US20160271688A1 - Low cost high ductility cast aluminum alloy - Google Patents
Low cost high ductility cast aluminum alloy Download PDFInfo
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- US20160271688A1 US20160271688A1 US15/061,257 US201615061257A US2016271688A1 US 20160271688 A1 US20160271688 A1 US 20160271688A1 US 201615061257 A US201615061257 A US 201615061257A US 2016271688 A1 US2016271688 A1 US 2016271688A1
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- 229910000838 Al alloy Inorganic materials 0.000 title claims abstract description 116
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 44
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 44
- 239000010703 silicon Substances 0.000 claims abstract description 44
- 238000005266 casting Methods 0.000 claims abstract description 28
- 239000011575 calcium Substances 0.000 claims abstract description 16
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 15
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 15
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052684 Cerium Inorganic materials 0.000 claims abstract description 9
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 9
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052797 bismuth Inorganic materials 0.000 claims abstract description 9
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 9
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims description 24
- 238000004519 manufacturing process Methods 0.000 claims description 10
- 239000010949 copper Substances 0.000 claims description 8
- 239000011777 magnesium Substances 0.000 claims description 8
- 239000011572 manganese Substances 0.000 claims description 8
- 239000010936 titanium Substances 0.000 claims description 8
- 238000002844 melting Methods 0.000 claims description 7
- 230000008018 melting Effects 0.000 claims description 7
- JBQYATWDVHIOAR-UHFFFAOYSA-N tellanylidenegermanium Chemical compound [Te]=[Ge] JBQYATWDVHIOAR-UHFFFAOYSA-N 0.000 claims description 7
- 239000000725 suspension Substances 0.000 claims description 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 229910052796 boron Inorganic materials 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 238000004512 die casting Methods 0.000 claims description 4
- 229910052749 magnesium Inorganic materials 0.000 claims description 4
- 229910052748 manganese Inorganic materials 0.000 claims description 4
- 229910052750 molybdenum Inorganic materials 0.000 claims description 4
- 239000011733 molybdenum Substances 0.000 claims description 4
- 229910052702 rhenium Inorganic materials 0.000 claims description 4
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 4
- 229910052706 scandium Inorganic materials 0.000 claims description 4
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 claims description 4
- VSZWPYCFIRKVQL-UHFFFAOYSA-N selanylidenegallium;selenium Chemical compound [Se].[Se]=[Ga].[Se]=[Ga] VSZWPYCFIRKVQL-UHFFFAOYSA-N 0.000 claims description 4
- 229910052712 strontium Inorganic materials 0.000 claims description 4
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 238000009716 squeeze casting Methods 0.000 claims description 3
- 238000004064 recycling Methods 0.000 claims 1
- 238000005275 alloying Methods 0.000 abstract description 7
- 238000005336 cracking Methods 0.000 abstract description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 2
- 230000001627 detrimental effect Effects 0.000 abstract description 2
- 239000011701 zinc Substances 0.000 abstract description 2
- 229910052725 zinc Inorganic materials 0.000 abstract description 2
- 230000007797 corrosion Effects 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000005476 soldering Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 230000005496 eutectics Effects 0.000 description 3
- 229910001315 Tool steel Inorganic materials 0.000 description 2
- CSDREXVUYHZDNP-UHFFFAOYSA-N alumanylidynesilicon Chemical compound [Al].[Si] CSDREXVUYHZDNP-UHFFFAOYSA-N 0.000 description 2
- 229910002056 binary alloy Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910018566 Al—Si—Mg Inorganic materials 0.000 description 1
- 229910001297 Zn alloy Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000003116 impacting effect Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D21/00—Casting non-ferrous metals or metallic compounds so far as their metallurgical properties are of importance for the casting procedure; Selection of compositions therefor
- B22D21/002—Castings of light metals
- B22D21/007—Castings of light metals with low melting point, e.g. Al 659 degrees C, Mg 650 degrees C
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D17/00—Pressure die casting or injection die casting, i.e. casting in which the metal is forced into a mould under high pressure
- B22D17/007—Semi-solid pressure die casting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D17/00—Pressure die casting or injection die casting, i.e. casting in which the metal is forced into a mould under high pressure
- B22D17/02—Hot chamber machines, i.e. with heated press chamber in which metal is melted
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D18/00—Pressure casting; Vacuum casting
- B22D18/02—Pressure casting making use of mechanical pressure devices, e.g. cast-forging
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D18/00—Pressure casting; Vacuum casting
- B22D18/04—Low pressure casting, i.e. making use of pressures up to a few bars to fill the mould
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
- C22C1/026—Alloys based on aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/02—Alloys based on aluminium with silicon as the next major constituent
Definitions
- the invention relates generally to an aluminum alloy for casting, a method of forming the aluminum alloy, an automotive vehicle component formed of the cast aluminum alloy, and a method of manufacturing the cast component.
- Casting of aluminum alloys is oftentimes used in the automotive industry to form lightweight components, including complex structural, body-in-white, suspension, and chassis components.
- There are many types of known casting processes for example high pressure die casting, low pressure casting, and squeeze casting.
- the die is typically formed of a hardened tool steel. Although the casting equipment is expensive, the cost per component formed is relatively low, which makes the process suitable for high volume production.
- an aluminum alloy capable of forming a component having higher ductility, without loss of fluidity or castability is desired.
- the aluminum alloy should also be resistant to damage associated with hot cracking, soldering, shrinkage, and corrosion.
- the components should still provide a high strength and toughness.
- the aluminum alloy includes aluminum in an amount of at least 70 weight percent (wt. %) and silicon in an amount of 0.1 wt. % to less than 7.0 wt. %, based on the total weight of the aluminum alloy.
- This amount of silicon is reduced amount compared to other aluminum alloys used for casting which typically include 7.0 wt. % to 11.0 wt. % silicon.
- the reduced amount of silicon provides a smaller eutectic phase and thus improved elongation, without loss of castability.
- the reduced amount of silicon also reduces the cost of the aluminum alloy.
- Additional alloying elements can also be present in the aluminum alloy to improve resistance to hot cracking, soldering, shrinkage, and corrosion, and also to achieve a desired strength and toughness, or even higher ductility.
- a method for manufacturing an improved aluminum alloy for casting includes providing an aluminum alloy, wherein the aluminum alloy is selected from a 300 series aluminum alloy, 5000 series aluminum alloy, and 6000 series aluminum alloy.
- the method further includes melting the aluminum alloy; and adding silicon to the melted aluminum alloy so that the total amount of silicon present ranges from 0.1 wt. % to less than 7.0 wt. %, based on the total weight of the melted aluminum alloy.
- Another aspect of the invention provides a cast component formed of the improved aluminum alloy.
- the cast component has increased ductility and elongation, compared to the same component formed of the comparative aluminum alloys with greater amounts of silicon.
- a method for manufacturing the component by casting the improved aluminum alloy is also provided.
- FIG. 1 is a graph illustrating the effect of silicon content on fluidity of an aluminum-silicon binary alloy
- FIG. 2 illustrates a portion of an example component formed of an aluminum alloy according to an embodiment of the invention
- FIG. 3 is a photomicrograph of the component of FIG. 2 ;
- FIG. 4 illustrates method steps used to form the component of FIG. 2 according to an example embodiment.
- One aspect of the invention provides an improved aluminum alloy for casting components, such as a lightweight automotive vehicle component, is provided.
- components include structural, body-in-white, suspension, or chassis components.
- the aluminum alloy provides a component with improved ductility and elongation, and without loss of fluidity or castability.
- the aluminum alloy is also less expensive than other aluminum alloys used for casting, which is especially beneficial for high volume production.
- the improved aluminum alloy is aluminum-based, and thus typically includes aluminum in an amount of at least 70 weight percent (wt. %), based on the total weight of the aluminum alloy.
- the aluminum alloy is formed by modifying a 5000 series alloy, which includes 88.2 wt. % to 99.8 wt. % aluminum.
- the aluminum alloy is formed by modifying a 6000 series alloy, which includes 91.7 wt. % to 99.6 wt. % aluminum.
- other amounts of aluminum could be used.
- the aluminum alloy also includes an amount of silicon (Si) which helps achieve the improved elongation and ductility with reduced costs.
- the amount of silicon ranges from 0.1 to less than 7.0 wt. %, and typically 2.0 to 4.0 wt. %, based on the total weight of the aluminum alloy. This amount of silicon is reduced compared to other aluminum alloys used for casting, which typically include 7.0 wt. % to 11.0 wt. % silicon.
- the lower amount of silicon present in the improved aluminum alloy creates a smaller eutectic phase, which leads to increased elongation in the finished component, as the eutectic phase is one of the main limitations for elongation.
- the elongation of a component formed of the improved aluminum alloy with reduced silicon content is typically 8% to 10%.
- the reduced amount of silicon also reduces the total cost of the aluminum alloy.
- the castability, strength, and toughness of the aluminum alloy can also be adjusted based on the amount of silicon.
- the reduced amount of silicon does not sacrifice fluidity or castability of the aluminum alloy, when compared to the other aluminum alloys which include 7.0 wt. % silicon or greater.
- the castability of the improved aluminum alloy is better than that of the other aluminum alloys including 7.0 wt. % silicon or greater.
- FIG. 1 is a graph illustrating the effect of silicon content on fluidity of an aluminum-silicon binary alloy.
- Additional alloying elements can also be present in the improved aluminum alloy to further improve elongation and ductility, or to achieve the desired strength and toughness.
- magnesium (Mg), manganese (Mn), cerium (Ce), and/or iron (Fe) can be added to further improve ductility, castability, strength, ductility, and/or toughness.
- the aluminum alloy can also include at least one of copper (Cu) and zinc (Zn) to increase strength, preferably without negatively impacting corrosion resistance.
- the additional alloying elements can provide other metallurgical effects as well, such as improved resistance to hot cracking, soldering, shrinkage, and corrosion.
- FIG. 2 illustrates a portion of an example component 10 formed of the improved aluminum alloy
- FIG. 3 is a photomicrograph 12 of a portion of the component 10 shown in FIG. 2 .
- FIG. 4 illustrates steps of the method according to an example embodiment.
- the aluminum alloy is preferable formed from recycled wrought aluminum, such as a 5000 series or 6000 series aluminum alloy. Recycled cast aluminum alloys in the 300 series, such as Al—Si—Mg alloys, could alternatively be used as the base material. Other aluminum-based materials that could be used to form the improved aluminum alloy are sold by Cosma International or Magna International, such as Aural-4 or a Promatek self-hardened Al—Si—Mg—Zn alloy. Manufacturing the improved aluminum alloy from one of the recycled materials lowers the raw material cost, as it takes 95% less energy to recycle an aluminum alloy than to create it from primary elements.
- the method typically begins by melting the recycled wrought aluminum, or other base aluminum alloy.
- the melting step can be conducted by an induction melter, or another source of heat.
- the method includes adding silicon to the melt and mixing the silicon with the base aluminum alloy so that the total amount of silicon ranges from 0.1 wt. % to less than 7.0 wt. %, and preferably 4.0 wt. % or less, based on the total weight of the melted aluminum alloy, i.e. the final alloy composition.
- the additional alloying elements discussed above, can be added to the melted mixture to form the improved aluminum alloy. Alternatively, the additional alloying elements could be present in the wrought aluminum or other base aluminum alloy. Once all of the elements are mixed together, the aluminum alloy is ready for casting.
- Another aspect of the invention provides a cast component for an automotive vehicle formed of the improved aluminum alloy, and a method for manufacturing the cast component.
- Any casting process used to form components from an aluminum-based material can be used with the improved aluminum alloy, for example high pressure die casting, low pressure casting, or squeeze casting.
- the casting process is a die casting process, which typically includes forcing the molten aluminum alloy into an unheated die or mold cavity under pressure.
- the die is typically formed from hardened tool steel.
- the castability and fluidity of the molten aluminum alloy with the reduced amount of silicon is equal to or slightly better than other aluminum alloys with higher amounts of silicon.
- the molten aluminum is formed to a solid component having the shape of the mold, which can be a complex shape.
- the casting process can include an optional heat treating process or other finishing processes.
- a heat treatment process may not be necessary when the component is formed from the improved aluminum alloy, which would provide the advantage of reduced process time and costs.
- the component formed from the improved aluminum alloy has improved ductility and elongation due to the lower amount of silicon in the aluminum alloy.
- the aluminum alloy can include additional alloying elements to improve resistance to hot cracking, soldering, shrinkage, and corrosion, and also to achieve a desired strength and toughness, or even higher ductility.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Body Structure For Vehicles (AREA)
Abstract
Description
- This U.S. Patent Application claims the benefit of U.S. Provisional Patent Application Ser. No. 62/134,072, filed on Mar. 17, 2015, and entitled “Low Cost High Ductility Cast Aluminum Alloy,” the entire disclosure of the application being considered part of the disclosure of this application and hereby incorporated by reference.
- 1. Field of the Invention
- The invention relates generally to an aluminum alloy for casting, a method of forming the aluminum alloy, an automotive vehicle component formed of the cast aluminum alloy, and a method of manufacturing the cast component.
- 2. Related Art
- Casting of aluminum alloys is oftentimes used in the automotive industry to form lightweight components, including complex structural, body-in-white, suspension, and chassis components. There are many types of known casting processes, for example high pressure die casting, low pressure casting, and squeeze casting. The die is typically formed of a hardened tool steel. Although the casting equipment is expensive, the cost per component formed is relatively low, which makes the process suitable for high volume production.
- However, improvements to the casting process and materials used in the casting process are desired. For example, an aluminum alloy capable of forming a component having higher ductility, without loss of fluidity or castability, is desired. The aluminum alloy should also be resistant to damage associated with hot cracking, soldering, shrinkage, and corrosion. In addition, although lightweight components are desired, the components should still provide a high strength and toughness.
- One aspect of the invention provides an improved aluminum alloy for casting. The aluminum alloy includes aluminum in an amount of at least 70 weight percent (wt. %) and silicon in an amount of 0.1 wt. % to less than 7.0 wt. %, based on the total weight of the aluminum alloy. This amount of silicon is reduced amount compared to other aluminum alloys used for casting which typically include 7.0 wt. % to 11.0 wt. % silicon. The reduced amount of silicon provides a smaller eutectic phase and thus improved elongation, without loss of castability. The reduced amount of silicon also reduces the cost of the aluminum alloy. Additional alloying elements can also be present in the aluminum alloy to improve resistance to hot cracking, soldering, shrinkage, and corrosion, and also to achieve a desired strength and toughness, or even higher ductility.
- A method for manufacturing an improved aluminum alloy for casting is also provided. The method includes providing an aluminum alloy, wherein the aluminum alloy is selected from a 300 series aluminum alloy, 5000 series aluminum alloy, and 6000 series aluminum alloy. The method further includes melting the aluminum alloy; and adding silicon to the melted aluminum alloy so that the total amount of silicon present ranges from 0.1 wt. % to less than 7.0 wt. %, based on the total weight of the melted aluminum alloy.
- Another aspect of the invention provides a cast component formed of the improved aluminum alloy. The cast component has increased ductility and elongation, compared to the same component formed of the comparative aluminum alloys with greater amounts of silicon.
- A method for manufacturing the component by casting the improved aluminum alloy is also provided.
- Other advantages of the present invention will be readily appreciated, as the same becomes better understood by reference to the following detailed description when considered in connection with the accompanying drawings wherein:
-
FIG. 1 is a graph illustrating the effect of silicon content on fluidity of an aluminum-silicon binary alloy; -
FIG. 2 illustrates a portion of an example component formed of an aluminum alloy according to an embodiment of the invention; -
FIG. 3 is a photomicrograph of the component ofFIG. 2 ; and -
FIG. 4 illustrates method steps used to form the component ofFIG. 2 according to an example embodiment. - One aspect of the invention provides an improved aluminum alloy for casting components, such as a lightweight automotive vehicle component, is provided. Examples of such components include structural, body-in-white, suspension, or chassis components. The aluminum alloy provides a component with improved ductility and elongation, and without loss of fluidity or castability. The aluminum alloy is also less expensive than other aluminum alloys used for casting, which is especially beneficial for high volume production.
- The improved aluminum alloy is aluminum-based, and thus typically includes aluminum in an amount of at least 70 weight percent (wt. %), based on the total weight of the aluminum alloy. In one embodiment, the aluminum alloy is formed by modifying a 5000 series alloy, which includes 88.2 wt. % to 99.8 wt. % aluminum. In another embodiment, the aluminum alloy is formed by modifying a 6000 series alloy, which includes 91.7 wt. % to 99.6 wt. % aluminum. However, other amounts of aluminum could be used.
- The aluminum alloy also includes an amount of silicon (Si) which helps achieve the improved elongation and ductility with reduced costs. The amount of silicon ranges from 0.1 to less than 7.0 wt. %, and typically 2.0 to 4.0 wt. %, based on the total weight of the aluminum alloy. This amount of silicon is reduced compared to other aluminum alloys used for casting, which typically include 7.0 wt. % to 11.0 wt. % silicon. The lower amount of silicon present in the improved aluminum alloy creates a smaller eutectic phase, which leads to increased elongation in the finished component, as the eutectic phase is one of the main limitations for elongation. The elongation of a component formed of the improved aluminum alloy with reduced silicon content is typically 8% to 10%.
- The reduced amount of silicon also reduces the total cost of the aluminum alloy. The castability, strength, and toughness of the aluminum alloy can also be adjusted based on the amount of silicon. In addition, it has been found that the reduced amount of silicon does not sacrifice fluidity or castability of the aluminum alloy, when compared to the other aluminum alloys which include 7.0 wt. % silicon or greater. In some cases, the castability of the improved aluminum alloy is better than that of the other aluminum alloys including 7.0 wt. % silicon or greater.
FIG. 1 is a graph illustrating the effect of silicon content on fluidity of an aluminum-silicon binary alloy. - Additional alloying elements can also be present in the improved aluminum alloy to further improve elongation and ductility, or to achieve the desired strength and toughness. For example, magnesium (Mg), manganese (Mn), cerium (Ce), and/or iron (Fe) can be added to further improve ductility, castability, strength, ductility, and/or toughness. The aluminum alloy can also include at least one of copper (Cu) and zinc (Zn) to increase strength, preferably without negatively impacting corrosion resistance. The additional alloying elements can provide other metallurgical effects as well, such as improved resistance to hot cracking, soldering, shrinkage, and corrosion. Special properties or other metallurgical effects can be achieved by adding at least one of titanium (Ti), strontium (Sr), calcium (Ca), zirconium (Zr), bismuth (Bi), antimony (Sb), boron (B), molybdenum (Mo), scandium (Sc), and rhenium (Re). In an exemplary embodiment, antimony, calcium, and/or bismuth is added to counter any detrimental effect of the low silicon content on hot cracking behavior; zinc is added to increase strength, and cerium is added to further increase ductility.
FIG. 2 illustrates a portion of anexample component 10 formed of the improved aluminum alloy, andFIG. 3 is aphotomicrograph 12 of a portion of thecomponent 10 shown inFIG. 2 . - Another aspect of the invention provides a method of manufacturing the aluminum alloy.
FIG. 4 illustrates steps of the method according to an example embodiment. The aluminum alloy is preferable formed from recycled wrought aluminum, such as a 5000 series or 6000 series aluminum alloy. Recycled cast aluminum alloys in the 300 series, such as Al—Si—Mg alloys, could alternatively be used as the base material. Other aluminum-based materials that could be used to form the improved aluminum alloy are sold by Cosma International or Magna International, such as Aural-4 or a Promatek self-hardened Al—Si—Mg—Zn alloy. Manufacturing the improved aluminum alloy from one of the recycled materials lowers the raw material cost, as it takes 95% less energy to recycle an aluminum alloy than to create it from primary elements. - The method typically begins by melting the recycled wrought aluminum, or other base aluminum alloy. The melting step can be conducted by an induction melter, or another source of heat. Once the base aluminum alloy is melted, the method includes adding silicon to the melt and mixing the silicon with the base aluminum alloy so that the total amount of silicon ranges from 0.1 wt. % to less than 7.0 wt. %, and preferably 4.0 wt. % or less, based on the total weight of the melted aluminum alloy, i.e. the final alloy composition. The additional alloying elements, discussed above, can be added to the melted mixture to form the improved aluminum alloy. Alternatively, the additional alloying elements could be present in the wrought aluminum or other base aluminum alloy. Once all of the elements are mixed together, the aluminum alloy is ready for casting.
- Another aspect of the invention provides a cast component for an automotive vehicle formed of the improved aluminum alloy, and a method for manufacturing the cast component. Any casting process used to form components from an aluminum-based material can be used with the improved aluminum alloy, for example high pressure die casting, low pressure casting, or squeeze casting. In one example embodiment, the casting process is a die casting process, which typically includes forcing the molten aluminum alloy into an unheated die or mold cavity under pressure. The die is typically formed from hardened tool steel. As discussed above, the castability and fluidity of the molten aluminum alloy with the reduced amount of silicon is equal to or slightly better than other aluminum alloys with higher amounts of silicon. The molten aluminum is formed to a solid component having the shape of the mold, which can be a complex shape. Many different types of components can be formed by the casting process, for example, a structural, body-in-white, suspension, or chassis component. After the casting process, the method can include an optional heat treating process or other finishing processes. However, it has been found that a heat treatment process may not be necessary when the component is formed from the improved aluminum alloy, which would provide the advantage of reduced process time and costs.
- The component formed from the improved aluminum alloy has improved ductility and elongation due to the lower amount of silicon in the aluminum alloy. In addition, the aluminum alloy can include additional alloying elements to improve resistance to hot cracking, soldering, shrinkage, and corrosion, and also to achieve a desired strength and toughness, or even higher ductility.
- Obviously, many modifications and variations of the present invention are possible in light of the above teachings and may be practiced otherwise than as specifically described while within the scope of the following claims.
Claims (20)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15/061,257 US20160271688A1 (en) | 2015-03-17 | 2016-03-04 | Low cost high ductility cast aluminum alloy |
| US17/079,818 US20210079501A1 (en) | 2015-03-17 | 2020-10-26 | Low cost high ductility cast aluminum alloy |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201562134072P | 2015-03-17 | 2015-03-17 | |
| US15/061,257 US20160271688A1 (en) | 2015-03-17 | 2016-03-04 | Low cost high ductility cast aluminum alloy |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US17/079,818 Continuation-In-Part US20210079501A1 (en) | 2015-03-17 | 2020-10-26 | Low cost high ductility cast aluminum alloy |
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| US20160271688A1 true US20160271688A1 (en) | 2016-09-22 |
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| US15/061,257 Abandoned US20160271688A1 (en) | 2015-03-17 | 2016-03-04 | Low cost high ductility cast aluminum alloy |
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| US (1) | US20160271688A1 (en) |
| CN (1) | CN105986152A (en) |
| DE (1) | DE102016002689A1 (en) |
Cited By (5)
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| WO2018165012A1 (en) * | 2017-03-08 | 2018-09-13 | NanoAL LLC | High-performance 5000-series aluminum alloys |
| US10697046B2 (en) | 2016-07-07 | 2020-06-30 | NanoAL LLC | High-performance 5000-series aluminum alloys and methods for making and using them |
| US11781202B1 (en) | 2022-09-14 | 2023-10-10 | Suzhou Huijin Smart Materials Technology Co., Ltd. | Aluminum alloy for new energy vehicle integral die-cast part, preparation method therefor and application thereof |
| JP2025026298A (en) * | 2023-08-08 | 2025-02-21 | 小米汽車科技有限公司 | Die-cast aluminum alloy not requiring heat treatment, its manufacturing method and uses |
| JP2025029565A (en) * | 2023-08-21 | 2025-03-06 | 小米汽車科技有限公司 | Die-cast aluminum alloy material not requiring heat treatment, its manufacturing method, and automotive structural parts |
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| CN108070746A (en) * | 2016-11-14 | 2018-05-25 | 镇江市润州金山金属粉末厂 | A kind of aluminum alloy die casting |
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| CN106636790A (en) * | 2016-12-14 | 2017-05-10 | 宁波翔博机械有限公司 | High-strength aluminum alloy and preparation method thereof |
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| CN109750191B (en) * | 2019-01-31 | 2021-02-12 | 华为技术有限公司 | High-strength high-toughness high-heat-conductivity aluminum alloy for die casting |
| US20220017997A1 (en) * | 2019-02-08 | 2022-01-20 | Magna International Inc. | Aluminum alloys for structural high pressure vacuum die casting applications |
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| CN111074103A (en) * | 2019-11-28 | 2020-04-28 | 西安昆仑工业(集团)有限责任公司 | Die-casting aluminum alloy and refining process thereof |
| CN112159916B (en) * | 2020-08-27 | 2021-09-03 | 比亚迪股份有限公司 | Aluminum alloy and application thereof |
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| BRPI0409700A (en) * | 2003-04-24 | 2006-05-02 | Alcan Int Ltd | recycled aluminum scrap alloys containing high levels of iron and silicon |
| WO2013133976A1 (en) * | 2012-03-07 | 2013-09-12 | Alcoa Inc. | Improved 6xxx aluminum alloys, and methods for producing the same |
| EP2832874B1 (en) * | 2012-03-29 | 2018-04-25 | Furukawa Electric Co., Ltd. | Aluminum alloy wire and process for producing same |
| DE102013108127A1 (en) * | 2012-08-23 | 2014-02-27 | Ksm Castings Group Gmbh | Al-cast alloy |
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2016
- 2016-03-04 US US15/061,257 patent/US20160271688A1/en not_active Abandoned
- 2016-03-08 DE DE102016002689.8A patent/DE102016002689A1/en not_active Ceased
- 2016-03-17 CN CN201610154588.5A patent/CN105986152A/en active Pending
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| Ferreira US20080181812 * |
| Martin US3199979 * |
| Smet US20110250469 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10697046B2 (en) | 2016-07-07 | 2020-06-30 | NanoAL LLC | High-performance 5000-series aluminum alloys and methods for making and using them |
| WO2018165012A1 (en) * | 2017-03-08 | 2018-09-13 | NanoAL LLC | High-performance 5000-series aluminum alloys |
| US11814701B2 (en) | 2017-03-08 | 2023-11-14 | NanoAL LLC | High-performance 5000-series aluminum alloys |
| US11781202B1 (en) | 2022-09-14 | 2023-10-10 | Suzhou Huijin Smart Materials Technology Co., Ltd. | Aluminum alloy for new energy vehicle integral die-cast part, preparation method therefor and application thereof |
| JP2025026298A (en) * | 2023-08-08 | 2025-02-21 | 小米汽車科技有限公司 | Die-cast aluminum alloy not requiring heat treatment, its manufacturing method and uses |
| JP7812401B2 (en) | 2023-08-08 | 2026-02-09 | 小米汽車科技有限公司 | Die-cast aluminum alloy not requiring heat treatment, its manufacturing method, and automobile body structural parts |
| JP2025029565A (en) * | 2023-08-21 | 2025-03-06 | 小米汽車科技有限公司 | Die-cast aluminum alloy material not requiring heat treatment, its manufacturing method, and automotive structural parts |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105986152A (en) | 2016-10-05 |
| DE102016002689A1 (en) | 2016-09-22 |
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