[go: up one dir, main page]

US20160064299A1 - Structure and method to minimize warpage of packaged semiconductor devices - Google Patents

Structure and method to minimize warpage of packaged semiconductor devices Download PDF

Info

Publication number
US20160064299A1
US20160064299A1 US14/472,882 US201414472882A US2016064299A1 US 20160064299 A1 US20160064299 A1 US 20160064299A1 US 201414472882 A US201414472882 A US 201414472882A US 2016064299 A1 US2016064299 A1 US 2016064299A1
Authority
US
United States
Prior art keywords
oxygen barrier
encapsulant
packaged semiconductor
substrate
barrier layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US14/472,882
Inventor
Nishant Lakhera
James R. Guajardo
Varughese Mathew
Akhilesh K. Singh
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NXP USA Inc
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to US14/472,882 priority Critical patent/US20160064299A1/en
Assigned to FREESCALE SEMICONDUCTOR, INC. reassignment FREESCALE SEMICONDUCTOR, INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: GUAJARDO, JAMES R., LAKHERA, NISHANT, MATHEW, VARUGHESE, SINGH, AKHILESH K.
Application filed by Individual filed Critical Individual
Assigned to CITIBANK, N.A., AS NOTES COLLATERAL AGENT reassignment CITIBANK, N.A., AS NOTES COLLATERAL AGENT SUPPLEMENT TO IP SECURITY AGREEMENT Assignors: FREESCALE SEMICONDUCTOR, INC.
Assigned to CITIBANK, N.A., AS NOTES COLLATERAL AGENT reassignment CITIBANK, N.A., AS NOTES COLLATERAL AGENT SUPPLEMENT TO IP SECURITY AGREEMENT Assignors: FREESCALE SEMICONDUCTOR, INC.
Assigned to CITIBANK, N.A., AS NOTES COLLATERAL AGENT reassignment CITIBANK, N.A., AS NOTES COLLATERAL AGENT SUPPLEMENT TO IP SECURITY AGREEMENT Assignors: FREESCALE SEMICONDUCTOR, INC.
Assigned to FREESCALE SEMICONDUCTOR, INC. reassignment FREESCALE SEMICONDUCTOR, INC. PATENT RELEASE Assignors: CITIBANK, N.A., AS COLLATERAL AGENT
Assigned to MORGAN STANLEY SENIOR FUNDING, INC. reassignment MORGAN STANLEY SENIOR FUNDING, INC. ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Assignors: CITIBANK, N.A.
Assigned to MORGAN STANLEY SENIOR FUNDING, INC. reassignment MORGAN STANLEY SENIOR FUNDING, INC. ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Assignors: CITIBANK, N.A.
Publication of US20160064299A1 publication Critical patent/US20160064299A1/en
Assigned to MORGAN STANLEY SENIOR FUNDING, INC. reassignment MORGAN STANLEY SENIOR FUNDING, INC. SUPPLEMENT TO THE SECURITY AGREEMENT Assignors: FREESCALE SEMICONDUCTOR, INC.
Priority to US15/191,870 priority patent/US9978614B2/en
Assigned to NXP, B.V., F/K/A FREESCALE SEMICONDUCTOR, INC. reassignment NXP, B.V., F/K/A FREESCALE SEMICONDUCTOR, INC. RELEASE OF SECURITY INTEREST Assignors: MORGAN STANLEY SENIOR FUNDING, INC.
Assigned to NXP B.V. reassignment NXP B.V. RELEASE OF SECURITY INTEREST Assignors: MORGAN STANLEY SENIOR FUNDING, INC.
Assigned to NXP B.V. reassignment NXP B.V. RELEASE OF SECURITY INTEREST Assignors: MORGAN STANLEY SENIOR FUNDING, INC.
Assigned to NXP B.V. reassignment NXP B.V. CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE ICATION 11759915 AND REPLACE IT WITH APPLICATION 9935 PREVIOUSLY RECORDED ON REEL 040928 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY REST. Assignors: MORGAN STANLEY SENIOR FUNDING, INC.
Assigned to NXP, B.V. F/K/A FREESCALE SEMICONDUCTOR, INC. reassignment NXP, B.V. F/K/A FREESCALE SEMICONDUCTOR, INC. CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE ICATION 11759915 AND REPLACE IT WITH APPLICATION 9935 PREVIOUSLY RECORDED ON REEL 040925 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY REST. Assignors: MORGAN STANLEY SENIOR FUNDING, INC.
Abandoned legal-status Critical Current

Links

Images

Classifications

    • H10W74/016
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L23/00Details of semiconductor or other solid state devices
    • H01L23/28Encapsulations, e.g. encapsulating layers, coatings, e.g. for protection
    • H01L23/31Encapsulations, e.g. encapsulating layers, coatings, e.g. for protection characterised by the arrangement or shape
    • H01L23/3107Encapsulations, e.g. encapsulating layers, coatings, e.g. for protection characterised by the arrangement or shape the device being completely enclosed
    • H01L23/3135Double encapsulation or coating and encapsulation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/50Assembly of semiconductor devices using processes or apparatus not provided for in a single one of the groups H01L21/18 - H01L21/326 or H10D48/04 - H10D48/07 e.g. sealing of a cap to a base of a container
    • H01L21/56Encapsulations, e.g. encapsulation layers, coatings
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L23/00Details of semiconductor or other solid state devices
    • H01L23/28Encapsulations, e.g. encapsulating layers, coatings, e.g. for protection
    • H01L23/29Encapsulations, e.g. encapsulating layers, coatings, e.g. for protection characterised by the material, e.g. carbon
    • H01L23/291Oxides or nitrides or carbides, e.g. ceramics, glass
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L23/00Details of semiconductor or other solid state devices
    • H01L23/28Encapsulations, e.g. encapsulating layers, coatings, e.g. for protection
    • H01L23/29Encapsulations, e.g. encapsulating layers, coatings, e.g. for protection characterised by the material, e.g. carbon
    • H01L23/293Organic, e.g. plastic
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L23/00Details of semiconductor or other solid state devices
    • H01L23/28Encapsulations, e.g. encapsulating layers, coatings, e.g. for protection
    • H01L23/29Encapsulations, e.g. encapsulating layers, coatings, e.g. for protection characterised by the material, e.g. carbon
    • H01L23/293Organic, e.g. plastic
    • H01L23/296Organo-silicon compounds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L23/00Details of semiconductor or other solid state devices
    • H01L23/564Details not otherwise provided for, e.g. protection against moisture
    • H10P54/00
    • H10W42/121
    • H10W74/121
    • H10W90/00
    • H10W72/0198
    • H10W72/352
    • H10W72/354
    • H10W72/536
    • H10W72/5363
    • H10W72/884
    • H10W74/00
    • H10W90/734
    • H10W90/736
    • H10W90/754
    • H10W90/756

Definitions

  • This disclosure relates generally to semiconductor devices, and more specifically, to minimizing warpage of packaged semiconductor devices.
  • Warpage or deformation of a packaged semiconductor device is a common problem experienced in testing and real world environments. In some cases, warpage greatly affects the reliability and functionality of packaged semiconductor devices.
  • FIG. 1-4 illustrates block diagrams depicting cross-sectional views of example packaged semiconductor devices in which the disclosure is implemented, according to some embodiments.
  • FIG. 5 illustrates side views contrasting warpage of example packaged semiconductor devices, according to some embodiments.
  • FIG. 6-7 illustrates block diagrams depicting cross-sectional views of other example packaged semiconductor devices in which the disclosure is implemented, according to some embodiments.
  • Oxidation of a semiconductor material often densifies the material, which may result in shrinkage of the material. Such shrinkage induces residual stresses in a packaged semiconductor device and causes warpage or deformation of the packaged semiconductor device. For example, when an encapsulant over a packaged semiconductor device oxidizes, the encapsulant densifies and shrinks, which results in the encapsulant “pulling” up on the sides of the packaged semiconductor device, which causes the packaged semiconductor device to warp.
  • Warpage influences coplanarity of the packaged semiconductor device, where solder connections of a warped packaged semiconductor device are no longer coplanar within a same contact plane (e.g., the solder connections fail to make electrical contact with external pads). Warpage also affects board level device testing and reliability, where a packaged semiconductor device will experience extreme warpage after exposure to testing conditions that accelerate oxidation (e.g., 175° C. at 504 hours, or 150° C. at 1008 hours). The effects of oxidation will be increasingly damaging as packaged semiconductor devices become smaller and thinner.
  • the present disclosure provides for structures and methods to minimize warpage of a packaged semiconductor device by the presence of an oxygen barrier layer on one or more surfaces of a packaged semiconductor device.
  • the oxygen barrier layer reduces or eliminates oxygen exposure to materials used in a packaged semiconductor device, which reduces or eliminates the oxidation resulting from such oxygen exposure in an ambient environment, which in turn reduces or eliminates the warpage of the packaged semiconductor device resulting from such oxidation.
  • FIG. 1 illustrates a block diagram depicting a cross-sectional view of an example packaged semiconductor device 100 in which the present disclosure is implemented.
  • Packaged semiconductor device 100 includes a package substrate 12 having a top surface, a die 16 attached to the top surface of package substrate 12 with die attach material 14 , and wire bonds 22 and 24 providing electrical connections between die 16 and package substrate 12 .
  • Packaged semiconductor device 100 also includes an encapsulant 18 formed over the top surface of package substrate 12 , where encapsulant 18 surrounds and covers die 16 and wire bonds 22 and 24 .
  • Encapsulant 18 may include one or more layers of encapsulant materials.
  • Packaged semiconductor device 100 also includes an oxygen barrier layer 20 formed over a top surface of encapsulant 18 , as well as over side surfaces of encapsulant 18 , where the side surfaces may or may not be perpendicular to the top surface of encapsulant 18 .
  • packaged semiconductor device 100 also includes a plurality of solder connections 26 that are attached to the bottom surface of package substrate 12 and provide external connections, where the bottom surface of package substrate 12 is opposite the top surface of package substrate 12 . In other embodiments, packaged semiconductor device 100 does not include solder connections 26 .
  • Examples of die attach material 14 include polymer adhesives, epoxies, solders, films, and the like.
  • package substrate 12 include, but are not limited to, a ball grid array (BGA) package substrate, redistributed chip package (RCP) substrate, flip chip package substrate, wire bond BGA package substrate, enhanced wafer level BGA package substrate, fan out wafer level package substrate, a land grid array (LGA) package substrate, a pin grid array (PGA) package substrate, flat package substrate, small outline package substrate, chip-scale package substrate, a die pad of a lead frame, lead fingers of a lead frame, and other form factors including a die mounting structure, a surface mount, a through-hole, a chip carrier, and the like.
  • BGA ball grid array
  • RCP redistributed chip package
  • RCP redistributed chip package
  • flip chip package substrate flip chip package substrate
  • wire bond BGA package substrate wire bond BGA package substrate
  • enhanced wafer level BGA package substrate fan out wafer level package substrate
  • LGA land
  • Examples of die 16 include, but are not limited to, an integrated circuit (IC) die, a semiconductor die including a semiconductor substrate, a sensor die, a passive component such as a resistor, a capacitor, an inductor, a battery, an oscillator, and the like, a sensor device, and the like.
  • Examples of encapsulant 18 include, but are not limited to, mold compound, epoxy, underfill, glob top, dam and fill, and the like.
  • Oxygen barrier layer 20 includes one or more layers of an oxygen barrier material that reduces or eliminates oxygen exposure to encapsulant 18 from the ambient environment by preventing diffusion of oxygen through the one or more layers.
  • the oxygen barrier material is also thermally stable and has good adhesion to materials used in packaged semiconductor devices.
  • the amount of oxidation affecting the packaged semiconductor device is proportional to the surface area of encapsulant 18 that is exposed to the ambient environment.
  • the presence of oxygen barrier material reduces or eliminates oxygen exposure to encapsulant 18 , which reduces or eliminates the oxidation resulting from such oxygen exposure from the ambient environment, which in turn reduces or eliminates the warpage of the packaged semiconductor device resulting from such oxidation.
  • the presence of oxygen barrier layer 20 may be beneficial in packaged semiconductor devices having an encapsulant thickness of 500 microns or less over the die, and may be especially beneficial in ultra thin packaged semiconductor devices having a total thickness of 500 microns or less.
  • oxygen barrier layer 20 has a thickness that is less than 100 micrometers (microns). In some embodiments, oxygen barrier layer 20 has a thickness that is also greater than 1 nanometer. In some embodiments, oxygen barrier layer 20 has a thickness that is also greater than 10 nanometers. In some embodiments, oxygen barrier layer 20 has a thickness in the range of 1 to 5 microns. Oxygen barrier layer 20 may be formed from one or more organic (e.g., polymers, synthetic rubbers) or inorganic (e.g., ceramic oxides) oxygen barrier materials.
  • oxygen barrier materials include, but are not limited to, ceramic coating, ceramic oxide coating, zirconium oxide coating, alumina coating, synthetic rubber based coating, butyl rubber with filler, nitrile rubber with filler, polyurethane based coating, silicone based coating, silsesquioxane based coatings, and polymeric material with or without filler, and the like.
  • oxygen barrier layer 20 is formed over encapsulant 18 after packaged semiconductor device 100 has been singulated from a group of packaged semiconductor devices formed from a single package substrate (e.g., a “chocolate bar” structure).
  • oxygen barrier layer 20 covers top and side surfaces of encapsulant 18 to provide increased protection against oxygen exposure to encapsulant 18 from the ambient environment (e.g., coating top and side surfaces of encapsulant 18 with oxygen barrier layer 20 minimizes exposed surface area of encapsulant 18 ).
  • Oxygen barrier layer 20 is formed by some method of applying oxygen barrier material to encapsulant 18 .
  • oxygen barrier layer 20 is formed by some method of spraying packaged semiconductor device 100 with oxygen barrier layer 20 to coat encapsulant 18 .
  • oxygen barrier layer 20 is formed by some method of dipping packaged semiconductor device 100 into oxygen barrier material in order to coat encapsulant 18 with oxygen barrier layer 20 .
  • oxygen barrier layer 20 is applied to encapsulant 18 by at least one method of a group including, but not limited to, atomic layer deposition, physical vapor deposition, chemical vapor deposition, electrochemical deposition, sol-gel deposition, self-aligned monolayer coating, melting and enameling process, spin coating, spray coat, rolling on, brushing on, sponging on, dip coating, and the like.
  • oxygen barrier layer 20 also covers at least a portion of at least one side surface of package substrate 12 (e.g., oxygen barrier layer 20 extends down the side surfaces of encapsulant 18 and also covers at least a portion of the side surfaces of package substrate 12 ).
  • oxygen barrier layer 20 is formed over encapsulant 18 before solder connections 26 are attached to package substrate 12 , where solder pads for solder connections 26 are masked to prevent oxygen barrier layer 20 from being formed over the solder pads.
  • oxygen barrier layer 20 is formed over encapsulant 18 after solder connections 26 are attached to package substrate 12 , where package substrate 12 and solder connections 26 are masked to prevent oxygen barrier layer 20 from being formed over the bottom surface of package substrate 12 and over solder connections 26 .
  • FIG. 2 illustrates a block diagram depicting a cross-sectional view of another example packaged semiconductor device 200 in which the present disclosure is implemented.
  • Packaged semiconductor device 200 includes oxygen barrier layer 20 formed over a top surface of encapsulant 18 .
  • oxygen barrier layer 20 is formed on the top surface of encapsulant 18 before packaged semiconductor device 200 is singulated from a group of packaged semiconductor devices formed on a single package substrate (e.g., a “chocolate bar” structure). Once singulated, oxygen barrier layer 20 remains on the top surface of encapsulant 18 of packaged semiconductor device 200 , while the side surfaces of encapsulant 18 are exposed to the ambient environment.
  • the amount of oxidation affecting the packaged semiconductor device is proportional to the exposed surface area of encapsulant 18 .
  • the presence of oxygen barrier layer 20 over the top surface of encapsulant 18 reduces or eliminates oxygen exposure to encapsulant 18 , which reduces or eliminates the oxidation resulting from such oxygen exposure, which in turn reduces or eliminates the warpage of the packaged semiconductor device resulting from such oxidation.
  • the surface area of the top surface of encapsulant 18 is much greater (e.g., eight times greater) than the surface area of the exposed side surfaces of encapsulant 18 , indicating that reduction of oxidation over the top surface of encapsulant 18 reduces or eliminates warpage of the packaged semiconductor device, despite encapsulant 18 having exposed side surfaces.
  • forming oxygen barrier layer 20 before singulation provides some benefit, such as simplifying the fabrication process and reducing fabrication costs and resources needed to produce the packaged semiconductor device. Aspects of oxygen barrier layer 20 are discussed above in connection with FIG. 1 .
  • FIG. 3 illustrates a block diagram depicting a cross-sectional view of another example packaged semiconductor device 300 in which the present disclosure is implemented.
  • Packaged semiconductor device 300 includes oxygen barrier layer 20 formed over a top surface of encapsulant 18 , over side surfaces of encapsulant 18 , over side surfaces of package substrate 12 , and over a bottom surface of package substrate 12 .
  • the amount of oxidation affecting the packaged semiconductor device is proportional to the surface area of encapsulant 18 and package substrate 12 that is exposed to the ambient environment.
  • oxygen barrier layer 20 is formed after packaged semiconductor device 300 has been singulated from a group of packaged semiconductor devices formed from a single package substrate (e.g., a “chocolate bar” structure).
  • oxygen barrier layer 20 is formed over top and side surfaces of encapsulant 18 and over bottom and side surfaces of package substrate 12 to provide increased protection against oxygen exposure to encapsulant 18 and package substrate 12 from the ambient environment (e.g., coating top and side surfaces of encapsulant 18 and bottom and side surfaces of package substrate 12 with oxygen barrier layer 20 minimizes exposed surface area of encapsulant 18 and package substrate 12 ).
  • oxygen barrier layer 20 is formed over top and side surfaces of encapsulant 18 and bottom and side surfaces of package substrate 12 before solder connections 26 are attached to package substrate 12 , where solder pads for solder connections 26 are masked to prevent oxygen barrier layer 20 from being formed over the solder pads. In other embodiments, oxygen barrier layer 20 is formed over top and side surfaces of encapsulant 18 and bottom and side surfaces of package substrate 12 after solder connections 26 are attached to package substrate 12 , where solder connections 26 are masked to prevent oxygen barrier layer 20 from being formed over solder connections 26 . Aspects of oxygen barrier layer 20 are discussed above in connection with FIG. 1 .
  • FIG. 4 illustrates a block diagram depicting a cross-sectional view of another example packaged semiconductor device 400 in which the present disclosure is implemented.
  • Packaged semiconductor device 400 includes oxygen barrier layer 20 formed over a top surface of encapsulant 18 and a bottom surface of package substrate 12 .
  • oxygen barrier layer 20 is formed on the top surface of encapsulant 18 and on the bottom surface of package substrate 12 before packaged semiconductor device 400 is singulated from a group of packaged semiconductor devices formed on a single package substrate (e.g., a “chocolate bar” structure).
  • oxygen barrier layer 20 remains on the top surface of encapsulant 18 and on the bottom surface of package substrate 12 of packaged semiconductor device 400 , while the side surfaces of encapsulant 18 and package substrate 12 are exposed to the ambient environment.
  • the presence of oxygen barrier layer 20 over the top surface of encapsulant 18 and the bottom surface of package substrate 12 reduces or eliminates oxygen exposure to encapsulant 18 and package substrate 12 , despite encapsulant 18 and package substrate 12 having exposed side surfaces.
  • the oxidation resulting from such oxygen exposure is reduced or eliminated, which in turn reduces or eliminates the warpage of the packaged semiconductor device resulting from such oxidation.
  • oxygen barrier layer 20 is formed over a top surface of encapsulant 18 and a bottom surface package substrate 12 before solder connections 26 are attached to package substrate 12 , where solder pads for solder connections 26 are masked to prevent oxygen barrier layer 20 from being formed over the solder pads. In other embodiments, oxygen barrier layer 20 is formed over a top surface of encapsulant 18 and a bottom surface of package substrate 12 after solder connections 26 are attached to package substrate 12 , where solder connections 26 are masked to prevent oxygen barrier layer 20 from being formed over solder connections 26 . Aspects of oxygen barrier layer 20 are discussed above in connection with FIG. 1 .
  • FIG. 5 illustrates side views contrasting warpage of example packaged semiconductor devices.
  • Surface curve 28 represents a maximum curvature of a bottom surface of a first packaged semiconductor device that has an encapsulant but does not have an oxygen barrier layer.
  • Surface curve 30 represents a maximum curvature of a bottom surface of a second packaged semiconductor device that has both encapsulant and oxygen barrier layer (such as those packaged semiconductor devices illustrated in FIGS. 1-4 and 6 - 7 ).
  • Warpage of the first and second packaged semiconductor devices is illustrated as the curvature of the surface curves 28 and 30 , respectively.
  • a first amount of warpage 34 of the first packaged semiconductor device is measured as the difference between a center point of surface curve 28 to an edge point of surface curve 28 .
  • a second amount of warpage 32 of the second packaged semiconductor device is measured as the difference between a center point of surface curve 30 to an edge point of surface curve 30 .
  • warpage amount 32 is much smaller than warpage amount 34 (e.g., eight times smaller), indicating that the second packaged semiconductor device (with the oxygen barrier layer) has less warpage than the first packaged semiconductor device (without the oxygen barrier layer).
  • An example warpage amount 34 includes, but is not limited to, 100 to 300 microns, such as 160 microns.
  • An example warpage amount 32 includes, but is not limited to, 20 to 100 microns, such as 80 microns. In some embodiments, an example warpage amount 32 is also less than 65 microns.
  • Warpage amount 32 and 34 may be lesser or greater depending upon the thickness and stiffness of the package substrate, the thickness of the encapsulant, and the ratio of the encapsulant thickness to oxygen barrier layer thickness (where warpage may become more severe in packaged semiconductor devices that have a thin encapsulant thickness, as compared to oxygen barrier layer thickness).
  • FIG. 6 illustrates a block diagram depicting a cross-sectional view of an example packaged semiconductor device 600 in which the present disclosure is implemented.
  • Packaged semiconductor device 600 includes encapsulant 18 , oxygen barrier layer 40 , and an encapsulant layer 42 reaching a total thickness 36 , which is measured from the top surface of the package substrate 12 to a top surface of encapsulant layer 42 .
  • encapsulant layer 42 includes the same encapsulant material(s) as encapsulant 18 .
  • encapsulant layer 42 is a different encapsulant material than encapsulant 18 .
  • a partial thickness 38 is illustrated as some percentage of total thickness 36 , which is measured from the top surface of layer 42 to the dotted line positioned at the percentage of thickness 36 .
  • partial thickness 38 is 50% of total thickness 36 .
  • partial thickness 38 is less than 50% of total thickness 36 , such as 33% or 25% of total thickness 36 .
  • Oxygen barrier layer 40 is formed within some portion of partial thickness 38 .
  • encapsulant 18 is formed over package substrate 12
  • oxygen barrier layer 40 is formed over encapsulant 18
  • encapsulant layer 42 is formed over oxygen barrier layer 40 .
  • oxygen barrier layer 40 is non-uniformly diffused through a portion of encapsulant 18 within partial thickness 38 , while in other embodiments, oxygen barrier layer 40 is uniformly diffused through a portion of encapsulant 18 within partial thickness 38 .
  • a non-uniform encapsulant layer 42 is present over at least a portion of oxygen barrier layer 40
  • a uniform encapsulant layer 48 is present over at least a portion of oxygen barrier layer 40 .
  • oxygen barrier layer 40 is formed along a surface of a mold structure cavity
  • packaged semiconductor device 600 is positioned into the mold structure cavity
  • encapsulant 18 is formed in the negative space between oxygen barrier layer 40 and package substrate 12 , die 16 , die attach material 14 , and wire bonds 22 and 24 .
  • FIG. 7 illustrates a block diagram depicting a cross-sectional view of an example packaged semiconductor device 700 in which the present disclosure is implemented.
  • Packaged semiconductor device 700 includes a package substrate 50 (such as package substrate 12 , including a flip chip package substrate, as discussed above), a die 54 (such as die 16 , as discussed above), and encapsulant 52 (such as encapsulant 18 , as discussed above) that underfills the negative space between die 54 and a top surface of package substrate 50 .
  • packaged semiconductor device 700 also includes a plurality of solder connections 58 .
  • Packaged semiconductor device 700 also includes oxygen barrier layer 56 formed over encapsulant 52 to reduce or eliminate oxygen exposure to encapsulant 52 .
  • oxygen barrier layer 56 also covers a portion of at least one side surface of die 54 .
  • oxygen barrier layer 56 also covers at least a portion of a top surface of die 54 , while in other embodiments, oxygen barrier layer 56 covers the entire top surface of die 54 .
  • oxygen barrier layer 56 also covers at least a portion of a top exposed surface of package substrate 50 , while in other embodiments oxygen barrier layer 56 covers the entire top exposed surface of package substrate 50 .
  • oxygen barrier layer 56 also covers a portion of at least one side surface of package substrate 50 , while in other embodiments, oxygen barrier layer 56 covers the entire side surface(s) of package substrate 50 .
  • the oxygen barrier layer reduces or eliminates oxygen exposure to materials used in a packaged semiconductor device, which reduces or eliminates the oxidation resulting from such oxygen exposure in an ambient environment, which in turn reduces or eliminates the warpage of the packaged semiconductor device resulting from such oxidation.
  • the present disclosure provides an embodiment of a packaged semiconductor device including a substrate; an electronic device coupled to the substrate; encapsulant including a first major surface surrounding the electronic device; and an oxygen barrier layer within fifty percent of a thickness of the encapsulant from a second major surface of the encapsulant.
  • the oxygen barrier covers at least a portion of an area of the second major surface of the encapsulant, where a thickness of the oxygen barrier layer is less than 100 microns.
  • One aspect of the above embodiment further provides that the oxygen barrier is in direct contact with the second major surface of the encapsulant.
  • Another aspect of the above embodiment further provides that the thickness of the oxygen barrier layer is greater than 1 nanometer.
  • the packaged semiconductor device further includes the oxygen barrier layer covers at least one sidewall of the encapsulant.
  • the packaged semiconductor device further includes the oxygen barrier layer covers at least a portion of a major surface of the substrate.
  • the oxygen barrier layer is made of one of a group consisting of: ceramic coating, ceramic oxide coating, zirconium oxide coating, alumina coating, synthetic rubber based coating, butyl rubber with filler, nitrile rubber with filler, polyurethane based coating, silicone based coating, silsesquioxane based coatings, and polymeric material with or without filler.
  • oxygen barrier layer is applied by one of a group consisting of: atomic layer deposition, physical vapor deposition, chemical vapor deposition, electrochemical deposition, sol-gel deposition, self-aligned monolayer coating, melting and enameling process, spin coating, spray coat, rolling on, brushing on, sponging on, dip coating.
  • the oxygen barrier layer includes a first layer of a first material and a second layer of a second material.
  • the present disclosure provides an embodiment of a method, which includes encapsulating a semiconductor device on a substrate in an encapsulant; and adding a layer of oxygen barrier material to the encapsulant, where a thickness of the oxygen barrier material is less than 100 microns.
  • the adding the oxygen barrier material is performed by one of a group consisting of: embedding the oxygen barrier material within fifty percent of a thickness of the encapsulant from a first major surface of the encapsulant, applying the oxygen barrier material over the first major surface of the encapsulant, and applying the oxygen barrier material to a surface of a mold cavity before the encapsulant is injected into the mold cavity.
  • One aspect of the above embodiment further provides that the method further includes applying the oxygen barrier material to at least one sidewall of the encapsulant.
  • Another aspect of the above embodiment further provides that the method further includes applying the oxygen barrier to at least a portion of a surface of the substrate.
  • Another aspect of the above embodiment further provides that the applying the oxygen barrier material is performed at one of a time consisting of: after the encapsulating and before the encapsulating.
  • Another aspect of the above embodiment further provides that the oxygen barrier material extends over at least a portion of an area of the first major surface of the encapsulant.
  • the present disclosure provides another embodiment of a packaged semiconductor device that includes a substrate; an electronic device coupled to the substrate; encapsulant including a first major surface surrounding the electronic device; and oxygen barrier material covering at least a portion of a second major surface of the encapsulant, where a thickness of the oxygen barrier material is less than 100 microns.
  • One aspect of the above embodiment further provides that the oxygen barrier material is in direct contact with the second major surface of the encapsulant.
  • Another aspect of the above embodiment further provides that the thickness of the oxygen barrier material is greater than 1 nanometer.
  • Another aspect of the above embodiment further provides that the oxygen barrier material covers at least one sidewall of the encapsulant.
  • Another aspect of the above embodiment further provides that the oxygen barrier material covers at least a portion of a major surface of the substrate.
  • the oxygen barrier material includes a first layer of a first material and a second layer of a second material.
  • a form factor of the packaged semiconductor device is one of a group consisting of: a through-hole, surface mount, chip carrier, pin grid array, flat package, small outline package, chip-scale package, redistributed chip package, wafer level fan-out, and ball grid array.
  • the semiconductor substrate described herein can be any semiconductor material or combinations of materials, such as gallium arsenide, silicon germanium, silicon-on-insulator (SOI), silicon, monocrystalline silicon, the like, and combinations of the above.
  • SOI silicon-on-insulator
  • Coupled is not intended to be limited to a direct coupling or a mechanical coupling.

Landscapes

  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Computer Hardware Design (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Structures Or Materials For Encapsulating Or Coating Semiconductor Devices Or Solid State Devices (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)

Abstract

A packaged semiconductor device includes a substrate, an electronic device coupled to the substrate, encapsulant including a first major surface surrounding the electronic device, and an oxygen barrier layer within fifty percent of a thickness of the encapsulant from a second major surface of the encapsulant. The oxygen barrier covers at least a portion of an area of the second major surface of the encapsulant to help reduce or eliminate warping of the encapsulant and/or the substrate of the packaged semiconductor device due to oxidation. A thickness of the oxygen barrier layer is less than 100 microns.

Description

    BACKGROUND
  • 1. Field
  • This disclosure relates generally to semiconductor devices, and more specifically, to minimizing warpage of packaged semiconductor devices.
  • 2. Related Art
  • Warpage or deformation of a packaged semiconductor device is a common problem experienced in testing and real world environments. In some cases, warpage greatly affects the reliability and functionality of packaged semiconductor devices.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • The present invention may be better understood, and its numerous objects, features, and advantages made apparent to those skilled in the art by referencing the accompanying drawings.
  • FIG. 1-4 illustrates block diagrams depicting cross-sectional views of example packaged semiconductor devices in which the disclosure is implemented, according to some embodiments.
  • FIG. 5 illustrates side views contrasting warpage of example packaged semiconductor devices, according to some embodiments.
  • FIG. 6-7 illustrates block diagrams depicting cross-sectional views of other example packaged semiconductor devices in which the disclosure is implemented, according to some embodiments.
  • The present invention is illustrated by way of example and is not limited by the accompanying figures, in which like references indicate similar elements, unless otherwise noted. Elements in the figures are illustrated for simplicity and clarity and have not necessarily been drawn to scale.
  • DETAILED DESCRIPTION
  • The following sets forth a detailed description of various embodiments intended to be illustrative of the invention and should not be taken to be limiting.
  • Overview
  • Materials used in packaged semiconductor devices oxidize when exposed to oxygen in the ambient environment. Oxidation is dependent upon various factors such as temperature, time, and material thickness. Oxidation of a semiconductor material often densifies the material, which may result in shrinkage of the material. Such shrinkage induces residual stresses in a packaged semiconductor device and causes warpage or deformation of the packaged semiconductor device. For example, when an encapsulant over a packaged semiconductor device oxidizes, the encapsulant densifies and shrinks, which results in the encapsulant “pulling” up on the sides of the packaged semiconductor device, which causes the packaged semiconductor device to warp. Warpage influences coplanarity of the packaged semiconductor device, where solder connections of a warped packaged semiconductor device are no longer coplanar within a same contact plane (e.g., the solder connections fail to make electrical contact with external pads). Warpage also affects board level device testing and reliability, where a packaged semiconductor device will experience extreme warpage after exposure to testing conditions that accelerate oxidation (e.g., 175° C. at 504 hours, or 150° C. at 1008 hours). The effects of oxidation will be increasingly damaging as packaged semiconductor devices become smaller and thinner.
  • The present disclosure provides for structures and methods to minimize warpage of a packaged semiconductor device by the presence of an oxygen barrier layer on one or more surfaces of a packaged semiconductor device. The oxygen barrier layer reduces or eliminates oxygen exposure to materials used in a packaged semiconductor device, which reduces or eliminates the oxidation resulting from such oxygen exposure in an ambient environment, which in turn reduces or eliminates the warpage of the packaged semiconductor device resulting from such oxidation.
  • Example Embodiments
  • FIG. 1 illustrates a block diagram depicting a cross-sectional view of an example packaged semiconductor device 100 in which the present disclosure is implemented. Packaged semiconductor device 100 includes a package substrate 12 having a top surface, a die 16 attached to the top surface of package substrate 12 with die attach material 14, and wire bonds 22 and 24 providing electrical connections between die 16 and package substrate 12. Packaged semiconductor device 100 also includes an encapsulant 18 formed over the top surface of package substrate 12, where encapsulant 18 surrounds and covers die 16 and wire bonds 22 and 24. Encapsulant 18 may include one or more layers of encapsulant materials. Packaged semiconductor device 100 also includes an oxygen barrier layer 20 formed over a top surface of encapsulant 18, as well as over side surfaces of encapsulant 18, where the side surfaces may or may not be perpendicular to the top surface of encapsulant 18. In some embodiments, packaged semiconductor device 100 also includes a plurality of solder connections 26 that are attached to the bottom surface of package substrate 12 and provide external connections, where the bottom surface of package substrate 12 is opposite the top surface of package substrate 12. In other embodiments, packaged semiconductor device 100 does not include solder connections 26.
  • Examples of die attach material 14 include polymer adhesives, epoxies, solders, films, and the like. Examples of package substrate 12 include, but are not limited to, a ball grid array (BGA) package substrate, redistributed chip package (RCP) substrate, flip chip package substrate, wire bond BGA package substrate, enhanced wafer level BGA package substrate, fan out wafer level package substrate, a land grid array (LGA) package substrate, a pin grid array (PGA) package substrate, flat package substrate, small outline package substrate, chip-scale package substrate, a die pad of a lead frame, lead fingers of a lead frame, and other form factors including a die mounting structure, a surface mount, a through-hole, a chip carrier, and the like. Examples of die 16 include, but are not limited to, an integrated circuit (IC) die, a semiconductor die including a semiconductor substrate, a sensor die, a passive component such as a resistor, a capacitor, an inductor, a battery, an oscillator, and the like, a sensor device, and the like. Examples of encapsulant 18 include, but are not limited to, mold compound, epoxy, underfill, glob top, dam and fill, and the like.
  • Oxygen barrier layer 20 includes one or more layers of an oxygen barrier material that reduces or eliminates oxygen exposure to encapsulant 18 from the ambient environment by preventing diffusion of oxygen through the one or more layers. The oxygen barrier material is also thermally stable and has good adhesion to materials used in packaged semiconductor devices. In some embodiments, the amount of oxidation affecting the packaged semiconductor device is proportional to the surface area of encapsulant 18 that is exposed to the ambient environment. The presence of oxygen barrier material reduces or eliminates oxygen exposure to encapsulant 18, which reduces or eliminates the oxidation resulting from such oxygen exposure from the ambient environment, which in turn reduces or eliminates the warpage of the packaged semiconductor device resulting from such oxidation. The presence of oxygen barrier layer 20 may be beneficial in packaged semiconductor devices having an encapsulant thickness of 500 microns or less over the die, and may be especially beneficial in ultra thin packaged semiconductor devices having a total thickness of 500 microns or less.
  • In some embodiments, oxygen barrier layer 20 has a thickness that is less than 100 micrometers (microns). In some embodiments, oxygen barrier layer 20 has a thickness that is also greater than 1 nanometer. In some embodiments, oxygen barrier layer 20 has a thickness that is also greater than 10 nanometers. In some embodiments, oxygen barrier layer 20 has a thickness in the range of 1 to 5 microns. Oxygen barrier layer 20 may be formed from one or more organic (e.g., polymers, synthetic rubbers) or inorganic (e.g., ceramic oxides) oxygen barrier materials. Examples of oxygen barrier materials include, but are not limited to, ceramic coating, ceramic oxide coating, zirconium oxide coating, alumina coating, synthetic rubber based coating, butyl rubber with filler, nitrile rubber with filler, polyurethane based coating, silicone based coating, silsesquioxane based coatings, and polymeric material with or without filler, and the like.
  • In some embodiments, oxygen barrier layer 20 is formed over encapsulant 18 after packaged semiconductor device 100 has been singulated from a group of packaged semiconductor devices formed from a single package substrate (e.g., a “chocolate bar” structure). In the embodiment shown in FIG. 1, oxygen barrier layer 20 covers top and side surfaces of encapsulant 18 to provide increased protection against oxygen exposure to encapsulant 18 from the ambient environment (e.g., coating top and side surfaces of encapsulant 18 with oxygen barrier layer 20 minimizes exposed surface area of encapsulant 18).
  • Oxygen barrier layer 20 is formed by some method of applying oxygen barrier material to encapsulant 18. In some embodiments, oxygen barrier layer 20 is formed by some method of spraying packaged semiconductor device 100 with oxygen barrier layer 20 to coat encapsulant 18. In other embodiments, oxygen barrier layer 20 is formed by some method of dipping packaged semiconductor device 100 into oxygen barrier material in order to coat encapsulant 18 with oxygen barrier layer 20. In still other embodiments, oxygen barrier layer 20 is applied to encapsulant 18 by at least one method of a group including, but not limited to, atomic layer deposition, physical vapor deposition, chemical vapor deposition, electrochemical deposition, sol-gel deposition, self-aligned monolayer coating, melting and enameling process, spin coating, spray coat, rolling on, brushing on, sponging on, dip coating, and the like.
  • In some embodiments, oxygen barrier layer 20 also covers at least a portion of at least one side surface of package substrate 12 (e.g., oxygen barrier layer 20 extends down the side surfaces of encapsulant 18 and also covers at least a portion of the side surfaces of package substrate 12). In some embodiments, oxygen barrier layer 20 is formed over encapsulant 18 before solder connections 26 are attached to package substrate 12, where solder pads for solder connections 26 are masked to prevent oxygen barrier layer 20 from being formed over the solder pads. In other embodiments, oxygen barrier layer 20 is formed over encapsulant 18 after solder connections 26 are attached to package substrate 12, where package substrate 12 and solder connections 26 are masked to prevent oxygen barrier layer 20 from being formed over the bottom surface of package substrate 12 and over solder connections 26.
  • FIG. 2 illustrates a block diagram depicting a cross-sectional view of another example packaged semiconductor device 200 in which the present disclosure is implemented. Packaged semiconductor device 200 includes oxygen barrier layer 20 formed over a top surface of encapsulant 18. In some embodiments, oxygen barrier layer 20 is formed on the top surface of encapsulant 18 before packaged semiconductor device 200 is singulated from a group of packaged semiconductor devices formed on a single package substrate (e.g., a “chocolate bar” structure). Once singulated, oxygen barrier layer 20 remains on the top surface of encapsulant 18 of packaged semiconductor device 200, while the side surfaces of encapsulant 18 are exposed to the ambient environment.
  • As discussed above, the amount of oxidation affecting the packaged semiconductor device is proportional to the exposed surface area of encapsulant 18. The presence of oxygen barrier layer 20 over the top surface of encapsulant 18 reduces or eliminates oxygen exposure to encapsulant 18, which reduces or eliminates the oxidation resulting from such oxygen exposure, which in turn reduces or eliminates the warpage of the packaged semiconductor device resulting from such oxidation. The surface area of the top surface of encapsulant 18 is much greater (e.g., eight times greater) than the surface area of the exposed side surfaces of encapsulant 18, indicating that reduction of oxidation over the top surface of encapsulant 18 reduces or eliminates warpage of the packaged semiconductor device, despite encapsulant 18 having exposed side surfaces. Further, forming oxygen barrier layer 20 before singulation provides some benefit, such as simplifying the fabrication process and reducing fabrication costs and resources needed to produce the packaged semiconductor device. Aspects of oxygen barrier layer 20 are discussed above in connection with FIG. 1.
  • FIG. 3 illustrates a block diagram depicting a cross-sectional view of another example packaged semiconductor device 300 in which the present disclosure is implemented. Packaged semiconductor device 300 includes oxygen barrier layer 20 formed over a top surface of encapsulant 18, over side surfaces of encapsulant 18, over side surfaces of package substrate 12, and over a bottom surface of package substrate 12. In some embodiments, the amount of oxidation affecting the packaged semiconductor device is proportional to the surface area of encapsulant 18 and package substrate 12 that is exposed to the ambient environment.
  • In some embodiments, oxygen barrier layer 20 is formed after packaged semiconductor device 300 has been singulated from a group of packaged semiconductor devices formed from a single package substrate (e.g., a “chocolate bar” structure). In the embodiment shown in FIG. 3, oxygen barrier layer 20 is formed over top and side surfaces of encapsulant 18 and over bottom and side surfaces of package substrate 12 to provide increased protection against oxygen exposure to encapsulant 18 and package substrate 12 from the ambient environment (e.g., coating top and side surfaces of encapsulant 18 and bottom and side surfaces of package substrate 12 with oxygen barrier layer 20 minimizes exposed surface area of encapsulant 18 and package substrate 12).
  • In some embodiments, oxygen barrier layer 20 is formed over top and side surfaces of encapsulant 18 and bottom and side surfaces of package substrate 12 before solder connections 26 are attached to package substrate 12, where solder pads for solder connections 26 are masked to prevent oxygen barrier layer 20 from being formed over the solder pads. In other embodiments, oxygen barrier layer 20 is formed over top and side surfaces of encapsulant 18 and bottom and side surfaces of package substrate 12 after solder connections 26 are attached to package substrate 12, where solder connections 26 are masked to prevent oxygen barrier layer 20 from being formed over solder connections 26. Aspects of oxygen barrier layer 20 are discussed above in connection with FIG. 1.
  • FIG. 4 illustrates a block diagram depicting a cross-sectional view of another example packaged semiconductor device 400 in which the present disclosure is implemented. Packaged semiconductor device 400 includes oxygen barrier layer 20 formed over a top surface of encapsulant 18 and a bottom surface of package substrate 12. In some embodiments, oxygen barrier layer 20 is formed on the top surface of encapsulant 18 and on the bottom surface of package substrate 12 before packaged semiconductor device 400 is singulated from a group of packaged semiconductor devices formed on a single package substrate (e.g., a “chocolate bar” structure). Once singulated, oxygen barrier layer 20 remains on the top surface of encapsulant 18 and on the bottom surface of package substrate 12 of packaged semiconductor device 400, while the side surfaces of encapsulant 18 and package substrate 12 are exposed to the ambient environment. As discussed above, the presence of oxygen barrier layer 20 over the top surface of encapsulant 18 and the bottom surface of package substrate 12 reduces or eliminates oxygen exposure to encapsulant 18 and package substrate 12, despite encapsulant 18 and package substrate 12 having exposed side surfaces. The oxidation resulting from such oxygen exposure is reduced or eliminated, which in turn reduces or eliminates the warpage of the packaged semiconductor device resulting from such oxidation.
  • In some embodiments, oxygen barrier layer 20 is formed over a top surface of encapsulant 18 and a bottom surface package substrate 12 before solder connections 26 are attached to package substrate 12, where solder pads for solder connections 26 are masked to prevent oxygen barrier layer 20 from being formed over the solder pads. In other embodiments, oxygen barrier layer 20 is formed over a top surface of encapsulant 18 and a bottom surface of package substrate 12 after solder connections 26 are attached to package substrate 12, where solder connections 26 are masked to prevent oxygen barrier layer 20 from being formed over solder connections 26. Aspects of oxygen barrier layer 20 are discussed above in connection with FIG. 1.
  • FIG. 5 illustrates side views contrasting warpage of example packaged semiconductor devices. Surface curve 28 represents a maximum curvature of a bottom surface of a first packaged semiconductor device that has an encapsulant but does not have an oxygen barrier layer. Surface curve 30 represents a maximum curvature of a bottom surface of a second packaged semiconductor device that has both encapsulant and oxygen barrier layer (such as those packaged semiconductor devices illustrated in FIGS. 1-4 and 6-7). Warpage of the first and second packaged semiconductor devices is illustrated as the curvature of the surface curves 28 and 30, respectively. A first amount of warpage 34 of the first packaged semiconductor device is measured as the difference between a center point of surface curve 28 to an edge point of surface curve 28. A second amount of warpage 32 of the second packaged semiconductor device is measured as the difference between a center point of surface curve 30 to an edge point of surface curve 30.
  • As illustrated, warpage amount 32 is much smaller than warpage amount 34 (e.g., eight times smaller), indicating that the second packaged semiconductor device (with the oxygen barrier layer) has less warpage than the first packaged semiconductor device (without the oxygen barrier layer). An example warpage amount 34 includes, but is not limited to, 100 to 300 microns, such as 160 microns. An example warpage amount 32 includes, but is not limited to, 20 to 100 microns, such as 80 microns. In some embodiments, an example warpage amount 32 is also less than 65 microns. Warpage amount 32 and 34 may be lesser or greater depending upon the thickness and stiffness of the package substrate, the thickness of the encapsulant, and the ratio of the encapsulant thickness to oxygen barrier layer thickness (where warpage may become more severe in packaged semiconductor devices that have a thin encapsulant thickness, as compared to oxygen barrier layer thickness).
  • FIG. 6 illustrates a block diagram depicting a cross-sectional view of an example packaged semiconductor device 600 in which the present disclosure is implemented. Packaged semiconductor device 600 includes encapsulant 18, oxygen barrier layer 40, and an encapsulant layer 42 reaching a total thickness 36, which is measured from the top surface of the package substrate 12 to a top surface of encapsulant layer 42. In some embodiments, encapsulant layer 42 includes the same encapsulant material(s) as encapsulant 18. In other embodiments, encapsulant layer 42 is a different encapsulant material than encapsulant 18. In the embodiment shown, a partial thickness 38 is illustrated as some percentage of total thickness 36, which is measured from the top surface of layer 42 to the dotted line positioned at the percentage of thickness 36. In some embodiments, partial thickness 38 is 50% of total thickness 36. In other embodiments, partial thickness 38 is less than 50% of total thickness 36, such as 33% or 25% of total thickness 36. Oxygen barrier layer 40 is formed within some portion of partial thickness 38. In some embodiments, encapsulant 18 is formed over package substrate 12, oxygen barrier layer 40 is formed over encapsulant 18, and encapsulant layer 42 is formed over oxygen barrier layer 40.
  • In some embodiments, oxygen barrier layer 40 is non-uniformly diffused through a portion of encapsulant 18 within partial thickness 38, while in other embodiments, oxygen barrier layer 40 is uniformly diffused through a portion of encapsulant 18 within partial thickness 38. In some embodiments, a non-uniform encapsulant layer 42 is present over at least a portion of oxygen barrier layer 40, while in other embodiments, a uniform encapsulant layer 48 is present over at least a portion of oxygen barrier layer 40. In some embodiments, oxygen barrier layer 40 is formed along a surface of a mold structure cavity, packaged semiconductor device 600 is positioned into the mold structure cavity, and encapsulant 18 is formed in the negative space between oxygen barrier layer 40 and package substrate 12, die 16, die attach material 14, and wire bonds 22 and 24.
  • FIG. 7 illustrates a block diagram depicting a cross-sectional view of an example packaged semiconductor device 700 in which the present disclosure is implemented. Packaged semiconductor device 700 includes a package substrate 50 (such as package substrate 12, including a flip chip package substrate, as discussed above), a die 54 (such as die 16, as discussed above), and encapsulant 52 (such as encapsulant 18, as discussed above) that underfills the negative space between die 54 and a top surface of package substrate 50. In some embodiments, packaged semiconductor device 700 also includes a plurality of solder connections 58.
  • Packaged semiconductor device 700 also includes oxygen barrier layer 56 formed over encapsulant 52 to reduce or eliminate oxygen exposure to encapsulant 52. In some embodiments, oxygen barrier layer 56 also covers a portion of at least one side surface of die 54. In some embodiments, oxygen barrier layer 56 also covers at least a portion of a top surface of die 54, while in other embodiments, oxygen barrier layer 56 covers the entire top surface of die 54. In some embodiments, oxygen barrier layer 56 also covers at least a portion of a top exposed surface of package substrate 50, while in other embodiments oxygen barrier layer 56 covers the entire top exposed surface of package substrate 50. In some embodiments, oxygen barrier layer 56 also covers a portion of at least one side surface of package substrate 50, while in other embodiments, oxygen barrier layer 56 covers the entire side surface(s) of package substrate 50.
  • By now it should be appreciated that there has been provided embodiments of methods and packaged semiconductor devices for minimizing warpage of a packaged semiconductor device by the presence of an oxygen barrier layer on one or more surfaces of a packaged semiconductor device. The oxygen barrier layer reduces or eliminates oxygen exposure to materials used in a packaged semiconductor device, which reduces or eliminates the oxidation resulting from such oxygen exposure in an ambient environment, which in turn reduces or eliminates the warpage of the packaged semiconductor device resulting from such oxidation.
  • The present disclosure provides an embodiment of a packaged semiconductor device including a substrate; an electronic device coupled to the substrate; encapsulant including a first major surface surrounding the electronic device; and an oxygen barrier layer within fifty percent of a thickness of the encapsulant from a second major surface of the encapsulant. The oxygen barrier covers at least a portion of an area of the second major surface of the encapsulant, where a thickness of the oxygen barrier layer is less than 100 microns.
  • One aspect of the above embodiment further provides that the oxygen barrier is in direct contact with the second major surface of the encapsulant.
  • Another aspect of the above embodiment further provides that the thickness of the oxygen barrier layer is greater than 1 nanometer.
  • Another aspect of the above embodiment further provides that the packaged semiconductor device further includes the oxygen barrier layer covers at least one sidewall of the encapsulant.
  • Another aspect of the above embodiment further provides that the packaged semiconductor device further includes the oxygen barrier layer covers at least a portion of a major surface of the substrate.
  • Another aspect of the above embodiment further provides that the oxygen barrier layer is made of one of a group consisting of: ceramic coating, ceramic oxide coating, zirconium oxide coating, alumina coating, synthetic rubber based coating, butyl rubber with filler, nitrile rubber with filler, polyurethane based coating, silicone based coating, silsesquioxane based coatings, and polymeric material with or without filler.
  • Another aspect of the above embodiment further provides that the oxygen barrier layer is applied by one of a group consisting of: atomic layer deposition, physical vapor deposition, chemical vapor deposition, electrochemical deposition, sol-gel deposition, self-aligned monolayer coating, melting and enameling process, spin coating, spray coat, rolling on, brushing on, sponging on, dip coating.
  • Another aspect of the above embodiment further provides that the oxygen barrier layer includes a first layer of a first material and a second layer of a second material.
  • The present disclosure provides an embodiment of a method, which includes encapsulating a semiconductor device on a substrate in an encapsulant; and adding a layer of oxygen barrier material to the encapsulant, where a thickness of the oxygen barrier material is less than 100 microns. The adding the oxygen barrier material is performed by one of a group consisting of: embedding the oxygen barrier material within fifty percent of a thickness of the encapsulant from a first major surface of the encapsulant, applying the oxygen barrier material over the first major surface of the encapsulant, and applying the oxygen barrier material to a surface of a mold cavity before the encapsulant is injected into the mold cavity.
  • One aspect of the above embodiment further provides that the method further includes applying the oxygen barrier material to at least one sidewall of the encapsulant.
  • Another aspect of the above embodiment further provides that the method further includes applying the oxygen barrier to at least a portion of a surface of the substrate.
  • Another aspect of the above embodiment further provides that the applying the oxygen barrier material is performed at one of a time consisting of: after the encapsulating and before the encapsulating.
  • Another aspect of the above embodiment further provides that the oxygen barrier material extends over at least a portion of an area of the first major surface of the encapsulant.
  • The present disclosure provides another embodiment of a packaged semiconductor device that includes a substrate; an electronic device coupled to the substrate; encapsulant including a first major surface surrounding the electronic device; and oxygen barrier material covering at least a portion of a second major surface of the encapsulant, where a thickness of the oxygen barrier material is less than 100 microns.
  • One aspect of the above embodiment further provides that the oxygen barrier material is in direct contact with the second major surface of the encapsulant.
  • Another aspect of the above embodiment further provides that the thickness of the oxygen barrier material is greater than 1 nanometer.
  • Another aspect of the above embodiment further provides that the oxygen barrier material covers at least one sidewall of the encapsulant.
  • Another aspect of the above embodiment further provides that the oxygen barrier material covers at least a portion of a major surface of the substrate.
  • Another aspect of the above embodiment further provides that the oxygen barrier material includes a first layer of a first material and a second layer of a second material.
  • Another aspect of the above embodiment further provides that a form factor of the packaged semiconductor device is one of a group consisting of: a through-hole, surface mount, chip carrier, pin grid array, flat package, small outline package, chip-scale package, redistributed chip package, wafer level fan-out, and ball grid array.
  • The semiconductor substrate described herein can be any semiconductor material or combinations of materials, such as gallium arsenide, silicon germanium, silicon-on-insulator (SOI), silicon, monocrystalline silicon, the like, and combinations of the above.
  • Because the apparatus implementing the present invention is, for the most part, composed of electronic components and circuits known to those skilled in the art, circuit details will not be explained in any greater extent than that considered necessary as illustrated above, for the understanding and appreciation of the underlying concepts of the present invention and in order not to obfuscate or distract from the teachings of the present invention.
  • Moreover, the terms “front,” “back,” “top,” “bottom,” “over,” “under” and the like in the description and in the claims, if any, are used for descriptive purposes and not necessarily for describing permanent relative positions. It is understood that the terms so used are interchangeable under appropriate circumstances such that the embodiments of the invention described herein are, for example, capable of operation in other orientations than those illustrated or otherwise described herein.
  • Although the invention is described herein with reference to specific embodiments, various modifications and changes can be made without departing from the scope of the present invention as set forth in the claims below. Accordingly, the specification and figures are to be regarded in an illustrative rather than a restrictive sense, and all such modifications are intended to be included within the scope of the present invention. Any benefits, advantages, or solutions to problems that are described herein with regard to specific embodiments are not intended to be construed as a critical, required, or essential feature or element of any or all the claims.
  • The term “coupled,” as used herein, is not intended to be limited to a direct coupling or a mechanical coupling.
  • Furthermore, the terms “a” or “an,” as used herein, are defined as one or more than one. Also, the use of introductory phrases such as “at least one” and “one or more” in the claims should not be construed to imply that the introduction of another claim element by the indefinite articles “a” or “an” limits any particular claim containing such introduced claim element to inventions containing only one such element, even when the same claim includes the introductory phrases “one or more” or “at least one” and indefinite articles such as “a” or “an.” The same holds true for the use of definite articles.
  • Unless stated otherwise, terms such as “first” and “second” are used to arbitrarily distinguish between the elements such terms describe. Thus, these terms are not necessarily intended to indicate temporal or other prioritization of such elements.

Claims (22)

1. A packaged semiconductor device, comprising:
a substrate;
an electronic device coupled to the substrate;
encapsulant including a first major surface surrounding the electronic device; and
an oxygen barrier layer within fifty percent of a thickness of the encapsulant from a second major surface of the encapsulant, the oxygen barrier covering at least a portion of an area of the second major surface of the encapsulant, wherein a thickness of the oxygen barrier layer is less than 100 microns.
2. The device of claim 1, wherein the oxygen barrier is in direct contact with the second major surface of the encapsulant.
3. The device of claim 1, wherein the thickness of the oxygen barrier layer is greater than 1 nanometer.
4. The device of claim 1, further comprising the oxygen barrier layer covers at least one sidewall of the encapsulant.
5. The device of claim 1, further comprising the oxygen barrier layer covers at least a portion of a major surface of the substrate.
6-7. (canceled)
8. The device of claim 1, wherein the oxygen barrier layer includes a first layer of a first material and a second layer of a second material.
9-13. (canceled)
14. A packaged semiconductor device, comprising:
a substrate having a top surface;
a semiconductor die coupled to the top surface of the substrate;
encapsulant surrounding the semiconductor die and covering at least a portion of the top surface of the substrate, the encapsulant having a first major surface in contact with the top surface of the substrate, and a second major surface opposing the first major surface; and
oxygen barrier material covering at least a portion of the second major surface of the encapsulant, wherein a thickness of the oxygen barrier material is less than 100 microns, and the oxygen barrier material is configured to reduce diffusion of oxygen from an ambient environment to the encapsulant.
15. The device of claim 14, wherein the oxygen barrier material is in direct contact with the second major surface of the encapsulant.
16. The device of claim 14, wherein the thickness of the oxygen barrier material is greater than 1 nanometer.
17. The device of claim 14, further comprising the oxygen barrier material covers at least one sidewall of the encapsulant.
18. The device of claim 14, further comprising the oxygen barrier material covers at least a portion of a bottom surface of the substrate, the bottom surface opposing the top surface of the substrate.
19. The device of claim 14, wherein the oxygen barrier material includes a first layer of a first material and a second layer of a second material.
20. The device of claim 14, wherein a form factor of the packaged semiconductor device is one of a group consisting of: a through-hole, surface mount, chip carrier, pin grid array, flat package, small outline package, chip-scale package, redistributed chip package, wafer level fan-out, and ball grid array.
21. The device of claim 14, wherein the oxygen barrier material includes at least one of a group comprising: ceramic coating, ceramic oxide coating, zirconium oxide coating, alumina coating, synthetic rubber based coating, butyl rubber with filler, nitrile rubber with filler, polyurethane based coating, silicone based coating, silsesquioxane based coatings, and polymeric material with or without filler.
22. The device of claim 14, wherein the oxygen barrier material is applied by at least one of a group comprising: atomic layer deposition, physical vapor deposition, chemical vapor deposition, electrochemical deposition, sol-gel deposition, self-aligned monolayer coating, melting and enameling process, spin coating, spray coat, rolling on, brushing on, sponging on, dip coating.
23. The device of claim 14, further comprising a plurality of connections attached to a bottom surface of the substrate, the bottom surface opposing the top surface of the substrate.
24. The device of claim 14, further comprising a plurality of wire bonds attached to the semiconductor die and the top surface of the substrate, the plurality of wire bonds surrounded by the encapsulant.
25. The device of claim 14, wherein a thickness of the encapsulant is 500 microns or less.
26. The device of claim 14, wherein a warpage of the packaged semiconductor device is within a range of 20 to 100 microns.
27. The device of claim 14, wherein the oxygen barrier material is thermally stable and has good adhesion to materials utilized in the packaged semiconductor device.
US14/472,882 2014-08-29 2014-08-29 Structure and method to minimize warpage of packaged semiconductor devices Abandoned US20160064299A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US14/472,882 US20160064299A1 (en) 2014-08-29 2014-08-29 Structure and method to minimize warpage of packaged semiconductor devices
US15/191,870 US9978614B2 (en) 2014-08-29 2016-06-24 Structure and method to minimize warpage of packaged semiconductor devices

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US14/472,882 US20160064299A1 (en) 2014-08-29 2014-08-29 Structure and method to minimize warpage of packaged semiconductor devices

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US15/191,870 Division US9978614B2 (en) 2014-08-29 2016-06-24 Structure and method to minimize warpage of packaged semiconductor devices

Publications (1)

Publication Number Publication Date
US20160064299A1 true US20160064299A1 (en) 2016-03-03

Family

ID=55403353

Family Applications (2)

Application Number Title Priority Date Filing Date
US14/472,882 Abandoned US20160064299A1 (en) 2014-08-29 2014-08-29 Structure and method to minimize warpage of packaged semiconductor devices
US15/191,870 Expired - Fee Related US9978614B2 (en) 2014-08-29 2016-06-24 Structure and method to minimize warpage of packaged semiconductor devices

Family Applications After (1)

Application Number Title Priority Date Filing Date
US15/191,870 Expired - Fee Related US9978614B2 (en) 2014-08-29 2016-06-24 Structure and method to minimize warpage of packaged semiconductor devices

Country Status (1)

Country Link
US (2) US20160064299A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20160141217A1 (en) * 2014-11-17 2016-05-19 Siliconware Precision Industries Co., Ltd. Electronic package and fabrication method thereof
US20220285309A1 (en) * 2019-08-26 2022-09-08 X-Celeprint Limited Variable stiffness modules
US20240047329A1 (en) * 2022-08-03 2024-02-08 Shinko Electric Industries Co., Ltd. Semiconductor device

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120104591A1 (en) * 2010-10-29 2012-05-03 Conexant Systems, Inc. Systems and methods for improved heat dissipation in semiconductor packages

Family Cites Families (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5355016A (en) * 1993-05-03 1994-10-11 Motorola, Inc. Shielded EPROM package
CN1516251A (en) * 1994-03-18 2004-07-28 �������ɹ�ҵ��ʽ���� Manufacturing method of semiconductor component and semiconductor component
US6583444B2 (en) * 1997-02-18 2003-06-24 Tessera, Inc. Semiconductor packages having light-sensitive chips
KR100249784B1 (en) * 1997-11-20 2000-04-01 정선종 Packaging method of organic or polymer electroluminescent device using polymer composite membrane
US6376769B1 (en) * 1999-05-18 2002-04-23 Amerasia International Technology, Inc. High-density electronic package, and method for making same
US6573652B1 (en) 1999-10-25 2003-06-03 Battelle Memorial Institute Encapsulated display devices
US6541310B1 (en) * 2000-07-24 2003-04-01 Siliconware Precision Industries Co., Ltd. Method of fabricating a thin and fine ball-grid array package with embedded heat spreader
US20020163062A1 (en) * 2001-02-26 2002-11-07 International Business Machines Corporation Multiple material stacks with a stress relief layer between a metal structure and a passivation layer
US20030183915A1 (en) * 2002-04-02 2003-10-02 Motorola, Inc. Encapsulated organic semiconductor device and method
US7042072B1 (en) 2002-08-02 2006-05-09 Amkor Technology, Inc. Semiconductor package and method of manufacturing the same which reduces warpage
DE10238581B4 (en) * 2002-08-22 2008-11-27 Qimonda Ag Semiconductor component
JP4020097B2 (en) 2004-05-11 2007-12-12 セイコーエプソン株式会社 Semiconductor chip, semiconductor device, manufacturing method thereof, and electronic device
KR100970156B1 (en) * 2005-12-08 2010-07-14 후지쯔 세미컨덕터 가부시키가이샤 Semiconductor devices
US7790237B2 (en) * 2006-02-21 2010-09-07 Cbrite Inc. Multilayer films for package applications and method for making same
US7776434B2 (en) 2006-05-12 2010-08-17 General Electric Company Organic matrix composite structures and thermal oxidative barrier coating therefor
JP5028988B2 (en) * 2006-12-13 2012-09-19 ヤマハ株式会社 Manufacturing method of semiconductor device
US7927920B2 (en) * 2007-02-15 2011-04-19 Headway Technologies, Inc. Method of manufacturing electronic component package, and wafer and substructure used for manufacturing electronic component package
KR100875099B1 (en) * 2007-06-05 2008-12-19 삼성모바일디스플레이주식회사 Organic light emitting device and method for manufacturing same
TWI388078B (en) 2008-01-30 2013-03-01 歐斯朗奧托半導體股份有限公司 Electronic component manufacturing method and electronic component
KR20090107882A (en) * 2008-04-10 2009-10-14 삼성전자주식회사 Inclined composition encapsulation thin film comprising a fixed layer and a method of manufacturing the same
WO2009148722A2 (en) * 2008-06-02 2009-12-10 3M Innovative Properties Company Adhesive encapsulating composition and electronic devices made therewith
KR101030381B1 (en) * 2008-11-13 2011-04-20 삼성전기주식회사 Wafer level package and manufacturing method thereof
US8212340B2 (en) * 2009-07-13 2012-07-03 Advanced Semiconductor Engineering, Inc. Chip package and manufacturing method thereof
US8460972B2 (en) * 2009-11-05 2013-06-11 Freescale Semiconductor, Inc. Method of forming semiconductor package
JP5232185B2 (en) * 2010-03-05 2013-07-10 株式会社東芝 Manufacturing method of semiconductor device
US8258012B2 (en) * 2010-05-14 2012-09-04 Stats Chippac, Ltd. Semiconductor device and method of forming discontinuous ESD protection layers between semiconductor die
US9484279B2 (en) * 2010-06-02 2016-11-01 STATS ChipPAC Pte. Ltd. Semiconductor device and method of forming EMI shielding layer with conductive material around semiconductor die
US20120025362A1 (en) 2010-07-30 2012-02-02 Qualcomm Incorporated Reinforced Wafer-Level Molding to Reduce Warpage
US8823186B2 (en) * 2010-12-27 2014-09-02 Shin-Etsu Chemical Co., Ltd. Fiber-containing resin substrate, sealed substrate having semiconductor device mounted thereon, sealed wafer having semiconductor device formed thereon, a semiconductor apparatus, and method for manufacturing semiconductor apparatus
US8872358B2 (en) * 2012-02-07 2014-10-28 Shin-Etsu Chemical Co., Ltd. Sealant laminated composite, sealed semiconductor devices mounting substrate, sealed semiconductor devices forming wafer, semiconductor apparatus, and method for manufacturing semiconductor apparatus
KR20130123682A (en) * 2012-05-03 2013-11-13 삼성전자주식회사 Semiconductor pacakge and method of forming the package
US9349663B2 (en) 2012-06-29 2016-05-24 Taiwan Semiconductor Manufacturing Co., Ltd. Package-on-package structure having polymer-based material for warpage control
US20150236003A1 (en) * 2012-09-14 2015-08-20 Renesas Electronics Corporation Method of manufacturing semiconductor device
US9620413B2 (en) * 2012-10-02 2017-04-11 STATS ChipPAC Pte. Ltd. Semiconductor device and method of using a standardized carrier in semiconductor packaging
US9496195B2 (en) * 2012-10-02 2016-11-15 STATS ChipPAC Pte. Ltd. Semiconductor device and method of depositing encapsulant along sides and surface edge of semiconductor die in embedded WLCSP
JP5934078B2 (en) * 2012-11-19 2016-06-15 信越化学工業株式会社 Fiber-containing resin substrate and method for manufacturing semiconductor device
US9362191B2 (en) * 2013-08-29 2016-06-07 Infineon Technologies Austria Ag Encapsulated semiconductor device
US9978700B2 (en) * 2014-06-16 2018-05-22 STATS ChipPAC Pte. Ltd. Method for building up a fan-out RDL structure with fine pitch line-width and line-spacing
TWI614870B (en) * 2014-07-25 2018-02-11 Siliconware Precision Industries Co., Ltd. Package structure and its manufacturing method

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120104591A1 (en) * 2010-10-29 2012-05-03 Conexant Systems, Inc. Systems and methods for improved heat dissipation in semiconductor packages

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20160141217A1 (en) * 2014-11-17 2016-05-19 Siliconware Precision Industries Co., Ltd. Electronic package and fabrication method thereof
US20220285309A1 (en) * 2019-08-26 2022-09-08 X-Celeprint Limited Variable stiffness modules
US12456706B2 (en) * 2019-08-26 2025-10-28 X-Celeprint Limited Variable stiffness modules
US20240047329A1 (en) * 2022-08-03 2024-02-08 Shinko Electric Industries Co., Ltd. Semiconductor device

Also Published As

Publication number Publication date
US20160307780A1 (en) 2016-10-20
US9978614B2 (en) 2018-05-22

Similar Documents

Publication Publication Date Title
US7595226B2 (en) Method of packaging an integrated circuit die
CN101770958B (en) Protective thin film coating in chip packaging
US7632715B2 (en) Method of packaging semiconductor devices
US9073748B2 (en) Microelectro mechanical system encapsulation scheme
US9978614B2 (en) Structure and method to minimize warpage of packaged semiconductor devices
US10170340B2 (en) Semiconductor structure
CN109887890B (en) Fan-out type inverted packaging structure and preparation method thereof
US20020119605A1 (en) Reworkable encapsulant
US11152274B2 (en) Multi-moldings fan-out package and process
US20200411385A1 (en) Semiconductor structure and manufacturing method thereof
US20150035130A1 (en) Integrated Circuit with Stress Isolation
US11056457B2 (en) Semiconductor device with bond wire reinforcement structure
US20130037931A1 (en) Semiconductor package with a heat spreader and method of making
US7154185B2 (en) Encapsulation method for SBGA
TW201401451A (en) Semiconductor package structure
US8237293B2 (en) Semiconductor package with protective tape
US20110156283A1 (en) Use of die backside films to modulate EOL coplanarity of thin packages while providing thermal capability and laser markability of packages
Lu et al. Adhesion and material properties between polyimide and passivation layers for polymer/metal hybrid bonding in 3-D integration
US11984408B2 (en) Cavity formed in a molding compound of a semiconductor package to reduce mechanical stress on a portion of a die in the package, and methods of formation
Ikeda et al. Mobility change of MOSFETs in a chip‐stacked multichip package
Scalise Plastic encapsulated microcircuits (PEM) qualification testing
US11877505B2 (en) Fluorinated polymers with low dielectric loss for environmental protection in semiconductor devices
Tomiyoshi et al. Development of Epoxy-Silicone Hybrid Polymer and Application for Semiconductor Assembly
Kim et al. New encapsulation process for the SiP (System in Package)
van Weelden et al. The encapsulation of MEMS/sensors and the realization of molded vias on package level and wafer level with film assisted molding

Legal Events

Date Code Title Description
AS Assignment

Owner name: FREESCALE SEMICONDUCTOR, INC., TEXAS

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:LAKHERA, NISHANT;GUAJARDO, JAMES R.;MATHEW, VARUGHESE;AND OTHERS;REEL/FRAME:033639/0012

Effective date: 20140819

AS Assignment

Owner name: CITIBANK, N.A., AS NOTES COLLATERAL AGENT, NEW YORK

Free format text: SUPPLEMENT TO IP SECURITY AGREEMENT;ASSIGNOR:FREESCALE SEMICONDUCTOR, INC.;REEL/FRAME:034160/0370

Effective date: 20141030

Owner name: CITIBANK, N.A., AS NOTES COLLATERAL AGENT, NEW YORK

Free format text: SUPPLEMENT TO IP SECURITY AGREEMENT;ASSIGNOR:FREESCALE SEMICONDUCTOR, INC.;REEL/FRAME:034160/0351

Effective date: 20141030

Owner name: CITIBANK, N.A., AS NOTES COLLATERAL AGENT, NEW YORK

Free format text: SUPPLEMENT TO IP SECURITY AGREEMENT;ASSIGNOR:FREESCALE SEMICONDUCTOR, INC.;REEL/FRAME:034153/0027

Effective date: 20141030

Owner name: CITIBANK, N.A., AS NOTES COLLATERAL AGENT, NEW YOR

Free format text: SUPPLEMENT TO IP SECURITY AGREEMENT;ASSIGNOR:FREESCALE SEMICONDUCTOR, INC.;REEL/FRAME:034160/0370

Effective date: 20141030

Owner name: CITIBANK, N.A., AS NOTES COLLATERAL AGENT, NEW YOR

Free format text: SUPPLEMENT TO IP SECURITY AGREEMENT;ASSIGNOR:FREESCALE SEMICONDUCTOR, INC.;REEL/FRAME:034153/0027

Effective date: 20141030

Owner name: CITIBANK, N.A., AS NOTES COLLATERAL AGENT, NEW YOR

Free format text: SUPPLEMENT TO IP SECURITY AGREEMENT;ASSIGNOR:FREESCALE SEMICONDUCTOR, INC.;REEL/FRAME:034160/0351

Effective date: 20141030

AS Assignment

Owner name: FREESCALE SEMICONDUCTOR, INC., TEXAS

Free format text: PATENT RELEASE;ASSIGNOR:CITIBANK, N.A., AS COLLATERAL AGENT;REEL/FRAME:037357/0921

Effective date: 20151207

AS Assignment

Owner name: MORGAN STANLEY SENIOR FUNDING, INC., MARYLAND

Free format text: ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS;ASSIGNOR:CITIBANK, N.A.;REEL/FRAME:037458/0460

Effective date: 20151207

Owner name: MORGAN STANLEY SENIOR FUNDING, INC., MARYLAND

Free format text: ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS;ASSIGNOR:CITIBANK, N.A.;REEL/FRAME:037458/0502

Effective date: 20151207

AS Assignment

Owner name: MORGAN STANLEY SENIOR FUNDING, INC., MARYLAND

Free format text: SUPPLEMENT TO THE SECURITY AGREEMENT;ASSIGNOR:FREESCALE SEMICONDUCTOR, INC.;REEL/FRAME:039138/0001

Effective date: 20160525

AS Assignment

Owner name: NXP, B.V., F/K/A FREESCALE SEMICONDUCTOR, INC., NETHERLANDS

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:MORGAN STANLEY SENIOR FUNDING, INC.;REEL/FRAME:040925/0001

Effective date: 20160912

Owner name: NXP, B.V., F/K/A FREESCALE SEMICONDUCTOR, INC., NE

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:MORGAN STANLEY SENIOR FUNDING, INC.;REEL/FRAME:040925/0001

Effective date: 20160912

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION

AS Assignment

Owner name: NXP B.V., NETHERLANDS

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:MORGAN STANLEY SENIOR FUNDING, INC.;REEL/FRAME:040928/0001

Effective date: 20160622

AS Assignment

Owner name: NXP B.V., NETHERLANDS

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:MORGAN STANLEY SENIOR FUNDING, INC.;REEL/FRAME:050744/0097

Effective date: 20190903

AS Assignment

Owner name: NXP B.V., NETHERLANDS

Free format text: CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVEAPPLICATION 11759915 AND REPLACE IT WITH APPLICATION11759935 PREVIOUSLY RECORDED ON REEL 040928 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITYINTEREST;ASSIGNOR:MORGAN STANLEY SENIOR FUNDING, INC.;REEL/FRAME:052915/0001

Effective date: 20160622

Owner name: NXP B.V., NETHERLANDS

Free format text: CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040928 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST;ASSIGNOR:MORGAN STANLEY SENIOR FUNDING, INC.;REEL/FRAME:052915/0001

Effective date: 20160622

AS Assignment

Owner name: NXP, B.V. F/K/A FREESCALE SEMICONDUCTOR, INC., NETHERLANDS

Free format text: CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVEAPPLICATION 11759915 AND REPLACE IT WITH APPLICATION11759935 PREVIOUSLY RECORDED ON REEL 040925 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITYINTEREST;ASSIGNOR:MORGAN STANLEY SENIOR FUNDING, INC.;REEL/FRAME:052917/0001

Effective date: 20160912

Owner name: NXP, B.V. F/K/A FREESCALE SEMICONDUCTOR, INC., NETHERLANDS

Free format text: CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040925 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST;ASSIGNOR:MORGAN STANLEY SENIOR FUNDING, INC.;REEL/FRAME:052917/0001

Effective date: 20160912