US20160211352A1 - Method of trimming fin structure - Google Patents
Method of trimming fin structure Download PDFInfo
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- US20160211352A1 US20160211352A1 US14/597,700 US201514597700A US2016211352A1 US 20160211352 A1 US20160211352 A1 US 20160211352A1 US 201514597700 A US201514597700 A US 201514597700A US 2016211352 A1 US2016211352 A1 US 2016211352A1
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- H10D30/00—Field-effect transistors [FET]
- H10D30/01—Manufacture or treatment
- H10D30/021—Manufacture or treatment of FETs having insulated gates [IGFET]
- H10D30/024—Manufacture or treatment of FETs having insulated gates [IGFET] of fin field-effect transistors [FinFET]
- H10D30/0245—Manufacture or treatment of FETs having insulated gates [IGFET] of fin field-effect transistors [FinFET] by further thinning the channel after patterning the channel, e.g. using sacrificial oxidation on fins
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- H01L29/66818—
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- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/302—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
- H01L21/306—Chemical or electrical treatment, e.g. electrolytic etching
- H01L21/30625—With simultaneous mechanical treatment, e.g. mechanico-chemical polishing
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- H—ELECTRICITY
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/302—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
- H01L21/306—Chemical or electrical treatment, e.g. electrolytic etching
- H01L21/308—Chemical or electrical treatment, e.g. electrolytic etching using masks
- H01L21/3083—Chemical or electrical treatment, e.g. electrolytic etching using masks characterised by their size, orientation, disposition, behaviour, shape, in horizontal or vertical plane
- H01L21/3085—Chemical or electrical treatment, e.g. electrolytic etching using masks characterised by their size, orientation, disposition, behaviour, shape, in horizontal or vertical plane characterised by their behaviour during the process, e.g. soluble masks, redeposited masks
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/302—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
- H01L21/306—Chemical or electrical treatment, e.g. electrolytic etching
- H01L21/308—Chemical or electrical treatment, e.g. electrolytic etching using masks
- H01L21/3083—Chemical or electrical treatment, e.g. electrolytic etching using masks characterised by their size, orientation, disposition, behaviour, shape, in horizontal or vertical plane
- H01L21/3086—Chemical or electrical treatment, e.g. electrolytic etching using masks characterised by their size, orientation, disposition, behaviour, shape, in horizontal or vertical plane characterised by the process involved to create the mask, e.g. lift-off masks, sidewalls, or to modify the mask, e.g. pre-treatment, post-treatment
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- H01L29/1037—
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- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/01—Manufacture or treatment
- H10D30/021—Manufacture or treatment of FETs having insulated gates [IGFET]
- H10D30/024—Manufacture or treatment of FETs having insulated gates [IGFET] of fin field-effect transistors [FinFET]
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/60—Insulated-gate field-effect transistors [IGFET]
- H10D30/62—Fin field-effect transistors [FinFET]
- H10D30/6212—Fin field-effect transistors [FinFET] having fin-shaped semiconductor bodies having non-rectangular cross-sections
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- H—ELECTRICITY
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- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D62/00—Semiconductor bodies, or regions thereof, of devices having potential barriers
- H10D62/10—Shapes, relative sizes or dispositions of the regions of the semiconductor bodies; Shapes of the semiconductor bodies
- H10D62/17—Semiconductor regions connected to electrodes not carrying current to be rectified, amplified or switched, e.g. channel regions
- H10D62/213—Channel regions of field-effect devices
- H10D62/221—Channel regions of field-effect devices of FETs
- H10D62/235—Channel regions of field-effect devices of FETs of IGFETs
- H10D62/292—Non-planar channels of IGFETs
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- H—ELECTRICITY
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- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D62/00—Semiconductor bodies, or regions thereof, of devices having potential barriers
- H10D62/40—Crystalline structures
- H10D62/405—Orientations of crystalline planes
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- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D84/00—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
- H10D84/01—Manufacture or treatment
- H10D84/0123—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs
- H10D84/0126—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs the components including insulated gates, e.g. IGFETs
- H10D84/0158—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs the components including insulated gates, e.g. IGFETs the components including FinFETs
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- H—ELECTRICITY
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- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D84/00—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
- H10D84/01—Manufacture or treatment
- H10D84/02—Manufacture or treatment characterised by using material-based technologies
- H10D84/03—Manufacture or treatment characterised by using material-based technologies using Group IV technology, e.g. silicon technology or silicon-carbide [SiC] technology
- H10D84/038—Manufacture or treatment characterised by using material-based technologies using Group IV technology, e.g. silicon technology or silicon-carbide [SiC] technology using silicon technology, e.g. SiGe
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- H10P50/644—
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- H10P50/694—
Definitions
- FinFET fin-like field effect transistors
- a typical FinFET is fabricated with a thin “fin” extending on a substrate.
- the channel of the FinFET is formed in the fin.
- a gate is formed to wrap the fin, and therefore a tri-gate structure is fabricated.
- FinFET devices further include strained source/drain features to enhance carrier mobility and improve device performance.
- conventional techniques have not been entirely satisfactory in all respects.
- FIGS. 1A-1H are schematic cross-sectional views showing methods for trimming a fin structure according to various embodiments of the present disclosure.
- FIGS. 2A-2H are schematic cross-sectional views showing methods for trimming a fin structure according to various embodiments of the present disclosure.
- FIGS. 3A-3D are perspective views schematically illustrating other features of an integrated circuit device formed in various fabrication stages according to various embodiments of the present disclosure.
- first and second features are formed in direct contact
- additional features may be formed between the first and second features, such that the first and second features may not be in direct contact
- present disclosure may repeat reference numerals and/or letters in the various examples. This repetition is for the purpose of simplicity and clarity and does not in itself dictate a relationship between the various embodiments and/or configurations discussed.
- spatially relative terms such as “under,” “below,” “lower,” “above,” “upper”, “on” and the like, may be used herein for ease of description to describe one element or feature's relationship to another element(s) or feature(s) as illustrated in the figures.
- the spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures.
- the apparatus may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein may likewise be interpreted accordingly.
- the present disclosure relates generally to a method of trimming a fin structure for an active device such as for example a fin-like field effect transistor (FinFET).
- FinFET fin-like field effect transistor
- the width of the fin structure is less than certain dimension such as for example 16 nm
- the carrier mobility of the FinFET is unsatisfied, and a strain inducing layer covering the fin structure is used to enhance the carrier mobility.
- the strain inducing layer is formed on the fin structure, the width of the fin structure is unfavorably increased.
- the fin structure is trimmed prior to forming the strain inducing layer.
- conventional fin-trimming techniques suffer problems in that a tip-top is formed on the top of the fin structure, and that leads to a poor electrical performance.
- the present disclosure provides a novel method of trimming a fin structure that at least resolves the issue of the tip-top.
- Various embodiments of the present disclosure will be described in detail hereinafter.
- FIGS. 1A-1H are schematic cross-sectional views showing methods for trimming a fin structure according to various embodiments of the present disclosure.
- the substrate 100 includes semiconductor material.
- the substrate 100 may be a silicon-on-insulator (SOI) substrate.
- SOI substrate may be fabricated using any suitable methods.
- the SOI substrate can be formed using separation by implantation of oxygen, wafer bonding, or other methods.
- the substrate 100 may be a bulk silicon substrate.
- the substrate 100 include an elementary semiconductor such as for example germanium or silicon in a crystalline structure.
- the substrate 100 include a compound semiconductor such as for example gallium arsenic, silicon carbide, indium phosphide, gallium phosphide or indium antimonide, or combinations thereof.
- the substrate 100 may include isolation structures, such as for example shallow trench isolation structures. The isolation structure may surround the fin structure 110 , so that the fin structure 110 may be isolated from other features.
- the substrate 100 may include various doped regions and other features according to some embodiments of the present disclosure.
- the fin structure 110 includes crystalline silicon.
- the top surface of the fin structure 110 has a lattice plane with Miller index (100), and the sidewall of the fin structure 110 has a lattice plane with Miller index (110).
- the fin structure 110 may include a lower part containing silicon (Si) and an upper part containing silicon germanium (SiGe).
- the fin structure 110 may be doped during deposition by adding impurities to the source/drain material of the epitaxy process or subsequent to its deposition process by an ion implantation process.
- the fin structure 110 has a width d 1 which is ranged from about 5 nm to about 25 nm.
- the width d 1 may be about 5 nm to about 15 nm. In yet some examples, the width d 1 may be about 10 nm to about 20 nm. In yet some examples, the width d 1 may be about 15 nm to about 25 nm.
- a single fin structure 110 is shown for illustrative purposes only. As such, some embodiments may include a plurality of fin structures 110 .
- an epitaxy structure 120 is formed on the fin structure 110 .
- the epitaxy structure 120 includes the same material as the fin structure 110 so that semiconductor material may be epitaxially grown on the exposed surface of the fin structure 110 to form the epitaxy structure 120 .
- the epitaxy process may use molecular beam epitaxy, vapor-phase epitaxy (VPE), ultra-high vacuum CVD (UHV-CVD)) or other suitable techniques.
- the epitaxy process may use precursors which interact with the composition of the fin structure 110 .
- the precursors interact with silicon of the fin structure 110 .
- the precursors interact with silicon germanium (SiGe) of the fin structure 110 .
- the epitaxy structure 120 includes a first lattice plane 121 , a second lattice plane 123 , a third lattice plane 125 and a fourth lattice plane 127 .
- the first lattice plane 121 and the second lattice plane 123 form a top angle Z of the epitaxy structure 120 , and the top angle Z may be about 50 degrees to about 60 degrees.
- each of the first, second, third and fourth lattice planes 121 , 123 , 125 , 127 has Miller index (111).
- the epitaxy structure 120 has a maximum width d 2 that is about 2 folds to about 7 folds of the width d 1 of the fin structure 110 .
- the maximum width d 2 may be about 2.5 folds to about 6 folds of the width d 1 of the fin structure 110 .
- the maximum width d 2 of the epitaxy structure 120 may be about 25 nm to about 60 nm.
- the width d 2 may be about 25 nm to about 40 nm.
- the width d 2 may be about 30 nm to about 50 nm.
- the width d 2 may be about 40 nm to about 60 nm.
- a planar layer 130 is formed to cover the epitaxy structure 120 .
- the planar layer 130 may be formed by coating a layer of flowable oxide on the substrate 100 , and then an annealing process is performed to form the planar layer 130 . Therefore, the planar layer 130 may be an oxide layer, and have a substantially flat surface according to some examples of the present disclosure.
- the space under the lattice planes 125 , 127 (shown in FIG. 1B ) of the epitaxy structure 120 may be filled with the planar layer 130 .
- a portion of the planar layer 130 and a portion of the epitaxy structure 120 are removed such that a portion 122 of the epitaxy structure 120 is exposed out of the planar layer 130 .
- portions of the planar layer 130 and the epitaxy structure 120 may be removed by suitable processes such as for example chemical mechanical polishing (CMP) processes and/or etching processes.
- CMP chemical mechanical polishing
- a lattice plane 124 of the epitaxy structure 120 is formed after removing the portions of the planar layer 130 and the epitaxy structure 120 , in which the lattice plane 124 has Miller index (100).
- the exposed portion 122 of the epitaxy structure 120 has a width d 3 that is greater than the width d 1 (shown in FIG. 1A ) of the fin structure 110 , but the width d 3 of the exposed portion 122 is less than the width d 2 (shown in FIG. 1B ) of the epitaxy structure 120 .
- the width d 3 may be ranged from about 10 nm to about 60 nm. In some examples, the width d 3 may be about 10 nm to about 30 nm. In yet some examples, the width d 3 may be about 20 nm to about 45 nm. In yet some examples, the width d 3 may be about 30 nm to about 60 nm.
- the exposed portion 122 of the epitaxy structure 120 still covers the top of the fin structure 110 , and a distance d 4 between the lattice plane 124 and the top of the fin structure 110 is ranged from about 5 nm to about 30 nm, for example. In some examples, the distance d 4 is ranged from about 5 nm to about 20 nm. In yet some examples, the distance d 4 is ranged from about 10 nm to about 30 nm.
- a masking layer 140 is formed over the exposed portion 122 of the epitaxy structure 120 .
- the masking layer 140 is formed of a patterned photoresist layer.
- the masking layer 140 a has a width d 5 that is greater than the width d 3 of the exposed portion 122 .
- the width d 5 of the masking layer 140 may be less than the width d 3 of the exposed portion 122 but is greater than the width d 1 of the fin structure 110 .
- the width d 5 of the masking layer 140 may be about 1.5 folds to about 4 folds of the width d 1 of the fin structure 110 .
- the width d 5 of the masking layer 140 may be greater than the width d 3 of the exposed portion 122 and less than the maximum width d 2 of the epitaxy structure 120 .
- the width d 5 may be ranged from about 10 nm to about 60 nm.
- the width d 5 may be about 10 nm to about 25 nm.
- the width d 5 may be about 15 nm to about 40 nm.
- the width d 5 may be about 25 nm to about 60 nm.
- the planar layer 130 and the epitaxy structure 120 are patterned by using the masking layer 140 , and thereby a remaining portion 130 a of the planar layer 130 and a remaining epitaxy structure 120 a are obtained.
- the pattern of the masking layer 140 is transferred to the planar layer 130 and the epitaxy structure 120 .
- anisotropic etching processes such as for example dry etching processes may be utilized.
- the etching process uses a mixture of HBr, Cl 2 and O 2 as an etchant.
- the remaining portion 130 a of the planar layer 130 includes a first portion 131 and a second portion 132 , and the first portion 131 is spaced apart from the second portion 132 by the remaining epitaxy structure 120 a.
- the first portion 131 is located between the masking layer 140 and the remaining epitaxy structure 120 a
- the second portion 132 is located between the remaining epitaxy structure 120 a and the substrate 100 .
- the operation of patterning the planar layer 130 and the epitaxy structure 120 includes forming lattice planes 126 and 128 on the remaining epitaxy structure 120 a. Both the lattice planes 126 and 128 have Miller index (110), and are positioned on opposite sides of the remaining epitaxy structure 120 a.
- the masking layer 140 and the remaining portion 130 a of the planar layer 130 are removed so that the remaining epitaxy structure 120 a is exposed.
- the lattice planes 121 , 123 are exposed, and thus forming slant planes on the remaining epitaxy structure 120 a.
- the lattice planes 125 , and 127 are exposed, and at least an undercut is formed under the lattice planes 125 and/or 127 .
- the remaining epitaxy structure 120 a includes lattice planes 121 , 123 , 125 , and 127 with Miller index (111), lattice plane 124 with Miller index (100), and lattice planes 126 and 128 with Miller index (110).
- the structure illustrated in FIG. 1G is partially removed to form a trimmed fin structure 110 a, as shown in FIG. 1H .
- the remaining epitaxy structure 120 a is removed, and further a portion of the fin structure 110 is removed so that the trimmed fin structure 110 a has a smaller width T 1 than the width d 1 (shown in FIG. 1A ) of the fin structure 110 .
- the width T 1 may be ranged from about 3 nm to about 20 nm. In some examples, the width T 1 may be about 3 nm to about 10 nm. In yet some examples, the width T 1 may be about 7 nm to about 12 nm.
- the width T 1 may be about 10 nm to about 20 nm.
- the operation of forming the trimmed fin structure 110 a includes applying a wet etching process.
- the wet etching process may use etchant including tetramethylammonium hydroxide (TMAH), surfactant and organic solvent.
- TMAH tetramethylammonium hydroxide
- the etching rate depends upon the orientations of the lattice planes. For instance, lattice planes with Miller index (100) have fast etching rates in the etching process, lattice planes with Miller index (110) have moderate etching rates, and lattice planes with Miller index (111) have slow etching rates. Significantly, the difference in etching rates between different lattice planes leads to the tip-top issue in typical fin-trimming approaches. Accordingly, the shape of the remaining epitaxy structure 120 a with certain lattice planes shown in FIG. 1G is configured to compensate the difference in etching rates between different lattice planes during the etching process.
- the portion between the lattice plane 124 and the top of the fin structure 110 is configured to compensate the rapid etching rate on the lattice plane with Miller index (100), and this portion may be controlled by the distance d 4 (shown in FIG. 1D ) between the lattice plane 124 and the top of the fin structure 110 . Therefore, the height of the fin structure 110 may be kept. Furthermore, the lattice planes 121 and 123 with Miller index (111) having slow etching rate are configured to avoid the tip-top issue, and therefore a flat top of the trimmed fin structure 110 a may be obtained.
- the side portion with the lattice planes 126 and 128 is configured to compensate the moderate etching rate on the lattice planes with Miller index (110), and this side portion may be managed by the width d 5 (shown in FIG. 1E ) of the masking layer 140 .
- the lattice planes 125 and 127 with Miller index (111) having slow etching rate may secure the shape of the bottom portion of the trimmed fin structure 110 a . Therefore, the trimmed fin structure 110 a illustrated in FIG. 1H exhibits a cross section of substantially trapezoidal shape with a flat top according to various embodiments of the present disclosure.
- the shape of the remaining epitaxy structure 120 a may be well controlled by the method illustrates in FIGS. 1A-1F , and more significantly the trimmed fin structure 110 a exhibits a substantially conformal shape in consistence with the original fin structure 110 , and provides an excellent electrical performance for active devices such as FinFETs.
- FIGS. 2A-2H are schematic cross-sectional views showing methods for trimming a fin structure according to various embodiments of the present disclosure.
- 2 A- 2 H the same or similar features are identified by the same reference numerals. These features are the same as or similar to like-numbered features described with respect to FIGS. 1A-1H . Therefore, these features are descried briefly to avoid repetition.
- a fin structure 110 is formed over a substrate 100 .
- the fin structure 110 has a width d 1 which is ranged from about 5 nm to about 25 nm.
- the width d 1 may be about 5 nm to about 15 nm.
- the width d 1 may be about 10 nm to about 20 nm.
- the width d 1 may be about 15 nm to about 25 nm.
- an epitaxy structure 120 is formed on the fin structure 110 .
- the epitaxy structure 120 includes the same material as the fin structure 110 so that semiconductor material may be epitaxially grown on the exposed surface of the fin structure 110 to form the epitaxy structure 120 .
- the epitaxy structure 120 includes a first lattice plane 121 , a second lattice plane 123 , a third lattice plane 125 and a fourth lattice plane 127 .
- Each of the first, second, third and fourth lattice planes 121 , 123 , 125 , 127 has a Miller index (111).
- the maximum width d 2 may be about 2.5 folds to about 6 folds of the width d 1 of the fin structure 110 .
- the maximum width d 2 of the epitaxy structure 120 may be about 25 nm to about 60 nm.
- the width d 2 may be about 25 nm to about 40 nm.
- the width d 2 may be about 30 nm to about 50 nm.
- the width d 2 may be about 40 nm to about 60 nm.
- Other features and details of the epitaxy structure 120 may be the same as those described above in connection with FIG. 1B .
- a planar layer 130 is subsequently formed to cover the epitaxy structure 120 .
- the planar layer 130 includes applying a flowable oxide on the substrate 130 , and therefore the space under the lattice planes 125 and 127 (shown in FIG. 2B ) of the epitaxy structure 120 may be filled with the planar layer 130 .
- Other features and details of the planar layer 130 may be the same as those described above in connection with FIG. 1C .
- a portion of the planar layer 130 and a portion of the epitaxy structure 120 are removed such that a portion 122 of the epitaxy structure 120 is exposed out of the planar layer 130 .
- a lattice plane 124 with Miller index (100) is formed on the exposed portion 122 of the epitaxy structure 120 after or during the operation of removing the portions of the planar layer 130 and the epitaxy structure 120 .
- the exposed portion 122 of the epitaxy structure 120 has a width d 3 that is greater than the width d 1 (shown in FIG. 2A ) of the fin structure 110 , but is less than the width d 2 (shown in FIG.
- the width d 3 may be ranged from about 10 nm to about 60 nm. In some examples, the width d 3 may be about 10 nm to about 30 nm. In yet some examples, the width d 3 may be about 20 nm to about 45 nm. In yet some examples, the width d 3 may be about 30 nm to about 60 nm. In yet some embodiments, a distance d 4 between the lattice plane 124 and the top of the fin structure 110 is ranged from about 5 nm to about 30 nm, for example. In some examples, the distance d 4 is ranged from about 5 nm to about 20 nm. In yet some examples, the distance d 4 is ranged from about 10 nm to about 30 nm. Other features and details of the planar layer 130 may be the same as those described above in connection with FIG. 1D .
- an epitaxy layer 150 is epitaxially grown on the exposed portion 122 of the epitaxy structure 120 .
- the epitaxy layer 150 includes the same material as the epitaxy structure 120 and the fin structure 110 .
- the epitaxy layer 150 may include semiconductor materials such as silicon, silicon germanium or the like.
- the epitaxy layer 150 is formed on the exposed portion 122 only so that the width d 6 of the epitaxy layer 150 is substantially the same as the width d 3 (shown in FIG. 2D ) of the exposed portion 122 .
- the width d 6 may be ranged from about 10 nm to about 60 nm.
- the width d 6 may be about 10 nm to about 30 nm. In yet some examples, the width d 6 may be about 20 nm to about 45 nm. In yet some examples, the width d 6 may be about 30 nm to about 60 nm.
- the epitaxy layer 150 may be epitaxially grown on the exposed portion 122 , and naturally no epitaxy layer is formed on the top surface of the planar layer 130 . In yet some embodiments, the top surface of the epitaxy layer 150 includes a lattice plane with Miller index (100).
- the epitaxy process may use molecular beam epitaxy, vapor-phase epitaxy (VPE), ultra-high vacuum CVD (UHV-CVD)) or other suitable techniques.
- the epitaxy process may use precursors which interact with the composition of exposed portion 122 of the epitaxy structure 120 .
- the precursors interact with silicon of the exposed portion 122 .
- the precursors interact with silicon germanium (SiGe) of the exposed portion 122 of the epitaxy structure 120 .
- the width d 6 of the epitaxy layer 150 is greater than the width d 1 of the fin structure 110 . In some examples, the width d 6 of the epitaxy layer 150 may be about 1.5 folds to about 4 folds of the width d 1 of the fin structure 110 . In yet some embodiments, the width d 6 of the epitaxy layer 150 is less than the maximum width d 2 of the epitaxy structure 120 .
- the planar layer 130 and the epitaxy structure 120 are patterned, and thereby a remaining portion 130 a of the planar layer 130 and a remaining epitaxy structure 120 a are obtained.
- the epitaxy layer 150 is used as a hard mask to pattern the planar layer 130 and the epitaxy structure 120 .
- the epitaxy layer 150 is partially removed in the operation of patterning the planar layer 130 and the epitaxy structure 120 , and a lattice plane 151 with Miller index (100) is formed on the top surface of the remaining epitaxy layer 150 a.
- the operation of patterning the planar layer 130 and the epitaxy structure 120 includes forming lattice planes 126 and 128 on the remaining epitaxy structure 120 a. Both the lattice planes 126 and 128 have Miller index (110), and are positioned on opposite sides of the remaining epitaxy structure 120 a. In yet some embodiments, the remaining portion 130 a of the planar layer 130 is positioned between the substrate 100 and the remaining epitaxy structure 120 a. Any suitable anisotropic etching processes may be used to pattern the planar layer 130 and the epitaxy structure 120 . In examples, the patterning operation includes applying a dry etching process using a mixture of HBr, Cl 2 and O 2 as an etchant.
- the remaining portion 130 a of the planar layer 130 is removed.
- the lattice planes 125 and 127 are exposed, and at least an undercut 160 of the remaining epitaxy structure 120 a is formed under the lattice planes 125 and/or 127 .
- the remaining portion 130 a of the planar layer 130 is removed by wet etching processes.
- any etchant suitable for removing oxide may be used in the wet etching process.
- the structure illustrated in FIG. 2G is partially removed to form a trimmed fin structure 110 a, as shown in FIG. 2H .
- the remaining epitaxy structure 120 a is removed, the remaining epitaxy layer 150 a is partially or completely removed, and further a portion of the fin structure 110 is removed so that the trimmed fin structure 110 a has a smaller width T 1 than the width d 1 (shown in FIG. 2A ) of the fin structure 110 .
- the width T 1 may be ranged from about 3 nm to about 20 nm. In some examples, the width T 1 may be about 3 nm to about 10 nm.
- the width T 1 may be about 7 nm to about 12 nm. In yet some examples, the width T 1 may be about 10 nm to about 20 nm.
- the operation of forming the trimmed fin structure 110 a includes applying a wet etching process.
- the wet etching process may use etchant including tetramethylammonium hydroxide (TMAH), surfactant and organic solvent. The etching rate depends upon the orientations of the lattice planes.
- TMAH tetramethylammonium hydroxide
- lattice planes with Miller index (100) have fast etching rates in the etching process
- lattice planes with Miller index (110) have moderate etching rates
- lattice planes with Miller index (111) have slow etching rates.
- the difference in etching rates between different lattice planes leads to the tip-top issue in general fin-trimming approaches.
- the shape of the remaining epitaxy structure 120 a with certain lattice planes shown in FIG. 2G is configured to compensate the difference in etching rates between different lattice planes during the etching process.
- the trimmed fin structure 110 a illustrated in Fig, 2 H exhibits a cross section of substantially rectangular shape according to various embodiments of the present disclosure.
- the thickness and width of the epitaxy layer 150 may be independently controlled through the operations illustrated in FIG. 2D and FIG. 2E , and therefore not only avoid the tip-top issue but also modify the sidewall profile of the trimmed fin structure 110 a.
- the epitaxy layer 150 (or the remaining epitaxy layer 150 a ) may compensate the rapid etching rate on the lattice plane with Miller index (100). Therefore, a flat top and a height of the trimmed fin structure 110 a may be secured.
- the side portion with the lattice planes 126 and 128 may compensate the moderate etching rate on the lattice planes with Miller index (110).
- the lattice planes 125 , and 127 with Miller index (111) having slow etching rate may secure the shape of the bottom portion of the trimmed fin structure 110 a. Consequently, after etching the structure illustrated in FIG. 2G , the trimmed fin structure 110 a shows a cross section of substantially rectangular shape, as shown in FIG. 2H .
- FIGS. 3A-3D are perspective views schematically illustrating other features formed in various fabrication stages according to various embodiments of the present disclosure.
- the fin structure 110 a may optionally include a strain-inducing layer 202 formed thereon so as to increase the carrier mobility.
- the strain-inducing layer 202 may contain suitable material and induce a certain strain such as a compressive strain or a tensile strain, depending upon the type of the device being fabricated, such as a p-channel FETs (PFETs) or an re-channel FETs (NFETs).
- PFETs p-channel FETs
- NFETs re-channel FETs
- a gate structure 204 may be formed over a portion of the fin structure 110 a, and the gate structure 204 traverses the fin structure 110 a.
- the gate structure 204 may include a gate electrode and a gate dielectric layer.
- the gate dielectric layer may be made of dielectric material such as for example silicon oxide, silicon nitride, high-k dielectric material, and/or other suitable dielectric material. Examples of high-k dielectric material include, but are limited to, HfZrO, HfSiON, HfTaO, HfSiO, HfTiO, HfO 2 , zirconium oxide, aluminum oxide, or the like.
- the gate electrode may include any suitable material such as for example polysilicon, copper, titanium, aluminum, tantalum, tungsten, molybdenum, nickel silicide, cobalt silicide, or other suitable materials.
- the gate structure 204 may further include spacers 206 , as illustrated in FIG. 3A .
- the spacers 206 may be formed by any suitable process to any suitable thickness.
- the spacers 206 may include a dielectric material such as for example silicon nitride, silicon carbide, silicon oxynitride, or the like.
- doped regions such as source and drain regions may be formed in the fin structure 110 a according to some embodiments of the present disclosure.
- the gate structure 204 traversing the fin structure 110 a may separate the doped source and drain regions.
- the source and drain regions may include lightly doped regions and/or heavily doped source.
- the doping species depend on the type of the device being fabricated, such as a p-channel FETs (PFETs) or an n-channel FETs (NFETs).
- the doped source and drain regions may be formed by implantation processes, diffusion process, and/or other suitable processes.
- an annealing process may further be performed to activate the source and drain regions.
- the annealing processes may be, for example, a laser annealing process, a rapid thermal annealing (RTA) process, and/or other suitable annealing processes.
- RTA rapid thermal annealing
- a capping layer 208 may be formed over both the fin structure 110 a and the gate structure 204 .
- the capping layer 212 may include materials such as for example silicon oxide, silicon oxynitride (SiON), silicon nitride, SiC, SiOC, spin-on glass (SOG), a low-k material, or the like.
- CMP chemical mechanical polishing
- the CMP process may be performed until a portion of the gate structure 204 are exposed.
- one or more openings 210 are formed in the capping layer 208 to expose portions of the fin structure 110 a.
- the openings 210 may be formed by any conventional method such as for example photolithography and etching approaches.
- an epitaxial layer 212 may be grown on the exposed portions of the fin structure 110 a to form raised source and drain reasons.
- the epitaxial layer 212 may be grown over the exposed portions of the fin structure 110 a within the opening 210 using one or more epitaxy processes. Any suitable epitaxy processes may be employed to form the epitaxial layer 212 .
- vapor-phase epitaxy (VPE), ultra-high vacuum CVD (UHV-CVD), molecular beam epitaxy or other suitable processes may be used.
- the epitaxy process may use gaseous and/or liquid precursors, which interact with the composition of the fin structure 110 a.
- the epitaxial layer 212 may contain silicon formed by silicon epitaxial deposition processes according to some embodiments of the present disclosure. In yet some embodiments, the epitaxial layer 212 may contain silicon germanium (SiGe). Additionally, the epitaxial layer 212 may be a doped epitaxial layer in some examples of the present disclosure. For example, the epitaxial layer 212 may include a silicon epitaxial layer doped with phosphorous. Further, the doped epitaxial layer may have a gradient doping profile. In yet some examples, a CMP process may be subsequently performed to planarize the epitaxial layer 212 .
- interconnect metal routing layer an inter-layer dielectric (ILD) layers, via contacts, inter-metal dielectric (IMD) layers and metallic connecting wire and/or other suitable features, according to various embodiments of the present disclosure.
- ILD inter-layer dielectric
- Advantages of various embodiments of the present disclosure include providing novel methods of trimming fin structures for active devices such as FinFETs.
- the methods disclosed herein provide an excellent shape of the fin structure, and therefore the FinFET exhibits excellent electrical performances such as for example a low leakage current and a high ratio of turn-on current to turn-off current (I on /I off ).
- the epitaxy structure with certain shapes and lattice planes disclosed herein compensates the difference in etching rates between different lattice planes during the etching process, and thereby obtaining an excellent cross section of the fin structure.
- a method includes the operations described below.
- a fin structure is formed over a substrate.
- An epitaxy structure is formed on the fin structure.
- a planar layer is formed to cover the epitaxy structure. Portions of the planar layer and the epitaxy structure are removed such that a portion of the epitaxy structure is exposed out of the planar layer.
- a masking layer is formed over the exposed portion of the epitaxy structure.
- the planar layer and the epitaxy structure are patterned by using the masking layer, and thereby a remaining portion of the planar layer and a remaining epitaxy structure are obtained.
- the masking layer and the remaining portion of the planar layer are removed. Thereafter, the remaining epitaxy structure and a portion of the fin structure are removed so as to form a trimmed fin structure.
- a method includes the operations described below.
- a fin structure is formed over a substrate.
- An epitaxy structure is formed on the fin structure.
- a planar layer is formed to cover the epitaxy structure. Portions of the planar layer and the epitaxy structure are removed such that a portion of the epitaxy structure is exposed out of the planar layer.
- An epitaxy layer is epitaxially grown on the exposed portion of the epitaxy structure.
- the planar layer and the epitaxy structure are patterned so that a remaining portion of the planar layer and a remaining epitaxy structure are obtained. The remaining portion of the planar layer is removed. Thereafter, the remaining epitaxy structure and portions of the epitaxy layer and the fin structure are removed so as to form a trimmed fin structure.
- a method includes the operations described below.
- a fin structure is formed over a substrate.
- An epitaxy structure is epitaxially grown on the fin structure such that fin structure is clad in the epitaxy structure.
- the epitaxy structure includes a first lattice plane with Miller index (111), a second lattice plane with Miller index (100) and a third lattice plane with Miller index (110), and the first lattice plane with Miller index (111) forms an undercut of the epitaxy structure.
- the epitaxy structure and a portion of the fin structure are subsequently removed to obtain a trimmed fin structure.
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Abstract
Description
- The semiconductor integrated circuit (IC) industry has experienced rapid growth. Technological progress in IC manufacture has produced several generations of ICs, and each generation fabricates smaller and more complex circuits than the previous generation. Currently, the semiconductor industry has progressed into nanometer technology nodes for higher device density and better electrical performance, and a variety of challenges from fabrication and design have led semiconductor technologies to three dimensional designs, such as fin-like field effect transistors (FinFETs). A typical FinFET is fabricated with a thin “fin” extending on a substrate. The channel of the FinFET is formed in the fin. In addition, a gate is formed to wrap the fin, and therefore a tri-gate structure is fabricated. It is beneficial to have a gate on three sides of the channel that allows the gate to control the channel from several sides. FinFET devices further include strained source/drain features to enhance carrier mobility and improve device performance. However, as device scaling down continues, conventional techniques have not been entirely satisfactory in all respects.
- Aspects of the present disclosure are best understood from the following detailed description when read with the accompanying figures. It is noted that, in accordance with the standard practice in the industry, various features are not drawn to scale. In fact, the dimensions of the various features may be arbitrarily increased or reduced for clarity of discussion.
-
FIGS. 1A-1H are schematic cross-sectional views showing methods for trimming a fin structure according to various embodiments of the present disclosure. -
FIGS. 2A-2H are schematic cross-sectional views showing methods for trimming a fin structure according to various embodiments of the present disclosure. -
FIGS. 3A-3D are perspective views schematically illustrating other features of an integrated circuit device formed in various fabrication stages according to various embodiments of the present disclosure. - The following disclosure provides many different embodiments, or examples, for implementing different features of the provided subject matter. Specific examples of components and arrangements are described below to simplify the present disclosure. These are, of course, merely examples and are not intended to be limiting. For example, the formation of a first feature over or on a second feature in the description that follows may include embodiments in which the first and second features are formed in direct contact, and may also include embodiments in which additional features may be formed between the first and second features, such that the first and second features may not be in direct contact. In addition, the present disclosure may repeat reference numerals and/or letters in the various examples. This repetition is for the purpose of simplicity and clarity and does not in itself dictate a relationship between the various embodiments and/or configurations discussed.
- Further, spatially relative terms, such as “under,” “below,” “lower,” “above,” “upper”, “on” and the like, may be used herein for ease of description to describe one element or feature's relationship to another element(s) or feature(s) as illustrated in the figures. The spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures. The apparatus may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein may likewise be interpreted accordingly.
- The present disclosure relates generally to a method of trimming a fin structure for an active device such as for example a fin-like field effect transistor (FinFET). In the FinFET, when the width of the fin structure is less than certain dimension such as for example 16 nm, the carrier mobility of the FinFET is unsatisfied, and a strain inducing layer covering the fin structure is used to enhance the carrier mobility. Nevertheless, when the strain inducing layer is formed on the fin structure, the width of the fin structure is unfavorably increased. Accordingly, in order to shrink the fin width, the fin structure is trimmed prior to forming the strain inducing layer. However, conventional fin-trimming techniques suffer problems in that a tip-top is formed on the top of the fin structure, and that leads to a poor electrical performance.
- Accordingly, the present disclosure provides a novel method of trimming a fin structure that at least resolves the issue of the tip-top. Various embodiments of the present disclosure will be described in detail hereinafter.
-
FIGS. 1A-1H are schematic cross-sectional views showing methods for trimming a fin structure according to various embodiments of the present disclosure. - As shown in
FIG. 1A , afin structure 110 is formed over asubstrate 100. According to various embodiments, thesubstrate 100 includes semiconductor material. In some embodiments, thesubstrate 100 may be a silicon-on-insulator (SOI) substrate. The SOI substrate may be fabricated using any suitable methods. For example, the SOI substrate can be formed using separation by implantation of oxygen, wafer bonding, or other methods. In some embodiments, thesubstrate 100 may be a bulk silicon substrate. In yet some embodiments, thesubstrate 100 include an elementary semiconductor such as for example germanium or silicon in a crystalline structure. In yet some embodiments, thesubstrate 100 include a compound semiconductor such as for example gallium arsenic, silicon carbide, indium phosphide, gallium phosphide or indium antimonide, or combinations thereof. Furthermore, in some examples, thesubstrate 100 may include isolation structures, such as for example shallow trench isolation structures. The isolation structure may surround thefin structure 110, so that thefin structure 110 may be isolated from other features. In addition, thesubstrate 100 may include various doped regions and other features according to some embodiments of the present disclosure. - According to various embodiments of the present disclosure, the
fin structure 110 includes crystalline silicon. In some embodiments, the top surface of thefin structure 110 has a lattice plane with Miller index (100), and the sidewall of thefin structure 110 has a lattice plane with Miller index (110). In yet some embodiments, thefin structure 110 may include a lower part containing silicon (Si) and an upper part containing silicon germanium (SiGe). In yet some embodiments, thefin structure 110 may be doped during deposition by adding impurities to the source/drain material of the epitaxy process or subsequent to its deposition process by an ion implantation process. In various examples, thefin structure 110 has a width d1 which is ranged from about 5 nm to about 25 nm. In some examples, the width d1 may be about 5 nm to about 15 nm. In yet some examples, the width d1 may be about 10 nm to about 20 nm. In yet some examples, the width d1 may be about 15 nm to about 25 nm. One skilled in the art will appreciate that asingle fin structure 110 is shown for illustrative purposes only. As such, some embodiments may include a plurality offin structures 110. - Referring to
FIG. 1B , anepitaxy structure 120 is formed on thefin structure 110. In various embodiments, theepitaxy structure 120 includes the same material as thefin structure 110 so that semiconductor material may be epitaxially grown on the exposed surface of thefin structure 110 to form theepitaxy structure 120. In some embodiments, the epitaxy process may use molecular beam epitaxy, vapor-phase epitaxy (VPE), ultra-high vacuum CVD (UHV-CVD)) or other suitable techniques. The epitaxy process may use precursors which interact with the composition of thefin structure 110. In some examples, the precursors interact with silicon of thefin structure 110. In yet some examples, the precursors interact with silicon germanium (SiGe) of thefin structure 110. - In some embodiments, the
epitaxy structure 120 includes afirst lattice plane 121, asecond lattice plane 123, athird lattice plane 125 and afourth lattice plane 127. In some examples, thefirst lattice plane 121 and thesecond lattice plane 123 form a top angle Z of theepitaxy structure 120, and the top angle Z may be about 50 degrees to about 60 degrees. In yet some examples, each of the first, second, third and fourth lattice planes 121, 123, 125, 127 has Miller index (111). - In yet some embodiments, the
epitaxy structure 120 has a maximum width d2 that is about 2 folds to about 7 folds of the width d1 of thefin structure 110. In some examples, the maximum width d2 may be about 2.5 folds to about 6 folds of the width d1 of thefin structure 110. For example, the maximum width d2 of theepitaxy structure 120 may be about 25 nm to about 60 nm. In some examples, the width d2 may be about 25 nm to about 40 nm. In yet some examples, the width d2 may be about 30 nm to about 50 nm. In yet some examples, the width d2 may be about 40 nm to about 60 nm. - Subsequently, as shown in
FIG. 1C , aplanar layer 130 is formed to cover theepitaxy structure 120. In some embodiments, theplanar layer 130 may be formed by coating a layer of flowable oxide on thesubstrate 100, and then an annealing process is performed to form theplanar layer 130. Therefore, theplanar layer 130 may be an oxide layer, and have a substantially flat surface according to some examples of the present disclosure. Furthermore, in some embodiments of the present disclosure, the space under the lattice planes 125, 127 (shown inFIG. 1B ) of theepitaxy structure 120 may be filled with theplanar layer 130. - Thereafter, as illustrated in
FIG. 1D , a portion of theplanar layer 130 and a portion of theepitaxy structure 120 are removed such that aportion 122 of theepitaxy structure 120 is exposed out of theplanar layer 130. In some embodiments, portions of theplanar layer 130 and theepitaxy structure 120 may be removed by suitable processes such as for example chemical mechanical polishing (CMP) processes and/or etching processes. In some embodiments, alattice plane 124 of theepitaxy structure 120 is formed after removing the portions of theplanar layer 130 and theepitaxy structure 120, in which thelattice plane 124 has Miller index (100). - In some embodiments, the exposed
portion 122 of theepitaxy structure 120 has a width d3 that is greater than the width d1 (shown inFIG. 1A ) of thefin structure 110, but the width d3 of the exposedportion 122 is less than the width d2 (shown inFIG. 1B ) of theepitaxy structure 120. For instance, the width d3 may be ranged from about 10 nm to about 60 nm. In some examples, the width d3 may be about 10 nm to about 30 nm. In yet some examples, the width d3 may be about 20 nm to about 45 nm. In yet some examples, the width d3 may be about 30 nm to about 60 nm. In yet some embodiments, the exposedportion 122 of theepitaxy structure 120 still covers the top of thefin structure 110, and a distance d4 between thelattice plane 124 and the top of thefin structure 110 is ranged from about 5 nm to about 30 nm, for example. In some examples, the distance d4 is ranged from about 5 nm to about 20 nm. In yet some examples, the distance d4 is ranged from about 10 nm to about 30 nm. - As illustrated in
FIG. 1E , amasking layer 140 is formed over the exposedportion 122 of theepitaxy structure 120. In some embodiments, themasking layer 140 is formed of a patterned photoresist layer. In examples, the masking layer 140 a has a width d5 that is greater than the width d3 of the exposedportion 122. In yet some embodiments, however, the width d5 of themasking layer 140 may be less than the width d3 of the exposedportion 122 but is greater than the width d1 of thefin structure 110. In yet some embodiments, the width d5 of themasking layer 140 may be about 1.5 folds to about 4 folds of the width d1 of thefin structure 110. In yet some embodiments, the width d5 of themasking layer 140 may be greater than the width d3 of the exposedportion 122 and less than the maximum width d2 of theepitaxy structure 120. Particularly, the width d5 may be ranged from about 10 nm to about 60 nm. In some examples, the width d5 may be about 10 nm to about 25 nm. In yet some examples, the width d5 may be about 15 nm to about 40 nm. In yet some examples, the width d5 may be about 25 nm to about 60 nm. - Thereafter, as illustrated in
FIG. 1F , theplanar layer 130 and theepitaxy structure 120 are patterned by using themasking layer 140, and thereby a remainingportion 130 a of theplanar layer 130 and a remainingepitaxy structure 120 a are obtained. In the operation of patterning theplanar layer 130 and theepitaxy structure 120, the pattern of themasking layer 140 is transferred to theplanar layer 130 and theepitaxy structure 120. For instance, anisotropic etching processes such as for example dry etching processes may be utilized. In examples, the etching process uses a mixture of HBr, Cl2 and O2 as an etchant. In some embodiments, the remainingportion 130 a of theplanar layer 130 includes afirst portion 131 and asecond portion 132, and thefirst portion 131 is spaced apart from thesecond portion 132 by the remainingepitaxy structure 120 a. In some examples, thefirst portion 131 is located between themasking layer 140 and the remainingepitaxy structure 120 a, whereas thesecond portion 132 is located between the remainingepitaxy structure 120 a and thesubstrate 100. In yet some embodiments, the operation of patterning theplanar layer 130 and theepitaxy structure 120 includes forming 126 and 128 on the remaininglattice planes epitaxy structure 120 a. Both the lattice planes 126 and 128 have Miller index (110), and are positioned on opposite sides of the remainingepitaxy structure 120 a. - As shown in
FIG. 1G , themasking layer 140 and the remainingportion 130 a of theplanar layer 130 are removed so that the remainingepitaxy structure 120 a is exposed. In some embodiments, when thefirst portion 131 of the remainingportion 130 a of theplanar layer 130 is removed, the lattice planes 121, 123 are exposed, and thus forming slant planes on the remainingepitaxy structure 120 a. In yet some embodiments, when thesecond portion 132 of the remainingportion 130 a of theplanar layer 130 is removed, the lattice planes 125, and 127 are exposed, and at least an undercut is formed under the lattice planes 125 and/or 127. In yet some embodiments, the remainingepitaxy structure 120 a includes lattice planes 121, 123, 125, and 127 with Miller index (111),lattice plane 124 with Miller index (100), and 126 and 128 with Miller index (110).lattice planes - Subsequently, the structure illustrated in
FIG. 1G is partially removed to form a trimmedfin structure 110 a, as shown inFIG. 1H . Specifically, the remainingepitaxy structure 120 a is removed, and further a portion of thefin structure 110 is removed so that the trimmedfin structure 110 a has a smaller width T1 than the width d1 (shown inFIG. 1A ) of thefin structure 110. For instance, the width T1 may be ranged from about 3 nm to about 20 nm. In some examples, the width T1 may be about 3 nm to about 10 nm. In yet some examples, the width T1 may be about 7 nm to about 12 nm. In yet some examples, the width T1 may be about 10 nm to about 20 nm. In some embodiments, the operation of forming the trimmedfin structure 110 a includes applying a wet etching process. For examples, the wet etching process may use etchant including tetramethylammonium hydroxide (TMAH), surfactant and organic solvent. - For many semiconductor materials such as silicon, silicon germanium or the like, the etching rate depends upon the orientations of the lattice planes. For instance, lattice planes with Miller index (100) have fast etching rates in the etching process, lattice planes with Miller index (110) have moderate etching rates, and lattice planes with Miller index (111) have slow etching rates. Significantly, the difference in etching rates between different lattice planes leads to the tip-top issue in typical fin-trimming approaches. Accordingly, the shape of the remaining
epitaxy structure 120 a with certain lattice planes shown inFIG. 1G is configured to compensate the difference in etching rates between different lattice planes during the etching process. For example, the portion between thelattice plane 124 and the top of thefin structure 110 is configured to compensate the rapid etching rate on the lattice plane with Miller index (100), and this portion may be controlled by the distance d4 (shown inFIG. 1D ) between thelattice plane 124 and the top of thefin structure 110. Therefore, the height of thefin structure 110 may be kept. Furthermore, the lattice planes 121 and 123 with Miller index (111) having slow etching rate are configured to avoid the tip-top issue, and therefore a flat top of the trimmedfin structure 110 a may be obtained. In addition, the side portion with the lattice planes 126 and 128 is configured to compensate the moderate etching rate on the lattice planes with Miller index (110), and this side portion may be managed by the width d5 (shown inFIG. 1E ) of themasking layer 140. Moreover, the lattice planes 125 and 127 with Miller index (111) having slow etching rate may secure the shape of the bottom portion of the trimmedfin structure 110 a. Therefore, the trimmedfin structure 110 a illustrated inFIG. 1H exhibits a cross section of substantially trapezoidal shape with a flat top according to various embodiments of the present disclosure. - Accordingly, the shape of the remaining
epitaxy structure 120 a may be well controlled by the method illustrates inFIGS. 1A-1F , and more significantly the trimmedfin structure 110 a exhibits a substantially conformal shape in consistence with theoriginal fin structure 110, and provides an excellent electrical performance for active devices such as FinFETs. -
FIGS. 2A-2H are schematic cross-sectional views showing methods for trimming a fin structure according to various embodiments of the present disclosure. In 2A-2H, the same or similar features are identified by the same reference numerals. These features are the same as or similar to like-numbered features described with respect toFIGS. 1A-1H . Therefore, these features are descried briefly to avoid repetition. - As shown in
FIG. 2A , afin structure 110 is formed over asubstrate 100. Other features and details of thesubstrate 100 and thefin structure 110 may be the same as those described above in connection withFIG. 1A . In various examples, thefin structure 110 has a width d1 which is ranged from about 5 nm to about 25 nm. In some examples, the width d1 may be about 5 nm to about 15 nm. In yet some examples, the width d1 may be about 10 nm to about 20 nm. In yet some examples, the width d1 may be about 15 nm to about 25 nm. - Referring to
FIG. 2B , anepitaxy structure 120 is formed on thefin structure 110. In some embodiments, theepitaxy structure 120 includes the same material as thefin structure 110 so that semiconductor material may be epitaxially grown on the exposed surface of thefin structure 110 to form theepitaxy structure 120. In some embodiments, theepitaxy structure 120 includes afirst lattice plane 121, asecond lattice plane 123, athird lattice plane 125 and afourth lattice plane 127. Each of the first, second, third and fourth lattice planes 121, 123, 125, 127 has a Miller index (111). In some embodiments, the maximum width d2 may be about 2.5 folds to about 6 folds of the width d1 of thefin structure 110. For example, the maximum width d2 of theepitaxy structure 120 may be about 25 nm to about 60 nm. In some examples, the width d2 may be about 25 nm to about 40 nm. In yet some examples, the width d2 may be about 30 nm to about 50 nm. In yet some examples, the width d2 may be about 40 nm to about 60 nm. Other features and details of theepitaxy structure 120 may be the same as those described above in connection withFIG. 1B . - With reference to
FIG. 2C , aplanar layer 130 is subsequently formed to cover theepitaxy structure 120. In some embodiments, theplanar layer 130 includes applying a flowable oxide on thesubstrate 130, and therefore the space under the lattice planes 125 and 127 (shown inFIG. 2B ) of theepitaxy structure 120 may be filled with theplanar layer 130. Other features and details of theplanar layer 130 may be the same as those described above in connection withFIG. 1C . - As illustrated in
FIG. 2D , a portion of theplanar layer 130 and a portion of theepitaxy structure 120 are removed such that aportion 122 of theepitaxy structure 120 is exposed out of theplanar layer 130. In some embodiments, alattice plane 124 with Miller index (100) is formed on the exposedportion 122 of theepitaxy structure 120 after or during the operation of removing the portions of theplanar layer 130 and theepitaxy structure 120. In some embodiments, the exposedportion 122 of theepitaxy structure 120 has a width d3 that is greater than the width d1 (shown inFIG. 2A ) of thefin structure 110, but is less than the width d2 (shown inFIG. 2B ) of theepitaxy structure 120. For instance, the width d3 may be ranged from about 10 nm to about 60 nm. In some examples, the width d3 may be about 10 nm to about 30 nm. In yet some examples, the width d3 may be about 20 nm to about 45 nm. In yet some examples, the width d3 may be about 30 nm to about 60 nm. In yet some embodiments, a distance d4 between thelattice plane 124 and the top of thefin structure 110 is ranged from about 5 nm to about 30 nm, for example. In some examples, the distance d4 is ranged from about 5 nm to about 20 nm. In yet some examples, the distance d4 is ranged from about 10 nm to about 30 nm. Other features and details of theplanar layer 130 may be the same as those described above in connection withFIG. 1D . - Referring to
FIG. 2E , anepitaxy layer 150 is epitaxially grown on the exposedportion 122 of theepitaxy structure 120. In some embodiments, theepitaxy layer 150 includes the same material as theepitaxy structure 120 and thefin structure 110. For example, theepitaxy layer 150 may include semiconductor materials such as silicon, silicon germanium or the like. In some embodiments, theepitaxy layer 150 is formed on the exposedportion 122 only so that the width d6 of theepitaxy layer 150 is substantially the same as the width d3 (shown inFIG. 2D ) of the exposedportion 122. Particularly, the width d6 may be ranged from about 10 nm to about 60 nm. In some examples, the width d6 may be about 10 nm to about 30 nm. In yet some examples, the width d6 may be about 20 nm to about 45 nm. In yet some examples, the width d6 may be about 30 nm to about 60 nm. Specifically, theepitaxy layer 150 may be epitaxially grown on the exposedportion 122, and naturally no epitaxy layer is formed on the top surface of theplanar layer 130. In yet some embodiments, the top surface of theepitaxy layer 150 includes a lattice plane with Miller index (100). In yet some embodiments, the epitaxy process may use molecular beam epitaxy, vapor-phase epitaxy (VPE), ultra-high vacuum CVD (UHV-CVD)) or other suitable techniques. In some examples, the epitaxy process may use precursors which interact with the composition of exposedportion 122 of theepitaxy structure 120. In some examples, the precursors interact with silicon of the exposedportion 122. In yet some examples, the precursors interact with silicon germanium (SiGe) of the exposedportion 122 of theepitaxy structure 120. - In some embodiments, the width d6 of the
epitaxy layer 150 is greater than the width d1 of thefin structure 110. In some examples, the width d6 of theepitaxy layer 150 may be about 1.5 folds to about 4 folds of the width d1 of thefin structure 110. In yet some embodiments, the width d6 of theepitaxy layer 150 is less than the maximum width d2 of theepitaxy structure 120. - As shown in
FIG. 2F , theplanar layer 130 and theepitaxy structure 120 are patterned, and thereby a remainingportion 130 a of theplanar layer 130 and a remainingepitaxy structure 120 a are obtained. In some embodiments, theepitaxy layer 150 is used as a hard mask to pattern theplanar layer 130 and theepitaxy structure 120. In examples, theepitaxy layer 150 is partially removed in the operation of patterning theplanar layer 130 and theepitaxy structure 120, and alattice plane 151 with Miller index (100) is formed on the top surface of the remainingepitaxy layer 150 a. In yet some embodiments, the operation of patterning theplanar layer 130 and theepitaxy structure 120 includes forming 126 and 128 on the remaininglattice planes epitaxy structure 120 a. Both the lattice planes 126 and 128 have Miller index (110), and are positioned on opposite sides of the remainingepitaxy structure 120 a. In yet some embodiments, the remainingportion 130 a of theplanar layer 130 is positioned between thesubstrate 100 and the remainingepitaxy structure 120 a. Any suitable anisotropic etching processes may be used to pattern theplanar layer 130 and theepitaxy structure 120. In examples, the patterning operation includes applying a dry etching process using a mixture of HBr, Cl2 and O2 as an etchant. - With reference to
FIG. 2G , the remainingportion 130 a of theplanar layer 130 is removed. According to some embodiments of the present disclosure, when the remainingportion 130 a of theplanar layer 130 is removed, the lattice planes 125 and 127 are exposed, and at least an undercut 160 of the remainingepitaxy structure 120 a is formed under the lattice planes 125 and/or 127. In some embodiments, the remainingportion 130 a of theplanar layer 130 is removed by wet etching processes. For example, any etchant suitable for removing oxide may be used in the wet etching process. - As illustrated in
FIG. 2H , the structure illustrated inFIG. 2G is partially removed to form a trimmedfin structure 110 a, as shown inFIG. 2H . In some embodiment, the remainingepitaxy structure 120 a is removed, the remainingepitaxy layer 150 a is partially or completely removed, and further a portion of thefin structure 110 is removed so that the trimmedfin structure 110 a has a smaller width T1 than the width d1 (shown inFIG. 2A ) of thefin structure 110. For instance, the width T1 may be ranged from about 3 nm to about 20 nm. In some examples, the width T1 may be about 3 nm to about 10 nm. In yet some examples, the width T1 may be about 7 nm to about 12 nm. In yet some examples, the width T1 may be about 10 nm to about 20 nm. In some embodiments, the operation of forming the trimmedfin structure 110 a includes applying a wet etching process. For examples, the wet etching process may use etchant including tetramethylammonium hydroxide (TMAH), surfactant and organic solvent. The etching rate depends upon the orientations of the lattice planes. For example, lattice planes with Miller index (100) have fast etching rates in the etching process, lattice planes with Miller index (110) have moderate etching rates, and lattice planes with Miller index (111) have slow etching rates. Significantly, the difference in etching rates between different lattice planes leads to the tip-top issue in general fin-trimming approaches. Accordingly, the shape of the remainingepitaxy structure 120 a with certain lattice planes shown inFIG. 2G is configured to compensate the difference in etching rates between different lattice planes during the etching process. - The trimmed
fin structure 110 a illustrated in Fig, 2H exhibits a cross section of substantially rectangular shape according to various embodiments of the present disclosure. Significantly the thickness and width of theepitaxy layer 150 may be independently controlled through the operations illustrated inFIG. 2D andFIG. 2E , and therefore not only avoid the tip-top issue but also modify the sidewall profile of the trimmedfin structure 110 a. In specifics, the epitaxy layer 150 (or the remainingepitaxy layer 150 a) may compensate the rapid etching rate on the lattice plane with Miller index (100). Therefore, a flat top and a height of the trimmedfin structure 110 a may be secured. In addition, the side portion with the lattice planes 126 and 128 may compensate the moderate etching rate on the lattice planes with Miller index (110). Also, the lattice planes 125, and 127 with Miller index (111) having slow etching rate may secure the shape of the bottom portion of the trimmedfin structure 110 a. Consequently, after etching the structure illustrated inFIG. 2G , the trimmedfin structure 110 a shows a cross section of substantially rectangular shape, as shown inFIG. 2H . - Other features may optionally be formed after the trimmed
fin structure 110 a is fabricated.FIGS. 3A-3D are perspective views schematically illustrating other features formed in various fabrication stages according to various embodiments of the present disclosure. - As shown in
FIG. 3A , in some embodiments, thefin structure 110 a may optionally include a strain-inducinglayer 202 formed thereon so as to increase the carrier mobility. The strain-inducinglayer 202 may contain suitable material and induce a certain strain such as a compressive strain or a tensile strain, depending upon the type of the device being fabricated, such as a p-channel FETs (PFETs) or an re-channel FETs (NFETs). - In some embodiments, a
gate structure 204 may be formed over a portion of thefin structure 110 a, and thegate structure 204 traverses thefin structure 110 a. In some embodiments, thegate structure 204 may include a gate electrode and a gate dielectric layer. The gate dielectric layer may be made of dielectric material such as for example silicon oxide, silicon nitride, high-k dielectric material, and/or other suitable dielectric material. Examples of high-k dielectric material include, but are limited to, HfZrO, HfSiON, HfTaO, HfSiO, HfTiO, HfO2, zirconium oxide, aluminum oxide, or the like. The gate electrode may include any suitable material such as for example polysilicon, copper, titanium, aluminum, tantalum, tungsten, molybdenum, nickel silicide, cobalt silicide, or other suitable materials. Thegate structure 204 may further includespacers 206, as illustrated inFIG. 3A . Thespacers 206 may be formed by any suitable process to any suitable thickness. In some examples, thespacers 206 may include a dielectric material such as for example silicon nitride, silicon carbide, silicon oxynitride, or the like. - In addition, before or after the
spacers 206 are formed, doped regions such as source and drain regions may be formed in thefin structure 110 a according to some embodiments of the present disclosure. Thegate structure 204 traversing thefin structure 110 a may separate the doped source and drain regions. The source and drain regions may include lightly doped regions and/or heavily doped source. The doping species depend on the type of the device being fabricated, such as a p-channel FETs (PFETs) or an n-channel FETs (NFETs). The doped source and drain regions may be formed by implantation processes, diffusion process, and/or other suitable processes. In some embodiments, an annealing process may further be performed to activate the source and drain regions. The annealing processes may be, for example, a laser annealing process, a rapid thermal annealing (RTA) process, and/or other suitable annealing processes. - As illustrated in
FIG. 3B , in some embodiments, acapping layer 208 may be formed over both thefin structure 110 a and thegate structure 204. Thecapping layer 212 may include materials such as for example silicon oxide, silicon oxynitride (SiON), silicon nitride, SiC, SiOC, spin-on glass (SOG), a low-k material, or the like. In some examples, chemical mechanical polishing (CMP) processes may be performed to planarize thecapping layer 208. In specifics, the CMP process may be performed until a portion of thegate structure 204 are exposed. - In yet some embodiments, as illustrated in
FIG. 3C , one ormore openings 210 are formed in thecapping layer 208 to expose portions of thefin structure 110 a. Theopenings 210 may be formed by any conventional method such as for example photolithography and etching approaches. - As illustrated in
FIG. 3D , in some embodiments, anepitaxial layer 212 may be grown on the exposed portions of thefin structure 110 a to form raised source and drain reasons. In specifics, theepitaxial layer 212 may be grown over the exposed portions of thefin structure 110 a within theopening 210 using one or more epitaxy processes. Any suitable epitaxy processes may be employed to form theepitaxial layer 212. For example, vapor-phase epitaxy (VPE), ultra-high vacuum CVD (UHV-CVD), molecular beam epitaxy or other suitable processes may be used. The epitaxy process may use gaseous and/or liquid precursors, which interact with the composition of thefin structure 110 a. In addition, theepitaxial layer 212 may contain silicon formed by silicon epitaxial deposition processes according to some embodiments of the present disclosure. In yet some embodiments, theepitaxial layer 212 may contain silicon germanium (SiGe). Additionally, theepitaxial layer 212 may be a doped epitaxial layer in some examples of the present disclosure. For example, theepitaxial layer 212 may include a silicon epitaxial layer doped with phosphorous. Further, the doped epitaxial layer may have a gradient doping profile. In yet some examples, a CMP process may be subsequently performed to planarize theepitaxial layer 212. - Other features may continuously be fabricated, including for example, forming an interconnect metal routing layer, an inter-layer dielectric (ILD) layers, via contacts, inter-metal dielectric (IMD) layers and metallic connecting wire and/or other suitable features, according to various embodiments of the present disclosure.
- It will be understood that, although the terms first, second, etc. may be used herein to describe various elements, these elements should not be limited by these terms. These terms are only used to distinguish one element from another. For example, a first element could be termed a second element, and, similarly, a second element could be termed a first element, without departing from the scope of the embodiments. As used herein, the term “and/or” includes any and all combinations of one or more of the associated listed items.
- Advantages of various embodiments of the present disclosure include providing novel methods of trimming fin structures for active devices such as FinFETs. The methods disclosed herein provide an excellent shape of the fin structure, and therefore the FinFET exhibits excellent electrical performances such as for example a low leakage current and a high ratio of turn-on current to turn-off current (Ion/Ioff). The epitaxy structure with certain shapes and lattice planes disclosed herein compensates the difference in etching rates between different lattice planes during the etching process, and thereby obtaining an excellent cross section of the fin structure.
- In accordance with one aspect of some embodiments, a method includes the operations described below. A fin structure is formed over a substrate. An epitaxy structure is formed on the fin structure. A planar layer is formed to cover the epitaxy structure. Portions of the planar layer and the epitaxy structure are removed such that a portion of the epitaxy structure is exposed out of the planar layer. A masking layer is formed over the exposed portion of the epitaxy structure. The planar layer and the epitaxy structure are patterned by using the masking layer, and thereby a remaining portion of the planar layer and a remaining epitaxy structure are obtained. The masking layer and the remaining portion of the planar layer are removed. Thereafter, the remaining epitaxy structure and a portion of the fin structure are removed so as to form a trimmed fin structure.
- In accordance with another aspect of some embodiments, a method includes the operations described below. A fin structure is formed over a substrate. An epitaxy structure is formed on the fin structure. A planar layer is formed to cover the epitaxy structure. Portions of the planar layer and the epitaxy structure are removed such that a portion of the epitaxy structure is exposed out of the planar layer. An epitaxy layer is epitaxially grown on the exposed portion of the epitaxy structure. The planar layer and the epitaxy structure are patterned so that a remaining portion of the planar layer and a remaining epitaxy structure are obtained. The remaining portion of the planar layer is removed. Thereafter, the remaining epitaxy structure and portions of the epitaxy layer and the fin structure are removed so as to form a trimmed fin structure.
- In accordance with another aspect of some embodiments, a method includes the operations described below. A fin structure is formed over a substrate. An epitaxy structure is epitaxially grown on the fin structure such that fin structure is clad in the epitaxy structure. The epitaxy structure includes a first lattice plane with Miller index (111), a second lattice plane with Miller index (100) and a third lattice plane with Miller index (110), and the first lattice plane with Miller index (111) forms an undercut of the epitaxy structure. The epitaxy structure and a portion of the fin structure are subsequently removed to obtain a trimmed fin structure.
- The foregoing outlines features of several embodiments so that those skilled in the art may better understand the aspects of the present disclosure. Those skilled in the art should appreciate that they may readily use the present disclosure as a basis for designing or modifying other processes and structures for carrying out the same purposes and/or achieving the same advantages of the embodiments introduced herein. Those skilled in the art should also realize that such equivalent constructions do not depart from the spirit and scope of the present disclosure, and that they may make various changes, substitutions, and alterations herein without departing from the spirit and scope of the present disclosure.
Claims (20)
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| US14/597,700 US9412850B1 (en) | 2015-01-15 | 2015-01-15 | Method of trimming fin structure |
| CN201510321483.XA CN106206314B (en) | 2015-01-15 | 2015-06-12 | The method for modifying fin structure |
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| CN106206314B (en) | 2019-07-16 |
| US9412850B1 (en) | 2016-08-09 |
| CN106206314A (en) | 2016-12-07 |
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