US20160141601A1

US20160141601A1 - High energy materials for a battery and methods for making and use

Info

Publication number: US20160141601A1
Application number: US15/008,252
Authority: US
Inventors: Cory O'Neill; Steven Kaye
Original assignee: Wildcat Discovery Technologies Inc
Current assignee: Wildcat Discovery Technologies Inc
Priority date: 2013-03-15
Filing date: 2016-01-27
Publication date: 2016-05-19
Also published as: JP2017092042A; EP2973804A1; KR20150120498A; JP6474779B2; WO2014144202A1; KR20170117237A; JP2016516281A; CN105051955A; EP2973804A4; US20150140206A1; EP2973804B1; CN105051955B

Abstract

A method of forming an electrode active material by reacting a metal fluoride and a reactant. The method includes a coating step and a comparatively low temperature annealing step. Also included is the electrode formed following the method.

Description

CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a continuation of U.S. patent application Ser. No. 14/604,013, having a filing date of Jan. 23, 2015 entitled “High Energy Materials for a Battery and Methods for Making and Use” which is a continuation-in-part of International Application No. PCT/US2014/028506, having an international filing date of Mar. 14, 2014 entitled “High Energy Materials For A Battery And Methods For Making And Use,” which claims priority to U.S. Provisional Application No. 61/786,602 filed Mar. 15, 2013 entitled “High Energy Materials For A Battery And Methods For Making And Use.” This application claims priority to and the benefit of each of these applications, and each application is incorporated herein by reference in its entirety.

BACKGROUND OF THE INVENTION

The present invention is in the field of battery technology, and more particularly in the area of materials for making high-energy electrodes for batteries, including metal-fluoride materials.
One type of battery consists of a negative electrode made primarily from lithium and a positive electrode made primarily from a compound containing a metal and fluorine. During discharge, lithium ions and electrons are generated from oxidation of the negative electrode while fluoride ions are produced from reduction of the positive electrode. The generated fluoride ions react with lithium ions near the positive electrode to produce a compound containing lithium and fluorine, which may deposit at the positive electrode surface.
Metal fluoride based batteries are an attractive energy storage technology because of their extremely high theoretical energy densities. For example, certain metal fluoride active materials can have theoretical energy densities greater than about 1600 Wh/kg or greater than about 7500 Wh/L. Further, metal fluorides have a relatively low raw material cost, for example less than about $10/kg. However, a number of technical challenges currently limit their widespread use and realization of their performance potential.
One challenge for certain metal fluoride materials is comparatively poor rate performance. Many metal fluoride active materials have electrochemical potentials greater than about 2.5 V because of their relatively large bandgap produced by the highly ionic bonding between the metal and fluorine, and in particular between a transition metal and fluorine. Unfortunately, one of the drawbacks to wide bandgap materials is the intrinsically low electronic conductivity that results from the wide bandgap. As a result of this low conductivity, discharge rates of less than 0.1 C are required in order to obtain full theoretical capacity. More typically, discharge rates of 0.05 C to 0.02 C are reported in the literature. Such low discharge rates limit the widespread use of metal fluoride active materials.
Another challenge for certain metal fluoride active materials is a significant hysteresis observed between the charge and discharge voltages during cycling. This hysteresis is typically on the order of about 1.0V to about 1.5V. While the origin of this hysteresis is uncertain, current evidence suggests that kinetic limitations imposed by low conductivity play an important role. Further, asymmetry in the reaction paths upon charge and discharge may also play a role. Since the electrochemical potential for many of the metal fluorides is on the order of 3.0V, this hysteresis of about 1.0V to about 1.5V limits the overall energy efficiency to approximately 50%.
Limited cycle life is another challenge for certain metal fluoride active materials. Although rechargeability has been demonstrated for many metal fluoride active materials, their cycle life is typically limited to tens of cycles and is also subject to rapid capacity fade. Two mechanisms are currently believed to limit the cycle life for the metal fluoride active materials: agglomeration of metallic nanoparticles and mechanical stress due to volume expansion. It is believed that metal fluoride active materials can cycle by virtue of the formation during lithiation of a continuous metallic network within a matrix of insulating LiF. As the number of cycles increases, the metal particles tend to accumulate together into larger, discrete particles. The larger agglomerated particles in turn create islands that are electrically disconnected from one another, thus reducing the capacity and ability to cycle the metal fluoride active materials. The second limitation to extended cycle life is the mechanical stress imparted to the binder materials by the metal fluoride particles as a result of the volume expansion that occurs during the conversion reaction. Over time, the binder is pulverized, compromising the integrity of the cathode. Notably, for the metal fluoride CuF₂, no demonstrations of rechargeability have been reported.
For CuF₂, an additional challenge prevents rechargeability. The potential required to recharge a CuF₂electrode is 3.55V. However, in typical electrolytes for lithium ion batteries, Cu metal oxidizes to Cu²⁺at approximately 3.4 V vs. Li/Li⁺. The oxidized copper can migrate to the anode, where it is irreversibly reduced back to Cu metal. As a result, Cu dissolution competes with the recharge of Cu+2LiF to CuF₂, preventing cycling of the cell. The Cu metal accumulating on the anode surface can increase the impedance and/or destroy the solid-electrolyte interphase (SEI) on the anode.
The following papers and patents are among the published literature on metal fluorides that employ mixed conductors that are not electrochemically active within the voltage window of the metal fluoride: Badway, F. et al., Chem. Mater., 2007, 19, 4129; Badway, F. et al., J. Electrochem. Soc,. 2007, 150, A1318; “Bismuth fluoride based nanocomposites as electrode materials” U.S. Pat. No. 7,947,392; “Metal Fluoride And Phosphate Nanocomposites As Electrode Materials” US 2008/0199772; “Copper fluoride based nanocomposites as electrode materials” US 2006/0019163; and “Bismuth oxyfluoride based nanocomposites as electrode materials” U.S. Pat. No. 8,039,149.
Certain embodiments of the present invention can be used to form electrochemical cells having metal fluoride active material that exhibit improved rate performance, improved energy efficiency, and improved cycle life when compared to prior batteries. Thus, these and other challenges can be addressed by embodiments of the present invention described below.

BRIEF SUMMARY OF THE INVENTION

Certain embodiments of the invention include a method of making a composition for use in forming a cathode for a battery. The method includes coating a metal fluoride material with a coating precursor material including a metal or a metal complex and annealing coated metal fluoride material, wherein at least a portion of the metal fluoride material and at least a portion of the coating undergo a phase change. The metal fluoride material is preferably CuF₂. The metal can be, for example, Ni, Ba, or Ta. The metal complex can be, for example a metal oxide, such as Al₂O₃, SiO₂, Ta₂O₅, TiO₂; a metal nitride, such as AlN, TaN; a metal silicate, such as ZrSiO₄; or other materials that are volatile enough to be evaporated and re-condensed onto a substrate. The annealing temperature is less than 450 degrees C., less than 400 degrees C., less than 325 degrees C., or less than 200 degrees C. Preferably, the annealing temperature is about 325 degrees C. The temperature is chosen such that it is sufficiently high for the metal complex to react with the metal fluoride, but not high enough to decompose the metal fluoride. Without such heat treatment and the resulting reaction, the material is not rechargeable, as is demonstrated by experiments described herein.
Certain embodiments of the invention include a composition formed by the methods disclosed herein. The composition is characterized by having reversible capacity. The composition can include particles with a grain size greater than 100 nm, 110 nm, 120 nm, or 130 nm. The composition can include a particle having a first phase and a coating on the particle having a second phase. Preferably, the first phase includes the metal fluoride and the second phase includes the metal oxide. The coating can be covalently bonded to the particle.
Certain embodiments of the invention include batteries having electrodes formed from the compositions disclosed herein, the method of making such batteries, and the method of use of such batteries.

BRIEF DESCRIPTION OF SEVERAL VIEWS OF THE DRAWINGS

FIG. 1 illustrates electrochemical characterization of different hybrid cathode formulations according to embodiments of the invention in which the content of a conductive precursor material is varied in the cathode.

FIG. 2 illustrates electrochemical characterization of a cathode formulation from FIG. 1 in which the voltage of a hybrid cathode according to embodiments of the invention is plotted against the capacity for the first and second cycles.

FIG. 3 illustrates electrochemical characterization of different hybrid cathode formulations according to embodiments of the invention in which the discharge is plotted as a function of cycle for 10 cycles.

FIG. 4 illustrates electrochemical characterization of a hybrid cathode formed from a metal fluoride and a reactant material according to certain embodiments. The cathode demonstrates rechargeability.

FIG. 5 illustrates a powder X-ray diffraction pattern of a material used to form a rechargeable metal fluoride cathode.

FIG. 6 illustrates second cycle discharge capacity for a variety of hybrid cathode materials used according to embodiments of the invention.

FIG. 7 illustrates second cycle discharge capacity for a hybrid cathode material used according to embodiments of the invention versus annealing temperature.

FIG. 8 illustrates second cycle the capacity retention and reversible capacity for cathode active materials formed from reacting 85 wt % CuF₂with 15 wt % of certain metal oxides (in this case NiO or TiO₂) at certain annealing temperatures.

FIG. 9 illustrates the second-cycle capacity retention and reversible capacity for cathode active materials formed from reacting 85 wt % CuF₂with 15 wt % of certain metal oxides (in this case NiO or TiO₂) for certain annealing times.

FIG. 10 illustrates the second-cycle capacity retention and reversible capacity for cathode active materials formed from reacting 85 wt %, 90 wt %, or 95 wt % CuF₂with 5 wt %, 10 wt %, 15 wt % of NiO.

FIG. 11 illustrates the second-cycle capacity retention and reversible capacity for cathode active materials formed from reacting 85 wt %, CuF₂with 15 wt % of NiO as a function of milling energy.

FIG. 12 illustrates the second-cycle capacity retention and reversible capacity for cathode active materials formed from reacting 85 wt %, CuF₂with 15 wt % of NiO as a function of milling time.

FIG. 13 illustrates the second cycle reversible capacity measured for various starting materials used to react with CuF₂.

FIG. 14 illustrates the second-cycle capacity retention and reversible capacity for cathode active materials formed from reacting CuF₂with nickel (II) acetylacetonate using various processing conditions.

FIG. 15 illustrates the capacity as a function of cycle for cathode active materials formed from reacting 85 wt %, CuF₂with 15 wt % of NiO and for a control material.

FIG. 16 illustrates a galvanostatic intermittent titration technique measurement for cathode active materials formed from reacting 85 wt %, CuF₂with 15 wt % of NiO.

FIG. 17 illustrates the capacity of full cells and half cells as a function of cycle for cathode active materials formed from reacting 85 wt %, CuF₂with 15 wt % of NiO.

FIG. 18 illustrates voltage traces of the full cell and half cells prepared as described in relation to FIG. 17.

FIG. 19 illustrates the capacity retention of full cells and half cells as a function of cycle for cathode active materials formed from reacting 85 wt %, CuF₂with 15 wt % of NiO.

FIG. 20 illustrates the second cycle reversible capacity measured for various coating precursor materials used to react with CuF₂.

DETAILED DESCRIPTION OF THE INVENTION

The following definitions apply to some of the aspects described with respect to some embodiments of the invention. These definitions may likewise be expanded upon herein. Each term is further explained and exemplified throughout the description, figures, and examples. Any interpretation of the terms in this description should take into account the full description, figures, and examples presented herein.
The singular terms “a,” “an,” and “the” include the plural unless the context clearly dictates otherwise. Thus, for example, reference to an object can include multiple objects unless the context clearly dictates otherwise.
The terms “substantially” and “substantial” refer to a considerable degree or extent. When used in conjunction with an event or circumstance, the terms can refer to instances in which the event or circumstance occurs precisely as well as instances in which the event or circumstance occurs to a close approximation, such as accounting for typical tolerance levels or variability of the embodiments described herein.
The term “about” refers to the range of values approximately near the given value in order to account for typical tolerance levels, measurement precision, or other variability of the embodiments described herein.
The terms “conductive,” “conductor,” “conductivity,” and the like refer to the intrinsic ability of a material to facilitate electron or ion transport and the process of doing the same. The terms include materials whose ability to conduct electricity may be less than typically suitable for conventional electronics applications but still greater than an electrically-insulating material.
The term “active material” and the like refers to the material in an electrode, particularly in a cathode, that donates, liberates, or otherwise supplies the conductive species during an electrochemical reaction in an electrochemical cell.
The term “transition metal” refers to a chemical element in groups 3 through 12 of the periodic table, including scandium (Sc), titanium (Ti), vanadium (V), chromium (Cr), manganese (Mn), iron (Fe), cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn), yttrium (Y), zirconium (Zr), niobium (Nb), molybdenum (Mo), technetium (Tc), ruthenium (Ru), rhodium (Rh), palladium (Pd), silver (Ag), cadmium (Cd), hafnium (Hf), tantalum (Ta), tungsten (W), rhenium (Re), osmium (Os), iridium (Ir), platinum (Pt), gold (Au), mercury (Hg), rutherfordium (Rf), dubnium (Db), seaborgium (Sg), bohrium (Bh), hassium (Hs), and meitnerium (Mt).
The term “halogen” refers to any of the chemical elements in group 17 of the periodic table, including fluorine (F), chlorine (Cl), bromine (Br), iodine (I), and astatine (At).
The term “chalcogen” refers to any of chemical elements in group 16 of the periodic table, including oxygen (O), sulfur (S), selenium (Se), tellurium (Te), and polonium (Po).
The term “alkali metal” refers to any of the chemical elements in group 1 of the periodic table, including lithium (Li), sodium (Na), potassium (K), rubidium (Rb), cesium (Cs), and francium (Fr).
The term “alkaline earth metals” refers to any of the chemical elements in group 2 of the periodic table, including beryllium (Be), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), and radium (Ra).
The term “rare earth element” refers to scandium (Sc), yttrium (Y), lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), promethium (Pm), samarium (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), and lutetium (Lu).
A rate “C” refers to either (depending on context) the discharge current as a fraction or multiple relative to a “1 C” current value under which a battery (in a substantially fully charged state) would substantially fully discharge in one hour, or the charge current as a fraction or multiple relative to a “1 C” current value under which the battery (in a substantially fully discharged state) would substantially fully charge in one hour.
In certain embodiments, a novel active material is prepared for use in a cathode with metal fluoride (MeF_x) active materials. In some embodiments, the novel active material, sometimes referred to herein as a hybrid material, is prepared by combining a metal fluoride and a metal complex, followed by heat treatment of the mixture under an inert atmosphere according to the Formula (I)
MeF_x+Me′_yX_z+heat (I)
According to certain embodiments, the heat treatment of the metal fluoride and metal complex causes a reaction to form a new phase according to the formula (II)
MeF_x+Me′_yX_z→Me_aMe′_bX_cF_d (II)
where x, y, z, a, b, and c depend on the identity and valence of the Me, Me′, and X. In some instances, 0<a≦1, 0<b≦1, 0≦c≦1, and 0≦d≦1. In other embodiments, the heat treatment causes the formation of covalent bonds between the metal fluoride and the metal complex, improving conductivity and passivating the surface.
Suitable metal complexes, which can act as precursors for the reaction described herein, for use in synthesizing the active material include, but are not limited to, MoO₃, MoO₂, NiO, CuO, VO₂, V₂O₅, TiO₂, Al₂O₃, SiO₂, LiFePO₄, LiMe_TPO₄(where Me_Tis one or more transition metal(s)), metal phosphates, and combinations thereof. According to embodiments of the invention, these oxides can be used in Formula (I).
It is understood that the synthetic route for achieving the active material may vary, and other such synthetic routes are within the scope of the disclosure. The material can be represented by Me_aMe′_bX_cF and in the examples herein is embodied by a Cu₃Mo₂O₉active material. Other active materials are within the scope of this disclosure, for example, NiCuO₂, Ni₂CuO₃, and Cu₃TiO₄.
The coating materials disclosed herein provide rechargeability to otherwise non-rechargeable metal fluoride materials. Without being bound by a particular theory or mechanism of action, the rechargeability may be due to the electrochemical properties of the novel hybrid material, the coating of the metal fluoride to prevent copper dissolution, or a more intimate interface between the metal fluoride and the coating material as a result of the heat treatment and reaction. Further, the novel hybrid material may provide a kinetic barrier to the Cu dissolution reaction, or to similar dissolution reactions for other metal fluoride materials to the extent such dissolution reactions occur in the cycling of electrochemical cells.
In the case of oxide-based hybrid materials, intimate mixing of the metal fluoride and the metal complex (or other suitable precursor material) and moderate heat treatment can be used to generate rechargeable electrode materials. Suitable coating precursors include materials that decompose to form metal oxides (and in particular, transition metal oxides) as opposed to using a metal oxide to directly react with the metal fluoride. Examples of such precursors include, but are not limited to, metal acetates, metal acetylacetonates, metal hydroxides, metal ethoxides, and other similar organo-metal complexes. In either event, the final rechargeable material is not necessarily a pure oxide or a purely crystalline material. The reaction of Formula II predicts that there would not be a pure oxide or a purely crystalline material. In some instances, the metal oxide precursor or metal oxide material can form a coating, or at least a partial coating, on the metal fluoride active material. Without being bound by a particular theory or mechanism of action, the reaction of the metal oxide precursor or metal oxide material with the surface of the metal fluoride (and in particular copper fluoride) active material is important for generating a rechargeable electrode active material.

EXAMPLES

The following examples describe specific aspects of some embodiments of the invention to illustrate and provide a description for those of ordinary skill in the art. The examples should not be construed as limiting the invention, as the examples merely provide specific methodology useful in understanding and practicing some embodiments of the invention.

Example 1

Fabrication of Hybrid and/or Coated Electrodes for Rechargeable Cells

Materials and Synthetic Methods. All reactions were prepared in a high purity argon filled glove box (M-Braun, O₂and humidity contents <0.1 ppm). Unless otherwise specified, materials were obtained from commercial sources (e.g., Sigma-Aldrich, Advanced Research Chemicals Inc., Alfa Aesar, Strem) without further purification.
Preparation of CuF₂Hybrid. Milling vessels were loaded with CuF₂at from about 85 wt % to about 95 wt % and reactant (metal oxide or metal oxide precursor) at from about 5 wt % to about 15 wt %, and the vessels were sealed. The mixture was milled. After milling, samples were annealed at from about 200 degrees C. to about 575 degrees C. for 1 to 12 hours under flowing N₂. Specific hybrid-forming reactants were processed as described below.
Preparation of CuF₂/Cu₃Mo₂O₉. Milling vessels were loaded with CuF₂(85 wt %) and MoO₃(15 wt %), sealed, and then milled. After milling, samples were annealed at 450 degrees C. for 6 hours under flowing N₂.
Preparation of CuF_2/NiO. Milling vessels were loaded with CuF₂(85 wt %) and NiO (15 wt %), sealed, and then milled. After milling, samples were annealed at 325 degrees C. for 6 hours under flowing N₂.
Preparation of CuF_2/Nickel (II) acetylacetonate. A fine dispersion of CuF₂was prepared by milling in the presence of THF (40-120 mg CuF₂/mL THF). The dispersed sample was then added to a solution of Ni(AcAc)₂in THF such that Nickel (II) acetylacetonate accounted for 15 wt % of the solids in the solution. The solution was then agitated by either shaking, sonication, or low energy milling for from about 1 to about 12 hours. The solution was then dried at room temperature under vacuum and the resulting solid was annealed at 450 degrees C. for 6 hours under dry air.
Preparation of Vapor Deposited Coatings The coating material (nickel metal) was vaporized and then physically condensed onto the substrate at 20 weight percent. X-ray diffraction measurements were performed on the coated material to confirm the bulk CuF₂was not altered. The coated material was then annealed similarly to materials prepared by other methods.
Preparation of Atomic Layer Deposited Coatings CuF₂was coated with TiO₂by atomic layer deposition methods. The expected coating thickness was about 8.5 nm based on ellipsometry measurements on a silicon witness sample, which represented a nominal 3 weight percent coating on the CuF₂. The coated material was then annealed similarly to materials prepared by other methods.
Electrode Formulation. Cathodes were prepared using a formulation composition of 80:15:5 (active material:binder:conductive additive) according to the following formulation method: 133 mg PVDF (Sigma Aldrich) and about 44 mg Super P Li (Timcal) was dissolved in 10 mL NMP (Sigma Aldrich) overnight. 70 mg of coated composite powder was added to 1 mL of this solution and stirred overnight. Films were cast by dropping about 70 μL of slurry onto stainless steel current collectors and drying at 150 degrees C. for about 1 hour. Dried films were allowed to cool, and were then pressed at 1 ton/cm². Electrodes were further dried at 150 degrees C. under vacuum for 12 hours before being brought into a glove box for battery assembly.

Example 2

Electrochemical Characterization of Electrochemical Cells Containing Rechargeable Electrodes

All batteries were assembled in a high purity argon filled glove box (M-Braun, O₂and humidity contents <0.1 ppm), unless otherwise specified. Cells were made using lithium as an anode, Celgard 2400 separator, and 90 μL of 1M LiPF₆in 1:2 EC:EMC electrolyte. Electrodes and cells were electrochemically characterized at 30 degrees C. with a constant current C/50 charge and discharge rate between 4.0 V and 2.0 V. A 3 hour constant voltage step was used at the end of each charge. In some instances, cathodes were lithiated pressing lithium foil to the electrode in the presence of electrolyte (1M LiPF₆in 1:2 EC:EMC) for about 15 minutes. The electrode was then rinsed with EMC and built into cells as described above, except graphite was used as the anode rather than lithium.
FIG. 1 illustrates the results of electrochemical characterization of certain embodiments disclosed herein. Specifically, the second cycle discharge capacity of three different cathode formulations containing a LiFePO₄material is plotted as a function of LiFePO₄content (labeled LFP) in the cathode in FIG. 1. The dotted line depicts the theoretical capacity of LiFePO₄. One cathode formulation is 100% LiFePO₄. Another cathode formulation is a combination of CuF₂and LiFePO₄in which the content of LiFePO₄was varied from 10% to 50% of the total weight of conductive material. The third cathode formulation is a combination of CuF₂and the conventional conductive oxide MoO₃and LiFePO₄in which the content of LiFePO₄was varied from 10% to 50% of the total weight of conductive material. As this is second cycle data, FIG. 1 demonstrates that all of the CuF₂/LiFePO₄matrices are rechargeable. In addition, the (CuF₂/MoO₃)/LiFePO₄hybrid cathode containing 50% LiFePO₄is also able to recharge. FIG. 1 further demonstrates a direct relationship between the capacity and the percent content of LiFePO₄.
FIG. 2 illustrates the results of electrochemical characterization of certain embodiments disclosed herein. Specifically, the voltage of a hybrid cathode is plotted against the capacity for the first and second cycles. The dashed line indicates the expected theoretical capacity from the LiFePO₄content in cathode. The cathode formulation is the CuF₂(70%)/LiFePO₄(30%) hybrid cathode from FIG. 1. During the first cycle, very little discharge capacity is observed, indicating that the LiFePO₄material is not capable of accepting charge on this cycle. Without being bound to a particular theory or mechanism of action, the LiFePO₄material may not accept charge as a result of defects introduced during milling. This data suggests that all of the capacity observed during the first and second cycles can be attributed solely to the CuF₂.
FIG. 3 illustrates the results of electrochemical characterization of certain embodiments disclosed herein. Specifically, the discharge capacity for cells with a range of LiFePO₄content is plotted as a function of cycle for 10 cycles. The cathode formulation is CuF₂with LiFePO₄content ranging from 10% to 50% of the total weight of conductive material. FIG. 4 demonstrates that the hybrid cathode is able to consistently recharge across a number of cycles. Based on data from FIG. 2, it is expected that the discharge capacity is contributed solely by CuF₂and not LiFePO₄. This is a significant finding because CuF₂has not been previously shown to have such significant reversible capacity. The combination of certain conductive materials with CuF₂renders the CuF₂cathode material rechargeable.
FIG. 4 illustrates the results of electrochemical characterization of certain embodiments disclosed herein. Specifically, the first and second cycle voltage traces for a cell containing a cathode formed from a metal fluoride and the new hybrid material. In this case, the metal fluoride active material is CuF₂and the hybrid material is Cu₃Mo₂O₉. FIG. 4 demonstrates that the cell has about 140 mAh/g of reversible capacity. Previously known cathodes containing CuF₂have not demonstrated such significant reversible capacity.
FIG. 5 illustrates the results of structural characterization of certain embodiments disclosed herein. Specifically, the powder X-ray diffraction pattern of the material forming the cathode tested in FIG. 4 is shown along with the powder X-ray diffraction patterns of CuF₂and Cu₃Mo₂O₉. FIG. 5 demonstrates that the material contains phases rich in CuF₂and phases rich in Cu₃Mo₂O₉. Thus, FIG. 5 demonstrates a new hybrid material in combination with a metal fluoride active material. Further, grain size analysis of this powder X-ray diffraction data shows that the CuF₂has a grain size greater than 130 nm. This is a significant finding since such comparatively large particles were thought to be too large to provide good electrochemical performance.
For many of the rechargeable matrices described herein (and in particular for matrices including Mo, Ni, or Ti), the reactions described herein yield a new material at least at the surface of the particles of the metal fluoride active material. The novel material present at least at the surface of the particles of the metal fluoride active material is believed to provide many of the benefits disclosed herein.
FIG. 6 illustrates the results of electrochemical characterization of certain embodiments disclosed herein. Specifically, the second cycle discharge capacity of CuF₂with various materials and annealing temperatures. FIG. 6 shows many oxide materials that provide recharge capability, demonstrated by capacities greater than 100 mAh/g.
Table 1 presents the results of further electrochemical characterization of certain embodiments disclosed herein. Table 1 shows that many metal oxide and metal oxide precursor starting materials can be used in the reactions described herein to yield rechargeable metal fluoride electrode materials. The materials in Table 1 include metal oxides, metal phosphates, metal fluorides, and precursors expected to decompose to oxides. In particular, nickel oxide showed excellent performance.

TABLE 1

Electrochemical Characterization of Various Precursor Materials as a
Function of Anneal Temperature

		Initial Capacity	Reversible
Precursor	Annealing Temp	(0.02 C, Cy1,	Capacity (0.05 C,
Material	(C.)	mAh/g)	Cy2, mAh/g)

None	200	181	30
None	325	394	216
None	450	247	61
(NH₄)H₂PO₄	200	307	5
(NH₄)H₂PO₄	325	406	178
(NH₄)H₂PO₄	450	397	0
Al₂O₃	200	281	70
Al₂O₃	325	348	107
Al₂O₃	400	203	78
AlF₃	200	397	124
AlF₃	325	384	125
AlF₃	400	320	98
AlPO₄	200	410	115
AlPO₄	325	356	136
AlPO₄	450	284	74
Bi₂O₃	200	128	32
Bi₂O₃	325	89	34
Bi₂O₃	400	103	36
CaF₂	200	301	86
CaF₂	325	310	107
CaF₂	400	282	125
CaO	200	1	1
CaO	325	138	27
CaO	400	84	29
Co₃(PO₄)₂	200	323	93
Co₃(PO₄)₂	325	373	161
Co₃(PO₄)₂	450	382	126
Co₃O₄	200	167	112
Co₃O₄	325	216	132
Co₃O₄	450	329	151
Co₃O₄	575	310	134
Cr₂O₃	200	223	88
Cr₂O₃	325	234	132
Cr₂O₃	450	227	102
Cr₂O₃	575	184	70
Fe Acetate	200	407	31
Fe Acetate	325	431	11
Fe Acetate	450	393	180
Fe₂O₃	200	197	135
Fe₂O₃	325	200	142
Fe₂O₃	450	170	112
Fe₂O₃	575	308	131
FeF₂	200	427	202
FeF₂	325	382	220
FeF₂	400	370	155
FeF₃	200	443	188
FeF₃	325	406	218
FeF₃	400	359	141
FePO₄	200	252	76
FePO₄	325	393	147
FePO₄	450	429	197
In₂O₃	200	250	64
In₂O₃	325	203	106
In₂O₃	400	347	109
La₂O₃	200	281	74
La₂O₃	325	155	39
La₂O₃	450	68	29
La₂O₃	575	114	36
Li₂O	200	32	11
Li₂O	325	49	18
Li₂O	400	38	18
Li₃PO₄	200	318	123
Li₃PO₄	325	435	136
Li₃PO₄	450	409	114
LiCoPO₄	200	372	97
LiCoPO₄	325	408	142
LiCoPO₄	450	338	136
LiH₂PO₄	200	300	111
LiH₂PO₄	325	423	149
LiH₂PO₄	450	387	107
LiMnPO₄	200	351	77
LiMnPO₄	325	368	102
LiMnPO₄	450	397	178
LiNiPO₄	200	402	116
LiNiPO₄	325	396	191
LiNiPO₄	450	405	176
MgF₂	200	387	135
MgF₂	325	378	147
MgF₂	400	360	122
MgO	200	313	181
MgO	325	259	155
MgO	400	198	126
MnO	200	117	52
MnO	325	130	65
MnO	450	83	55
MnO	575	59	38
MnO₂	200	120	76
MnO₂	325	123	57
MnO₂	450	242	150
MnO₂	575	104	69
Mo Acetate	200	396	10
Mo Acetate	325	433	17
Mo Acetate	450	398	46
Na₂O	200	2	1
Na₂O	325	26	13
Na₂O	400	24	13
Ni	200	345	197
Ni	325	301	178
Ni	400	302	158
Ni	450	300	152
Ni acac	200	425	56
Ni acac	325	306	87
Ni Acac	400	247	30
Ni acac	450	362	172
Ni acetate	200	397	148
Ni acetate	325	376	46
Ni acetate	350	370	191
Ni acetate	400	383	180
Ni acetate	450	371	186
Ni acetate	500	373	171
Ni₃(PO₄)₂	200	410	124
Ni₃(PO₄)₂	325	430	52
Ni₃(PO₄)₂	450	126	44
Ni(C₂O₂)	200	359	90
Ni(C₂O₂)	325	395	195
Ni(C₂O₂)	450	381	175
Ni(CP)₂	200	304	27
Ni(CP)₂	325	317	14
Ni(CP)₂	450	258	148
Ni(OH)₂	200	412	186
Ni(OH)₂	325	362	196
Ni(OH)₂	400	327	181
Ni(OH)₂	450	300	169
NiBr₂	200	125	0
NiBr₂	325	225	78
NiBr₂	400	244	113
NiCO₃*Ni(OH)₂	200	380	17
NiCO₃*Ni(OH)₂	325	359	215
NiCO₃*Ni(OH)₂	450	317	184
NiF₂	200	367	121
NiF₂	325	395	207
NiF₂	400	411	170
NiF₂	450	396	177
NiO	125	257	131
NiO	200	403	222
NiO	225	384	212
NiO	250	385	221
NiO	275	370	229
NiO	300	335	175
NiO	325	402	252
NiO	350	365	209
NiO	375	260	123
NiO	400	371	200
NiO	425	361	186
NiO	450	386	183
NiO	500	308	150
NiO	575	319	112
Sb₂O₃	200	111	34
Sb₂O₃	325	147	37
Sb₂O₃	400	223	104
Sc₂O₃	200	359	159
Sc₂O₃	325	293	159
Sc₂O₃	400	84	33
Sc₂O₃	450	150	68
Sc₂O₃	575	55	17
ScF₃	200	400	178
ScF₃	325	387	174
ScF₃	400	243	100
SiO₂	200	1	1
SiO₂	325	114	28
SiO₂	400	230	92
SnO₂	200	210	48
SnO₂	325	182	68
SnO₂	400	133	65
SrO	200	152	12
SrO	325	66	16
SrO	400	134	48
Ta₂O₅	200	289	4
Ta₂O₅	325	269	141
Ta₂O₅	450	298	121
Ta₂O₅	575	317	74
Ti(OEt)₄	200	438	21
Ti(OEt)₄	325	453	12
Ti(OEt)₄	450	353	5
TiO₂	225	322	150
TiO₂	250	309	169
TiO₂	275	262	162
TiO₂	300	199	127
TiO₂	325	322	173
TiO₂	350	327	187
TiO₂	375	120	77
TiO₂	400	359	199
TiO₂	425	345	194
TiO₂	450	353	169
Y₂O₃	200	353	130
Y₂O₃	325	279	104
Y₂O₃	450	83	37
Y₂O₃	575	80	30
ZnF₂	200	438	206
ZnF₂	325	372	191
ZnF₂	400	318	134
ZnO	200	210	95
ZnO	325	242	93
ZnO	400	194	44
ZnO	450	205	99
ZnO	575	151	71
ZrO₂	200	302	122
ZrO₂	325	288	129

FIG. 7 illustrates the results of electrochemical characterization of certain embodiments disclosed herein. Specifically, the second cycle discharge capacity for cells containing a cathode formed from a metal fluoride and the precursor material treated at different temperatures. In this case, the metal fluoride active material is CuF₂and the precursor material is NiO. FIG. 7 shows a peak for cycle 2 capacity at about 325 degrees C. for NiO precursors, with nearly 250 mAh/g discharge capacity.
FIG. 8 illustrates the results of electrochemical characterization of certain embodiments disclosed herein, specifically, the second-cycle capacity retention and reversible capacity for cathode active materials formed from reacting 85 wt % CuF₂with 15 wt % of certain metal oxides (in this case NiO or TiO₂) at certain annealing temperatures. The mixtures were milled at high energy for about 20 hours. The anneal temperatures ranged from about 225 degrees C. to about 450 degrees C. and the anneal time was 6 hours. The 325 degree C. anneal temperature for the NiO starting material generated the best performance. The cells used a Li anode and an electrolyte containing 1M LiPF₆in EC:EMC. The testing was performed at a rate of 0.02 C and over a voltage range of 2.0 V to 4.0 V.
FIG. 9 illustrates the results of electrochemical characterization of certain embodiments disclosed herein, specifically, the second-cycle capacity retention and reversible capacity for cathode active materials formed from reacting 85 wt % CuF₂with 15 wt % of certain metal oxides (in this case NiO or TiO₂) for certain annealing times. The mixtures were milled at high energy for about 20 hours. The anneal temperature was 325 degrees C. and the anneal time was 1 hour, 6 hours, or 12 hours. The 6 hour anneal time yielded the best results for both the NiO and TiO₂starting materials, and the NiO starting material generated better performance. The cells used a Li anode and an electrolyte containing 1M LiPF₆in EC:EMC. The testing was performed at a rate of 0.02 C and over a voltage range of 2.0 V to 4.0 V.
FIG. 10 illustrates the results of electrochemical characterization of certain embodiments disclosed herein, specifically, the second-cycle capacity retention and reversible capacity for cathode active materials formed from reacting 85 wt %, 90 wt %, or 95 wt % CuF₂with 5 wt %, 10 wt %, 15 wt % of NiO. The mixtures were milled at high energy for about 20 hours. The anneal temperature was 325 degrees C. and the anneal time was 6 hours. Using 10 wt % or 15 wt % of the NiO starting material generated better performance. The cells used a Li anode and an electrolyte containing 1M LiPF₆in EC:EMC. The testing was performed at a rate of 0.02 C and over a voltage range of 2.0 V to 4.0 V.
FIG. 11 illustrates the results of electrochemical characterization of certain embodiments disclosed herein, specifically, the second-cycle capacity retention and reversible capacity for cathode active materials formed from reacting 85 wt %, CuF₂with 15 wt % of NiO. The mixtures were milled at various energies comparable to milling on a Fritch Pulverisette 7 Planatery Mill at 305, 445, 595, and 705 RPM for about 20 hours. The anneal temperature was 325 degrees C. and the anneal time was 6 hours. Performance improves with increasing milling energy, suggesting that intimate physical interaction of the materials is required. The cells used a Li anode and an electrolyte containing 1M LiPF₆in EC:EMC. The testing was performed at a rate of 0.05 C and over a voltage range of 2.0 V to 4.0 V.
FIG. 12 illustrates the results of electrochemical characterization of certain embodiments disclosed herein, specifically, the second-cycle capacity retention and reversible capacity for cathode active materials formed from reacting 85 wt %, CuF₂with 15 wt % of NiO. The mixtures were milled for various times (3 hours, 20 hours, or 40 hours) at a high energy (comparable to 705 RPM on Fritch Pulverisette 7). The anneal temperature was 325 degrees C. and the anneal time was 6 hours. Performance does not improve after 20 hours of milling. The cells used a Li anode and an electrolyte containing 1M LiPF₆in EC:EMC. The testing was performed at a rate of 0.05 C and over a voltage range of 2.0 V to 4.0 V.
FIG. 13 illustrates the results of electrochemical characterization of certain embodiments disclosed herein. Specifically, FIG. 13 shows the second cycle reversible capacity measured for various starting materials used to react with CuF₂. The starting materials include NiO, nickel (II) acetylacetonate (Ni acac in Table 1), nickel acetate, nickel hydroxide, NiCO₃*Ni(OH)₂, Ni(C₂O₂), Ni(CP)₂, and Ni. In some instances, the starting materials react to form a new phase. The materials react with the surface of the CuF₂particles. Additionally, the anneal atmosphere was either N₂or dry air. The precursor starting materials decompose to NiO (although this depends on the atmosphere for some precursors) at or below the annealing temperatures used for the reaction. The precursors that are soluble or have low boiling points can enable solution or vapor deposition processing methods. The cells used a Li anode and an electrolyte containing 1M LiPF₆in EC:EMC. The testing was performed at a rate of 0.05 C and over a voltage range of 2.0 V to 4.0 V. Several materials show similar performance to the NiO baseline.
FIG. 14 illustrates the results of electrochemical characterization of certain embodiments disclosed herein, specifically, the second-cycle capacity retention and reversible capacity for cathode active materials formed from reacting CuF₂with nickel (II) acetylacetonate using various processing conditions. In some cases, the CuF₂was dispersed using methods described herein. The coatings were applied using mill coating techniques (that is, agitating the mixture in a milling apparatus) or by solution coating techniques (including solution coating driven by physisorption). All samples were annealed under dry air. The cells used a Li anode and an electrolyte containing 1M LiPF₆in EC:EMC. The testing was performed at a rate of 0.05 C and over a voltage range of 2.0 V to 4.0 V. Testing demonstrates that solution coating methods can provide similar performance to the mill coating techniques.
FIG. 20 illustrates the results of electrochemical characterization of certain embodiments disclosed herein, specifically, the second-cycle capacity retention and reversible capacity for cathode active materials formed from reacting CuF₂with coatings formed from various coating methods and from various precursors. The precursors included NiO, Ni, TiO₂, nickel (II) acetylacetonate, and nickel acetate. All five precursor types were applied according to the mill coating techniques (that is, agitating the mixture in a milling apparatus). Solution coating techniques were used for nickel (II) acetylacetonate, and nickel acetate. Physical vapor deposition (PVD) techniques were used to form a coating from Ni precursor, and atomic layer deposition (ALD) techniques were used to form a coating from TiO₂. All samples were annealed under dry air. The cells used a Li anode and an electrolyte containing 1M LiPF₆in EC:EMC. The testing was performed at a rate of 0.05 C and over a voltage range of 2.0 V to 4.0 V.
The solution, vapor, and atomic layer deposition methods can provide comparatively more uniform coatings on metal fluoride particles than the coatings obtained by milling methods. A comparatively thinner, more uniform coatings can provide the benefits of the coating material, such as more complete protection of the metal fluoride particle, with less precursor material. To the extent that excess precursor material is less active (and therefore less desirable) than the active material, thin, conformal coatings can provide an advantage in terms of weight-normalized reversible capacity.
FIG. 20 shows that although absolute reversible capacity was inferior for solution and vapor coatings as compared to milled coatings, the reversible capacity per weight percentage of coating was significantly improved. For example, for the TiO₂the atomic layer deposition coating method yielded greater than about 60% more reversible capacity per coating weight than the milled coating method. The ALD coated material had a coating that was about 8 nm thick and less than about 3 weight percent of the coated particle.
Notably, the non-milling coating methods shown in FIG. 20 (that is, the solution coating, vapor deposition, and atomic layer deposition methods) are compatible with a subset of the metal complexes disclosed herein. A variety of coating materials is possible with atomic layer deposition methods including metals (e.g., Ni), metal oxides (e.g., Al₂O₃, SiO₂, Ta₂O₅, TiO₂), metal nitrides (e.g., AlN, TaN), and others. Physical vapor deposition techniques can also deposit coatings of a wide number of materials including metals (e.g., Ni, Ba, Ta), metal oxides (e.g., SiO₂, Ta₂O₅, TiO₂, NiO), metal nitrides (e.g., TiN, AlN), metal silicates (e.g., ZrSiO₄) or other materials that are volatile enough to be evaporated and re-condensed onto a substrate.
FIG. 15 illustrates the results of electrochemical characterization of certain embodiments disclosed herein, specifically, the capacity as a function of cycle for cathode active materials formed from reacting 85 wt %, CuF₂with 15 wt % of NiO and for a control material. The NiO/CuF₂mixture was milled at high energy for about 20 hours. The anneal temperature was 325 degrees C. and the anneal time was 6 hours. The cells used a Li anode and an electrolyte containing 1M LiPF₆in EC:EMC. The testing was performed at a cycle 1 rate of 0.02 C, a cycle 2 rate of 0.05 C, and a cycle 3 through cycle 25 rate of 0.5 C and over a voltage range of 2.0 V to 4.0 V. With the reacted NiO/CuF₂as the active material, the cell cycles reversibly for extended cycling with capacity greater than 100 mAh/g for 25 cycles. Further, the reacted NiO/CuF₂active material demonstrates retention of 80% of cycle 3 capacity as far out as cycle 15. The control material, which was prepared according to the process described in Badway, F. et al., Chem. Mater., 2007, 19, 4129, does not demonstrate any rechargeable capacity. Thus, the material prepared according to embodiments described herein is significantly superior to known materials processed according to known methods.
FIG. 16 illustrates the results of electrochemical characterization of certain embodiments disclosed herein, specifically, a galvanostatic intermittent titration technique (GITT) measurement for cathode active materials formed from reacting 85 wt %, CuF₂with 15 wt % of NiO and for a control material. The NiO/CuF₂mixture was milled at high energy for about 20 hours. The anneal temperature was 325 degrees C. and the anneal time was 6 hours. The cells used a Li anode and an electrolyte containing 1M LiPF₆in EC:EMC. The testing was performed over a voltage range of 2.0 V to 4.0 V at a rate of 0.1 C and with a 10 hour relaxation time. The GITT measurement relaxation points show low voltage hysteresis (about 100 mV), which indicate that the overpotential and/or underpotential are likely caused by kinetic and not thermodynamic limitations. This is consistent with other properties and characteristics observed for the reacted NiO/CuF₂active material.
FIG. 17 illustrates the results of electrochemical characterization of certain embodiments disclosed herein, specifically, the capacity of full cells and half cells as a function of cycle for cathode active materials formed from reacting 85 wt %, CuF₂with 15 wt % of NiO. The NiO/CuF₂mixture was milled at high energy for about 20 hours. The anneal temperature was 325 degrees C. and the anneal time was 6 hours. The label “Cu+2LiF” indicated that the NiO/CuF₂electrode was lithiated by pressing Li foil to CuF₂electrode in the presence of electrolyte as described above. The other half cell was lithiated electrochemically in the initial cycles. The cells used a Li anode and an electrolyte containing 1M LiPF₆in EC:EMC. The testing was performed over a voltage range of 2.0 V to 4.0 V. Half cell performance is essentially identical between the two lithiation methods after cycle 2, while full cell shows additional irreversible capacity loss as compared to the half cells but similar capacity retention.
FIG. 18 illustrates the results of electrochemical characterization of certain embodiments disclosed herein, specifically, the voltage traces of the full cell and half cells prepared as described in relation to FIG. 17. The full cell has similar charge capacity to the half cells, but larger irreversible capacity loss and lower discharge voltage (which can indicate increased cell impedance). FIG. 18 demonstrates that the full cell has about 250 mAh/g of reversible capacity and about 500 mV hysteresis between charge and discharge plateau voltages.
FIG. 19 illustrates the results of electrochemical characterization of certain embodiments disclosed herein, specifically, the capacity retention of full cells and half cells as a function of cycle for cathode active materials formed from reacting 85 wt %, CuF₂with 15 wt % of NiO. The results from a control material are also depicted. The full cell and half cells were prepared as described in relation to FIG. 17. The cells used a Li anode and an electrolyte containing 1M LiPF₆in EC:EMC. The testing was performed at a cycle 1 rate of 0.1 C and over a voltage range of 2.0 V to 4.0 V. The capacity retention is essentially identical for the full and half cells of the NiO/CuF₂active material. The control material shows essentially no rechargeable capacity.
While the invention has been described with reference to the specific embodiments thereof, it should be understood by those skilled in the art that various changes may be made and equivalents may be substituted without departing from the true spirit and scope of the invention as defined by the appended claims. In addition, many modifications may be made to adapt a particular situation, material, composition of matter, method, or process to the objective, spirit and scope of the invention. All such modifications are intended to be within the scope of the claims appended hereto. In particular, while the methods disclosed herein have been described with reference to particular operations performed in a particular order, it will be understood that these operations may be combined, sub-divided, or re-ordered to form an equivalent method without departing from the teachings of the invention. Accordingly, unless specifically indicated herein, the order and grouping of the operations are not limitations of the invention.

Claims

We claim:

1. A method of making an electrode, comprising:

coating particles, wherein each particle includes a metal fluoride material, with a coating precursor material, wherein the coating precursor material includes a transition metal;

annealing the particles such that at least a portion of the metal fluoride material and at least a portion of the transition metal react to undergo a phase change; and

forming the coated particles into an electrode.

2. The method of claim 1, wherein the electrode forming step comprises preparing a formulation composition of coated particles, binder, and conductive additive.

3. The method of claim 1, wherein the metal fluoride material comprises copper fluoride.

4. The method of claim 1, wherein the coating step comprising milling the particles with the coating precursor material.

5. The method of claim 4, wherein the coating precursor material comprises a organo-metal complex.

6. The method of claim 4, wherein the coating precursor material comprises a metal oxide.

7. The method of claim 4, wherein the coating precursor material comprises elemental metal.

8. The method of claim 4, wherein the coating precursor material comprises NiO.

9. The method of claim 4, wherein the coating precursor material comprises TiO₂.

10. The method of claim 4, wherein the coating precursor material is Ni.

11. The method of claim 4, wherein the coating precursor material comprises nickel (II) acetylacetonate.

12. The method of claim 4, wherein the coating precursor material comprises nickel acetate.

13. The method of claim 1, wherein the coating step comprises a solution coating process.

14. The method of claim 13, wherein the coating precursor material comprises an organo-metal complex.

15. The method of claim 13, wherein the coating precursor material comprises nickel (II) acetylacetonate.

16. The method of claim 1, wherein the coating step comprises a physical vapor deposition process.

17. The method of claim 16, wherein the coating precursor material comprises a metal oxide.

18. The method of claim 16, wherein the coating precursor material comprises a metal nitride.

19. The method of claim 16, wherein the coating precursor material comprises a metal silicate.

20. The method of claim 16, wherein the coating precursor material is Ni or Ti.