US20130168261A1 - Anode for cathodic protection and method for manufacturing the same - Google Patents
Anode for cathodic protection and method for manufacturing the same Download PDFInfo
- Publication number
- US20130168261A1 US20130168261A1 US13/819,643 US201113819643A US2013168261A1 US 20130168261 A1 US20130168261 A1 US 20130168261A1 US 201113819643 A US201113819643 A US 201113819643A US 2013168261 A1 US2013168261 A1 US 2013168261A1
- Authority
- US
- United States
- Prior art keywords
- ribbon
- cathodic protection
- metal
- anode
- anode according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000004210 cathodic protection Methods 0.000 title claims abstract description 19
- 238000000034 method Methods 0.000 title claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 229910052751 metal Inorganic materials 0.000 claims abstract description 28
- 239000002184 metal Substances 0.000 claims abstract description 28
- 239000011150 reinforced concrete Substances 0.000 claims description 9
- 239000007787 solid Substances 0.000 claims description 9
- 230000003197 catalytic effect Effects 0.000 claims description 5
- 238000004080 punching Methods 0.000 claims description 5
- 230000002787 reinforcement Effects 0.000 claims description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 238000006073 displacement reaction Methods 0.000 claims description 3
- 229910000510 noble metal Inorganic materials 0.000 claims description 2
- 238000003825 pressing Methods 0.000 claims 2
- 238000005520 cutting process Methods 0.000 abstract description 11
- 239000004567 concrete Substances 0.000 description 8
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 4
- 238000009434 installation Methods 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000002161 passivation Methods 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000001805 chlorine compounds Chemical class 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 229910001294 Reinforcing steel Inorganic materials 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F13/00—Inhibiting corrosion of metals by anodic or cathodic protection
- C23F13/02—Inhibiting corrosion of metals by anodic or cathodic protection cathodic; Selection of conditions, parameters or procedures for cathodic protection, e.g. of electrical conditions
- C23F13/06—Constructional parts, or assemblies of cathodic-protection apparatus
- C23F13/08—Electrodes specially adapted for inhibiting corrosion by cathodic protection; Manufacture thereof; Conducting electric current thereto
- C23F13/10—Electrodes characterised by the structure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D31/00—Other methods for working sheet metal, metal tubes, metal profiles
- B21D31/04—Expanding other than provided for in groups B21D1/00 - B21D28/00, e.g. for making expanded metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D31/00—Other methods for working sheet metal, metal tubes, metal profiles
- B21D31/04—Expanding other than provided for in groups B21D1/00 - B21D28/00, e.g. for making expanded metal
- B21D31/043—Making use of slitting discs or punch cutters
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F2201/00—Type of materials to be protected by cathodic protection
- C23F2201/02—Concrete, e.g. reinforced
Definitions
- the invention relates to the field of cathodic protection of reinforced concrete structures, and in particular to a design of anode particularly efficient in terms of electrical resistance per unit length and of flexibility, and particularly safe to install and handle.
- the invention also relates to the method of production of such anode.
- cathodic protection of reinforced concrete is practised by coupling anodic structures of various kinds to the concrete, respect to which the reinforcement to be protected acts as a cathodic counterelectrode; the electrical currents involved supported by an external rectifier transit across the electrolyte consisting of the porous concrete partially soaked with a salty solution.
- the anodes commonly used for the cathodic protection of reinforced concrete consist of a titanium substrate coated with transition metal oxides or other types of catalysts for anodic oxygen evolution.
- European Patent EP458951 discloses a grid-type electrodic structure for cathodic protection consisting of a plurality of metal ribbons having an electrocatalytic coating, said metal ribbons having voids of different geometries.
- This type of ribbons can be manufactured by punching of solid metal ribbons or more commonly by the traditional methods of metal expansion wherein a metal sheet is expanded by pressuring and punching through a series of knives arranged orthogonal to the advancement direction of the ribbon itself.
- This first step allows obtaining an expanded metal sheet.
- Such sheet is then subjected to a second step of cutting suitable for obtaining ribbons of the required dimensions.
- Said expanded metal ribbons present meshes having voids of rhomboidal shape with the major diagonal oriented orthogonal to the ribbon length.
- This method of manufacturing has the inconvenience of producing metal ribbons with meshes having cutting side protrusions automatically formed during the operation of cutting, making these anodes difficult to handle and the installation phase accordingly dangerous.
- the invention relates to an anode in form of mesh ribbon for systems of cathodic protection, for instance of cathodic protection of reinforced concrete structures, overcoming the inconveniences of the prior art, whose edges are substantially free of discontinuities in form of cutting protrusions and have a sinusoidal shape.
- the invention relates to a method for manufacturing said anode.
- the invention relates to a cathodic protection system comprising at least one anode in form of mesh ribbon whose edges are substantially free of cutting protrusions.
- the anode according to the invention consists of a ribbon of expanded metal characterised by meshes with rhomboidal shaped voids with the major diagonal oriented along the direction of the ribbon length.
- the lateral edges of the ribbon have a sinusoidal profile and are free of cutting protrusions.
- an anode for cathodic protection displays a remarkably reduced ohmic resistance per unit length, for instance up to 4-fold reduced, with respect to the anodes of the prior art.
- the lower electrical resistance makes possible to reduce the number of electrical connections, for instance in a grid system, with sensible savings of material and installation time.
- the metal mesh ribbon is made of titanium.
- the metal mesh ribbon is coated with a catalytic coating containing noble metals or oxides thereof.
- the dimensions of the ribbon can have a width ranging from 3 mm to 100 mm with a thickness of 0.25 mm to 2.5 mm and a length of 1 m to 150 m.
- FIG. 1A shows a top-view of a traditional expanded metal anode.
- FIG. 1B shows a top-view of an expanded metal anode according to the invention.
- FIG. 1A shows a top view of the traditional anode in which are distinguishable cutting protrusions 1 due to the manufacturing method including a cutting step, the rhomboidal geometry with major diagonal 3 of rhomboidal voids arranged in the direction of the ribbon width and the minor diagonal 4 of the same arranged in the direction of the ribbon length.
- FIG. 1B shows a top-view of the anode according to the invention in which are distinguishable non-cutting blunt lateral edges 2 , the rhomboidal geometry with major diagonal 3 of rhomboidal voids arranged in the direction of the ribbon length and the minor diagonal 4 of the same arranged in the direction of the ribbon width.
- Anodes labelled A and B are anodes of rhomboidal geometry with the major diagonal of rhomboids oriented orthogonal to the ribbon length likewise depicted in FIG. 1A , traditionally obtained by longitudinal expansion with respect to the displacement direction of a solid metal ribbon.
- Anodes labelled C and D are anodes of rhomboidal geometry according to one embodiment of the invention, likewise depicted in FIG. 1B .
- Anodes C and D were prepared by orthogonal expansion with respect to the displacement direction of a solid metal ribbon allowed to run in an apparatus along a parallel row of knives which expand the solid ribbon in an orthogonal direction by pressuring and punching.
- the ribbon manufacturing is completed by means of a last series of knives, having blades of predefined length higher than the blades of previous knives, which upon applying a pressure are suitable for modelling the lateral edge of the ribbon as depicted in FIG. 1B .
- this method has the advantage of providing an expanded metal ribbon free of longitudinally-extending solid sections which, being not subsequently cut, does not present any cutting edge and is therefore much safer and easy to handle during the installation.
- This method moreover allows to advantageously obtain a metal ribbon of the desired length directly upon completion of the expansion.
- Such method of production furthermore allows obtaining ribbons of higher length than the traditional method thereby facilitating big size installation which would require connections of multiple ribbons, with a lower solidity of the overall anodic system.
- the anodes of the invention display an ohmic resistance about 60% lower.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Prevention Of Electric Corrosion (AREA)
- Electrolytic Production Of Metals (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Building Environments (AREA)
- Cell Electrode Carriers And Collectors (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT001689A ITMI20101689A1 (it) | 2010-09-17 | 2010-09-17 | Anodo per protezione catodica e metodo per il suo ottenimento |
| ITMI2010A001689 | 2010-09-17 | ||
| PCT/EP2011/066021 WO2012035107A1 (en) | 2010-09-17 | 2011-09-15 | Anode for cathodic protection and method for manufacturing the same |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP2011/066021 A-371-Of-International WO2012035107A1 (en) | 2010-09-17 | 2011-09-15 | Anode for cathodic protection and method for manufacturing the same |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US14/919,191 Continuation US20160040302A1 (en) | 2010-09-17 | 2015-10-21 | Anode for cathodic protection and method for manufacturing the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US20130168261A1 true US20130168261A1 (en) | 2013-07-04 |
Family
ID=43738911
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US13/819,643 Abandoned US20130168261A1 (en) | 2010-09-17 | 2011-09-15 | Anode for cathodic protection and method for manufacturing the same |
| US14/919,191 Abandoned US20160040302A1 (en) | 2010-09-17 | 2015-10-21 | Anode for cathodic protection and method for manufacturing the same |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US14/919,191 Abandoned US20160040302A1 (en) | 2010-09-17 | 2015-10-21 | Anode for cathodic protection and method for manufacturing the same |
Country Status (24)
| Country | Link |
|---|---|
| US (2) | US20130168261A1 (es) |
| EP (1) | EP2616568B1 (es) |
| JP (1) | JP6068343B2 (es) |
| KR (1) | KR20140001837A (es) |
| CN (1) | CN103119201B (es) |
| AR (1) | AR084116A1 (es) |
| AU (1) | AU2011303882B2 (es) |
| BR (1) | BR112013006334B1 (es) |
| CA (1) | CA2808397C (es) |
| CO (1) | CO6680713A2 (es) |
| DK (1) | DK2616568T3 (es) |
| EA (1) | EA024024B1 (es) |
| EC (1) | ECSP13012490A (es) |
| ES (1) | ES2711605T3 (es) |
| IT (1) | ITMI20101689A1 (es) |
| MA (1) | MA34596B1 (es) |
| MX (1) | MX2013002844A (es) |
| MY (1) | MY159927A (es) |
| NZ (1) | NZ606985A (es) |
| PE (1) | PE20140396A1 (es) |
| PL (1) | PL2616568T3 (es) |
| PT (1) | PT2616568T (es) |
| SG (1) | SG188189A1 (es) |
| WO (1) | WO2012035107A1 (es) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104763506A (zh) * | 2015-04-09 | 2015-07-08 | 上海天纳克排气系统有限公司 | 排气系统 |
| US10376946B1 (en) * | 2016-05-25 | 2019-08-13 | James E. Ealer, Sr. | System and method of making an expanded metal gutter cover having a solid edge margin |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4923583A (en) * | 1985-11-04 | 1990-05-08 | Olin Corporation | Electrode elements for filter press membrane electrolytic cells |
| CA2078616A1 (en) * | 1991-09-20 | 1993-03-21 | James B. Bushman | Cathodic protection anode and method |
| US5421968A (en) * | 1985-05-07 | 1995-06-06 | Eltech Systems Corporation | Cathodic protection system for a steel-reinforced concrete structure |
| US6139705A (en) * | 1998-05-06 | 2000-10-31 | Eltech Systems Corporation | Lead electrode |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR450528A (fr) * | 1912-10-24 | 1913-03-27 | The Universal Metal Lath And Patent Company | Machine à fendre et à repousser les feuilles de métal |
| US2223497A (en) * | 1940-03-01 | 1940-12-03 | Bostwick Steel Lath Company | Expanded metal lath cutting machine |
| US3162925A (en) * | 1962-04-24 | 1964-12-29 | Robert M Felsenthal | Apparatus for producing expanded metal |
| US3607411A (en) * | 1968-03-21 | 1971-09-21 | Exmet Corp | Prestretched expanded metal and method of making it |
| JPS50140359A (es) * | 1974-04-27 | 1975-11-11 | ||
| IT209004Z2 (it) * | 1986-12-30 | 1988-09-02 | Magneti Marelli Spa | Macchina per la realizzazione di un nastro grigliato di lega di metallo o di materia plastica utilizzabile per la fabbricazione di piastre per accumulatori |
| GB8903321D0 (en) * | 1989-02-14 | 1989-04-05 | Ici Plc | Metal mesh and production thereof |
| CA2018869A1 (en) * | 1989-07-07 | 1991-01-07 | William A. Kovatch | Mesh anode and mesh separator for use with steel-reinforced concrete |
| US5062934A (en) | 1989-12-18 | 1991-11-05 | Oronzio Denora S.A. | Method and apparatus for cathodic protection |
| AU5257996A (en) * | 1995-03-24 | 1996-10-16 | Alltrista Corporation | Jacketed sacrificial anode cathodic protection system |
| JP4899239B2 (ja) * | 2000-08-03 | 2012-03-21 | パナソニック株式会社 | エキスパンド網目シートの製造方法および鉛蓄電池用格子体の製造方法 |
| ITMI20080714A1 (it) * | 2008-04-18 | 2009-10-19 | Industrie De Nora S P A | Anodo per protezione catodica |
-
2010
- 2010-09-17 IT IT001689A patent/ITMI20101689A1/it unknown
-
2011
- 2011-07-04 AR ARP110102393A patent/AR084116A1/es active IP Right Grant
- 2011-09-15 CA CA2808397A patent/CA2808397C/en active Active
- 2011-09-15 AU AU2011303882A patent/AU2011303882B2/en active Active
- 2011-09-15 ES ES11757856T patent/ES2711605T3/es active Active
- 2011-09-15 EP EP11757856.7A patent/EP2616568B1/en active Active
- 2011-09-15 PT PT11757856T patent/PT2616568T/pt unknown
- 2011-09-15 EA EA201390399A patent/EA024024B1/ru not_active IP Right Cessation
- 2011-09-15 US US13/819,643 patent/US20130168261A1/en not_active Abandoned
- 2011-09-15 PE PE2013000509A patent/PE20140396A1/es active IP Right Grant
- 2011-09-15 KR KR1020137006504A patent/KR20140001837A/ko not_active Ceased
- 2011-09-15 DK DK11757856.7T patent/DK2616568T3/en active
- 2011-09-15 MA MA35798A patent/MA34596B1/fr unknown
- 2011-09-15 WO PCT/EP2011/066021 patent/WO2012035107A1/en not_active Ceased
- 2011-09-15 MY MYPI2013000543A patent/MY159927A/en unknown
- 2011-09-15 NZ NZ606985A patent/NZ606985A/en unknown
- 2011-09-15 SG SG2013007562A patent/SG188189A1/en unknown
- 2011-09-15 CN CN201180044409.8A patent/CN103119201B/zh active Active
- 2011-09-15 JP JP2013528672A patent/JP6068343B2/ja active Active
- 2011-09-15 BR BR112013006334A patent/BR112013006334B1/pt active IP Right Grant
- 2011-09-15 MX MX2013002844A patent/MX2013002844A/es active IP Right Grant
- 2011-09-15 PL PL11757856T patent/PL2616568T3/pl unknown
-
2013
- 2013-03-15 EC ECSP13012490 patent/ECSP13012490A/es unknown
- 2013-03-15 CO CO13052521A patent/CO6680713A2/es unknown
-
2015
- 2015-10-21 US US14/919,191 patent/US20160040302A1/en not_active Abandoned
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5421968A (en) * | 1985-05-07 | 1995-06-06 | Eltech Systems Corporation | Cathodic protection system for a steel-reinforced concrete structure |
| US4923583A (en) * | 1985-11-04 | 1990-05-08 | Olin Corporation | Electrode elements for filter press membrane electrolytic cells |
| CA2078616A1 (en) * | 1991-09-20 | 1993-03-21 | James B. Bushman | Cathodic protection anode and method |
| US6139705A (en) * | 1998-05-06 | 2000-10-31 | Eltech Systems Corporation | Lead electrode |
Also Published As
| Publication number | Publication date |
|---|---|
| MY159927A (en) | 2017-02-15 |
| ES2711605T3 (es) | 2019-05-06 |
| CA2808397C (en) | 2019-12-03 |
| PE20140396A1 (es) | 2014-04-23 |
| ECSP13012490A (es) | 2013-04-30 |
| PT2616568T (pt) | 2019-02-25 |
| HK1185386A1 (zh) | 2014-02-14 |
| BR112013006334B1 (pt) | 2020-01-21 |
| DK2616568T3 (en) | 2019-02-18 |
| CN103119201B (zh) | 2015-12-16 |
| AU2011303882A1 (en) | 2013-02-28 |
| KR20140001837A (ko) | 2014-01-07 |
| MA34596B1 (fr) | 2013-10-02 |
| JP6068343B2 (ja) | 2017-01-25 |
| EA201390399A1 (ru) | 2013-07-30 |
| AR084116A1 (es) | 2013-04-24 |
| MX2013002844A (es) | 2013-06-18 |
| AU2011303882B2 (en) | 2015-01-22 |
| ITMI20101689A1 (it) | 2012-03-18 |
| EP2616568B1 (en) | 2018-11-21 |
| CA2808397A1 (en) | 2012-03-22 |
| CN103119201A (zh) | 2013-05-22 |
| PL2616568T3 (pl) | 2019-05-31 |
| SG188189A1 (en) | 2013-04-30 |
| BR112013006334A2 (pt) | 2016-06-21 |
| NZ606985A (en) | 2014-12-24 |
| WO2012035107A1 (en) | 2012-03-22 |
| US20160040302A1 (en) | 2016-02-11 |
| CO6680713A2 (es) | 2013-05-31 |
| EA024024B1 (ru) | 2016-08-31 |
| JP2013537261A (ja) | 2013-09-30 |
| EP2616568A1 (en) | 2013-07-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| AS | Assignment |
Owner name: INDUSTRIE DE NORA S.P.A., ITALY Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:MOJANA, CORRADO;TREMOLADA, SIMONE;REEL/FRAME:029889/0195 Effective date: 20130125 |
|
| STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |