US20140054462A1 - Device and Method for Increasing Infrared Absorption in MEMS Bolometers - Google Patents
Device and Method for Increasing Infrared Absorption in MEMS Bolometers Download PDFInfo
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- US20140054462A1 US20140054462A1 US13/970,786 US201313970786A US2014054462A1 US 20140054462 A1 US20140054462 A1 US 20140054462A1 US 201313970786 A US201313970786 A US 201313970786A US 2014054462 A1 US2014054462 A1 US 2014054462A1
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J5/00—Radiation pyrometry, e.g. infrared or optical thermometry
- G01J5/10—Radiation pyrometry, e.g. infrared or optical thermometry using electric radiation detectors
- G01J5/20—Radiation pyrometry, e.g. infrared or optical thermometry using electric radiation detectors using resistors, thermistors or semiconductors sensitive to radiation, e.g. photoconductive devices
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J5/00—Radiation pyrometry, e.g. infrared or optical thermometry
- G01J5/02—Constructional details
- G01J5/08—Optical arrangements
- G01J5/0853—Optical arrangements having infrared absorbers other than the usual absorber layers deposited on infrared detectors like bolometers, wherein the heat propagation between the absorber and the detecting element occurs within a solid
Definitions
- This disclosure relates to MEMS (Microelectro-mechanical) bolometers and more particularly to structuring a MEMS bolometer to increase radiation absorption in a desired range of wavelengths.
- MEMS Microelectro-mechanical
- a bolometer is a type of thermal sensor that senses a change in temperature of an object based on a change in electromagnetic radiation emitted by the object.
- bolometers are configured to detect radiation in the infrared range, which has a wavelength of approximately three to twelve micrometers (3-12 ⁇ m).
- bolometers include an absorber for detecting/receiving the radiation emitted by the object.
- metals are not typically considered suitable. This is because in general metals are very good at shielding/reflecting infrared radiations. It was discovered, however, that at ultra-thin layers, for example approximately ten nanometers ( ⁇ 10 nm), metals act as good absorbers for infrared radiation. Upon absorbing radiation, the ultra-thin layer of metal heats-up and exhibits a change in electrical resistance, which is monitored by external circuitry to sense a change in temperature of an object.
- the bolometer When using an absorber formed from an imperforate ultra-thin layer of metal, the bolometer exhibits a relatively narrow bandwidth and a moderate capacity for absorbing incident radiation.
- the bandwidth of the bolometer refers to the range of wavelengths that are detectable by the absorber.
- the capacity for absorption of the bolometer refers to the percentage of incident radiation that is absorbed by the absorber. Ideally, a bolometer absorbs 100% of the incident radiation across a wide bandwidth. Known bolometers, however, do not achieve these ideal specifications.
- a semiconductor sensor includes a substrate and an absorber.
- the substrate includes at least one reflective component.
- the absorber is spaced apart from the at least one reflective component by a distance.
- the absorber defines a plurality of openings each having a maximum width that is less than or equal to the distance.
- a method of forming a semiconductor sensor includes spacing an absorber apart from at least one reflective component by a distance, and forming a plurality of openings in the absorber.
- Each opening of the plurality of openings defines a maximum width that is less than the distance.
- the distance is based on a wavelength of radiation, and the distance is less than the wavelength of radiation. Accordingly, the openings are sub-wavelength openings.
- FIG. 1 is a perspective view of a prior art semiconductor sensor including an absorber spaced apart from a reflector;
- FIG. 2 is a graph showing an absorption spectrum of the semiconductor sensor of FIG. 1 ;
- FIG. 3 is a perspective view of a semiconductor sensor, as described herein, including an absorber spaced apart from a reflector, with the absorber defining a plurality of sub-wavelength openings;
- FIG. 4 is a graph showing an absorption spectrum of the semiconductor sensor of FIG. 3 ;
- FIG. 5 is a perspective view of another embodiment of a semiconductor sensor, as described herein, including a trenched reflector layer;
- FIG. 6 is a graph showing an absorption spectrum of the semiconductor sensor of FIG. 5 ;
- FIG. 7 is a perspective view of another embodiment of a semiconductor sensor, as described herein, including a trenched reflector layer that is sputter coated with a layer of aluminum;
- FIG. 8 is a graph showing an absorption spectrum of the semiconductor sensor of FIG. 7 ;
- FIG. 9 is a perspective view of another embodiment of a semiconductor sensor, as described herein, including a trenched reflector layer that is sputter coated with a layer of aluminum and an absorber layer that defines opening having different maximum widths;
- FIG. 10 is a graph showing an absorption spectrum of the semiconductor sensor of FIG. 9 ;
- FIG. 11 is a perspective view of another embodiment of a semiconductor sensor, as described herein, including an absorber defining a plurality of sub-wavelength openings and a reflector defining a plurality of sub-wavelength openings; and
- FIG. 12 is a perspective view of yet another embodiment of a semiconductor sensor, as described herein, including an absorber defining a plurality of sub-wavelength openings and a reflector defining a plurality of sub-wavelength openings.
- a prior art MEMS bolometer 100 includes an absorber 104 and substrate 106 including a reflector 108 .
- the absorber 104 is typically an ultra-thin layer/sheet of platinum having a thickness of approximately ten nanometers (10 nm).
- the absorber 104 defines a length 116 and a width 120 of approximately fifty micrometers (50 ⁇ m).
- the absorber 104 is spaced apart from the reflector layer 108 by a distance 112 , which is approximately three micrometers (3 ⁇ m).
- FIG. 1 is not drawn to scale.
- the reflector 108 is a reflective component that is spaced apart from the absorber layer 104 .
- the reflector 108 is typically formed from either platinum or aluminum. As compared to the absorber 104 , the reflector 108 is comparatively thick having a thickness of approximately five hundred nanometers (500 nm). The reflector 108 is approximately the same size in area as the absorber 104 .
- the bolometer 100 is exposed to radiation, typically in the infrared region.
- the radiation is imparted on the reflector 108 .
- At least a portion of the incident radiation is reflected by the reflector 108 onto the absorber 104 .
- the absorber 104 undergoes a change in response to the radiation that is reflected thereon.
- the change in the absorber 104 is detected/monitored by external circuitry (not shown) to determine the temperature of an object (not shown) from which the radiation originated.
- FIG. 2 illustrates an absorption spectrum of the bolometer 100 in the infrared region of radiation.
- the bolometer 100 absorbs approximately 29% of the radiation at eight micrometers and approximately 17% of the radiation at fourteen micrometers.
- the absorption percentage declines as the wavelength increases from eight micrometers (8 ⁇ m) to fourteen micrometers (14 ⁇ m).
- the bolometer 100 exhibits a maximum absorption percentage 130 of approximately 70% for radiation of approximately 6.5 micrometers (6.5 ⁇ m).
- the bolometer 100 exhibits a cavity resonance in the wavelength zone 134 that, as described below, is relatively narrow.
- the structure of the bolometer is modified to achieve wide-band radiation absorption in the infrared range.
- the bolometer 200 is particularly suited for absorbing infrared radiation in a wavelength range of eight micrometers to fourteen micrometers.
- a semiconductor sensor shown as a MEMS bolometer 200 , includes an absorber 204 spaced apart from a reflector 208 .
- the bolometer 200 is configurable to absorb/detect any desired wavelength of radiation.
- the absorber 204 which is also referred to herein as an absorber layer, is typically an ultra-thin layer/sheet of platinum having a thickness of approximately ten nanometers (10 nm). In the embodiment, of FIG. 1 , the absorber 204 defines a length 216 and a width 220 of approximately fifty micrometers (50 ⁇ m). In another embodiment, the absorber 204 is formed from any metal and has any size, shape, and thickness, as desired by those of ordinary skill in the art. The absorber 204 is shown as being generally flat, but in another embodiment the absorber may have any configuration, as desired by those of ordinary skill in the art, including bent, curved, and other nonplanar configurations.
- the absorber 204 is spaced apart from the reflector 208 by a distance 212 , which is approximately three micrometers (3 ⁇ m).
- the distance 212 is selected based on a desired wavelength of radiation (or range of wavelengths of radiation) to be detected by the bolometer 200 .
- FIG. 3 is not drawn to scale.
- the distance 212 in the exemplary embodiment, is less than a wavelength (or the shortest wavelength in a range of wavelengths) to be detected by the bolometer 200 .
- the region between the absorber 204 and the reflector 208 is referred to as a cavity 224 ; accordingly, the distance 212 is also referred to herein as a cavity distance.
- the distance 212 is between approximately 0.5 micrometers (0.5 ⁇ m) and ten micrometers (10 ⁇ m), or any other distance as desired by those of ordinary skill in the art.
- the absorber 204 defines a plurality of generally circular openings 220 that extend completely through the absorber 204 (the perspective view of FIG. 3 makes the openings appear slightly elliptical).
- the absorber 204 of FIG. 3 includes six rows with six of the openings 220 in each row, such that the openings 220 are arranged in a rectangular array.
- the absorber 204 defines one hundred of the openings 220 arranged in ten rows of ten openings each.
- the absorber 204 defines any number of the openings 220 , arranged in any configuration, and spaced apart by any distance as desired by those of ordinary skill in the art.
- the openings 220 may have any shape as desired by those of ordinary skill in the art, such as rectangular, elliptical, and, triangular.
- the openings 220 in one embodiment, are void of any substance except air. In another embodiment, the openings 220 are at least partially filled with a substance, as desired by those of ordinary skill in the art.
- Each opening 220 defines a maximum width 228 of approximately three micrometers (3 ⁇ m). Since, the openings 220 are generally circular the maximum width 228 corresponds to the diameter of the openings 220 . In the embodiment of FIG. 3 , each opening 220 is substantially identical; however, in another embodiment some of the openings have different maximum widths (See FIG. 9 ). The openings 220 are spaced apart from each other by a distance 232 of approximately two micrometers (2 ⁇ m). The maximum width 228 is less than or equal to the distance 212 .
- the reflector 208 which is also referred to herein as a reflector layer, is typically formed from either platinum or aluminum. As compared to the absorber 204 , the reflector 208 is comparatively thick and defines a thickness of approximately five hundred nanometers (500 nm). The reflector 208 is approximately the same size in area as the absorber 104 . The reflector 208 is generally imperforate. In another embodiment, the reflector 208 is formed from any material and defines any size and shape, as desired by those of ordinary skill in the art.
- a method of making the bolometer 200 includes forming the absorber 204 and the reflector 208 .
- the absorber 204 is spaced apart from the reflector 208 by the distance 212 .
- the openings 220 are formed in the absorber 204 , using any process as desired by those of ordinary skill in the art.
- the openings 220 are sized such that the maximum width 228 is less than the distance 212 , thereby making the openings “sub-wavelength” openings. If the openings 220 are to be exposed to radiation exhibiting a range of wavelengths and corresponding frequencies, then the openings 220 are sized so that the maximum width is less than the shortest wavelength of the desired wavelength range.
- the bolometer 200 is exposed to radiation, typically in the infrared region.
- the radiation is imparted on the reflector 208 .
- At least a portion of the incident radiation is reflected by the reflector 208 onto the absorber 204 .
- FIG. 4 illustrates the absorption spectrum of the bolometer 200 in an infrared region of radiation.
- the bolometer 200 absorbs approximately 95% of the radiation at eight micrometers and approximately 35% of the radiation at fourteen micrometers.
- the absorption percentage declines as the wavelength increases from eight micrometers (8 ⁇ m) to fourteen micrometers (14 ⁇ m).
- the bolometer 200 exhibits a maximum absorption percentage 240 of approximately 95% at an optical resonance zone centered at about 8.0 micrometers (8.0 ⁇ m).
- the bolometer 200 exhibits a cavity resonance zone 244 between approximately 7.5 micrometers to 8.5 micrometers.
- the bolometer 200 with sub-wavelength openings 220 exhibits a greater maximum absorption percentage 240 (compare 130 of FIG. 2 to 240 of FIG. 4 ).
- the cavity resonance 244 is wider in the bolometer 200 as compared to the cavity resonance 134 of the bolometer 100 .
- the width of the cavity resonance 244 and the maximum absorption percentage 240 are increased when the maximum width 228 of the openings 220 is approximately, equal to the distance 212 .
- the graph of FIG. 4 shows that the sub-wavelength openings 220 increase the FWHM (Full Width at Half Maximum) of optical resonance between the absorber 204 and the reflector 208 .
- the cavity resonance 244 narrows and the maximum absorption percentage 240 decreases.
- the maximum width of the openings 220 is reduced to zero the results converge toward the results achieved with an imperforate absorber 104 , as plotted in FIG. 2 .
- a MEMS bolometer 300 includes an absorber layer 304 spaced apart from a stepped reflector layer 308 .
- the absorber layer 304 is identical to the absorber layer 204 of FIG. 3 , and defines a plurality of openings 306 that are identical to the openings 220 .
- the reflector layer 308 includes six upper segments 312 and five lower segments 316 .
- the segments 312 , 316 are also referred to as reflective components.
- An upper surface 314 of the segments 312 defines an upper level, and an upper surface 318 of the segments 316 defines a lower level.
- the segments 312 are interlaced with the segments 316 .
- the segments 312 and the segments 316 define a width 328 of approximately 2.5 micrometers (2.5 ⁇ m) and are made of a high-index material. The width 328 is less than a maximum width 332 of the openings in the absorber 304 .
- the upper surfaces 314 of the upper level are spaced apart from the upper surfaces 318 of the lower level by a distance 330 .
- the distance 330 is approximately five micrometers (5.0 ⁇ m).
- the reflector layer 308 includes any number of the segments 312 , 316 , as desired by those of ordinary skill in the art. Additionally, the segments 312 , 316 may have any width and the distance 330 is any magnitude as desired by those of ordinary skill in the art. Accordingly, in one embodiment, the segments 312 have a different width than the segments 316 .
- the segments 312 , 316 in another embodiment, are formed from any material, as desired by those of ordinary skill in the art.
- the upper level of the segments 312 and the lower level of the segments 316 each operate as a high-contrast grating reflector.
- a low-index material is interposed between the segments 312 , 316 and the segments 316 to maintain the position thereof.
- the segments 312 , 316 are formed from platinum, aluminum, or any material as desired by those of ordinary skill in the art.
- the absorber layer 304 is spaced apart from the upper level by a distance 320 (a first cavity distance), which is equal to approximately three micrometers (3 ⁇ m).
- the absorber layer 304 is spaced apart from the second level by a distance 324 (a second cavity distance), which is equal to approximately eight micrometers (8 ⁇ m).
- FIG. 6 illustrates an absorption spectrum of the bolometer 300 in the infrared region of radiation.
- the bolometer 300 exhibits a first optical resonance zone 350 , a second optical resonance zone 354 , and three destructive interference zones 358 , 362 , 366 .
- the bolometer 300 exhibits two optical resonance zones 350 , 354 due to the stepped reflector 308 defining two surfaces (i.e. the upper surface and the lower surface).
- the bolometer 300 absorbs approximately 75% of the radiation at approximately seven micrometers (7.0 ⁇ m).
- the bolometer absorbs approximately 60% of the radiation at approximately 8.5 micrometers.
- the absorption percentage forms a trough between the optical resonance zones 350 , 354 , which is one of the destructive interference zones 362 .
- the absorption percentage gradually decreases. Both segments 312 , 316 work simultaneously to reflect the radiation and to form the absorption spectrum.
- the wavelengths at which the destructive interference zones 358 , 362 , 366 occur are at least partially based on the distances 320 , 324 .
- the destructive interference zone 358 is based on the distance 320 and occurs at half of the incident wavelength ( 212 ).
- the destructive interference zone 358 affects radiation having a wavelength of approximately six micrometers (6 ⁇ m).
- the destructive interference zone 362 is based on the distance 324 and occurs at the full value of the incident wavelength ( ⁇ ).
- the destructive interference zone 362 affects radiation having a wavelength of approximately six micrometers (6 ⁇ m).
- the destructive interference zone 366 is based on the distance 324 and occurs at half of the incident wavelength ( 212 ).
- the destructive interference zone 366 affects radiation having a wavelength of approximately sixteen micrometers (16 ⁇ m).
- the reflector 308 having two layers achieves a filer-like response in the absorption spectrum that is dependent on the distance 320 and the distance 324 , among other factors.
- the segments 312 , 316 are formed from five hundred nanometer thick “bars” of silicon arranged in the high contrast grating configuration of FIG. 5 .
- the absorption response shows a filter-like response that is similar to the absorption spectrum shown in FIG. 6 .
- the segments 312 , 316 are formed from five hundred nanometer thick “bars” of silicon arranged in the high contrast grating configuration of FIG. 5 .
- the segments 312 , 316 are supported by a trenched structure 410 (see FIG. 7 ) formed from silicon dioxide.
- the segments 312 , 316 and the trenched structure 410 are integrally formed from silicon and are arranged in the high contrast grating configuration of FIG. 5 .
- the segments 312 , 316 and the trenched structure 410 are integrally formed from aluminum and are arranged in the high contrast grating configuration of FIG. 5 .
- a MEMS bolometer 400 includes an absorber layer 404 spaced apart from a stepped reflector layer 408 .
- the absorber layer 404 is identical to the absorber layer 204 of FIG. 3 , and defines a plurality of openings 406 that are identical to the openings 220 .
- the reflector 408 includes a substrate referred to as a trenched structure 410 and a layer of material 424 deposited thereon.
- the trenched structure 410 defines five trenches 412 , which are generally parallel to each other.
- the trenched structure 410 is formed from silicon.
- the trenched structure 410 is formed form silicon dioxide, aluminum, or any other material as desired by those of ordinary skill in the art.
- the trenched structure 410 defines any desired number of trenches 412 of any shape or configuration.
- the material 424 is a metal layer that is deposited onto the trenched structure 410 by sputtering or by any deposition process desired by those of ordinary skill in the art.
- the material 424 is aluminum, platinum, or any other metal as desired by those of ordinary skill in the art.
- the material defines six upper surfaces 416 , five lower surfaces 420 , and a plurality of vertical surfaces 428 .
- the upper surfaces 416 define an upper level, and the lower surfaces 420 define a lower level.
- the upper surfaces 416 define a width 432 of approximately 2.5 micrometers (2.5 ⁇ m) wide.
- the lower surfaces 420 are slightly narrower.
- the upper surfaces 416 are spaced apart from the absorber 204 by the distance 406 , which is approximately three micrometers (3 ⁇ m).
- the lower surfaces 420 are spaced apart from the absorber 204 by the distance 414 , which is approximately six micrometers (6 ⁇ m).
- the upper surfaces 416 are spaced apart from the lower surfaces 420 by a distance 430 .
- the distance 430 is approximately five micrometers (5 ⁇ m).
- the vertical surfaces 428 connect the upper surfaces 416 to the lower surfaces 420 .
- the material 424 as a thickness 436 of approximately five hundred nanometers, such that the material 424 is thicker than the skin depth of the radiation on the material 424 . So long as the material 424 is thicker than the skin depth of the radiation, the composition of the trenched structure 410 is immaterial.
- FIG. 8 illustrates the absorption spectrum of the bolometer 400 in the infrared region of radiation.
- the bolometer 400 exhibits an optical resonance point 450 , two destructive interference points 458 , 466 , and a pass band 470 . Due to the distances 406 , 414 the bolometer 400 exhibits a blended optical resonance zone 450 even though the reflector 408 is stepped. At the center of the optical resonance zone 450 , the bolometer 400 absorbs approximately 95% of the radiation at approximately 7.5 micrometers (7.5 ⁇ m).
- FIG. 8 also shows that the absorption response at the destructive interference zone 458 has been brought down to approximately 0% absorption, as compared to the destructive interference zone 358 of FIG. 6 .
- the absorption at the destructive interference zone 466 has been brought down to approximately 0% absorption, as compared to the destructive interference zone 366 of FIG. 6 .
- the reduction in absorption at the 212 destructive interference zones 458 , 466 is due to the material 424 and the distances 406 , 410 , among other factors.
- the pass band 470 exhibits a peak absorption at the optical resonance point 450 and tapers down at the boundaries thereof.
- a MEMS bolometer 500 includes an absorber 504 and a stepped reflector 508 .
- the reflector 508 is identical to the reflector 408 of FIG. 7 .
- the reflector 508 includes a material 512 that is identical to the material 424 and defines a plurality of upper surfaces 516 and a plurality of lower surfaces 520 .
- the upper surfaces 516 are identical to the upper surfaces 416
- the lower surfaces 520 are identical to the lower surfaces 420 .
- the absorber 504 is spaced apart from the upper surfaces 516 by a distance 506 , which is approximately three micrometers (3 ⁇ m).
- the absorber 504 is spaced apart from the lower surfaces 520 by a distance 510 , which is approximately six micrometers (6 ⁇ m).
- the absorber 504 defines a plurality of openings 514 , 518 that extend completely through the absorber 504 .
- the openings 514 are generally circular (the perspective view of FIG. 9 makes the openings appear slightly elliptical).
- Each opening 514 defines a maximum width 524 of approximately four micrometers (4 ⁇ m).
- the openings 518 are also generally circular.
- Each opening 518 defines a maximum width 528 of approximately two micrometers (2 ⁇ m). Since, the openings 514 , 518 are generally circular the maximum widths 524 , 528 correspond to the diameters of the openings 514 , 518 .
- the maximum width 524 is less than or equal to the distance 510
- the maximum width 528 is less than or equal to the distance 506 .
- FIG. 10 shows an absorption spectrum of the bolometer 500 of FIG. 9 .
- mixing sub-wavelength openings 514 , 518 of different maximum widths 524 , 528 with the stepped reflector 508 having the material 512 widens a pass band 570 of the response as compared to the pass band of 450 shown in FIG. 8 .
- FIG. 11 shows another embodiment of a bolometer 600 that includes an absorber 604 and a reflector 608 .
- the absorber 604 defines a plurality of openings 612 therethrough.
- the reflector 608 also defines a plurality of openings 616 therethrough.
- the absorber 604 is spaced apart from the reflector 608 by a distance 620 .
- the openings 612 are aligned with the openings 616 .
- the openings 616 serve to widen the cavity resonance of an absorption response (not shown) of the bolometer 600 .
- the openings 612 , 616 define a maximum width 624 that is less than the distance 620 .
- FIG. 11 is not drawn to scale.
- FIG. 12 shows another embodiment of a bolometer 700 that includes an absorber 704 and a reflector 708 .
- the absorber 704 defines a plurality of openings 712 therethrough.
- the reflector 708 also defines a plurality of openings 716 therethrough.
- the absorber 704 is spaced apart from the reflector 708 by a distance 720 .
- the openings 712 are misaligned with the openings 716 as shown by the position 724 (shown in phantom) of the one of the openings 716 on the absorber 704 .
- the openings 716 serve to widen the cavity resonance of the absorption response of the bolometer 700 .
- the openings 712 , 716 define a maximum width 728 that is less than the distance 720 .
- FIG. 12 is not drawn to scale.
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Abstract
Description
- This application claims the benefit of U.S. Provisional Application No. 61/692,406, filed on Aug. 23, 2012, the entire contents of which are herein incorporated by reference.
- This disclosure relates to MEMS (Microelectro-mechanical) bolometers and more particularly to structuring a MEMS bolometer to increase radiation absorption in a desired range of wavelengths.
- A bolometer is a type of thermal sensor that senses a change in temperature of an object based on a change in electromagnetic radiation emitted by the object. Typically, bolometers are configured to detect radiation in the infrared range, which has a wavelength of approximately three to twelve micrometers (3-12 μm).
- Most bolometers include an absorber for detecting/receiving the radiation emitted by the object. Of the various materials available for forming the absorber, metals are not typically considered suitable. This is because in general metals are very good at shielding/reflecting infrared radiations. It was discovered, however, that at ultra-thin layers, for example approximately ten nanometers (˜10 nm), metals act as good absorbers for infrared radiation. Upon absorbing radiation, the ultra-thin layer of metal heats-up and exhibits a change in electrical resistance, which is monitored by external circuitry to sense a change in temperature of an object.
- When using an absorber formed from an imperforate ultra-thin layer of metal, the bolometer exhibits a relatively narrow bandwidth and a moderate capacity for absorbing incident radiation. The bandwidth of the bolometer refers to the range of wavelengths that are detectable by the absorber. The capacity for absorption of the bolometer refers to the percentage of incident radiation that is absorbed by the absorber. Ideally, a bolometer absorbs 100% of the incident radiation across a wide bandwidth. Known bolometers, however, do not achieve these ideal specifications.
- Accordingly, a need exists to further improve the structure of bolometers to increase the bandwidth and the capacity for absorbing incident radiation, thereby resulting in a more efficient bolometer.
- According to one embodiment of the disclosure, a semiconductor sensor includes a substrate and an absorber. The substrate includes at least one reflective component. The absorber is spaced apart from the at least one reflective component by a distance. The absorber defines a plurality of openings each having a maximum width that is less than or equal to the distance.
- According to another embodiment of the disclosure, a method of forming a semiconductor sensor includes spacing an absorber apart from at least one reflective component by a distance, and forming a plurality of openings in the absorber. Each opening of the plurality of openings defines a maximum width that is less than the distance. The distance is based on a wavelength of radiation, and the distance is less than the wavelength of radiation. Accordingly, the openings are sub-wavelength openings.
- The above-described features and advantages, as well as others, should become more readily apparent to those of ordinary skill in the art by reference to the following detailed description and the accompanying figures in which:
-
FIG. 1 is a perspective view of a prior art semiconductor sensor including an absorber spaced apart from a reflector; -
FIG. 2 is a graph showing an absorption spectrum of the semiconductor sensor ofFIG. 1 ; -
FIG. 3 is a perspective view of a semiconductor sensor, as described herein, including an absorber spaced apart from a reflector, with the absorber defining a plurality of sub-wavelength openings; -
FIG. 4 is a graph showing an absorption spectrum of the semiconductor sensor ofFIG. 3 ; -
FIG. 5 is a perspective view of another embodiment of a semiconductor sensor, as described herein, including a trenched reflector layer; -
FIG. 6 is a graph showing an absorption spectrum of the semiconductor sensor ofFIG. 5 ; -
FIG. 7 is a perspective view of another embodiment of a semiconductor sensor, as described herein, including a trenched reflector layer that is sputter coated with a layer of aluminum; -
FIG. 8 is a graph showing an absorption spectrum of the semiconductor sensor ofFIG. 7 ; -
FIG. 9 is a perspective view of another embodiment of a semiconductor sensor, as described herein, including a trenched reflector layer that is sputter coated with a layer of aluminum and an absorber layer that defines opening having different maximum widths; -
FIG. 10 is a graph showing an absorption spectrum of the semiconductor sensor ofFIG. 9 ; -
FIG. 11 is a perspective view of another embodiment of a semiconductor sensor, as described herein, including an absorber defining a plurality of sub-wavelength openings and a reflector defining a plurality of sub-wavelength openings; and -
FIG. 12 is a perspective view of yet another embodiment of a semiconductor sensor, as described herein, including an absorber defining a plurality of sub-wavelength openings and a reflector defining a plurality of sub-wavelength openings. - For the purpose of promoting an understanding of the principles of the disclosure, reference will now be made to the embodiments illustrated in the drawings and described in the following written specification. It is understood that no limitation to the scope of the disclosure is thereby intended. It is further understood that this disclosure includes any alterations and modifications to the illustrated embodiments and includes further applications of the principles of the disclosure as would normally occur to one skilled in the art to which this disclosure pertains.
- As shown in
FIG. 1 , a priorart MEMS bolometer 100 includes anabsorber 104 andsubstrate 106 including areflector 108. Theabsorber 104 is typically an ultra-thin layer/sheet of platinum having a thickness of approximately ten nanometers (10 nm). In the embodiment, ofFIG. 1 , theabsorber 104 defines alength 116 and awidth 120 of approximately fifty micrometers (50 μm). Theabsorber 104 is spaced apart from thereflector layer 108 by adistance 112, which is approximately three micrometers (3 μm).FIG. 1 is not drawn to scale. - The
reflector 108 is a reflective component that is spaced apart from theabsorber layer 104. Thereflector 108 is typically formed from either platinum or aluminum. As compared to theabsorber 104, thereflector 108 is comparatively thick having a thickness of approximately five hundred nanometers (500 nm). Thereflector 108 is approximately the same size in area as theabsorber 104. - In use, the
bolometer 100 is exposed to radiation, typically in the infrared region. The radiation is imparted on thereflector 108. At least a portion of the incident radiation is reflected by thereflector 108 onto theabsorber 104. Theabsorber 104 undergoes a change in response to the radiation that is reflected thereon. The change in theabsorber 104 is detected/monitored by external circuitry (not shown) to determine the temperature of an object (not shown) from which the radiation originated. -
FIG. 2 illustrates an absorption spectrum of thebolometer 100 in the infrared region of radiation. Considering a range of wavelengths extending from approximately eight micrometers (8 μm) to fourteen micrometers (14 μm), thebolometer 100 absorbs approximately 29% of the radiation at eight micrometers and approximately 17% of the radiation at fourteen micrometers. The absorption percentage declines as the wavelength increases from eight micrometers (8 μm) to fourteen micrometers (14 μm). Thebolometer 100 exhibits amaximum absorption percentage 130 of approximately 70% for radiation of approximately 6.5 micrometers (6.5 μm). Further, thebolometer 100 exhibits a cavity resonance in thewavelength zone 134 that, as described below, is relatively narrow. - In the novel and nonobvious bolometer 200 (
FIG. 3 ) described herein, the structure of the bolometer is modified to achieve wide-band radiation absorption in the infrared range. In particular, thebolometer 200 is particularly suited for absorbing infrared radiation in a wavelength range of eight micrometers to fourteen micrometers. - As shown in
FIG. 3 , a semiconductor sensor, shown as aMEMS bolometer 200, includes anabsorber 204 spaced apart from areflector 208. As described below, thebolometer 200 is configurable to absorb/detect any desired wavelength of radiation. - The
absorber 204, which is also referred to herein as an absorber layer, is typically an ultra-thin layer/sheet of platinum having a thickness of approximately ten nanometers (10 nm). In the embodiment, ofFIG. 1 , theabsorber 204 defines alength 216 and awidth 220 of approximately fifty micrometers (50 μm). In another embodiment, theabsorber 204 is formed from any metal and has any size, shape, and thickness, as desired by those of ordinary skill in the art. Theabsorber 204 is shown as being generally flat, but in another embodiment the absorber may have any configuration, as desired by those of ordinary skill in the art, including bent, curved, and other nonplanar configurations. - The
absorber 204 is spaced apart from thereflector 208 by adistance 212, which is approximately three micrometers (3 μm). Thedistance 212 is selected based on a desired wavelength of radiation (or range of wavelengths of radiation) to be detected by thebolometer 200.FIG. 3 is not drawn to scale. Thedistance 212, in the exemplary embodiment, is less than a wavelength (or the shortest wavelength in a range of wavelengths) to be detected by thebolometer 200. The region between theabsorber 204 and thereflector 208 is referred to as acavity 224; accordingly, thedistance 212 is also referred to herein as a cavity distance. In another embodiment, thedistance 212 is between approximately 0.5 micrometers (0.5 μm) and ten micrometers (10 μm), or any other distance as desired by those of ordinary skill in the art. - The
absorber 204 defines a plurality of generallycircular openings 220 that extend completely through the absorber 204 (the perspective view ofFIG. 3 makes the openings appear slightly elliptical). Theabsorber 204 ofFIG. 3 includes six rows with six of theopenings 220 in each row, such that theopenings 220 are arranged in a rectangular array. In another embodiment, theabsorber 204 defines one hundred of theopenings 220 arranged in ten rows of ten openings each. In yet another embodiment, theabsorber 204 defines any number of theopenings 220, arranged in any configuration, and spaced apart by any distance as desired by those of ordinary skill in the art. Also, theopenings 220 may have any shape as desired by those of ordinary skill in the art, such as rectangular, elliptical, and, triangular. Theopenings 220, in one embodiment, are void of any substance except air. In another embodiment, theopenings 220 are at least partially filled with a substance, as desired by those of ordinary skill in the art. - Each
opening 220 defines amaximum width 228 of approximately three micrometers (3 μm). Since, theopenings 220 are generally circular themaximum width 228 corresponds to the diameter of theopenings 220. In the embodiment ofFIG. 3 , eachopening 220 is substantially identical; however, in another embodiment some of the openings have different maximum widths (SeeFIG. 9 ). Theopenings 220 are spaced apart from each other by adistance 232 of approximately two micrometers (2 μm). Themaximum width 228 is less than or equal to thedistance 212. - The
reflector 208, which is also referred to herein as a reflector layer, is typically formed from either platinum or aluminum. As compared to theabsorber 204, thereflector 208 is comparatively thick and defines a thickness of approximately five hundred nanometers (500 nm). Thereflector 208 is approximately the same size in area as theabsorber 104. Thereflector 208 is generally imperforate. In another embodiment, thereflector 208 is formed from any material and defines any size and shape, as desired by those of ordinary skill in the art. - A method of making the
bolometer 200 includes forming theabsorber 204 and thereflector 208. Next, theabsorber 204 is spaced apart from thereflector 208 by thedistance 212. Then, theopenings 220 are formed in theabsorber 204, using any process as desired by those of ordinary skill in the art. Theopenings 220 are sized such that themaximum width 228 is less than thedistance 212, thereby making the openings “sub-wavelength” openings. If theopenings 220 are to be exposed to radiation exhibiting a range of wavelengths and corresponding frequencies, then theopenings 220 are sized so that the maximum width is less than the shortest wavelength of the desired wavelength range. - In operation, the
bolometer 200 is exposed to radiation, typically in the infrared region. The radiation is imparted on thereflector 208. At least a portion of the incident radiation is reflected by thereflector 208 onto theabsorber 204. -
FIG. 4 illustrates the absorption spectrum of thebolometer 200 in an infrared region of radiation. Considering a range of wavelengths extending from approximately eight micrometers (8 μm) to fourteen micrometers (14 μm), thebolometer 200 absorbs approximately 95% of the radiation at eight micrometers and approximately 35% of the radiation at fourteen micrometers. The absorption percentage declines as the wavelength increases from eight micrometers (8 μm) to fourteen micrometers (14 μm). Thebolometer 200 exhibits amaximum absorption percentage 240 of approximately 95% at an optical resonance zone centered at about 8.0 micrometers (8.0 μm). Further, thebolometer 200 exhibits acavity resonance zone 244 between approximately 7.5 micrometers to 8.5 micrometers. - As compared to the
bolometer 100 having animperforate absorber 104, thebolometer 200 withsub-wavelength openings 220 exhibits a greater maximum absorption percentage 240 (compare 130 ofFIG. 2 to 240 ofFIG. 4 ). Additionally, thecavity resonance 244 is wider in thebolometer 200 as compared to thecavity resonance 134 of thebolometer 100. In particular, the width of thecavity resonance 244 and themaximum absorption percentage 240 are increased when themaximum width 228 of theopenings 220 is approximately, equal to thedistance 212. Furthermore, the graph ofFIG. 4 shows that thesub-wavelength openings 220 increase the FWHM (Full Width at Half Maximum) of optical resonance between theabsorber 204 and thereflector 208. - As the
maximum width 228 of theopenings 220 is reduced, thecavity resonance 244 narrows and themaximum absorption percentage 240 decreases. In particular, as the maximum width of theopenings 220 is reduced to zero the results converge toward the results achieved with animperforate absorber 104, as plotted inFIG. 2 . - As shown in
FIG. 5 , another embodiment of aMEMS bolometer 300 includes anabsorber layer 304 spaced apart from a steppedreflector layer 308. Theabsorber layer 304 is identical to theabsorber layer 204 ofFIG. 3 , and defines a plurality ofopenings 306 that are identical to theopenings 220. - The
reflector layer 308 includes sixupper segments 312 and fivelower segments 316. The 312, 316 are also referred to as reflective components. Ansegments upper surface 314 of thesegments 312 defines an upper level, and anupper surface 318 of thesegments 316 defines a lower level. Thesegments 312 are interlaced with thesegments 316. Thesegments 312 and thesegments 316 define awidth 328 of approximately 2.5 micrometers (2.5 μm) and are made of a high-index material. Thewidth 328 is less than amaximum width 332 of the openings in theabsorber 304. - The
upper surfaces 314 of the upper level are spaced apart from theupper surfaces 318 of the lower level by adistance 330. Thedistance 330 is approximately five micrometers (5.0 μm). In another embodiment, thereflector layer 308 includes any number of the 312, 316, as desired by those of ordinary skill in the art. Additionally, thesegments 312, 316 may have any width and thesegments distance 330 is any magnitude as desired by those of ordinary skill in the art. Accordingly, in one embodiment, thesegments 312 have a different width than thesegments 316. The 312, 316, in another embodiment, are formed from any material, as desired by those of ordinary skill in the art.segments - The upper level of the
segments 312 and the lower level of thesegments 316 each operate as a high-contrast grating reflector. A low-index material is interposed between the 312, 316 and thesegments segments 316 to maintain the position thereof. The 312, 316 are formed from platinum, aluminum, or any material as desired by those of ordinary skill in the art.segments - The
absorber layer 304 is spaced apart from the upper level by a distance 320 (a first cavity distance), which is equal to approximately three micrometers (3 μm). Theabsorber layer 304 is spaced apart from the second level by a distance 324 (a second cavity distance), which is equal to approximately eight micrometers (8 μm). -
FIG. 6 illustrates an absorption spectrum of thebolometer 300 in the infrared region of radiation. Considering a range of wavelengths extending from approximately six micrometers (6 μm) to fourteen micrometers (14 μm), thebolometer 300 exhibits a firstoptical resonance zone 350, a secondoptical resonance zone 354, and three 358, 362, 366. Thedestructive interference zones bolometer 300 exhibits two 350, 354 due to the steppedoptical resonance zones reflector 308 defining two surfaces (i.e. the upper surface and the lower surface). At the firstoptical resonance zone 350, thebolometer 300 absorbs approximately 75% of the radiation at approximately seven micrometers (7.0 μm). At the secondoptical resonance zone 354 the bolometer absorbs approximately 60% of the radiation at approximately 8.5 micrometers. The absorption percentage forms a trough between the 350, 354, which is one of theoptical resonance zones destructive interference zones 362. As the wavelength of the radiation increases from approximately nine micrometers (9 μm) to fourteen micrometers (16 μm) the absorption percentage gradually decreases. Both 312, 316 work simultaneously to reflect the radiation and to form the absorption spectrum.segments - The wavelengths at which the
358, 362, 366 occur are at least partially based on thedestructive interference zones 320, 324. In particular, thedistances destructive interference zone 358 is based on thedistance 320 and occurs at half of the incident wavelength (212). Thus, in the illustrated example, thedestructive interference zone 358 affects radiation having a wavelength of approximately six micrometers (6 μm). Thedestructive interference zone 362 is based on thedistance 324 and occurs at the full value of the incident wavelength (λ). Thus, in the illustrated example, thedestructive interference zone 362 affects radiation having a wavelength of approximately six micrometers (6 μm). Thedestructive interference zone 366 is based on thedistance 324 and occurs at half of the incident wavelength (212). Thus, in the illustrated example, thedestructive interference zone 366 affects radiation having a wavelength of approximately sixteen micrometers (16 μm). - The
reflector 308 having two layers achieves a filer-like response in the absorption spectrum that is dependent on thedistance 320 and thedistance 324, among other factors. - In another embodiment, the
312, 316 are formed from five hundred nanometer thick “bars” of silicon arranged in the high contrast grating configuration ofsegments FIG. 5 . In this embodiment, the absorption response shows a filter-like response that is similar to the absorption spectrum shown inFIG. 6 . - In yet another embodiment, the
312, 316 are formed from five hundred nanometer thick “bars” of silicon arranged in the high contrast grating configuration ofsegments FIG. 5 . The 312, 316 are supported by a trenched structure 410 (seesegments FIG. 7 ) formed from silicon dioxide. - In a further embodiment, the
312, 316 and the trenchedsegments structure 410 are integrally formed from silicon and are arranged in the high contrast grating configuration ofFIG. 5 . - In another embodiment, the
312, 316 and the trenchedsegments structure 410 are integrally formed from aluminum and are arranged in the high contrast grating configuration ofFIG. 5 . - As shown in
FIG. 7 , another embodiment of aMEMS bolometer 400 includes anabsorber layer 404 spaced apart from a steppedreflector layer 408. Theabsorber layer 404 is identical to theabsorber layer 204 ofFIG. 3 , and defines a plurality ofopenings 406 that are identical to theopenings 220. - The
reflector 408 includes a substrate referred to as a trenchedstructure 410 and a layer ofmaterial 424 deposited thereon. The trenchedstructure 410 defines fivetrenches 412, which are generally parallel to each other. The trenchedstructure 410 is formed from silicon. In another embodiment, the trenchedstructure 410 is formed form silicon dioxide, aluminum, or any other material as desired by those of ordinary skill in the art. Also in another embodiment, the trenchedstructure 410 defines any desired number oftrenches 412 of any shape or configuration. - The
material 424 is a metal layer that is deposited onto the trenchedstructure 410 by sputtering or by any deposition process desired by those of ordinary skill in the art. Thematerial 424 is aluminum, platinum, or any other metal as desired by those of ordinary skill in the art. The material defines sixupper surfaces 416, fivelower surfaces 420, and a plurality ofvertical surfaces 428. Theupper surfaces 416 define an upper level, and thelower surfaces 420 define a lower level. Theupper surfaces 416 define awidth 432 of approximately 2.5 micrometers (2.5 μm) wide. Thelower surfaces 420 are slightly narrower. Theupper surfaces 416 are spaced apart from theabsorber 204 by thedistance 406, which is approximately three micrometers (3 μm). Thelower surfaces 420 are spaced apart from theabsorber 204 by thedistance 414, which is approximately six micrometers (6 μm). Theupper surfaces 416 are spaced apart from thelower surfaces 420 by adistance 430. Thedistance 430 is approximately five micrometers (5 μm). Thevertical surfaces 428 connect theupper surfaces 416 to the lower surfaces 420. The material 424 as athickness 436 of approximately five hundred nanometers, such that thematerial 424 is thicker than the skin depth of the radiation on thematerial 424. So long as thematerial 424 is thicker than the skin depth of the radiation, the composition of the trenchedstructure 410 is immaterial. -
FIG. 8 illustrates the absorption spectrum of thebolometer 400 in the infrared region of radiation. Considering a range of wavelengths extending from approximately six micrometers (6 μm) to fourteen micrometers (14 μm), thebolometer 400 exhibits anoptical resonance point 450, two destructive interference points 458, 466, and apass band 470. Due to the 406, 414 thedistances bolometer 400 exhibits a blendedoptical resonance zone 450 even though thereflector 408 is stepped. At the center of theoptical resonance zone 450, thebolometer 400 absorbs approximately 95% of the radiation at approximately 7.5 micrometers (7.5 μm). -
FIG. 8 also shows that the absorption response at thedestructive interference zone 458 has been brought down to approximately 0% absorption, as compared to thedestructive interference zone 358 ofFIG. 6 . Similarly, the absorption at thedestructive interference zone 466 has been brought down to approximately 0% absorption, as compared to thedestructive interference zone 366 ofFIG. 6 . The reduction in absorption at the 212 458, 466 is due to thedestructive interference zones material 424 and the 406, 410, among other factors.distances - The
pass band 470 exhibits a peak absorption at theoptical resonance point 450 and tapers down at the boundaries thereof. - As shown in
FIG. 9 , aMEMS bolometer 500 includes anabsorber 504 and a steppedreflector 508. Thereflector 508 is identical to thereflector 408 ofFIG. 7 . Thereflector 508 includes a material 512 that is identical to thematerial 424 and defines a plurality ofupper surfaces 516 and a plurality oflower surfaces 520. Theupper surfaces 516 are identical to theupper surfaces 416, and thelower surfaces 520 are identical to the lower surfaces 420. - The
absorber 504 is spaced apart from theupper surfaces 516 by adistance 506, which is approximately three micrometers (3 μm). Theabsorber 504 is spaced apart from thelower surfaces 520 by adistance 510, which is approximately six micrometers (6 μm). - The
absorber 504 defines a plurality of 514, 518 that extend completely through theopenings absorber 504. Theopenings 514 are generally circular (the perspective view ofFIG. 9 makes the openings appear slightly elliptical). Eachopening 514 defines amaximum width 524 of approximately four micrometers (4 μm). Theopenings 518 are also generally circular. Eachopening 518 defines amaximum width 528 of approximately two micrometers (2 μm). Since, the 514, 518 are generally circular theopenings 524, 528 correspond to the diameters of themaximum widths 514, 518. Theopenings maximum width 524 is less than or equal to thedistance 510, and themaximum width 528 is less than or equal to thedistance 506. -
FIG. 10 shows an absorption spectrum of thebolometer 500 ofFIG. 9 . As shown, mixing 514, 518 of differentsub-wavelength openings 524, 528 with the steppedmaximum widths reflector 508 having the material 512 widens apass band 570 of the response as compared to the pass band of 450 shown inFIG. 8 . -
FIG. 11 shows another embodiment of abolometer 600 that includes anabsorber 604 and areflector 608. Theabsorber 604 defines a plurality ofopenings 612 therethrough. Thereflector 608 also defines a plurality ofopenings 616 therethrough. Theabsorber 604 is spaced apart from thereflector 608 by adistance 620. Theopenings 612 are aligned with theopenings 616. Theopenings 616 serve to widen the cavity resonance of an absorption response (not shown) of thebolometer 600. The 612, 616 define aopenings maximum width 624 that is less than thedistance 620.FIG. 11 is not drawn to scale. -
FIG. 12 shows another embodiment of abolometer 700 that includes anabsorber 704 and areflector 708. Theabsorber 704 defines a plurality ofopenings 712 therethrough. Thereflector 708 also defines a plurality ofopenings 716 therethrough. Theabsorber 704 is spaced apart from thereflector 708 by adistance 720. Theopenings 712 are misaligned with theopenings 716 as shown by the position 724 (shown in phantom) of the one of theopenings 716 on theabsorber 704. Theopenings 716 serve to widen the cavity resonance of the absorption response of thebolometer 700. The 712, 716 define aopenings maximum width 728 that is less than thedistance 720.FIG. 12 is not drawn to scale. - While the disclosure has been illustrated and described in detail in the drawings and foregoing description, the same should be considered as illustrative and not restrictive in character. It is understood that only the preferred embodiments have been presented and that all changes, modifications and further applications that come within the spirit of the disclosure are desired to be protected.
Claims (20)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/970,786 US9274005B2 (en) | 2012-08-23 | 2013-08-20 | Device and method for increasing infrared absorption in MEMS bolometers |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261692406P | 2012-08-23 | 2012-08-23 | |
| US13/970,786 US9274005B2 (en) | 2012-08-23 | 2013-08-20 | Device and method for increasing infrared absorption in MEMS bolometers |
Publications (2)
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| US20140054462A1 true US20140054462A1 (en) | 2014-02-27 |
| US9274005B2 US9274005B2 (en) | 2016-03-01 |
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| US13/970,786 Expired - Fee Related US9274005B2 (en) | 2012-08-23 | 2013-08-20 | Device and method for increasing infrared absorption in MEMS bolometers |
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| Country | Link |
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| US (1) | US9274005B2 (en) |
| JP (1) | JP6235016B2 (en) |
| CN (1) | CN104755890B (en) |
| DE (1) | DE112013004113T5 (en) |
| TW (1) | TWI613424B (en) |
| WO (1) | WO2014031876A1 (en) |
Cited By (4)
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| WO2016094693A1 (en) * | 2014-12-10 | 2016-06-16 | Robert Bosch Gmbh | Resistive switching for mems devices |
| EP3153831A1 (en) * | 2015-10-09 | 2017-04-12 | Commissariat à l'Energie Atomique et aux Energies Alternatives | Bolometer with high spectral sensitivity |
| FR3059824A1 (en) * | 2016-12-07 | 2018-06-08 | Ulis | INFRARED IMAGE SENSOR |
| US11215510B2 (en) * | 2016-05-13 | 2022-01-04 | Mitsubishi Electric Corporation | Thermal infrared detector and manufacturing method for thermal infrared detector |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN113614499B (en) | 2019-03-11 | 2025-09-30 | 泰立戴恩菲力尔商业系统公司 | Microbolometer systems and methods |
| CN110118604B (en) * | 2019-05-30 | 2020-03-13 | 中国科学院长春光学精密机械与物理研究所 | Wide-spectrum microbolometer based on mixed resonance mode and preparation method thereof |
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- 2013-08-22 JP JP2015528658A patent/JP6235016B2/en not_active Expired - Fee Related
- 2013-08-22 WO PCT/US2013/056226 patent/WO2014031876A1/en not_active Ceased
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Also Published As
| Publication number | Publication date |
|---|---|
| CN104755890B (en) | 2018-09-14 |
| TW201418678A (en) | 2014-05-16 |
| DE112013004113T5 (en) | 2015-05-07 |
| WO2014031876A1 (en) | 2014-02-27 |
| JP2015531869A (en) | 2015-11-05 |
| CN104755890A (en) | 2015-07-01 |
| US9274005B2 (en) | 2016-03-01 |
| JP6235016B2 (en) | 2017-11-22 |
| TWI613424B (en) | 2018-02-01 |
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