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US20140196865A1 - Heat exchanger - Google Patents

Heat exchanger Download PDF

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Publication number
US20140196865A1
US20140196865A1 US14/238,906 US201214238906A US2014196865A1 US 20140196865 A1 US20140196865 A1 US 20140196865A1 US 201214238906 A US201214238906 A US 201214238906A US 2014196865 A1 US2014196865 A1 US 2014196865A1
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US
United States
Prior art keywords
heat
boiler
heat exchanger
recited
frame
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US14/238,906
Inventor
Dhiti Towiwat
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from TH1101001578A external-priority patent/TH1101001578A/en
Application filed by Individual filed Critical Individual
Publication of US20140196865A1 publication Critical patent/US20140196865A1/en
Abandoned legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D20/00Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
    • F28D20/0056Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using solid heat storage material
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24HFLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H7/00Storage heaters, i.e. heaters in which the energy is stored as heat in masses for subsequent release
    • F24H7/02Storage heaters, i.e. heaters in which the energy is stored as heat in masses for subsequent release the released heat being conveyed to a transfer fluid
    • F24H7/04Storage heaters, i.e. heaters in which the energy is stored as heat in masses for subsequent release the released heat being conveyed to a transfer fluid with forced circulation of the transfer fluid
    • F24H7/045Storage heaters, i.e. heaters in which the energy is stored as heat in masses for subsequent release the released heat being conveyed to a transfer fluid with forced circulation of the transfer fluid using fluid fuel
    • F24H7/0458Storage heaters, i.e. heaters in which the energy is stored as heat in masses for subsequent release the released heat being conveyed to a transfer fluid with forced circulation of the transfer fluid using fluid fuel the transfer fluid being air
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24HFLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H9/00Details
    • F24H9/18Arrangement or mounting of grates or heating means
    • F24H9/1809Arrangement or mounting of grates or heating means for water heaters
    • F24H9/1832Arrangement or mounting of combustion heating means, e.g. grates or burners
    • F24H9/1836Arrangement or mounting of combustion heating means, e.g. grates or burners using fluid fuel
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D17/00Regenerative heat-exchange apparatus in which a stationary intermediate heat-transfer medium or body is contacted successively by each heat-exchange medium, e.g. using granular particles
    • F28D17/02Regenerative heat-exchange apparatus in which a stationary intermediate heat-transfer medium or body is contacted successively by each heat-exchange medium, e.g. using granular particles using rigid bodies, e.g. of porous material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/14Thermal energy storage

Definitions

  • the present invention relates to combustion system, heat storage and heat release for combustion or other processes in connection with combustion, heat storage and heat release.
  • Boiler has been currently designed to allow one or the combination of three forms of heat exchange; namely heat conduction, heat convection and heat radiation.
  • heat radiation is normally capable of exchanging heat at a proportion of 60% which is considered to be most effective when compared to other methods.
  • the heat radiation is similar to the transfer of heat caused by the sun's radiation through air, space the earth's atmosphere and eventually to materials in solid or liquid form.
  • the frame is preferably in cylindrical circular or polygonal shape.
  • the surface of the frame is configured to the installment of the said heat sustaining materials.
  • the apparatus further includes a ventilation control mechanism for improving and managing the performance of the apparatus.
  • the said frame may comprise a plurality of small frames connected to each other. Said small frame can be disconnected in order to adjust the size of the overall frames for accommodating the size of boiler which may be different depending on the case by case basis. This is to enhance effectiveness and provide ease of installation, and also to avoid any potential damages due to the variation in shape and size of boiler to be applied with.
  • the apparatus is characterized in that a plurality of heat sustaining materials preferably in the form of plate, are closely placed on the surface of the frame.
  • the frame can be further installed with the vertical or horizontal boiler.
  • the porosity of surface of heal sustaining materials may be varied.
  • the shape of materials can also be provided in several forms including triangular, rectangular, polygonal, curved or cylindrical plate.
  • the said plates can then be installed with the frame which is made of heat resistant materials capable of the usage in the temperature of up to 800° C.
  • the frame can have multiple connected layers of surface. For multilayer surface, a space is provided between each layer in order to allow installation and arrangement of heat sustaining materials, and achieve a desired level of appropriate heat exchange between each layer. It is also preferable that the porosity of the heat sustaining materials located at the layer closer to the boiler is greater than that of the other layer.
  • heat sustaining materials and frame can be altogether manufactured as a part of the frame surface in order to avoid subsequent installations of materials to the frame.
  • the frame is configured to include a plate at one end in order to control the direction of flame and the corresponding air circulation. This is to ensure that heat from the burner is circulated distributed throughout the frame.
  • the frame can also be assembled to a base for supporting the boiler.
  • the apparatus for storing and releasing heat for boilers allows efficient heat exchange and the effective, use of fuel and energy for combustion.
  • the said apparatus also provides ease of installation in accordance with the characteristic of boiler and increases the space for the sustaining of heat before the heat is distributed into the fire tube.
  • FIG. 1 demonstrating installment location in combustion chamber or large fire tube in fire-tube boiler, and installment location in water-tube boiler or one-through boiler.
  • FIG. 2 demonstrating the overlapping of heat storage/release plates in case of overlapping layers.
  • FIG. 3 demonstrating the assembly pattern and shapes of heat storage/release plates as assembled to the supporting frame.
  • FIG. 4 demonstrating characteristics of supporting frame for heat storage/release plates which are divided into short series.
  • FIG. 5 demonstrating the assembly and attachment of heat storage/release materials together.
  • FIG. 6 demonstrating the structure of the invention in the event that the frame and heat storage/release materials are produced and installed as one piece.
  • FIG. 1 The preferred embodiment is shown as in FIG. 1 in which it is installed in the outlet of large fire tube or combustion chamber ( 2 ) of the boiler or other apparatus that requires heat for its operation.
  • the overall characteristic is cylindrical tube comprising of
  • the frame for installment of heat sustaining materials can be in triangular cylindrical or polygonal shape.
  • heat sustaining material can be manufactured as one part of surface of frame as shown in FIG. 6 .
  • the present invention can effectively reduce the use of fuel resource through a better heat exchange in form of heat radiation and the reduction of heat loss. This assists in manufacturing and stabilizing the temperature in combustion chamber stable, thereby preventing any change.

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
  • Air Supply (AREA)

Abstract

An apparatus for storing and releasing heat for boilers. The apparatus is preferably provided in a cylindrical form having at least one open end. The apparatus comprises a frame which can support the installation of heat storing materials, manufactured from heat resistant materials. Heat storing materials are installed on the surface of the frame. The heat exchange is conducted by heat conduction and radiation. The surface where heat radiation takes place may be varied by height to ensure the heat distribution and circulation. The invention improves the performance through the continuous heat radiation from heat sustaining materials.

Description

    FIELD OF INVENTION
  • The present invention relates to combustion system, heat storage and heat release for combustion or other processes in connection with combustion, heat storage and heat release.
  • BACKGROUND OF INVENTION
  • Boiler has been currently designed to allow one or the combination of three forms of heat exchange; namely heat conduction, heat convection and heat radiation. Among which, heat radiation is normally capable of exchanging heat at a proportion of 60% which is considered to be most effective when compared to other methods. The heat radiation is similar to the transfer of heat caused by the sun's radiation through air, space the earth's atmosphere and eventually to materials in solid or liquid form.
  • However, for the boiler adapted for industrial use, it is still necessary to further develop the boiler to the extent that the performance in heat exchanger is improved and the level of the required fuel is decreased. With the development, the pollution caused by use of boiler should also be decreased. There are industrial needs and demands for improvement of boiler currently designed to allow heat exchange in terms of effectiveness in exchanging heat for water and reducing fuel for combustion, as well as minimizing pollution from combustion taken place in the boiler.
  • SUMMARY OF INVENTION
  • It is therefore the objective of the invention to provide an apparatus for storing and releasing heat for boilers, which consists of heat sustaining materials, the frames for covering at least a certain part of the boiler. The frame is preferably in cylindrical circular or polygonal shape. The surface of the frame is configured to the installment of the said heat sustaining materials. The apparatus further includes a ventilation control mechanism for improving and managing the performance of the apparatus.
  • The said frame may comprise a plurality of small frames connected to each other. Said small frame can be disconnected in order to adjust the size of the overall frames for accommodating the size of boiler which may be different depending on the case by case basis. This is to enhance effectiveness and provide ease of installation, and also to avoid any potential damages due to the variation in shape and size of boiler to be applied with.
  • The apparatus is characterized in that a plurality of heat sustaining materials preferably in the form of plate, are closely placed on the surface of the frame. The frame can be further installed with the vertical or horizontal boiler.
  • In one aspect, the porosity of surface of heal sustaining materials may be varied. The shape of materials can also be provided in several forms including triangular, rectangular, polygonal, curved or cylindrical plate. The said plates can then be installed with the frame which is made of heat resistant materials capable of the usage in the temperature of up to 800° C. The frame can have multiple connected layers of surface. For multilayer surface, a space is provided between each layer in order to allow installation and arrangement of heat sustaining materials, and achieve a desired level of appropriate heat exchange between each layer. It is also preferable that the porosity of the heat sustaining materials located at the layer closer to the boiler is greater than that of the other layer.
  • In another aspect, heat sustaining materials and frame can be altogether manufactured as a part of the frame surface in order to avoid subsequent installations of materials to the frame.
  • In another aspect, the frame is configured to include a plate at one end in order to control the direction of flame and the corresponding air circulation. This is to ensure that heat from the burner is circulated distributed throughout the frame. The frame can also be assembled to a base for supporting the boiler.
  • With the aforementioned characteristics, the apparatus for storing and releasing heat for boilers, allows efficient heat exchange and the effective, use of fuel and energy for combustion. The said apparatus also provides ease of installation in accordance with the characteristic of boiler and increases the space for the sustaining of heat before the heat is distributed into the fire tube.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1—demonstrating installment location in combustion chamber or large fire tube in fire-tube boiler, and installment location in water-tube boiler or one-through boiler.
  • FIG. 2—demonstrating the overlapping of heat storage/release plates in case of overlapping layers.
  • FIG. 3—demonstrating the assembly pattern and shapes of heat storage/release plates as assembled to the supporting frame.
  • FIG. 4—demonstrating characteristics of supporting frame for heat storage/release plates which are divided into short series.
  • FIG. 5—demonstrating the assembly and attachment of heat storage/release materials together.
  • FIG. 6—demonstrating the structure of the invention in the event that the frame and heat storage/release materials are produced and installed as one piece.
  • DETAILED DESCRIPTIONS OF THE PREFERRED EMBODIMENT
  • The preferred embodiment is shown as in FIG. 1 in which it is installed in the outlet of large fire tube or combustion chamber (2) of the boiler or other apparatus that requires heat for its operation. The overall characteristic is cylindrical tube comprising of
      • Structure or Frame (21) supporting heat sustaining materials (11) manufactured from heat resistant materials having the same heat tolerance. The two columns of bases are provided at one side of the frame for accommodating the support and installation with the boiler.
      • Heat sustaining materials (11) in form of plates are installed on the surface of the cylinder. Said materials are heat sustaining materials capable of air and heat ventilation for heat exchange in the form of convection and radiation. These plates may be provided in square, curved and cylindrical shapes.
      • The number of layers of heat storage/release materials can be one or multiple as shown in FIG. 2 in order to increase the performance in the heat exchange process. The numbers of layers may be varied depending on the size of the tube (2) and burner (8) used in boiler.
      • Heat sustaining materials (11) which is the closest to the boiler is slightly larger than the burner (8) and distributed along the length of the fire tube or combustion chamber (2) of the boiler. Heat will accumulate at the first, innermost layer (11) and then subsequently transfer to the second layer which is outer layer by convection and radiation. The subsequent layer will further transfer heat to the other external layers. Therefore, heat is distributed throughout the entire combustion chamber, the heat then will be circulated and transferred to the wall of fire tube (2) and tire tube (3) for continuous heat exchange as shown in Figure and 2.
      • The air flows through the front of the fire tube (2) and transfers heat toward fire tube (3). Such air may be air from stack or one from other sources I.e. air blower (4,5) as shown in FIG. 1
      • Frame can be divided into a series of short flames in order to prevent any damage from the expansion of materials due to the heat, Said small frames can be assembled until desirable length is acquired for the use according to the size of the fire tube (2) of the boiler. Heat sustaining materials can be loaded as shown in FIG. 4 and FIG. 5.
      • Plate positioned at one end of the cylindrical shape, (if any) is used For controlling the direction of the flame to the extent that the flame is directed to the side surface of cylinder, thereby causing, flame circulation along the side surface and allowing the continuous exchange of heat by radiation.
  • Alternately, the frame for installment of heat sustaining materials can be in triangular cylindrical or polygonal shape.
  • In other form of the invention, heat sustaining material can be manufactured as one part of surface of frame as shown in FIG. 6.
  • The present invention can effectively reduce the use of fuel resource through a better heat exchange in form of heat radiation and the reduction of heat loss. This assists in manufacturing and stabilizing the temperature in combustion chamber stable, thereby preventing any change.
  • Thus, the preceding description of various embodiments of heat exchanger was given for purposes of illustration and example. Those skilled in the art will appreciate that the present invention may be carried out in other ways than those specifically set forth herein without departing from essential characteristics of the invention. The present embodiments are thus to be considered in all respects as illustrative and not restrictive, and all changes coming within the meaning and equivalency range of the appended claims are intended to be embraced therein.

Claims (11)

1. Heat exchanger for boiler consists of
Heat storing materials (11)
A hollow frame (21) made of heat resistant materials having a solid surface bounded by at least three plains or a circular surface which can elongated along a certain part of boiler wherein said surface is configured to support the installation of a plurality of heat storing material and be attached with ventilation controlling means
characterized in that said heat storing materials are porous and are substantially positioned adjacent to each other on the surface of the frame (21), which can be installed in the boiler.
2. Heat exchanger for the boiler as recited in claim 1 wherein the apparatus comprises supporting bases for installation of the apparatus with the boiler.
3. Heat exchanger as recited in claim 1 wherein porous heat storing materials are varied in term of sizes and configured to have different porosities.
4. Heat exchanger as recited in claim 1 wherein the porous heat storing materials are principally made of ceramic, and is in form of square or curved plate.
5. Heat exchanger as recited in claim 1 wherein the plurality of surfaces of the hollow frame are used for supporting the installation of a plurality of heat storing materials thereby forming more than one layer of surfaces which are spaced apart from each other and the boiler.
6. Heat exchanger for boiler as recited in claim 5 wherein the porosity of the porous heat storing materials being located at the layer closest to the boiler is greater than those of the outer layer.
7. Heat exchanger as recited in claim 1 wherein the frame comprises a plurality of frames which can be disassembled.
8. Heat exchanger as recited in claim 1 wherein the apparatus further comprised a plate located at one end of the frame for controlling the direction of flame.
9. Heat exchanger as recited in claim 1 wherein the apparatus can be used with a horizontal or vertical boiler.
10. Heat exchanger as recited in claim 1 wherein heat storing materials can be manufactured as a part of the surface of the frame.
11. Heat exchanger as recited in any of the above claims wherein heat sustaing materials can be manufactured as a part of the surface of the frame.
US14/238,906 2011-08-17 2012-08-16 Heat exchanger Abandoned US20140196865A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
TH1101001578 2011-08-17
TH1101001578A TH1101001578A (en) 2011-08-17 The patent has not yet been announced.
PCT/TH2012/000035 WO2013025178A2 (en) 2011-08-17 2012-08-16 Heat exchanger

Publications (1)

Publication Number Publication Date
US20140196865A1 true US20140196865A1 (en) 2014-07-17

Family

ID=47010697

Family Applications (1)

Application Number Title Priority Date Filing Date
US14/238,906 Abandoned US20140196865A1 (en) 2011-08-17 2012-08-16 Heat exchanger

Country Status (14)

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US (1) US20140196865A1 (en)
EP (1) EP2745057A2 (en)
JP (1) JP2014527150A (en)
KR (1) KR20140057341A (en)
CN (1) CN103732997A (en)
AU (1) AU2012295611A1 (en)
BR (1) BR112014003630A2 (en)
CA (1) CA2845314A1 (en)
MX (1) MX2014001848A (en)
PH (1) PH12014500370A1 (en)
RU (1) RU2014104755A (en)
SG (1) SG2014008916A (en)
WO (1) WO2013025178A2 (en)
ZA (1) ZA201401151B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USD763418S1 (en) * 2014-07-23 2016-08-09 Dhiti Towiwat Heat exchanger

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3606015A (en) * 1969-11-28 1971-09-20 Inst Of Gas Technology The Heat-regenerative separator and method
US4089176A (en) * 1976-01-20 1978-05-16 The Garrett Corporation Heat storage method and apparatus
US4222434A (en) * 1978-04-27 1980-09-16 Clyde Robert A Ceramic sponge heat-exchanger member
US4465024A (en) * 1982-04-16 1984-08-14 Pvi Industries Incorporated Water heater
US4545329A (en) * 1983-09-23 1985-10-08 Pvi Industries, Inc. Water heater
US4666944A (en) * 1984-09-21 1987-05-19 The Standard Oil Company Copper-zirconium-manganese-containing catalysts and processes for making alcohol mixtures using same
US20040194908A1 (en) * 2003-02-19 2004-10-07 Honda Motor Co., Ltd. Heat storing element and method for manufacturing heat storage apparatus using the element
US20110146939A1 (en) * 2008-06-16 2011-06-23 Carbon Zero Limited Energy absorption and release devices and systems
US20120272643A1 (en) * 2011-05-01 2012-11-01 Thomas Mallory Sherlock Solar Air Conditioning Heat Pump with Minimized Dead Volume
US20120279679A1 (en) * 2010-01-29 2012-11-08 Soukhojak Andrey N Thermal energy storage
US8931276B2 (en) * 2010-10-06 2015-01-13 Dongho Kim Hybrid renewable energy system having underground heat storage apparatus

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2924195A1 (en) * 1979-06-15 1980-12-18 Peter Noerenberg Oil or gas fired heat generator - has heat accumulator clear of combustion chamber sidewalls and with passages through it
DE3231211C2 (en) * 1982-08-21 1986-10-02 Didier-Werke Ag, 6200 Wiesbaden Device for a combustion chamber with an oil or gas burner
EP1126217B1 (en) * 1999-09-01 2005-02-02 Nkk Corporation Heat treating plant, installation method for porous regenerative element, production method for heat treated substance
DE202010000357U1 (en) * 2010-03-11 2010-09-30 Holzmann, Adelheid Heat storage element
DE202010012076U1 (en) * 2010-03-23 2011-01-13 Accuramics Gmbh System for heat storage and exhaust flow optimization

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3606015A (en) * 1969-11-28 1971-09-20 Inst Of Gas Technology The Heat-regenerative separator and method
US4089176A (en) * 1976-01-20 1978-05-16 The Garrett Corporation Heat storage method and apparatus
US4222434A (en) * 1978-04-27 1980-09-16 Clyde Robert A Ceramic sponge heat-exchanger member
US4465024A (en) * 1982-04-16 1984-08-14 Pvi Industries Incorporated Water heater
US4545329A (en) * 1983-09-23 1985-10-08 Pvi Industries, Inc. Water heater
US4666944A (en) * 1984-09-21 1987-05-19 The Standard Oil Company Copper-zirconium-manganese-containing catalysts and processes for making alcohol mixtures using same
US20040194908A1 (en) * 2003-02-19 2004-10-07 Honda Motor Co., Ltd. Heat storing element and method for manufacturing heat storage apparatus using the element
US20110146939A1 (en) * 2008-06-16 2011-06-23 Carbon Zero Limited Energy absorption and release devices and systems
US20120279679A1 (en) * 2010-01-29 2012-11-08 Soukhojak Andrey N Thermal energy storage
US8931276B2 (en) * 2010-10-06 2015-01-13 Dongho Kim Hybrid renewable energy system having underground heat storage apparatus
US20120272643A1 (en) * 2011-05-01 2012-11-01 Thomas Mallory Sherlock Solar Air Conditioning Heat Pump with Minimized Dead Volume

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USD763418S1 (en) * 2014-07-23 2016-08-09 Dhiti Towiwat Heat exchanger

Also Published As

Publication number Publication date
CA2845314A1 (en) 2013-02-21
ZA201401151B (en) 2014-12-23
EP2745057A2 (en) 2014-06-25
AU2012295611A1 (en) 2014-03-06
CN103732997A (en) 2014-04-16
WO2013025178A2 (en) 2013-02-21
RU2014104755A (en) 2015-09-27
SG2014008916A (en) 2014-04-28
PH12014500370A1 (en) 2014-04-14
JP2014527150A (en) 2014-10-09
MX2014001848A (en) 2014-10-24
BR112014003630A2 (en) 2017-03-14
WO2013025178A3 (en) 2013-10-10
KR20140057341A (en) 2014-05-12

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