US20140199491A1

US20140199491A1 - One-component, dual-cure conformal coating compositions

Info

Publication number: US20140199491A1
Application number: US13/956,462
Authority: US
Inventors: Abdullah Ekin; Michael J. Dvorchak
Original assignee: Allnex IP SARL
Current assignee: Allnex IP SARL
Priority date: 2013-01-15
Filing date: 2013-08-01
Publication date: 2014-07-17
Also published as: EP2945974B1; US20150353772A1; EP2945974A1; US9932493B2; TW201441318A; WO2014111311A1

Abstract

Disclosed are one-component compositions that include: (1) an isocyanate-functional urethane acrylate and (2) a polyisocyanate containing allophanate and/or uretdione groups, wherein the one-component composition has a viscosity of less than or equal to about 500 mPas and an isocyanate content of greater than about 5% by weight, based on the weight of the one-component composition. Also disclosed are circuit boards and electronic components that are coated with such compositions.

Description

CROSS REFERENCE TO RELATED APPLICATION

This application claims the benefit, under 35 USC §119(e), of U.S. provisional patent application No. 61/752,548, filed Jan. 15, 2013, entitled “ONE-COMPONENT, DUE-CURE CONFORMAL COATING COMPOSITIONS”, the entire disclosure of which is hereby incorporated by reference.

BACKGROUND OF THE INVENTION

The present invention relates to one-component, dual-curing conformal coating compositions.
Conformal coatings are used to protect circuit boards and electronic components from moisture and from premature corrosion. Polyurethane coatings are a popular choice for conformal coatings due to their high chemical resistance, flexibility, and hardness.
Coatings curable by actinic radiation (e.g. “UV coatings”) find use as conformal coatings as such coatings may be cured relatively quickly by exposure to a radiation source, typically UV light. The fast cure allows manufacturers to increase throughput. However, because circuit boards and other electronic components have highly contoured surfaces, such UV coatings, when used as conformal coatings, suffer from a phenomenon whereby areas of the coating which cannot easily be exposed to UV light due to the contours (i.e. the “shadow” areas) remain uncured.
U.S. Pat. No. 4,424,252 describes the problem of “shadow cure” and solves such problem by the use of dual cure resins. Such resins cure by two mechanisms: a) exposure to UV light and b) curing by atmospheric moisture. The atmospheric moisture reacts with free isocyanate groups in the dual cure resin forming an amine group(s). The amine groups react with other isocyanate groups to form a polyurea. The curing by atmospheric moisture allows the areas of the coatings in the “shadows” to fully cure.
However, dual-cure polyurethane resins have suffered a disadvantage due to their relatively high viscosity. This issue is especially relevant for conformal coatings, due to the contoured shape of the substrate. Low viscosity resins are more favoured from a flowability standpoint—i.e. the low viscosity resins more easily flow around the contours of a circuit board and may more evenly coat such circuit boards.
Previous attempts to lower the viscosity of dual-cure polyurethane resins included adding a significant amount of reactive diluent to the dual-cure polyurethane resins. While the addition of reactive diluents served to lower the viscosity of the resin, it also reduced the wt. % of free isocyanate groups in the resin. This, in turn, has the effect of reducing the effectiveness of the moisture cure mechanism especially in shadow areas, which results in a coating with insufficient hardness and/or solvent resistance in such areas.
An object of the present invention is to provide coating compositions, which are suitable as conformal coatings and are characterized by their ability to be cured by exposure to actinic radiation, their ability to be cured by exposure to atmospheric moisture and their relatively low viscosity.
This object may be obtained with the coating compositions according to the invention, which are described below in greater detail.

SUMMARY OF THE INVENTION

The present invention relates to a one-component composition comprising: (1) an isocyanate-functional urethane (meth)acrylate and (2) a polyisocyanate containing allophanate and/or uretdione groups, wherein the one-component composition has (i) a viscosity of less than or equal to about 500 mPas according to ASTM Standard D 7395-07 using a Brookfield R/S Rheometer at 25° C., 100 s-1 shear rate for 2 minutes with a C-50-1 spindle, and (ii) an isocyanate content of greater than about 5% by weight, based on the weight of the one-component composition.
The present invention also relates to a conformal coating comprising the one-component composition.
Finally, the present invention relates to a circuit board or electronic component coated with the conformal coating.

DETAILED DESCRIPTION OF THE INVENTION

Various embodiments are described and illustrated in this specification to provide an overall understanding of the structure, function, operation, manufacture, and use of the disclosed products and processes. It is understood that the various embodiments described and illustrated in this specification are non-limiting and non-exhaustive. Thus, the invention is not limited by the description of the various non-limiting and non-exhaustive embodiments disclosed in this specification. Rather, the invention is defined solely by the claims. The features and characteristics illustrated and/or described in connection with various embodiments may be combined with the features and characteristics of other embodiments. Such modifications and variations are intended to be included within the scope of this specification. As such, the claims may be amended to recite any features or characteristics expressly or inherently described in, or otherwise expressly or inherently supported by, this specification. Further, Applicant reserves the right to amend the claims to affirmatively disclaim features or characteristics that may be present in the prior art. Therefore, any such amendments comply with the requirements of 35 U.S.C. §112, first paragraph, and 35 U.S.C. §132(a). The various embodiments disclosed and described in this specification can comprise, consist of, or consist essentially of the features and characteristics as variously described herein.
Any patent, publication, or other disclosure material identified herein is incorporated by reference into this specification in its entirety unless otherwise indicated, but only to the extent that the incorporated material does not conflict with existing definitions, statements, or other disclosure material expressly set forth in this specification. As such, and to the extent necessary, the express disclosure as set forth in this specification supersedes any conflicting material incorporated by reference herein. Any material, or portion thereof, that is said to be incorporated by reference into this specification, but which conflicts with existing definitions, statements, or other disclosure material set forth herein, is only incorporated to the extent that no conflict arises between that incorporated material and the existing disclosure material. Applicant reserves the right to amend this specification to expressly recite any subject matter, or portion thereof, incorporated by reference herein.
Reference throughout this specification to “various non-limiting embodiments,” or the like, means that a particular feature or characteristic may be included in an embodiment. Thus, use of the phrase “in various non-limiting embodiments,” or the like, in this specification does not necessarily refer to a common embodiment, and may refer to different embodiments. Further, the particular features or characteristics may be combined in any suitable manner in one or more embodiments. Thus, the particular features or characteristics illustrated or described in connection with various embodiments may be combined, in whole or in part, with the features or characteristics of one or more other embodiments without limitation. Such modifications and variations are intended to be included within the scope of the present specification. In this manner, the various embodiments described in this specification are non-limiting and non-exhaustive.
In this specification, other than where otherwise indicated, all numerical parameters are to be understood as being prefaced and modified in all instances by the term “about”, in which the numerical parameters possess the inherent variability characteristic of the underlying measurement techniques used to determine the numerical value of the parameter. At the very least, and not as an attempt to limit the application of the doctrine of equivalents to the scope of the claims, each numerical parameter described in the present description should at least be construed in light of the number of reported significant digits and by applying ordinary rounding techniques.
Also, any numerical range recited in this specification is intended to include all sub-ranges subsumed within the recited range. For example, a range of “1 to 10” is intended to include all sub-ranges between (and including) the recited minimum value of 1 and the recited maximum value of 10, that is, having a minimum value equal to or greater than 1 and a maximum value equal to or less than 10. Any maximum numerical limitation recited in this specification is intended to include all lower numerical limitations subsumed therein and any minimum numerical limitation recited in this specification is intended to include all higher numerical limitations subsumed therein. Accordingly, Applicant reserves the right to amend this specification, including the claims, to expressly recite any sub-range subsumed within the ranges expressly recited herein. All such ranges are intended to be inherently described in this specification such that amending to expressly recite any such sub-ranges would comply with the requirements of 35 U.S.C. §112, first paragraph, and 35 U.S.C. §132(a).
The grammatical articles “one”, “a”, “an”, and “the”, as used in this specification, are intended to include “at least one” or “one or more”, unless otherwise indicated. Thus, the articles are used in this specification to refer to one or more than one (i.e., to “at least one”) of the grammatical objects of the article. By way of example, “a component” means one or more components, and thus, possibly, more than one component is contemplated and may be employed or used in an implementation of the described embodiments. Further, the use of a singular noun includes the plural, and the use of a plural noun includes the singular, unless the context of the usage requires otherwise.
In accordance with the present invention the term “(cyclo)aliphatically bound isocyanate groups” means aliphatically and/or cycloaliphatically bound isocyanate groups. As used herein, the term (meth)acrylate encompasses acrylates and methacrylates.
The present invention relates to a one-component composition comprising: (1) an isocyanate-functional urethane (meth)acrylate and (2) a polyisocyanate containing allophanate and/or uretdione groups, wherein the one-component composition has a viscosity of less than or equal to about 500 mPas, such as less than or equal 450 mPas or less than or equal 400 mPas at 25° C. according to ASTM Standard D 7395-07 and an isocyanate content of greater than about 5% by weight, such as at least 6%, at least 7% or, in some cases, at least 7.5%, and/or up to 15% by weight, based on the weight of the one-component composition.
As used herein, the term “one-component composition” refers to a composition in which all of the composition components, including, but not necessarily limited to, components (1) and (2) are stored together in a single container, such as a moisture-free container, until such time as the composition is to be used, such as by application to a substrate, including, for example, a substrate that is a circuit board or electronic component. The “one-component compositions” of the present invention are contrasted with two-part or two-component compositions in which components of the composition are stored separately and then combined at or near the time of use.
In certain embodiments, the compositions of the present invention are themselves substantially, or, in some cases, completely free of any isocyanate-reactive components, which, as used herein, refers to materials that contain functional groups, such as aminic, hydroxyl, or thiol groups, that are reactive towards isocyanate groups. As used herein, the term “substantially free” when used in this context means that any isocyanate-reactive component present in the composition is not present in an amount sufficient to render the composition unsuitable for use as a one-component composition. In other words, the isocyanate-reactive component is not present in an amount sufficient such that, due to its reaction with the isocyanate-containing components 1) and 2), the one-component composition would gel in the container, thereby rendering it unsuitable to be applied as a thin-film coating to a substrate.
In certain embodiments, the one-component compositions of the present invention are high solids compositions, which, as used herein, means that the total solids content of the composition is at least 90 percent by weight, at least 95 percent by weight, or, in some cases, at least 99 percent by weight, the weight percents being based on the total weight of the one-component composition. Indeed, it was surprising to achieve such high-solids, one-component, dual cure compositions, having the viscosities and isocyanate content described herein.
Component (1) is an isocyanate-functional urethane (meth)acrylate, as described in, for example, U.S. Pat. No. 6,599,955, the entirety of which is incorporated herein by reference. Isocyanate-functional urethane (meth)acrylates are prepared from monohydric alcohols containing (meth)acryloyl groups and di- or polyisocyanates. The urethane (meth)acrylates according to the present invention contain free isocyanate groups, prepared generally as described above, but with the equivalent ratio of NCO (isocyanate) groups to OH (hydroxyl) groups being 1:0.2 to 1:0.8, such as 1:0.3 to 1:0.6.
Monohydric alcohols containing (meth)acryloyl groups are understood as including both esters, containing a free hydroxyl group, of acrylic acid or methacrylic acid with dihydric alcohols, such as 2-hydroxyethyl, 2- or 3-hydroxypropyl or 2-, 3- or 4-hydroxybutyl (meth)acrylate, and mixtures of such compounds. Monohydric alcohols containing (meth)acryloyl groups or reaction products substantially containing such alcohols, which are obtained by esterification of n-hydric alcohols with (meth)acrylic acid, are also possible. It is also possible to employ mixtures of different alcohols, so that n represents an integer or a fractional number from 2 to 4, in which 3(n−0.8) to (n−1.2), such as (n−1) mol of (meth)acrylic acid is employed per mol of the alcohols mentioned. These compounds or product mixtures include the reaction products of (i) glycerol, trimethylolpropane and/or pentaerythritol, low molecular weight alkoxylation products of such alcohols (such as ethoxylated or propoxylated trimethylolpropane, for example the addition product of ethylene oxide on trimethylolpropane of OH number 550), or of mixtures of such at least trihydric alcohols with dihydric alcohols (such as ethylene glycol or propylene glycol), with (ii) (meth)acrylic acid in the molar ratio mentioned.
These compounds often have a number-average molecular weight M_nof 116 g/mole to 1,000 g/mole, such as 116 to 750 g/mole, or, in some cases, 116 to 158 g/mole as determined by gel permeation chromatography (GPC) using polystyrene standards according to ASTM Standard D 5296-11.
Some specific examples of suitable (meth)acrylate-functional materials include hydroxymethyl (meth)acrylate, hydroxyethyl (meth)acrylate (HEA), hydroxypropyl (meth)acrylate (HPA), trimethylol propane di(meth)acrylate, pentaerythritol tri(meth)acrylate, GAMA ((meth)acrylic acid adduct of glycidyl (meth)acrylate), which can include the two isomers
CH₂═CH—C(O)—O—CH₂CH(OH)CH₂—O—C(O)—C(CH₃)CH₂
and
CH₁₂═CH—C(O)—O—CH(CH₂OH)CH₂—O—C(O)—C(CH₃)CH₂,
or a polycaprolactone hydroxy ethyl (meth)acrylate (PCHEA) can be used, however any hydroxyl functional (meth)acrylate can be used as described in the above defined structure.
In a particular embodiment of the invention, PCHEA is used either alone or in mixtures with other hydroxy functional (meth)acrylates to achieve low viscosity materials.
In an additional embodiment of the invention, the PCHEA is TONE® M 100 (poly(ε-caprolactone) ester of 2-hydroxyethyl acrylate) available from DOW Chemical Corp., Midland Mich.
In another particular embodiment of the invention, HEA or HPA are useful as the sole hydroxy functional (meth)acrylate, however, in some cases, these materials tend to crystallize, so that the resin cannot be used neat, but must be dissolved. Solvents, typically ester, ether or hydrocarbon solvents can be used. Esters which are particularly useful also have acrylic functionality, such as hexanediol diacrylate, which would make the solution 100% reactive under UV/EB conditions.
Suitable di- or polyisocyanates include aromatic, araliphatic, cycloaliphatic, and aliphatic compounds, aliphatic compounds being preferred. Examples include butylene-diisocyanate, hexamethylene-diisocyanate (HDI), isophorone-diisocyanate (IPDI), trimethylhexamethylene-diisocyanate (2,2,4- and/or 2,4,4-trimethylhexa-methylene-diisocyanate), neopentyl diisocyanate, dicyclohexylmethane-diisocyanate or 4-isocyanatomethyl-1,8-octane-diisocyanate and derivatives of these diisocyanates containing with a urethane, isocyanurate, allophanate, biuret, uretdione and/or iminooxadiazinedione groups. Di- or polyisocyanates which contain urethane groups and are based on di- or polyisocyanates and dihydric alcohols are also suitable.
Examples of suitable isocyanate-functional urethane acrylates are the commercially available DESMOLUX® line from Bayer MaterialScience LLC in Pittsburgh, Pa. DESMOLUX® D100, DESMOLUX® VPLS 2396, DESMOLUX® XP 2510, and Desmolux® D 200XP are specific examples.
In certain embodiments, component (1) is present in the one-component composition of the present invention in an amount of at least 10 percent by weight, such as at least 20 percent by weight, at least 30 percent by weight, or, in some cases, at least 40 percent by weight and/or no more than 90 percent by weight, no more than 80 percent by weight, no more than 70 percent by weight, or, in some cases, no more than 60 percent by weight, all of these weight percents being based on the total weight of the coating composition.
Useful as component (2) of the one-component coating composition are polyisocyanates containing uretdione and/or allophanate groups.
Suitable polyisocyanates containing uretdione groups include, for example, uretdione diisocyanates prepared by oligomerizing a portion of the isocyanate groups of a diisocyanate in the presence of a suitable catalyst, e.g., a trialkyl phosphine catalyst. Suitable polyisocyanates containing allophanate groups include, for example, those prepared according to the processes disclosed in U.S. Pat. Nos. 3,769,318, 4,160,080, 4,177,342, and 6,392,011. In some embodiments, the catalyst for the preparation of these polyisocyanates include organic tin(II) salts such as tin(II) octoate.
In the compositions of the present invention the polyisocyanates containing uretdione and/or allophanate groups may be used in admixture with other aliphatic and/or cycloaliphatic polyisocyanates. For example, and without limitation, such other aliphatic and/or cycloaliphatic polyisocyanates can include: (1) an isocyanurate group-containing polyisocyanate, such as may be prepared as set forth in DE-PS 2,616,416, EP-OS 3,765, EP-OS 10,589, EP-OS 47,452, U.S. Pat. No. 4,288,586 and U.S. Pat. No. 4,324,879; and/or (2) biuret group-containing polyisocyanates, such as may be prepared according to the processes disclosed in U.S. Pat. Nos. 3,124,605; 3,358,010; 3,644,490; 3,862,973; 3,903,126; 3,903,127; 4,051,165; 4,147,714; or 4,220,749 by using co-reactants such as water, tertiary alcohols, primary and secondary monoamines, and primary and/or secondary diamines.
Examples of suitable polyisocyanates which may be used in the polyisocyanate component include a) polyisocyanate adducts and b) isocyanate prepolymers having an average functionality of 1.5 to 6, such as 1.8 to 6, 2 to 6 or, in some cases, 2 to 4.
The polyisocyanates adducts often have an average functionality of 2 to 6, such as 2 to 4, and an isocyanate content of 5 to 30% by weight, such as 10 to 25% by weight and, in some cases, 15 to 25% by weight.
Suitable polyisocyanates include the commercially available DESMODUR® line from Bayer MaterialScience LLC in Pittsburgh, Pa. Specific allophanate-containing polyisocyanates include DESMODUR® XP 2580 and specific uretdione-containing polyisocyanates include DESMODUR® XP 2730.
In certain embodiments, the isocyanate groups of components (1) and (2) are at least partially unblocked. As such, embodiments of the one component compositions of the present invention are capable of cure at low temperatures, including temperatures of less than 100° C. or less than 50° C.
In certain embodiments, component (2) is present in the one-component composition of the present invention in an amount of at least 1 percent by weight, such as at least 5 percent by weight, or, in some cases, at least 10 percent by weight and/or no more than 50 percent by weight, no more than 40 percent by weight, no more than 30 percent by weight, or, in some cases, no more than 20 percent by weight, all of these weight percents being based on the total weight of the coating composition.
In some embodiments, the one-component compositions comprise a reactive diluent in addition to the reactive components described above. Suitable reactive diluents include, for example, vinyl ethers and mono-, di, or higher-functional (meth)acrylate monomers, such as those monomers that contain at least 4, at least 6, at least 8, at least 9, or, in some cases, at least 10 carbon atoms in the alkyl moiety (which may be linear, branched, alicyclic, substituted, or unsubstituted, for example). Exemplary mono-(meth)acrylates suitable for use in the present invention include butyl (meth)acrylates, hexyl (meth)acrylate, pentyl (meth)acrylates, heptyl (meth)acrylates, octyl (meth)acrylates, 2-ethylhexyl (meth)acrylate, nonyl (meth)acrylates, decyl (meth)acrylates, bornyl (meth)acrylates, such as isobornyl (meth)acrylate, dicyclopentanyl (meth)acrylates, cyclohexyl (meth)acrylates, lauryl (meth)acrylates, stearyl (meth)acrylates, alkoxyalkyl (meth)acrylates, such as butoxyethyl acrylate, among others. Exemplary di- or higher-(meth)acrylates suitable for use in the present invention include ethylene glycol di(meth)acrylate; dipropylene glycol diacrylate; hexanediol di(meth)acrylate; triethylene glycol di(meth)acrylate; tetraethylene glycol di(meth)acrylate; trimethylolpropane tri(meth)acrylate; ethoxylated trimethylolpropane tri(meth)acrylate; glycerol tri(meth)acrylate; pentaerythritol tri(meth)acrylate; pentaerythritol tetra(meth)acrylate; neopentylglycol di(meth)acrylate.
In certain embodiments, the reactive diluent is present in an amount of up to 50 percent by weight, such as 10 to 50 percent by weight, or, in some cases, 30 to 50 percent by weight, based on the total weight of the composition.
The coating compositions according to the invention can be mixed with known additives. These include fillers, pigments, dyestuffs, thixotropic agents, levelling agents, matting agents or flow agents, which are employed in the conventional amounts.
The application of the coating compositions of the invention to the material to be coated takes place with the methods known and customary in coatings technology, such as spraying, knife coating, curtain coating, vacuum coating, rolling, pouring, dipping, spin coating, squeegeeing, brushing or squirting or by means of printing techniques such as screen, gravure, flexographic or offset printing and also by means of transfer methods.
UV curing is initiated in the presence of photoinitiators. Suitable photoinitiators include, for example, aromatic ketone compounds, such as benzophenones, alkylbenzophenones, Michler's ketone, anthrone and halogenated benzophenones. Further suitable compounds include, for example, 2,4,6-trimethylbenzoyldiphenylphosphine oxide, phenylglyoxylic acid esters, anthraquinone and the derivatives thereof, benzil ketals and hydroxyalkyl-phenones. Illustrative of additional suitable photoinitiators include 2,2-diethoxyacetophenone; 2- or 3- or 4-bromoacetophenone; 3- or 4-allyl-acetophenone; 2-acetonaphthone; benzaldehyde; benzoin; the alkyl benzoin ethers; benzophenone; benzoquinone; 1-chloroanthraquinone; p-diacetyl-benzene; 9,10-dibromoanthracene 9,10-dichloroanthracene; 4,4-dichlorobenzophenone; thioxanthone; isopropyl-thioxanthone; methylthioxanthone; α,α,α-trichloro-para-t-butyl acetophenone; 4-methoxybenzophenone; 3-chloro-8-nonylxanthone; 3-iodo-7-methoxyxanthone; carbazole; 4-chloro-4′-benzylbenzophenone; fluoroene; fluoroenone; 1,4-naphthylphenylketone; 1,3-pentanedione; 2,2-di-sec.-butoxy acetophenone; dimethoxyphenyl acetophenone; propiophenone; isopropylthioxanthone; chlorothioxanthone; xanthone; maleimides and their derivatives; and mixtures thereof. There are several suitable photoinitiators commercially available from Ciba including Irgacure® 184 (1-hydroxy-cyclohexyl-phenyl-ketone), Irgacure® 819 (bis(2,4,6-trimethylbenzoyl)-phenylphosphineoxide), Irgacure® 1850 (a 50/50 mixture of bis(2,6-dimethoxybenzoyl)-2,4,4-trimethylpentyl-phosphine oxide and 1-hydroxy-cyclohexyl-phenyl-ketone), Irgacure® 1700 (a 25/75 mixture of bis(2,6-dimethoxybenzoyl)-2,4,4-trimethylpentyl-phosphine oxide and 2-hydroxy-2-methyl-1-phenyl-propan-1-one), Irgacure® 907 (2-methyl-1[4-(methylthio)phenyl]-2-morpholonopropan-1-one), Darocur® MBF (a phenyl glyoxylic acid methyl ester), Irgacure® 2022 Photoinitiator blend (20% by weight of phenylbis(2,3,6-trimethyl benzoyl)phosphine oxide and 80% by weight of 2-hydroxy-2-methyl-1-phenyl-1-propanone) and Darocur® 4265 (a 50/50 mixture of bis(2,4,6-trimethylbenzoyl)-phenylphosphineoxide and 2-hydroxy-2-methyl-1-phenyl-propan-1-one). Mixtures of the foregoing photoinitiators may also be used. The foregoing lists are meant to be illustrative only and are not meant to exclude any suitable photoinitiators.
Those skilled in the art of photochemistry are fully aware that photoactivators can be used in combination with the aforementioned photoinitiators and that synergistic effects are sometimes achieved when such combinations are used. Photoactivators are well known in the art and require no further description to make known what they are and the concentrations at which they are effective. Nonetheless, one can mention as illustrative of suitable photoactivators, methylamine, tributylamine, methyldiethanolamine, 2-aminoethylethanolamine, allylamine, cyclohexylamine, cyclopentadienylamine, diphenylamine, ditolylamine, trixylylamine, tribenzylamine, n-cyclohexylethylen-eimine, piperidine, N-methylpiperazine, 2,2-dimethyl-1,3-bis(3-N-morpholinyl)-propionyloxypropane, and mixtures thereof.
The radiation can be provided by any suitable source such as UV lamps having with or reduced infrared emission or UV lamps fitted with filters to eliminate infrared emissions or so-called LEDs (light-emitting devices) emitting radiation in the wavelength noted. Particularly useful commercially available devices include: the Fusion and Nordson high-intensity microwave powered lamps (mercury, iron doped and gallium doped lamps), high-intensity standard arc lamps, the Panacol UV 1H-254 lamp (available from Panacol-Elosol GmbH)—a 250 W ozone-free, iron doped metal halide lamp with spectral wavelength of from 320 to 450 nm; Panacol UVF-450 (320 nm to 450 nm depending on the black, blue or clear filter used); Honle UVA HAND 250 CUL (available from Honle UV America Inc.)—emitting maximum intensity UVA range of ˜320 to 390 nm; PMP 250 watt metal halide lamp (available from Pro Motor Car Products Inc.); Cure-Tek UVA-400 (available from H&S Autoshot) which has a 400-watt metal halide bulb and the lamp assembly can be fitted with different filters like blue, light blue or clear to control/eliminate the infra-red radiation from the lamp source); Con-Trol-Cure Scarab-250 UV-A shop lamp system (available from UV Process Supply Inc.—has a 250 W iron doped metal halide lamp with a spectral wavelength output of 320 to 450 nm); Con-Trol-Cure—UV LED Cure-All 415 (available from UV Process Supply Inc.—spectral wavelength of 415 nm with a 2.5 to 7.95 W operating wattage range); Con-Trol-Cure—UV LED Cure-All 390 (available from UV Process Supply Inc.—spectral wavelength of 390 nm with a 2.76 to 9.28 W operating wattage range); UV H253 UV lamp (available from UV Light Technologies—the unit contained a 250 W iron doped metal halide lamp fitted with a black glass filter to produce a spectral wavelength of between 300 and 400 nm); Radion RX10 module curing using solid state high intensity UV light source from Phoseon Technology; Low intensity microwave UV System Model QUANT-18/36 (available from Quantum Technologies—UV Intensity range: 3-30 mW/cm2; UV Spectral range: 330-390 nm); WorkLED (available from Inretech Technologies using 400 nm LED arrays); Flashlight MC with 20×LED adapter (available from Inretech Technologies using 400 nm LEDs); and Phillips TL03 lamp with radiation output above 380 nm; and sunlight.
In the following examples all parts and percentages are weight percentages, unless otherwise indicated.

EXAMPLES

Materials Used in the Examples

Desmolux® D 100 (NCO containing aliphatic urethane acrylate, Bayer MaterialScience LLC, Pittsburgh, Pa.); Desmolux® VPLS 2396 (NCO containing aliphatic urethane acrylate, Bayer MaterialScience LLC, Pittsburgh, Pa.); Desmolux® XP 2510 (NCO containing aliphatic urethane acrylate, Bayer MaterialScience LLC, Pittsburgh, Pa.); Desmodur® XP 2730 (low viscosity uretdione-containing polyisocyanate, Bayer MaterialScience LLC, Pittsburgh, Pa.); Miramer® M200 (Hexanedioldiacrylate (reactive diluent) Rahn USA Corp. Aurora, Ill.); Genomer® 1121 (isobornyl acrylate (reactive diluent) Rahn USA Corp. Aurora, Ill.); Tinopal® OB (optical brightener, BASF Florham Park, N.J.); Byk® 371 (flow and levelling additive, Wallingford, Conn.); Irgacure® 819 (photoinitiator, BASF Florham Park, N.J.); Darocur® 1173 (photoinitiator, BASF Florham Park, N.J.); p-toluenesulfonyl isocyanate (moisture scavenger, VanDeMark Chemical Inc. Lockport, N.Y.).

Formulation Details

Formulations; A, B, D, O, P, Q, R, and S were prepared using similar procedures. Miramer M200, Genomer 1121, Tinopal OB, Byk 371, Irgacure 819, Darocur 1173 (non isocyanate containing ingredients) were mixed in a tin can and moisture content was measured by Karl Fischer Titration according to ASTM D6304-07. After measuring the water content theoretical amount of moisture scavenger p-toluenesulfonyl isocyanate was calculated. To be on the safe side and ensure all moisture is scavenged 10% excess p-toluenesulfonyl isocyanate was calculated. Finally Desmolux D 100, Desmolux VPLS 2396, Desmolux XP 2510, Desmodur XP 2730 were added into the formulation.
As used herein, parts means parts by weight.
The Example A (Comparison) formulation was prepared as follows: 40 parts of Miramer M200, 40 parts of Genomer 1121, 0.2 parts of Tinopal OB, 1.8 parts of Byk 371, and 5.4 parts Irgacure 819 were mixed in a tin can. The can was attached to an overhead stirrer. Moisture content was measured using Karl Fischer Titration according to ASTM D6304-07. With 10% excess moisture scavenger it was calculated that 1.26 parts p-toluenesulfonyl isocyanate is needed. While solution was mixing with an overhead stirrer, 1.26 part of p-toluenesulfonyl isocyanate was added into the solution. The resulting formulation was mixed for 30 minutes to ensure the consumption of all the moisture. Finally 90 parts Desmolux D 100 and 10 parts Desmolux VPLS 2396 were added into the formulation while stirring. The resulting formulation was stirred for 5 minutes and purged with nitrogen before covering it with the lid. The formulation made was left at room temperature to de aerate.
Examples B, D, O, P, Q, R, and S were prepared utilizing the procedure set forth for Comparative Example A, utilizing the materials and amounts (parts) set forth in Table 1 below.

Application and Testing Details

Viscosities of the formulations were measured according to ASTM Standard D 7395-07 using a Brookfield R/S Rheometer at 25° C., 100 s-1 shear rate for 2 minutes with a C-50-1 spindle. “Initial viscosity” refers to the viscosity of the composition at the time it was made and “final viscosity” refers to the viscosity of the composition at storage for 6 months at ambient conditions.
Coatings for microhardness tests were prepared by applying 2 mils of formulations onto Bonderite® B1000 cold rolled steel panels. Microhardness (Marten's hardness) measurements were done using Fischerscope H100C instrument with the method DIN 14577. Microhardness readings were taken under a 30 mN test load run to a maximum of 5 μm indentation depth over a 20 second application time. Results were reported as an average of 3 readings for each formulation.
Coatings for MEK double rubs were prepared by applying 2 mils of formulations onto Bonderite B1000 cold rolled steel panels. MEK double rubs were measured using the method ASTM D4752-10.

Cure Details

The coatings were cured with Fusion UV equipment under 400 Watt Hg bulb at 10 feet/minute. To finalize the moisture cure component UV cured panels were left in a dark constant humidity and temperature room for 2 weeks. (If 0.1% catalyst dibutyltin diluarate is used, 3 days is enough for moisture cure)
For moisture curing only, the panels were not subjected to UV light and placed in a dark constant humidity and temperature room for 2 weeks. (If 0.1% catalyst dibutyltin diluarate is used, 3 days is enough for moisture cure)

	TABLE 1

	Example

Ingredient	A	B	D	O	P	Q	R	S

Desmolux ® D 100	90	50	—	50	50	—	—	—
Desmolux ® VP LS 2396	10	50	100	50	50	50	50	50
Desmolux ® XP 2510	—	—	—	—	—	50	50	50
Desmodur ® XP 2730	—	—	—	20	30	40	30	20
Miramar ® M200	40	40	40	30	25	40	50	60
Genomer ® 1121	40	40	40	30	25	—	—	—
Tinopal ® OB	0.2	0.2	0.2	0.2	0.2	0.2	0.2	0.2
BYK ® 371	1.8	1.8	1.8	1.8	1.8	1.8	1.8	1.8
Irgacure ® 819	5.4	5.4	5.4	5.4	5.4	—	—	—
Darocur ® 1173	—	—	—	—	—	7.2	9	9
p-Toluenesulfonyl Isocyanate	1.26	1.26	1.26	1.26	1.26	1.26	1.26	1.26
Weight Solids	99.43	99.43	99.43	99.43	99.43	96.81	96.84	96.84
Wt/Gal	8.88	8.93	8.99	9.05	9.11	9.29	9.23	9.18
Volume Solids	99.29	99.29	99.28	99.28	99.27	95.94	96.01	96.03
% NCO	6.5	5.38	3.98	7.79	8.99	8.5	7.24	6.05
P/B	0	0	0	0	0	0.3	0.29	0.29
Theoretical VOC	0.05	0.05	0.05	0.05	0.05	0.05	0.05	0.05
PVC	0.09	0.09	0.09	0.1	0.1	0.1	0.1	0.1
Initial Viscosity (mPas)	500	510	525	480	425	690	327	240
Final Viscosity (mPas)	600	770	650	575	635	—	—	—
Microhardness (mN/mm2)	73	72	86	153	193	123	113	129
MEK Double Rubs	>200	>200	>200	>200	>200	>200	>200	>200
MEK Double Rubs	5	5	5	20	25	20	20	15
(moisture cure only)

Although the invention has been described in detail in the foregoing for the purpose of illustration, it is to be understood that such detail is solely for that purpose and that variations can be made therein by those skilled in the art without departing from the spirit and scope of the invention except as it may be limited by the claims.

Claims

What is claimed is:

1. A one-component composition comprising:

1) an isocyanate functional urethane (meth)acrylate and

2) a polyisocyanate containing allophanate and/or uretdione groups,

wherein the one-component composition has:

(i) a viscosity of less than or equal to about 500 mPas according to ASTM Standard D 7395-07 using a Brookfield R/S Rheometer at 25° C., 100 s-1 shear rate for 2 minutes with a C-50-1 spindle, and

(ii) an isocyanate content of greater than about 5% by weight, based on the weight of the one-component composition.

2. The one-component composition of claim 1, wherein the solids content of the composition is at least 90 percent by weight, based on the total weight of the one-component composition.

3. The one-component composition of claim 1, wherein the solids content of the composition is at least 95 percent by weight, based on the total weight of the one-component composition.

4. The one-component composition of claim 1, wherein component 1) is a reaction product of a composition comprising: (a) a monohydric alcohol comprising (meth)acryloyl groups; and (b) a di- or polyisocyanate.

5. The one-component composition of claim 4, wherein the monohydric alcohol containing (meth)acryloyl groups comprises hydroxmethyl (meth)acrylate, hydroxyethyl (meth)acrylate, hydroxypropyl (meth)acrylate, trimethylol propane di(meth)acrylate, pentaerythritol tri(meth)acrylate, a (meth)acrylic acid adduct of glycidyl (meth)acrylate, and/or a polycaprolactone hydroxy ethyl (meth)acrylate.

6. The one-component composition of claim 4, wherein the monohydric alcohol containing (meth)acryloyl groups comprises a polycaprolactone hydroxy ethyl (meth)acrylate.

7. The one-component composition of claim 6, wherein the polycaprolactone hydroxy ethyl (meth)acrylate comprises a poly(ε-caprolactone) ester of 2-hydroxyethyl acrylate.

8. The one-component composition of claim 1, wherein component 1) is present in an amount of at least 40 percent by weight, based on the total weight of the coating composition.

9. The one-component composition of claim 1, wherein component 1) is present in an amount of no more than 60 percent by weight, based on the total weight of the coating composition.

10. The one-component composition of claim 1, wherein component 2) comprises a polyisocyanate containing uretdione groups.

11. The one-component composition of claim 1, wherein component 2) is present in an amount of at least 10 percent by weight and no more than no more than 30 percent by weight, based on the total weight of the coating composition.

12. The one-component composition of claim 1, further comprising a reactive diluent comprising a mono-functional (meth)acrylate monomer containing at least 6 carbon atoms in the alkyl moiety that is present in an amount of up to 50 percent by weight, based on the total weight of the composition.

13. The one-component composition of claim 1, wherein the composition has an isocyanate content of greater than about 6% by weight and a solids content of at least 95 percent by weight, based on the total weight of the composition.

14. A method comprising depositing the composition of claim 1 over at least a portion of a substrate and exposing the coated substrate to actinic radiation.

15. The method of claim 14, wherein the substrate comprises a circuit board or electronic component.