | International Business Machines Corporation | FinFET spacer formation by oriented implantation |
| US8637359B2 (en) | 2011-06-10 | 2014-01-28 | International Business Machines Corporation | Fin-last replacement metal gate FinFET process |
| US8809131B2 (en) | 2012-07-17 | 2014-08-19 | International Business Machines Corporation | Replacement gate fin first wire last gate all around devices |
| US9006087B2 (en) | 2013-02-07 | 2015-04-14 | International Business Machines Corporation | Diode structure and method for wire-last nanomesh technologies |
| US8778768B1 (en) | 2013-03-12 | 2014-07-15 | International Business Machines Corporation | Non-replacement gate nanomesh field effect transistor with epitixially grown source and drain |
| CN106030815B (en) * | 2014-03-24 | 2020-01-21 | 英特尔公司 | Integrated methods for fabricating internal spacers for nanowire devices |
-
2015
- 2015-06-30 US US14/754,751 patent/US10170608B2/en active Active
- 2015-11-23 US US14/948,509 patent/US10170609B2/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7892945B2 (en) * | 2009-02-17 | 2011-02-22 | International Business Machines Corporation | Nanowire mesh device and method of fabricating same |
| US9716091B2 (en) * | 2010-10-13 | 2017-07-25 | Taiwan Semiconductor Manufacturing Company, Ltd. | Fin field effect transistor |
| US8753942B2 (en) * | 2010-12-01 | 2014-06-17 | Intel Corporation | Silicon and silicon germanium nanowire structures |
| US9252275B2 (en) * | 2011-12-23 | 2016-02-02 | Intel Corporation | Non-planar gate all-around device and method of fabrication thereof |
| US8901607B2 (en) * | 2013-01-14 | 2014-12-02 | Taiwan Semiconductor Manufacturing Company, Ltd. | Semiconductor device and fabricating the same |
| US9853132B2 (en) * | 2015-11-13 | 2017-12-26 | International Business Machines Corporation | Nanosheet MOSFET with full-height air-gap spacer |
| US9847391B1 (en) * | 2017-04-05 | 2017-12-19 | Globalfoundries Inc. | Stacked nanosheet field-effect transistor with diode isolation |
Cited By (56)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10998423B2 (en) * | 2015-09-25 | 2021-05-04 | Intel Corporation | Fabrication of multi-channel nanowire devices with self-aligned internal spacers and SOI FinFETs using selective silicon nitride capping |
| US11652141B2 (en) | 2015-10-07 | 2023-05-16 | Taiwan Semiconductor Manufacturing Company, Ltd. | Strained nanowire CMOS device and method of forming |
| US11798989B2 (en) | 2015-10-07 | 2023-10-24 | Taiwan Semiconductor Manufacturing Company, Ltd. | Strained nanowire CMOS device and method of forming |
| US11309385B2 (en) | 2015-10-07 | 2022-04-19 | Taiwan Semiconductor Manufacturing Company, Ltd. | Strained nanowire CMOS device and method of forming |
| US20180090570A1 (en) * | 2015-10-07 | 2018-03-29 | Taiwan Semiconductor Manufacturing Company, Ltd. | Strained Nanowire CMOS Device and Method of Forming |
| US10727298B2 (en) * | 2015-10-07 | 2020-07-28 | Taiwan Semiconductor Manufacturing Company, Ltd. | Strained nanowire CMOS device and method of forming |
| US10535732B2 (en) * | 2015-10-07 | 2020-01-14 | Taiwan Semiconductor Manufacturing Company, Ltd. | Strained nanowire CMOS device and method of forming |
| US20180175036A1 (en) * | 2015-11-16 | 2018-06-21 | Taiwan Semiconductor Manufacturing Company, Ltd. | Multi-Gate Device and Method of Fabrication Thereof |
| US10790280B2 (en) * | 2015-11-16 | 2020-09-29 | Taiwan Semiconductor Manufacturing Company, Ltd. | Multi-gate device and method of fabrication thereof |
| US9887264B2 (en) * | 2015-12-10 | 2018-02-06 | International Business Machines Corporation | Nanowire field effect transistor (FET) and method for fabricating the same |
| US10916637B2 (en) | 2016-11-14 | 2021-02-09 | Tokyo Electron Limited | Method of forming gate spacer for nanowire FET device |
| US10347742B2 (en) * | 2016-11-14 | 2019-07-09 | Tokyo Electron Limited | Method of forming gate spacer for nanowire FET device |
| US20180138291A1 (en) * | 2016-11-14 | 2018-05-17 | Tokyo Electron Limited | Method of forming gate spacer for nanowire fet device |
| CN108288584A (en) * | 2017-01-09 | 2018-07-17 | 三星电子株式会社 | The production method of nanometer sheet transistor spacer including interior spacer |
| US12198951B2 (en) | 2017-03-10 | 2025-01-14 | Applied Materials, Inc. | High pressure wafer processing systems and related methods |
| WO2018195428A1 (en) * | 2017-04-20 | 2018-10-25 | Micromaterials Llc | Selective formation of silicon-containing spacer |
| US10522552B2 (en) | 2017-05-15 | 2019-12-31 | Imec Vzw | Method of fabricating vertical transistor device |
| EP3404701A1 (en) * | 2017-05-15 | 2018-11-21 | IMEC vzw | A method for defining a channel region in a vertical transistor device |
| CN108878293A (en) * | 2017-05-15 | 2018-11-23 | Imec 非营利协会 | The method for being used to form the column in vertical transistor devices |
| US10170485B2 (en) * | 2017-05-24 | 2019-01-01 | International Business Machines Corporation | Three-dimensional stacked junctionless channels for dense SRAM |
| US11705337B2 (en) | 2017-05-25 | 2023-07-18 | Applied Materials, Inc. | Tungsten defluorination by high pressure treatment |
| US11694912B2 (en) | 2017-08-18 | 2023-07-04 | Applied Materials, Inc. | High pressure and high temperature anneal chamber |
| US11469113B2 (en) | 2017-08-18 | 2022-10-11 | Applied Materials, Inc. | High pressure and high temperature anneal chamber |
| US11462417B2 (en) | 2017-08-18 | 2022-10-04 | Applied Materials, Inc. | High pressure and high temperature anneal chamber |
| US11018032B2 (en) | 2017-08-18 | 2021-05-25 | Applied Materials, Inc. | High pressure and high temperature anneal chamber |
| US11177128B2 (en) * | 2017-09-12 | 2021-11-16 | Applied Materials, Inc. | Apparatus and methods for manufacturing semiconductor structures using protective barrier layer |
| US10867866B2 (en) * | 2017-10-30 | 2020-12-15 | Taiwan Semiconductor Manufacturing Co., Ltd. | Semiconductor device and manufacturing method thereof |
| US12538548B2 (en) | 2017-10-30 | 2026-01-27 | Taiwan Semiconductor Manufacturing Company, Ltd. | Method of manufacturing a semiconductor device and a semiconductor device |
| US10818777B2 (en) * | 2017-10-30 | 2020-10-27 | Taiwan Semiconductor Manufacturing Co., Ltd. | Method of manufacturing a semiconductor device and a semiconductor device |
| US11682587B2 (en) | 2017-10-30 | 2023-06-20 | Taiwan Semiconductor Manufacturing Co., Ltd. | Semiconductor device and manufacturing method thereof |
| US11677010B2 (en) | 2017-10-30 | 2023-06-13 | Taiwan Semiconductor Manufacturing Co., Ltd. | Method of manufacturing a semiconductor device and a semiconductor device |
| US10943832B2 (en) | 2017-10-30 | 2021-03-09 | Taiwan Semiconductor Manufacturing Co., Ltd. | Semiconductor device and manufacturing method thereof |
| US11527421B2 (en) | 2017-11-11 | 2022-12-13 | Micromaterials, LLC | Gas delivery system for high pressure processing chamber |
| US11756803B2 (en) | 2017-11-11 | 2023-09-12 | Applied Materials, Inc. | Gas delivery system for high pressure processing chamber |
| US11610773B2 (en) | 2017-11-17 | 2023-03-21 | Applied Materials, Inc. | Condenser system for high pressure processing system |
| US10818490B2 (en) * | 2017-12-15 | 2020-10-27 | Applied Materials, Inc. | Controlled growth of thin silicon oxide film at low temperature |
| US11881411B2 (en) | 2018-03-09 | 2024-01-23 | Applied Materials, Inc. | High pressure annealing process for metal containing materials |
| US10367061B1 (en) | 2018-03-30 | 2019-07-30 | International Business Machines Corporation | Replacement metal gate and inner spacer formation in three dimensional structures using sacrificial silicon germanium |
| US11581183B2 (en) | 2018-05-08 | 2023-02-14 | Applied Materials, Inc. | Methods of forming amorphous carbon hard mask layers and hard mask layers formed therefrom |
| US11361978B2 (en) | 2018-07-25 | 2022-06-14 | Applied Materials, Inc. | Gas delivery module |
| US11110383B2 (en) | 2018-08-06 | 2021-09-07 | Applied Materials, Inc. | Gas abatement apparatus |
| US11227797B2 (en) | 2018-11-16 | 2022-01-18 | Applied Materials, Inc. | Film deposition using enhanced diffusion process |
| EP3660922A1 (en) * | 2018-11-27 | 2020-06-03 | IMEC vzw | A method of forming a stack of insulated cmos devices |
| US11056574B2 (en) | 2018-11-27 | 2021-07-06 | Imec Vzw | Stacked semiconductor device and method of forming same |
| US11749555B2 (en) | 2018-12-07 | 2023-09-05 | Applied Materials, Inc. | Semiconductor processing system |
| US12218226B2 (en) * | 2019-02-21 | 2025-02-04 | Taiwan Semiconductor Manufacturing Company, Ltd. | Methods of fabricating semiconductor devices having gate-all-around structure with inner spacer last process |
| US20210066473A1 (en) * | 2019-02-21 | 2021-03-04 | Taiwan Semiconductor Manufacturing Company, Ltd. | Methods of fabricating semiconductor devices having gate-all-around structure with inner spacer last process |
| CN112993011A (en) * | 2019-12-17 | 2021-06-18 | 台湾积体电路制造股份有限公司 | Semiconductor structure and forming method thereof |
| US11901222B2 (en) | 2020-02-17 | 2024-02-13 | Applied Materials, Inc. | Multi-step process for flowable gap-fill film |
| US12211927B2 (en) | 2021-04-07 | 2025-01-28 | Taiwan Semiconductor Manufacturing Company, Ltd. | Etch selectivity control for epitaxy process window enlargement in semiconductor devices |
| US20220328653A1 (en) * | 2021-04-07 | 2022-10-13 | Taiwan Semiconductor Manufacturing Company Ltd. | Etch selectivity control for epitaxy process window enlargement in semiconductor devices |
| US11757024B2 (en) * | 2021-04-07 | 2023-09-12 | Taiwan Semiconductor Manufacturing Company Ltd. | Etch selectivity control for epitaxy process window enlargement in semiconductor devices |
| US20230299175A1 (en) * | 2022-03-16 | 2023-09-21 | Taiwan Semiconductor Manufacturing Company, Ltd. | Gate spacer and formation method thereof |
| US12336249B2 (en) * | 2022-03-16 | 2025-06-17 | Taiwan Semiconductor Manufacturing Company, Ltd. | Gate spacer and formation method thereof |
| US12166075B2 (en) * | 2022-04-19 | 2024-12-10 | Taiwan Semiconductor Manufacturing Company, Ltd. | Method and structure for gate-all-around devices |
| US20230335586A1 (en) * | 2022-04-19 | 2023-10-19 | Taiwan Semiconductor Manufacturing Company, Ltd. | Method and structure for gate-all-around devices |
Also Published As
| Publication number | Publication date |
|---|---|
| US10170608B2 (en) | 2019-01-01 |
| US20170005180A1 (en) | 2017-01-05 |
| US10170609B2 (en) | 2019-01-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US10170609B2 (en) | Internal spacer formation from selective oxidation for Fin-first wire-last replacement gate-all-around nanowire FET | |
| US8809131B2 (en) | Replacement gate fin first wire last gate all around devices | |
| US8722472B2 (en) | Hybrid CMOS nanowire mesh device and FINFET device | |
| US8551833B2 (en) | Double gate planar field effect transistors | |
| US7893492B2 (en) | Nanowire mesh device and method of fabricating same | |
| US9831241B2 (en) | Method and structure for improving finFET with epitaxy source/drain | |
| JP5744854B2 (en) | Nanowire mesh FET having a plurality of threshold voltages and manufacturing method thereof | |
| US8709888B2 (en) | Hybrid CMOS nanowire mesh device and PDSOI device | |
| US8563376B2 (en) | Hybrid CMOS nanowire mesh device and bulk CMOS device | |
| US8901659B2 (en) | Tapered nanowire structure with reduced off current | |
| US9660035B2 (en) | Semiconductor device including superlattice SiGe/Si fin structure | |
| US12342565B2 (en) | Semiconductor devices and methods of manufacturing thereof | |
| CN104103506B (en) | Semiconductor device manufacturing method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| AS | Assignment |
Owner name: INTERNATIONAL BUSINESS MACHINES CORPORATION, NEW Y Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:CHENG, SZU-LIN;GUILLORN, MICHAEL A.;LAUER, GEN P.;AND OTHERS;REEL/FRAME:037115/0597 Effective date: 20150629 |
|
| STCF | Information on status: patent grant |
Free format text: PATENTED CASE |
|
| MAFP | Maintenance fee payment |
Free format text: PAYMENT OF MAINTENANCE FEE, 4TH YEAR, LARGE ENTITY (ORIGINAL EVENT CODE: M1551); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY Year of fee payment: 4 |